CN113547656B - Production method of corrosion-resistant rubber molded sieve plate - Google Patents
Production method of corrosion-resistant rubber molded sieve plate Download PDFInfo
- Publication number
- CN113547656B CN113547656B CN202110828209.7A CN202110828209A CN113547656B CN 113547656 B CN113547656 B CN 113547656B CN 202110828209 A CN202110828209 A CN 202110828209A CN 113547656 B CN113547656 B CN 113547656B
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- Prior art keywords
- sieve plate
- fluororubber
- corrosion
- roller
- resistant rubber
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- 229920001971 elastomer Polymers 0.000 title claims abstract description 44
- 238000005260 corrosion Methods 0.000 title claims abstract description 32
- 230000007797 corrosion Effects 0.000 title claims abstract description 32
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 15
- 229920001973 fluoroelastomer Polymers 0.000 claims abstract description 50
- CMLFRMDBDNHMRA-UHFFFAOYSA-N 2h-1,2-benzoxazine Chemical compound C1=CC=C2C=CNOC2=C1 CMLFRMDBDNHMRA-UHFFFAOYSA-N 0.000 claims abstract description 32
- 238000000034 method Methods 0.000 claims abstract description 30
- 230000008569 process Effects 0.000 claims abstract description 28
- 238000004073 vulcanization Methods 0.000 claims abstract description 19
- 229920005989 resin Polymers 0.000 claims abstract description 15
- 239000011347 resin Substances 0.000 claims abstract description 15
- 239000011230 binding agent Substances 0.000 claims abstract description 7
- 239000000463 material Substances 0.000 claims description 40
- 238000002156 mixing Methods 0.000 claims description 27
- 239000004744 fabric Substances 0.000 claims description 23
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 18
- 239000000203 mixture Substances 0.000 claims description 18
- 239000003795 chemical substances by application Substances 0.000 claims description 13
- 150000001412 amines Chemical class 0.000 claims description 10
- 239000003431 cross linking reagent Substances 0.000 claims description 10
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 10
- 229920003023 plastic Polymers 0.000 claims description 9
- 239000004033 plastic Substances 0.000 claims description 9
- 229920002748 Basalt fiber Polymers 0.000 claims description 8
- 238000011049 filling Methods 0.000 claims description 8
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 8
- 238000004513 sizing Methods 0.000 claims description 8
- 238000003723 Smelting Methods 0.000 claims description 6
- 238000005470 impregnation Methods 0.000 claims description 6
- 239000000843 powder Substances 0.000 claims description 6
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 claims description 5
- 238000000748 compression moulding Methods 0.000 claims description 5
- 238000005520 cutting process Methods 0.000 claims description 5
- 229910021389 graphene Inorganic materials 0.000 claims description 5
- 238000011417 postcuring Methods 0.000 claims description 5
- 239000012190 activator Substances 0.000 claims description 4
- 238000001816 cooling Methods 0.000 claims description 4
- DEQZTKGFXNUBJL-UHFFFAOYSA-N n-(1,3-benzothiazol-2-ylsulfanyl)cyclohexanamine Chemical compound C1CCCCC1NSC1=NC2=CC=CC=C2S1 DEQZTKGFXNUBJL-UHFFFAOYSA-N 0.000 claims description 4
- 239000002243 precursor Substances 0.000 claims description 4
- 238000005303 weighing Methods 0.000 claims description 4
- BNCADMBVWNPPIZ-UHFFFAOYSA-N 2-n,2-n,4-n,4-n,6-n,6-n-hexakis(methoxymethyl)-1,3,5-triazine-2,4,6-triamine Chemical compound COCN(COC)C1=NC(N(COC)COC)=NC(N(COC)COC)=N1 BNCADMBVWNPPIZ-UHFFFAOYSA-N 0.000 claims description 3
- CMAUJSNXENPPOF-UHFFFAOYSA-N n-(1,3-benzothiazol-2-ylsulfanyl)-n-cyclohexylcyclohexanamine Chemical compound C1CCCCC1N(C1CCCCC1)SC1=NC2=CC=CC=C2S1 CMAUJSNXENPPOF-UHFFFAOYSA-N 0.000 claims description 3
- 238000005096 rolling process Methods 0.000 claims description 3
- VUICDAROYXXKCF-UHFFFAOYSA-N N-(6-aminohexyl)-3-phenylprop-2-enamide Chemical compound C(C=CC1=CC=CC=C1)(=O)NCCCCCCN VUICDAROYXXKCF-UHFFFAOYSA-N 0.000 claims 1
- ACWOEBLNSPFLBG-UHFFFAOYSA-N carbonic acid;hexane-1,1-diamine Chemical compound OC(O)=O.CCCCCC(N)N ACWOEBLNSPFLBG-UHFFFAOYSA-N 0.000 claims 1
- 238000003825 pressing Methods 0.000 abstract description 12
- 238000004132 cross linking Methods 0.000 abstract description 8
- 239000000126 substance Substances 0.000 abstract description 5
- 230000009286 beneficial effect Effects 0.000 abstract description 4
- 239000002131 composite material Substances 0.000 abstract description 4
- 229910000039 hydrogen halide Inorganic materials 0.000 abstract description 4
- 239000012433 hydrogen halide Substances 0.000 abstract description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract description 3
- 239000006096 absorbing agent Substances 0.000 abstract description 3
- 238000006243 chemical reaction Methods 0.000 abstract description 3
- 229910052739 hydrogen Inorganic materials 0.000 abstract description 3
- 239000001257 hydrogen Substances 0.000 abstract description 3
- 230000001360 synchronised effect Effects 0.000 abstract description 3
- 239000002253 acid Substances 0.000 abstract description 2
- 229910052751 metal Inorganic materials 0.000 description 13
- 239000002184 metal Substances 0.000 description 13
- 239000002585 base Substances 0.000 description 10
- 239000004814 polyurethane Substances 0.000 description 10
- 229920002635 polyurethane Polymers 0.000 description 10
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 9
- 238000003490 calendering Methods 0.000 description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 230000003213 activating effect Effects 0.000 description 6
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 6
- 230000014759 maintenance of location Effects 0.000 description 6
- 229910002804 graphite Inorganic materials 0.000 description 5
- 239000010439 graphite Substances 0.000 description 5
- 239000000853 adhesive Substances 0.000 description 4
- 230000001070 adhesive effect Effects 0.000 description 4
- 238000003801 milling Methods 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 238000005299 abrasion Methods 0.000 description 3
- URYUEMMCHKMUAG-UHFFFAOYSA-N carbonic acid;hexane-1,6-diamine Chemical compound OC(O)=O.NCCCCCCN URYUEMMCHKMUAG-UHFFFAOYSA-N 0.000 description 3
- 230000006835 compression Effects 0.000 description 3
- 238000007906 compression Methods 0.000 description 3
- 239000012535 impurity Substances 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- 229920002449 FKM Polymers 0.000 description 2
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 2
- 241000446313 Lamella Species 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 150000005130 benzoxazines Chemical group 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 238000007723 die pressing method Methods 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 239000011737 fluorine Substances 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 description 2
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 239000000395 magnesium oxide Substances 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 230000035515 penetration Effects 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 2
- 238000012216 screening Methods 0.000 description 2
- 238000002791 soaking Methods 0.000 description 2
- 102000003712 Complement factor B Human genes 0.000 description 1
- 108090000056 Complement factor B Proteins 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 1
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000004643 cyanate ester Substances 0.000 description 1
- 150000001913 cyanates Chemical class 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 1
- 235000010299 hexamethylene tetramine Nutrition 0.000 description 1
- 239000004312 hexamethylene tetramine Substances 0.000 description 1
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 1
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 1
- 229910000040 hydrogen fluoride Inorganic materials 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000009940 knitting Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229910021382 natural graphite Inorganic materials 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 230000001502 supplementing effect Effects 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 239000004636 vulcanized rubber Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/30—Mixing; Kneading continuous, with mechanical mixing or kneading devices
- B29B7/58—Component parts, details or accessories; Auxiliary operations
- B29B7/72—Measuring, controlling or regulating
- B29B7/728—Measuring data of the driving system, e.g. torque, speed, power, vibration
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C35/00—Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
- B29C35/02—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
- B29C35/0288—Controlling heating or curing of polymers during moulding, e.g. by measuring temperatures or properties of the polymer and regulating the process
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
- B29D7/00—Producing flat articles, e.g. films or sheets
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Oral & Maxillofacial Surgery (AREA)
- Thermal Sciences (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention belongs to the technical field of sieve plates, in particular to a production method of a corrosion-resistant rubber mould pressing sieve plate, which does not use the acid-absorbing agent and the acid-binding agent of the prior fluororubber, but uses hydrogen halide released in the vulcanization process of the fluororubber, and uses active hydrogen to carry out crosslinking reaction in the curing process of benzoxazine resin to form chemical bonds so as to achieve the purpose of synchronous crosslinking, improve the brittleness of the benzoxazine resin, increase the mechanical strength of a composite material, and improve the curing rate, thereby being beneficial to reducing the mould pressing forming difficulty of the sieve plate.
Description
Technical Field
The invention belongs to the technical field of sieve plates, and particularly relates to a production method of a corrosion-resistant rubber mould pressing sieve plate.
Background
The sieve plate has harsh use conditions, and has requirements of wear resistance, abrasion resistance, aging resistance, and accurate sieve pore and seam size, and the prior sieve plate (mesh) is mainly made of stainless steel, but the metal sieve plate has poor wear resistance, elasticity and corrosion resistance, large noise, high processing cost and short service life, and is being replaced by a polyurethane sieve plate in most occasions. Compared with a metal sieve plate, the polyurethane sieve plate fully exerts the characteristics of polyurethane in the aspects of high wear resistance, high elasticity, sound absorption, vibration reduction and the like, has the advantages of convenience in forming and processing, good wear resistance, long service life, high screening quality, strong self-cleaning capability, good sieve penetration performance, noise reduction, operation environment improvement, wide application range (materials with different particle sizes such as dry materials, wet materials, raw ores and crushed ores) and the like, and has a good prospect when the polyurethane sieve plate is used for replacing the metal sieve plate or a common rubber sieve plate. However, the corrosion resistance of the polyurethane sieve plate or the metal sieve plate is poor, and the screening application of corrosive minerals cannot be met. Chinese patent CN207327738U discloses a composite polyurethane strip-seam sieve plate with long service life, which is provided with an epoxy resin anticorrosive layer, a wear-resistant layer, and a ceramic wear-resistant layer, and the corrosion resistance is improved by the arrangement of the coating, but the purpose of the sieve plate is to utilize the wear resistance of polyurethane, when the anticorrosive coating with poor wear resistance is damaged, the anticorrosion function cannot be achieved, the essential performance of the polyurethane sieve plate is not brought into play, and the application effect is not good. In fact, because the polarity of the fluororubber is in place, the fluororubber is difficult to adhere to other frameworks such as metal and the like compared with common rubber, so related products and production methods of corrosion-resistant sieve plates are also available in the market at present, and the sieve plates have the use strength and corrosion-resistant characteristics required by the sieve plates. The person skilled in the art needs to develop a method for producing a corrosion-resistant rubber molded sieve plate.
Disclosure of Invention
Aiming at the problems, the invention aims to provide a production method of a corrosion-resistant rubber molded sieve plate.
The invention is realized by the following technical scheme:
a production method of a corrosion-resistant rubber molded sieve plate comprises the following steps: firstly, adding benzoxazine into a fluororubber mixed sizing material in an open mixing process, and mixing after the open mixing is finished to obtain a rubber-plastic premix; adding a vulcanizing agent in the remilling process to obtain a calendered rubber sheet, wherein the calendered base cloth is a basalt base cloth; the extrusion and the extrusion of the fluororubber sizing material are difficult, the sizing material needs to be fully remilled before being extruded, the plasticized flaky material is pressed into a screw rod of an extruder through a material pressing device, the material is continuously conveyed forwards by the screw rod, the impurities are removed through the filtration of a machine head to extrude the flaky material, the flaky material is conveyed into a calender through a conveying belt, the surface of a roller is damaged for preventing metal from being mixed into the material, and the flaky material needs to pass through a metal detector before entering the calender. The diameter of a screw is 250mm, the length-diameter ratio L/D is 6: 1, the compression ratio is 2, the machine barrel temperature is 50 to 60 ℃, the machine neck temperature is 50 to 60 ℃, the head temperature is 50 to 60 ℃, the calendering pressure is 2.5 to 3MPa, the lower roll is 40 to 50 ℃ during calendering, the middle roll temperature is controlled to be 50 to 60 ℃, and the upper roll temperature is controlled to be 70 to 80 ℃; and thirdly, cutting the rolled rubber sheets into strips, uniformly stacking and filling according to the sieve plate mold, and then carrying out compression molding, vulcanization and post curing to obtain the corrosion-resistant rubber molded sieve plate.
Furthermore, the fluororubber mixed and mixed rubber material in the first step is obtained by sequentially weighing 88 to 99phr of fluororubber, 0.5 to 1phr of accelerator, 13.5 to 14.8phr of microlite powdered ink and 0.7 to 0.98phr of fluorinated graphene in parts by weight, wherein the accelerator is one of accelerator DZ and accelerator CZ.
And the accelerator in the fluororubber sizing material can ensure that the sizing material has enough fluidity to be beneficial to the penetration of basalt fabrics into holes, and is preferably the accelerator DZ and the accelerator CZ.
The microcrystalline graphite is a dense aggregate composed of fine natural graphite crystals, and is also called as soil graphite or amorphous graphite, and the microcrystalline graphite includes graphite particles and graphite powder. The microcrystalline graphite powder is smooth, easy to stain hands, stable in chemical performance, resistant to high temperature, acid and alkali, corrosion and oxidation. Because the crystal is fine, the plasticity is strong, and the adhesive force is good.
The microlite ink powder has good mixing, extruding and mould pressing properties, the fluorinated graphene can reduce the friction coefficient of fluororubber, improve the wear resistance, obviously reduce friction temperature rise, has corrosion resistance, and is suitable for manufacturing high-vibration-frequency corrosion-resistant screens.
Further, the mixing process in the first step is that the speed ratio of a square-edged rotor is 1:1.15 to 1: 1.18, the rotation speed is 40 to 80rpm, the unit pressure of a top bolt on the material is 0.2 to 0.45MPa, the filling coefficient is 0.55 to 0.80, and the mixing time is 10 to 15min, wherein the mixing process comprises the steps of feeding fluororubber, fluorinated graphene, microcrystalline graphite powder and an accelerator in sequence, uniformly mixing, adding benzoxazine with the mass of the fluororubber being 25 to 30%, the rotation speed of a front roller is 27.5 to 28.5rpm, the speed ratio of a front roller to a rear roller is 1. Further, the vulcanizing agent is one of N, N-bis-cinnamylidene-1,6-hexamethylene diamine or hexamethylene diamine carbonate which accounts for 0.5-1% of the mass of the fluororubber. And (2) a vulcanization system: the vulcanizing system of the fluororubber of the invention only contains one component of the vulcanizing agent, does not contain other components, does not need other components, and has simple components.
Among them, hexamethylenediamine carbonate is an organic synthesis intermediate, and is almost exclusively used for the preparation of cyanate esters such as hexamethylene diisocyanate. Further, the basalt base cloth in the second step is a quadriaxial warp knitting basalt fabric impregnated with a mixture of a phenol activating agent and an amine crosslinking agent in a mass ratio of 1:1.15, wherein the impregnation content is 8-10%, the layering structure of yarn bundles is 90 °/45 °/0 °/45 °, the yarn bundles are basalt fiber twistless rovings, the diameters of basalt fiber precursors are 9-13 μm, the phenol activating agent is one or more of a binding agent RS or a binding agent RE, and the amine crosslinking agent is one or more of hexamethoxymethylmelamine or a binding agent H-80.
The impregnation of the phenolic activating agent and the amine crosslinking agent can improve the calendering combination of rubber and basalt fabrics, the phenolic activating agent and the amine crosslinking agent which are subjected to an impregnation treatment system can be simultaneously merged in the basalt fabrics to generate polycondensation to lay an adhesion foundation, for example, resorcinol and hexamethylenetetramine interact to enable the rubber and the basalt fabrics to form chemical bonding, so that the bonding strength is improved, the strip cutting, stacking and die pressing method is simple and convenient, and the method is suitable for preparing the screen plate with the basalt framework by rubber die pressing.
Further, the benzoxazine of the first step is B-m bisphenol A benzoxazine resin. The benzoxazine can improve the mixing manufacturability of the rubber material at the initial stage, so that the strength is improved, the heat resistance of the fluororubber is good, the benzoxazine curing temperature is higher, the fluororubber is not hard to cure, and the hydrogen halide in the vulcanization process of the fluororubber can catalyze benzoxazine crosslinking and is used together with the benzoxazine, so that the tear strength of the vulcanized fluororubber can be improved.
Further, the remilling process in the second step is that the rotation speed of a front roller is 27.5 to 28.5rpm, the ratio of the front roller speed to the rear roller speed is 1.15 to 1.28, the steam pressure is 0.4 to 0.5MPa, the roller gap is 1 to 2mm, the front roller is 55 to 60 ℃, the rear roller is 50 to 55 ℃, the thin pass is 10 to 12 times, the materials are fed and cooled, the vulcanization process is that the plate vulcanization is carried out under the pressure of 15 to 20MPa at the temperature of 150 to 160 ℃ for 50 to 60min, and the after-curing process is that the vulcanization is carried out in an oven under the temperature of 180 to 205 ℃ for 12 to 169h: the vulcanization of the fluororubber is carried out in two stages, wherein the first stage is used for shaping vulcanization products, and the second stage is used for supplementing and then curing.
In the benzoxazine curing process, hydrogen fluoride and hydrogen chloride separated out from fluororubber in the vulcanization process are neutralized, the vulcanization process is promoted, and the crosslinking density can be improved, so that the vulcanized rubber has better thermal stability.
The invention has the beneficial effects that:
firstly, the acid-absorbing agent of the prior fluororubber, including magnesium oxide and the like, is not used, but hydrogen halide released by the fluororubber in the vulcanization process is utilized, active hydrogen is utilized to perform crosslinking reaction in the curing process of the benzoxazine resin to form chemical bonds so as to achieve the purpose of synchronous crosslinking, the brittleness of the benzoxazine resin is improved, the mechanical strength of the composite material is increased, the curing rate is improved so as to be beneficial to reducing the molding difficulty of the sieve plate, the impact toughness and cohesiveness of the benzoxazine resin are improved, the fluidity of the benzoxazine resin is improved, the advantages of the benzoxazine resin are still maintained, the heat resistance and the modulus are high, the toughness and the strength of the base sieve plate can be improved by introducing the benzoxazine resin, after the sieve plate is subjected to external force, particularly, the feeding impact and the shock impact are eliminated, a plurality of fine cracks are generated in the sieve plate, the rubber particles cross over the high-strength benzoxazine cracks, the continuous expansion of the cracks can be slowed down, the rubber particles are deformed, the energy is also consumed, and the larger impact can be resisted, and the material is toughened and reinforced; the rubber-plastic toughening mechanism is that a rubber phase in the system continuously penetrates through a thermosetting resin benzoxazine network, after rubber toughening is carried out, external impact energy is mainly absorbed by formed silver lines by using a toughening system of a benzoxazine matrix, good toughness and low water absorption are kept in a cross-linked network, good strength is also kept, the benzoxazine also has good corrosion resistance, and the introduction of the benzoxazine does not cause great reduction of the corrosion resistance.
Compared with the prior art, the invention has the following advantages:
firstly, the acid-absorbing agent of the prior fluororubber, including magnesium oxide and the like, is not used, but hydrogen halide released by the fluororubber in the vulcanization process is utilized, active hydrogen is utilized to perform crosslinking reaction in the curing process of the benzoxazine resin to form chemical bonds, so that the aim of synchronous crosslinking is achieved, the brittleness of the benzoxazine resin is improved, the mechanical strength of the composite material is increased, and the curing rate is improved, so that the difficulty in compression molding of the sieve plate is reduced. The high-strength steel has the advantages of high load bearing strength, high temperature resistance, corrosion resistance, good mechanical property, safety, reliability, mineral corrosion and high use durability in a corrosive environment.
Detailed Description
The invention is illustrated by the following specific examples, which are not intended to be limiting.
Example 1
Wherein the basalt fabric DZXB-WFPM600 Dan Jin, fluorinated graphene with the fluorine content of 60 percent, the grain diameter D5050 mu m and the average lamella thickness of 5nm, viton A401C of fluororubber and microlite ink powder WT95-45.
Firstly, mixing and mixing a fluororubber mixture, namely weighing 88phr of fluororubber, DZ0.5phr of an accelerant, 13.5phr of microlite ink powder and 0.7phr of graphene fluoride in sequence, adding B-m bisphenol A benzoxazine resin into the fluororubber mixture in the open mixing process, mixing after the open mixing is finished, wherein the mixing process comprises the steps of enabling the speed ratio of a square rotor to be 1:1.15, enabling the rotation speed to be 40rpm, enabling the unit pressure of a top bolt on the materials to be 0.2MPa, enabling the filling coefficient to be 0.55 and enabling the mixing time to be 10min, enabling the feeding sequence to be fluororubber, the graphene fluoride, the microcrystalline graphite powder and the accelerant to be uniformly mixed, adding benzoxazine AIBZ321 with the mass of 25% of the fluororubber, enabling the rotation speed of a front roller to be 27.5rpm, enabling the speed ratio of the front roller to be 1.15, enabling the steam pressure to be 0.4MPa, enabling the roller gap to be 2mm, enabling the front roller to be 50 ℃, rear roller to be 45 ℃, enabling the mixture to be thin-passed for 8 times, and enabling the mixture to be cooled to be 25 ℃ to obtain a rubber-plastic premix; secondly, the back-smelting process comprises the steps that the rotation speed of a front roller is 27.5rpm, the speed ratio of the front roller to a rear roller is 1.15, the steam pressure is 0.4MPa, the roller gap is 1mm, the front roller is 55 ℃, the rear roller is 50 ℃ and the thin-pass is 10 times, the blanking and the cooling are carried out, the vulcanizing process is that the plate vulcanization is carried out under 15MPa and the temperature is 150 ℃ for 50min, the post-curing process is that the temperature is 180 ℃ for 12h in an oven, the rubber and plastic premix is pressed into an extruder screw through a pressing device after being back-smelted, the screw continuously conveys the material forwards, the screw filters the material through a machine head to remove impurities, extrudes the flaky material, and the flaky material is conveyed to a calender through a conveyor belt. To prevent metal from being incorporated into the material and damaging the surface of the roll, the sheet material is passed through a metal detector before entering the calender. The diameter of the screw is 250mm, the length-diameter ratio L/D is 6: 1, the compression ratio is 2, the temperature of a machine barrel is 50 ℃, the temperature of a machine neck is 50 ℃, the temperature of a machine head is 50 ℃, and the calendering pressure is 3MPa. Pressing a delay lower roller at 50 ℃, controlling a middle roller at 60 ℃, controlling an upper roller at 80 ℃, extruding and rolling the two surfaces of the delay lower roller into sheets, adding a vulcanizing agent in a remilling process, wherein the vulcanizing agent is N, N-bis-cinnamyl-1,6-hexamethylene diamine with the mass of 0.5 percent of fluororubber, so as to obtain a rolled rubber sheet, the rolled base cloth is basalt base cloth, the basalt base cloth is a tetraaxial warp-knitted basalt fabric impregnated by a mixture of a phenol activating agent and an amine crosslinking agent in a mass ratio of 1:1.15, the impregnation content is 8 percent, the layering structure of yarn bundles is 90 DEG/45 DEG/0 DEG/45 DEG, the yarn bundles are basalt fiber untwisted rovings, the diameter of basalt fiber precursor is 13 mu m, the phenol activating agent is an adhesive RS, and the amine crosslinking agent is hexamethoxymethylmelamine; and then cutting the rolled rubber sheets into strips, uniformly stacking and filling according to a sieve plate mold, carrying out compression molding, vulcanization and post curing on 2 layers of fabrics, wherein the sieve holes have the size of 12mm multiplied by 12mm and the external dimension of 2000mm multiplied by 1200mm multiplied by 20mm, and thus obtaining the corrosion-resistant rubber mould pressing sieve plate.
Wherein the tensile strength of the product sizing material is 42.27MPa, the hardness is 82.6 Shore A, and the elongation is 281.5%; the tensile strength retention rate of 144h at 70 ℃ of 36.5% hydrochloric acid with soaking corrosivity is 85.8%, the volume expansion rate is 3.2%, the tensile strength retention rate of 365d at 35 ℃ of 36.5% hydrochloric acid is 73.6%, the volume expansion rate is 4.4%, the tensile strength retention rate of 144h of sodium hydroxide with mass fraction of 45% is 77.5%, the volume expansion rate is 2.0%, the abrasion loss of Taber (Taber) is 0.102g (100g, H-22, 1000 turns).
Example 2
Wherein, viton A402C of fluororubber, DZXB-WFPM600 Dan Jin of basalt textile, fluorinated graphene with 60 percent of fluorine content, the grain diameter of D5060 mu m and the average lamella thickness of 10nm, and microlite ink powder WT92-75.
Firstly, mixing and mixing a fluororubber mixture, namely weighing 99phr of fluororubber, 1phr of an accelerator CZ, 14.8phr of microlite ink powder and 0.98phr of graphene fluoride in sequence, adding B-m bisphenol A benzoxazine resin AIBZ321 into the fluororubber mixture in an open milling process, and milling after the open milling is finished, wherein the mixing process comprises the steps of enabling the speed ratio of a square rotor to be 1: 1.18, enabling the rotation speed to be 80rpm, enabling the unit pressure of a top bolt to the materials to be 0.45MPa, enabling the filling coefficient to be 0.80 and enabling the mixing time to be 15min, enabling the fluororubber, the graphene fluoride, the microcrystalline graphite powder and the accelerator to be added in a feeding sequence after the mixing is uniform, enabling benzoxazine with the mass of 30% of the fluororubber to be added in a front roller rotation speed of 28.5rpm, enabling the front-back roller speed ratio to be 1.28, enabling the steam pressure to be 0.5MPa, enabling a roller gap to be 3mm, a front roller 55 ℃, enabling the rear roller to be 50 ℃ and thin pass to be carried out for 10 times, enabling the open milling time to be 15min, and cooling to be 30 ℃ to obtain a premix; secondly, the back-smelting process comprises the steps of rotating the front roller at 28.5rpm, enabling the speed ratio of the front roller to the back roller to be 1.28, enabling the steam pressure to be 0.5MPa, enabling the roller gap to be 2mm, enabling the front roller to be 60 ℃, enabling the back roller to be 55 ℃ and thin-pass for 12 times, blanking and cooling, vulcanizing a flat plate at the temperature of 160 ℃ for 60min under the pressure of 20MPa, enabling the back-curing process to be 16h under the temperature of 205 ℃ in an oven, back-smelting the rubber-plastic pre-mixture, extruding and rolling the rubber-plastic pre-mixture into sheets on two sides, adding hexamethylenediamine carbonate with the mass being 1% of that of the vulcanizing agent-fluororubber in the back-smelting process, pressing the hexamethylenediamine carbonate into a screw of an extruder through a pressing device, continuously conveying the materials forwards through the screw, filtering the materials through a machine head to remove impurities, extruding the sheet-shaped materials, and conveying the sheet-shaped materials into a calender through a conveying belt. In order to prevent the surface of the roller from being damaged by metal mixed into the material, the metal detector detects the metal before the metal enters the calender, wherein the screw diameter of the extruder is 250mm, the length-diameter ratio L/D is 6: 1, the compression ratio is 2, the temperature of a machine barrel is 60 ℃, the temperature of a machine neck is 60 ℃, the temperature of a machine head is 60 ℃, and the calendering pressure is 3MPa. Pressing the lower delay roller by 50 ℃, controlling the temperature of the middle roller at 60 ℃, controlling the temperature of the upper roller at 80 ℃ to obtain a rolled rubber sheet, wherein the rolled base cloth is basalt base cloth, the basalt base cloth is a quadriaxial warp-knitted basalt fabric impregnated by a mixture of a phenolic activator and an amine cross-linking agent in a mass ratio of 1:1.15, the impregnation content is 10%, the layering structure of yarn bundles is 90 °/45 °/0 °/45 °, the yarn bundles are basalt fiber untwisted rovings, the diameter of basalt fiber precursor is 9 μm, the phenolic activator is an adhesive RE, and the amine cross-linking agent is an adhesive H-80; thirdly, cutting the rolled rubber sheets into strips, uniformly stacking and filling the strips according to a sieve plate mold, then carrying out compression molding, vulcanization and post curing on 2 layers of fabrics, wherein the sieve holes have the size of 12mm multiplied by 12mm and the external dimension of 2000mm multiplied by 1200mm multiplied by 20mm, and thus obtaining the corrosion-resistant rubber mould pressing sieve plate.
Wherein the tensile strength of the product rubber is 45.63MPa, the hardness is 86.3 Shore A, and the elongation is 273.4%; the tensile strength retention rate of 144h at 70 ℃ of 36.5% hydrochloric acid with soaking corrosivity is 85.6%, the volume expansion rate is 3.3%, the tensile strength retention rate of 365d at 35 ℃ of 36.5% hydrochloric acid is 73.8%, the volume expansion rate is 4.5%, the tensile strength retention rate of 144h of sodium hydroxide with mass fraction of 45% is 77.6%, the volume expansion rate is 1.9%, the abrasion loss of Taber (Taber) is 0.101g (100g, H-22, 1000 turns).
Secondly, the screen needs to have certain mechanical strength to be used as the screen, and the orthogonal experiment L is designed 9 （3 4 ) Analyzing the rubber strength difference under the influence of different factors to find a sieve plate proportion with better strength and good corrosion resistance, wherein the fluororubber accounts for the most, so the factor A is the fluororubber, and the corresponding levels are 10 parts, 11 parts and 12 parts in sequence; the factor B is benzoxazine, and the corresponding levels are 1 part, 2 parts and 3 parts in sequence; the factor C is microcrystalline graphite powder, and the corresponding levels are 0.5 part, 1 part and 1.5 parts in sequence; the factor D is fluorinated graphene, and the factor D is respectively 0.1 part, 0.15 part and 0.2 part correspondingly; prepared according to the process of example 2, except that the corrosion-resistant screen deck sizing composition ratios were different, the results are shown in table 1.
Table 1 results of orthogonal test performance test of corrosion-resistant screen plate compound according to the method of reference example 2
| Serial number | Fluororubber | Benzoxazines | Microcrystalline graphite powder | Fluorinated graphene | Tensile strength MPa |
| 1 | 10 | 1 | 0.5 | 0.1 | 38.86 |
| 2 | 10 | 1 | 0.5 | 0.1 | 36.37 |
| 3 | 10 | 1 | 0.5 | 0.1 | 43.02 |
| 4 | 11 | 2 | 1 | 0.15 | 34.72 |
| 5 | 11 | 2 | 1 | 0.15 | 37.06 |
| 6 | 11 | 2 | 1 | 0.15 | 38.49 |
| 7 | 12 | 3 | 1.5 | 0.2 | 36.39 |
| 8 | 12 | 3 | 1.5 | 0.2 | 33.04 |
| 9 | 12 | 3 | 1.5 | 0.2 | 44.12 |
| K 1 | 118.257 | 109.978 | 110.391 | 120.048 | - |
| K 2 | 110.277 | 106.471 | 115.216 | 111.255 | - |
| K 3 | 113.551 | 125.636 | 116.478 | 110.781 | - |
| k 1 | 39.419 | 36.659 | 36.797 | 40.016 | - |
| k 2 | 36.759 | 35.490 | 38.405 | 37.085 | - |
| k 3 | 37.850 | 41.879 | 38.826 | 36.927 | - |
| R | 2.660 | 5.219 | 0.421 | 0.158 | - |
As can be seen, B > A > D > C, preferably formula A 1 B 3 C 3 D 1 The proportion of the fluororubber mixed and mixed rubber material in the third step of the example 2 is similar to that of the fluororubber mixed and mixed rubber material in the third step of the example 2, and the tensile strength of the fluororubber mixed and mixed rubber material in the example 2 is 45.63MPa, so that the strength requirement of a polyurethane sieve plate can be met.
Note: and the rubber performance requirement in the GB/T33091-2016 polyurethane sieve plate is referred to for detection.
Claims (6)
1. The production method of the corrosion-resistant rubber molded sieve plate is characterized by comprising the following steps of: firstly, adding benzoxazine into a fluororubber mixed sizing material in an open mixing process, and mixing after the open mixing is finished to obtain a rubber-plastic premix; secondly, back-smelting the rubber-plastic pre-mixture, extruding and rolling the two sides of the rubber-plastic pre-mixture into sheets, and adding a vulcanizing agent in the back-smelting process to obtain rolled rubber sheets, wherein the rolled base cloth is basalt base cloth; and thirdly, cutting the rolled rubber sheets into strips, uniformly stacking and filling according to the sieve plate mold, and then carrying out compression molding, vulcanization and post curing to obtain the corrosion-resistant rubber molded sieve plate.
2. The method for producing a corrosion-resistant rubber molded screen deck according to claim 1, wherein the step-benzoxazine is B-m bisphenol a benzoxazine resin.
3. The production method of the corrosion-resistant rubber molded sieve plate according to claim 1, wherein the fluororubber mixed and mixed rubber material in the first step is obtained by sequentially weighing 88 to 99phr of fluororubber, 0.5 to 1phr of accelerator, 13.5 to 14.8phr of microlite ink powder and 0.7 to 0.98phr of graphene fluoride in parts by weight, and the accelerator is one of accelerator DZ and accelerator CZ.
4. The production method of the corrosion-resistant rubber molded sieve plate according to claim 1, wherein the mixing process in the first step is that the speed ratio of a square rotor is 1:1.15 to 1: 1.18, the rotating speed is 40 to 80rpm, the unit pressure of a top plug to a material is 0.2 to 0.45MPa, the filling coefficient is 0.55 to 0.80, and the banburying time is 10 to 15min, the open mixing process comprises the steps of feeding the fluororubber, the fluorinated graphene, the microcrystalline graphite powder and the accelerator in sequence, adding benzoxazine with the mass of the fluororubber being 25 to 30% after the mixing is uniformly, feeding the benzoxazine at the rotating speed of a front roller being 27.5 to 28.5rpm and the roller speed ratio of 1.15 to 1.28, the steam pressure being 0.4 to 0.5MPa, the roller gap being 2 to 3mm, feeding the front roller being 50 to 55 ℃, feeding the rear roller being 45 to 50 ℃, and carrying out the thin-pass process for 8 to 10 to 15min, and cooling.
5. The production method of the corrosion-resistant rubber molded sieve plate according to claim 1, wherein the basalt base cloth in the second step is a quadriaxial warp-knitted basalt fabric impregnated with a mixture of a phenolic activator and an amine cross-linking agent in a mass ratio of 1:1.15, wherein the impregnation content is 8 to 10 percent, the layer structure of yarn bundles is 90 °/45 °/0 °/45 °, the yarn bundles are basalt fiber untwisted rovings, the diameter of the basalt fiber precursor is 9 to 13 μm, the phenolic activator is one or more of a binder RS or a binder RE, and the amine cross-linking agent is one or more of hexamethoxymethylmelamine or a binder H-80.
6. The production method of the corrosion-resistant rubber molded sieve plate according to claim 1, wherein a remixing process in the second step is that the rotation speed of a front roller is 27.5 to 28.5rpm, the ratio of the front roller speed to the rear roller speed is 1.15 to 1.28, the steam pressure is 0.4 to 0.5MPa, the roller gap is 1 to 2mm, the front roller is 55 to 60 ℃, the rear roller is 50 to 55 ℃, the mixture is thinly communicated for 10 to 12 times, the mixture is fed and cooled, a vulcanization process is that plate vulcanization is carried out under the pressure of 15 to 20MPa and the temperature is 150 to 160 ℃ and the temperature is 50 to 60min, an after-curing process in the third step is that the mixture is carried out in an oven under the temperature of 180 to 205 ℃ for 12 to 169h, and the vulcanizing agent is one of N, N-cinnamoyl-1,6-hexanediamine or hexanediamine carbonate with the mass of 0.5 to 1 percent of fluororubber.
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