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CN209168161U - Multiple anti-fake fluorescent two-dimensional code device - Google Patents

Multiple anti-fake fluorescent two-dimensional code device Download PDF

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Publication number
CN209168161U
CN209168161U CN201821963849.9U CN201821963849U CN209168161U CN 209168161 U CN209168161 U CN 209168161U CN 201821963849 U CN201821963849 U CN 201821963849U CN 209168161 U CN209168161 U CN 209168161U
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dimensional code
oxalate
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刘刚
杨园园
马培华
包焕康
多米尼克·西蒙·莱特
吕耀康
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Zhejiang University of Technology ZJUT
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Zhejiang University of Technology ZJUT
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Abstract

多重防伪荧光二维码器件,自外向里依次包括第一层透明PVC保护膜层、第二层普通二维码层、第三层草酸铽掺杂的PMMA薄膜层、第四层草酸铕掺杂的PMMA薄膜层、第五层白色基底层。本实用新型在不同光线下显示不同的二维码,使用方便,能在多方面保护隐私、财产安全。

The multiple anti-counterfeiting fluorescent two-dimensional code device, from outside to inside, includes a first layer of transparent PVC protective film layer, a second layer of ordinary two-dimensional code layer, a third layer of terbium oxalate doped PMMA film layer, and a fourth layer of europium oxalate doped The PMMA film layer and the fifth white base layer. The utility model displays different two-dimensional codes under different lights, is convenient to use, and can protect privacy and property safety in many aspects.

Description

多重防伪荧光二维码器件Multiple anti-counterfeiting fluorescent two-dimensional code device

技术领域technical field

本实用新型涉及一种多重防伪荧光二维码器件。The utility model relates to a multiple anti-counterfeiting fluorescent two-dimensional code device.

背景技术Background technique

二维码是用某种特定的几何图形按一定规律在平面(二维方向上)分布的黑白相间的图形记录数据符号信息的;在代码编制上巧妙地利用构成计算机内部逻辑基础的“0”、“1”比特流的概念。这就说明了二维码只是由很多0、1组成的数字矩阵,这一特点同时造就了二维码可通过复制、拍照、影印等方式被仿制。然而,对如今的社会来说信息泄露涉及到财产、隐私、身份等重大问题,这隐藏性的损失和潜在的威胁往往是难以被人们接受的。The two-dimensional code records the data symbol information with a black and white pattern distributed on a plane (two-dimensional direction) according to a certain specific geometric figure according to a certain rule; in the code compilation, the "0" that constitutes the internal logic foundation of the computer is cleverly used. , the concept of "1" bit stream. This shows that the two-dimensional code is just a digital matrix composed of many 0s and 1s. This feature also makes the two-dimensional code can be imitated by copying, photographing, photocopying, etc. However, in today's society, information leakage involves major issues such as property, privacy, and identity. This hidden loss and potential threat are often unacceptable.

发明内容SUMMARY OF THE INVENTION

本实用新型要克服现有技术的上述缺点,提供一种多重防伪荧光二维码器件。The utility model aims to overcome the above shortcomings of the prior art, and provides a multiple anti-counterfeiting fluorescent two-dimensional code device.

多重防伪荧光二维码器件,其特征在于:自外向里依次包括第一层透明保护膜层1、第二层普通二维码层2、第三层草酸铽掺杂的PMMA薄膜层3、第四层草酸铕掺杂的PMMA薄膜层4、第五层白色基底层5。The multiple anti-counterfeiting fluorescent two-dimensional code device is characterized in that: from the outside to the inside, it includes a first transparent protective film layer 1, a second ordinary two-dimensional code layer 2, a third terbium oxalate doped PMMA film layer 3, a third layer Four layers of europium oxalate doped PMMA thin film layer 4 and a fifth layer of white base layer 5 .

所述的含有普通二维码的薄纸是印有所需二维码并根据需要自行设计其表面式样的薄纸。所述的二维码可根据需要生成并用油墨打印的二维码,所述的镂空是在二维码上白色区域去掉指定形状的纸质部分。所述的白色底板采用普通的白纸即可。所述的草酸铕掺杂的PMMA薄膜是将草酸铕溶解到聚甲基丙烯酸甲酯溶胀液中,然后烘干成的透明薄膜。草酸铕在365nm波长的紫外光下发出红光并使薄膜变得不透明。所述的草酸铽掺杂的PMMA薄膜是将草酸铽通过溶解到聚甲基丙烯酸甲酯溶胀液中,然后烘干成的透明薄膜。草酸铽在400nm波长的紫外光下发出绿光并使薄膜变得不透明。所述的保护膜选用PVC薄膜。The thin paper containing the ordinary two-dimensional code is the thin paper printed with the required two-dimensional code and the surface pattern of which is designed according to the needs. The two-dimensional code can be generated as required and printed with ink, and the hollow is to remove the paper part of the specified shape from the white area on the two-dimensional code. The white bottom plate can be made of ordinary white paper. The europium oxalate doped PMMA film is a transparent film obtained by dissolving europium oxalate in a polymethyl methacrylate swelling solution and drying. Europium oxalate emits red light under ultraviolet light at a wavelength of 365 nm and makes the film opaque. The terbium oxalate doped PMMA film is a transparent film formed by dissolving terbium oxalate into a polymethyl methacrylate swelling solution and drying. Terbium oxalate emits green light under UV light at a wavelength of 400 nm and makes the film opaque. The protective film is made of PVC film.

草酸铽和草酸铕是常见的稀土化合物,它们的CAS号分别为:草酸铽(十水),CAS号58176-68-4,草酸铕(六水),CAS号3269-12-3。草酸铽掺杂的PMMA薄膜层和草酸铕掺杂的PMMA薄膜层的制备方法参照之前发表的文献"Novel Eu-containing titania compositesderived from a new Eu(III)-doped polyoxotitanate cage,RSC Adv.,2016,6,57"制备[Ti2O(OEt)8(EtOH)EuCl]2掺杂的PMMA薄膜层的方法制备的草酸铽掺杂的PMMA薄膜层和草酸铕掺杂的PMMA薄膜层(就是用草酸铽或草酸铕替代[Ti2O(OEt)8(EtOH)EuCl]2用同样的方法掺杂PMMA薄膜层)。Terbium oxalate and europium oxalate are common rare earth compounds, their CAS numbers are: terbium oxalate (decahydrate), CAS number 58176-68-4, europium oxalate (hexahydrate), CAS number 3269-12-3. For the preparation methods of the terbium oxalate doped PMMA thin film layer and the europium oxalate doped PMMA thin film layer, refer to the previously published literature "Novel Eu-containing titania composites derived from a new Eu(III)-doped polyoxotitanate cage, RSC Adv., 2016, 6,57 "The method for preparing [Ti 2 O(OEt) 8 (EtOH)EuCl] 2 doped PMMA thin film layer prepared by terbium oxalate doped PMMA thin film layer and europium oxalate doped PMMA thin film layer (that is, with oxalic acid) Terbium or europium oxalate instead of [Ti 2 O(OEt) 8 (EtOH)EuCl] 2 doping the PMMA film layer in the same way).

所述的多重防伪荧光二维码,其特征在于:所述的多重防伪荧光二维码是由多层物质组装而成,第一层为PVC保护膜,第二层为镂空的普通二维码,第三层为草酸铽掺杂的PMMA薄膜,然后在第二层镂空的地方选择性镂空部分区域,第四层是含草酸铕掺杂的PMMA薄膜,第五层是白色基底,将制得多重防伪荧光二维码压紧并用保护膜保护。The multiple anti-counterfeiting fluorescent two-dimensional code is characterized in that: the multiple anti-counterfeiting fluorescent two-dimensional code is assembled from multiple layers of materials, the first layer is a PVC protective film, and the second layer is a hollow ordinary two-dimensional code , the third layer is a PMMA film doped with terbium oxalate, and then selectively hollow out part of the area where the second layer is hollowed out, the fourth layer is a PMMA film doped with europium oxalate, and the fifth layer is a white substrate. Multiple anti-counterfeiting fluorescent QR codes are compressed and protected with protective film.

本实用新型产品可分别在450-700nm自然光,365-400nm波长紫外光和小于360nm波长紫外光的照射下呈现出有一些差别的图案。The product of the utility model can show some different patterns under the irradiation of 450-700nm natural light, 365-400nm wavelength ultraviolet light and less than 360nm wavelength ultraviolet light respectively.

450-700nm自然光照射下呈现出普通的二维码。Under the illumination of 450-700nm natural light, ordinary QR codes appear.

365-400nm波长紫外光照射下,在原先黑色二维码的基础上多出不透明绿色符号点,构成新的二维码。Under the irradiation of 365-400nm wavelength ultraviolet light, on the basis of the original black two-dimensional code, there are more opaque green symbol points to form a new two-dimensional code.

小于365nm紫外波长照射光下,二维码上除绿色符号点外,在其他空白部位出现不透明红色符号点,与400nm波长光下的二维码构成新的二维码。Under the light of ultraviolet wavelength less than 365nm, in addition to the green symbol dots, opaque red symbol dots appear in other blank parts on the two-dimensional code, and the two-dimensional code under the wavelength of 400nm constitutes a new two-dimensional code.

本实用新型的优点是:使用方便,能在多方面保护隐私、财产安全,适合人们的需求。The utility model has the advantages that it is convenient to use, can protect privacy and property safety in many aspects, and is suitable for people's needs.

附图说明Description of drawings

图1为本实用新型在波长为450nm-700nm的可见光照下的显示二维码内容的示意图;Fig. 1 is the schematic diagram that the utility model displays two-dimensional code content under the visible light that wavelength is 450nm-700nm;

图2为本实用新型在波长为365-400nm的紫外光照下的显示二维码内容的示意图;Fig. 2 is the schematic diagram that the utility model displays two-dimensional code content under the ultraviolet light that the wavelength is 365-400nm;

图3为本实用新型在波长小于360nm的紫外光照下的显示二维码内容的示意图;3 is a schematic diagram of the utility model displaying two-dimensional code content under ultraviolet light with a wavelength less than 360 nm;

图4为本实用新型主体层状结构示意图。FIG. 4 is a schematic diagram of the layered structure of the main body of the present invention.

具体实施方式Detailed ways

参照图1和图2,一种多重防伪荧光二维码实施如下:1 and 2, a multiple anti-counterfeiting fluorescent two-dimensional code is implemented as follows:

本实用新型专利所述的多重防伪荧光二维码器件自外向里依次包括第一层透明保护膜层1、第二层普通二维码层2、第三层草酸铽掺杂的PMMA薄膜层3、第四层草酸铕掺杂的PMMA薄膜层4、第五层白色基底层5。The multiple anti-counterfeiting fluorescent two-dimensional code device described in the utility model patent sequentially includes a first transparent protective film layer 1 , a second ordinary two-dimensional code layer 2 , and a third terbium oxalate-doped PMMA film layer 3 from the outside to the inside. , the fourth layer 4 of europium oxalate doped PMMA thin film, the fifth layer of white base layer 5 .

所述的透明保护膜是PVC薄膜。The transparent protective film is a PVC film.

所述的普通二维码是自主生成并根据需要进行镂空的二维码。The common two-dimensional code is a two-dimensional code that is generated independently and hollowed out as required.

所述的草酸铽掺杂的PMMA薄膜是将草酸铽溶解到聚甲基丙烯酸甲酯溶胀液中烘干生成并在第二层普通二维码镂空的部分选择性镂空的透明薄膜,薄膜在365nm和400nm的紫外光下变成绿色不透明薄膜。The terbium oxalate doped PMMA film is a transparent film formed by dissolving terbium oxalate in a polymethyl methacrylate swelling solution and drying and selectively hollowing out the part of the second layer of ordinary two-dimensional code. And 400nm UV light becomes green opaque film.

所述的草酸铕掺杂的PMMA薄膜是将草酸铕溶解到聚甲基丙烯酸甲酯溶胀液中烘干生成的透明薄膜,薄膜在365nm紫外光下变成红色不透明薄膜,在400nm紫外光下无颜色变化。The PMMA film doped with europium oxalate is a transparent film produced by dissolving europium oxalate in a polymethyl methacrylate swelling solution and drying. Color changes.

所述的白色基底可以是普通的纸板、塑料板、玻璃板等的一种。The white substrate can be one of ordinary cardboard, plastic plate, glass plate and the like.

本说明书实施例所述的内容仅仅是对发明构思的实现形式的列举,本实用新型的保护范围不应当被视为仅限于实施例所陈述的具体形式,本实用新型的保护范围也包括本领域技术人员根据本实用新型构思所能够想到的等同技术手段。The content described in the embodiments of the present specification is only an enumeration of the realization forms of the inventive concept, and the protection scope of the present invention should not be regarded as limited to the specific forms stated in the embodiments, and the protection scope of the present invention also includes this field Equivalent technical means that can be conceived by a skilled person according to the concept of the present invention.

Claims (1)

1.多重防伪荧光二维码器件,其特征在于:自外向里依次包括第一层PVC透明保护膜层(1)、第二层普通二维码层(2)、第三层草酸铽掺杂的PMMA薄膜层(3)、第四层草酸铕掺杂的PMMA薄膜层(4)、第五层白色基底层(5)。1. The multiple anti-counterfeiting fluorescent two-dimensional code device is characterized in that: from the outside to the inside, it comprises a first layer of PVC transparent protective film layer (1), a second layer of ordinary two-dimensional code layer (2), and a third layer of terbium oxalate doped The PMMA thin film layer (3), the fourth layer of the PMMA thin film layer (4) doped with europium oxalate, and the fifth layer of the white base layer (5).
CN201821963849.9U 2018-11-27 2018-11-27 Multiple anti-fake fluorescent two-dimensional code device Expired - Fee Related CN209168161U (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110569942A (en) * 2019-07-17 2019-12-13 浙江工业大学 A kind of preparation method of multiple anti-counterfeiting fluorescent two-dimensional code device

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110569942A (en) * 2019-07-17 2019-12-13 浙江工业大学 A kind of preparation method of multiple anti-counterfeiting fluorescent two-dimensional code device
CN110569942B (en) * 2019-07-17 2023-05-23 浙江工业大学 A preparation method of multiple anti-counterfeiting fluorescent two-dimensional code devices

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