CN204237750U - A kind of time controlled type steady power ultrasonic breaking emulsion and dewatering and reducing thick oil viscosity device - Google Patents
A kind of time controlled type steady power ultrasonic breaking emulsion and dewatering and reducing thick oil viscosity device Download PDFInfo
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Abstract
本实用新型公开了一种时控型稳恒功率超声波破乳脱水及稠油降粘装置,包括超声波电源控制柜、超声波换能器和罐体;超声波电源控制柜含若干路超声波电源,并通过特种超声电缆与超声波换能器一一对应相连接,通过时间控制的方式实现超声波换能器功率输出的稳恒化,确保破乳脱水或降粘的持续有效性;超声波换能器按设计要求安装排列在罐体中,确保超声波在罐体中的均衡有效分布。本实用新型利用超声波单独作用或与破乳剂的联合作用,可以取得比单独破乳剂工艺下更好的破乳脱水效果,节约了破乳脱水成本;利用超声波单独作用或与降粘剂的联合作用,可以取得比单独降粘剂工艺下对稠油更好的降粘效果,节约了降粘成本。
The utility model discloses a time-controlled stable power ultrasonic demulsification dehydration and heavy oil viscosity reduction device, which comprises an ultrasonic power control cabinet, an ultrasonic transducer and a tank body; the ultrasonic power control cabinet contains several ultrasonic power sources, and passes through The special ultrasonic cables are connected with the ultrasonic transducers in one-to-one correspondence, and the power output of the ultrasonic transducers is stabilized through time control to ensure the continuous effectiveness of demulsification and dehydration or viscosity reduction; the ultrasonic transducers are designed according to the design requirements The installation is arranged in the tank body to ensure the balanced and effective distribution of ultrasonic waves in the tank body. The utility model utilizes the single action of ultrasonic waves or the joint action of demulsifiers, which can achieve better demulsification and dehydration effect than that of single demulsifier process, saving the cost of demulsification dehydration; the single action of ultrasonic waves or the joint action of viscosity reducers , can achieve a better viscosity reduction effect on heavy oil than the single viscosity reducer process, saving the cost of viscosity reduction.
Description
技术领域technical field
本实用新型属于石油化工技术领域,尤其涉及一种时控型稳恒功率超声波破乳脱水及稠油降粘装置。The utility model belongs to the technical field of petrochemical industry, in particular to a time-controlled stable power ultrasonic demulsification dehydration and heavy oil viscosity reduction device.
背景技术Background technique
原油破乳脱水的方法主要有加热沉降、破乳剂、电脱水等方法,通常这三种方法或其中的两种方法结合使用。但随着油田的深度开发和各种新的采油技术的应用,尤其是三次采油中化学方法的使用,使原油的化学成分及乳状液结构越来越复杂,原油破乳脱水的难度越来越大,采用上述传统方法无法对这些复杂的乳化油顺利实现油水分离;除此之外,含胶质或沥青质高的稠油、酸化油、老化油等,由于其化学成分及乳状结构的复杂性,也难以用常规方法破乳脱水。国内外研究表明,超声破乳是十分有效的强化原油脱水的方法。超声波破乳是基于超声波作用于性质不同的流体介质产生的位移效应来实现的,由于位移效应的存在,乳状液中的水粒子将不断向波腹或波节移动、聚积并发生碰撞,生成直径较大的水滴,因密度差异,水滴借助重力从油中沉降分离,达到脱水目的。由于超声波在液体中具有良好的传导性,故这种方法适用于各种类型的原油乳状液。Crude oil demulsification and dehydration methods mainly include heating sedimentation, demulsifier, electric dehydration and other methods, usually these three methods or two of them are used in combination. However, with the in-depth development of oil fields and the application of various new oil recovery technologies, especially the use of chemical methods in tertiary oil recovery, the chemical composition and emulsion structure of crude oil are becoming more and more complex, and the difficulty of demulsification and dehydration of crude oil is becoming more and more difficult. It is difficult to achieve oil-water separation for these complex emulsified oils by using the above-mentioned traditional methods; in addition, heavy oils containing colloids or asphaltene, acidified oils, aged oils, etc. It is also difficult to demulsify and dehydrate by conventional methods. Research at home and abroad has shown that ultrasonic demulsification is a very effective method to strengthen crude oil dehydration. Ultrasonic demulsification is realized based on the displacement effect produced by ultrasonic waves acting on fluid media with different properties. Due to the existence of the displacement effect, the water particles in the emulsion will continuously move to antinodes or nodes, accumulate and collide, forming diameter Larger water droplets, due to the difference in density, the water droplets will settle and separate from the oil by gravity to achieve the purpose of dehydration. Due to the good conductivity of ultrasonic waves in liquids, this method is suitable for various types of crude oil emulsions.
稠油粘度高,流动性差,造成稠油开采、输送中存在困难,因此,降粘是稠油开采和输送的关键问题。地面输送时,常规的降粘方法有加热、掺稀,以及采用降粘剂、降凝剂、减阻剂等化学药剂。以上这些方法都有各自的特点和局限性,主要问题是耗能多、成本高、效果不稳定:掺稀油会造成稀油用量大,投资大,成本高,管理工作量大,而且掺入稀油后会使各自的物性发生改变;掺热水既要消耗大量的燃料,掺水后再脱水,又增加了生产成本;采用化学药剂,一是药剂选型问题,选型不好,降粘效果就不明显或不稳定,二是在添加了大量的化学药剂后,对后续原油、污水的处理难度加大,而且会产生污染问题。超声波降粘技术是近几年来迅速发展起来的一种新技术,利用超声波的振动作用、空化作用及热作用可以有效地降低稠油粘度。超声波单独作用时,降粘率一般为25~50%,超声波与表面活性剂联合作用时,降粘率可高达到70~80%。超声波降粘方法具有投资少、成本低、见效快、效益高等特点,是实现较低温度下输送稠油的有效方法。Heavy oil has high viscosity and poor fluidity, which causes difficulties in heavy oil production and transportation. Therefore, viscosity reduction is a key issue in heavy oil production and transportation. For ground transportation, conventional viscosity reduction methods include heating, diluting, and using chemical agents such as viscosity reducers, pour point depressants, and drag reducers. The above methods have their own characteristics and limitations. The main problems are high energy consumption, high cost, and unstable effect: mixing thin oil will result in a large amount of thin oil, large investment, high cost, and heavy management workload. Thin oil will change their physical properties; mixing hot water will consume a lot of fuel, and dehydration after mixing with water will increase the production cost; the use of chemical agents, one is the problem of agent selection. The sticking effect is not obvious or unstable. Second, after adding a large amount of chemical agents, it is more difficult to treat subsequent crude oil and sewage, and pollution problems will occur. Ultrasonic viscosity reduction technology is a new technology developed rapidly in recent years. Vibration, cavitation and thermal effects of ultrasonic waves can effectively reduce the viscosity of heavy oil. When ultrasonic waves act alone, the viscosity reduction rate is generally 25-50%, and when ultrasonic waves and surfactants act together, the viscosity reduction rate can reach as high as 70-80%. Ultrasonic viscosity reduction method has the characteristics of less investment, low cost, quick effect and high benefit, and is an effective method for transporting heavy oil at relatively low temperature.
实用新型内容Utility model content
本实用新型实施例的目的在于提供一种时控型稳恒功率超声波破乳脱水及稠油降粘装置,旨在解决现有的破乳脱水及稠油降粘方法存在的原油破乳脱水难度大,油水分离难,成本高,耗能大的问题。The purpose of the embodiment of the utility model is to provide a time-controlled stable power ultrasonic demulsification dehydration and heavy oil viscosity reduction device, which aims to solve the difficulty of demulsification and dehydration of crude oil existing in the existing methods of demulsification dehydration and heavy oil viscosity reduction Large, difficult oil-water separation, high cost, and high energy consumption.
本实用新型实施例是这样实现的,一种时控型稳恒功率超声波破乳脱水及稠油降粘装置,该时控型稳恒功率超声波破乳脱水及稠油降粘装置包括:超声波电源控制柜、超声波换能器、超声波电缆;超声波电源控制柜通过超声波电缆连接超声波换能器。The embodiment of the utility model is achieved in this way, a time-controlled constant power ultrasonic demulsification dehydration and heavy oil viscosity reduction device, the time-controlled constant power ultrasonic demulsification dehydration and heavy oil viscosity reduction device includes: ultrasonic power supply A control cabinet, an ultrasonic transducer, and an ultrasonic cable; the ultrasonic power supply control cabinet is connected to the ultrasonic transducer through an ultrasonic cable.
进一步,该时控型稳恒功率超声波破乳脱水及稠油降粘装置还包括:罐体、原油进口、排污口、检修口、原油出口;Further, the time-controlled stable power ultrasonic demulsification dehydration and heavy oil viscosity reduction device also includes: tank body, crude oil inlet, sewage outlet, inspection port, crude oil outlet;
超声波换能器按一定的间距和相互角度排列安装在罐体中,换能器的主体部分(即发声部分)在罐体内,而出线端通过法兰安装固定在罐壁。原油进口设置在罐体的左上方,原油出口安装在罐体的右下方,排污口安装在原油出口的左侧,检修口安装在罐体上方的中间位置。Ultrasonic transducers are arranged and installed in the tank body at a certain distance and mutual angle. The main part of the transducer (that is, the sounding part) is in the tank body, and the outlet end is fixed on the tank wall through flange installation. The crude oil inlet is installed on the upper left of the tank body, the crude oil outlet is installed on the lower right side of the tank body, the sewage outlet is installed on the left side of the crude oil outlet, and the inspection port is installed in the middle above the tank body.
进一步,超声波换能器的超声波频率为20Khz~24Khz。Further, the ultrasonic frequency of the ultrasonic transducer is 20Khz-24Khz.
进一步,超声波破乳脱水时间为12min~30min。Further, the time for ultrasonic demulsification and dehydration is 12 minutes to 30 minutes.
进一步,超声波降粘时间为5min~30min。Further, the time for ultrasonic viscosity reduction is 5 minutes to 30 minutes.
本实用新型提供的时控型稳恒功率超声波破乳脱水及稠油降粘装置,通过特种超声电缆与超声波换能器一一对应相连接,通过时间控制的方式实现换能器功率输出的稳恒化,确保破乳脱水或降粘的持续有效性;所述超声波换能器按设计要求安装排列在罐体中,确保超声波在罐体中的均衡有效分布;The time-controlled stable power ultrasonic demulsification dehydration and heavy oil viscosity reduction device provided by the utility model is connected with the ultrasonic transducer one by one through a special ultrasonic cable, and the stable power output of the transducer is realized through time control. Constant chemical to ensure the continuous effectiveness of demulsification and dehydration or viscosity reduction; the ultrasonic transducers are installed and arranged in the tank according to the design requirements to ensure the balanced and effective distribution of ultrasonic waves in the tank;
现有技术相比,本实用新型的优点在于:Compared with the prior art, the utility model has the advantages of:
1.与国内已有超声波破乳脱水或超声波降粘技术相比,本实用新型由于采用了时控技术,可以使需要的超声波功率一直保持在稳定的状态,而不存在衰减,以确保破乳脱水或稠油降粘的持续有效;同时,可以保证超声波换能器的工作故障率大大降低,保证油田的正常生产。1. Compared with the existing domestic ultrasonic demulsification and dehydration or ultrasonic viscosity reduction technology, the utility model adopts time control technology, which can keep the required ultrasonic power in a stable state without attenuation, so as to ensure demulsification Dehydration or heavy oil viscosity reduction is continuously effective; at the same time, it can ensure that the failure rate of the ultrasonic transducer is greatly reduced, and the normal production of the oil field is guaranteed.
2.经超声波处理后,原油脱水率提高,脱水速度明显加快,脱出水中的含油降低,脱后原油中的含水降低。同时。由于超声波强化了破乳剂的作用,可减少使用甚至停用破乳剂,也就是说,采用超声波破乳脱水技术后,可在大量减少破乳剂用量的情况下,使原油脱水效果达到外输标准;若原先采用化学破乳与电脱水相结合的处理工艺,采用超声波技术后,不但可以减少或停用破乳剂,而且可以降低电脱水装置的电流,稳定电脱水装置操作,减少跳闸频次,并使原油脱水效果达到外输标准。另外,由于脱出水中含油明显变少,可以有效降低污水站处理污水的成本。所以,超声波破乳脱水技术是一项技术效果好、节能明显且环保的技术。2. After ultrasonic treatment, the dehydration rate of crude oil is increased, the dehydration speed is obviously accelerated, the oil content in the extracted water is reduced, and the water content in the crude oil after dehydration is reduced. at the same time. Because ultrasonic waves strengthen the effect of demulsifiers, the use of demulsifiers can be reduced or even stopped. That is to say, after adopting ultrasonic demulsification and dehydration technology, the dehydration effect of crude oil can reach the export standard while greatly reducing the amount of demulsifiers; If the original combination of chemical demulsification and electric dehydration treatment process, the use of ultrasonic technology can not only reduce or stop using the demulsifier, but also reduce the current of the electric dehydration device, stabilize the operation of the electric dehydration device, reduce the trip frequency, and make The dehydration effect of crude oil reaches the export standard. In addition, since the oil content in the extracted water is significantly less, the cost of sewage treatment at sewage stations can be effectively reduced. Therefore, ultrasonic demulsification and dehydration technology is a technology with good technical effect, obvious energy saving and environmental protection.
3.超声波的机械、热及空化等效应的作用,可以降低原油粘度,增加流动性,从而降低原油输送温度,大大节约加热用的天然气或原油的消耗量,达到提高输送效率和节约能源的目的。经超声波处理后,原油的运动粘度降低,输送摩擦阻力降低,可大量增加不加热集输井的数量,大大减少掺水量,节约能源;可减少集输过程中的掺稀油量,节约稀油资源;可提高集输系统效率,减少输油泵耗电。超声波降粘技术对环境无污染,工艺技术简单,易操作、易管理,有利于安全生产,提高油田生产现代化水平。3. The mechanical, thermal and cavitation effects of ultrasonic waves can reduce the viscosity of crude oil and increase fluidity, thereby reducing the temperature of crude oil transportation, greatly saving the consumption of natural gas or crude oil for heating, and achieving the goal of improving transmission efficiency and saving energy. Purpose. After ultrasonic treatment, the kinematic viscosity of crude oil is reduced, and the frictional resistance of transportation is reduced, which can greatly increase the number of unheated gathering and transportation wells, greatly reduce the amount of water mixed, and save energy; it can reduce the amount of thin oil mixed in the process of gathering and transportation, saving thin oil resources; it can improve the efficiency of the gathering and transportation system and reduce the power consumption of the oil transportation pump. Ultrasonic viscosity reduction technology has no pollution to the environment, simple process technology, easy operation and management, which is conducive to safe production and improves the modernization level of oilfield production.
附图说明Description of drawings
图1是本实用新型实施例提供的时控型稳恒功率超声波破乳脱水及稠油降粘装置结构示意图;Fig. 1 is a schematic structural diagram of the time-controlled stable power ultrasonic demulsification dehydration and heavy oil viscosity reduction device provided by the embodiment of the utility model;
图中:1、超声波电源控制柜;2、超声波换能器;3、超声波电缆;4、罐体;5、原油进口;6、排污口;7、检修口;8、原油出口。In the figure: 1. Ultrasonic power supply control cabinet; 2. Ultrasonic transducer; 3. Ultrasonic cable; 4. Tank body; 5. Crude oil import; 6. Sewage outlet; 7. Inspection port; 8. Crude oil export.
具体实施方式Detailed ways
为了使本实用新型的目的、技术方案及优点更加清楚明白,以下结合实施例,对本实用新型进行进一步详细说明。应当理解,此处所描述的具体实施例仅仅用以解释本实用新型,并不用于限定本实用新型。In order to make the purpose, technical solution and advantages of the utility model clearer, the utility model will be further described in detail below in conjunction with the embodiments. It should be understood that the specific embodiments described here are only used to explain the utility model, and are not intended to limit the utility model.
下面结合附图及具体实施例对本实用新型的应用原理作进一步描述。The application principle of the present utility model will be further described below in conjunction with the accompanying drawings and specific embodiments.
如图1所示,本实用新型实施例的时控型稳恒功率超声波破乳脱水及稠油降粘装置主要包括:超声波电源控制柜1、超声波换能器2、超声波电缆3、罐体4、原油进口5、排污口6、检修口7、原油出口8;As shown in Figure 1, the time-controlled stable power ultrasonic demulsification dehydration and heavy oil viscosity reduction device of the embodiment of the utility model mainly includes: ultrasonic power supply control cabinet 1, ultrasonic transducer 2, ultrasonic cable 3, tank body 4 , crude oil import 5, sewage outlet 6, inspection port 7, crude oil export 8;
超声波电源控制柜1通过超声波电缆3连接超声波换能器2,超声波换能器2按一定的间距和相互角度排列安装在罐体中,换能器的主体部分(即发声部分)在罐体内,而出线端通过法兰安装固定在罐壁,原油进口5设置在罐体4的左上方,原油出口8安装在罐体4的右下方,排污口6安装在原油出口8的左侧,检修口7安装在罐体4上方的中间位置。The ultrasonic power supply control cabinet 1 is connected to the ultrasonic transducer 2 through the ultrasonic cable 3, and the ultrasonic transducers 2 are arranged and installed in the tank according to a certain distance and mutual angle. The outlet end is installed and fixed on the tank wall through the flange, the crude oil inlet 5 is arranged on the upper left of the tank body 4, the crude oil outlet 8 is installed on the lower right side of the tank body 4, the sewage outlet 6 is installed on the left side of the crude oil outlet 8, and the inspection port 7 is installed in the middle position above tank body 4.
超声波换能器按一定的间距和相互角度排列安装在罐体中,超声波换能器的主体部分(即发声部分)在罐体内,而出线端通过法兰安装固定在罐壁。The ultrasonic transducers are arranged and installed in the tank according to a certain distance and mutual angle. The main part of the ultrasonic transducer (that is, the sounding part) is in the tank, and the outlet end is fixed on the tank wall through the flange.
超声波换能器2的超声波频率为20Khz~24Khz;The ultrasonic frequency of the ultrasonic transducer 2 is 20Khz~24Khz;
原油流经罐体的时间,即超声波破乳脱水时间为12min~30min;The time for crude oil to flow through the tank, that is, the time for ultrasonic demulsification and dehydration is 12 minutes to 30 minutes;
用于稠油降粘时,原油流经罐体的时间,即超声波降粘时间为5min~30min。When used for viscosity reduction of heavy oil, the time for crude oil to flow through the tank, that is, the time for ultrasonic viscosity reduction, is 5 minutes to 30 minutes.
具体案例:Specific case:
中石化某油田联合站处理原油15000m3/天,原油高含水,平均含水率为90%,经三相分离器分离游离水后,含水率降为(平均)39%,三相分离器出口端原油液量平均3600m3/天。由于原油中含有多种组分的化合物,原油乳化交严重,造成乳化水脱水困难,原有流程中,将原油加热到80℃,并加入300ppm的破乳剂,经24小时沉降后,原油含水为0.5~3.5%,每月达不到含水0.5%的外输要求的天数超过10天。根据现场工况,在加热炉后安装了一套超声波破乳脱水装置。An oilfield joint station of Sinopec processes 15,000m 3 /day of crude oil. The crude oil has high water content, with an average water content of 90%. After the free water is separated by a three-phase separator, the water content drops to (average) 39%. The average liquid volume is 3600m 3 /day. Because the crude oil contains compounds of various components, the emulsification of the crude oil is serious, which makes it difficult to dehydrate the emulsified water. In the original process, the crude oil is heated to 80°C and 300ppm of demulsifier is added. After 24 hours of settlement, the water content of the crude oil is 0.5-3.5%, and the number of days that fail to meet the export requirement of 0.5% water content exceeds 10 days per month. According to the working conditions on site, a set of ultrasonic demulsification and dehydration device is installed behind the heating furnace.
装置主体由超声波电源柜(共4个,每个含4路电源,共16路电源)、超声波换能器(共16支)组成。换能器安装在罐体中,通过超声波电缆连接到超声波电源柜;换能器分成4排,每排4支,上端2支135°,下端2支135°,上下对称;罐体容积为50m3,超声波处理时间为20min。在流程中加入超声波破乳脱水装置后,在加热温度和破乳剂加药量不变的情况下,外输原油含水率均低于0.5%;不改变加热温度、将破乳剂加药量减少为200ppm,外输原油含水率为0.2~0.6%,每月达不到含水0.5%的外输要求的天数仅为1天。说明超声波装置提高了原油脱水率和外输原油含水达标率,并可以减少化学破乳剂的使用量,节约了破乳脱水的生产成本。The main body of the device is composed of ultrasonic power supply cabinets (4 in total, each containing 4 power supplies, 16 power supplies in total), and ultrasonic transducers (16 in total). The transducers are installed in the tank and connected to the ultrasonic power cabinet through ultrasonic cables; the transducers are divided into 4 rows, 4 in each row, 2 at the upper end at 135°, and 2 at the lower end at 135°, symmetrical up and down; the volume of the tank is 50m 3. Ultrasonic treatment time is 20min. After the ultrasonic demulsification and dehydration device is added to the process, the moisture content of the exported crude oil is lower than 0.5% under the condition that the heating temperature and demulsifier dosage remain unchanged; without changing the heating temperature, the demulsifier dosage is reduced to 200ppm, the water content of crude oil exported is 0.2-0.6%, and the number of days that cannot meet the export requirement of 0.5% water content is only 1 day per month. It shows that the ultrasonic device improves the dehydration rate of crude oil and the compliance rate of the water content of crude oil exported, and can reduce the use of chemical demulsifiers, saving the production cost of demulsification and dehydration.
本实用新型的工作原理:Working principle of the utility model:
本实用新型包括超声波电源控制柜、超声波换能器和罐体;超声波电源控制柜含若干路超声波电源,并通过特种超声电缆与超声波换能器一一对应相连接,通过时间控制的方式实现超声波换能器功率输出的稳恒化,确保破乳脱水或降粘的持续有效性;超声波换能器按设计要求安装排列在罐体中,确保超声波在罐体中的均衡有效分布;本实用新型利用超声波单独作用或与破乳剂的联合作用,可以取得比单独破乳剂工艺下更好的破乳脱水效果,并可节约破乳脱水成本;本实用新型利用超声波单独作用或与降粘剂的联合作用,可以取得比单独降粘剂工艺下对稠油更好的降粘效果,并可节约降粘成本。The utility model includes an ultrasonic power supply control cabinet, an ultrasonic transducer and a tank body; the ultrasonic power supply control cabinet contains several ultrasonic power supplies, and is connected with the ultrasonic transducers one by one through special ultrasonic cables, and the ultrasonic transducer is realized through time control. The stability of the power output of the transducer ensures the continuous effectiveness of demulsification and dehydration or viscosity reduction; the ultrasonic transducers are installed and arranged in the tank according to the design requirements to ensure the balanced and effective distribution of ultrasonic waves in the tank; the utility model Using ultrasonic wave alone or in combination with demulsifier can achieve better demulsification and dehydration effect than that of single demulsifier process, and can save the cost of demulsification dehydration; the utility model uses ultrasonic wave alone or in combination with viscosity reducer It can achieve a better viscosity reduction effect on heavy oil than the single viscosity reducer process, and can save the cost of viscosity reduction.
作为优选,本实用新型是通过时间控制的方式来实现换能器功率输出的稳恒化,但破乳脱水的时间控制方式和稠油降粘的时间控制方式是有区别的。As a preference, the utility model realizes the stabilization of the power output of the transducer through time control, but the time control mode of demulsification and dehydration is different from the time control mode of heavy oil viscosity reduction.
作为优选,本实用新型中的罐体其容积大小要根据原油处理量、超声波作用时间来进行计算设计。As a preference, the volume of the tank body in the present invention should be calculated and designed according to the crude oil processing capacity and the ultrasonic action time.
作为优选,本实用新型既可以用于原油的破乳脱水,又可以用于稠油的降粘输送,但破乳脱水与降粘需要不同的超声波功率、频率和作用时间,同样是破乳脱水,或同样是稠油降粘,不同区块的原油需要不同的超声波功率、频率和作用时间。As a preference, the utility model can be used not only for demulsification and dehydration of crude oil, but also for viscosity reduction transportation of heavy oil, but demulsification dehydration and viscosity reduction require different ultrasonic power, frequency and action time. , or the same for heavy oil viscosity reduction, crude oil in different blocks requires different ultrasonic power, frequency and action time.
参见图1,一种时控型稳恒功率超声波破乳脱水及稠油降粘装置,其特征在于:包括超声波电源控制柜1、超声波换能器2和罐体4;所述超声波电源控制柜1含若干路超声波电源,并通过特种超声电缆3与超声波换能器2一一对应相连接,通过时间控制的方式实现换能器功率输出的稳恒化,确保破乳脱水或降粘的持续有效性。Referring to Fig. 1, a time-controlled stable power ultrasonic demulsification dehydration and heavy oil viscosity reduction device is characterized in that it includes an ultrasonic power control cabinet 1, an ultrasonic transducer 2 and a tank body 4; the ultrasonic power control cabinet 1 Contains several ultrasonic power sources, and is connected to the ultrasonic transducer 2 one by one through special ultrasonic cables 3, and the power output of the transducer is stabilized by time control to ensure the continuous demulsification and dehydration or viscosity reduction effectiveness.
所述超声波换能器2按设计要求安装排列在罐体4中,确保超声波在罐体4中的均衡有效分布。The ultrasonic transducers 2 are installed and arranged in the tank body 4 according to design requirements, so as to ensure the balanced and effective distribution of ultrasonic waves in the tank body 4 .
本实用新型利用超声波单独作用或与破乳剂的联合作用,可以取得比单独破乳剂工艺下更好的破乳脱水效果,并可节约破乳脱水成本;本实用新型利用超声波单独作用或与降粘剂的联合作用,可以取得比单独降粘剂工艺下对稠油更好的降粘效果,并可节约降粘成本。破乳剂或降粘剂在图1所示加药点加入。The utility model uses the ultrasonic wave alone or in combination with the demulsifier to obtain a better demulsification and dehydration effect than the single demulsifier process, and can save the cost of demulsification and dehydration; the utility model uses the ultrasonic wave alone or combined with the viscosity reduction The combined effect of the agent can achieve a better viscosity reduction effect on heavy oil than that of a single viscosity reducer process, and can save the cost of viscosity reduction. Demulsifier or viscosity reducer is added at the dosing point shown in Figure 1.
需要破乳脱水的原油或需要降粘的稠油从本实用新型装置的进口5进入装有超声波换能器2的罐体4,经超声波处理一定时间后,从装置的出口8流出;由于原油中含有一定数量的污泥和固体物,所以,经一段时间后,需要进行排污处理,污泥和固体物等从排污口6排出;另外,7为检修口。The crude oil that needs to be demulsified and dehydrated or the heavy oil that needs to be reduced in viscosity enters the tank body 4 equipped with the ultrasonic transducer 2 from the inlet 5 of the utility model device, and flows out from the outlet 8 of the device after ultrasonic treatment for a certain period of time; There is a certain amount of sludge and solid matter in it, so after a period of time, sewage treatment is required, and the sludge and solid matter are discharged from the sewage outlet 6; in addition, 7 is an inspection port.
所述本实用新型采用的超声波频率为20~24Khz。The ultrasonic frequency used in the utility model is 20-24Khz.
所述本实用新型用于原油破乳脱水时,原油流经罐体的时间(即超声波破乳脱水时间)为12~30min,原油的物性、含水率高低、破乳剂加药量、加热温度等都是影响破乳脱水时间的因素。When the utility model is used for demulsification and dehydration of crude oil, the time for the crude oil to flow through the tank (i.e., the time for ultrasonic demulsification and dehydration) is 12 to 30 minutes. All are factors that affect the demulsification and dehydration time.
所述本实用新型用于稠油降粘时,原油流经罐体的时间(即超声波降粘时间)为5~30min,稠油的初始粘度、稠油温度、稠油含水率、降粘剂加药量等都是影响降粘时间的因素。When the utility model is used for viscosity reduction of heavy oil, the time for the crude oil to flow through the tank (ie ultrasonic viscosity reduction time) is 5-30 minutes, the initial viscosity of the heavy oil, the temperature of the heavy oil, the water content of the heavy oil, and the viscosity reducing Dosing amount and so on are factors that affect the viscosity reduction time.
超声波破乳脱水的机理是:1)机械振动作用促使水粒子凝聚。超声波作用于油水乳状液后,由于油、水的物性不同,对超声波的响应不同,出现油、水粒子各自集聚的现象,称之为“位移效应”,由于位移效应的存在,乳状液中的水粒子将不断向波腹或波节移动、聚积并发生碰撞,生成直径较大的水滴,因密度差异,水滴借助重力从油中沉降分离,达到脱水目的。2)超声波产生的高频振动、位移效应的联合作用,可有效破坏原油乳化结构,使油水界面膜直接破裂,这是超声波的“破乳效应”。3)机械振动作用可使原油中的石蜡、胶质、沥青质等天然乳化剂分散均匀,增加其溶解度,降低油-水界面膜的机械强度,有利于水相沉降分离;4)热作用可降低油、水界面膜强度和原油粘度。一方面,边界摩擦使油、水分界处温度升高,有利于界面膜的破裂;另一方面,原油吸收部分声能转化成热能,可降低原油的粘度,有利于水的沉降分离。The mechanism of ultrasonic demulsification and dehydration is: 1) Mechanical vibration promotes the aggregation of water particles. After the ultrasonic wave acts on the oil-water emulsion, due to the different physical properties of the oil and water, the response to the ultrasonic wave is different, and the phenomenon that the oil and water particles gather separately, which is called the "displacement effect". Due to the existence of the displacement effect, the particles in the emulsion Water particles will continue to move to the antinode or node, accumulate and collide, forming water droplets with larger diameters. Due to the difference in density, the water droplets will settle and separate from the oil by gravity to achieve the purpose of dehydration. 2) The combination of high-frequency vibration and displacement effect generated by ultrasonic waves can effectively destroy the emulsified structure of crude oil and directly rupture the oil-water interface film. This is the "emulsification effect" of ultrasonic waves. 3) Mechanical vibration can disperse natural emulsifiers such as paraffin, colloid, and asphaltene in crude oil evenly, increase their solubility, reduce the mechanical strength of the oil-water interface film, and facilitate the settlement and separation of water phase; 4) thermal action can Reduce oil, water interface film strength and crude oil viscosity. On the one hand, boundary friction increases the temperature of the oil-water interface, which is conducive to the rupture of the interfacial film; on the other hand, crude oil absorbs part of the sound energy and converts it into heat energy, which can reduce the viscosity of crude oil and facilitate the sedimentation and separation of water.
超声波对稠油降粘的机理是:(1)超声波空化效应产生的高温高压和高速微射流作用于原油中的大分子团,使沥青质大分子团遭到破坏而解体,充分破碎,并部分被乳化;同时,汽泡在湮灭运动过程中将对原油产生机械剪切,这些效应都会对原油产生很好的降粘、降凝效果。(2)超声波的机械振动作用可加速原油中较小分子与惰性大的大分子链之间的相对运动,从而增大了它们之间的摩擦力。当这种摩擦力足够大时,可以打断C一C键,使沥青质大分子链、长链石蜡烃分子链断裂而破碎,起到降粘和防蜡的作用。(3)在原油与管壁的分界面处,由于振动速度的巨大差异,使得原油与管壁之间发生摩擦,这种边界摩擦产生的局部高温和空化作用产生的超声波热效应使原油的温度升高,分子运动加剧,可以降低原油的粘度和凝固点。(4)在超声波作用下,介质的电导率和表面张力下降,分子间、分子与输油管道间亲和力减弱,有利于降低原油粘度,增加原油的流动性。The mechanism of ultrasonic viscosity reduction for heavy oil is: (1) The high temperature, high pressure and high-speed micro-jet generated by the ultrasonic cavitation effect act on the macromolecular clusters in crude oil, causing the asphaltene macromolecular clusters to be destroyed and disintegrated, fully broken, and Partially emulsified; at the same time, the gas bubbles will produce mechanical shear on the crude oil during the annihilation movement, and these effects will have a good effect on reducing the viscosity and pour point of the crude oil. (2) The mechanical vibration of ultrasonic waves can accelerate the relative movement between smaller molecules in crude oil and large inert macromolecular chains, thereby increasing the friction between them. When this friction force is large enough, it can break the C-C bond, break and break the asphaltene macromolecular chain and long-chain paraffin molecular chain, and play the role of reducing viscosity and preventing wax. (3) At the interface between the crude oil and the pipe wall, due to the huge difference in vibration velocity, friction occurs between the crude oil and the pipe wall. The local high temperature generated by this boundary friction and the ultrasonic thermal effect generated by cavitation make the temperature of the crude oil As the temperature rises, the molecular motion intensifies, which can reduce the viscosity and freezing point of crude oil. (4) Under the action of ultrasonic waves, the conductivity and surface tension of the medium decrease, and the affinity between molecules, molecules and oil pipelines weakens, which is beneficial to reduce the viscosity of crude oil and increase the fluidity of crude oil.
以上所述仅为本实用新型的较佳实施例而已,并不用以限制本实用新型,凡在本实用新型的精神和原则之内所作的任何修改、等同替换和改进等,均应包含在本实用新型的保护范围之内。The above descriptions are only preferred embodiments of the present utility model, and are not intended to limit the present utility model. Any modifications, equivalent replacements and improvements made within the spirit and principles of the present utility model shall be included in this utility model. within the scope of protection of utility models.
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105156894A (en) * | 2015-08-14 | 2015-12-16 | 黑龙江兰德超声科技股份有限公司 | Super-high power ultrasonic crude oil cooling transportation and viscosity reduction device |
| CN107570485A (en) * | 2017-09-14 | 2018-01-12 | 浙江海洋大学 | A kind of crude oil storage tank sonify silt system |
| CN110714741A (en) * | 2018-07-11 | 2020-01-21 | 中国科学院声学研究所 | Ultrasonic heavy oil viscosity reducing device at wellhead of oil well |
| CN114605015A (en) * | 2020-12-08 | 2022-06-10 | 中国石油天然气股份有限公司 | Method for treating oil refining processing sewage |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105156894A (en) * | 2015-08-14 | 2015-12-16 | 黑龙江兰德超声科技股份有限公司 | Super-high power ultrasonic crude oil cooling transportation and viscosity reduction device |
| CN107570485A (en) * | 2017-09-14 | 2018-01-12 | 浙江海洋大学 | A kind of crude oil storage tank sonify silt system |
| CN110714741A (en) * | 2018-07-11 | 2020-01-21 | 中国科学院声学研究所 | Ultrasonic heavy oil viscosity reducing device at wellhead of oil well |
| CN114605015A (en) * | 2020-12-08 | 2022-06-10 | 中国石油天然气股份有限公司 | Method for treating oil refining processing sewage |
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