[go: up one dir, main page]

CN113517334A - A kind of power MOSFET device with high-K dielectric trench and preparation method thereof - Google Patents

A kind of power MOSFET device with high-K dielectric trench and preparation method thereof Download PDF

Info

Publication number
CN113517334A
CN113517334A CN202110633949.5A CN202110633949A CN113517334A CN 113517334 A CN113517334 A CN 113517334A CN 202110633949 A CN202110633949 A CN 202110633949A CN 113517334 A CN113517334 A CN 113517334A
Authority
CN
China
Prior art keywords
trench
dielectric
epitaxial layer
well
layer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202110633949.5A
Other languages
Chinese (zh)
Inventor
何艳静
袁纯纯
江希
袁嵩
弓小武
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Xidian University
Original Assignee
Xidian University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Xidian University filed Critical Xidian University
Priority to CN202110633949.5A priority Critical patent/CN113517334A/en
Publication of CN113517334A publication Critical patent/CN113517334A/en
Pending legal-status Critical Current

Links

Images

Classifications

    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10DINORGANIC ELECTRIC SEMICONDUCTOR DEVICES
    • H10D30/00Field-effect transistors [FET]
    • H10D30/60Insulated-gate field-effect transistors [IGFET]
    • H10D30/63Vertical IGFETs
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10DINORGANIC ELECTRIC SEMICONDUCTOR DEVICES
    • H10D30/00Field-effect transistors [FET]
    • H10D30/01Manufacture or treatment
    • H10D30/021Manufacture or treatment of FETs having insulated gates [IGFET]
    • H10D30/025Manufacture or treatment of FETs having insulated gates [IGFET] of vertical IGFETs
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10DINORGANIC ELECTRIC SEMICONDUCTOR DEVICES
    • H10D62/00Semiconductor bodies, or regions thereof, of devices having potential barriers
    • H10D62/10Shapes, relative sizes or dispositions of the regions of the semiconductor bodies; Shapes of the semiconductor bodies
    • H10D62/102Constructional design considerations for preventing surface leakage or controlling electric field concentration
    • H10D62/103Constructional design considerations for preventing surface leakage or controlling electric field concentration for increasing or controlling the breakdown voltage of reverse-biased devices
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10DINORGANIC ELECTRIC SEMICONDUCTOR DEVICES
    • H10D62/00Semiconductor bodies, or regions thereof, of devices having potential barriers
    • H10D62/10Shapes, relative sizes or dispositions of the regions of the semiconductor bodies; Shapes of the semiconductor bodies
    • H10D62/102Constructional design considerations for preventing surface leakage or controlling electric field concentration
    • H10D62/103Constructional design considerations for preventing surface leakage or controlling electric field concentration for increasing or controlling the breakdown voltage of reverse-biased devices
    • H10D62/105Constructional design considerations for preventing surface leakage or controlling electric field concentration for increasing or controlling the breakdown voltage of reverse-biased devices by having particular doping profiles, shapes or arrangements of PN junctions; by having supplementary regions, e.g. junction termination extension [JTE] 
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10DINORGANIC ELECTRIC SEMICONDUCTOR DEVICES
    • H10D62/00Semiconductor bodies, or regions thereof, of devices having potential barriers
    • H10D62/10Shapes, relative sizes or dispositions of the regions of the semiconductor bodies; Shapes of the semiconductor bodies
    • H10D62/124Shapes, relative sizes or dispositions of the regions of semiconductor bodies or of junctions between the regions

Landscapes

  • Electrodes Of Semiconductors (AREA)

Abstract

The invention discloses a power MOSFET device with a high-K dielectric groove and a preparation method thereof, wherein the device sequentially comprises the following components from bottom to top: the device comprises a first metal layer, an N + substrate, an N-epitaxial layer and a main body structure layer; the N-epitaxial layer is internally provided with a plurality of groove well structures, the groove well structures extend downwards from the upper surface of the N-epitaxial layer, and the depth of the groove well structures is smaller than the thickness of the N-epitaxial layer; a high-K dielectric groove is arranged between two adjacent groove well structures, and the depth of the high-K dielectric groove is the same as the thickness of the N-epitaxial layer; the upper surface of the high-K dielectric groove region is provided with a groove gate, the groove gate is positioned between two adjacent main body structure layers, and a second metal layer is arranged on the groove gate; and a device source electrode is formed on the main body structure layer. The power MOSFET device provided by the invention combines the trench gate, the high-K dielectric trench and the trench well, obtains the maximum breakdown voltage, reduces the on-resistance to the maximum extent and improves the device performance.

Description

一种具有高K介电沟槽的功率MOSFET器件及其制备方法A kind of power MOSFET device with high-K dielectric trench and preparation method thereof

技术领域technical field

本发明属于半导体技术领域,具体涉及一种具有高K介电沟槽的功率MOSFET器件及其制备方法。The invention belongs to the technical field of semiconductors, and in particular relates to a power MOSFET device with a high-K dielectric trench and a preparation method thereof.

背景技术Background technique

随着半导体技术的不断发展,对电子电力系统中的功率器件提出了更高的要求。功率金属氧化物半导体场效应晶体管(Power Metal-Oxide-Semiconductor Field-EffectTransistor,Power MOSFET),也称电力场效应晶体管,是一种用栅极电压来控制漏极电流的场效应晶体管,它的显著特点是驱动电路简单,驱动功率小,开关速度快,工作频率高;但是其电流容量小,耐压低,只用于小功率的电力电子装置,无法在高压领域得到广泛应用。With the continuous development of semiconductor technology, higher requirements are put forward for power devices in electronic power systems. Power Metal-Oxide-Semiconductor Field-Effect Transistor (Power MOSFET), also known as power field effect transistor, is a field effect transistor that uses gate voltage to control drain current. It is characterized by simple driving circuit, small driving power, fast switching speed and high operating frequency; however, its current capacity is small and its withstand voltage is low, so it is only used for low-power power electronic devices and cannot be widely used in high-voltage fields.

近年来,人们致力于改善场效应晶体管导通电阻Ron和击穿电压VB的关系,试图在高击穿电压的同时得到最小的导通电阻。1991年,电子科技大学的陈星弼教授独立提出了复合缓冲层(Composite Buffer,CB)结构,并提出该结构具有Ron∝VB1.32的关系,这成功地打破了传统耐压层的“硅极限”。CB结构也即是现在为大家所熟知的超结(Superjunction,SJ)耐压层。采用超结耐压层的MOSFET被称为超结MOSFET(SJ-MOSFET)。在相同击穿电压下,SJ-MOSFET的导通电阻可以比传统功率MOSFET的导通电阻低一个数量级。In recent years, people have been devoted to improving the relationship between the on-resistance Ron and the breakdown voltage VB of the field effect transistor, trying to obtain the smallest on-resistance while having a high breakdown voltage. In 1991, Professor Chen Xingbi from the University of Electronic Science and Technology of China independently proposed the composite buffer layer (CB) structure, and proposed that the structure has the relationship of Ron∝VB 1.32 , which successfully broke the "silicon limit" of the traditional pressure-resistant layer. The CB structure is also known as a super junction (Superjunction, SJ) withstand voltage layer. A MOSFET using a superjunction withstand voltage layer is called a superjunction MOSFET (SJ-MOSFET). Under the same breakdown voltage, the on-resistance of SJ-MOSFET can be an order of magnitude lower than that of conventional power MOSFETs.

然而,基于电子电力技术的发展,现有的超结MOSFET器件低导通电阻和高击穿电压等性能方法仍然无法使用所有场景;此外,现有的超结MOSFET还存在一定电荷平衡问题,这些在一定程度上限制了其应用范围。However, based on the development of electronic power technology, the existing performance methods such as low on-resistance and high breakdown voltage of superjunction MOSFET devices still cannot be used in all scenarios; To a certain extent, its application scope is limited.

发明内容SUMMARY OF THE INVENTION

为了解决现有技术中存在的上述问题,本发明提供了一种具有高K介电沟槽的功率MOSFET器件及其制备方法。本发明要解决的技术问题通过以下技术方案实现:In order to solve the above problems existing in the prior art, the present invention provides a power MOSFET device with a high-K dielectric trench and a preparation method thereof. The technical problem to be solved by the present invention is realized by the following technical solutions:

一种具有高K介电沟槽的功率MOSFET器件,自下而上依次包括:第一金属层、N+衬底、N-外延层以及主体结构层;其中,A power MOSFET device with a high-K dielectric trench, including from bottom to top: a first metal layer, an N+ substrate, an N- epitaxial layer and a main structure layer; wherein,

所述N-外延层内设有若干沟槽阱结构,所述沟槽阱结构从所述N-外延层的上表面向下延伸,且其深度小于所述N-外延层的厚度;The N-epitaxial layer is provided with a plurality of trench well structures, the trench well structures extend downward from the upper surface of the N-epitaxial layer, and the depth thereof is smaller than the thickness of the N-epitaxial layer;

相邻两个沟槽阱结构之间设有高K介电沟槽,且所述高K介电沟槽的深度与所述N-外延层的厚度相同;所述沟槽阱结构、所述高K介电沟槽以及两者之间的所述N-外延层一起形成三维超结结构;A high-K dielectric trench is arranged between two adjacent trench well structures, and the depth of the high-K dielectric trench is the same as the thickness of the N- epitaxial layer; the trench well structure, the The high-K dielectric trench and the N-epitaxial layer therebetween together form a three-dimensional superjunction structure;

所述高K介电沟槽区上表面设有沟槽栅,所述沟槽栅位于相邻两个所述主体结构层之间,其上具有第二金属层;A trench gate is provided on the upper surface of the high-K dielectric trench region, the trench gate is located between two adjacent main body structure layers, and a second metal layer is formed thereon;

所述主体结构层上形成有器件源极。A device source electrode is formed on the main body structure layer.

在本发明的一个实施例中,所述沟槽阱结构的掺杂浓度自下而上逐渐降低。In an embodiment of the present invention, the doping concentration of the trench well structure gradually decreases from bottom to top.

在本发明的一个实施例中,所述沟槽阱结构包括第一沟槽阱和第二沟槽阱;其中,所述第二沟槽阱起始于所述N-外延层上表面,并向所述N-外延层内部延伸;In an embodiment of the present invention, the trench well structure includes a first trench well and a second trench well; wherein the second trench well starts from the upper surface of the N- epitaxial layer, and extending inside the N-epitaxial layer;

所述第一沟槽阱位于所述第二沟槽阱下方,且与所述N-外延层之间具有一定间距,以形成耗尽区。The first trench well is located below the second trench well and has a certain distance from the N- epitaxial layer to form a depletion region.

在本发明的一个实施例中,所述第一沟槽阱的宽度小于所述第二沟槽阱的宽度。In an embodiment of the present invention, the width of the first trench well is smaller than the width of the second trench well.

在本发明的一个实施例中,所述第一沟槽阱的深度小于所述第二沟槽阱的深度。In one embodiment of the present invention, the depth of the first trench well is smaller than the depth of the second trench well.

在本发明的一个实施例中,所述第一沟槽阱的离子掺杂浓度大于所述第二沟槽阱的离子掺杂浓度。In an embodiment of the present invention, the ion doping concentration of the first trench well is greater than the ion doping concentration of the second trench well.

在本发明的一个实施例中,所述主体结构层包括P+衬底、N+掺杂区以及P+掺杂区,所述P+衬底位于所述N-外延层上,所述N+掺杂区和所述P+掺杂区均位于所述P+衬底上,且所述P+掺杂区位于两个N+掺杂区之间。In an embodiment of the present invention, the body structure layer includes a P+ substrate, an N+ doped region and a P+ doped region, the P+ substrate is located on the N- epitaxial layer, the N+ doped region and The P+ doped regions are all located on the P+ substrate, and the P+ doped regions are located between two N+ doped regions.

在本发明的一个实施例中,所述P+衬底的离子掺杂浓度大于所述第二沟槽阱的离子掺杂浓度,且小于所述P+掺杂区的离子注入浓度。In an embodiment of the present invention, the ion doping concentration of the P+ substrate is greater than the ion doping concentration of the second trench well, and is smaller than the ion implantation concentration of the P+ doping region.

在本发明的一个实施例中,所述高K介电沟槽区由高K介电离子注入形成,所述高K介电离子包括氮化物或金氧化物。In one embodiment of the present invention, the high-K dielectric trench region is formed by implanting high-K dielectric ions, and the high-K dielectric ions include nitride or gold oxide.

本发明的另一个实施例还提供了一种具有高K介电沟槽的功率MOSFET器件的制备方法,包括以下步骤:Another embodiment of the present invention also provides a method for fabricating a power MOSFET device with a high-K dielectric trench, comprising the following steps:

选取第一金属层作为器件漏极,并在其上生长N+衬底;Selecting the first metal layer as the drain electrode of the device, and growing an N+ substrate on it;

在所述N+衬底上多次外延生长N-外延层,并在每次生长之后进行刻蚀和离子注入,以形成沟槽阱结构;epitaxially growing an N- epitaxial layer on the N+ substrate for many times, and performing etching and ion implantation after each growth to form a trench well structure;

对所述沟槽阱中间的N-外延层进行离子注入形成高K介电沟槽区;performing ion implantation on the N-epitaxial layer in the middle of the trench well to form a high-K dielectric trench region;

对样品表面进行多次离子注入形成主体结构层;Perform multiple ion implantation on the surface of the sample to form a main structure layer;

制作沟槽栅结构以及源极,以完成器件的制备。A trench gate structure and a source electrode are fabricated to complete the device fabrication.

本发明的有益效果:Beneficial effects of the present invention:

1、本发明通过在器件外延层中设置沟槽阱结构以在沟槽阱与外延层之间形成耗尽区,增加了器件耗尽区面积,提高了击穿电压,同时,在沟槽阱结构之间还设置有高K介电沟槽结构,改变了漂移区中的电场分布,使电场的横向分量减小,垂直电场分布均匀,进一步提升了击穿电压;1. In the present invention, a trench well structure is arranged in the epitaxial layer of the device to form a depletion region between the trench well and the epitaxial layer, thereby increasing the area of the depletion region of the device and improving the breakdown voltage. A high-K dielectric trench structure is also arranged between the structures, which changes the electric field distribution in the drift region, reduces the lateral component of the electric field, and makes the vertical electric field distribution uniform, which further improves the breakdown voltage;

2、本发明采用高K介电质离子注入技术形成K介电沟槽结构,取代了部分N-漂移区,使得漂移区的等效介电常数增加,优化了电场,改善了电荷平衡问题;同时,对于高K介质,其介电常数越高,MIS电容效应越强,从而使器件具有更高的杂质浓度和更小的导通电阻;2. The present invention uses high-K dielectric ion implantation technology to form a K dielectric trench structure, which replaces part of the N-drift region, increases the equivalent dielectric constant of the drift region, optimizes the electric field, and improves the charge balance problem; At the same time, for high-K dielectrics, the higher the dielectric constant, the stronger the MIS capacitance effect, so that the device has higher impurity concentration and smaller on-resistance;

3、本发明将沟槽阱结构的离子注入浓度设置成自下而上逐渐降低的非均匀模式,在保持耗尽区最大的情况下,折衷了击穿电压和导通电阻的关系;3. In the present invention, the ion implantation concentration of the trench well structure is set to a non-uniform mode that gradually decreases from bottom to top, and the relationship between breakdown voltage and on-resistance is compromised under the condition that the depletion region is kept to a maximum;

4、本发明提供的具有高K介电沟槽的功率MOSFET器件将沟槽栅、高K介电沟槽和沟槽阱相结合,在得到最大的击穿电压的同时,最大程度上降低了导通电阻,提高了器件性能。4. The power MOSFET device with the high-K dielectric trench provided by the present invention combines the trench gate, the high-K dielectric trench and the trench well to obtain the maximum breakdown voltage while reducing the maximum breakdown voltage to the greatest extent. On-resistance improves device performance.

以下将结合附图及实施例对本发明做进一步详细说明。The present invention will be further described in detail below with reference to the accompanying drawings and embodiments.

附图说明Description of drawings

图1是本发明实施例提供的一种具有高K介电沟槽的功率MOSFET器件结构示意图;1 is a schematic structural diagram of a power MOSFET device with a high-K dielectric trench provided by an embodiment of the present invention;

图2a是现有普通沟道的等势面;Fig. 2a is the equipotential surface of the existing common channel;

图2b是本发明实施例提供的高K介电沟槽的等势面;2b is an equipotential surface of a high-K dielectric trench provided by an embodiment of the present invention;

图3是本发明实施例提供的一种具有高K介电沟槽的功率MOSFET器件的制备方法流程图;3 is a flowchart of a method for preparing a power MOSFET device with a high-K dielectric trench provided by an embodiment of the present invention;

图4a-4j是本发明实施例提供的一种具有高K介电沟槽的功率MOSFET器件的制备过程示意图;4a-4j are schematic diagrams of a preparation process of a power MOSFET device with a high-K dielectric trench provided by an embodiment of the present invention;

附图标记说明:Description of reference numbers:

1-第一金属层;2-N+外延区;3-N-外延区;4-第一沟槽阱;5-第二沟槽阱;6-高K介电沟槽;7-P+注入区;8-沟槽栅;9-N+注入区;10-P+注入区;11-第三金属层;12-二氧化硅层;13-第二金属层。1-first metal layer; 2-N+ epitaxial region; 3-N- epitaxial region; 4-first trench well; 5-second trench well; 6-high-K dielectric trench; 7-P+ implantation region ; 8-trench gate; 9-N+ implantation region; 10-P+ implantation region; 11-third metal layer; 12-silicon dioxide layer; 13-second metal layer.

具体实施方式Detailed ways

下面结合具体实施例对本发明做进一步详细的描述,但本发明的实施方式不限于此。The present invention will be described in further detail below with reference to specific embodiments, but the embodiments of the present invention are not limited thereto.

实施例一Example 1

请参见图1,图1是本发明实施例提供的一种具有高K介电沟槽的功率MOSFET器件结构示意图,自下而上依次包括:第一金属层1、N+衬底2、N-外延层3以及主体结构层;其中,Please refer to FIG. 1. FIG. 1 is a schematic structural diagram of a power MOSFET device with a high-K dielectric trench provided by an embodiment of the present invention. From bottom to top, it includes: a first metal layer 1, an N+ substrate 2, an N- Epitaxial layer 3 and main structure layer; wherein,

N-外延层3内设有若干沟槽阱结构,沟槽阱结构从N-外延层3的上表面向下延伸,且其深度小于N-外延层3的厚度;A plurality of trench well structures are arranged in the N-epitaxial layer 3, and the trench well structures extend downward from the upper surface of the N-epitaxial layer 3, and the depth thereof is smaller than the thickness of the N-epitaxial layer 3;

相邻两个沟槽阱结构之间设有高K介电沟槽6,且高K介电沟槽6的深度与N-外延层3的厚度相同;沟槽阱结构、高K介电沟槽6以及两者之间的N-外延层3一起形成三维超结结构;A high-K dielectric trench 6 is arranged between two adjacent trench well structures, and the depth of the high-K dielectric trench 6 is the same as the thickness of the N- epitaxial layer 3; the trench well structure, the high-K dielectric trench The groove 6 and the N-epitaxial layer 3 between the two together form a three-dimensional superjunction structure;

高K介电沟槽区6上表面设有沟槽栅8,沟槽栅8位于相邻两个主体结构层之间,其上具有第二金属层11;A trench gate 8 is provided on the upper surface of the high-K dielectric trench region 6, and the trench gate 8 is located between two adjacent main body structure layers, and has a second metal layer 11 thereon;

主体结构层上形成有器件源极13。A device source electrode 13 is formed on the body structure layer.

具体的,第一金属层1是MOSFET器件的漏极,位于N+衬底区2背面。第二金属层13用于为沟槽栅8提供栅极电压。Specifically, the first metal layer 1 is the drain of the MOSFET device and is located on the backside of the N+ substrate region 2 . The second metal layer 13 is used to provide a gate voltage for the trench gate 8 .

本实施例采用沟槽栅结构,与平面栅结构相比缩短沟道长度,沟槽下的高K介电沟槽能够调整载流子分布,降低导通电阻。This embodiment adopts the trench gate structure, which shortens the channel length compared with the planar gate structure, and the high-K dielectric trench under the trench can adjust the carrier distribution and reduce the on-resistance.

进一步地,沟槽阱结构可以包括多个垂直分布的沟槽阱,其掺杂浓度自下而上逐渐降低。本实施例将沟槽阱结构的离子注入浓度设置成自下而上逐渐降低的非均匀模式,在保持耗尽区最大的情况下,折衷了击穿电压和导通电阻的关系。Further, the trench well structure may include a plurality of vertically distributed trench wells, the doping concentration of which is gradually decreased from bottom to top. In this embodiment, the ion implantation concentration of the trench well structure is set to a non-uniform mode that gradually decreases from bottom to top, and the relationship between the breakdown voltage and the on-resistance is compromised under the condition of keeping the maximum depletion region.

例如,在本实施例中,沟槽阱结构可以包括第一沟槽阱4和第二沟槽阱5;其中,第二沟槽阱5起始于N-外延层3上表面,并向N-外延层3内部延伸;For example, in the present embodiment, the trench well structure may include a first trench well 4 and a second trench well 5; wherein, the second trench well 5 starts from the upper surface of the N- epitaxial layer 3 and extends toward the N - the internal extension of the epitaxial layer 3;

第一沟槽阱4位于第二沟槽阱5下方,且与N-外延层3之间具有一定间距,以形成耗尽区。The first trench well 4 is located under the second trench well 5 and has a certain distance from the N- epitaxial layer 3 to form a depletion region.

其中,第一沟槽阱4的宽度和深度均小于第二沟槽阱5的宽度和深度,且第一沟槽阱4的离子掺杂浓度大于第二沟槽阱5的离子掺杂浓度。The width and depth of the first trench well 4 are both smaller than those of the second trench well 5 , and the ion doping concentration of the first trench well 4 is greater than that of the second trench well 5 .

在本实施例中,第一沟槽阱和第二沟槽阱使用深沟道填充技术,也就是说,在深沟槽填充方法中,可以通过外延方法或化学气相沉积来产生多个第一沟槽阱和多个第二沟槽阱。In this embodiment, the first trench well and the second trench well use deep trench filling technology, that is, in the deep trench filling method, a plurality of first trenches can be formed by epitaxy or chemical vapor deposition a trench well and a plurality of second trench wells.

更进一步地,本实施例还通过高K介电离子注入形成了高K介电沟槽区6,其中,高K介电离子包括氮化物或金氧化物,例如Si3N4、Al2O3、TiO2等。Furthermore, in this embodiment, the high-K dielectric trench region 6 is formed by implanting high-K dielectric ions, wherein the high-K dielectric ions include nitrides or gold oxides, such as Si 3 N 4 , Al 2 O 3 , TiO2 , etc.

具体地,本实施例采用高K介电质离子注入技术形成高K介电沟槽结构,取代了部分N-漂移区,使得漂移区的等效介电常数增加,优化了电场,改善了电荷平衡问题;同时,对于高K介质,其介电常数越高,MIS电容效应越强,从而使器件具有更高的杂质浓度和更小的导通电阻。Specifically, in this embodiment, a high-K dielectric trench structure is formed by using a high-K dielectric ion implantation technology, which replaces part of the N-drift region, so that the equivalent dielectric constant of the drift region is increased, the electric field is optimized, and the charge is improved. At the same time, for high-K dielectrics, the higher the dielectric constant, the stronger the MIS capacitive effect, resulting in a higher impurity concentration and smaller on-resistance for the device.

请参见图2a-2b,图2a是现有普通沟道的等势面,图2b是本发明实施例提供的高K介电沟槽的等势面;对比图2a和图2b可以发现,高K材料沟槽改变了漂移区中的电场分布,使其更加均匀和紧凑。由于HK物质在E场上的调制,电场的横向分量非常小,垂直电场分布非常均匀,因此获得了很高的击穿电压。2a-2b, FIG. 2a is an equipotential surface of an existing common channel, and FIG. 2b is an equipotential surface of a high-K dielectric trench provided by an embodiment of the present invention; The K material trench changes the electric field distribution in the drift region, making it more uniform and compact. Due to the modulation of the HK species on the E field, the lateral component of the electric field is very small and the vertical electric field distribution is very uniform, thus obtaining a high breakdown voltage.

多次实验表明,延伸的高K材料沟槽在漂移区中带来更大的MIS电容,从而增强了辅助耗尽,因此导通电阻降低,并且对电荷平衡的灵敏度也变弱。与没有介电沟槽的金属氧化物半导体场效应晶体管器件相比,其击穿电压上升了百分之十二,导通电阻下降了百分之五十。Multiple experiments have shown that the extended high-K material trench brings a larger MIS capacitance in the drift region, thereby enhancing the auxiliary depletion, thus reducing the on-resistance and the sensitivity to charge balance. Compared with a MOSFET device without a dielectric trench, its breakdown voltage increased by 12 percent and on-resistance decreased by 50 percent.

本实施例通过在器件外延层中设置沟槽阱结构以在沟槽阱与外延层之间形成耗尽区,增加了器件耗尽区面积,提高了击穿电压,同时,在沟槽阱结构之间还设置有高K介电沟槽结构,改变了漂移区中的电场分布,使电场的横向分量减小,垂直电场分布均匀,进一步提升了击穿电压。In this embodiment, a trench well structure is arranged in the epitaxial layer of the device to form a depletion region between the trench well and the epitaxial layer, thereby increasing the area of the depletion region of the device and improving the breakdown voltage. At the same time, in the trench well structure There is also a high-K dielectric trench structure between them, which changes the electric field distribution in the drift region, reduces the lateral component of the electric field, and makes the vertical electric field distribution uniform, which further improves the breakdown voltage.

在本实施例中,主体结构层包括P+衬底7、N+掺杂区9以及P+掺杂区10,P+衬底7位于N-外延层3上,N+掺杂区9和P+掺杂区10均位于P+衬底7上,且P+掺杂区10位于两个N+掺杂区9之间。In this embodiment, the main structure layer includes a P+ substrate 7 , an N+ doped region 9 and a P+ doped region 10 , the P+ substrate 7 is located on the N− epitaxial layer 3 , the N+ doped region 9 and the P+ doped region 10 Both are located on the P+ substrate 7 , and the P+ doped region 10 is located between the two N+ doped regions 9 .

其中,P+衬底7的离子掺杂浓度大于第二沟槽阱5的离子掺杂浓度,且小于P+掺杂区10的离子注入浓度。The ion doping concentration of the P+ substrate 7 is greater than the ion doping concentration of the second trench well 5 , and is smaller than the ion implantation concentration of the P+ doping region 10 .

进一步地,P+掺杂区10以及部分N+掺杂区9上设有第三金属层11,以作为器件的源极,第三金属层11和第二金属层13之间通过二氧化硅层12隔开。Further, a third metal layer 11 is provided on the P+ doped region 10 and part of the N+ doped region 9 to serve as the source electrode of the device, and the silicon dioxide layer 12 is passed between the third metal layer 11 and the second metal layer 13 separated.

本发明提供的具有高K介电沟槽的功率MOSFET器件将沟槽栅、高K介电沟槽和沟槽阱相结合,在得到最大的击穿电压的同时,最大程度上降低了导通电阻,提高了器件性能。The power MOSFET device with the high-K dielectric trench provided by the present invention combines the trench gate, the high-K dielectric trench and the trench well, so as to obtain the maximum breakdown voltage and reduce the conduction to the greatest extent. resistance, improving device performance.

实施例二Embodiment 2

在上述实施例一的基础上,本实施例提供了一种具有高K介电沟槽的功率MOSFET器件的制备方法。请参见图3,图3是本发明实施例提供的一种具有高K介电沟槽的功率MOSFET器件的制备方法流程图,具体包括以下步骤:On the basis of the above-mentioned first embodiment, this embodiment provides a method for fabricating a power MOSFET device with a high-K dielectric trench. Please refer to FIG. 3. FIG. 3 is a flowchart of a method for preparing a power MOSFET device with a high-K dielectric trench provided by an embodiment of the present invention, which specifically includes the following steps:

S1:选取第一金属层作为器件漏极,并在其上生长N+衬底;S1: Select the first metal layer as the device drain, and grow an N+ substrate on it;

S2:在N+衬底上多次外延生长N-外延层,并在每次生长之后进行刻蚀和离子注入,以形成沟槽阱结构;S2: epitaxially grow the N- epitaxial layer on the N+ substrate for many times, and perform etching and ion implantation after each growth to form a trench well structure;

S3:对沟槽阱中间的N-外延层进行离子注入形成高K介电沟槽区;S3: perform ion implantation on the N-epitaxial layer in the middle of the trench well to form a high-K dielectric trench region;

S4:对样品表面进行多次离子注入形成主体结构层;S4: perform multiple ion implantation on the surface of the sample to form a main structure layer;

其中,主体结构层包括P+衬底、N+掺杂区以及P+掺杂区,P+衬底位于N-外延层上部,N+掺杂区和P+掺杂区均位于P+衬底上,且P+掺杂区位于两个N+掺杂区之间。The main structure layer includes a P+ substrate, an N+ doped region and a P+ doped region, the P+ substrate is located on the upper part of the N- epitaxial layer, the N+ doped region and the P+ doped region are both located on the P+ substrate, and the P+ doped region The region is located between the two N+ doped regions.

S5:制作沟槽栅结构以及源极,以完成器件的制备。S5: fabricating a trench gate structure and a source electrode to complete device fabrication.

本实施例在制备具有高K介电沟槽的功率MOSFET器件的过程中,采用多次外延技术和离子注入技术,减少了工艺难度。In this embodiment, in the process of preparing a power MOSFET device with a high-K dielectric trench, multiple epitaxy techniques and ion implantation techniques are used, which reduces the difficulty of the process.

下面以结合附图,对本发明的制备过程进行详细说明。请参见图4a-4j,图4a-4j是本发明实施例提供的一种具有高K介电沟槽的功率MOSFET器件的制备过程示意图,具体包括:The preparation process of the present invention will be described in detail below with reference to the accompanying drawings. Please refer to FIGS. 4a-4j. FIGS. 4a-4j are schematic diagrams of a preparation process of a power MOSFET device with a high-K dielectric trench provided by an embodiment of the present invention, which specifically includes:

步骤1:选取第一金属,例如铜等作为第一金属层1,并在其上生长N+衬底2,如图4a所示。Step 1: Select a first metal, such as copper, etc., as the first metal layer 1, and grow an N+ substrate 2 thereon, as shown in FIG. 4a.

具体的,由于沟槽功率MOSFET的导通沟道是从硅片表面的源极到达背面的漏极,为了降低导通,必须尽可能的提高硅衬底的掺杂浓度,一般采用高浓度的红磷掺杂的硅衬底,掺杂浓度一般为1×1013cm-3~1×1013cm-3Specifically, since the conduction channel of the trench power MOSFET is from the source on the surface of the silicon wafer to the drain on the back, in order to reduce conduction, the doping concentration of the silicon substrate must be increased as much as possible. The red phosphorus-doped silicon substrate generally has a doping concentration of 1×10 13 cm -3 to 1×10 13 cm -3 .

步骤2:在N+衬底2上先外延一部分的多晶硅3,如图4b所示。Step 2: A part of polysilicon 3 is firstly epitaxially grown on the N+ substrate 2, as shown in FIG. 4b.

步骤3:对上述部分多晶硅3形成的外延层进行沟槽刻蚀,经过光罩投影和曝光,采用干法刻蚀在外延单晶硅上形成第一沟槽,如图4c所示。Step 3: Perform trench etching on the epitaxial layer formed by the above-mentioned part of the polysilicon 3. After mask projection and exposure, dry etching is used to form a first trench on the epitaxial single crystal silicon, as shown in FIG. 4c.

步骤4:通过深沟槽填充技术对第一沟槽进行P+离子注入,形成第一沟槽阱4,如图4d所示。Step 4: Perform P+ ion implantation into the first trench by using the deep trench filling technology to form the first trench well 4, as shown in FIG. 4d.

具体的,第一沟槽阱的掺杂浓度为1×1015cm-3~1×1017cm-3Specifically, the doping concentration of the first trench well is 1×10 15 cm -3 to 1×10 17 cm -3 .

步骤5:在N-外延层3中继续外延N-材料,此次外延层厚度大于第一次外延厚度,如图4e所示。Step 5: Continue to epitaxy the N-material in the N-epitaxial layer 3, and the thickness of the epitaxial layer this time is greater than the thickness of the first epitaxial layer, as shown in FIG. 4e.

步骤6:对上述外延层进行沟槽刻蚀,经过光罩投影和曝光,采用干法刻蚀在外延单晶硅上形成第二沟槽,如图4f所示。Step 6: Perform trench etching on the above epitaxial layer, after mask projection and exposure, dry etching is used to form a second trench on the epitaxial single crystal silicon, as shown in FIG. 4f.

步骤7:通过深沟槽填充技术对第二沟槽进行P+离子注入,此时离子浓度低于第一沟槽阱中的离子浓度,形成第二沟槽阱5,如图4g所示。Step 7: Implanting P+ ions into the second trench by using the deep trench filling technique. At this time, the ion concentration is lower than the ion concentration in the first trench well, and the second trench well 5 is formed, as shown in FIG. 4g.

具体的,第二沟槽阱的掺杂浓度为1×1014cm-3~1×1016cm-3,相比于第一沟槽的离子浓度低大约一个数量级。Specifically, the doping concentration of the second trench well is 1×10 14 cm −3 to 1×10 16 cm −3 , which is about an order of magnitude lower than the ion concentration of the first trench.

步骤8:通过离子注入高K介质材料,形成高K介电沟槽,高K介电材料如图4h所示。Step 8: A high-K dielectric trench is formed by ion implantation of a high-K dielectric material, and the high-K dielectric material is shown in FIG. 4h.

具体地,这里通常选用相对介电常数为100~2000的材料,例如TiO2。材料的相对介电常数越高,越能加强其漂移区的电场。Specifically, a material with a relative dielectric constant of 100-2000 is usually selected here, such as TiO 2 . The higher the relative permittivity of a material, the more it can strengthen the electric field in its drift region.

步骤9:继续采用离子注入方式依次在N-外延层3上面形成P+衬底7、N+掺杂区9以及P+掺杂区10,从而形成期间的主体层结构,如图4i所示。Step 9: Continue to use ion implantation to form P+ substrate 7, N+ doped region 9 and P+ doped region 10 on the N- epitaxial layer 3 in sequence, so as to form the main layer structure during the formation, as shown in FIG. 4i.

步骤10:制作沟槽栅8,并在整个器件表面覆盖金属和二氧化硅,以形成器件栅极和源极,如图4j所示。Step 10: Fabricate the trench gate 8, and cover the entire surface of the device with metal and silicon dioxide to form the gate and source of the device, as shown in FIG. 4j.

至此,完成具有扩展的高K介电沟槽和三维超结的功率金属氧化物半导体场效应晶体管器件的制备。So far, the fabrication of power metal-oxide-semiconductor field-effect transistor devices with extended high-K dielectric trenches and three-dimensional superjunctions is completed.

应当说明的是,在本实施例中,诸如第一和第二等之类的关系术语仅仅用来将一个实体或者操作与另一个实体或操作区分开来,而不一定要求或者暗示这些实体或操作之间存在任何这种实际的关系或者顺序。It should be noted that, in this embodiment, relational terms such as first and second, etc. are only used to distinguish one entity or operation from another entity or operation, and do not necessarily require or imply these entities or operations. There is no such actual relationship or sequence between operations.

以上内容是结合具体的优选实施方式对本发明所作的进一步详细说明,不能认定本发明的具体实施只局限于这些说明。对于本发明所属技术领域的普通技术人员来说,在不脱离本发明构思的前提下,还可以做出若干简单推演或替换,都应当视为属于本发明的保护范围。The above content is a further detailed description of the present invention in combination with specific preferred embodiments, and it cannot be considered that the specific implementation of the present invention is limited to these descriptions. For those of ordinary skill in the technical field of the present invention, without departing from the concept of the present invention, some simple deductions or substitutions can be made, which should be regarded as belonging to the protection scope of the present invention.

Claims (10)

1.一种具有高K介电沟槽的功率MOSFET器件,其特征在于,自下而上依次包括:第一金属层(1)、N+衬底(2)、N-外延层(3)以及主体结构层;其中,1. A power MOSFET device with a high-K dielectric trench, characterized in that, from bottom to top, it comprises: a first metal layer (1), an N+ substrate (2), an N- epitaxial layer (3) and main structure layer; of which, 所述N-外延层(3)内设有若干沟槽阱结构,所述沟槽阱结构从所述N-外延层(3)的上表面向下延伸,且其深度小于所述N-外延层(3)的厚度;A plurality of trench well structures are arranged in the N-epitaxial layer (3), the trench well structures extend downward from the upper surface of the N-epitaxial layer (3), and the depth thereof is smaller than that of the N-epitaxial layer thickness of layer (3); 相邻两个沟槽阱结构之间设有高K介电沟槽(6),且所述高K介电沟槽(6)的深度与所述N-外延层(3)的厚度相同;所述沟槽阱结构、所述高K介电沟槽(6)以及两者之间的所述N-外延层(3)一起形成三维超结结构;A high-K dielectric trench (6) is provided between two adjacent trench well structures, and the depth of the high-K dielectric trench (6) is the same as the thickness of the N-epitaxial layer (3); The trench well structure, the high-K dielectric trench (6) and the N-epitaxial layer (3) therebetween together form a three-dimensional superjunction structure; 所述高K介电沟槽区(6)上表面设有沟槽栅(8),所述沟槽栅(8)位于相邻两个所述主体结构层之间,其上具有第二金属层(13);A trench gate (8) is provided on the upper surface of the high-K dielectric trench region (6), the trench gate (8) is located between two adjacent main body structure layers, and a second metal is formed thereon layer(13); 所述主体结构层上形成有器件源极(13)。A device source electrode (13) is formed on the main body structure layer. 2.根据权利要求1所述的功率MOSFET器件,其特征在于,所述沟槽阱结构的掺杂浓度自下而上逐渐降低。2 . The power MOSFET device according to claim 1 , wherein the doping concentration of the trench well structure gradually decreases from bottom to top. 3 . 3.根据权利要求1所述的功率MOSFET器件,其特征在于,所述沟槽阱结构包括第一沟槽阱(4)和第二沟槽阱(5);其中,所述第二沟槽阱(5)起始于所述N-外延层(3)上表面,并向所述N-外延层(3)内部延伸;3. The power MOSFET device according to claim 1, wherein the trench well structure comprises a first trench well (4) and a second trench well (5); wherein the second trench A well (5) starts from the upper surface of the N-epitaxial layer (3) and extends toward the interior of the N-epitaxial layer (3); 所述第一沟槽阱(4)位于所述第二沟槽阱(5)下方,且与所述N-外延层(3)之间具有一定间距,以形成耗尽区。The first trench well (4) is located below the second trench well (5) and has a certain distance from the N- epitaxial layer (3) to form a depletion region. 4.根据权利要求3所述的功率MOSFET器件,其特征在于,所述第一沟槽阱(4)的宽度小于所述第二沟槽阱(5)的宽度。4. The power MOSFET device according to claim 3, wherein the width of the first trench well (4) is smaller than the width of the second trench well (5). 5.根据权利要求3所述的功率MOSFET器件,其特征在于,所述第一沟槽阱(4)的深度小于所述第二沟槽阱(5)的深度。5. The power MOSFET device according to claim 3, characterized in that the depth of the first trench well (4) is smaller than the depth of the second trench well (5). 6.根据权利要求3所述的功率MOSFET器件,其特征在于,所述第一沟槽阱(4)的离子掺杂浓度大于所述第二沟槽阱(5)的离子掺杂浓度。6. The power MOSFET device according to claim 3, wherein the ion doping concentration of the first trench well (4) is greater than the ion doping concentration of the second trench well (5). 7.根据权利要求3所述的功率MOSFET器件,其特征在于,所述主体结构层包括P+衬底(7)、N+掺杂区(9)以及P+掺杂区(10),所述P+衬底(7)位于所述N-外延层(3)上,所述N+掺杂区(9)和所述P+掺杂区(10)均位于所述P+衬底(7)上,且所述P+掺杂区(10)位于两个N+掺杂区(9)之间。7. The power MOSFET device according to claim 3, characterized in that, the main structure layer comprises a P+ substrate (7), an N+ doped region (9) and a P+ doped region (10), the P+ substrate The bottom (7) is located on the N- epitaxial layer (3), the N+ doped region (9) and the P+ doped region (10) are both located on the P+ substrate (7), and the A P+ doped region (10) is located between the two N+ doped regions (9). 8.根据权利要求6所述的功率MOSFET器件,其特征在于,所述P+衬底(7)的离子掺杂浓度大于所述第二沟槽阱(5)的离子掺杂浓度,且小于所述P+掺杂区(10)的离子注入浓度。8. The power MOSFET device according to claim 6, characterized in that, the ion doping concentration of the P+ substrate (7) is greater than the ion doping concentration of the second trench well (5), and is less than the ion doping concentration of the second trench well (5) The ion implantation concentration of the P+ doped region (10). 9.根据权利要求1所述的功率MOSFET器件,其特征在于,所述高K介电沟槽区(6)由高K介电离子注入形成,所述高K介电离子包括氮化物或金氧化物。9. The power MOSFET device according to claim 1, wherein the high-K dielectric trench region (6) is formed by implanting high-K dielectric ions, the high-K dielectric ions comprising nitride or gold oxide. 10.一种具有高K介电沟槽的功率MOSFET器件的制备方法,其特征在于,包括以下步骤:10. A preparation method of a power MOSFET device with a high-K dielectric trench, characterized in that, comprising the following steps: 选取第一金属层作为器件漏极,并在其上生长N+衬底;Selecting the first metal layer as the drain electrode of the device, and growing an N+ substrate on it; 在所述N+衬底上多次外延生长N-外延层,并在每次生长之后进行刻蚀和离子注入,以形成沟槽阱结构;epitaxially growing an N- epitaxial layer on the N+ substrate for many times, and performing etching and ion implantation after each growth to form a trench well structure; 对所述沟槽阱中间的N-外延层进行离子注入形成高K介电沟槽区;performing ion implantation on the N-epitaxial layer in the middle of the trench well to form a high-K dielectric trench region; 对样品表面进行多次离子注入形成主体结构层;Perform multiple ion implantation on the surface of the sample to form a main structure layer; 制作沟槽栅结构以及源极,以完成器件的制备。A trench gate structure and a source electrode are fabricated to complete the device fabrication.
CN202110633949.5A 2021-06-07 2021-06-07 A kind of power MOSFET device with high-K dielectric trench and preparation method thereof Pending CN113517334A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202110633949.5A CN113517334A (en) 2021-06-07 2021-06-07 A kind of power MOSFET device with high-K dielectric trench and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202110633949.5A CN113517334A (en) 2021-06-07 2021-06-07 A kind of power MOSFET device with high-K dielectric trench and preparation method thereof

Publications (1)

Publication Number Publication Date
CN113517334A true CN113517334A (en) 2021-10-19

Family

ID=78065563

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202110633949.5A Pending CN113517334A (en) 2021-06-07 2021-06-07 A kind of power MOSFET device with high-K dielectric trench and preparation method thereof

Country Status (1)

Country Link
CN (1) CN113517334A (en)

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20100314659A1 (en) * 2009-06-12 2010-12-16 Alpha & Omega Semiconductor, Inc. Nanotube Semiconductor Devices
CN102110716A (en) * 2010-12-29 2011-06-29 电子科技大学 Trench type semiconductor power device
US20120018800A1 (en) * 2010-07-22 2012-01-26 Suku Kim Trench Superjunction MOSFET with Thin EPI Process
CN103367226A (en) * 2012-03-29 2013-10-23 中国科学院微电子研究所 Semiconductor device manufacturing method
CN106298491A (en) * 2016-11-09 2017-01-04 上海华力微电子有限公司 A method for forming a high-k metal gate
CN107579119A (en) * 2017-07-27 2018-01-12 西安电子科技大学 Vertical superjunction double-diffused metal oxide semiconductor field effect transistor with composite dielectric layer and manufacturing method thereof
US20180204907A1 (en) * 2017-01-16 2018-07-19 Leadtrend Technology Corp. Power metal-oxide-semiconductor field-effect transistor device with three-dimensional super junction and fabrication method thereof

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20100314659A1 (en) * 2009-06-12 2010-12-16 Alpha & Omega Semiconductor, Inc. Nanotube Semiconductor Devices
US20120018800A1 (en) * 2010-07-22 2012-01-26 Suku Kim Trench Superjunction MOSFET with Thin EPI Process
CN102347220A (en) * 2010-07-22 2012-02-08 飞兆半导体公司 Trench superjunction mosfet with thin epi process
CN102110716A (en) * 2010-12-29 2011-06-29 电子科技大学 Trench type semiconductor power device
CN103367226A (en) * 2012-03-29 2013-10-23 中国科学院微电子研究所 Semiconductor device manufacturing method
CN106298491A (en) * 2016-11-09 2017-01-04 上海华力微电子有限公司 A method for forming a high-k metal gate
US20180204907A1 (en) * 2017-01-16 2018-07-19 Leadtrend Technology Corp. Power metal-oxide-semiconductor field-effect transistor device with three-dimensional super junction and fabrication method thereof
CN107579119A (en) * 2017-07-27 2018-01-12 西安电子科技大学 Vertical superjunction double-diffused metal oxide semiconductor field effect transistor with composite dielectric layer and manufacturing method thereof

Similar Documents

Publication Publication Date Title
CN108807548B (en) Extensible SGT architecture with improved FOM
CN114023810B (en) An L-type base SiC MOSFET cell structure, device and manufacturing method
US7898024B2 (en) Semiconductor device and method for manufacturing the same
CN102148163B (en) Methods for manufacturing superjunction structure and superjunction semiconductor device
CN116230774B (en) Asymmetric silicon carbide trench gate MOSFET and its manufacturing method
JP2013503491A (en) Super Junction Trench Power MOSFET Device
JP2013503492A (en) Manufacture of super junction trench power MOSFET devices
US20200395452A1 (en) Semiconductor device
US20220148923A1 (en) METHOD FOR INCREASING AN OXIDE THICKNESS AT TRENCH CORNER OF AN U-shaped gate METAL-OXIDE-SEMICONDUCTOR FIELD-EFFECT TRANSISTOR
JP2003518748A (en) Self-aligned silicon carbide LMOSFET
JP2025515379A (en) Silicon carbide planar MOSFET device and method for fabricating same
JP2023554134A (en) Silicon carbide power device and its manufacturing method
US12154944B2 (en) Super junction power device
CN115241283A (en) Integrated planar-trench gate power MOSFET
CN114464674A (en) LDMOSFET device, manufacturing method and chip
CN117613098A (en) Vertical trench capacitively coupled gate-controlled junction field effect transistor and preparation method thereof
CN102945799B (en) Method for manufacturing longitudinal power semiconductor device
CN104851915B (en) Groove gate type compound semiconductor power VDMOSFET device and the method for improving its breakdown voltage
CN118448461A (en) A novel super junction SGT MOSFET device and its preparation method
CN105826360A (en) Trench-type semi super junction power device and manufacturing method thereof
CN107785433A (en) A kind of ladder high-K dielectric layer wide band gap semiconducter vertical double-diffused MOS FET
CN107134492B (en) Super junction power device and manufacturing method thereof
WO2021164246A1 (en) Semiconductor power device
CN117673163A (en) Super-junction MOSFET with high short-circuit tolerance, preparation method thereof and chip
CN113517334A (en) A kind of power MOSFET device with high-K dielectric trench and preparation method thereof

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20211019