CN1442193A - Method of continuously producing eucommia extract powder, gutta percha, eucommia resin and organic fertilizer using eucommia leaf - Google Patents
Method of continuously producing eucommia extract powder, gutta percha, eucommia resin and organic fertilizer using eucommia leaf Download PDFInfo
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- 238000000034 method Methods 0.000 title claims abstract description 36
- 239000000843 powder Substances 0.000 title claims abstract description 14
- 239000011347 resin Substances 0.000 title claims abstract description 11
- 229920005989 resin Polymers 0.000 title claims abstract description 11
- 239000000899 Gutta-Percha Substances 0.000 title claims description 30
- 229920000588 gutta-percha Polymers 0.000 title claims description 30
- 240000000342 Palaquium gutta Species 0.000 title claims description 29
- 241000208688 Eucommia Species 0.000 title abstract description 9
- 239000003895 organic fertilizer Substances 0.000 title abstract 2
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 63
- 239000002904 solvent Substances 0.000 claims description 48
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 39
- 239000000463 material Substances 0.000 claims description 32
- 239000003292 glue Substances 0.000 claims description 24
- 238000004519 manufacturing process Methods 0.000 claims description 22
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 21
- 230000003442 weekly effect Effects 0.000 claims description 15
- 239000002893 slag Substances 0.000 claims description 13
- 239000007787 solid Substances 0.000 claims description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
- 238000000855 fermentation Methods 0.000 claims description 11
- 230000004151 fermentation Effects 0.000 claims description 11
- 241000208689 Eucommia ulmoides Species 0.000 claims description 10
- 239000008367 deionised water Substances 0.000 claims description 10
- 229910021641 deionized water Inorganic materials 0.000 claims description 10
- 238000000605 extraction Methods 0.000 claims description 10
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 9
- 239000003337 fertilizer Substances 0.000 claims description 9
- 239000008187 granular material Substances 0.000 claims description 9
- 239000002699 waste material Substances 0.000 claims description 9
- 241000894006 Bacteria Species 0.000 claims description 8
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 6
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims description 6
- 238000000638 solvent extraction Methods 0.000 claims description 6
- 238000010924 continuous production Methods 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 5
- 238000002386 leaching Methods 0.000 claims description 5
- 238000012216 screening Methods 0.000 claims description 5
- 239000004575 stone Substances 0.000 claims description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 4
- 239000012141 concentrate Substances 0.000 claims description 4
- 238000001125 extrusion Methods 0.000 claims description 4
- 230000018984 mastication Effects 0.000 claims description 4
- 238000010077 mastication Methods 0.000 claims description 4
- 238000001556 precipitation Methods 0.000 claims description 4
- 238000011084 recovery Methods 0.000 claims description 4
- 238000005469 granulation Methods 0.000 claims description 2
- 230000003179 granulation Effects 0.000 claims description 2
- 239000003208 petroleum Substances 0.000 claims description 2
- 230000001105 regulatory effect Effects 0.000 claims description 2
- 238000003756 stirring Methods 0.000 claims description 2
- 238000003912 environmental pollution Methods 0.000 abstract 1
- 238000007599 discharging Methods 0.000 description 10
- 238000010960 commercial process Methods 0.000 description 7
- 238000011161 development Methods 0.000 description 6
- 238000012545 processing Methods 0.000 description 5
- 238000010298 pulverizing process Methods 0.000 description 4
- 229920001971 elastomer Polymers 0.000 description 3
- 238000009835 boiling Methods 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000003203 everyday effect Effects 0.000 description 2
- 238000011081 inoculation Methods 0.000 description 2
- 238000011031 large-scale manufacturing process Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 239000012254 powdered material Substances 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 1
- 238000010923 batch production Methods 0.000 description 1
- 238000010009 beating Methods 0.000 description 1
- 210000004027 cell Anatomy 0.000 description 1
- 210000002421 cell wall Anatomy 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 238000010025 steaming Methods 0.000 description 1
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/40—Bio-organic fraction processing; Production of fertilisers from the organic fraction of waste or refuse
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Abstract
A process for continuously preparing eucommia extract powder, eucommia gum, eucommia resin and organic fertilizer from eucommia leaf is disclosed. Its avdantages are short technological flow path, low cost and no environmental pollution.
Description
Technical field
The present invention relates to a kind of method of comprehensive utilization of Folium Eucommiae, relate in particular to a kind of production method with Folium Eucommiae continuous production eucommia ulmoides extract powder, gutta-percha, Cortex Eucommiae resin and fertilizer.
Background technology
The Cortex Eucommiae is the rare protective plant of Chinese distinctive secondary, is the famous and precious medicine in the Chinese traditional medicine.Simultaneously, be rich in a kind of novel high polymer material-gutta-percha in Folium Eucommiae, skin and the fruit with the double character of rubber plastic.Since nineteen fifties, because the cultivating and growing climax of the Cortex Eucommiae several times, the cultivating eucommia area of China has reached more than 400 ten thousand mu at present.Since the 1980s, the research and development of gutta-percha have been obtained important breakthrough, these just make the development and use of Folium Eucommiae becomes focus several years ago.Simultaneously, a collection of patent by extraction gutta-percha method in the Folium Eucommiae is declared successively, and granted.Chinese patent gets notification number " 1003069 ", denomination of invention " is extracted the method for gutta-percha " by Folium Eucommiae or skin in, there is following problem: because gel content is extremely low in the Folium Eucommiae, generally has only 2-5%, adopting the method for " fermentation or steaming and decocting destroy its cell wall " is unfavorable in suitability for industrialized production, because the treating capacity of material is too big like this, production cost can be very high.The gutta-percha that this method is produced is because the price height is can not become commodity to be accepted by market.And the method for " smashing its tissue with high speed waterpower beating crusher tool, to dissociate Folium glue wire " can strengthen the loss of Folium glue wire in follow-up separation circuit, reduces the extraction efficiency of gutta-percha.Increased the production cost of gutta-percha equally again.Chinese patent gets notification number " 1356153 ", and denomination of invention " a kind of gutta-percha and Folium Eucommiae leach the preparation method of powder ", this method are the substep batch process.Have following problem as carrying out suitability for industrialized production by this method: one, because the capacity of Folium Eucommiae is 100-150kg/m
3, directly " with the Folium Eucommiae extractor of packing into " can limit the charge weight of every batch materials, greatly because the capacity of extractor is limited.Like this, limit inventory and just limited output, do not had the product of output also just can not form market.Its two, " under normal pressure, temperature is 10 ℃-70 ℃ to be extracted 60-180 minute with the ethanol of 20 °-80 ° of concentration or methanol or ethyl acetate, and isolated by filtration gets extracting solution and leaf slag; " at this time separating the leaf slag obtain, oneself could " with benzene or toluene under normal pressure " extract after contain considerable moisture, must carrying out drying.This certainly will increase energy consumption, strengthens cost.Because gel content generally has only 2-5% in the Folium Eucommiae, the increase of dried leaves slag cost can strengthen the production cost of gutta-percha greatly, and too high production cost can come into the market as commodity by the restriction gutta-percha.Simultaneously, increase the up-front investment that drying equipment also can add large project.They are three years old, " the leaf slag with benzene or toluene under normal pressure; temperature is 20 ℃-100 ℃ and extracted 60-180 minute ", because the boiling range of benzene (primes) is 79.6 ℃-80.5 ℃, the boiling range of toluene is 109.8 ℃-111 ℃, in " temperature is 20 ℃-100 ℃ and extracted 60-180 minute ", the consumption that can strengthen benzene or toluene.Owing to be to produce at " under the normal pressure ", the hidden danger that benzene that leaks in slave unit, pipeline and the valve or toluene steam can cause operator's health and production safety can not be ignored simultaneously.In sum, because these patented technologies all do not have to solve the commercial production problem of Folium Eucommiae comprehensive exploitation and serialization, scale, cost is too high, and lays aside and neglects.Cause the problems such as industrialization, the industrialization of Folium Eucommiae comprehensive development and utilization of producing gutta-percha with Folium Eucommiae, unresolved always.Thereby also greatly restricted the development of this industry.Therefore, in recent years, the comprehensive development and utilization of Folium Eucommiae stagnates.More than 100 ten thousand tons of Folium Eucommiaes that more than the 400 ten thousand mu of Cortex Eucommiae woodss in the whole nation are grown just rot in vain on the ground.The annual resource that can create tens billion of output values just has been lost in vain.Even more serious is that the regional Cortex Eucommiae plantation family that has is chopping at a tree owing to lose benefit.
Summary of the invention
The object of the present invention is to provide that a kind of up-front investment is few, technological process is short, production cost is low, do not have the production method that " three wastes " pollute with Folium Eucommiae continuous production eucommia ulmoides extract powder, gutta-percha, Cortex Eucommiae resin and fertilizer.
Production method of the present invention comprises the steps:
(1) with Folium Eucommiae, after past stone, deironing are handled, enter pulverizer, handle through screening then, obtain netted material and granular material;
(2) netted material leaches continuously with the B solvent, leachate obtains the thick glue of the Cortex Eucommiae after concentrating recovery B solvent, after crushed, leach continuously with the C solvent, obtain the smart glue of the solid content Cortex Eucommiae, after mastication, granulation, obtained the commodity gutta-percha, C solvent extraction liquid is after concentrating recovery C solvent, and extrusion modling obtains Cortex Eucommiae resin; This step adopts micro-negative pressure operation, operating pressure to be controlled at 0.03-0.05MPa for well;
(3) the solid content slag leaf that obtains after the B solvent leaches continuously of netted material is after carrying out precipitation treatment reclaims the B solvent, after granular material that screening is come out mixes, leach continuously with the A solvent, A solvent extraction liquid through concentrate reclaimed the A solvent after, carry out drying, pulverize and obtain the eucommia ulmoides extract powder;
(4) waste residue that obtains after the A solvent leaches is continuously regulated moisture to 40--55% through stirring, inoculate active bacterium after, ferment, fermentation temperature is controlled at 40--65 ℃, fermentation time is 5-7 days, pulverizes then, granulating obtains Cortex Eucommiae fertilizer.
Method of the present invention, wherein the A solvent can be selected ethanol or the methanol of deionized water, 60%--70% for use, extraction temperature is controlled at 40 ℃-80 ℃, leach and adopt loop type extractor or flat rotary extractor, the rotating speed of flat rotary extractor was controlled at revolution 90-175 minute, be preferably at revolution 100-130 minute, loop type extractor weekly the duration of runs be 50--160 minute, be preferably and turning round weekly 130-160 minute.
Method of the present invention, wherein the B solvent can be selected petroleum ether, benzene or toluene for use, extraction temperature is controlled at 45 ℃-75 ℃, leach and adopt loop type extractor or flat rotary extractor, the rotating speed of flat rotary extractor was controlled at revolution 90-175 minute, be preferably at revolution 100-130 minute, loop type extractor weekly the duration of runs be 50--160 minute, be preferably and turning round weekly 130-160 minute.
Method of the present invention, wherein the C solvent can be selected acetone, ethyl acetate or hexane for use, and extraction temperature is controlled at 45 ℃-75 ℃, leaches and adopts loop type extractor or flat rotary extractor, the rotating speed of flat rotary extractor was controlled at revolution 90-175 minute, was preferably at revolution 100-130 minute.Loop type extractor weekly the duration of runs be 50--160 minute, be preferably and turning round weekly 130-160 minute.
Method of the present invention, the liquid-solid ratio scope of solvent and material is 0.5-1.5 in wherein leaching: 1, be preferably 0.8-1: 1.
Method of the present invention, wherein Jie Zhong active bacterium is FU series zymocyte and nitrogen-fixating and P and K decomposing functions bacterium.
In the production method of the present invention, directly " with Folium Eucommiae, after past stone, deironing are handled, enter pulverizer, handle through screening then, obtain netted material and granular material; " be because: one, Folium Eucommiae is pulverized after the unit rubbing pulverizes by the Folium Eucommiae of special use, Folium glue wire very thin in the Folium Eucommiae is reticulated group by rubbing, the mesophyll of no glue partly is ground into the powdered material.Help the enrichment of Folium glue wire like this, reduce the loss of Folium glue wire in subsequent handling.Simultaneously, owing to pulverize the cell tissue of having destroyed gutta-percha, help the extraction separation of gutta-percha in subsequent handling.These all can improve the extraction efficiency of gutta-percha.Its two because the netted material that contains glue and powdered material separating before abstraction process, just reduced the treating capacity of material, make the B solvent load that is used to extract gutta-percha significantly reduce, help reducing production costs.The day processing Folium Eucommiae amount that the Folium Eucommiae of developing among the present invention is pulverized unit separate unit (cover) equipment can reach more than 50 tons, can guarantee industrialized large-scale production fully.
Because the leaching system that adopts continuous infusers such as " flat rotary extractor or loop type extractors " and vertical desolventizing machine to form, make material from feeding intake, just " enter the commercial process of automatic continuous feed, leaching continuously, continuous draining, continuous discharging slag." maximum day output can reach more than 500 tons, thereby make successful implementation of the present invention be guaranteed.Simultaneously, this method is to extract gutta-percha earlier from the netted material of Folium glue wire, then from the leaf slag of discharging, extract the eucommia ulmoides extract powder again, thereby must not carry out drying to the leaf slag in process of production, greatly reduce the production cost of gutta-percha, reduce the up-front investment of project, improved the competitiveness of product in market.Because second step of this method is adopted negative pressure system, adds recycling step, make the consumption of B solvent and C solvent all less than 5/1000ths.
As from the foregoing; the present invention compares with other production method; have following remarkable result: the present invention is by the comprehensive development and utilization to Folium Eucommiae; successfully solved industrial problems with Folium Eucommiae industrialization continuous production eucommia ulmoides extract powder, gutta-percha, Cortex Eucommiae resin and fertilizer; and do not have " three wastes " in the technological process of production substantially and produce, realized the utilization to resource, cost control and the serialization and the large-scale production of product.Therefore, the present invention has that up-front investment is few, technological process is short, production cost is low, there are not characteristics such as " three wastes " pollution, because the present invention has successfully carried out comprehensive development and utilization to Folium Eucommiae, greatly reduce the production cost of core product gutta-percha, improved the market competitiveness of gutta-percha, make gutta-percha be able to really come into the market as a kind of virgin rubber kind of general purpose rubber, simultaneously, for bringing new opportunity to develop in numerous Cortex Eucommiae forest farm, the whole nation, Cortex Eucommiae crop cultivation speciality family, in China, construction of the West Region brings ecological benefits, economic benefit and social benefit.
Description of drawings
Accompanying drawing is a process chart of the present invention.
The specific embodiment
Embodiment 1:
(1) 50 ton of gel content is that 3% Folium Eucommiae is continuously by conveyer, after past stone, deironing are handled, by its top feed mouth input high speed disintegrator.Very thin Folium glue wire is crumpled into the netted material group that 150 grams-300 gram weight do not wait, and the mesophyll that does not have glue partly is ground into fine powder not, passes through the processing of shaking screen again, obtains about 23 tons of netted material, about 27 tons of granular material.
(2) 23 tons of separated netted materials drop into loop type extractor with per hour about 1.15 tons speed through the material stock jar by conveyer, turned round weekly 130-160 minute, and entered automatic continuous feed, leach, discharge continuously the toluene solvant leachate continuously, discharge the commercial process of slag leaf continuously with toluene solvant.The liquid-solid ratio of toluene solvant and material 0.8: 1.The toluene solvant leachate of discharging continues to enter follow-up concentrating continuously, has reclaimed toluene solvant and has obtained about 1.97 tons of the thick glue of the Cortex Eucommiae.The thick glue of the Cortex Eucommiae after the pulverization process drops into loop type extractor through the material stock jar again, turned round weekly 130-160 minute, and entered automatic continuous feed once more, leach, discharge continuously the ethyl acetate solvent leachate continuously, discharge the commercial process of the smart glue of the Cortex Eucommiae continuously with ethyl acetate solvent.The liquid-solid ratio of ethyl acetate solvent and material 0.8: 1.The smart glue of the Cortex Eucommiae through after follow-up mastication, the molding procedure processing, has obtained about 1.35 tons of commodity gutta-percha again.The continuous ethyl acetate solvent leachate of discharging, through concentrated reclaimed ethyl acetate solvent after, extrusion modling obtains about 0.62 ton of Cortex Eucommiae resin.This step is adopted micro-negative pressure operation, and operating pressure is controlled at 0.03-0.05MPa;
(3) netted material continuous solid content slag leaf of discharging after toluene solvant leaches continuously, after carrying out precipitation treatment reclaims toluene solvant, mix by the granular material that conveyer is sent to step 1 obtains, send into flat rotary extractor by conveyer with per hour about 2.3 tons speed again, rotating speed was controlled at revolution 100-130 minute.Enter automatic continuous feed, leach, discharge continuously ionized water solvent extraction liquid continuously, discharge the commercial process of waste residue continuously with deionized water solvent.The continuous deionized water solvent leachate of discharging, through concentrate reclaimed deionized water solvent after, dry, pulverizing obtains about 5.6 tons of eucommia ulmoides extract powder.
(4) waste residue 55 tons (containing moisture about 30%) that leaches discharge continuously through deionized water solvent is sent into blender successively through conveying machinery, in blender, regulate moisture to 40--55%, inoculation FU series zymocyte and nitrogen-fixating and P and K decomposing functions bacterium, carry again and remove fermentation tower, fermentation temperature is controlled at 40--65 ℃, and fermentation time is 6 days.Can produce fertilizer every day and be about 55 tons.
Embodiment 2:
(1) 100 ton of gel content is that 3% Folium Eucommiae is continuously by conveyer, after past stone, deironing are handled, by its top feed mouth input high speed disintegrator.Very thin Folium glue wire is crumpled into the netted material group that 150 grams-300 gram weight do not wait, and the mesophyll that does not have glue partly is ground into thin powdered, passes through the processing of shaking screen again, obtains about 46 tons of netted material, about 54 tons of granular material.
(2) 46 tons of separated netted materials drop into flat rotary extractor with per hour about 2.3 tons speed through the material stock jar by conveyer, rotating speed was controlled at revolution 100-130 minute, entered automatic continuous feed, leached, discharges continuously the toluene solvant leachate continuously, discharges the commercial process of slag leaf continuously with toluene solvant.The liquid-solid ratio of toluene solvant and material 0.8: 1.The toluene solvant leachate of discharging continues to enter follow-up concentrating continuously, has reclaimed toluene solvant and has obtained about 3.94 tons of the thick glue of the Cortex Eucommiae.The thick glue of the Cortex Eucommiae after the pulverization process drops into flat rotary extractor through the material stock jar again, rotating speed was controlled at revolution 100-130 minute, entered automatic continuous feed once more, leached, discharges continuously the ethyl acetate solvent leachate continuously, discharges the commercial process of the smart glue of the Cortex Eucommiae continuously with ethyl acetate solvent.The liquid-solid ratio of ethyl acetate solvent and material 0.8: 1.The smart glue of the Cortex Eucommiae through after follow-up mastication, the molding procedure processing, has obtained about 2.7 tons of commodity gutta-percha again.The continuous ethyl acetate solvent leachate of discharging, through concentrated reclaimed ethyl acetate solvent after, extrusion modling obtains about 1.24 tons of Cortex Eucommiae resin.This step is adopted micro-negative pressure operation, and operating pressure is controlled at 0.03-0.05MPa;
(3) netted material continuous solid content slag leaf of discharging after toluene solvant leaches continuously, after carrying out precipitation treatment reclaims toluene solvant, mix by the granular material that conveyer is sent to step 1 obtains, send into loop type extractor by conveyer with per hour about 4.6 tons speed again, turned round weekly 130-160 minute.Enter automatic continuous feed, leach, discharge continuously ionized water solvent extraction liquid continuously, discharge the commercial process of waste residue continuously with deionized water solvent.The continuous deionized water solvent leachate of discharging, through concentrate reclaimed deionized water solvent after, dry, pulverizing obtains about 11.2 tons of eucommia ulmoides extract powder.
(4) waste residue 110 tons (containing moisture about 30%) that leaches discharge continuously through deionized water solvent is sent into blender successively through conveying machinery, in blender, regulate moisture to 40--55%, inoculation FU series zymocyte and nitrogen-fixating and P and K decomposing functions bacterium, carry again and remove fermentation tower, fermentation temperature is controlled at 40--65 ℃, and fermentation time is 6 days.Can produce fertilizer every day and be about 110 tons.
Claims (10)
1, a kind of production method with Folium Eucommiae continuous production eucommia ulmoides extract powder, gutta-percha, Cortex Eucommiae resin and fertilizer comprises the steps:
(1) with Folium Eucommiae, after past stone, deironing are handled, enter pulverizer, handle through screening then, obtain netted material and granular material;
(2) netted material leaches continuously with the B solvent, leachate obtains the thick glue of the Cortex Eucommiae after concentrating recovery B solvent, after crushed, leach continuously with the C solvent, obtain the smart glue of the solid content Cortex Eucommiae, after mastication, granulation, obtained the commodity gutta-percha, C solvent extraction liquid is after concentrating recovery C solvent, and extrusion modling obtains Cortex Eucommiae resin; This step adopts micro-negative pressure operation, operating pressure to be controlled at 0.03-0.05MPa for well;
(3) the solid content slag leaf that obtains after the B solvent leaches continuously of netted material is after carrying out precipitation treatment reclaims the B solvent, after granular material that screening is come out mixes, leach continuously with the A solvent, A solvent extraction liquid through concentrate reclaimed the A solvent after, carry out drying, pulverize and obtain the eucommia ulmoides extract powder;
(4) waste residue that obtains after the A solvent leaches is continuously regulated moisture to 40--55% through stirring, inoculate active bacterium after, ferment, fermentation temperature is controlled at 40--65 ℃, fermentation time is 5-7 days, pulverizes then, granulating obtains Cortex Eucommiae fertilizer.
2, the method for claim 1, wherein the A solvent is selected ethanol or the methanol of deionized water, 60%--70% for use, extraction temperature is controlled at 40 ℃-80 ℃, leach and adopt loop type extractor or flat rotary extractor, the rotating speed of flat rotary extractor was controlled at revolution 90-175 minute, loop type extractor weekly the duration of runs be 50--160 minute.
3, method as claimed in claim 2, wherein the rotating speed of flat rotary extractor was controlled at revolution 100-130 minute, and loop type extractor is controlled at and turns round 130-160 minute weekly.
4, the method for claim 1, wherein the B solvent is selected petroleum ether, benzene or toluene for use, extraction temperature is controlled at 45 ℃-75 ℃, leach and adopt loop type extractor or flat rotary extractor, the rotating speed of flat rotary extractor, be controlled at revolution 90-175 minute, loop type extractor weekly the duration of runs be 50--160 minute.
5, method as claimed in claim 3, wherein the rotating speed of flat rotary extractor was controlled at revolution 100-130 minute, and loop type extractor is controlled at and turns round 130-160 minute weekly.
6, the method for claim 1, wherein the C solvent is selected acetone, ethyl acetate or hexane for use, extraction temperature is controlled at 45 ℃-75 ℃, leach and adopt loop type extractor or flat rotary extractor, the rotating speed of flat rotary extractor, be controlled at revolution 90-175 minute, loop type extractor weekly the duration of runs be 50--160 minute.
7, method as claimed in claim 6, wherein the rotating speed of flat rotary extractor was controlled at revolution 100-130 minute, and loop type extractor is controlled at and turns round 130-160 minute weekly.
8, as the described method of claim 1-6, the liquid-solid ratio scope of solvent and material is 0.5-1.5 in wherein leaching: 1.
9, method as claimed in claim 8, the liquid-solid ratio scope of solvent and material is 0.8-1 in wherein leaching: 1.
10, method as claimed in claim 9, wherein Jie Zhong active bacterium is FU series zymocyte and nitrogen-fixating and P and K decomposing functions bacterium.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB03117678XA CN1183955C (en) | 2003-04-09 | 2003-04-09 | Method of continuously producing eucommia extract powder, gutta percha, eucommia resin and organic fertilizer using eucommia leaf |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB03117678XA CN1183955C (en) | 2003-04-09 | 2003-04-09 | Method of continuously producing eucommia extract powder, gutta percha, eucommia resin and organic fertilizer using eucommia leaf |
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| CN1442193A true CN1442193A (en) | 2003-09-17 |
| CN1183955C CN1183955C (en) | 2005-01-12 |
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| CNB03117678XA Expired - Fee Related CN1183955C (en) | 2003-04-09 | 2003-04-09 | Method of continuously producing eucommia extract powder, gutta percha, eucommia resin and organic fertilizer using eucommia leaf |
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Cited By (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100457846C (en) * | 2006-11-08 | 2009-02-04 | 贵州大学 | Method of extracting gutta percha by solvent circulation |
| CN101906176A (en) * | 2010-07-06 | 2010-12-08 | 刘志成 | Method for continuously generating fine gutta-percha through digestion-reextraction |
| CN101900912B (en) * | 2004-08-03 | 2012-05-23 | 芝浦机械电子株式会社 | Apparatus for bonding substrates |
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