CN1733445A - Production method of two-color artificial marble - Google Patents
Production method of two-color artificial marble Download PDFInfo
- Publication number
- CN1733445A CN1733445A CN 200510035524 CN200510035524A CN1733445A CN 1733445 A CN1733445 A CN 1733445A CN 200510035524 CN200510035524 CN 200510035524 CN 200510035524 A CN200510035524 A CN 200510035524A CN 1733445 A CN1733445 A CN 1733445A
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- artificial marble
- production method
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- component
- material compound
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- 239000002928 artificial marble Substances 0.000 title claims abstract description 25
- 238000004519 manufacturing process Methods 0.000 title claims description 21
- 239000000463 material Substances 0.000 claims abstract description 17
- 238000000034 method Methods 0.000 claims abstract description 15
- 239000003086 colorant Substances 0.000 claims abstract description 13
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 12
- 229920005989 resin Polymers 0.000 claims abstract description 12
- 239000011347 resin Substances 0.000 claims abstract description 12
- 238000004512 die casting Methods 0.000 claims abstract description 10
- 239000000945 filler Substances 0.000 claims abstract description 7
- 238000004040 coloring Methods 0.000 claims abstract description 6
- 150000001875 compounds Chemical class 0.000 claims description 13
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 9
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 6
- 239000000654 additive Substances 0.000 claims description 6
- 230000000996 additive effect Effects 0.000 claims description 6
- 239000003431 cross linking reagent Substances 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- 238000001746 injection moulding Methods 0.000 claims description 5
- 239000011159 matrix material Substances 0.000 claims description 5
- 230000002269 spontaneous effect Effects 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 4
- 238000003756 stirring Methods 0.000 claims description 4
- 239000004575 stone Substances 0.000 claims description 4
- 229920001187 thermosetting polymer Polymers 0.000 claims description 4
- 229920006337 unsaturated polyester resin Polymers 0.000 claims description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 claims description 3
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 3
- 150000001252 acrylic acid derivatives Chemical class 0.000 claims description 3
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 3
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims description 3
- 239000003963 antioxidant agent Substances 0.000 claims description 3
- 230000003078 antioxidant effect Effects 0.000 claims description 3
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 3
- 239000003153 chemical reaction reagent Substances 0.000 claims description 3
- 239000003063 flame retardant Substances 0.000 claims description 3
- 239000003112 inhibitor Substances 0.000 claims description 3
- 239000000395 magnesium oxide Substances 0.000 claims description 3
- 238000000465 moulding Methods 0.000 claims description 3
- -1 perester compound Chemical class 0.000 claims description 3
- 150000002978 peroxides Chemical class 0.000 claims description 3
- 238000005498 polishing Methods 0.000 claims description 3
- 238000006116 polymerization reaction Methods 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 3
- 239000002562 thickening agent Substances 0.000 claims description 3
- 239000006097 ultraviolet radiation absorber Substances 0.000 claims description 3
- 239000002699 waste material Substances 0.000 claims description 3
- 229940126062 Compound A Drugs 0.000 claims description 2
- 239000004150 EU approved colour Substances 0.000 claims description 2
- NLDMNSXOCDLTTB-UHFFFAOYSA-N Heterophylliin A Natural products O1C2COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC2C(OC(=O)C=2C=C(O)C(O)=C(O)C=2)C(O)C1OC(=O)C1=CC(O)=C(O)C(O)=C1 NLDMNSXOCDLTTB-UHFFFAOYSA-N 0.000 claims description 2
- 229940006093 opthalmologic coloring agent diagnostic Drugs 0.000 claims description 2
- 229920003002 synthetic resin Polymers 0.000 claims description 2
- 239000000057 synthetic resin Substances 0.000 claims description 2
- 239000002994 raw material Substances 0.000 abstract description 2
- 239000000470 constituent Substances 0.000 abstract 2
- 238000005520 cutting process Methods 0.000 abstract 1
- 238000007711 solidification Methods 0.000 abstract 1
- 230000008023 solidification Effects 0.000 abstract 1
- 230000014509 gene expression Effects 0.000 description 8
- 239000004579 marble Substances 0.000 description 5
- 238000005266 casting Methods 0.000 description 3
- 239000000049 pigment Substances 0.000 description 2
- 238000010923 batch production Methods 0.000 description 1
- 230000003796 beauty Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
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- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
Abstract
The produce method for two-color artificial marble comprises burdening, mixing, coloring, injecting mould, die casting, solidification, saw cutting and grinding; wherein, dividing the raw material composed of resin, filler, solidifying agent and addition agent into A and B constituents; adding separately basal body and grain colorant to mix; mixing the A and B constituents to inject, die casting and solidify that makes two kinds color material mixed with resin and not single mixed color. The product has grain and natural texture and fits to spread to improve existing device.
Description
Affiliated technical field
The present invention relates to a kind of production method of artificial marble, particularly a kind of production method of two-color artificial marble that has the decorative pattern texture with casting die production.
Background technology
At present, utilize thermosetting resin and metaling to produce artificial marble, the overwhelming majority adopts the casting die of Batch Process.The artificial marble of producing by casting die, all are one color product, the colouring agent that no matter adds (pigment) is one or more different colors, used raw material are after mixing and die casting, the famine material of institute's moulding obtains having only a kind of color, no matter be matrix or texture, all be with a kind of mixed color.Thereby these products can not manifest the native texture texture that " marble " peculiar the sort of cloud and mist curls up, cloud is elegant of the local Yunfu of picture special product.Nature, with regard to outward appearance, monochromatic artificial marble is difficult to compare favourably with natural marble or marble, thus its range of application is restricted.
Chinese invention patent application publication number CN1262645A discloses the international application file that 9980430.8 of application numbers are called " production method with artificial marble of candy strip ".Disclosed method is to adopt the liquid resin injection mould of different colours indoor, through being laminated into two-layer or multilayer, inserts in the middle of each layer with the pectination instrument before it solidifies, and pulls the pectination instrument, makes the colorant diffusion between each layer and infiltrates the formation floral designs.This method has adopted the complicated process units of a cover, particularly on the pectination instrument, designs the comb of various ways.This is higher to the requirement meeting of a whole set of process units after all; And resulting final products may not necessarily reach such texture of natural marble and texture.
Summary of the invention
The objective of the invention is to avoid above-mentioned the deficiencies in the prior art part, and provide a kind of equipment simple, can produce production method of two-color artificial marble with decorative pattern texture.
Purpose of the present invention can reach by following measure:
A kind of production method of two-color artificial marble comprises and will comprise synthetic resin, filler, colouring agent, the curing agent and the additive that comprise initator and crosslinking agent are prepared burden at material compound interior, that produce artificial marble, mix also painted, injection molding, die casting is solidified, and the waste material of obtained by molding is cut saw, polishing waits each operation, it is characterized in that
1. in mixed process, with described material compound is two components, and adopt different colouring agents respectively, mix respectively separately, in vigorous stirring in the agitator more than 15 minutes, wherein, as the deal of a kind of material compound B component of decorative pattern colorant, with ratio as the deal of the another kind of material compound A component of matrix colorant be the B component: A component=(5～10): 100;
2. above-mentioned A component and the B component after mixing respectively is mixed in the blend tank, at the rotating speed below 30 rev/mins, and slight again the stirring mixed 10 seconds～1 minute, or with manual mode mixing, injection molding then.
Above-mentioned material compound can be to comprise that one or more are selected from unsaturated polyester resin, the thermosetting resin of acrylate and methacrylate resin, one or more be selected from aluminium hydroxide, calcium carbonate, silicate, magnesia and marble chips stone and powder filler, one or more are selected from the initator of peroxide and perester compound, with the acrylate compounds as crosslinking agent, and one or more comprise the additive of ultra-violet absorber, fire retardant, releasing agent, fluidizing reagent, thickener, polymerization inhibitor, antioxidant.
Above-mentioned die casting operation is to apply pressure to the pressure of 2.5MPa～4.5MPa on the press on the mold.
The viscosity of above-mentioned material compound is at 1 pool～50 pools.
Above-mentioned curing process can be to place spontaneous curing at normal temperatures or heating 2 hours and solidify under 30 ℃～60 ℃ temperature atmosphere.
Production method of the present invention has following advantage:
1. utilize the existing device of producing monochromatic artificial marble, can produce two-color artificial marble with the decorative pattern texture that can match in excellence or beauty with natural marble.Separate by matrix colorant and decorative pattern colorant and to carry out fully mixedly separately, two kinds of colors just interpenetrate when treating die casting, have avoided two kinds of pigment mixed too early and form single secondary colour.The inventive method is the applicant through producing test and grope out the needs of complete realistic production for up to a hundred times one year over.And production equipment is simple.
2. the good product quality of gained.Have graceful floral designs in appearance, have natural texture on the quality, strength difference and the stress warpage due to reversing does not appear in even structure.
Below in conjunction with drawings and Examples the present invention is done further non-limiting narration.
Description of drawings
Fig. 1 is the technological process of production schematic diagram of the inventive method, wherein the code name of each operation is, mixing of 1 expression batching, 2 expression A components, mixing of 2 ' expression B component, two kinds of parts of 3 expressions are mixed, 4 expression injection moldings, 5 represent that die casting, 6 expressions are solidified, saw is cut in 7 expressions, 8 expressions are polished.
The specific embodiment
With 10 parts of viscosity unsaturated polyester resin that is cp, with 90 parts from 20 order to 80 purpose rubbles, the filler of forming with 100 order to 800 purpose stone flours etc., and 0.5% initator of weight resin and weight resin " 2% crosslinking agent; and according to the additive of corresponding requirements; place in the material-compound tank to mix, obtain the material compound that viscosity is cp.Total amount is divided into two components about 1.2T～2.0T (ton) with it, adds the colouring agent 1 as the matrix colorant in the wherein big component, becomes the A component; Add colouring agent 2 in the little component, become the B component as the decorative pattern colorant.Two components must be distinguished mixing fully, fiercely stir more than 15 minutes, lump together then, are gently mixing 10 seconds～1 minute with the low speed below 30 rev/mins in the mixing tank, or mixed with manual mode, that is are that they are mixed fully.
Above-mentioned mixed material compound is presented to 1.25 * a 2.45 * 0.2m
3Mold in, move on the press with the pressure die casting of 3MPa (MPa) 10 minutes, spontaneous curing then, perhaps heat 2 hours to quicken curing at 30 ℃～60 ℃, obtain the waste material of monoblock, cut saw and polishing more on request, obtain the two-color artificial marble that the inventive method is produced with texture and natural texture and outward appearance.
Claims (8)
1. a production method of two-color artificial marble comprises and will comprise synthetic resin, filler, colouring agent comprises that the curing agent of initator and crosslinking agent and additive prepare burden at the material compound of interior production artificial marble, mix and painted injection molding, die casting, solidify, and the waste material of obtained by molding cut saw, each operation of polishing, and make artificial marble, it is characterized in that
(1) in mixed process, described material compound is divided into two components, and adopt different colouring agents respectively, mix respectively separately, in agitator, stirred 15 minutes, wherein, as the deal of a kind of material compound B component of decorative pattern colorant, with ratio as the deal of the another kind of material compound A component of matrix colorant be the B component: A component=(5～10): 100
(2) above-mentioned A component and the B component after mixing respectively is incorporated in the blend tank, stirs mixed 10 seconds to 1 minute at 30 rev/mins rotating speeds again, or mixes with manual mode, then injection molding.
2. production method of two-color artificial marble according to claim 1 is characterized in that, the pressure that described die casting operation adopts is 2.5MPa～4.5MPa (MPa).
3. production method of two-color artificial marble according to claim 1 and 2 is characterized in that, the viscosity of described material compound is 1 pool～50 pools.
4. production method of two-color artificial marble according to claim 1 and 2, it is characterized in that, wherein said material compound, comprise that one or more are selected from unsaturated polyester resin, the thermosetting resin of acrylate and methacrylate resin, one or more are selected from aluminium hydroxide, calcium carbonate, silicate, magnesia, filler with marble chips stone and powder, one or more are selected from the initator of peroxide and perester compound, with the acrylate compounds as crosslinking agent, and one or more comprise ultra-violet absorber, fire retardant, releasing agent, fluidizing reagent, thickener, polymerization inhibitor, antioxidant is at interior additive.
5. production method of two-color artificial marble according to claim 3, it is characterized in that, wherein said material compound, comprise that one or more are selected from unsaturated polyester resin, the thermosetting resin of acrylate and methacrylate resin, one or more are selected from aluminium hydroxide, calcium carbonate, silicate, magnesia, filler with marble chips stone and powder, one or more are selected from the initator of peroxide and perester compound, with the acrylate compounds as crosslinking agent, and one or more comprise ultra-violet absorber, fire retardant, releasing agent, fluidizing reagent, thickener, polymerization inhibitor, antioxidant is at interior additive.
6. production method of two-color artificial marble according to claim 1 and 2 is characterized in that, described curing process is to place spontaneous curing at normal temperatures, or solidified in 2 hours 30 ℃～60 ℃ heating.
7. production method of two-color artificial marble according to claim 3 is characterized in that, described curing process is to place spontaneous curing at normal temperatures, or solidified in 2 hours 30 ℃～60 ℃ heating.
8. production method of two-color artificial marble according to claim 4 is characterized in that, described curing process is to place spontaneous curing at normal temperatures, or solidified in 2 hours 30 ℃～60 ℃ heating.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200510035524 CN1733445A (en) | 2005-07-04 | 2005-07-04 | Production method of two-color artificial marble |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200510035524 CN1733445A (en) | 2005-07-04 | 2005-07-04 | Production method of two-color artificial marble |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1733445A true CN1733445A (en) | 2006-02-15 |
Family
ID=36076168
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200510035524 Pending CN1733445A (en) | 2005-07-04 | 2005-07-04 | Production method of two-color artificial marble |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1733445A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1864969B (en) * | 2006-03-06 | 2010-04-07 | 云浮市粤云新型石材有限公司 | Production process and device for producing coloured grain artificial marble |
| CN103512832A (en) * | 2013-10-09 | 2014-01-15 | 广东生益科技股份有限公司 | Method for detecting flowing condition of glue during laminating boards |
| CN104446145A (en) * | 2014-11-21 | 2015-03-25 | 广东中旗新材料科技有限公司 | Double-color double-pattern artificial quartz stone plate and production process thereof |
| CN105417996A (en) * | 2015-11-18 | 2016-03-23 | 湖北本格重工科技有限公司 | White shimmering artificial marbles |
| CN109651768A (en) * | 2018-12-13 | 2019-04-19 | 北京华祥瑞野营装备有限公司 | A kind of preparation method for simulating Triton block |
-
2005
- 2005-07-04 CN CN 200510035524 patent/CN1733445A/en active Pending
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1864969B (en) * | 2006-03-06 | 2010-04-07 | 云浮市粤云新型石材有限公司 | Production process and device for producing coloured grain artificial marble |
| CN103512832A (en) * | 2013-10-09 | 2014-01-15 | 广东生益科技股份有限公司 | Method for detecting flowing condition of glue during laminating boards |
| CN103512832B (en) * | 2013-10-09 | 2015-08-19 | 广东生益科技股份有限公司 | The method of glue flow state during detection pressing plate |
| CN104446145A (en) * | 2014-11-21 | 2015-03-25 | 广东中旗新材料科技有限公司 | Double-color double-pattern artificial quartz stone plate and production process thereof |
| CN105417996A (en) * | 2015-11-18 | 2016-03-23 | 湖北本格重工科技有限公司 | White shimmering artificial marbles |
| CN109651768A (en) * | 2018-12-13 | 2019-04-19 | 北京华祥瑞野营装备有限公司 | A kind of preparation method for simulating Triton block |
| CN109651768B (en) * | 2018-12-13 | 2021-06-29 | 北京华祥瑞野营装备有限公司 | Preparation method of simulated trinitrotoluene medicine block |
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| AD01 | Patent right deemed abandoned | ||
| C20 | Patent right or utility model deemed to be abandoned or is abandoned |