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CN221217884U - Laterite nickel ore leaching liquid pretreatment mechanism, neutralization treatment device and system - Google Patents

Laterite nickel ore leaching liquid pretreatment mechanism, neutralization treatment device and system Download PDF

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Publication number
CN221217884U
CN221217884U CN202322803157.5U CN202322803157U CN221217884U CN 221217884 U CN221217884 U CN 221217884U CN 202322803157 U CN202322803157 U CN 202322803157U CN 221217884 U CN221217884 U CN 221217884U
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China
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laterite
nickel ore
neutralization
ore leaching
premixing
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CN202322803157.5U
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Inventor
马俊
鲍玉超
邱江
闫俊超
任震
张巍
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Xian Shaangu Power Co Ltd
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Xian Shaangu Power Co Ltd
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    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling

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Abstract

A laterite nickel ore leaching liquid pretreatment mechanism, a neutralization treatment device and a system thereof comprise a premixing tank body, wherein the premixing tank body is a hollow cylinder member; the premixing tank body side wall is connected with a first input pipe, the first input pipe is communicated with the premixing tank body cavity, the lower end of the premixing tank body is coaxially connected with a second input pipe, the second input pipe is communicated with the premixing tank body cavity, and the premixing tank body side wall is provided with an outlet. Through the reasonable arrangement of the component structure, the mixing efficiency is greatly improved, the problem of local overbase phenomenon is solved, the production stability is ensured, and the product quality and the productivity are improved.

Description

Laterite nickel ore leaching liquid pretreatment mechanism, neutralization treatment device and system
Technical Field
The utility model belongs to the technical field of hydrometallurgy, and particularly relates to a laterite nickel ore leaching liquid pretreatment mechanism, a laterite nickel ore leaching liquid neutralization treatment device and a laterite nickel ore leaching liquid neutralization treatment system.
Background
In the laterite-nickel ore wet smelting process, the leaching process mainly comprises a neutralization leaching reaction of metal oxide and sulfuric acid, and the leaching solution impurity removal and product neutralization process mainly comprises a neutralization reaction of metal ion hydrolysis into hydroxide, hydrolysis acid and neutralization of a neutralizing agent. The neutralization reaction process comprises the following steps: pre-neutralization, first-stage iron and aluminum removal, second-stage iron and aluminum removal, first-stage nickel and cobalt precipitation, second-stage nickel and cobalt precipitation, and neutralization and manganese precipitation. In the neutralization reaction process, a neutralizing agent is added to adjust the pH value of the leaching solution, so that the system reaches the hydrolysis pH value of the preset metal ions. The hydroxide precipitate generated by the hydrolysis of metal ions is subjected to solid-liquid separation to separate out impurity metals (or products).
The current production configuration scheme is that neutralization tanks of each neutralization reaction procedure are generally connected in series of 5 stages or 6 stages, so as to finely control the neutralization reaction time and the neutralization progress in stages. The neutralization tanks in series are arranged in a step manner, and the reacted liquid in the neutralization tank 1 automatically flows into the neutralization tank 2 through the chute and then flows to the neutralization tank in the last stage. In the actual production process, a neutralization tank is started to stir, leaching liquid from the upstream is pumped into a neutralization impurity removal first tank in the process through an upstream discharge pump, a neutralizing agent is added into the tank through a pipe orifice of a top cover of the neutralization tank, and the adding amount of the neutralizing agent in the stage is controlled by detecting the pH value of an overflow liquid outlet of the neutralization tank.
In the existing laterite-nickel ore wet smelting production process, the defects of the existing equipment and method in the neutralization reaction process are mainly that: firstly, the neutralizer is easy to cause blockage and scaling of pipelines and spray heads, so that neutralizer distributor equipment cannot be used in actual production; secondly, a mode of filling a neutralizing agent into a top pipeline is adopted, the neutralizing agent is mixed on the upper surface in the reaction tank, and the mixing is uneven; third, the reaction process produces a gas foam, causing the neutralizing agent to float on top of the foam, preventing rapid mixing of the neutralizing agent with the solution. All three conditions finally lead to local over-alkali in the neutralization reaction process of the neutralization tank, so that nickel cobalt metal is lost, and the product yield is reduced.
Disclosure of Invention
Aiming at the problems, the utility model aims to provide a laterite nickel ore leaching liquid pretreatment mechanism, a neutralization treatment device and a system, which greatly improve the mixing efficiency, solve the problem of local overbasing phenomenon, ensure the stability of production and improve the product quality and the productivity through reasonable arrangement of component structures.
In order to achieve the above purpose, the technical scheme adopted by the utility model comprises the following steps:
the laterite nickel ore leaching liquid pretreatment mechanism comprises a premixing tank body, wherein the premixing tank body is a hollow column member; the premixing tank body side wall is connected with a first input pipe, the first input pipe is communicated with the premixing tank body cavity, the lower end of the premixing tank body is coaxially connected with a second input pipe, the second input pipe is communicated with the premixing tank body cavity, and the premixing tank body side wall is provided with an outlet.
Preferably, the stirring device also comprises a stirring component coaxially arranged in the inner cavity of the premixing tank body.
Preferably, the foam removing device also comprises a foam removing component coaxially arranged at the upper part of the inner cavity of the premixing groove body.
Preferably, the premixing tank body cavity is sealed.
The utility model discloses a laterite-nickel ore leaching liquid neutralization treatment device, which comprises a neutralization tank and also comprises a laterite-nickel ore leaching liquid pretreatment mechanism disclosed by the utility model, wherein a third input pipe for communicating an inner cavity of the premixing tank with an inner cavity of the neutralization tank is connected between the premixing tank body and the neutralization tank.
Preferably, the inlet of the third input pipe is connected with the outlet of the side wall of the premixing tank body, and the outlet of the third input pipe is connected with the inlet of the upper end of the side wall of the neutralization tank.
Preferably, the outlet at the lower end of the side wall of the neutralization tank is connected with an output pipe of the neutralization tank.
The utility model discloses a laterite-nickel ore leaching liquid neutralization treatment system, which comprises at least 2 laterite-nickel ore leaching liquid neutralization treatment devices disclosed by the utility model, wherein the at least 2 laterite-nickel ore leaching liquid neutralization treatment devices are sequentially connected in series, a serial pipe is connected between every two adjacent laterite-nickel ore leaching liquid neutralization treatment devices, an inlet of the serial pipe is connected with an outlet at the lower end of the side wall of a previous neutralization tank, and an outlet of the serial pipe is connected with a second input pipe below a next premixing tank body.
Preferably, the outlet at the lower end of the side wall of the last neutralization tank is connected with a neutralization tank output pipe.
Preferably, the neutralization treatment device for the laterite nickel ore leaching liquid comprises 5 laterite nickel ore leaching liquid disclosed by the utility model, which are sequentially connected in series.
Compared with the prior art, the utility model has the advantages that:
(1) According to the laterite-nickel ore leaching liquid pretreatment mechanism, through reasonable arrangement of the component structure, when the mechanism is applied to the laterite-nickel ore leaching liquid pretreatment device, the mixing efficiency is greatly improved, the occurrence of local overbasing phenomenon is solved, the production stability is ensured, and the product quality and the productivity are improved.
(2) According to the laterite nickel ore leaching liquid pretreatment mechanism, through reasonable arrangement of the component structure, bubbles are easy to generate in the rapid stirring process of the stirring component according to the characteristics of the neutralizer, foam clusters are formed and continuously rise, the foam clusters can be rapidly broken by the foam removing component at the upper part of the inner cavity of the mixing tank body, the neutralizer is prevented from floating on the foam, rapid mixing of the neutralizer and the solution is prevented, and meanwhile, particles wrapped by the foam are prevented from entering the mechanical seal of the top stirring device, so that the sealing device is damaged, and the service life of the stirring device is shortened.
(3) According to the laterite nickel ore leaching liquid neutralization treatment device, through reasonable arrangement of the component structure, the liquid inlet at the bottom of the premixing tank body is vertically mixed with the side neutralization agent, then the mixed liquid is in opposite-impact contact with the liquid inlet at the lower part through the stirring component, the paddle of the stirring component rotates at a high speed, the mixed liquid is rapidly and uniformly mixed with the neutralization agent, and then the mixed liquid is sent into the neutralization tank for neutralization reaction through the third input pipe, so that the mixing efficiency is greatly improved, the problem of local overbasing is solved, the production stability is ensured, and the product quality and the productivity are improved.
(4) According to the laterite-nickel ore leaching liquid neutralization treatment system, the whole scheme adopts the laterite-nickel ore leaching liquid pretreatment mechanism, so that leaching liquid and a neutralizing agent can be quickly and uniformly mixed, the loss of main metal elements caused by partial overbasing is avoided, the neutralization reaction time and the neutralization progress can be finely controlled in stages in the whole process of the neutralization process, the production stability of a production line is ensured, and the product quality and the productivity are ensured.
Drawings
The accompanying drawings are included to provide a further understanding of the utility model, and are incorporated in and constitute a part of this specification, illustrate the utility model and together with the description serve to explain, without limitation, the utility model. In the drawings:
Fig. 1 is a schematic structural view of a laterite-nickel ore leaching solution pretreatment mechanism, a neutralization treatment device and a system of the utility model.
The reference numerals in the figures are as follows:
0 neutralization tank, 1 premixing tank body, 2 first input pipe, 3 second input pipe, 4 defoaming component, 5 stirring component, 6 third input pipe, 7 neutralization tank output pipe, 8 series pipe
Detailed Description
The utility model is not limited to the following specific embodiments, and all equivalent changes made on the basis of the technical scheme of the utility model fall within the protection scope of the utility model.
It should be noted that directional terms mentioned herein, such as "inner cavity", "upper portion", "side wall", etc., are consistent with a specific direction on a paper surface in the drawings of the specification or a corresponding direction of a space shown in the drawings; all parts and devices of the present utility model, unless otherwise specified, are known in the art.
Example 1
The embodiment discloses a laterite nickel ore leaching liquid pretreatment mechanism, which comprises a premixing tank body 1, wherein the premixing tank body 1 is a hollow cylinder member; the side wall of the premixing tank body 1 is connected with a first input pipe 2, the first input pipe 2 is communicated with the inner cavity of the premixing tank body 1, the lower end of the premixing tank body 1 is coaxially connected with a second input pipe 3, the second input pipe 3 is communicated with the inner cavity of the premixing tank body 1, and the side wall of the premixing tank body 1 is provided with an outlet;
The function is as follows: the pre-mixing tank body 1 is used for bearing the whole laterite nickel ore leaching liquid pretreatment mechanism, the first input pipe 2 is used for conveying the neutralizing agent to the inner cavity of the pre-mixing tank body 1, the second input pipe 3 is used for conveying the upstream leaching liquid to the inner cavity of the pre-mixing tank body 1, namely, the upstream leaching liquid is vertically contacted and evenly mixed by the bottom inlet liquid and the side neutralizing agent and then is conveyed into downstream equipment (a neutralization tank), and when the device is applied to the laterite nickel ore leaching liquid pretreatment device, the mixing efficiency is greatly improved, the problem of local alkali-exceeding is solved, the production stability is ensured, and the product quality and the productivity are improved.
The inner cavity of the premixing tank body 1 in the embodiment is always in a sealed state.
Specifically, the stirring device also comprises a stirring member 5 coaxially arranged in the inner cavity of the mixing tank body 1;
The function is as follows: when in use, the stirring member 5 is in opposite-impact contact with the leaching solution in the premixing tank body 1, the blades of the stirrer rotate at high speed, and the mixed solution is rapidly stirred, so that the neutralizer and the leaching solution are rapidly and uniformly mixed.
Wherein the stirring member 5 is preferably a top-inserted ribbon mechanical stirring device.
Specifically, the foam removing device also comprises a foam removing component 4 coaxially arranged at the upper part of the inner cavity of the mixing tank body 1;
The function is as follows: according to the characteristic of neutralizer, at stirring component 5 rapid stirring in-process, the bubble of easily producing forms the foam group, and the continuous rising removes foam group, and the foam component 4 of removing on mixing tank body 1 inner chamber upper portion can break the foam group fast, avoids the neutralizer to float on the foam, has hindered the rapid mixing of neutralizer and solution, avoids the granule that the foam was wrapped up in simultaneously to get into top agitating unit's mechanical seal inside to destroy sealing device, reduce agitating unit's life.
Among them, the defoaming member 4 is preferably a drawer type wave-shaped wire mesh defoamer.
Example 2
The embodiment discloses a laterite-nickel ore leaching liquid neutralization treatment device, which comprises a neutralization tank 0 and the laterite-nickel ore leaching liquid pretreatment mechanism disclosed in the embodiment 1, wherein a third input pipe 6 for communicating the inner cavity of the premixing tank 1 with the inner cavity of the neutralization tank 0 is connected between the premixing tank 1 and the neutralization tank 0;
The function is as follows: the bottom feed liquor of the premixing tank body 1 is vertically mixed with the side-feeding neutralizing agent, the mixing liquor is in opposite-impact contact with the lower feed mixed liquor through the stirring component 5, the paddle of the stirring component 5 rotates at a high speed, the mixing liquor is rapidly and uniformly stirred, the neutralizing agent and the solution are fed into the neutralization tank 0 for neutralization reaction through the third input pipe 6 after being rapidly and uniformly mixed, the mixing efficiency is greatly improved, the occurrence of local overbase phenomenon is solved, the production stability is ensured, and the product quality and the productivity are improved.
The inlet of the third input pipe 6 disclosed in this embodiment is connected to the outlet of the sidewall of the premixing tank body 1, the outlet of the third input pipe 6 is connected to the inlet of the upper end of the sidewall of the neutralization tank 0, and the outlet of the lower end of the sidewall of the neutralization tank 0 is connected to the outlet of the neutralization tank 7, i.e. the leached mixed solution after the neutralization reaction is sent out from the outlet of the neutralization tank 7 to enter the downstream process.
Example 3
The embodiment discloses a laterite-nickel ore leaching liquid neutralization treatment system which is characterized by comprising at least 2 laterite-nickel ore leaching liquid neutralization treatment devices disclosed in embodiment 2, wherein the at least 2 laterite-nickel ore leaching liquid neutralization treatment devices are sequentially connected in series, a serial pipe 8 is connected between every two adjacent laterite-nickel ore leaching liquid neutralization treatment devices, an inlet of the serial pipe 8 is connected with an outlet at the lower end of the side wall of a previous neutralization tank 0, and an outlet of the serial pipe 8 is connected with a second input pipe 3 below a next premixing tank 1;
In this embodiment, 5 stages are connected in series, that is, the laterite-nickel ore leaching solution neutralization treatment device disclosed in embodiment 2 includes that 5 stages are sequentially connected in series, leaching solution from upstream is sent into a premixing tank body 1 of the first stage laterite-nickel ore leaching solution neutralization treatment device to be vertically contacted with a neutralizing agent for pre-mixing treatment, and after being stirred at a high speed, the leaching solution is quickly mixed, the leaching solution enters a neutralization tank 0 for neutralization reaction, and after the pH value of the outlet of the tank is met, the leaching solution enters a premixing tank body 1 of the second stage laterite-nickel ore leaching solution neutralization treatment device, the steps are repeated to sequentially pass through three stages, four stages and five stages of laterite-nickel ore leaching solution neutralization treatment devices, and finally, after the neutralization tank 0 of the five stages of laterite-nickel ore leaching solution neutralization treatment devices meets the pH value of the outlet, the leaching solution enters a downstream process. The whole scheme adopts the laterite nickel ore leaching liquid pretreatment mechanism, can lead the leaching liquid and the neutralizer to be quickly and evenly mixed, avoids the loss of main metal elements caused by partial overalkaline, can finely control the neutralization reaction time and the neutralization progress in stages in the whole process of neutralization, ensures the production stability of a production line, and ensures the quality and the productivity of products.
Specifically, the outlet of the lower end of the side wall of the last neutralization tank 0 is connected with a neutralization tank output pipe 7, namely, the neutralization tank 0 of the five-stage laterite-nickel ore leaching liquid neutralization treatment device enters the downstream working procedure from the neutralization tank output pipe 7 after meeting the pH value of the outlet.
The preferred embodiments of the present disclosure have been described in detail above with reference to the accompanying drawings, but the present disclosure is not limited to the specific details of the embodiments described above, and various simple modifications may be made to the technical solutions of the present disclosure within the scope of the technical concept of the present disclosure, and all the simple modifications belong to the protection scope of the present disclosure.
In addition, the specific features described in the foregoing embodiments may be combined in any suitable manner, and in order to avoid unnecessary repetition, the present disclosure does not further describe various possible combinations.
Moreover, any combination of the various embodiments disclosed in the present embodiment can be made, so long as it does not deviate from the idea of the present disclosure, and it should also be regarded as the invention of the present disclosure.

Claims (10)

1. The laterite nickel ore leaching liquid pretreatment mechanism is characterized by comprising a premixing tank body (1), wherein the premixing tank body (1) is a hollow column member;
The side wall of the premixing groove body (1) is connected with a first input pipe (2), the first input pipe (2) is communicated with the inner cavity of the premixing groove body (1), the lower end of the premixing groove body (1) is coaxially connected with a second input pipe (3), the second input pipe (3) is communicated with the inner cavity of the premixing groove body (1), and the side wall of the premixing groove body (1) is provided with an outlet.
2. The laterite-nickel ore leaching solution pretreatment mechanism according to claim 1, further comprising a stirring member (5) coaxially arranged in the inner cavity of the premixing tank body (1).
3. The pretreatment mechanism for laterite-nickel ore leaching solution as claimed in claim 2, further comprising a defoaming member (4) coaxially provided at the upper part of the inner cavity of the premixing tank body (1).
4. A laterite nickel ore leaching liquor pretreatment mechanism as claimed in any one of claims 1 to 3, wherein the premixing tank (1) is internally sealed.
5. The laterite-nickel ore leaching liquid neutralization treatment device comprises a neutralization tank (0), and is characterized by further comprising the laterite-nickel ore leaching liquid pretreatment mechanism according to any one of claims 1-4, wherein a third input pipe (6) for communicating the inner cavity of the premixing tank (1) with the inner cavity of the neutralization tank (0) is connected between the premixing tank (1) and the neutralization tank (0).
6. The laterite-nickel ore leaching liquid neutralization treatment device according to claim 5, wherein an inlet of the third input pipe (6) is connected with an outlet of the side wall of the premixing tank body (1), and an outlet of the third input pipe (6) is connected with an inlet of the upper end of the side wall of the neutralization tank (0).
7. The neutralization treatment device for the laterite-nickel ore leaching solution according to any one of claims 5 or 6, wherein an outlet at the lower end of the side wall of the neutralization tank (0) is connected with a neutralization tank output pipe (7).
8. A laterite-nickel ore leaching liquid neutralization treatment system, which is characterized by comprising at least 2 laterite-nickel ore leaching liquid neutralization treatment devices according to any one of claims 5-6, wherein the at least 2 laterite-nickel ore leaching liquid neutralization treatment devices are sequentially connected in series, a serial pipe (8) is connected between two adjacent laterite-nickel ore leaching liquid neutralization treatment devices, an inlet of the serial pipe (8) is connected with an outlet at the lower end of the side wall of a last neutralization tank (0), and an outlet of the serial pipe (8) is connected with a second input pipe (3) below a next premixing tank body (1).
9. The laterite-nickel ore leaching liquid neutralization treatment system according to claim 8, wherein the outlet at the lower end of the side wall of the last neutralization tank (0) is connected with a neutralization tank output pipe (7).
10. The laterite-nickel ore leaching solution neutralization treatment system according to any one of claims 8 and 9, comprising 5 laterite-nickel ore leaching solution neutralization treatment devices according to any one of claims 5 to 6, which are sequentially connected in series.
CN202322803157.5U 2023-10-18 2023-10-18 Laterite nickel ore leaching liquid pretreatment mechanism, neutralization treatment device and system Active CN221217884U (en)

Priority Applications (1)

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CN202322803157.5U CN221217884U (en) 2023-10-18 2023-10-18 Laterite nickel ore leaching liquid pretreatment mechanism, neutralization treatment device and system

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CN202322803157.5U CN221217884U (en) 2023-10-18 2023-10-18 Laterite nickel ore leaching liquid pretreatment mechanism, neutralization treatment device and system

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CN221217884U true CN221217884U (en) 2024-06-25

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