CN112940431B - Laser-induced fluorescence emission composition and patterned fluorescence emission method - Google Patents
Laser-induced fluorescence emission composition and patterned fluorescence emission method Download PDFInfo
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- CN112940431B CN112940431B CN202110154996.1A CN202110154996A CN112940431B CN 112940431 B CN112940431 B CN 112940431B CN 202110154996 A CN202110154996 A CN 202110154996A CN 112940431 B CN112940431 B CN 112940431B
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Abstract
本发明涉及荧光材料技术领域，具体涉及一种激光诱导的荧光发射组合物及图案化荧光发射方法。本发明的组合物由如下重量份的组分组成：有机颜料0.01～10份；聚合物树脂90～99.99份。所述聚合物树脂为链段含有酯基或羟基的树脂。本发明采用如下方法获得图案化荧光发射：用激光辐照所述组合物表面，形成辐照区域；然后用紫外光诱导组合物激光辐照的区域，使所述激光辐照区域产生荧光发射。本发明操作简便，而且安全、环保、能耗低，非常适合工业上的大规模化生产，具有良好的应用前景。
The invention relates to the technical field of fluorescent materials, in particular to a laser-induced fluorescent emission composition and a patterned fluorescent emission method. The composition of the invention consists of the following components in parts by weight: 0.01-10 parts of organic pigment; 90-99.99 parts of polymer resin. The polymer resin is a resin whose chain segment contains ester groups or hydroxyl groups. The present invention adopts the following method to obtain patterned fluorescent emission: irradiating the surface of the composition with laser to form an irradiated area; then using ultraviolet light to induce the laser irradiated area of the composition, so that the laser irradiated area produces fluorescent emission. The invention has the advantages of simple operation, safety, environmental protection and low energy consumption, is very suitable for industrial large-scale production, and has good application prospects.
Description
技术领域technical field
本发明涉及荧光材料技术领域，具体涉及一种激光诱导的荧光发射组合物及图案化荧光发射方法。The invention relates to the technical field of fluorescent materials, in particular to a laser-induced fluorescent emission composition and a patterned fluorescent emission method.
背景技术Background technique
防伪标志是能粘贴、全国315产品防伪查询中心制作印刷、粘贴在物品的表面，或包装上的物附属物(如商品吊牌、合格证以及防伪证卡)上，具有防伪作用的标志。现有的防伪标志大多是在产品表面外加各种可变色的掩膜。The anti-counterfeiting mark is a mark that can be pasted, printed, and pasted on the surface of the article, or on the appendages on the package (such as commodity tags, certificates of conformity, and anti-counterfeiting cards), and has anti-counterfeiting effects. Most of the existing anti-counterfeiting marks are to add various color-changing masks on the product surface.
目前防伪的手段有滴水变色(或消失)、高温变色(或消失)、埋线、紫外照射变色(或消失)等传统印刷技术，以及二维码、查询码等数码防伪技术。紫外照射变色(或消失)的技术通常是利用具有荧光特性的分子，这些荧光分子在可见光下为一种颜色，而在紫外光照射下，由于产生了荧光发射而产生另外一种荧光颜色。The current anti-counterfeiting methods include traditional printing technologies such as dripping water discoloration (or disappearance), high temperature discoloration (or disappearance), thread embedding, ultraviolet radiation discoloration (or disappearance), and digital anti-counterfeiting technologies such as QR codes and query codes. The technology of changing color (or disappearing) by ultraviolet irradiation usually utilizes molecules with fluorescent properties, which are one color under visible light, and produce another fluorescent color due to fluorescence emission under ultraviolet light irradiation.
然而，普通防伪标志作为印刷品，其制备技术十分成熟，且制造技术过于简单，这导致其易于被仿制而失去防伪作用。因此，不断开发新的防伪标志制造技术非常有必要。However, ordinary anti-counterfeiting marks are printed matter, and their preparation technology is very mature, and the manufacturing technology is too simple, which makes it easy to be imitated and loses its anti-counterfeiting effect. Therefore, it is very necessary to continuously develop new anti-counterfeiting mark manufacturing technology.
激光由于同时具备光、热效应，一般说来，当聚合物被一定能量的激光辐照后，其形态、链段、结晶程度会发生改变。近年来激光与聚合物相互作用广受关注，现已被应用于激光标记、激光写入技术、选择性激光烧结等领域。由于聚合物被激光照射后的外观与其组成、激光照射参数等各种工艺条件都有关联，因此难以仿制。如果能够将激光加工聚合物的方法应用在防伪标志中，将能够大幅度增加仿制防伪标志的难度。但是，激光加工生产的聚合物制件本身并没有变色的功能，不能够直接用作防伪标志。Because the laser has both light and thermal effects, generally speaking, when the polymer is irradiated by a certain energy laser, its shape, chain segment, and crystallization degree will change. In recent years, the interaction between laser and polymer has attracted wide attention, and has been applied in laser marking, laser writing technology, selective laser sintering and other fields. Because the appearance of the polymer after laser irradiation is related to various process conditions such as its composition and laser irradiation parameters, it is difficult to imitate. If the method of laser processing polymers can be applied to anti-counterfeiting marks, it will greatly increase the difficulty of imitating anti-counterfeiting marks. However, the polymer parts produced by laser processing do not have the function of discoloration and cannot be directly used as anti-counterfeiting marks.
为了使激光加工生产的聚合物制件产生变色的功能，可以将有机颜料分子加入这些聚合物中。但是，大多数有机颜料分子只能在极稀溶液中呈现出较强的荧光发射，而在高浓度的溶液或者固态时，其荧光发射会被减弱甚至完全消失，这种现象叫聚集态诱导猝灭。由于聚集态诱导猝灭的问题，获得固态的荧光发射材料非常困难。In order to make the polymer parts produced by laser processing have the function of changing color, organic pigment molecules can be added to these polymers. However, most organic pigment molecules can only show strong fluorescence emission in very dilute solution, but in high concentration solution or solid state, the fluorescence emission will be weakened or even disappear completely. This phenomenon is called aggregation-induced quenching. off. Due to the problem of aggregation-induced quenching, it is very difficult to obtain solid-state fluorescent emitting materials.
例如，喹吖啶酮分子由于具有五个芳杂环，分子内共轭形成大Π键，从而使得分子具有平面刚性结构，无法发生旋转，同时喹吖啶酮分子之间还存在连续的氢键和Π-Π相互作用，这些强相互作用使得喹吖啶酮分子密集堆积，从而引起剧烈的荧光猝灭，导致其发光效率低，且固态下无法实现荧光发射。这限制了喹吖啶酮分子的应用。同样地吡咯并吡咯二酮系颜料、苯并咪唑酮系颜料也存在共同的问题。For example, the quinacridone molecule has five aromatic heterocycles, and the intramolecular conjugation forms a large Π bond, so that the molecule has a planar rigid structure and cannot be rotated. At the same time, there are continuous hydrogen bonds between the quinacridone molecules. These strong interactions make the quinacridone molecules densely packed, causing severe fluorescence quenching, resulting in low luminous efficiency, and the inability to achieve fluorescence emission in the solid state. This limits the application of quinacridone molecules. Similarly, diketopyrrolopyrrole pigments and benzimidazolone pigments have common problems.
由于聚集态诱导猝灭现象，随意选取有机颜料分子和聚合物简单混合并固化后，得到的混合物无法产生荧光发射现象。因而，目前激光加工生产的聚合物尚无法应用于防伪标志的制造。Due to the aggregation-induced quenching phenomenon, random selection of organic pigment molecules and polymers after simple mixing and curing, the resulting mixture cannot produce fluorescence emission. Therefore, the polymers produced by laser processing cannot be applied to the manufacture of anti-counterfeiting signs.
发明内容Contents of the invention
针对现有技术的缺陷，本发明提供一种激光诱导的荧光发射组合物及图案化荧光发光发射方法，其目的在于：利用激光辐照聚合物与有机颜料的组合物，再利用紫外光进一步诱导，在激光辐照区域能产生图案化荧光发射。从而通过非常简单快捷的方式，实现了聚合物材料在激光照射下产生荧光发射的目的。Aiming at the defects of the prior art, the present invention provides a laser-induced fluorescence emission composition and a patterned fluorescence emission emission method. , can generate patterned fluorescence emission in the laser irradiated area. Therefore, the purpose of fluorescent emission of the polymer material under laser irradiation is achieved in a very simple and quick manner.
一种激光诱导的荧光发射组合物，其特征在于，由如下重量份的组分组成：有机颜料0.01～10份；聚合物树脂90～99.99份；A laser-induced fluorescence emission composition, characterized in that it consists of the following components by weight: 0.01-10 parts of organic pigment; 90-99.99 parts of polymer resin;
所述有机颜料选自喹吖啶酮系颜料、吡咯并吡咯二酮系颜料、苯并咪唑酮系颜料中的至少一种。The organic pigment is at least one selected from quinacridone-based pigments, diketopyrrolopyrrole-based pigments, and benzimidazolone-based pigments.
优选的，由如下重量份的组分组成：有机颜料0.01～5份；聚合物树脂 95～99.99份；Preferably, it consists of the following components by weight: 0.01-5 parts of organic pigment; 95-99.99 parts of polymer resin;
优选为：有机颜料0.01～1份；聚合物树脂99～99.99份；Preferably: 0.01-1 part of organic pigment; 99-99.99 parts of polymer resin;
进一步优选为：有机颜料0.1～0.5份；聚合物树脂99.5～99.9份。More preferably: 0.1-0.5 parts of organic pigment; 99.5-99.9 parts of polymer resin.
优选的，所述聚合物树脂分子链中含有酯基和/或羟基；优选的，所述含有酯基的聚合物树脂选自聚醋酸乙烯酯、聚对苯二甲酸乙二醇酯、聚对苯二甲酸丙二醇酯、聚对苯二甲酸丁二醇酯、聚萘二甲酸乙二醇酯、聚芳酯、聚碳酸酯、聚甲基丙烯酸甲酯、聚甲基丙烯酸乙酯、聚甲基丙烯酸丁酯、聚酯弹性体、聚丁二酸丁二醇酯、聚丁二酸-对苯二甲酸-丁二醇酯、聚丁二酸-己二酸-丁二醇酯、聚甲基丙烯酸酯-丁二烯-苯乙烯共聚物、苯乙烯-丙烯腈-丙烯酸酯共聚物、甲基丙烯酸酯-苯乙烯共聚物或甲基丙烯酸酯-丁二烯-苯乙烯共聚物中的至少一种。Preferably, the molecular chain of the polymer resin contains ester groups and/or hydroxyl groups; preferably, the polymer resin containing ester groups is selected from polyvinyl acetate, polyethylene terephthalate, polyethylene terephthalate Trimethylene phthalate, Polybutylene terephthalate, Polyethylene naphthalate, Polyarylate, Polycarbonate, Polymethyl methacrylate, Polyethyl methacrylate, Polymethyl methacrylate Butyl acrylate, polyester elastomer, polybutylene succinate, polybutylene succinate-terephthalate, polybutylene succinate-adipate, polymethyl At least one of acrylate-butadiene-styrene copolymer, styrene-acrylonitrile-acrylate copolymer, methacrylate-styrene copolymer or methacrylate-butadiene-styrene copolymer kind.
优选地，所述喹吖啶酮系颜料为5,12-二氢-喹啉并[2,3-B]吖啶-7,14-二酮、2.9-二甲基喹吖啶酮、2,9-二氯喹吖啶酮、4,11-二氯喹吖啶酮、3,10-二氯喹吖啶酮、1,8-二氯喹吖啶酮中的至少一种；Preferably, the quinacridone pigments are 5,12-dihydro-quinolino[2,3-B]acridine-7,14-dione, 2.9-dimethylquinacridone, 2 , at least one of 9-dichloroquinacridone, 4,11-dichloroquinacridone, 3,10-dichloroquinacridone, and 1,8-dichloroquinacridone;
优选的，所述吡咯并吡咯二酮系颜料为双(间晴基苯)1,4-吡咯并吡咯二酮、 3,6-双(4-叔丁基苯基)-2,5-二氢吡咯并[3,4-c]吡咯-1,4-二酮、双(对氯苯基)-1,4- 二酮吡咯并吡咯、3,6-二苯基-2,5-二氢吡咯并[3,4-c]吡咯-1,4-二酮、3,6-双(4- 苯基-苯基)-2,5-二氢-吡咯并[3,4-c]吡咯-1,4-二酮、3,6-双(4-甲基苯基)-2,5- 二氢-吡咯并[3,4-c]吡咯-1,4-二酮中的至少一种；Preferably, the diketopyrrolopyrrole pigment is bis(m-acrylbenzene) 1,4-diketopyrrolopyrrole, 3,6-bis(4-tert-butylphenyl)-2,5-di Hydrogen pyrrolo[3,4-c]pyrrole-1,4-dione, bis(p-chlorophenyl)-1,4-diketopyrrolopyrrole, 3,6-diphenyl-2,5-dione Hydrogen pyrrolo[3,4-c]pyrrolo-1,4-dione, 3,6-bis(4-phenyl-phenyl)-2,5-dihydro-pyrrolo[3,4-c] At least one of pyrrole-1,4-dione, 3,6-bis(4-methylphenyl)-2,5-dihydro-pyrrolo[3,4-c]pyrrole-1,4-dione A sort of;
优选的，所述苯并咪唑酮系颜料为2-[[1-[[(2,3-二氢-2-氧代-1H-苯并咪唑 -5-基)氨基]甲酰]-2-氧代丙基]偶氮]苯甲酸、N-(2,3-二氢-2-氧代-1H-苯并咪唑 -5-基)-3-氧代-2-[[2-(三氟甲基)苯基]偶氮]丁酰胺、2-[[1-[[(2,3-二氢-2-氧代 -1H-苯并咪唑-5-基)氨基]羰基]-2-氧代丙基]偶氮]-1,4-苯二甲酸二甲酯、 2,2'-[1,2-亚乙基二(氧基-2,1-亚苯基偶氮)]二[N-(2,3-二氢-2-氧代-1H-苯并咪唑)-5-基]-3-氧代-丁酰胺、N-[4-(氨基羰基)苯基]-4-[[1-[[(2,3-二氢-2-氧代-1H- 苯并咪唑-5-基)-氨基]羰基]-2-氧代丙基]偶氮]苯甲酰胺、10,12-二氢-7H,11H- 苯并[DE]咪唑并[4',5':5,6]苯并咪唑并[2,1-A]异喹啉-7,11-二酮、2-[(4-氯-2-硝基苯基)偶氮]-N-(2,3-二氢-2-氧代-1H-苯并咪唑-5-基)-3-氧代丁酰胺、N-(2,3- 二氢-2-氧代-5-苯并咪唑)-3-羟基-4-[[2-甲氧基-5-甲基-4-[(甲氨基)磺酰]苯基] 重氮]萘-2-甲酰胺中的至少一种。Preferably, the benzimidazolone pigment is 2-[[1-[[(2,3-dihydro-2-oxo-1H-benzimidazol-5-yl)amino]formyl]-2 -Oxopropyl]azo]benzoic acid, N-(2,3-dihydro-2-oxo-1H-benzimidazol-5-yl)-3-oxo-2-[[2-( Trifluoromethyl)phenyl]azo]butanamide, 2-[[1-[[(2,3-dihydro-2-oxo-1H-benzimidazol-5-yl)amino]carbonyl]- 2-Oxopropyl]azo]-1,4-dimethyl phthalate, 2,2'-[1,2-ethylenebis(oxy-2,1-phenyleneazo) ] Di[N-(2,3-dihydro-2-oxo-1H-benzimidazolium)-5-yl]-3-oxo-butanamide, N-[4-(aminocarbonyl)phenyl] -4-[[1-[[(2,3-Dihydro-2-oxo-1H-benzimidazol-5-yl)-amino]carbonyl]-2-oxopropyl]azo]benzyl Amide, 10,12-dihydro-7H,11H-benzo[DE]imidazo[4',5':5,6]benzimidazo[2,1-A]isoquinoline-7,11- Diketone, 2-[(4-chloro-2-nitrophenyl)azo]-N-(2,3-dihydro-2-oxo-1H-benzimidazol-5-yl)-3- Oxobutyramide, N-(2,3-dihydro-2-oxo-5-benzimidazole)-3-hydroxy-4-[[2-methoxy-5-methyl-4-[( At least one of methylamino)sulfonyl]phenyl]diazo]naphthalene-2-carboxamide.
优选的，所述组合物为粉末、片材、板材、棒材或膜材料。Preferably, the composition is a powder, sheet, plate, rod or film material.
本发明还提供上述组合物的一种制备方法，包括如下步骤：将有机颜料与聚合物树脂混合、共混挤出、造粒和注塑后即得；优选的，共混挤出过程中的温度为180℃～270℃；注塑温度为180℃～270℃。The present invention also provides a preparation method of the above-mentioned composition, comprising the following steps: mixing the organic pigment with the polymer resin, blending and extruding, granulating and injection molding; preferably, the temperature in the blending and extrusion process It is 180℃～270℃; the injection temperature is 180℃～270℃.
本发明还提供上述组合物的一种制备方法，包括如下步骤：将聚合物树脂、有机颜料依次溶于溶剂后制成膜材料，挥干溶剂，即得；优选的，所述有机颜料与溶剂的重量比为0.00001：1～1：1。The present invention also provides a preparation method of the above-mentioned composition, comprising the following steps: dissolving the polymer resin and the organic pigment in a solvent successively to form a film material, and evaporating the solvent to obtain the product; preferably, the organic pigment and the solvent The weight ratio is 0.00001:1～1:1.
本发明还提供一种激光诱导的图案化荧光发射方法，其特征在于，包括如下步骤：The present invention also provides a laser-induced patterned fluorescence emission method, characterized in that it comprises the following steps:
(1)取上述组合物，用激光辐照所述组合物表面，形成辐照区域；(1) Take the above composition and irradiate the surface of the composition with laser to form an irradiation area;
(2)用紫外光辐照所述辐照区域，即可使所述激光辐照区域产生荧光发射。(2) irradiating the irradiated area with ultraviolet light, so that the laser irradiated area can produce fluorescence emission.
优选的，所述激光选自近红外激光、绿激光、紫外激光、CO2激光、准分子激光中的一种或两种以上的组合；优选的，所述激光为CO2激光；进一步优选的，所述CO2激光的波长为9.3～10.6μm；Preferably, the laser is selected from near-infrared laser, green laser, ultraviolet laser, CO2 laser, excimer laser, or a combination of two or more; preferably, the laser is CO2 laser; further preferred , the wavelength of the CO 2 laser is 9.3-10.6 μm;
和/或，所述激光为连续激光或脉冲激光；And/or, the laser is a continuous laser or a pulsed laser;
和/或，所述激光的功率为1.8～80W，所述激光的扫描速度为 1～10000mm/s；优选的，所述激光的功率为5～70W，所述激光的扫描速度为 1000mm/s；进一步优选的，所述激光的功率为5～50W，所述激光的扫描速度为1000mm/s，所述激光的频率为20kHz。And/or, the power of the laser is 1.8-80W, and the scanning speed of the laser is 1-10000mm/s; preferably, the power of the laser is 5-70W, and the scanning speed of the laser is 1000mm/s ; Further preferably, the power of the laser is 5-50W, the scanning speed of the laser is 1000mm/s, and the frequency of the laser is 20kHz.
和/或，所述紫外光波长为365～395nm；优选的，所述紫外光波长为365nm。And/or, the wavelength of the ultraviolet light is 365-395 nm; preferably, the wavelength of the ultraviolet light is 365 nm.
本发明还提供一种固态荧光发射材料，它是将权利要求1-6任一项所述的组合物用激光辐照后制成；The present invention also provides a solid-state fluorescent emitting material, which is made by irradiating the composition according to any one of claims 1-6 with laser light;
优选的，所述激光选自近红外激光、绿激光、紫外激光、CO2激光、准分子激光中的一种或两种以上的组合；优选的，所述激光为CO2激光；进一步优选的，所述CO2激光的波长为9.3～10.6μm；Preferably, the laser is selected from near-infrared laser, green laser, ultraviolet laser, CO2 laser, excimer laser, or a combination of two or more; preferably, the laser is CO2 laser; further preferred , the wavelength of the CO 2 laser is 9.3-10.6 μm;
优选的，所述激光为连续激光或脉冲激光；Preferably, the laser is continuous laser or pulsed laser;
优选的，所述激光的功率为1.8～80W，所述激光的扫描速度为 1～10000mm/s；优选的，所述激光的功率为5～70W，所述激光的扫描速度为 1000mm/s；进一步优选的，所述激光的功率为5～50W，所述激光的扫描速度为1000mm/s，所述激光的频率为20kHz。Preferably, the power of the laser is 1.8-80W, and the scanning speed of the laser is 1-10000mm/s; preferably, the power of the laser is 5-70W, and the scanning speed of the laser is 1000mm/s; Further preferably, the power of the laser is 5-50W, the scanning speed of the laser is 1000mm/s, and the frequency of the laser is 20kHz.
本发明还提供上述组合物或发射材料在制造防伪标志中的用途。The present invention also provides the application of the above-mentioned composition or emissive material in the manufacture of anti-counterfeit marks.
本发明将原本在固态下为聚集态诱导猝灭(ACQ)的有机颜料，分散在固态组合物中使其具备强荧光发射的特性。这打破了平面刚性有机颜料分子无法在固态下发射荧光的常规，扩宽了有机颜料的应用范围。另一方面，本发明实现了在聚合物树脂上产生荧光发射，也拓展了聚合物树脂的应用范围。这使得本发明具有十分良好的产业应用前景。此外，本发明方法是一种利用激光器辐照聚合物树脂与有机颜料组合物，继而利用紫外灯激发，可产生强的图案化荧光发射的方法。在防伪领域非常具有应用潜力。The present invention disperses the organic pigments that are aggregated state induced quenching (ACQ) in the solid state into the solid composition to have strong fluorescence emission characteristics. This breaks the rule that planar rigid organic pigment molecules cannot emit fluorescence in the solid state, and broadens the application range of organic pigments. On the other hand, the invention realizes the generation of fluorescent emission on the polymer resin, and also expands the application range of the polymer resin. This makes the invention have very good industrial application prospects. In addition, the method of the present invention is a method of irradiating the polymer resin and the organic pigment composition with a laser, and then exciting it with an ultraviolet lamp to generate strong patterned fluorescent emission. It has great application potential in the field of anti-counterfeiting.
在优选的技术方案中，本发明对聚合物树脂和有机颜料分子的种类及用量比例进行了优选，对激光器的波长、功率和扫描速度等参数进行了优选。实验证明，在优选的方案下，本发明的组合物能够产生较强的图案化荧光发射，而超出本发明优选的方案范围后，组合物的荧光发射强度较弱或无法产生荧光发射。In the preferred technical solution, the present invention optimizes the type and dosage ratio of the polymer resin and the organic pigment molecule, and optimizes parameters such as the wavelength, power and scanning speed of the laser. Experiments have proved that, under the preferred scheme, the composition of the present invention can produce strong patterned fluorescent emission, but beyond the scope of the preferred scheme of the present invention, the fluorescent emission intensity of the composition is weak or unable to produce fluorescent emission.
关于本发明的使用术语的定义：除非另有说明，本文中基团或者术语提供的初始定义适用于整篇说明书的该基团或者术语；对于本文没有具体定义的术语，应该根据公开内容和上下文，给出本领域技术人员能够给予它们的含义。Definition of terms used in the present invention: Unless otherwise stated, the initial definition provided by a group or term herein applies to the group or term throughout the specification; for terms that are not specifically defined herein, they should be based on the disclosure and context , giving the meanings a person skilled in the art can assign to them.
荧光发射即荧光分子发出荧光的过程。该过程具体为：荧光分子吸收能量后，基态电子被激发到单线激发态后从第一单线激发态回到基态，同时以产生光子的形式释放能量。Fluorescence emission is the process by which fluorescent molecules emit fluorescence. The process is specifically: after the fluorescent molecules absorb energy, the ground state electrons are excited to the singlet excited state and then return to the ground state from the first singlet excited state, and at the same time release energy in the form of photons.
显然，根据本发明的上述内容，按照本领域的普通技术知识和惯用手段，在不脱离本发明上述基本技术思想前提下，还可以做出其它多种形式的修改、替换或变更。Apparently, according to the above content of the present invention, according to common technical knowledge and conventional means in this field, without departing from the above basic technical idea of the present invention, other various forms of modification, replacement or change can also be made.
以下通过实施例形式的具体实施方式，对本发明的上述内容再作进一步的详细说明。但不应将此理解为本发明上述主题的范围仅限于以下的实例。凡基于本发明上述内容所实现的技术均属于本发明的范围。The above-mentioned content of the present invention will be further described in detail below through specific implementation in the form of examples. However, this should not be construed as limiting the scope of the above-mentioned subject matter of the present invention to the following examples. All technologies realized based on the above contents of the present invention belong to the scope of the present invention.
附图说明Description of drawings
图1为通过CO2激光器辐照实施例39的组合物后在可见光下的照片；Fig. 1 is the photograph under visible light after the composition of embodiment 39 is irradiated by CO laser ;
图2为实施例39的组合物用激光辐射后在365nm紫外灯下的照片。Figure 2 is a photograph of the composition of Example 39 under a 365 nm ultraviolet lamp after being irradiated with laser light.
其中，激光发射器为脉冲式CO2激光器；波长为9.3μm；打标速度(激光的扫描速度)1000mm/s；激光功率为10W，激光脉冲频率为20kHz。Among them, the laser transmitter is a pulsed CO 2 laser; the wavelength is 9.3 μm; the marking speed (scanning speed of the laser) is 1000mm/s; the laser power is 10W, and the laser pulse frequency is 20kHz.
具体实施方式Detailed ways
本发明具体实施方式中使用的原料、设备均为已知产品，通过购买市售产品获得。The raw materials and equipment used in the specific embodiment of the present invention are all known products, obtained by purchasing commercially available products.
(1)本发明所用的设备信息如下：(1) The used equipment information of the present invention is as follows:
注塑机，型号K-TEC 40，米拉克龙国际公司生产；可调式涂膜器，型号 KTQ-II，上海亮研智能科技有限公司生产；CO2激光打标机，型号BK-C30，激光器最大功率100W，激光波长9.3μm，激光脉冲频率可变范围为1-200kHz。标克激光科技(杭州)有限公司生产；365nm紫外灯，功率为3-5W。Injection molding machine, model K-TEC 40, produced by Milacron International Company; adjustable film applicator, model KTQ-II, produced by Shanghai Liangyan Intelligent Technology Co., Ltd.; CO 2 laser marking machine, model BK-C30, with the largest laser The power is 100W, the laser wavelength is 9.3μm, and the variable range of laser pulse frequency is 1-200kHz. Produced by Mark Laser Technology (Hangzhou) Co., Ltd.; 365nm ultraviolet lamp with a power of 3-5W.
(2)本发明用于制备组合物的原料具体信息如下：(2) The present invention is used to prepare the raw material specific information of composition as follows:
2,9-二氯喹吖啶酮：广州玉隆化工有限公司；二氯甲烷：成都市科隆化学品有限公司，AR，含量≥99.5％；聚甲基丙烯酸甲酯(PMMA)：赢创德固赛， 8N；聚甲基丙烯酸甲酯(PMMA)：中国台湾奇美，CM-211；聚甲基丙烯酸甲酯(PMMA)：日本南通三菱丽阳，MF001；聚甲基丙烯酸甲酯(PMMA)：法国阿科玛，V020；聚碳酸酯(PC)：科思创，Makrolon 6557；聚碳酸酯(PC)：中国台湾奇美，WONDERLITF PC-175；聚对苯二甲酸乙二醇酯(PET)：远纺工业，CB-602；聚对苯二甲酸丁二醇酯(PBT)：德国巴斯夫，PBT B41000；聚乙烯醇(PVA-1788)：探索平台，AR；水。2,9-Dichloroquinacridone: Guangzhou Yulong Chemical Co., Ltd.; Dichloromethane: Chengdu Kelong Chemical Co., Ltd., AR, content ≥ 99.5%; Polymethylmethacrylate (PMMA): Evonik Degus Sai, 8N; Polymethyl methacrylate (PMMA): Chimei, Taiwan, China, CM-211; Polymethyl methacrylate (PMMA): Mitsubishi Rayon, Nantong, Japan, MF001; Polymethyl methacrylate (PMMA): Arkema, France, V020; Polycarbonate (PC): Covestro, Makrolon 6557; Polycarbonate (PC): Chimei, Taiwan, China, WONDERLITF PC-175; Polyethylene terephthalate (PET): Yuanfang Industry, CB-602; polybutylene terephthalate (PBT): BASF, Germany, PBT B41000; polyvinyl alcohol (PVA-1788): Discovery Platform, AR; water.
实施例1Example 1
喹吖啶酮颜料：2,9-二氯喹吖啶酮；Quinacridone pigments: 2,9-dichloroquinacridone;
聚合物树脂：聚甲基丙烯酸甲酯(PMMA)赢创德固赛，8N；Polymer resin: polymethyl methacrylate (PMMA) Evonik Degussa, 8N;
将99.9重量份聚甲基丙烯酸甲酯，0.1重量份2,9-二氯喹吖啶酮置于高速混料机中混合均匀；再将上述混合物料加入到双螺杆挤出机共混挤出，将挤出料造粒后注塑成板材，共混挤出加工过程中的温度控制在180℃～230℃；注塑温度控制在180℃～230℃。Put 99.9 parts by weight of polymethyl methacrylate and 0.1 parts by weight of 2,9-dichloroquinacridone in a high-speed mixer and mix them uniformly; then add the above-mentioned mixture to a twin-screw extruder for blending and extrusion, The extruded material is granulated and then injected into a plate. The temperature during the blending and extrusion process is controlled at 180°C to 230°C; the injection molding temperature is controlled at 180°C to 230°C.
采用以下条件对上述复合板材进行激光辐照：二氧化碳激光器波长为 9.3μm，打标速度为1000mm/s，激光功率为10W，激光频率为20kHz。The following conditions are used to irradiate the above-mentioned composite plate with laser: the wavelength of the carbon dioxide laser is 9.3 μm, the marking speed is 1000 mm/s, the laser power is 10 W, and the laser frequency is 20 kHz.
激光辐照后，利用365nm的紫外灯辐照整块板材，目测被激光器辐照区域是否有荧光产生。荧光强度按照目测分为：After laser irradiation, use a 365nm ultraviolet lamp to irradiate the entire plate, and visually check whether there is fluorescence in the area irradiated by the laser. The fluorescence intensity is divided into:
荧光强度评价中，“☆”表示没有荧光发射，“★”个数越多，说明荧光强度越强。In the evaluation of fluorescence intensity, "☆" means no fluorescence emission, and the more "★", the stronger the fluorescence intensity.
荧光标记效果如表1所示。The fluorescent labeling effect is shown in Table 1.
实施例2Example 2
喹吖啶酮颜料：2,9-二氯喹吖啶酮；Quinacridone pigments: 2,9-dichloroquinacridone;
聚合物树脂：聚甲基丙烯酸甲酯(PMMA)赢创德固赛,8N；Polymer resin: polymethyl methacrylate (PMMA) Evonik Degussa, 8N;
将99.5重量份聚甲基丙烯酸甲酯，0.5重量份2,9-二氯喹吖啶酮置于高速混料机中混合均匀；再将上述混合物料加入到双螺杆挤出机共混挤出，将挤出料造粒后注塑成板材，共混挤出加工过程中的温度控制在180℃～230℃；注塑温度控制在180℃～230℃。Put 99.5 parts by weight of polymethyl methacrylate and 0.5 parts by weight of 2,9-dichloroquinacridone in a high-speed mixer and mix them uniformly; then add the above-mentioned mixture to a twin-screw extruder for blending and extrusion, The extruded material is granulated and then injected into a plate. The temperature during the blending and extrusion process is controlled at 180°C to 230°C; the injection molding temperature is controlled at 180°C to 230°C.
激光辐照条件同实施例1。紫外辐照条件及方式同实施例1。目测被激光器辐照区域是否有荧光产生，结果如表1所示。Laser irradiation conditions are the same as in Example 1. The ultraviolet irradiation conditions and mode are the same as in Example 1. Visually inspect whether there is fluorescence in the area irradiated by the laser, and the results are shown in Table 1.
实施例3Example 3
喹吖啶酮颜料：2,9-二氯喹吖啶酮；Quinacridone pigments: 2,9-dichloroquinacridone;
聚合物树脂：聚甲基丙烯酸甲酯(PMMA)赢创德固赛,8N；Polymer resin: polymethyl methacrylate (PMMA) Evonik Degussa, 8N;
将95重量份聚甲基丙烯酸甲酯，5重量份2,9-二氯喹吖啶酮置于高速混料机中混合均匀；再将上述混合物料加入到双螺杆挤出机共混挤出，将挤出料造粒后注塑成板材，共混挤出加工过程中的温度控制在180℃～230℃；注塑温度控制在180℃～230℃。Put 95 parts by weight of polymethyl methacrylate and 5 parts by weight of 2,9-dichloroquinacridone in a high-speed mixer and mix them uniformly; then add the above-mentioned mixture to a twin-screw extruder for blending and extrusion, The extruded material is granulated and then injected into a plate. The temperature during the blending and extrusion process is controlled at 180°C to 230°C; the injection molding temperature is controlled at 180°C to 230°C.
激光辐照条件同实施例1。紫外辐照条件及方式同实施例1。目测被激光器辐照区域是否有荧光产生，结果如表1所示。Laser irradiation conditions are the same as in Example 1. The ultraviolet irradiation conditions and mode are the same as in Example 1. Visually inspect whether there is fluorescence in the area irradiated by the laser, and the results are shown in Table 1.
实施例4Example 4
喹吖啶酮颜料：2,9-二氯喹吖啶酮；Quinacridone pigments: 2,9-dichloroquinacridone;
聚合物树脂：聚甲基丙烯酸甲酯(PMMA)赢创德固赛,8N；Polymer resin: polymethyl methacrylate (PMMA) Evonik Degussa, 8N;
将90重量份聚甲基丙烯酸甲酯，10重量份2,9-二氯喹吖啶酮置于高速混料机中混合均匀；再将上述混合物料加入到双螺杆挤出机共混挤出，将挤出料造粒后注塑成板材，共混挤出加工过程中的温度控制在180℃～230℃；注塑温度控制在180℃～230℃。Put 90 parts by weight of polymethyl methacrylate and 10 parts by weight of 2,9-dichloroquinacridone in a high-speed mixer and mix them uniformly; then add the above-mentioned mixture to a twin-screw extruder for blending and extrusion, The extruded material is granulated and then injected into a plate. The temperature during the blending and extrusion process is controlled at 180°C to 230°C; the injection molding temperature is controlled at 180°C to 230°C.
激光辐照条件同实施例1。紫外辐照条件及方式同实施例1。目测被激光器辐照区域是否有荧光产生，结果如表1所示。Laser irradiation conditions are the same as in Example 1. The ultraviolet irradiation conditions and mode are the same as in Example 1. Visually inspect whether there is fluorescence in the area irradiated by the laser, and the results are shown in Table 1.
实施例5Example 5
喹吖啶酮颜料：2,9-二氯喹吖啶酮；Quinacridone pigments: 2,9-dichloroquinacridone;
聚合物树脂：聚甲基丙烯酸甲酯(PMMA)赢创德固赛,8N；Polymer resin: polymethyl methacrylate (PMMA) Evonik Degussa, 8N;
将85重量份聚甲基丙烯酸甲酯，15重量份2,9-二氯喹吖啶酮置于高速混料机中混合均匀；再将上述混合物料加入到双螺杆挤出机共混挤出，将挤出料造粒后注塑成板材，共混挤出加工过程中的温度控制在180℃～230℃；注塑温度控制在180℃～230℃。Put 85 parts by weight of polymethyl methacrylate and 15 parts by weight of 2,9-dichloroquinacridone in a high-speed mixer and mix them uniformly; then add the above-mentioned mixture to a twin-screw extruder for blending and extrusion, The extruded material is granulated and then injected into a plate. The temperature during the blending and extrusion process is controlled at 180°C to 230°C; the injection molding temperature is controlled at 180°C to 230°C.
激光辐照条件同实施例1。紫外辐照条件及方式同实施例1。目测被激光器辐照区域是否有荧光产生，结果如表1所示。Laser irradiation conditions are the same as in Example 1. The ultraviolet irradiation conditions and mode are the same as in Example 1. Visually inspect whether there is fluorescence in the area irradiated by the laser, and the results are shown in Table 1.
实施例6Example 6
喹吖啶酮颜料：2,9-二氯喹吖啶酮；Quinacridone pigments: 2,9-dichloroquinacridone;
聚合物树脂：聚甲基丙烯酸甲酯(PMMA)赢创德固赛,8N；Polymer resin: polymethyl methacrylate (PMMA) Evonik Degussa, 8N;
将80重量份聚甲基丙烯酸甲酯，20重量份2,9-二氯喹吖啶酮置于高速混料机中混合均匀；再将上述混合物料加入到双螺杆挤出机共混挤出，将挤出料造粒后注塑成板材，共混挤出加工过程中的温度控制在180℃～230℃；注塑温度控制在180℃～230℃。Put 80 parts by weight of polymethyl methacrylate and 20 parts by weight of 2,9-dichloroquinacridone in a high-speed mixer and mix them uniformly; then add the above-mentioned mixture to a twin-screw extruder for blending and extrusion, The extruded material is granulated and then injected into a plate. The temperature during the blending and extrusion process is controlled at 180°C to 230°C; the injection molding temperature is controlled at 180°C to 230°C.
激光辐照条件同实施例1。紫外辐照条件及方式同实施例1。目测被激光器辐照区域是否有荧光产生，结果如表1所示。Laser irradiation conditions are the same as in Example 1. The ultraviolet irradiation conditions and mode are the same as in Example 1. Visually inspect whether there is fluorescence in the area irradiated by the laser, and the results are shown in Table 1.
实施例7Example 7
喹吖啶酮颜料：2,9-二氯喹吖啶酮；Quinacridone pigments: 2,9-dichloroquinacridone;
聚合物树脂：聚甲基丙烯酸甲酯(PMMA)中国台湾奇美,CM-211；Polymer resin: Polymethyl methacrylate (PMMA) Chimei, Taiwan, China, CM-211;
将99.9重量份聚甲基丙烯酸甲酯，0.1重量份2,9-二氯喹吖啶酮置于高速混料机中混合均匀；再将上述混合物料加入到双螺杆挤出机共混挤出，将挤出料造粒后注塑成板材，共混挤出加工过程中的温度控制在180℃～230℃；注塑温度控制在180℃～230℃。Put 99.9 parts by weight of polymethyl methacrylate and 0.1 parts by weight of 2,9-dichloroquinacridone in a high-speed mixer and mix them uniformly; then add the above-mentioned mixture to a twin-screw extruder for blending and extrusion, The extruded material is granulated and then injected into a plate. The temperature during the blending and extrusion process is controlled at 180°C to 230°C; the injection molding temperature is controlled at 180°C to 230°C.
激光辐照条件同实施例1。紫外辐照条件及方式同实施例1。目测被激光器辐照区域是否有荧光产生，结果如表1所示。Laser irradiation conditions are the same as in Example 1. The ultraviolet irradiation conditions and mode are the same as in Example 1. Visually inspect whether there is fluorescence in the area irradiated by the laser, and the results are shown in Table 1.
实施例8Example 8
喹吖啶酮颜料：2,9-二氯喹吖啶酮；Quinacridone pigments: 2,9-dichloroquinacridone;
聚合物树脂：聚甲基丙烯酸甲酯(PMMA)中国台湾奇美,CM-211；Polymer resin: Polymethyl methacrylate (PMMA) Chimei, Taiwan, China, CM-211;
将99.5重量份聚甲基丙烯酸甲酯，0.5重量份2,9-二氯喹吖啶酮置于高速混料机中混合均匀；再将上述混合物料加入到双螺杆挤出机共混挤出，将挤出料造粒后注塑成板材，共混挤出加工过程中的温度控制在180℃～230℃；注塑温度控制在180℃～230℃。Put 99.5 parts by weight of polymethyl methacrylate and 0.5 parts by weight of 2,9-dichloroquinacridone in a high-speed mixer and mix them uniformly; then add the above-mentioned mixture to a twin-screw extruder for blending and extrusion, The extruded material is granulated and then injected into a plate. The temperature during the blending and extrusion process is controlled at 180°C to 230°C; the injection molding temperature is controlled at 180°C to 230°C.
激光辐照条件同实施例1。紫外辐照条件及方式同实施例1。目测被激光器辐照区域是否有荧光产生，结果如表1所示。Laser irradiation conditions are the same as in Example 1. The ultraviolet irradiation conditions and mode are the same as in Example 1. Visually inspect whether there is fluorescence in the area irradiated by the laser, and the results are shown in Table 1.
实施例9Example 9
喹吖啶酮颜料：2,9-二氯喹吖啶酮；Quinacridone pigments: 2,9-dichloroquinacridone;
聚合物树脂：聚甲基丙烯酸甲酯(PMMA)中国台湾奇美,CM-211；Polymer resin: Polymethyl methacrylate (PMMA) Chimei, Taiwan, China, CM-211;
将95重量份聚甲基丙烯酸甲酯，5重量份2,9-二氯喹吖啶酮置于高速混料机中混合均匀；再将上述混合物料加入到双螺杆挤出机共混挤出，将挤出料造粒后注塑成板材，共混挤出加工过程中的温度控制在180℃～230℃；注塑温度控制在180℃～230℃。Put 95 parts by weight of polymethyl methacrylate and 5 parts by weight of 2,9-dichloroquinacridone in a high-speed mixer and mix them uniformly; then add the above-mentioned mixture to a twin-screw extruder for blending and extrusion, The extruded material is granulated and then injected into a plate. The temperature during the blending and extrusion process is controlled at 180°C to 230°C; the injection molding temperature is controlled at 180°C to 230°C.
激光辐照条件同实施例1。紫外辐照条件及方式同实施例1。目测被激光器辐照区域是否有荧光产生，结果如表1所示。Laser irradiation conditions are the same as in Example 1. The ultraviolet irradiation conditions and mode are the same as in Example 1. Visually inspect whether there is fluorescence in the area irradiated by the laser, and the results are shown in Table 1.
实施例10Example 10
喹吖啶酮颜料：2,9-二氯喹吖啶酮；Quinacridone pigments: 2,9-dichloroquinacridone;
聚合物树脂：聚甲基丙烯酸甲酯(PMMA)中国台湾奇美,CM-211；Polymer resin: Polymethyl methacrylate (PMMA) Chimei, Taiwan, China, CM-211;
将90重量份聚甲基丙烯酸甲酯，10重量份2,9-二氯喹吖啶酮置于高速混料机中混合均匀；再将上述混合物料加入到双螺杆挤出机共混挤出，将挤出料造粒后注塑成板材，共混挤出加工过程中的温度控制在180℃～230℃；注塑温度控制在180℃～230℃。Put 90 parts by weight of polymethyl methacrylate and 10 parts by weight of 2,9-dichloroquinacridone in a high-speed mixer and mix them uniformly; then add the above-mentioned mixture to a twin-screw extruder for blending and extrusion, The extruded material is granulated and then injected into a plate. The temperature during the blending and extrusion process is controlled at 180°C to 230°C; the injection molding temperature is controlled at 180°C to 230°C.
激光辐照条件同实施例1。紫外辐照条件及方式同实施例1。目测被激光器辐照区域是否有荧光产生，结果如表1所示。Laser irradiation conditions are the same as in Example 1. The ultraviolet irradiation conditions and mode are the same as in Example 1. Visually inspect whether there is fluorescence in the area irradiated by the laser, and the results are shown in Table 1.
实施例11Example 11
喹吖啶酮颜料：2,9-二氯喹吖啶酮；Quinacridone pigments: 2,9-dichloroquinacridone;
聚合物树脂：聚甲基丙烯酸甲酯(PMMA)中国台湾奇美,CM-211；Polymer resin: Polymethyl methacrylate (PMMA) Chimei, Taiwan, China, CM-211;
将85重量份聚甲基丙烯酸甲酯，15重量份2,9-二氯喹吖啶酮置于高速混料机中混合均匀；再将上述混合物料加入到双螺杆挤出机共混挤出，将挤出料造粒后注塑成板材，共混挤出加工过程中的温度控制在180℃～230℃；注塑温度控制在180℃～230℃。Put 85 parts by weight of polymethyl methacrylate and 15 parts by weight of 2,9-dichloroquinacridone in a high-speed mixer and mix them uniformly; then add the above-mentioned mixture to a twin-screw extruder for blending and extrusion, The extruded material is granulated and then injected into a plate. The temperature during the blending and extrusion process is controlled at 180°C to 230°C; the injection molding temperature is controlled at 180°C to 230°C.
激光辐照条件同实施例1。紫外辐照条件及方式同实施例1。目测被激光器辐照区域是否有荧光产生，结果如表1所示。Laser irradiation conditions are the same as in Example 1. The ultraviolet irradiation conditions and mode are the same as in Example 1. Visually inspect whether there is fluorescence in the area irradiated by the laser, and the results are shown in Table 1.
实施例12Example 12
喹吖啶酮颜料：2,9-二氯喹吖啶酮；Quinacridone pigments: 2,9-dichloroquinacridone;
聚合物树脂：聚甲基丙烯酸甲酯(PMMA)中国台湾奇美,CM-211；Polymer resin: Polymethyl methacrylate (PMMA) Chimei, Taiwan, China, CM-211;
将80重量份聚甲基丙烯酸甲酯，20重量份2,9-二氯喹吖啶酮置于高速混料机中混合均匀；再将上述混合物料加入到双螺杆挤出机共混挤出，将挤出料造粒后注塑成板材，共混挤出加工过程中的温度控制在180℃～230℃；注塑温度控制在180℃～230℃。Put 80 parts by weight of polymethyl methacrylate and 20 parts by weight of 2,9-dichloroquinacridone in a high-speed mixer and mix them uniformly; then add the above-mentioned mixture to a twin-screw extruder for blending and extrusion, The extruded material is granulated and then injected into a plate. The temperature during the blending and extrusion process is controlled at 180°C to 230°C; the injection molding temperature is controlled at 180°C to 230°C.
激光辐照条件同实施例1。紫外辐照条件及方式同实施例1。目测被激光器辐照区域是否有荧光产生，结果如表1所示。Laser irradiation conditions are the same as in Example 1. The ultraviolet irradiation conditions and mode are the same as in Example 1. Visually inspect whether there is fluorescence in the area irradiated by the laser, and the results are shown in Table 1.
实施例13Example 13
喹吖啶酮颜料：2,9-二氯喹吖啶酮；Quinacridone pigments: 2,9-dichloroquinacridone;
聚合物树脂：聚甲基丙烯酸甲酯(PMMA)日本南通三菱丽阳,MF001；Polymer resin: Polymethyl methacrylate (PMMA) Mitsubishi Rayon, Nantong, Japan, MF001;
将99.9重量份聚甲基丙烯酸甲酯，0.1重量份2,9-二氯喹吖啶酮置于高速混料机中混合均匀；再将上述混合物料加入到双螺杆挤出机共混挤出，将挤出料造粒后注塑成板材，共混挤出加工过程中的温度控制在180℃～230℃；注塑温度控制在180℃～230℃。Put 99.9 parts by weight of polymethyl methacrylate and 0.1 parts by weight of 2,9-dichloroquinacridone in a high-speed mixer and mix them uniformly; then add the above-mentioned mixture to a twin-screw extruder for blending and extrusion, The extruded material is granulated and then injected into a plate. The temperature during the blending and extrusion process is controlled at 180°C to 230°C; the injection molding temperature is controlled at 180°C to 230°C.
激光辐照条件同实施例1。紫外辐照条件及方式同实施例1。目测被激光器辐照区域是否有荧光产生，结果如表1所示。Laser irradiation conditions are the same as in Example 1. The ultraviolet irradiation conditions and mode are the same as in Example 1. Visually inspect whether there is fluorescence in the area irradiated by the laser, and the results are shown in Table 1.
实施例14Example 14
喹吖啶酮颜料：2,9-二氯喹吖啶酮；Quinacridone pigments: 2,9-dichloroquinacridone;
聚合物树脂：聚甲基丙烯酸甲酯(PMMA)日本南通三菱丽阳,MF001；Polymer resin: Polymethyl methacrylate (PMMA) Mitsubishi Rayon, Nantong, Japan, MF001;
将99.5重量份聚甲基丙烯酸甲酯，0.5重量份2,9-二氯喹吖啶酮置于高速混料机中混合均匀；再将上述混合物料加入到双螺杆挤出机共混挤出，将挤出料造粒后注塑成板材，共混挤出加工过程中的温度控制在180℃～230℃；注塑温度控制在180℃～230℃。Put 99.5 parts by weight of polymethyl methacrylate and 0.5 parts by weight of 2,9-dichloroquinacridone in a high-speed mixer and mix them uniformly; then add the above-mentioned mixture to a twin-screw extruder for blending and extrusion, The extruded material is granulated and then injected into a plate. The temperature during the blending and extrusion process is controlled at 180°C to 230°C; the injection molding temperature is controlled at 180°C to 230°C.
激光辐照条件同实施例1。紫外辐照条件及方式同实施例1。目测被激光器辐照区域是否有荧光产生，结果如表1所示。Laser irradiation conditions are the same as in Example 1. The ultraviolet irradiation conditions and mode are the same as in Example 1. Visually inspect whether there is fluorescence in the area irradiated by the laser, and the results are shown in Table 1.
实施例15Example 15
喹吖啶酮颜料：2,9-二氯喹吖啶酮；Quinacridone pigments: 2,9-dichloroquinacridone;
聚合物树脂：聚甲基丙烯酸甲酯(PMMA)日本南通三菱丽阳,MF001；Polymer resin: Polymethyl methacrylate (PMMA) Mitsubishi Rayon, Nantong, Japan, MF001;
将95重量份聚甲基丙烯酸甲酯，5重量份2,9-二氯喹吖啶酮置于高速混料机中混合均匀；再将上述混合物料加入到双螺杆挤出机共混挤出，将挤出料造粒后注塑成板材，共混挤出加工过程中的温度控制在180℃～230℃；注塑温度控制在180℃～230℃。Put 95 parts by weight of polymethyl methacrylate and 5 parts by weight of 2,9-dichloroquinacridone in a high-speed mixer and mix them uniformly; then add the above-mentioned mixture to a twin-screw extruder for blending and extrusion, The extruded material is granulated and then injected into a plate. The temperature during the blending and extrusion process is controlled at 180°C to 230°C; the injection molding temperature is controlled at 180°C to 230°C.
激光辐照条件同实施例1。紫外辐照条件及方式同实施例1。目测被激光器辐照区域是否有荧光产生，结果如表1所示。Laser irradiation conditions are the same as in Example 1. The ultraviolet irradiation conditions and mode are the same as in Example 1. Visually inspect whether there is fluorescence in the area irradiated by the laser, and the results are shown in Table 1.
实施例16Example 16
喹吖啶酮颜料：2,9-二氯喹吖啶酮；Quinacridone pigments: 2,9-dichloroquinacridone;
聚合物树脂：聚甲基丙烯酸甲酯(PMMA)日本南通三菱丽阳,MF001；Polymer resin: Polymethyl methacrylate (PMMA) Mitsubishi Rayon, Nantong, Japan, MF001;
将90重量份聚甲基丙烯酸甲酯，10重量份2,9-二氯喹吖啶酮置于高速混料机中混合均匀；再将上述混合物料加入到双螺杆挤出机共混挤出，将挤出料造粒后注塑成板材，共混挤出加工过程中的温度控制在180℃～230℃；注塑温度控制在180℃～230℃。Put 90 parts by weight of polymethyl methacrylate and 10 parts by weight of 2,9-dichloroquinacridone in a high-speed mixer and mix them uniformly; then add the above-mentioned mixture to a twin-screw extruder for blending and extrusion, The extruded material is granulated and then injected into a plate. The temperature during the blending and extrusion process is controlled at 180°C to 230°C; the injection molding temperature is controlled at 180°C to 230°C.
激光辐照条件同实施例1。紫外辐照条件及方式同实施例1。目测被激光器辐照区域是否有荧光产生，结果如表1所示。Laser irradiation conditions are the same as in Example 1. The ultraviolet irradiation conditions and mode are the same as in Example 1. Visually inspect whether there is fluorescence in the area irradiated by the laser, and the results are shown in Table 1.
实施例17Example 17
喹吖啶酮颜料：2,9-二氯喹吖啶酮；Quinacridone pigments: 2,9-dichloroquinacridone;
聚合物树脂：聚甲基丙烯酸甲酯(PMMA)日本南通三菱丽阳,MF001；Polymer resin: Polymethyl methacrylate (PMMA) Mitsubishi Rayon, Nantong, Japan, MF001;
将85重量份聚甲基丙烯酸甲酯，15重量份2,9-二氯喹吖啶酮置于高速混料机中混合均匀；再将上述混合物料加入到双螺杆挤出机共混挤出，将挤出料造粒后注塑成板材，共混挤出加工过程中的温度控制在180℃～230℃；注塑温度控制在180℃～230℃。Put 85 parts by weight of polymethyl methacrylate and 15 parts by weight of 2,9-dichloroquinacridone in a high-speed mixer and mix them uniformly; then add the above-mentioned mixture to a twin-screw extruder for blending and extrusion, The extruded material is granulated and then injected into a plate. The temperature during the blending and extrusion process is controlled at 180°C to 230°C; the injection molding temperature is controlled at 180°C to 230°C.
激光辐照条件同实施例1。紫外辐照条件及方式同实施例1。目测被激光器辐照区域是否有荧光产生，结果如表1所示。Laser irradiation conditions are the same as in Example 1. The ultraviolet irradiation conditions and mode are the same as in Example 1. Visually inspect whether there is fluorescence in the area irradiated by the laser, and the results are shown in Table 1.
实施例18Example 18
喹吖啶酮颜料：2,9-二氯喹吖啶酮；Quinacridone pigments: 2,9-dichloroquinacridone;
聚合物树脂：聚甲基丙烯酸甲酯(PMMA)日本南通三菱丽阳,MF001；Polymer resin: Polymethyl methacrylate (PMMA) Mitsubishi Rayon, Nantong, Japan, MF001;
将80重量份聚甲基丙烯酸甲酯，20重量份2,9-二氯喹吖啶酮置于高速混料机中混合均匀；再将上述混合物料加入到双螺杆挤出机共混挤出，将挤出料造粒后注塑成板材，共混挤出加工过程中的温度控制在180℃～230℃；注塑温度控制在180℃～230℃。Put 80 parts by weight of polymethyl methacrylate and 20 parts by weight of 2,9-dichloroquinacridone in a high-speed mixer and mix them uniformly; then add the above-mentioned mixture to a twin-screw extruder for blending and extrusion, The extruded material is granulated and then injected into a plate. The temperature during the blending and extrusion process is controlled at 180°C to 230°C; the injection molding temperature is controlled at 180°C to 230°C.
激光辐照条件同实施例1。紫外辐照条件及方式同实施例1。目测被激光器辐照区域是否有荧光产生，结果如表1所示。Laser irradiation conditions are the same as in Example 1. The ultraviolet irradiation conditions and mode are the same as in Example 1. Visually inspect whether there is fluorescence in the area irradiated by the laser, and the results are shown in Table 1.
实施例19Example 19
喹吖啶酮颜料：2,9-二氯喹吖啶酮；Quinacridone pigments: 2,9-dichloroquinacridone;
聚合物树脂：聚甲基丙烯酸甲酯(PMMA)法国阿科玛,V020；Polymer resin: Polymethyl methacrylate (PMMA) France Arkema, V020;
将99.9重量份聚甲基丙烯酸甲酯，0.1重量份2,9-二氯喹吖啶酮置于高速混料机中混合均匀；再将上述混合物料加入到双螺杆挤出机共混挤出，将挤出料造粒后注塑成板材，共混挤出加工过程中的温度控制在180℃～230℃；注塑温度控制在180℃～230℃。Put 99.9 parts by weight of polymethyl methacrylate and 0.1 parts by weight of 2,9-dichloroquinacridone in a high-speed mixer and mix them uniformly; then add the above-mentioned mixture to a twin-screw extruder for blending and extrusion, The extruded material is granulated and then injected into a plate. The temperature during the blending and extrusion process is controlled at 180°C to 230°C; the injection molding temperature is controlled at 180°C to 230°C.
激光辐照条件同实施例1。紫外辐照条件及方式同实施例1。目测被激光器辐照区域是否有荧光产生，结果如表1所示。Laser irradiation conditions are the same as in Example 1. The ultraviolet irradiation conditions and mode are the same as in Example 1. Visually inspect whether there is fluorescence in the area irradiated by the laser, and the results are shown in Table 1.
实施例20Example 20
喹吖啶酮颜料：2,9-二氯喹吖啶酮；Quinacridone pigments: 2,9-dichloroquinacridone;
聚合物树脂：聚甲基丙烯酸甲酯(PMMA)法国阿科玛,V020；Polymer resin: Polymethyl methacrylate (PMMA) France Arkema, V020;
将99.5重量份聚甲基丙烯酸甲酯，0.5重量份2,9-二氯喹吖啶酮置于高速混料机中混合均匀；再将上述混合物料加入到双螺杆挤出机共混挤出，将挤出料造粒后注塑成板材，共混挤出加工过程中的温度控制在180℃～230℃；注塑温度控制在180℃～230℃。Put 99.5 parts by weight of polymethyl methacrylate and 0.5 parts by weight of 2,9-dichloroquinacridone in a high-speed mixer and mix them uniformly; then add the above-mentioned mixture to a twin-screw extruder for blending and extrusion, The extruded material is granulated and then injected into a plate. The temperature during the blending and extrusion process is controlled at 180°C to 230°C; the injection molding temperature is controlled at 180°C to 230°C.
激光辐照条件同实施例1。紫外辐照条件及方式同实施例1。目测被激光器辐照区域是否有荧光产生，结果如表1所示。Laser irradiation conditions are the same as in Example 1. The ultraviolet irradiation conditions and mode are the same as in Example 1. Visually inspect whether there is fluorescence in the area irradiated by the laser, and the results are shown in Table 1.
实施例21Example 21
喹吖啶酮颜料：2,9-二氯喹吖啶酮；Quinacridone pigments: 2,9-dichloroquinacridone;
聚合物树脂：聚甲基丙烯酸甲酯(PMMA)法国阿科玛,V020；Polymer resin: Polymethyl methacrylate (PMMA) France Arkema, V020;
将95重量份聚甲基丙烯酸甲酯，15重量份2,9-二氯喹吖啶酮置于高速混料机中混合均匀；再将上述混合物料加入到双螺杆挤出机共混挤出，将挤出料造粒后注塑成板材，共混挤出加工过程中的温度控制在180℃～230℃；注塑温度控制在180℃～230℃。Put 95 parts by weight of polymethyl methacrylate and 15 parts by weight of 2,9-dichloroquinacridone in a high-speed mixer and mix them uniformly; then add the above-mentioned mixture to a twin-screw extruder for blending and extrusion, The extruded material is granulated and then injected into a plate. The temperature during the blending and extrusion process is controlled at 180°C to 230°C; the injection molding temperature is controlled at 180°C to 230°C.
激光辐照条件同实施例1。紫外辐照条件及方式同实施例1。目测被激光器辐照区域是否有荧光产生，结果如表1所示。Laser irradiation conditions are the same as in Example 1. The ultraviolet irradiation conditions and mode are the same as in Example 1. Visually inspect whether there is fluorescence in the area irradiated by the laser, and the results are shown in Table 1.
实施例22Example 22
喹吖啶酮颜料：2,9-二氯喹吖啶酮；Quinacridone pigments: 2,9-dichloroquinacridone;
聚合物树脂：聚甲基丙烯酸甲酯(PMMA)法国阿科玛,V020；Polymer resin: Polymethyl methacrylate (PMMA) France Arkema, V020;
将90重量份聚甲基丙烯酸甲酯，10重量份2,9-二氯喹吖啶酮置于高速混料机中混合均匀；再将上述混合物料加入到双螺杆挤出机共混挤出，将挤出料造粒后注塑成板材，共混挤出加工过程中的温度控制在180℃～230℃；注塑温度控制在180℃～230℃。Put 90 parts by weight of polymethyl methacrylate and 10 parts by weight of 2,9-dichloroquinacridone in a high-speed mixer and mix them uniformly; then add the above-mentioned mixture to a twin-screw extruder for blending and extrusion, The extruded material is granulated and then injected into a plate. The temperature during the blending and extrusion process is controlled at 180°C to 230°C; the injection molding temperature is controlled at 180°C to 230°C.
激光辐照条件同实施例1。紫外辐照条件及方式同实施例1。目测被激光器辐照区域是否有荧光产生，结果如表1所示。Laser irradiation conditions are the same as in Example 1. The ultraviolet irradiation conditions and mode are the same as in Example 1. Visually inspect whether there is fluorescence in the area irradiated by the laser, and the results are shown in Table 1.
实施例23Example 23
喹吖啶酮颜料：2,9-二氯喹吖啶酮；Quinacridone pigments: 2,9-dichloroquinacridone;
聚合物树脂：聚甲基丙烯酸甲酯(PMMA)法国阿科玛,V020；Polymer resin: Polymethyl methacrylate (PMMA) France Arkema, V020;
将85重量份聚甲基丙烯酸甲酯，15重量份2,9-二氯喹吖啶酮置于高速混料机中混合均匀；再将上述混合物料加入到双螺杆挤出机共混挤出，将挤出料造粒后注塑成板材，共混挤出加工过程中的温度控制在180℃～230℃；注塑温度控制在180℃～230℃。Put 85 parts by weight of polymethyl methacrylate and 15 parts by weight of 2,9-dichloroquinacridone in a high-speed mixer and mix them uniformly; then add the above-mentioned mixture to a twin-screw extruder for blending and extrusion, The extruded material is granulated and then injected into a plate. The temperature during the blending and extrusion process is controlled at 180°C to 230°C; the injection molding temperature is controlled at 180°C to 230°C.
激光辐照条件同实施例1。紫外辐照条件及方式同实施例1。目测被激光器辐照区域是否有荧光产生，结果如表1所示。Laser irradiation conditions are the same as in Example 1. The ultraviolet irradiation conditions and mode are the same as in Example 1. Visually inspect whether there is fluorescence in the area irradiated by the laser, and the results are shown in Table 1.
实施例24Example 24
喹吖啶酮颜料：2,9-二氯喹吖啶酮；Quinacridone pigments: 2,9-dichloroquinacridone;
聚合物树脂：聚甲基丙烯酸甲酯(PMMA)法国阿科玛,V020；Polymer resin: Polymethyl methacrylate (PMMA) France Arkema, V020;
将80重量份聚甲基丙烯酸甲酯，20重量份2,9-二氯喹吖啶酮置于高速混料机中混合均匀；再将上述混合物料加入到双螺杆挤出机共混挤出，将挤出料造粒后注塑成板材，共混挤出加工过程中的温度控制在180℃～230℃；注塑温度控制在180℃～230℃。Put 80 parts by weight of polymethyl methacrylate and 20 parts by weight of 2,9-dichloroquinacridone in a high-speed mixer and mix them uniformly; then add the above-mentioned mixture to a twin-screw extruder for blending and extrusion, The extruded material is granulated and then injected into a plate. The temperature during the blending and extrusion process is controlled at 180°C to 230°C; the injection molding temperature is controlled at 180°C to 230°C.
激光辐照条件同实施例1。紫外辐照条件及方式同实施例1。目测被激光器辐照区域是否有荧光产生，结果如表1所示。Laser irradiation conditions are the same as in Example 1. The ultraviolet irradiation conditions and mode are the same as in Example 1. Visually inspect whether there is fluorescence in the area irradiated by the laser, and the results are shown in Table 1.
实施例25Example 25
喹吖啶酮颜料：2,9-二氯喹吖啶酮；Quinacridone pigments: 2,9-dichloroquinacridone;
聚合物树脂：聚碳酸酯(PC)科思创，Makrolon 6557；Polymer resin: polycarbonate (PC) Covestro, Makrolon 6557;
将99.9重量份聚碳酸酯，0.1重量份2,9-二氯喹吖啶酮置于高速混料机中混合均匀；再将上述混合物料加入到双螺杆挤出机共混挤出，将挤出料造粒后注塑成板材，共混挤出加工过程中的温度控制在180℃～270℃；注塑温度控制在180℃～270℃。Put 99.9 parts by weight of polycarbonate and 0.1 parts by weight of 2,9-dichloroquinacridone in a high-speed mixer and mix them evenly; After the material is granulated, it is injected into a sheet, and the temperature during the blending and extrusion process is controlled at 180°C to 270°C; the injection molding temperature is controlled at 180°C to 270°C.
激光辐照条件同实施例1。紫外辐照条件及方式同实施例1。目测被激光器辐照区域是否有荧光产生，结果如表1所示。Laser irradiation conditions are the same as in Example 1. The ultraviolet irradiation conditions and mode are the same as in Example 1. Visually inspect whether there is fluorescence in the area irradiated by the laser, and the results are shown in Table 1.
实施例26Example 26
喹吖啶酮颜料：2,9-二氯喹吖啶酮；Quinacridone pigments: 2,9-dichloroquinacridone;
聚合物树脂：聚碳酸酯(PC)科思创，Makrolon 6557；Polymer resin: polycarbonate (PC) Covestro, Makrolon 6557;
将99.5重量份聚碳酸酯，0.5重量份2,9-二氯喹吖啶酮置于高速混料机中混合均匀；再将上述混合物料加入到双螺杆挤出机共混挤出，将挤出料造粒后注塑成板材，共混挤出加工过程中的温度控制在180℃～270℃；注塑温度控制在180℃～270℃。Put 99.5 parts by weight of polycarbonate and 0.5 parts by weight of 2,9-dichloroquinacridone in a high-speed mixer and mix them evenly; After the material is granulated, it is injected into a sheet, and the temperature during the blending and extrusion process is controlled at 180°C to 270°C; the injection molding temperature is controlled at 180°C to 270°C.
激光辐照条件同实施例1。紫外辐照条件及方式同实施例1。目测被激光器辐照区域是否有荧光产生，结果如表1所示。Laser irradiation conditions are the same as in Example 1. The ultraviolet irradiation conditions and mode are the same as in Example 1. Visually inspect whether there is fluorescence in the area irradiated by the laser, and the results are shown in Table 1.
实施例27Example 27
喹吖啶酮颜料：2,9-二氯喹吖啶酮；Quinacridone pigments: 2,9-dichloroquinacridone;
聚合物树脂：聚碳酸酯(PC)科思创，Makrolon 6557；Polymer resin: polycarbonate (PC) Covestro, Makrolon 6557;
将95重量份聚碳酸酯，0.5重量份2,9-二氯喹吖啶酮置于高速混料机中混合均匀；再将上述混合物料加入到双螺杆挤出机共混挤出，将挤出料造粒后注塑成板材，共混挤出加工过程中的温度控制在180℃～270℃；注塑温度控制在180℃～270℃。Put 95 parts by weight of polycarbonate and 0.5 parts by weight of 2,9-dichloroquinacridone in a high-speed mixer and mix them uniformly; After the material is granulated, it is injected into a sheet, and the temperature during the blending and extrusion process is controlled at 180°C to 270°C; the injection molding temperature is controlled at 180°C to 270°C.
激光辐照条件同实施例1。紫外辐照条件及方式同实施例1。目测被激光器辐照区域是否有荧光产生，结果如表1所示。Laser irradiation conditions are the same as in Example 1. The ultraviolet irradiation conditions and mode are the same as in Example 1. Visually inspect whether there is fluorescence in the area irradiated by the laser, and the results are shown in Table 1.
实施例28Example 28
喹吖啶酮颜料：2,9-二氯喹吖啶酮；Quinacridone pigments: 2,9-dichloroquinacridone;
聚合物树脂：聚碳酸酯(PC)科思创，Makrolon 6557；Polymer resin: polycarbonate (PC) Covestro, Makrolon 6557;
将90重量份聚碳酸酯，10重量份2,9-二氯喹吖啶酮置于高速混料机中混合均匀；再将上述混合物料加入到双螺杆挤出机共混挤出，将挤出料造粒后注塑成板材，共混挤出加工过程中的温度控制在180℃～270℃；注塑温度控制在180℃～270℃。Put 90 parts by weight of polycarbonate and 10 parts by weight of 2,9-dichloroquinacridone in a high-speed mixer and mix them uniformly; After the material is granulated, it is injected into a sheet, and the temperature during the blending and extrusion process is controlled at 180°C to 270°C; the injection molding temperature is controlled at 180°C to 270°C.
激光辐照条件同实施例1。紫外辐照条件及方式同实施例1。目测被激光器辐照区域是否有荧光产生，结果如表1所示。Laser irradiation conditions are the same as in Example 1. The ultraviolet irradiation conditions and mode are the same as in Example 1. Visually inspect whether there is fluorescence in the area irradiated by the laser, and the results are shown in Table 1.
实施例29Example 29
喹吖啶酮颜料：2,9-二氯喹吖啶酮；Quinacridone pigments: 2,9-dichloroquinacridone;
聚合物树脂：聚碳酸酯(PC)科思创，Makrolon 6557；Polymer resin: polycarbonate (PC) Covestro, Makrolon 6557;
将85重量份聚碳酸酯，15重量份2,9-二氯喹吖啶酮置于高速混料机中混合均匀；再将上述混合物料加入到双螺杆挤出机共混挤出，将挤出料造粒后注塑成板材，共混挤出加工过程中的温度控制在180℃～270℃；注塑温度控制在180℃～270℃。Put 85 parts by weight of polycarbonate and 15 parts by weight of 2,9-dichloroquinacridone in a high-speed mixer and mix them evenly; After the material is granulated, it is injected into a sheet, and the temperature during the blending and extrusion process is controlled at 180°C to 270°C; the injection molding temperature is controlled at 180°C to 270°C.
激光辐照条件同实施例1。紫外辐照条件及方式同实施例1。目测被激光器辐照区域是否有荧光产生，结果如表1所示。Laser irradiation conditions are the same as in Example 1. The ultraviolet irradiation conditions and mode are the same as in Example 1. Visually inspect whether there is fluorescence in the area irradiated by the laser, and the results are shown in Table 1.
实施例30Example 30
喹吖啶酮颜料：2,9-二氯喹吖啶酮；Quinacridone pigments: 2,9-dichloroquinacridone;
聚合物树脂：聚碳酸酯(PC)科思创，Makrolon 6557；Polymer resin: polycarbonate (PC) Covestro, Makrolon 6557;
将80重量份聚碳酸酯，20重量份2,9-二氯喹吖啶酮置于高速混料机中混合均匀；再将上述混合物料加入到双螺杆挤出机共混挤出，将挤出料造粒后注塑成板材，共混挤出加工过程中的温度控制在180℃～270℃；注塑温度控制在180℃～270℃。Put 80 parts by weight of polycarbonate and 20 parts by weight of 2,9-dichloroquinacridone in a high-speed mixer and mix them uniformly; After the material is granulated, it is injected into a sheet, and the temperature during the blending and extrusion process is controlled at 180°C to 270°C; the injection molding temperature is controlled at 180°C to 270°C.
激光辐照条件同实施例1。紫外辐照条件及方式同实施例1。目测被激光器辐照区域是否有荧光产生，结果如表1所示。Laser irradiation conditions are the same as in Example 1. The ultraviolet irradiation conditions and mode are the same as in Example 1. Visually inspect whether there is fluorescence in the area irradiated by the laser, and the results are shown in Table 1.
实施例31Example 31
喹吖啶酮颜料：2,9-二氯喹吖啶酮；Quinacridone pigments: 2,9-dichloroquinacridone;
聚合物树脂：聚碳酸酯(PC)中国台湾奇美，WONDERLITF PC-175；Polymer resin: polycarbonate (PC) China Taiwan Chi Mei, WONDERLITF PC-175;
将99.9重量份聚碳酸酯，0.1重量份2,9-二氯喹吖啶酮置于高速混料机中混合均匀；再将上述混合物料加入到双螺杆挤出机共混挤出，将挤出料造粒后注塑成板材，共混挤出加工过程中的温度控制在180℃～270℃；注塑温度控制在180℃～270℃。Put 99.9 parts by weight of polycarbonate and 0.1 parts by weight of 2,9-dichloroquinacridone in a high-speed mixer and mix them evenly; After the material is granulated, it is injected into a sheet, and the temperature during the blending and extrusion process is controlled at 180°C to 270°C; the injection molding temperature is controlled at 180°C to 270°C.
激光辐照条件同实施例1。紫外辐照条件及方式同实施例1。目测被激光器辐照区域是否有荧光产生，结果如表1所示。Laser irradiation conditions are the same as in Example 1. The ultraviolet irradiation conditions and mode are the same as in Example 1. Visually inspect whether there is fluorescence in the area irradiated by the laser, and the results are shown in Table 1.
实施例32Example 32
喹吖啶酮颜料：2,9-二氯喹吖啶酮；Quinacridone pigments: 2,9-dichloroquinacridone;
聚合物树脂：聚碳酸酯(PC)中国台湾奇美，WONDERLITF PC-175；Polymer resin: polycarbonate (PC) China Taiwan Chi Mei, WONDERLITF PC-175;
将99.5重量份聚碳酸酯，0.5重量份2,9-二氯喹吖啶酮置于高速混料机中混合均匀；再将上述混合物料加入到双螺杆挤出机共混挤出，将挤出料造粒后注塑成板材，共混挤出加工过程中的温度控制在180℃～270℃；注塑温度控制在180℃～270℃。Put 99.5 parts by weight of polycarbonate and 0.5 parts by weight of 2,9-dichloroquinacridone in a high-speed mixer and mix them evenly; After the material is granulated, it is injected into a sheet, and the temperature during the blending and extrusion process is controlled at 180°C to 270°C; the injection molding temperature is controlled at 180°C to 270°C.
激光辐照条件同实施例1。紫外辐照条件及方式同实施例1。目测被激光器辐照区域是否有荧光产生，结果如表1所示。Laser irradiation conditions are the same as in Example 1. The ultraviolet irradiation conditions and mode are the same as in Example 1. Visually inspect whether there is fluorescence in the area irradiated by the laser, and the results are shown in Table 1.
实施例33Example 33
喹吖啶酮颜料：2,9-二氯喹吖啶酮；Quinacridone pigments: 2,9-dichloroquinacridone;
聚合物树脂：聚碳酸酯(PC)中国台湾奇美，WONDERLITF PC-175；Polymer resin: polycarbonate (PC) China Taiwan Chi Mei, WONDERLITF PC-175;
将95重量份聚碳酸酯，5重量份2,9-二氯喹吖啶酮置于高速混料机中混合均匀；再将上述混合物料加入到双螺杆挤出机共混挤出，将挤出料造粒后注塑成板材，共混挤出加工过程中的温度控制在180℃～270℃；注塑温度控制在180℃～270℃。Put 95 parts by weight of polycarbonate and 5 parts by weight of 2,9-dichloroquinacridone in a high-speed mixer and mix them uniformly; After the material is granulated, it is injected into a sheet, and the temperature during the blending and extrusion process is controlled at 180°C to 270°C; the injection molding temperature is controlled at 180°C to 270°C.
激光辐照条件同实施例1。紫外辐照条件及方式同实施例1。目测被激光器辐照区域是否有荧光产生，结果如表1所示。Laser irradiation conditions are the same as in Example 1. The ultraviolet irradiation conditions and mode are the same as in Example 1. Visually inspect whether there is fluorescence in the area irradiated by the laser, and the results are shown in Table 1.
实施例34Example 34
喹吖啶酮颜料：2,9-二氯喹吖啶酮；Quinacridone pigments: 2,9-dichloroquinacridone;
聚合物树脂：聚碳酸酯(PC)中国台湾奇美，WONDERLITF PC-175；Polymer resin: polycarbonate (PC) China Taiwan Chi Mei, WONDERLITF PC-175;
将90重量份聚碳酸酯，10重量份2,9-二氯喹吖啶酮置于高速混料机中混合均匀；再将上述混合物料加入到双螺杆挤出机共混挤出，将挤出料造粒后注塑成板材，共混挤出加工过程中的温度控制在180℃～270℃；注塑温度控制在180℃～270℃。Put 90 parts by weight of polycarbonate and 10 parts by weight of 2,9-dichloroquinacridone in a high-speed mixer and mix them uniformly; After the material is granulated, it is injected into a sheet, and the temperature during the blending and extrusion process is controlled at 180°C to 270°C; the injection molding temperature is controlled at 180°C to 270°C.
激光辐照条件同实施例1。紫外辐照条件及方式同实施例1。目测被激光器辐照区域是否有荧光产生，结果如表1所示。Laser irradiation conditions are the same as in Example 1. The ultraviolet irradiation conditions and mode are the same as in Example 1. Visually inspect whether there is fluorescence in the area irradiated by the laser, and the results are shown in Table 1.
实施例35Example 35
喹吖啶酮颜料：2,9-二氯喹吖啶酮；Quinacridone pigments: 2,9-dichloroquinacridone;
聚合物树脂：聚碳酸酯(PC)中国台湾奇美，WONDERLITF PC-175；Polymer resin: polycarbonate (PC) China Taiwan Chi Mei, WONDERLITF PC-175;
将85重量份聚碳酸酯，15重量份2,9-二氯喹吖啶酮置于高速混料机中混合均匀；再将上述混合物料加入到双螺杆挤出机共混挤出，将挤出料造粒后注塑成板材，共混挤出加工过程中的温度控制在180℃～270℃；注塑温度控制在180℃～270℃。Put 85 parts by weight of polycarbonate and 15 parts by weight of 2,9-dichloroquinacridone in a high-speed mixer and mix them evenly; After the material is granulated, it is injected into a sheet, and the temperature during the blending and extrusion process is controlled at 180°C to 270°C; the injection molding temperature is controlled at 180°C to 270°C.
激光辐照条件同实施例1。紫外辐照条件及方式同实施例1。目测被激光器辐照区域是否有荧光产生，结果如表1所示。Laser irradiation conditions are the same as in Example 1. The ultraviolet irradiation conditions and mode are the same as in Example 1. Visually inspect whether there is fluorescence in the area irradiated by the laser, and the results are shown in Table 1.
实施例36Example 36
喹吖啶酮颜料：2,9-二氯喹吖啶酮；Quinacridone pigments: 2,9-dichloroquinacridone;
聚合物树脂：聚碳酸酯(PC)中国台湾奇美，WONDERLITF PC-175；Polymer resin: polycarbonate (PC) China Taiwan Chi Mei, WONDERLITF PC-175;
将80重量份聚碳酸酯，20重量份2,9-二氯喹吖啶酮置于高速混料机中混合均匀；再将上述混合物料加入到双螺杆挤出机共混挤出，将挤出料造粒后注塑成板材，共混挤出加工过程中的温度控制在180℃～270℃；注塑温度控制在180℃～270℃。Put 80 parts by weight of polycarbonate and 20 parts by weight of 2,9-dichloroquinacridone in a high-speed mixer and mix them uniformly; After the material is granulated, it is injected into a sheet, and the temperature during the blending and extrusion process is controlled at 180°C to 270°C; the injection molding temperature is controlled at 180°C to 270°C.
激光辐照条件同实施例1。紫外辐照条件及方式同实施例1。目测被激光器辐照区域是否有荧光产生，结果如表1所示。Laser irradiation conditions are the same as in Example 1. The ultraviolet irradiation conditions and mode are the same as in Example 1. Visually inspect whether there is fluorescence in the area irradiated by the laser, and the results are shown in Table 1.
实施例37Example 37
喹吖啶酮颜料：2,9-二氯喹吖啶酮；Quinacridone pigments: 2,9-dichloroquinacridone;
聚合物树脂：聚对苯二甲酸乙二醇酯(PET)远纺工业，CB-602；Polymer resin: Polyethylene terephthalate (PET) Yuanfang Industry, CB-602;
将95重量份聚对苯二甲酸乙二醇酯，5重量份2,9-二氯喹吖啶酮置于高速混料机中混合均匀；再将上述混合物料加入到双螺杆挤出机共混挤出，将挤出料造粒后注塑成板材，共混挤出加工过程中的温度控制在180℃～230℃；注塑温度控制在180℃～230℃。Put 95 parts by weight of polyethylene terephthalate and 5 parts by weight of 2,9-dichloroquinacridone in a high-speed mixer and mix them uniformly; then add the above-mentioned mixture to a twin-screw extruder for blending Extrusion, the extruded material is granulated and then injected into a plate. The temperature during the blending and extrusion process is controlled at 180°C to 230°C; the injection molding temperature is controlled at 180°C to 230°C.
激光辐照条件同实施例1。紫外辐照条件及方式同实施例1。目测被激光器辐照区域是否有荧光产生，结果如表1所示。Laser irradiation conditions are the same as in Example 1. The ultraviolet irradiation conditions and mode are the same as in Example 1. Visually inspect whether there is fluorescence in the area irradiated by the laser, and the results are shown in Table 1.
实施例38Example 38
喹吖啶酮颜料：2,9-二氯喹吖啶酮；Quinacridone pigments: 2,9-dichloroquinacridone;
聚合物树脂：聚对苯二甲酸丁二醇酯(PBT)德国巴斯夫，PBT B41000；Polymer resin: polybutylene terephthalate (PBT) BASF, Germany, PBT B41000;
将95重量份聚对苯二甲酸丁二醇酯，5重量份2,9-二氯喹吖啶酮置于高速混料机中混合均匀；再将上述混合物料加入到双螺杆挤出机共混挤出，将挤出料造粒后注塑成板材，共混挤出加工过程中的温度控制在180℃～230℃；注塑温度控制在180℃～230℃。Put 95 parts by weight of polybutylene terephthalate and 5 parts by weight of 2,9-dichloroquinacridone in a high-speed mixer and mix them uniformly; then add the above-mentioned mixture to a twin-screw extruder for blending Extrusion, the extruded material is granulated and then injected into a plate. The temperature during the blending and extrusion process is controlled at 180°C to 230°C; the injection molding temperature is controlled at 180°C to 230°C.
激光辐照条件同实施例1。紫外辐照条件及方式同实施例1。目测被激光器辐照区域是否有荧光产生，结果如表1所示。Laser irradiation conditions are the same as in Example 1. The ultraviolet irradiation conditions and mode are the same as in Example 1. Visually inspect whether there is fluorescence in the area irradiated by the laser, and the results are shown in Table 1.
实施例39Example 39
喹吖啶酮颜料：2,9-二氯喹吖啶酮；Quinacridone pigments: 2,9-dichloroquinacridone;
聚合物树脂：聚甲基丙烯酸甲酯(PMMA)赢创德固赛,8N；Polymer resin: polymethyl methacrylate (PMMA) Evonik Degussa, 8N;
二氯甲烷：成都市科隆化学品有限公司，AR，含量≥99.5％；Dichloromethane: Chengdu Kelong Chemicals Co., Ltd., AR, content ≥99.5%;
将99重量份聚甲基丙烯酸甲酯溶解于500重量份二氯甲烷溶液中，待其全部溶解后，称取1重量份2,9-二氯喹吖啶酮加入其中，室温下搅拌1小时，继而用可调式涂膜器将上述混合物制成膜材料。待溶剂挥发后，采用以下条件对上述膜进行激光辐照：二氧化碳激光器波长为9.3μm，打标速度为1000mm/s，激光功率为10W，激光频率为20kHz。Dissolve 99 parts by weight of polymethyl methacrylate in 500 parts by weight of dichloromethane solution, after it is completely dissolved, weigh 1 part by weight of 2,9-dichloroquinacridone and add it, and stir at room temperature for 1 hour, The above mixture was then made into a film material with an adjustable film applicator. After the solvent evaporates, the above film is irradiated with laser light under the following conditions: the carbon dioxide laser wavelength is 9.3 μm, the marking speed is 1000 mm/s, the laser power is 10 W, and the laser frequency is 20 kHz.
激光辐照条件同实施例1。紫外辐照条件及方式同实施例1。目测被激光器辐照区域是否有荧光产生，结果如表1所示。Laser irradiation conditions are the same as in Example 1. The ultraviolet irradiation conditions and mode are the same as in Example 1. Visually inspect whether there is fluorescence in the area irradiated by the laser, and the results are shown in Table 1.
实施例40Example 40
喹吖啶酮颜料：2,9-二氯喹吖啶酮；Quinacridone pigments: 2,9-dichloroquinacridone;
聚合物树脂：聚甲基丙烯酸甲酯(PMMA)中国台湾奇美,CM-211；Polymer resin: Polymethyl methacrylate (PMMA) Chimei, Taiwan, China, CM-211;
二氯甲烷：成都市科隆化学品有限公司，AR，含量≥99.5％；Dichloromethane: Chengdu Kelong Chemicals Co., Ltd., AR, content ≥99.5%;
将99重量份聚甲基丙烯酸甲酯溶解于500重量份二氯甲烷溶液中，待其全部溶解后，称取1重量份2,9-二氯喹吖啶酮加入其中，室温下搅拌1小时，继而用可调式涂膜器将上述混合物制成膜材料。待溶剂挥发后Dissolve 99 parts by weight of polymethyl methacrylate in 500 parts by weight of dichloromethane solution, after it is completely dissolved, weigh 1 part by weight of 2,9-dichloroquinacridone and add it, and stir at room temperature for 1 hour, The above mixture was then made into a film material with an adjustable film applicator. After the solvent evaporates
激光辐照条件同实施例1。紫外辐照条件及方式同实施例1。目测被激光器辐照区域是否有荧光产生，结果如表1所示。Laser irradiation conditions are the same as in Example 1. The ultraviolet irradiation conditions and mode are the same as in Example 1. Visually inspect whether there is fluorescence in the area irradiated by the laser, and the results are shown in Table 1.
实施例41Example 41
喹吖啶酮颜料：2,9-二氯喹吖啶酮；Quinacridone pigments: 2,9-dichloroquinacridone;
聚合物树脂：聚甲基丙烯酸甲酯(PMMA)日本南通三菱丽阳,MF001；Polymer resin: Polymethyl methacrylate (PMMA) Mitsubishi Rayon, Nantong, Japan, MF001;
二氯甲烷：成都市科隆化学品有限公司，AR，含量≥99.5％；Dichloromethane: Chengdu Kelong Chemicals Co., Ltd., AR, content ≥99.5%;
将99重量份聚甲基丙烯酸甲酯溶解于500重量份二氯甲烷溶液中，待其全部溶解后，称取1重量份2,9-二氯喹吖啶酮加入其中，室温下搅拌1小时，继而用可调式涂膜器将上述混合物制成膜材料。待溶剂挥发后Dissolve 99 parts by weight of polymethyl methacrylate in 500 parts by weight of dichloromethane solution, after it is completely dissolved, weigh 1 part by weight of 2,9-dichloroquinacridone and add it, and stir at room temperature for 1 hour, The above mixture was then made into a film material with an adjustable film applicator. After the solvent evaporates
激光辐照条件同实施例1。紫外辐照条件及方式同实施例1。目测被激光器辐照区域是否有荧光产生，结果如表1所示。Laser irradiation conditions are the same as in Example 1. The ultraviolet irradiation conditions and mode are the same as in Example 1. Visually inspect whether there is fluorescence in the area irradiated by the laser, and the results are shown in Table 1.
实施例42Example 42
喹吖啶酮颜料：2,9-二氯喹吖啶酮；Quinacridone pigments: 2,9-dichloroquinacridone;
聚合物树脂：聚甲基丙烯酸甲酯(PMMA)法国阿科玛,V020；Polymer resin: Polymethyl methacrylate (PMMA) France Arkema, V020;
二氯甲烷：成都市科隆化学品有限公司，AR，含量≥99.5％；Dichloromethane: Chengdu Kelong Chemicals Co., Ltd., AR, content ≥99.5%;
将99重量份聚甲基丙烯酸甲酯溶解于500重量份二氯甲烷溶液中，待其全部溶解后，称取1重量份2,9-二氯喹吖啶酮加入其中，室温下搅拌1小时，继而用可调式涂膜器将上述混合物制成膜材料。待溶剂挥发后Dissolve 99 parts by weight of polymethyl methacrylate in 500 parts by weight of dichloromethane solution, after it is completely dissolved, weigh 1 part by weight of 2,9-dichloroquinacridone and add it, and stir at room temperature for 1 hour, The above mixture was then made into a film material with an adjustable film applicator. After the solvent evaporates
激光辐照条件同实施例1。紫外辐照条件及方式同实施例1。目测被激光器辐照区域是否有荧光产生，结果如表1所示。Laser irradiation conditions are the same as in Example 1. The ultraviolet irradiation conditions and mode are the same as in Example 1. Visually inspect whether there is fluorescence in the area irradiated by the laser, and the results are shown in Table 1.
实施例43Example 43
喹吖啶酮颜料：2,9-二氯喹吖啶酮；Quinacridone pigments: 2,9-dichloroquinacridone;
聚合物树脂：聚碳酸酯(PC)：科思创Makrolon 6557；Polymer resin: polycarbonate (PC): Covestro Makrolon 6557;
二氯甲烷：成都市科隆化学品有限公司，AR，含量≥99.5％；Dichloromethane: Chengdu Kelong Chemicals Co., Ltd., AR, content ≥99.5%;
将99重量份聚碳酸酯溶解于500重量份二氯甲烷溶液中，待其全部溶解后，称取1重量份2,9-二氯喹吖啶酮加入其中，室温下搅拌1小时，继而用可调式涂膜器将上述混合物制成膜材料。待溶剂挥发后Dissolve 99 parts by weight of polycarbonate in 500 parts by weight of dichloromethane solution, after it is completely dissolved, weigh 1 part by weight of 2,9-dichloroquinacridone and add it, stir at room temperature for 1 hour, and then use The above-mentioned mixture is made into a film material by a tune-up film applicator. After the solvent evaporates
激光辐照条件同实施例1。紫外辐照条件及方式同实施例1。目测被激光器辐照区域是否有荧光产生，结果如表1所示。Laser irradiation conditions are the same as in Example 1. The ultraviolet irradiation conditions and mode are the same as in Example 1. Visually inspect whether there is fluorescence in the area irradiated by the laser, and the results are shown in Table 1.
实施例44Example 44
喹吖啶酮颜料：2,9-二氯喹吖啶酮；Quinacridone pigments: 2,9-dichloroquinacridone;
聚合物树脂：聚碳酸酯(PC)中国台湾奇美，WONDERLITF PC-175；Polymer resin: polycarbonate (PC) China Taiwan Chi Mei, WONDERLITF PC-175;
二氯甲烷：成都市科隆化学品有限公司，AR，含量≥99.5％；Dichloromethane: Chengdu Kelong Chemicals Co., Ltd., AR, content ≥99.5%;
将99重量份聚碳酸酯溶解于500重量份二氯甲烷溶液中，待其全部溶解后，称取1重量份2,9-二氯喹吖啶酮加入其中，室温下搅拌1小时，继而用可调式涂膜器将上述混合物制成膜材料。待溶剂挥发后Dissolve 99 parts by weight of polycarbonate in 500 parts by weight of dichloromethane solution, after it is completely dissolved, weigh 1 part by weight of 2,9-dichloroquinacridone and add it, stir at room temperature for 1 hour, and then use The above-mentioned mixture is made into a film material by a tune-up film applicator. After the solvent evaporates
激光辐照条件同实施例1。紫外辐照条件及方式同实施例1。目测被激光器辐照区域是否有荧光产生，结果如表1所示。Laser irradiation conditions are the same as in Example 1. The ultraviolet irradiation conditions and mode are the same as in Example 1. Visually inspect whether there is fluorescence in the area irradiated by the laser, and the results are shown in Table 1.
实施例45Example 45
喹吖啶酮颜料：2,9-二氯喹吖啶酮；Quinacridone pigments: 2,9-dichloroquinacridone;
聚合物树脂：聚乙烯醇(PVA-1788)；Polymer resin: polyvinyl alcohol (PVA-1788);
将99重量份聚乙烯醇溶解于400重量份水溶液中，待其全部溶解后，称取 1重量份2,9-二氯喹吖啶酮加入其中，室温下搅拌1小时，继而用可调式涂膜器将上述混合物制成膜材料。待溶剂挥发后Dissolve 99 parts by weight of polyvinyl alcohol in 400 parts by weight of an aqueous solution. After it is completely dissolved, weigh 1 part by weight of 2,9-dichloroquinacridone and add it, stir at room temperature for 1 hour, and then use the adjustable coating film The machine makes the above mixture into film material. After the solvent evaporates
激光辐照条件同实施例1。紫外辐照条件及方式同实施例1。目测被激光器辐照区域是否有荧光产生，结果如表1所示。Laser irradiation conditions are the same as in Example 1. The ultraviolet irradiation conditions and mode are the same as in Example 1. Visually inspect whether there is fluorescence in the area irradiated by the laser, and the results are shown in Table 1.
实施例46Example 46
吡咯并吡咯二酮系颜料：双(对氯苯基)-1,4-二酮吡咯并吡咯；Diketopyrrolopyrrole pigments: bis(p-chlorophenyl)-1,4-diketopyrrolopyrrole;
聚合物树脂：聚乙烯醇(PVA-1788)；Polymer resin: polyvinyl alcohol (PVA-1788);
将99重量份聚乙烯醇溶解于400重量份水溶液中，待其全部溶解后，称取 1重量份双(对氯苯基)-1,4-二酮吡咯并吡咯加入其中，室温下搅拌1小时，继而用可调式涂膜器将上述混合物制成膜材料。待溶剂挥发后Dissolve 99 parts by weight of polyvinyl alcohol in 400 parts by weight of an aqueous solution. After it is completely dissolved, weigh 1 part by weight of bis(p-chlorophenyl)-1,4-diketopyrrolopyrrole and add it, and stir at room temperature for 1 Hours, then use an adjustable film applicator to make the above mixture into a film material. After the solvent evaporates
激光辐照条件同实施例1。紫外辐照条件及方式同实施例1。目测被激光器辐照区域是否有荧光产生，结果如表1所示。Laser irradiation conditions are the same as in Example 1. The ultraviolet irradiation conditions and mode are the same as in Example 1. Visually inspect whether there is fluorescence in the area irradiated by the laser, and the results are shown in Table 1.
实施例47Example 47
苯并咪唑酮系颜料：N-(2,3-二氢-2-氧代-1H-苯并咪唑-5-基)-3-氧代 -2-[[2-(三氟甲基)苯基]偶氮]丁酰胺；Benzimidazolone pigments: N-(2,3-dihydro-2-oxo-1H-benzimidazol-5-yl)-3-oxo-2-[[2-(trifluoromethyl) Phenyl] azo] butyramide;
聚合物树脂：聚乙烯醇(PVA-1788)；Polymer resin: polyvinyl alcohol (PVA-1788);
将99重量份聚乙烯醇溶解于400重量份水溶液中，待其全部溶解后，称取 1重量份N-(2,3-二氢-2-氧代-1H-苯并咪唑-5-基)-3-氧代-2-[[2-(三氟甲基)苯基] 偶氮]丁酰胺加入其中，室温下搅拌1小时，继而用可调式涂膜器将上述混合物制成膜材料。待溶剂挥发后Dissolve 99 parts by weight of polyvinyl alcohol in 400 parts by weight of an aqueous solution, and weigh 1 part by weight of N-(2,3-dihydro-2-oxo-1H-benzimidazol-5-yl )-3-oxo-2-[[2-(trifluoromethyl)phenyl]azo]butyramide was added, stirred at room temperature for 1 hour, and then the above mixture was made into a film material with an adjustable film applicator . After the solvent evaporates
激光辐照条件同实施例1。紫外辐照条件及方式同实施例1。目测被激光器辐照区域是否有荧光产生，结果如表1所示。Laser irradiation conditions are the same as in Example 1. The ultraviolet irradiation conditions and mode are the same as in Example 1. Visually inspect whether there is fluorescence in the area irradiated by the laser, and the results are shown in Table 1.
实施例48Example 48
喹吖啶酮颜料：2,9-二氯喹吖啶酮；Quinacridone pigments: 2,9-dichloroquinacridone;
聚合物树脂：聚甲基丙烯酸甲酯(PMMA)赢创德固赛,8N；Polymer resin: polymethyl methacrylate (PMMA) Evonik Degussa, 8N;
二氯甲烷：成都市科隆化学品有限公司，AR，含量≥99.5％；Dichloromethane: Chengdu Kelong Chemicals Co., Ltd., AR, content ≥99.5%;
将99.90重量份聚甲基丙烯酸甲酯溶解于500重量份二氯甲烷溶液中，待其全部溶解后，称取0.10重量份2,9-二氯喹吖啶酮加入其中，室温下搅拌1小时，继而用可调式涂膜器将上述混合物制成膜材料。待溶剂挥发后，采用以下条件对上述膜进行激光辐照：二氧化碳激光器波长为9.3μm，打标速度为 1000mm/s，激光功率为10W，激光频率为20kHz。Dissolve 99.90 parts by weight of polymethyl methacrylate in 500 parts by weight of dichloromethane solution. After it is completely dissolved, weigh 0.10 parts by weight of 2,9-dichloroquinacridone and add it, and stir at room temperature for 1 hour. The above mixture was then made into a film material with an adjustable film applicator. After the solvent evaporates, the above film is irradiated with laser light under the following conditions: the wavelength of the carbon dioxide laser is 9.3 μm, the marking speed is 1000 mm/s, the laser power is 10 W, and the laser frequency is 20 kHz.
激光辐照条件同实施例1。紫外辐照条件及方式同实施例1。目测被激光器辐照区域是否有荧光产生，结果如表1所示。Laser irradiation conditions are the same as in Example 1. The ultraviolet irradiation conditions and mode are the same as in Example 1. Visually inspect whether there is fluorescence in the area irradiated by the laser, and the results are shown in Table 1.
实施例49Example 49
喹吖啶酮颜料：2,9-二氯喹吖啶酮；Quinacridone pigments: 2,9-dichloroquinacridone;
聚合物树脂：聚甲基丙烯酸甲酯(PMMA)赢创德固赛,8N；Polymer resin: polymethyl methacrylate (PMMA) Evonik Degussa, 8N;
二氯甲烷：成都市科隆化学品有限公司，AR，含量≥99.5％；Dichloromethane: Chengdu Kelong Chemicals Co., Ltd., AR, content ≥99.5%;
将99.95重量份聚甲基丙烯酸甲酯溶解于500重量份二氯甲烷溶液中，待其全部溶解后，称取0.05重量份2,9-二氯喹吖啶酮加入其中，室温下搅拌1小时，继而用可调式涂膜器将上述混合物制成膜材料。待溶剂挥发后，采用以下条件对上述膜进行激光辐照：二氧化碳激光器波长为9.3μm，打标速度为 1000mm/s，激光功率为10W，激光频率为20kHz。Dissolve 99.95 parts by weight of polymethyl methacrylate in 500 parts by weight of dichloromethane solution. After it is completely dissolved, weigh 0.05 parts by weight of 2,9-dichloroquinacridone and add it, and stir at room temperature for 1 hour. The above mixture was then made into a film material with an adjustable film applicator. After the solvent evaporates, the above film is irradiated with laser light under the following conditions: the wavelength of the carbon dioxide laser is 9.3 μm, the marking speed is 1000 mm/s, the laser power is 10 W, and the laser frequency is 20 kHz.
激光辐照条件同实施例1。紫外辐照条件及方式同实施例1。目测被激光器辐照区域是否有荧光产生，结果如表1所示。Laser irradiation conditions are the same as in Example 1. The ultraviolet irradiation conditions and mode are the same as in Example 1. Visually inspect whether there is fluorescence in the area irradiated by the laser, and the results are shown in Table 1.
实施例50Example 50
喹吖啶酮颜料：2,9-二氯喹吖啶酮；Quinacridone pigments: 2,9-dichloroquinacridone;
聚合物树脂：聚甲基丙烯酸甲酯(PMMA)赢创德固赛,8N；Polymer resin: polymethyl methacrylate (PMMA) Evonik Degussa, 8N;
二氯甲烷：成都市科隆化学品有限公司，AR，含量≥99.5％；Dichloromethane: Chengdu Kelong Chemicals Co., Ltd., AR, content ≥99.5%;
将99.96重量份聚甲基丙烯酸甲酯溶解于500重量份二氯甲烷溶液中，待其全部溶解后，称取0.04重量份2,9-二氯喹吖啶酮加入其中，室温下搅拌1小时，继而用可调式涂膜器将上述混合物制成膜材料。待溶剂挥发后，采用以下条件对上述膜进行激光辐照：二氧化碳激光器波长为9.3μm，打标速度为 1000mm/s，激光功率为10W，激光频率为20kHz。Dissolve 99.96 parts by weight of polymethyl methacrylate in 500 parts by weight of dichloromethane solution. After it is completely dissolved, weigh 0.04 parts by weight of 2,9-dichloroquinacridone and add it, and stir at room temperature for 1 hour. The above mixture was then made into a film material with an adjustable film applicator. After the solvent evaporates, the above film is irradiated with laser light under the following conditions: the wavelength of the carbon dioxide laser is 9.3 μm, the marking speed is 1000 mm/s, the laser power is 10 W, and the laser frequency is 20 kHz.
激光辐照条件同实施例1。紫外辐照条件及方式同实施例1。目测被激光器辐照区域是否有荧光产生，结果如表1所示。Laser irradiation conditions are the same as in Example 1. The ultraviolet irradiation conditions and mode are the same as in Example 1. Visually inspect whether there is fluorescence in the area irradiated by the laser, and the results are shown in Table 1.
实施例51Example 51
喹吖啶酮颜料：2,9-二氯喹吖啶酮；Quinacridone pigments: 2,9-dichloroquinacridone;
聚合物树脂：聚甲基丙烯酸甲酯(PMMA)赢创德固赛,8N；Polymer resin: polymethyl methacrylate (PMMA) Evonik Degussa, 8N;
二氯甲烷：成都市科隆化学品有限公司，AR，含量≥99.5％；Dichloromethane: Chengdu Kelong Chemicals Co., Ltd., AR, content ≥99.5%;
将99.97重量份聚甲基丙烯酸甲酯溶解于500重量份二氯甲烷溶液中，待其全部溶解后，称取0.03重量份2,9-二氯喹吖啶酮加入其中，室温下搅拌1小时，继而用可调式涂膜器将上述混合物制成膜材料。待溶剂挥发后，采用以下条件对上述膜进行激光辐照：二氧化碳激光器波长为9.3μm，打标速度为 1000mm/s，激光功率为10W，激光频率为20kHz。Dissolve 99.97 parts by weight of polymethyl methacrylate in 500 parts by weight of dichloromethane solution. After it is completely dissolved, weigh 0.03 parts by weight of 2,9-dichloroquinacridone and add it, and stir at room temperature for 1 hour. The above mixture was then made into a film material with an adjustable film applicator. After the solvent evaporates, the above film is irradiated with laser light under the following conditions: the wavelength of the carbon dioxide laser is 9.3 μm, the marking speed is 1000 mm/s, the laser power is 10 W, and the laser frequency is 20 kHz.
激光辐照条件同实施例1。紫外辐照条件及方式同实施例1。目测被激光器辐照区域是否有荧光产生，结果如表1所示。Laser irradiation conditions are the same as in Example 1. The ultraviolet irradiation conditions and mode are the same as in Example 1. Visually inspect whether there is fluorescence in the area irradiated by the laser, and the results are shown in Table 1.
实施例52Example 52
喹吖啶酮颜料：2,9-二氯喹吖啶酮；Quinacridone pigments: 2,9-dichloroquinacridone;
聚合物树脂：聚甲基丙烯酸甲酯(PMMA)赢创德固赛,8N；Polymer resin: polymethyl methacrylate (PMMA) Evonik Degussa, 8N;
二氯甲烷：成都市科隆化学品有限公司，AR，含量≥99.5％；Dichloromethane: Chengdu Kelong Chemicals Co., Ltd., AR, content ≥99.5%;
将99.98重量份聚甲基丙烯酸甲酯溶解于500重量份二氯甲烷溶液中，待其全部溶解后，称取0.02重量份2,9-二氯喹吖啶酮加入其中，室温下搅拌1小时，继而用可调式涂膜器将上述混合物制成膜材料。待溶剂挥发后，采用以下条件对上述膜进行激光辐照：二氧化碳激光器波长为9.3μm，打标速度为 1000mm/s，激光功率为10W，激光频率为20kHz。Dissolve 99.98 parts by weight of polymethyl methacrylate in 500 parts by weight of dichloromethane solution. After it is completely dissolved, weigh 0.02 parts by weight of 2,9-dichloroquinacridone and add it, and stir at room temperature for 1 hour. The above mixture was then made into a film material with an adjustable film applicator. After the solvent evaporates, the above film is irradiated with laser light under the following conditions: the wavelength of the carbon dioxide laser is 9.3 μm, the marking speed is 1000 mm/s, the laser power is 10 W, and the laser frequency is 20 kHz.
激光辐照条件同实施例1。紫外辐照条件及方式同实施例1。目测被激光器辐照区域是否有荧光产生，结果如表1所示。Laser irradiation conditions are the same as in Example 1. The ultraviolet irradiation conditions and mode are the same as in Example 1. Visually inspect whether there is fluorescence in the area irradiated by the laser, and the results are shown in Table 1.
实施例53Example 53
喹吖啶酮颜料：2,9-二氯喹吖啶酮；Quinacridone pigments: 2,9-dichloroquinacridone;
聚合物树脂：聚甲基丙烯酸甲酯(PMMA)赢创德固赛,8N；Polymer resin: polymethyl methacrylate (PMMA) Evonik Degussa, 8N;
二氯甲烷：成都市科隆化学品有限公司，AR，含量≥99.5％；Dichloromethane: Chengdu Kelong Chemicals Co., Ltd., AR, content ≥99.5%;
将99.99重量份聚甲基丙烯酸甲酯溶解于500重量份二氯甲烷溶液中，待其全部溶解后，称取0.01重量份2,9-二氯喹吖啶酮加入其中，室温下搅拌1小时，继而用可调式涂膜器将上述混合物制成膜材料。待溶剂挥发后，采用以下条件对上述膜进行激光辐照：二氧化碳激光器波长为9.3μm，打标速度为 1000mm/s，激光功率为10W，激光频率为20kHz。Dissolve 99.99 parts by weight of polymethyl methacrylate in 500 parts by weight of dichloromethane solution. After it is completely dissolved, weigh 0.01 parts by weight of 2,9-dichloroquinacridone and add it, and stir at room temperature for 1 hour. The above mixture was then made into a film material with an adjustable film applicator. After the solvent evaporates, the above film is irradiated with laser light under the following conditions: the wavelength of the carbon dioxide laser is 9.3 μm, the marking speed is 1000 mm/s, the laser power is 10 W, and the laser frequency is 20 kHz.
激光辐照条件同实施例1。紫外辐照条件及方式同实施例1。目测被激光器辐照区域是否有荧光产生，结果如表1所示。Laser irradiation conditions are the same as in Example 1. The ultraviolet irradiation conditions and mode are the same as in Example 1. Visually inspect whether there is fluorescence in the area irradiated by the laser, and the results are shown in Table 1.
实施例54Example 54
喹吖啶酮颜料：2,9-二氯喹吖啶酮；Quinacridone pigments: 2,9-dichloroquinacridone;
聚合物树脂：聚甲基丙烯酸甲酯(PMMA)赢创德固赛,8N；Polymer resin: polymethyl methacrylate (PMMA) Evonik Degussa, 8N;
二氯甲烷：成都市科隆化学品有限公司，AR，含量≥99.5％；Dichloromethane: Chengdu Kelong Chemicals Co., Ltd., AR, content ≥99.5%;
将99.999重量份聚甲基丙烯酸甲酯溶解于500重量份二氯甲烷溶液中，待其全部溶解后，称取0.001重量份2,9-二氯喹吖啶酮加入其中，室温下搅拌1小时，继而用可调式涂膜器将上述混合物制成膜材料。待溶剂挥发后，采用以下条件对上述膜进行激光辐照：二氧化碳激光器波长为9.3μm，打标速度为 1000mm/s，激光功率为10W，激光频率为20kHz。Dissolve 99.999 parts by weight of polymethyl methacrylate in 500 parts by weight of dichloromethane solution. After it is completely dissolved, weigh 0.001 parts by weight of 2,9-dichloroquinacridone and add it, and stir at room temperature for 1 hour. The above mixture was then made into a film material with an adjustable film applicator. After the solvent evaporates, the above film is irradiated with laser light under the following conditions: the wavelength of the carbon dioxide laser is 9.3 μm, the marking speed is 1000 mm/s, the laser power is 10 W, and the laser frequency is 20 kHz.
激光辐照条件同实施例1。紫外辐照条件及方式同实施例1。目测被激光器辐照区域是否有荧光产生，结果如表1所示。Laser irradiation conditions are the same as in Example 1. The ultraviolet irradiation conditions and mode are the same as in Example 1. Visually inspect whether there is fluorescence in the area irradiated by the laser, and the results are shown in Table 1.
对比例1Comparative example 1
二萘嵌苯系颜料：3,4,9,10-二萘嵌苯四甲酸二酐；Perylene pigments: 3,4,9,10-perylenetetracarboxylic dianhydride;
聚合物树脂：聚甲基丙烯酸甲酯(PMMA)赢创德固赛,8N；Polymer resin: polymethyl methacrylate (PMMA) Evonik Degussa, 8N;
二氯甲烷：成都市科隆化学品有限公司，AR，含量≥99.5％；Dichloromethane: Chengdu Kelong Chemicals Co., Ltd., AR, content ≥99.5%;
将99重量份聚甲基丙烯酸甲酯溶解于500重量份二氯甲烷溶液中，待其全部溶解后，称取1重量份3,4,9,10-二萘嵌苯四甲酸二酐加入其中，室温下搅拌1 小时，继而用可调式涂膜器将上述混合物制成膜材料。待溶剂挥发后，采用以下条件对上述膜进行激光辐照：二氧化碳激光器波长为9.3μm，打标速度为 1000mm/s，激光功率为10W，激光频率为20kHz。Dissolve 99 parts by weight of polymethyl methacrylate in 500 parts by weight of dichloromethane solution, after it is completely dissolved, weigh 1 part by weight of 3,4,9,10-perylenetetracarboxylic dianhydride and add it , stirred at room temperature for 1 hour, and then used an adjustable film applicator to make the above mixture into a film material. After the solvent evaporates, the above film is irradiated with laser light under the following conditions: the wavelength of the carbon dioxide laser is 9.3 μm, the marking speed is 1000 mm/s, the laser power is 10 W, and the laser frequency is 20 kHz.
激光辐照条件同实施例1。紫外辐照条件及方式同实施例1。目测被激光器辐照区域是否有荧光产生，结果如表1所示。Laser irradiation conditions are the same as in Example 1. The ultraviolet irradiation conditions and mode are the same as in Example 1. Visually inspect whether there is fluorescence in the area irradiated by the laser, and the results are shown in Table 1.
对比例2Comparative example 2
阴丹酮系颜料：6,15-二氢二蒽并哒嗪-5,9,14,18-四酮；Indanthrone pigments: 6,15-dihydrodianthracenepyridazine-5,9,14,18-tetraketone;
聚合物树脂：聚甲基丙烯酸甲酯(PMMA)赢创德固赛,8N；Polymer resin: polymethyl methacrylate (PMMA) Evonik Degussa, 8N;
二氯甲烷：成都市科隆化学品有限公司，AR，含量≥99.5％；Dichloromethane: Chengdu Kelong Chemicals Co., Ltd., AR, content ≥99.5%;
将99重量份聚甲基丙烯酸甲酯溶解于500重量份二氯甲烷溶液中，待其全部溶解后，称取1重量份6,15-二氢二蒽并哒嗪-5,9,14,18-四酮加入其中，室温下搅拌1小时，继而用可调式涂膜器将上述混合物制成膜材料。待溶剂挥发后，采用以下条件对上述膜进行激光辐照：二氧化碳激光器波长为9.3μm，打标速度为1000mm/s，激光功率为10W，激光频率为20kHz。Dissolve 99 parts by weight of polymethyl methacrylate in 500 parts by weight of dichloromethane solution, after it is completely dissolved, weigh 1 part by weight of 6,15-dihydrodianthracene pyridazine-5,9,14, 18-tetraketone was added thereto, stirred at room temperature for 1 hour, and then the above mixture was made into a film material with an adjustable film applicator. After the solvent evaporates, the above film is irradiated with laser light under the following conditions: the carbon dioxide laser wavelength is 9.3 μm, the marking speed is 1000 mm/s, the laser power is 10 W, and the laser frequency is 20 kHz.
激光辐照条件同实施例1。紫外辐照条件及方式同实施例1。目测被激光器辐照区域是否有荧光产生，结果如表1所示。Laser irradiation conditions are the same as in Example 1. The ultraviolet irradiation conditions and mode are the same as in Example 1. Visually inspect whether there is fluorescence in the area irradiated by the laser, and the results are shown in Table 1.
对比例3Comparative example 3
偶氮系颜料：N-(4-氯-2-甲基苯基)-2-[(4-氯-2-硝基苯基)偶氮]-3-氧代丁酰胺；Azo pigments: N-(4-chloro-2-methylphenyl)-2-[(4-chloro-2-nitrophenyl)azo]-3-oxobutyramide;
聚合物树脂：聚甲基丙烯酸甲酯(PMMA)赢创德固赛,8N；Polymer resin: polymethyl methacrylate (PMMA) Evonik Degussa, 8N;
二氯甲烷：成都市科隆化学品有限公司，AR，含量≥99.5％；Dichloromethane: Chengdu Kelong Chemicals Co., Ltd., AR, content ≥99.5%;
将99重量份聚甲基丙烯酸甲酯溶解于500重量份二氯甲烷溶液中，待其全部溶解后，称取1重量份N-(4-氯-2-甲基苯基)-2-[(4-氯-2-硝基苯基)偶氮]-3-氧代丁酰胺加入其中，室温下搅拌1小时，继而用可调式涂膜器将上述混合物制成膜材料。待溶剂挥发后，采用以下条件对上述膜进行激光辐照：二氧化碳激光器波长为9.3μm，打标速度为1000mm/s，激光功率为10W，激光频率为20kHz。Dissolve 99 parts by weight of polymethyl methacrylate in 500 parts by weight of dichloromethane solution, after it is completely dissolved, weigh 1 part by weight of N-(4-chloro-2-methylphenyl)-2-[ (4-Chloro-2-nitrophenyl)azo]-3-oxobutyramide was added thereto, stirred at room temperature for 1 hour, and then the above mixture was made into a membrane material with an adjustable film applicator. After the solvent evaporates, the above film is irradiated with laser light under the following conditions: the carbon dioxide laser wavelength is 9.3 μm, the marking speed is 1000 mm/s, the laser power is 10 W, and the laser frequency is 20 kHz.
激光辐照条件同实施例1。紫外辐照条件及方式同实施例1。目测被激光器辐照区域是否有荧光产生，结果如表1所示。Laser irradiation conditions are the same as in Example 1. The ultraviolet irradiation conditions and mode are the same as in Example 1. Visually inspect whether there is fluorescence in the area irradiated by the laser, and the results are shown in Table 1.
对比例4Comparative example 4
异吲哚系颜料：3,3'-[(2-甲基-1,3-亚苯基)二亚氨基]二[4,5,6,7-四氯-1H-异吲哚-1-酮]；Isoindole pigments: 3,3'-[(2-methyl-1,3-phenylene)diimino]bis[4,5,6,7-tetrachloro-1H-isoindole-1 -ketone];
聚合物树脂：聚甲基丙烯酸甲酯(PMMA)赢创德固赛,8N；Polymer resin: polymethyl methacrylate (PMMA) Evonik Degussa, 8N;
二氯甲烷：成都市科隆化学品有限公司，AR，含量≥99.5％；Dichloromethane: Chengdu Kelong Chemicals Co., Ltd., AR, content ≥99.5%;
将99重量份聚甲基丙烯酸甲酯溶解于500重量份二氯甲烷溶液中，待其全部溶解后，称取1重量份3,3'-[(2-甲基-1,3-亚苯基)二亚氨基]二[4,5,6,7-四氯-1H- 异吲哚-1-酮]加入其中，室温下搅拌1小时，继而用可调式涂膜器将上述混合物制成膜材料。待溶剂挥发后，采用以下条件对上述膜进行激光辐照：二氧化碳激光器波长为9.3μm，打标速度为1000mm/s，激光功率为10W，激光频率为20kHz。Dissolve 99 parts by weight of polymethyl methacrylate in 500 parts by weight of dichloromethane solution, after it is completely dissolved, weigh 1 part by weight of 3,3'-[(2-methyl-1,3-phenylene base) diimino] bis[4,5,6,7-tetrachloro-1H-isoindol-1-one] was added, stirred at room temperature for 1 hour, and then the above mixture was made into membrane material. After the solvent evaporates, the above film is irradiated with laser light under the following conditions: the carbon dioxide laser wavelength is 9.3 μm, the marking speed is 1000 mm/s, the laser power is 10 W, and the laser frequency is 20 kHz.
激光辐照条件同实施例1。紫外辐照条件及方式同实施例1。目测被激光器辐照区域是否有荧光产生，结果如表1所示。Laser irradiation conditions are the same as in Example 1. The ultraviolet irradiation conditions and mode are the same as in Example 1. Visually inspect whether there is fluorescence in the area irradiated by the laser, and the results are shown in Table 1.
对比例5Comparative example 5
酞菁颜料：4316颜料酞菁蓝B4G；Phthalocyanine pigment: 4316 pigment phthalocyanine blue B4G;
聚合物树脂：聚甲基丙烯酸甲酯(PMMA)赢创德固赛,8N；Polymer resin: polymethyl methacrylate (PMMA) Evonik Degussa, 8N;
二氯甲烷：成都市科隆化学品有限公司，AR，含量≥99.5％；Dichloromethane: Chengdu Kelong Chemicals Co., Ltd., AR, content ≥99.5%;
将99重量份聚甲基丙烯酸甲酯溶解于500重量份二氯甲烷溶液中，待其全部溶解后，称取1重量份4316颜料酞菁蓝B4G加入其中，室温下搅拌1小时，继而用可调式涂膜器将上述混合物制成膜材料。待溶剂挥发后，采用以下条件对上述膜进行激光辐照：二氧化碳激光器波长为9.3μm，打标速度为1000mm/s，激光功率为10W，激光频率为20kHz。Dissolve 99 parts by weight of polymethyl methacrylate in 500 parts by weight of dichloromethane solution. After it is completely dissolved, weigh 1 part by weight of 4316 pigment phthalocyanine blue B4G and add it, stir at room temperature for 1 hour, and then use The above-mentioned mixture is made into a film material by a tune-up film applicator. After the solvent evaporates, the above film is irradiated with laser light under the following conditions: the carbon dioxide laser wavelength is 9.3 μm, the marking speed is 1000 mm/s, the laser power is 10 W, and the laser frequency is 20 kHz.
激光辐照条件同实施例1。紫外辐照条件及方式同实施例1。目测被激光器辐照区域是否有荧光产生，结果如表1所示。Laser irradiation conditions are the same as in Example 1. The ultraviolet irradiation conditions and mode are the same as in Example 1. Visually inspect whether there is fluorescence in the area irradiated by the laser, and the results are shown in Table 1.
对比例6Comparative example 6
喹吖啶酮颜料：2,9-二氯喹吖啶酮；Quinacridone pigments: 2,9-dichloroquinacridone;
聚合物树脂：聚甲基丙烯酸甲酯(PMMA)赢创德固赛,8N；Polymer resin: polymethyl methacrylate (PMMA) Evonik Degussa, 8N;
二氯甲烷：成都市科隆化学品有限公司，AR，含量≥99.5％；Dichloromethane: Chengdu Kelong Chemicals Co., Ltd., AR, content ≥99.5%;
将99重量份聚甲基丙烯酸甲酯溶解于500重量份二氯甲烷溶液中，待其全部溶解后，称取1重量份2,9-二氯喹吖啶酮加入其中，室温下搅拌1小时，继而用可调式涂膜器将上述混合物制成膜材料。待溶剂挥发后，采用以下条件对上述膜进行激光辐照：二氧化碳激光器波长为9.3μm，打标速度为1000mm/s，激光功率为1.8W，激光频率为20kHz。Dissolve 99 parts by weight of polymethyl methacrylate in 500 parts by weight of dichloromethane solution, after it is completely dissolved, weigh 1 part by weight of 2,9-dichloroquinacridone and add it, and stir at room temperature for 1 hour, The above mixture was then made into a film material with an adjustable film applicator. After the solvent evaporates, the above film is irradiated with laser under the following conditions: the wavelength of the carbon dioxide laser is 9.3 μm, the marking speed is 1000 mm/s, the laser power is 1.8 W, and the laser frequency is 20 kHz.
激光辐照条件同实施例1。紫外辐照条件及方式同实施例1。目测被激光器辐照区域是否有荧光产生，结果如表1所示。Laser irradiation conditions are the same as in Example 1. The ultraviolet irradiation conditions and mode are the same as in Example 1. Visually inspect whether there is fluorescence in the area irradiated by the laser, and the results are shown in Table 1.
对比例7Comparative example 7
喹吖啶酮颜料：2,9-二氯喹吖啶酮；Quinacridone pigments: 2,9-dichloroquinacridone;
聚合物树脂：聚甲基丙烯酸甲酯(PMMA)赢创德固赛,8N；Polymer resin: polymethyl methacrylate (PMMA) Evonik Degussa, 8N;
二氯甲烷：成都市科隆化学品有限公司，AR，含量≥99.5％；Dichloromethane: Chengdu Kelong Chemicals Co., Ltd., AR, content ≥99.5%;
将99重量份聚甲基丙烯酸甲酯溶解于500重量份二氯甲烷溶液中，待其全部溶解后，称取1重量份2,9-二氯喹吖啶酮加入其中，室温下搅拌1小时，继而用可调式涂膜器将上述混合物制成膜材料。待溶剂挥发后，采用以下条件对上述膜进行激光辐照：二氧化碳激光器波长为9.3μm，打标速度为1000mm/s，激光功率为1.7W，激光频率为20kHz。Dissolve 99 parts by weight of polymethyl methacrylate in 500 parts by weight of dichloromethane solution, after it is completely dissolved, weigh 1 part by weight of 2,9-dichloroquinacridone and add it, and stir at room temperature for 1 hour, The above mixture was then made into a film material with an adjustable film applicator. After the solvent evaporates, the above film is irradiated with laser under the following conditions: the wavelength of the carbon dioxide laser is 9.3 μm, the marking speed is 1000 mm/s, the laser power is 1.7 W, and the laser frequency is 20 kHz.
激光辐照条件同实施例1。紫外辐照条件及方式同实施例1。目测被激光器辐照区域是否有荧光产生，结果如表1所示。Laser irradiation conditions are the same as in Example 1. The ultraviolet irradiation conditions and mode are the same as in Example 1. Visually inspect whether there is fluorescence in the area irradiated by the laser, and the results are shown in Table 1.
对比例8Comparative example 8
喹吖啶酮颜料：2,9-二氯喹吖啶酮；Quinacridone pigments: 2,9-dichloroquinacridone;
聚合物树脂：聚甲基丙烯酸甲酯(PMMA)赢创德固赛,8N；Polymer resin: polymethyl methacrylate (PMMA) Evonik Degussa, 8N;
二氯甲烷：成都市科隆化学品有限公司，AR，含量≥99.5％；Dichloromethane: Chengdu Kelong Chemicals Co., Ltd., AR, content ≥99.5%;
将99重量份聚甲基丙烯酸甲酯溶解于500重量份二氯甲烷溶液中，待其全部溶解后，称取1重量份2,9-二氯喹吖啶酮加入其中，室温下搅拌1小时，继而用可调式涂膜器将上述混合物制成膜材料。待溶剂挥发后，采用以下条件对上述膜进行激光辐照：二氧化碳激光器波长为9.3μm，打标速度为1000mm/s，激光功率为1.5W，激光频率为20kHz。Dissolve 99 parts by weight of polymethyl methacrylate in 500 parts by weight of dichloromethane solution, after it is completely dissolved, weigh 1 part by weight of 2,9-dichloroquinacridone and add it, and stir at room temperature for 1 hour, The above mixture was then made into a film material with an adjustable film applicator. After the solvent evaporates, the above film is irradiated with laser under the following conditions: the wavelength of the carbon dioxide laser is 9.3 μm, the marking speed is 1000 mm/s, the laser power is 1.5 W, and the laser frequency is 20 kHz.
激光辐照条件同实施例1。紫外辐照条件及方式同实施例1。目测被激光器辐照区域是否有荧光产生，结果如表1所示。Laser irradiation conditions are the same as in Example 1. The ultraviolet irradiation conditions and mode are the same as in Example 1. Visually inspect whether there is fluorescence in the area irradiated by the laser, and the results are shown in Table 1.
对比例9Comparative example 9
喹吖啶酮颜料：2,9-二氯喹吖啶酮；Quinacridone pigments: 2,9-dichloroquinacridone;
聚合物树脂：聚甲基丙烯酸甲酯(PMMA)赢创德固赛,8N；Polymer resin: polymethyl methacrylate (PMMA) Evonik Degussa, 8N;
二氯甲烷：成都市科隆化学品有限公司，AR，含量≥99.5％；Dichloromethane: Chengdu Kelong Chemicals Co., Ltd., AR, content ≥99.5%;
将99重量份聚甲基丙烯酸甲酯溶解于500重量份二氯甲烷溶液中，待其全部溶解后，称取1重量份2,9-二氯喹吖啶酮加入其中，室温下搅拌1小时，继而用可调式涂膜器将上述混合物制成膜材料。待溶剂挥发后，采用以下条件对上述膜进行激光辐照：二氧化碳激光器波长为9.3μm，打标速度为1000mm/s，激光功率为75W，激光频率为20kHz。Dissolve 99 parts by weight of polymethyl methacrylate in 500 parts by weight of dichloromethane solution, after it is completely dissolved, weigh 1 part by weight of 2,9-dichloroquinacridone and add it, and stir at room temperature for 1 hour, The above mixture was then made into a film material with an adjustable film applicator. After the solvent evaporates, the above film is irradiated with laser light under the following conditions: the carbon dioxide laser wavelength is 9.3 μm, the marking speed is 1000 mm/s, the laser power is 75 W, and the laser frequency is 20 kHz.
激光辐照条件同实施例1。紫外辐照条件及方式同实施例1。目测被激光器辐照区域是否有荧光产生，结果如表1所示。Laser irradiation conditions are the same as in Example 1. The ultraviolet irradiation conditions and mode are the same as in Example 1. Visually inspect whether there is fluorescence in the area irradiated by the laser, and the results are shown in Table 1.
对比例10Comparative example 10
喹吖啶酮颜料：2,9-二氯喹吖啶酮；Quinacridone pigments: 2,9-dichloroquinacridone;
聚合物树脂：聚甲基丙烯酸甲酯(PMMA)赢创德固赛,8N；Polymer resin: polymethyl methacrylate (PMMA) Evonik Degussa, 8N;
二氯甲烷：成都市科隆化学品有限公司，AR，含量≥99.5％；Dichloromethane: Chengdu Kelong Chemicals Co., Ltd., AR, content ≥99.5%;
将99重量份聚甲基丙烯酸甲酯溶解于500重量份二氯甲烷溶液中，待其全部溶解后，称取1重量份2,9-二氯喹吖啶酮加入其中，室温下搅拌1小时，继而用可调式涂膜器将上述混合物制成膜材料。待溶剂挥发后，采用以下条件对上述膜进行激光辐照：二氧化碳激光器波长为9.3μm，打标速度为1000mm/s，激光功率为80W，激光频率为20kHz。Dissolve 99 parts by weight of polymethyl methacrylate in 500 parts by weight of dichloromethane solution, after it is completely dissolved, weigh 1 part by weight of 2,9-dichloroquinacridone and add it, and stir at room temperature for 1 hour, The above mixture was then made into a film material with an adjustable film applicator. After the solvent evaporates, the above film is irradiated with laser under the following conditions: the wavelength of the carbon dioxide laser is 9.3 μm, the marking speed is 1000 mm/s, the laser power is 80 W, and the laser frequency is 20 kHz.
激光辐照条件同实施例1。紫外辐照条件及方式同实施例1。目测被激光器辐照区域是否有荧光产生，结果如表1所示。Laser irradiation conditions are the same as in Example 1. The ultraviolet irradiation conditions and mode are the same as in Example 1. Visually inspect whether there is fluorescence in the area irradiated by the laser, and the results are shown in Table 1.
对比例11Comparative example 11
喹吖啶酮颜料：2,9-二氯喹吖啶酮；Quinacridone pigments: 2,9-dichloroquinacridone;
聚合物树脂：聚甲基丙烯酸甲酯(PMMA)赢创德固赛,8N；Polymer resin: polymethyl methacrylate (PMMA) Evonik Degussa, 8N;
二氯甲烷：成都市科隆化学品有限公司，AR，含量≥99.5％；Dichloromethane: Chengdu Kelong Chemicals Co., Ltd., AR, content ≥99.5%;
将99重量份聚甲基丙烯酸甲酯溶解于500重量份二氯甲烷溶液中，待其全部溶解后，称取1重量份2,9-二氯喹吖啶酮加入其中，室温下搅拌1小时，继而用可调式涂膜器将上述混合物制成膜材料。待溶剂挥发后，采用以下条件对上述膜进行激光辐照：二氧化碳激光器波长为9.3μm，打标速度为1000mm/s，激光功率为81W，激光频率为20kHz。Dissolve 99 parts by weight of polymethyl methacrylate in 500 parts by weight of dichloromethane solution, after it is completely dissolved, weigh 1 part by weight of 2,9-dichloroquinacridone and add it, and stir at room temperature for 1 hour, The above mixture was then made into a film material with an adjustable film applicator. After the solvent evaporates, the above film is irradiated with laser under the following conditions: the carbon dioxide laser wavelength is 9.3 μm, the marking speed is 1000 mm/s, the laser power is 81 W, and the laser frequency is 20 kHz.
激光辐照条件同实施例1。紫外辐照条件及方式同实施例1。目测被激光器辐照区域是否有荧光产生，结果如表1所示。Laser irradiation conditions are the same as in Example 1. The ultraviolet irradiation conditions and mode are the same as in Example 1. Visually inspect whether there is fluorescence in the area irradiated by the laser, and the results are shown in Table 1.
对比例12Comparative example 12
喹吖啶酮颜料：2,9-二氯喹吖啶酮；Quinacridone pigments: 2,9-dichloroquinacridone;
聚合物树脂：聚甲基丙烯酸甲酯(PMMA)赢创德固赛,8N；Polymer resin: polymethyl methacrylate (PMMA) Evonik Degussa, 8N;
二氯甲烷：成都市科隆化学品有限公司，AR，含量≥99.5％；Dichloromethane: Chengdu Kelong Chemicals Co., Ltd., AR, content ≥99.5%;
将99重量份聚甲基丙烯酸甲酯溶解于500重量份二氯甲烷溶液中，待其全部溶解后，称取1重量份2,9-二氯喹吖啶酮加入其中，室温下搅拌1小时，继而用可调式涂膜器将上述混合物制成膜材料。待溶剂挥发后，采用以下条件对上述膜进行激光辐照：二氧化碳激光器波长为9.3μm，打标速度为1000mm/s，激光功率为85W，激光频率为20kHz。Dissolve 99 parts by weight of polymethyl methacrylate in 500 parts by weight of dichloromethane solution, after it is completely dissolved, weigh 1 part by weight of 2,9-dichloroquinacridone and add it, and stir at room temperature for 1 hour, The above mixture was then made into a film material with an adjustable film applicator. After the solvent is volatilized, the above film is irradiated with laser under the following conditions: the wavelength of the carbon dioxide laser is 9.3 μm, the marking speed is 1000 mm/s, the laser power is 85 W, and the laser frequency is 20 kHz.
激光辐照条件同实施例1。紫外辐照条件及方式同实施例1。目测被激光器辐照区域是否有荧光产生，结果如表1所示。Laser irradiation conditions are the same as in Example 1. The ultraviolet irradiation conditions and mode are the same as in Example 1. Visually inspect whether there is fluorescence in the area irradiated by the laser, and the results are shown in Table 1.
实施例1～54以及对比例1～12通过激光器辐照组合物，再用365nm紫外灯激发后，荧光强度产生情况如表1所示。After the compositions of Examples 1-54 and Comparative Examples 1-12 were irradiated with a laser and then excited with a 365nm ultraviolet lamp, the fluorescence intensity is shown in Table 1.
表1.各实施例荧光强度产生情况Table 1. The generation of fluorescence intensity in each embodiment
结果表明，无论在板材还是膜材料中，有机颜料加入后组合物在激光作用下，利用紫外灯激发后都可产生图案化的荧光发射。相比于现有技术必须将荧光分子与聚合物进行反应，本发明的组合物只需要双螺杆共混挤出或混合溶解后挥干溶剂即可制备，工艺简单高效，操作简便，而且安全、环保、能耗低，非常适合工业大规模生产。The results show that no matter in the sheet material or the film material, the composition after adding the organic pigment can produce patterned fluorescence emission under the action of laser light and excitation by ultraviolet light. Compared with the prior art, which must react fluorescent molecules with polymers, the composition of the present invention can be prepared only by twin-screw blending extrusion or mixing and dissolving, then evaporating the solvent. The process is simple and efficient, easy to operate, and safe, Environmental protection, low energy consumption, very suitable for industrial mass production.
此外，本发明将荧光与激光辐照相结合，利用激光辐照组合物，再经紫外光诱导出荧光，可在聚合物表面产生图案化的荧光发射。为聚合物防伪领域提供了一种新的方法。In addition, the present invention combines fluorescence with laser irradiation, uses laser to irradiate the composition, and then induces fluorescence by ultraviolet light, which can generate patterned fluorescence emission on the polymer surface. A new method is provided for the field of polymer anti-counterfeiting.
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB9001642D0 (en) * | 1989-01-26 | 1990-03-21 | Ciba Geigy Ag | Coloured laser marking of plastics materials |
| EP0893737A2 (en) * | 1997-07-24 | 1999-01-27 | JSR Corporation | Radiation sensitive composition |
| JP2001348441A (en) * | 2000-06-09 | 2001-12-18 | Printing Bureau Ministry Of Finance | Colored polymer materials that can be converted into fluorescent materials by laser |
| WO2008055796A1 (en) * | 2006-11-07 | 2008-05-15 | Ciba Holding Inc. | Laser marking of pigmented substrates |
| EP2505624A1 (en) * | 2011-03-29 | 2012-10-03 | Toyo Ink SC Holdings Co., Ltd. | Active energy ray-curable inkjet ink composition |
| CN105164122A (en) * | 2013-03-28 | 2015-12-16 | 拜耳制药股份公司 | Substituted oxopyridine derivatives and their use in the treatment of cardiovascular disorders |
-
2021
- 2021-02-04 CN CN202110154996.1A patent/CN112940431B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB9001642D0 (en) * | 1989-01-26 | 1990-03-21 | Ciba Geigy Ag | Coloured laser marking of plastics materials |
| EP0893737A2 (en) * | 1997-07-24 | 1999-01-27 | JSR Corporation | Radiation sensitive composition |
| JP2001348441A (en) * | 2000-06-09 | 2001-12-18 | Printing Bureau Ministry Of Finance | Colored polymer materials that can be converted into fluorescent materials by laser |
| WO2008055796A1 (en) * | 2006-11-07 | 2008-05-15 | Ciba Holding Inc. | Laser marking of pigmented substrates |
| EP2505624A1 (en) * | 2011-03-29 | 2012-10-03 | Toyo Ink SC Holdings Co., Ltd. | Active energy ray-curable inkjet ink composition |
| CN105164122A (en) * | 2013-03-28 | 2015-12-16 | 拜耳制药股份公司 | Substituted oxopyridine derivatives and their use in the treatment of cardiovascular disorders |
Non-Patent Citations (2)
| Title |
|---|
| "Spectral photoluminescence properties of YAG: Ce, R (R: Gd3+, Pr3+, Gd3+ and Pr3+) transparent fluorescent thin film prepared by pulse laser deposition";XingCao等;《Journal of Luminescence》;20201231;第223卷;第1-9页 * |
| "基于激光诱导荧光技术的煤矿水源识别研究";闫鹏程等;《光谱学与光谱分析》;20201231;第40卷(第07期);第2176-2181页 * |
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