DE102004029328A1 - Cosmetic preparation, useful as e.g. foamable cleaning preparation and shampoo, comprises transparent or translucent gel forming aqueous phase (comprising e.g. polyacrylate thickener) and floating droplets in the aqueous phase - Google Patents

Abstract

Cosmetic preparation comprises a transparent or translucent gel forming aqueous phase (comprising polyacrylate thickener and/or carrageenan thickener) and floating droplets in the aqueous phase, where the droplets are formed from a cosmetic emulsion. An independent claim is also included for preparation of (I).

Description

The The present invention relates to a cosmetic of a transparent one or translucent gel in which emulsion droplets float.

Of the Wish, nice and looking attractive, is inherently rooted in man. Even if the ideal of beauty has undergone changes over time, so is the pursuit of a flawless appearance always been the goal of the people. A substantial portion of one beautiful and attractive looks while the condition and appearance of the skin.

In order to the skin can fulfill its biological functions to the full extent, it requires regular cleaning and care. The cleaning of the skin serves the removal of Dirt, sweat and leftovers Dead skin particles that provide an ideal breeding ground for pathogens and parasites of all kinds. Cosmetic cleansing products contain in the Usually washing-active substances such as soaps and surfactants. you will be mostly water-based in the form of thickened gels prepared and presented. Skin care products, usually creams, ointments or lotions, are used usually moistening and refatting of the skin. Often are added to them active ingredients that regenerate the skin and for example, their premature aging (e.g., the emergence of Pucker, To prevent and reduce wrinkles).

cosmetic, Surfactant-containing cleaning preparations often provide externally uniform, homogeneous preparations These are usually transparent or translucent. They will however increasingly perceived by consumers as monotonous and boring. To the preparations for To make the user more attractive, effect substances can be added to them become. These are usually solid capsules, peeling particles and glitter. However, capsules, peeling particles and glitter have the Disadvantage that they damage the uppermost skin layers and pose a significant burden in wastewater, as a rule are not biodegradable.

Around with cosmetic, surfactant-containing cleaning products a sufficient To achieve cosmetic care effect, the preparations must be cosmetic Active and care substances are added. Are such active and Nursing substances hydrophobic or water sensitive or performs their Incorporation into a haze of usually transparent-gelatinous Preparation remains according to the prior art as a way out only the Encapsulation of substances by means of solid capsules. The usual However, capsules containing active ingredients are often considered by the consumer to be too felt hard in the application. Furthermore, open in the application only part of the capsules, so that only insufficient quantities with the Skin are effectively brought into contact. Sharp-edged fragments opened Scratch capsules and damage when rubbing the preparation on the skin the upper layers of skin.

The Object of the present invention was therefore to overcome the disadvantages of State of the art eliminate and environmentally friendly, visually to develop attractive water-based formulations with which also water-sensitive and / or hydrophobic active ingredients and care substances incorporate into the preparations in cosmetically effective amounts to let. Furthermore, the preparations should have a lower abrasive Have effect, as the preparations of the prior art.

• a) einer transparenten oder transluzenten, gelförmigen, wässrigen Phase enthaltend Polyacrylatverdicker und/oder Carrageenanverdicker sowie
• b) in dieser wässrigen Phase schwebenden Tröpfchen, wobei die Tröpfchen aus einer kosmetischen Emulsion gebildet werden.

Surprisingly, the tasks are solved by a cosmetic preparation that is formed

• a) a transparent or translucent, gel-like, aqueous phase comprising polyacrylate thickener and / or carrageenan thickener and
• b) droplets floating in said aqueous phase, said droplets being formed from a cosmetic emulsion.

According to the invention preferred is a transparent, gel-like, aqueous phase.

The preparations according to the invention are over it Exceptionally stable (stable to transport, storage stable, temperature stable). This was special therefore for surprising the expert, since the emulsion itself contains its own water phase, the not in contrast to the expectations of the expert, with the gel-watery Phase united, but rather obtained as an independent phase of the emulsion remains.

This phenomenon has been observed even in O / W emulsions, ie emulsions with an outer aq phase, observed.

The emulsion droplets remain stable even in the gel-like, aqueous phase, if these one or more detergent substances such as soaps or surfactants contains. This was particularly surprising because the expert actually expected that the washing-active Substances compete with the emulsifiers of the emulsion and the oil phase The emulsion would dissolve over time by micelle formation.

Although the describes DE 101 11 536 thickened aqueous preparations containing liquid droplets, but this document could not point the way to the present invention.

Furthermore, the describes DE 197 14 424 acrylate-alkyl acrylate thickened detergent compositions in which gaseous, solid and or liquid objects may be embedded in the gels. Again, this document could not point the way to vorliegneden invention.

Favorable Gelling agent in the context of the present invention is carrageenan, an extract from North Atlantic, to the Florideen counting red algae (Chondrus crispus u. Gigartina stellata).

Frequently becomes the term carrageenan for the dried algae product and carrageenan are used for the extract from this. According to the invention advantageous can Both carrageenan and carrageenan are used. Under the The term "carrageenan" according to the invention is therefore both understood the actual Carrageenan as well as Carrageen.

The carrageenan precipitated from the hot-water extract of the algae is a colorless to sand-colored powder with a molecular weight range of 100,000-800,000 and a sulphate content of about 25%. Carrageenan, which is very slightly soluble in warm water; Upon cooling, a thixotropic gel forms, even if the water content is 95-98%. The strength of the gel is effected by the double helix structure of the carrageenan. Carrageenan has three main components: The gel-forming κ fraction consists of D-galactose-4-sulfate and 3,6-anhydro-α-D-galactose, which are alternately glycosidically linked in the 1,3- and 1,4-positions (Agar, in contrast, contains 3,6-anhydro-α-L-galactose). The non-gelling λ-fraction is composed of 1,3-glycosidically linked D-galactose-2-sulfate and 1,4-linked D-galactose-2,6-disulfate residues u. easily soluble in cold water. The ι-carrageenan composed of D-galactose-4-sulfate in 1,3-bond and 3,6-anhydro-α-D-galactose-2-sulfate in 1,4-bond is both water-soluble and gel-forming. Other carrageenan types are also denoted by Greek letters: α, β, γ, μ, ν, ξ, π, ω, χ. The type of cations present (K ⁺ , NH ₄ ⁺ , Na ⁺ , Mg ²⁺ , Ca ²⁺ ) also influences the solubility of the carrageenans.

Polyacrylates are also advantageous for use in the context of the present invention gelators. According to the invention advantageous polyacrylates are acrylate-alkyl acrylate copolymers, in particular those from the group of so-called carbomers or carbopols (Carbopol ^® is actually a registered trademark of NOVEON Inc.) are selected. In particular, the acrylate-alkyl acrylate copolymers which are advantageous according to the invention have the following structure:

In this put R 'one long-chain alkyl radical and x and y are numbers which the respective stoichiometric Symbolize the proportion of the respective comonomers.

Preferred are acrylate copolymers and / or acrylate-alkyl acrylate copolymers sold under the trade names Carbopol ^® 1382, Carbopol ^® 981 and Carbopol ^® 5984, Aqua SF-1 from NOVEON Inc. or as Aculyn ^® 33 from International Specialty Products Corp. are available.

Further advantageous are copolymers of C10-30-alkyl acrylates and a or more monomers of acrylic acid, methacrylic acid or their esters cross-linked with an allyl ether of sucrose or an allyl ether of pentaerythritol.

Advantageous are compounds which have the INCI name "Acrylates / C 10-30 Alkyl Acrylates Crosspolymer "wear. Particularly advantageous are those under the trade names Pemulen TR1 and Pemulen TR2 available from NOVEON Inc.

Also advantageous are compounds having the INCI name "acrylates / C12-24 pareth-25 acrylate copolymer" (under the trade names Synthalen ^® W2000 in 3V Inc.), the methacrylate, the INCI name "acrylates / steareth-20 copolymer "(under the trade names Aculyn ^® 22 available from International Specialty Products Corp.), which the INCI name" acyalates / steareth-20 itaconate copolymer "(available under the trade names Structure 2001 ^® available from National Starch), the INCI the name "acrylates / aminoacrylates / C10-30 alkyl PEG-20 itaconate copolymer" (available under the trade name Structure Plus ^® from National Starch) and similar polymers.

According to the invention preferred embodiments of the present invention are characterized in that as Polyacrylate thickening acrylate-alkyl acrylate copolymers used become.

The particularly according to the invention preferred hydrocolloids are: acrylates copolymer (AQUA SF-1) and Acrylates / C 10-30 alkyl acrylate cross polymers (Carbopol ETD 2020).

It is advantageous according to the invention when the concentration of polyacrylate thickener in the gel, aqueous Phase from 0.5 to 5% by weight and preferably from 1.0 to 4.0% by weight, in each case based on the total weight of the gel-like, aqueous phase.

It is advantageous according to the invention when the concentration of carrageenan thickener in the gel, aqueous Phase from 0.01 to 2% by weight and preferably from 0.1 to 0.5% by weight, in each case based on the total weight of the gel-like, aqueous phase.

According to the invention advantageous embodiments The present invention is characterized in that gel aqueous Phase surfactants in a concentration of 1 to 30% by weight, based on the total weight of the gel, aqueous Phase, contains. In this case, a concentration of surfactants of 10 to 20% by weight, based on the total weight of the gelled aqueous phase, according to the invention preferably.

According to the invention advantageous can both anionic, cationic, nonionic and zwitterionic Surfactants are used.

• • Acylglutamate, insbesondere Natriumacylglutamat
• • Sarcosinate, beispielsweise Myristoyl Sarcosin, TEA-lauroyl Sarcosinat, Natriumlauroylsarcosinat und Natriumcocoylsarkosinat,

Sulfonsäuren und deren Salze, wie

• • Acylisethionate, z.B. Natrium-/Ammoniumcocoylisethionat,
• • Sulfosuccinate, beispielsweise Dioctylnatriumsulfosuccinat, Dinatriumlaurethsulfosuccinat, Dinatriumlaurylsulfosuccinat und Dinatriumundecylenamido MEA-Sulfosuccinat, Dinatrium PEG-5 Laurylcitratsulfosuccinat und Derivate,

sowie Schwefelsäureester, wie

• • Alkylethersulfat, beispielsweise Natrium-, Ammonium-, Magnesium-, MIPA-, TIPA-Laurethsulfat, Natriummyrethsulfat und Natrium C_12-13 Parethsulfat,
• • Alkylsulfate, beispielsweise Natrium-, Ammonium- und TEA- Laurylsulfat.

Advantageous washing-active anionic surfactants for the purposes of the present invention are acylamino acids and their salts, such as

• Acylglutamates, especially sodium acylglutamate
• Sarcosinates, for example myristoyl sarcosine, TEA lauroyl sarcosinate, sodium lauroyl sarcosinate and sodium cocoyl sarcosinate,

Sulfonic acids and their salts, such as

• Acyl isethionates, eg sodium / ammonium cocoyl isethionate,
• Sulfosuccinates, for example dioctyl sodium sulphosuccinate, disodium laureth sulphosuccinate, disodium lauryl sulphosuccinate and disodium undecylenamido MEA sulphosuccinate, disodium PEG-5 lauryl citrate sulphosuccinate and derivatives,

and sulfuric acid esters, such as

• Alkyl ether sulfate, for example, sodium, ammonium, magnesium, MIPA, TIPA laureth sulfate, sodium myreth sulfate and sodium C _12-13 pareth sulfate,
• • Alkyl sulfates, for example sodium, ammonium and TEA lauryl sulfate.

advantageous Washing-active cationic surfactants in the context of the present invention are quaternary surfactants. quaternary Surfactants contain at least one N atom containing 4 alkyl or aryl groups covalently linked. For example, alkylbetaine, Alkylamidopropylbetaine and Alkylamidopropylhydroxysultaine.

• • Acyl-/dialkylethylendiamine, beispielsweise Natriumacylamphoacetat, Dinatriumacylamphodipropionat, Dinatriumalkylamphodiacetat, Natriumacylamphohydroxypropylsulfonat, Dinatriumacylamphodiacetat und Natriumacylamphopropionat,

Advantageous washing-active amphoteric surfactants in the context of the present invention are

• Acyl / dialkylethylenediamines, for example sodium acylamphoacetate, disodium acylamphodipropionate, disodium alkylamphodiacetate, sodium acylamphohydroxypropylsulfonate, disodium acylamphodiacetate and sodium acylamphopropionate,

• • Alkanolamide, wie Cocamide MEA/DEA/MIPA,
• • Ester, die durch Veresterung von Carbonsäuren mit Ethylenoxid, Glycerin, Sorbitan oder anderen Alkoholen entstehen,
• • Ether, beispielsweise ethoxylierte Alkohole, ethoxyliertes Lanolin, ethoxylierte Polysiloxane, propoxylierte POE Ether und Alkylpolyglycoside wie Laurylglucosid, Decylglycosid und Cocoglycosid.

Advantageous washing-active nonionic surfactants in the context of the present invention are

• Alkanolamides, such as cocamide MEA / DEA / MIPA,
• Esters formed by the esterification of carboxylic acids with ethylene oxide, glycerol, sorbitan or other alcohols,
• Ethers, for example ethoxylated alcohols, ethoxylated lanolin, ethoxylated polysiloxanes, propoxylated POE ethers and alkyl polyglycosides such as lauryl glucoside, decyl glycoside and cocoglycoside.

• • Taurate, beispielsweise Natriumlauroyltaurat und Natriummethylcocoyltaurat,
• • Ether-Carbonsäuren, beispielsweise Natriumlaureth-13 Carboxylat und Natrium PEG-6 Cocamide Carboxylat, Natrium PEG-7-Olivenöl-Carboxylat
• • Phosphorsäureester und Salze, wie beispielsweise DEA-Oleth-10 Phosphat und Dilaureth-4 Phosphat,
• • Alkylsulfonate, beispielsweise Natriumcocosmonoglyceridsulfat, Natrium C_12-13 Olefinsulfonat, Natriumlaurylsulfoacetat und Magnesium PEG-3 Cocamidsulfat.

Further advantageous anionic surfactants are

• Taurates, for example sodium lauroyl taurate and sodium methyl cocoyl taurate,
• Ether carboxylic acids, for example sodium laureth-13 carboxylate and sodium PEG-6 cocamide carboxylate, sodium PEG-7 olive oil carboxylate
• Phosphoric acid esters and salts, such as DEA-oleth-10 phosphate and dilaureth-4 phosphate,
• Alkyl sulfonates, for example sodium coconut monoglyceride sulfate, sodium C _12-13 olefinsulfonate, sodium lauryl sulfoacetate and magnesium PEG-3 cocamide sulfate.

• • N-Alkylaminosäuren, beispielsweise Aminopropylalkylglutamid, Alkylaminopropionsäure, Natriumalkylimidodipropionat und Lauroamphocarboxyglycinat und N-Kokosfettsäureamidoethyl-N-hydroxyethylglycinat Natriumsalze und deren Derivate.

Further advantageous amphoteric surfactants are

• N-alkylamino acids, for example aminopropylalkylglutamide, alkylaminopropionic acid, sodium alkylimidodipropionate and lauroamphocarboxyglycinate and N-coconut fatty acid amidoethyl-N-hydroxyethylglycinate sodium salts and derivatives thereof.

Further advantageous nonionic surfactants are alcohols.

• • Acylglutamate wie Di-TEA-palmitoylaspartat und Natrium Caprylic/Capric Glutamat,
• • Acylpeptide, beispielsweise Palmitoyl hydrolysiertes Milchprotein, Natrium Cocoyl hydrolysiertes Soja Protein und Natrium-/Kalium Cocoyl hydrolysiertes Kollagen

sowie Carbonsäuren und Derivate, wie

• • beispielsweise Laurinsäure, Aluminiumstearat, Magnesiumalkanolat und Zinkundecylenat,
• • Ester-Carbonsäuren, beispielsweise Calciumstearoyllactylat, Laureth-6 Citrat und Natrium PEG-4 Lauramidcarboxylat,
• • Alkylarylsulfonate.

Further suitable anionic surfactants for the purposes of the present invention are further

• Acylglutamates such as di-TEA-palmitoylaspartate and sodium caprylic / capric glutamate,
• Acyl peptides, for example palmitoyl hydrolyzed milk protein, sodium cocoyl hydrolyzed soy protein and sodium / potassium cocoyl hydrolyzed collagen

as well as carboxylic acids and derivatives, such as

• For example, lauric acid, aluminum stearate, magnesium alkoxide and zinc undecylenate,
• Ester carboxylic acids, for example calcium stearoyl lactylate, laureth-6 citrate and sodium PEG-4 lauramide carboxylate,
• • alkylarylsulfonates.

• • Alkylamine,
• • Alkylimidazole,
• • ethoxylierte Amine

insbesondere deren Salze.Further suitable cationic surfactants for the purposes of the present invention are further

• • alkylamines,
• • alkylimidazoles,
• • ethoxylated amines

in particular their salts.

Further suitable nonionic surfactants in the context of the present invention are also amine oxides, such as cocoamidopropylamine oxide.

It Advantageously, the detergent surfactant (s) of the invention is advantageous to choose the group of surfactants which have an HLB value of more than 25, particularly advantageous are those which have an HLB value of more than 35.

According to the invention preferred are alkyl sulfates or alkyl ether sulfates or a surfactant combinations of Alkyl ether sulfates with amphoteric or nonionic surfactants, wherein a surfactant combination of alkyl ether sulfates with Alkylamidopropylbetainen or alkylamphoacetates or alkylpoyglucosides are particularly preferred is. Also particularly preferred are combinations of alkyl ether sulfates with alkylamidopropylbetaines or alkylamphoacetates and acylglutamates.

Particularly according to the invention preferred embodiments The present invention is characterized in that gel aqueous Phase contains sodium lauryl ether sulfate.

It is advantageous in the context of the present invention, when the gel-like aqueous phase according to the invention and the drop-forming emulsion has certain yield strengths and tan δ values.

The yield stress of the invention is considered to be the critical shear stress of the flow curve. It can be determined according to the invention as follows:
The flow curve is measured on a shear stress-controlled rheometer at 25 ° C ± 1 ° C with 25 mm plate / plate geometry at a gap between 0.8 mm and 1.2 mm, filling the structure gently. A suitable constant shear stress time ramp is specified and a corresponding structure recovery time is maintained before the test and the critical shear stress is specified at the maximum of the flow curve.

The Product is carefully removed with a spatula and placed in the meter brought in. The product should not be sheared in order to a destruction or to avoid influencing the structures.

Under a tan δ becomes According to the invention, the quotient from the loss module and the memory module understood.

The tan δ is determined as follows:
The loss and storage modulus are measured by a dynamic frequency test on a shear stress controlled rheometer at 40 ° C ± 1 ° C with a 25 mm plate / plate geometry at a gap between 0.8 mm and 1.2 mm, filling the structure gently. It is carried out according to the prior art, the frequency test with a corresponding structure recovery time before the test and the tan δ in the frequency range between 0.05 rad / s and 3.0 rad / s specified, preferably between 0.08 rad / s and 1, 0 rad / s.

The gel, aqueous Phase has advantageous according to the invention a yield point from 0.5 Pa to 40 Pa, according to the invention preferably a yield point from 0.5 to 20 Pa and, according to the invention, particularly preferably one yield from 1 to 6 Pa.

The have emulsion droplets according to the invention According to the invention advantageous a yield point of 0.5 Pa to 300 Pa, according to the invention preferred a yield point from 0.5 to 100 Pa and, according to the invention, particularly preferably one yield from 1 to 60 Pa.

The gel, aqueous Phase has advantageous according to the invention a tan δ value from 0.02 to 0.8. It is inventively preferred if tan δ between 0.05 and 0.6, with the range of 0.1 to 0.5 being especially is preferred.

The have emulsion droplets according to the invention According to the invention advantageous a tan δ of 0.01 to 0.8. It is inventively preferred if tan δ between 0.01 and 0.6, with the range of 0.1 to 0.5 being especially is preferred.

The Emulsion droplets according to the invention can be advantageous according to the invention in the form of W / O, O / W, W / O / W or O / W / O emulsions. Such formulations can also in the form of a microemulsion (eg a PIT emulsion), a Solid emulsion (i.e., an emulsion formed by solids is stabilized, for. B. a Pickering emulsion or hydrodispersion) be formed. It is inventively preferred if the emulsion droplets in Form of an O / W emulsion.

The gel, aqueous Phase of the preparation and the aqueous phase of the droplet-shaped emulsion in addition to water according to the invention, other Ingredients include, for example, alcohols, diols or polyols low C number, and their ethers, preferably ethanol, isopropanol, Propylene glycol, glycerol, ethylene glycol, ethylene glycol monoethyl or -monobutyl ether, propylene glycol monomethyl, -monoethyl- or monobutyl ether, diethylene glycol monomethyl or monoethyl ether and analogous products, furthermore lower C number alcohols, e.g. ethanol, Isopropanol, 1,2-propanediol and glycerol.

The gel-like, aqueous phase of the preparation and the aqueous phase of the droplet-shaped emulsion may advantageously contain moistening or moisturizing agents (so-called moisturizers). Advantageous moisturizing agents for the purposes of the present invention are, for example, glycerol, lactic acid and / or lactates, in particular sodium lactate, butylene glycol, propylene glycol, biosaccharide gum-1, glycine soya, ethylhexyloxyglycerol, pyrrolidonecarboxylic acid and urea. Furthermore, it is particularly advantageous to use polymeric moisturizers from the group of water-soluble and / or water-swellable and / or with the aid of Water gelable polysaccharides to use. Hyaluronic acid, chitosan and / or a fucose-rich polysaccharide, for example, which are filed in the Chemical Abstracts under the registry number 178463-23-5 and z. B. under the name Fucogel ^® 1000 of the company SOLABIA SA is available.

Lies the potty emulsion according to the invention in the form of a W / O emulsion can, as advantageous according to the invention W / O emulsifiers surface-active Compounds are used which have an HLB value of 3 to 8.

According to the invention, preference is given to using one or more W / O emulsifiers selected from the group of the following compounds:
Sorbitan stearate, sorbitan oleate, lecithin, glyceryl lanolate, lanolin, ozokerite, hydrogenated castor oil, glyceryl isostearate, polyglyceryl-3-oleate, wool wax acid mixtures, wool wax alcohol mixtures, pentaerythritol isostearate, polyglyceryl-3-diisostearate, methyl glucose dioleate, PEG-7 hydrogenated castor oil, polyglyceryl-4-isostearate, Hexyl laurate, acrylate / C10-30 alkyl acrylate crosspolymer, sorbitan isostearate, poloxamer 101, polyglyceryl-2-dipolyhydroxystearate, polyglyceryl-4-dipolyhydroxystearate, PEG-30 dipolyhydroxystearate, diisostearoylpolyglyceryl-3-diisostearate, polyglyceryl-3-dipolyhydroxystearate, polyglyceryl-3 dioleate.

Lies the potty emulsion according to the invention in the form of an O / W emulsion can, as advantageous according to the invention O / W emulsifiers surface-active Compounds are used which have an HLB value of 8 to 18 exhibit.

• i) Glycerylstearatcitrat,
• ii) Cetearylalkohol + PEG-40 hydriertes Rizinusöl + Natriumcetearylsulfat + Glycerylstearat,
• iii) Polyglyceryl-3-methylglucosedistearat,
• iv) Stearinsäure,
• v) Kaliumcetylphosphat,
• vi) Glycerylmonostearat

enthält.Embodiments of the present invention which are preferred according to the invention are characterized in that the droplet-shaped O / W emulsion comprises one or more emulsifier / emulsifier systems selected from the group

• i) glyceryl stearate citrate,
• ii) cetearyl alcohol + PEG-40 hydrogenated castor oil + sodium cetearyl sulfate + glyceryl stearate,
• iii) polyglyceryl-3-methyl glucose distearate,
• iv) stearic acid,
• v) potassium cetyl phosphate,
• vi) glyceryl monostearate

contains.

The oil phase of emulsion according to the invention is chosen favorably from the group of polar oils, for example from the group of lecithins and fatty acid triglycerides, namely the triglycerol esters of saturated and / or unsaturated branched and / or unbranched alkanecarboxylic acids of a chain length of 8 to 24, in particular 12 to 18 carbon atoms. The fatty acid triglycerides may be, for example chosen favorably are selected from the group of synthetic, semisynthetic and natural oils, such as z. B. cocoglyceride, olive oil, Sunflower oil, Soybean oil, Peanut oil, rapeseed oil, almond oil, palm oil, coconut oil, castor oil, wheat germ oil, grapeseed oil, thistle oil, evening primrose oil, macadamia nut oil and the like more.

According to the invention advantageous are also z. Natural Waxes of animal and vegetable origin, such as Beeswax and other insect waxes as well as berry wax, shea butter and / or Lanolin (wool wax).

Further advantageous polar oil components can for the purposes of the present invention are further selected from the group of Esters of saturated and / or unsaturated, branched and / or unbranched alkanecarboxylic acids of a chain length of 3 to 30 carbon atoms and saturated and / or unsaturated, branched and / or unbranched alcohols of a chain length of 3 to 30 carbon atoms and from the group of esters of aromatic carboxylic acids and saturated and / or unsaturated, branched and / or unbranched alcohols of a chain length of 3 to 30 carbon atoms. Such ester oils can then chosen advantageous are from the group octyl palmitate, octyl cocoate, octyl isostearate, Octyldodeceyl myristate, octyldodecanol, cetearyl isononanoate, isopropyl myristate, Isopropyl palmitate, isopropyl stearate, isopropyl oleate, n-butyl stearate, n-hexyl laurate, n-decyl oleate, isooctyl stearate, isononyl stearate, isononyl isononanoate, 2-ethylhexyl palmitate, 2-ethylhexyl laurate, 2-hexyldecyl stearate, 2-octyl dodecyl palmitate, Stearylheptanoate, oleyl oleate, oleyl erucate, erucyl oleate, erucyl erucate, Tridecyl stearate, tridecyl trimellitate, as well as synthetic, semisynthetic and natural Mixtures of such esters, such as. B. jojoba oil.

Furthermore, the oil phase of the emulsion according to the invention can be advantageously selected from the group the dialkyl ethers and dialkyl carbonates, are advantageous for. B. dicaprylyl ether (Cetiol OE) and / or dicaprylyl, for example, that available under the trade name Cetiol CC in the company. Cognis.

It is further preferred that the oil component from the group consisting of isoeicosane, neopentyl glycol, propylene glycol dicaprylate / dicaprate, caprylic / capric / diglyceryl succinate, butylene glycol dicaprylate / dicaprate, cocoglycerides (z. B. Myritol ^® 331 from Henkel), C _12-13 alkyl lactate , Di-C _12-13 alkyl tartrate, triisostearin, dipentaerythrityl hexacaprylate / hexacaprate, propylene glycol monoisostearate, tricaprylin, dimethyl isosorbide. It is particularly advantageous if the oil phase of the formulations according to the invention has a content of C _12-15 -alkyl benzoate or consists entirely of this.

Advantageous oil components are also z. B. butyloctyl salicylate (for example that available under the trade designation Hallbrite BHB Fa. CP Hall), hexadecyl and butyloctyl benzoate and mixtures thereof (Hall AB) and / or diethylhexyl (Corapan ^® TQ by Haarmann & Reimer).

Also any mixtures of such oil and wax components are advantageous in the sense of the present Use invention.

Further can the oil phase also advantageously contain nonpolar oils, for example those who chose are from the group of branched and unbranched hydrocarbons and waxes, in particular mineral oil, Vaseline (petrolatum), paraffin oil, squalane and squalene, polyolefins, hydrogenated polyisobutenes and isohexadecane. Among the polyolefins, polydecenes are the preferred substances.

Advantageous can the oil phase also have a content of cyclic or linear silicone oils or Completely from such oils although it is preferred, except the silicone oil or silicone oils additional Content of other oil phase components to use.

werden auch als Polydimethylsiloxan bzw. Dimethicon (INCI) bezeichnet. Dimethicone gibt es in verschiedenen Kettenlängen bzw. mit verschiedenen Molekulargewichten.Silicone oils are high molecular weight synthetic polymeric compounds in which silicon atoms via oxygen atoms chain and / or net-like linked and the remaining valences of silicon by hydrocarbon radicals (usually methyl, more rarely ethyl, propyl, phenyl groups, etc.) are saturated. Systematically, the silicone oils are called polyorganosiloxanes. The methyl-substituted polyorganosiloxanes, which are the quantitatively most important compounds of this group and are characterized by the following structural formula

are also referred to as polydimethylsiloxane or dimethicone (INCI). Dimethicones are available in different chain lengths or with different molecular weights.

Especially advantageous polyorganosiloxanes in the context of the present invention are, for example, dimethylpolysiloxanes [poly (dimethylsiloxane)], which, for example, under the trade names Abil 10 bis 10,000 available from Th. Goldschmidt are. Also advantageous are phenylmethylpolysiloxanes (INCI: phenyl dimethicone, Phenyl trimethicone), cyclic silicones (octamethylcyclotetrasiloxane or decamethylcyclopentasiloxane), which according to INCI also called cyclomethicones amino-modified silicones (INCI: amodimethicone) and silicone waxes, e.g. B. Polysiloxane-polyalkylene copolymers (INCI: Stearyl dimethicones and cetyl dimethicones) and dialkoxydimethylpolysiloxanes (Stearoxy dimethicone and behenoxy stearyl dimethicone) which as different Abil wax types are available from Th. Goldschmidt. But also other silicone oils are advantageous for the purposes of the present invention to use for example, cetyl dimethicone, hexamethylcyclotrisiloxane, polydimethylsiloxane, Poly (methylphenylsiloxane).

Especially advantageous preparations are also obtained if, as additional or agents used antioxidants. Included in the invention the preparations advantageously one or more antioxidants. As cheap, but yet optional antioxidants can all be used for cosmetic Applications suitable or common Antioxidants are used. According to the invention, the antioxidants are preferred in the emulsion according to the invention incorporated.

Especially For the purposes of the present invention, water-soluble antioxidants may be advantageous be used, such as vitamins, eg. As ascorbic acid and their derivatives.

preferred Antioxidants are also vitamin E and its derivatives as well as vitamin A and its derivatives, niacinamide, gamma-oryzanol and panthenol.

The Amount of antioxidants (one or more compounds) in the Preparations is preferably from 0.001 to 30% by weight, particularly preferably from 0.05 to 20 Wt .-%, in particular 0.1 to 10 wt .-%, based on the total weight the preparation.

Provided Vitamin E and / or derivatives thereof are the antioxidant (s), is advantageous, their respective concentrations from the field from 0.001 to 10% by weight, based on the total weight of the formulation, to choose.

Provided Vitamin A or vitamin A derivatives, or carotenes or their derivatives the one or more antioxidants are advantageous, their respective Concentrations from the range of 0.001 to 10 wt .-%, based on the total weight of the formulation to choose.

It is particularly advantageous when the cosmetic preparations according to the present Contain cosmetic active ingredients, preferred agents Antioxidants are what protect the skin from oxidative stress protect can. The active compounds according to the invention become advantageous according to the invention in the emulsion according to the invention incorporated.

Further advantageous active ingredients in the context of the present invention are natural active ingredients and / or derivatives thereof, such as. Alpha-lipoic acid, phytoene, D-biotin, coenzyme Q10, alpha-glucosylrutin, carnitine, carnosine, natural and / or synthetic isoflavonoids, creatine, creatinine, taurine and / or β-alanine, and 8-hexadecene-1,16- dicarboxylic acid (dioic acid, CAS number 20701-68-2, provisional INCI name octadecenedioic acid) and / or licochalcone A, which is characterized by the following structural formula:

licochalcone may also be used advantageously as a component of plant extracts, in particular of aqueous radix Glycyrrhizae inflatae, are used.

It is advantageous according to the invention when the cosmetic preparations 0.001 to 10 wt .-%, in particular 0.05 to 5 wt .-%, especially 0.01 to 2 wt .-% of an extract from Radix Glycyrrhizae inflatae, in each case based on the Total weight of the emulsion.

All it is particularly advantageous to start from an extract which under the name Polyol Soluble Licorice Extract PU (INCI name Glycyrrhiza Inflata) can be obtained from the company Maruzen. The extract from Radix Glycyrrhizae inflatae contains about 25% % Licochalcone A.

Inventive formulations, which z. B. known anti-wrinkling agents such as flavone glycosides (especially α-glycosyl rutin), Coenzyme Q10, vitamin E and / or derivatives and the like (in particular in the emulsion), are particularly advantageous for cosmetic protection against aesthetics unattractive skin changes, as they are z. B. occur during skin aging (such as Dryness, roughness and formation of dryness wrinkles, reduced refatting (eg after washing), visible vascular dilations (telangiectasias, Cuperosis), slackness and development of wrinkles and wrinkles, local hyper-, hypo- and false pigmentations (eg age spots), increased susceptibility across from mechanical stress (eg cracking) and the like). Farther Advantageously, they are suitable against the appearance of dry or rough skin.

The cosmetic preparations according to the invention may contain cosmetic adjuvants, such as are commonly used in such preparations, for. B. preservatives, preservatives helper, complexing agents, bactericides, perfumes, substances for preventing or increasing foaming, dyes, pigments which have a coloring effect, thickeners, moisturizing and / or moisturizing substances, anti-dandruff agents, fillers which improve the feel on the skin, fats, Oils, waxes or other common ingredients of a cosmetic or dermatological formulation such as alcohols, polyols, polymers, foam stabilizers, electrolytes, organic solvents or silicone derivatives.

It is also advantageous, the preparations according to the invention complexing agents add. Advantageously, the complexing agents are selected from the group consisting of ethylenediaminetetraacetic acid (EDTA) and their anions, nitrilotriacetic acid (NTA) and their anions, hydroxyethylenediaminotriacetic acid (HOEDTA) and their anions, diethyleneaminopentaacetic acid (DPTA) and their anions, trans-1,2-diaminocyclohexanetetraacetic acid (CDTA) and its anions, Tetrasodium Iminodisuccinate, Trisodium Etylenediamine Disuccinate.

It is according to the invention of advantage the preparation according to the invention Add vitamins, plant extracts and UV sunscreen filters. Thus, for example, the addition of calcium-vitamin complexes according to the invention is particularly advantageous.

The preparations according to the invention can furthermore advantageously also contain self-tanning substances, such as dihydroxyactone and / or melanin derivatives in concentrations from 1% by weight up to 10% by weight, based on the total weight of the Emulsion.

Furthermore, the preparations according to the invention may also advantageously contain repellents for protection against mosquitoes, ticks and spiders and the like. Advantageous z. N, N-diethyl-3-methylbenzamide (trade name: meta-delphphene, "DEET"), dimethyl phthalate (trade name: Palatinol M, DMP), 1-piperidinecarboxylic acid 2- (2-hydroxyethyl) -1-methylpropyl ester, and especially 3- (Nn-butyl-N-acetyl-amino) -propionic acid ethyl ester (available under the trade name insect repellent ^® 3535 from Fa. Merck). the repellents may, both separately and in combination in a total concentration of 1 to 30% by weight , based on the total weight of the emulsion used.

The cosmetic preparations according to the invention may also advantageously, although not necessarily, contain fillers which are e.g. B. further improve the sensory and cosmetic properties of the formulations and, for example, cause or enhance a velvety or silky feel on the skin. Advantageous fillers for the purposes of the present invention are starch and starch derivatives (such as, for example, tapioca starch, distarch phosphate, aluminum or sodium starch, octenylsuccinate and the like), pigments which have neither chiefly UV filter nor coloring action (such as, for example, US Pat. B. boron nitride etc.) and / or Aerosils ^® (CAS no. 7631-86-9).

According to the invention, the preparation according to the invention can advantageously contain one or more preservatives. Advantageous preservatives for the purposes of the present invention are, for example, formaldehyde releasers (such as, for example, DMDM hydantoin, which is available under the trade name Glydant ^™ from Lonza), iodopropyl butylcarbamates (for example those sold under the trade names Glycacil-L, Glycacil -Sun available from Lonza Co. and / or Dekaben LMB from Jan Dekker), parabens (ie, p-hydroxybenzoic acid alkyl esters such as methyl, ethyl, propyl and / or butylparaben), phenoxyethanol, ethanol, benzoic acid, and the like. The preservative system according to the invention also advantageously also comprises preserving aids, such as, for example, octoxyglycerol, glycine soy etc. The following table gives an overview of some preservatives which are advantageous according to the invention:

Further advantageous in cosmetics are common preservatives or preservatives, such as dibromodicyanobutane (2-bromo-2-bromomethylglutarodinitrile), Phenoxyethanol, 3-iodo-2-propynyl butylcarbamate, 2-bromo-2-nitro-propane-1,3-diol, Imidazolidinyl urea, 5-chloro-2-methyl-4-isothiazolin-3-one, 2-chloroacetamide, Benzalkonium chloride, benzyl alcohol.

It is according to the invention particularly preferred, if as preservatives benzoic acid and / or salicylic acid and / or their derivatives or salts are used.

parabens and mixtures with phenoxyethanol / DMDM hydantoin are preferred according to the invention.

According to the invention advantageous are one or more preservatives in one concentration from 2% by weight or less than 2% by weight, preferably 1.5% by weight or less than 1.5% by weight, and more preferably 1% by weight or less than 1% by weight, based in each case on the total weight the preparation in the composition which this at the time of applying to the substrate, in the preparation according to the invention contain.

The preparations according to the invention advantageously contain one or more conditioners. Conditioners preferred according to the invention are, for example, all compounds disclosed in section 4 of the International Cosmetic Ingredient Dictionary and Handbook (Volume 4, publisher: RC Pepe, JA Wenninger, GN McEwen, The Cosmetic, Toiletry, and Fragrance Association, 9th Edition, 2002) The keywords Hair Conditioning Agents, Humectants, Skin Conditioning Agents, Skin Conditioning Agents Emollient, Skin Conditioning Agents Humactant, Skin Conditioning Agents-Miscellaneous, Skin Conditioning Agents-Occlusive and Skin Protectans are listed as well as all in the EP 0934956 (S.11-13) under water soluble conditioning agent and oil soluble conditioning agent listed compounds. Some of these compounds are listed by name among the components of the aqueous phase and the oil phase. Further conditioners advantageous according to the invention, for example, according to the international nomenclature for cosmetic ingredients (INCI) as Polyquaternium named compounds (in particular Polyquaternium-1 to Polyquaternium-56).

Conditioners preferred according to the invention can be found, for example, in the following list:

Further inventively advantageous film formers are cellulose derivatives and quaternized guar gum derivatives, in particular guar hydroxypropylammonium represents (eg Jaguar Excel ^®, Jaguar C 162 ^® from Rhodia, CAS 65497-29-2, CAS 39421-75-5).

And nonionic poly-N-vinylpyrrolidone / polyvinyl acetate copolymers (such as Luviskol VA 64W ^®, BASF), anionic acrylate copolymers (eg Luviflex Soft ^®, BASF), and / or amphoteric amide / acrylate / methacrylate copolymers (for example, Amphomer ^®, National Starch) can be advantageously used according to the invention as a film former.

Advantageous can preparations according to the invention Furthermore Contain substances that absorb UV radiation in the UVB range, the total amount of filter substances being e.g. 0.1% by weight to 30% by weight, preferably 0.5 to 10% by weight, in particular 1.0 to 6.0% by weight is, based on the total weight of the preparations to cosmetic Preparations available to put the hair or the skin in front of the entire area protect the ultraviolet radiation. You can also as a sunscreen for To serve hair.

• – 3-Benzylidencampher-Derivate, vorzugsweise 3-(4-Methylbenzyliden)campher, 3-Benzylidencampher;
• – 4-Aminobenzoesäure-Derivate, vorzugsweise 4-(Dimethylamino)-benzoesäure(2-ethylhexyl)ester, 4-(Dimethylamino)benzoesäureamylester;
• – Ester der Zimtsäure, vorzugsweise 4-Methoxyzimtsäure(2-ethylhexyl)ester, 4-Methoxyzimtsäureisopentylester;
• – Ester der Salicylsäure, vorzugsweise Salicylsäure(2-ethylhexyl)ester, Salicylsäure(4-isopropylbenzyl)ester, Salicylsäurehomomenthylester,
• – Derivate des Benzophenons, vorzugsweise 2-Hydroxy-4-methoxybenzophenon, 2-Hydroxy-4-methoxy-4'-methylbenzophenon, 2,2'-Dihydroxy-4-methoxybenzophenon;
• – Ester der Benzalmalonsäure, vorzugsweise 4-Methoxybenzalmalonsäuredi(2-ethylhexyl)ester,
• – Ester der 2-Cyano-3,3-Diphenylacrylsäure, bevorzugt Ethylhexyl-2-cyano-3,3-diphenylacrylat,
• – Diethylhexyl-butamidotriazon, 2,4,6-Trianilino-(p-carbo-2'-ethyl-1'-hexyloxy)-1,3,5-triazin.

If the preparations according to the invention contain UVB filter substances, they may be oil-soluble or water-soluble. Oil-soluble UVB filters which are advantageous according to the invention are, for example:

• 3-benzylidene camphor derivatives, preferably 3- (4-methylbenzylidene) camphor, 3-benzylidene camphor;
• 4-aminobenzoic acid derivatives, preferably 2-ethylhexyl 4- (dimethylamino) benzoate, 4- (dimethylamino) benzoic acid amyl ester;
• Esters of cinnamic acid, preferably 4-methoxycinnamic acid (2-ethylhexyl) ester, 4-methoxycinnamic acid isopentyl ester;
• Esters of salicylic acid, preferably 2-ethylhexyl salicylate, 4-isopropylbenzyl salicylate, homomenthyl salicylate,
• Derivatives of benzophenone, preferably 2-hydroxy-4-methoxybenzophenone, 2-hydroxy-4-methoxy-4'-methylbenzophenone, 2,2'-dihydroxy-4-methoxybenzophenone;
• Esters of benzalmalonic acid, preferably di-2-ethylhexyl 4-methoxybenzalmalonate,
• Esters of 2-cyano-3,3-diphenylacrylic acid, preferably ethylhexyl 2-cyano-3,3-diphenylacrylate,
• Diethylhexylbutamidotriazone, 2,4,6-trianilino- (p-carbo-2'-ethyl-1'-hexyloxy) -1,3,5-triazine.

• – Salze der 2-Phenylbenzimidazol-5-sulfonsäure wie ihr Natrium-, Kalium- oder ihr Triethanolammonium-Salz, sowie die Sulfonsäure selbst;
• – Sulfonsäure-Derivate von Benzophenonen, vorzugsweise 2-Hydroxy-4-methoxybenzophenon-5-sulfonsäure und ihre Salze;
• – Sulfonsäure-Derivate des 3-Benzylidencamphers, wie z.B. 4-(2-Oxo-3-bornylidenmethyl)benzolsulfonsäure, 2-Methyl-5-(2-oxo-3-bornylidenmethyl)sulfonsäure und ihre Salze sowie das 1,4-di(2-oxo-10-Sulfo-3-bornylidenmethyl)-Benzol und dessen Salze (die entprehenden 10-Sulfato-verbindungen, beispielsweise das entsprechende Natrium-, Kalium- oder Triethanolammonium-Salz), auch als Benzol-1,4-di(2-oxo-3-bornylidenmethyl-10-Sulfonsäure bezeichnet

Advantageous water-soluble UVB filters are, for example:

• Salts of 2-phenylbenzimidazole-5-sulphonic acid, such as its sodium, potassium or triethanolammonium salt, and the sulphonic acid itself;
• Sulfonic acid derivatives of benzophenones, preferably 2-hydroxy-4-methoxybenzophenone-5-sulfonic acid and its salts;
• - Sulfonic acid derivatives of 3-Benzylidencamphers, such as 4- (2-oxo-3-bomylidenemethyl) benzenesulfonic acid, 2-methyl-5- (2-oxo-3-bomylidenemethyl) sulfonic acid and its salts, and the 1,4-di (2-oxo-10-sulfo-3-bomylidenemethyl) benzene and its salts (the debasing 10-sulfato compounds, for example the corresponding sodium, potassium or triethanolammonium salt), also as benzene-1,4-di (2-oxo-3-bornylidenemethyl-10-sulfonic acid

The list of said UVB filters which can be used in combination with the active compound combinations according to the invention should of course not be limiting. It may also be advantageous to use UVA filters that are commonly included in cosmetic preparations. These substances are preferably derivatives of dibenzoylmethane, in particular 1- (4'-tert. Bu tylphenyl) -3- (4'-methoxyphenyl) -propane-1,3-dione and 1-phenyl-3- (4'-isopropylphenyl) propane-1,3-dione.

Further advantageous UVA filters originate from the group of triazines, for example 2,4-bis - {[4- (2-ethyl-hexyloxy) -2-hydroxy] -phenyl} -6- (4-methoxyphenyl) -1, 3,5-triazine (trade name Tinosorb S ^®) and the group of the triazoles, such as 2,2'-methylene-bis- [6-2H-benzotriazol-2-yl] -4- (1,1,3,3- tetramethylbutyl) phenol) (trade designation Tinosorb ^® M). An advantageous water-soluble UVA filter is the 2'-bis (1,4-phenylene) -1H-benzimidazole-4,6-disulfonic acid sodium salt (trade name Neo Heliopan ^AP® ).

It can the for the amounts used in the UVB combination are used.

Preferred inorganic pigments are metal oxides and / or other water-insoluble or insoluble metal compounds, in particular oxides of titanium (TiO ₂ ), zinc (ZnO), iron (eg Fe ₂ O ₃ ), zirconium (ZrO ₂ ), silicon ( SiO ₂ ), manganese (for example MnO), aluminum (Al ₂ O ₃ ), cerium (for example Ce ₂ O ₃ ), mixed oxides of the corresponding metals and mixtures of such oxides and also the barium sulfate (BaSO ₄ ).

The Pigments can advantageous in the context of the present invention also in the form of a commercial available oily or aqueous Predispersions are used. These predispersions can be beneficial Dispersing aids and / or solubilization promoters added be.

The Pigments can According to the invention advantageous superficial be treated ("coated"), for example a hydrophilic, amphiphilic or hydrophobic character formed should be or should be preserved. This surface treatment can consist of that the pigments according to known methods with a thin hydrophilic and / or hydrophobic inorganic and / or organic layer be provided. The different surface coatings can be used in the According to the present invention also contain water.

Inorganic surface coatings for the purposes of the present invention may consist of aluminum oxide (Al ₂ O ₃ ), aluminum hydroxide Al (OH) ₃ or aluminum oxide hydrate (also: Alumina, CAS No .: 1333-84-2), sodium hexametaphosphate (NaPO ₃ ) ₆ , sodium metaphosphate (NaPO ₃ ) _n , silicon dioxide (SiO ₂ ) (also: silica, CAS No .: 7631-86-9), or iron oxide (Fe ₂ O ₃ ). These inorganic surface coatings may be present alone, in combination and / or in combination with organic coating materials.

organic surface coatings For the purposes of the present invention may consist of vegetable or animal aluminum stearate, vegetable or animal stearic acid, lauric acid, dimethylpolysiloxane (also: dimethicone), methylpolysiloxane (methicone), simethicone (a mixture of dimethylpolysiloxane with an average chain length from 200 to 350 dimethylsiloxane units and silica gel) or alginic acid. These organic surface coatings can alone, in combination and / or in combination with inorganic Coating materials occur.

Zinc oxide particles which are suitable according to the invention and predispersions of zinc oxide particles are obtainable from the following companies under the following commercial names:

Suitable titanium dioxide particles and predispersions of titanium dioxide particles are available from the following companies under the following trade names:

It is advantageous according to the invention if the gel aqueous Phase and / or the emulsion droplets colored differently are.

The dyes and pigments can be selected from the corresponding positive list of the Cosmetics Regulation or EC List of cosmetic colorants. In most cases, they are identical to the food-approved dyes. Examples of advantageous color pigments are titanium dioxide, mica, iron oxides (eg Fe ₂ O ₃ , Fe ₃ O ₄ , FeO (OH)) and / or tin oxide. Advantageous dyes are, for example, carmine, Berlin blue, chrome oxide green, ultramarine blue and / or manganese violet. It is particularly advantageous to choose the dyes and / or color pigments from the following list. The Color Index Numbers (CIN) are taken from the Rowe Color Index, 3rd Edition, Society of Dyers and Colourists, Bradford, England, 1971.

It can also be cheap be, as a dye one or more substances from the following Group to choose: 2,4-dihydroxyazobenzene, 1- (2'-chloro-4'-nitro-1'-phenylazo) -2-hydroxynaphthalene, Ceres red, 2- (4-sulfo-1-naphthylazo) -1-naphthol-4-sulfonic acid, calcium salt 2-hydroxy-1,2'-azonaphthalene-1'-sulfonic acid, calcium and barium salts of 1- (2-sulfo-4-methyl-1-phenylazo) -2-naphthylcarboxylic acid, calcium salt of 1- (2-sulfo-1-naphthylazo) -2-hydroxynaphthalene-3-carboxylic acid, aluminum salt of 1- (4-sulfo-1-phenylazo) -2-naphthol-6-sulfonic acid, aluminum salt of 1- (4-sulfo-1-naphthylazo) -2-naphthol-3,6-disulfonic acid, 1- (4-sulfo-1-naphthylazo) -2-naphthol-6,8-disulfonic acid, aluminum salt the 8-amino-2-phenylazo 1-naphthol-3,6-disulfonic acid, Aluminum salt of 4- (4-sulfo-1-phenylazo) -1- (4-sulfophenyl) -5-hydroxy-pyrazolone-3-carboxylic acid, 4 '- [(4' '- sulfo-1' '- phenylazo) - 7'-sulfo-1'-naphthylazo] -1-hydroxy-8-acetylaminonaphthalene-3,5-disulfonic acid, aluminum and zirconium salts 4,5-dibromofluorescein, aluminum and zirconium salts of 2,4,5,7-tetrabromofluorescein, 3 ', 4', 5 ', 6'-tetrachloro-2,4,5,7-tetrabromfluorescein and its aluminum salt, aluminum salt of 2,4,5,7-tetraiodofluorescein, Aluminum salt of quinophthalone-disulfonic acid, aluminum salt of indigo-disulfonic acid, 4,4'-dimethyl-6,6'-dichlorothioindigo, complex salt (Na, Al, Ca) of carminic acid, red and black iron oxide (CIN: 77 491 (red) and 77 499 (black)), Iron oxide hydrate (CIN: 77 492), manganese ammonium diphosphate (CIN 77745), Ultramarine (CIN 77007) and titanium dioxide.

Further advantageous are oil-soluble natural dyes, such as B. Paprika extracts, β-carotene or cochineal.

Advantageously in accordance with the invention, the average droplet size of the emulsion droplets is 0.5 to 5 mm. In this case, it is preferred according to the invention if all emulsion droplets have approximately the same size. A pictorial idea of the appearance of the preparations according to the invention, the 1 in which a) the transparent or translucent gel-like aqueous phase and b) the teardrop-shaped emulsion is referred to.

According to the invention advantageous embodiments The present invention are characterized in that they a transparent storage container made of glass or plastic (also in tube form) is kept.

Also according to the invention the process for the preparation of the cosmetic preparation according to the invention, which is characterized in that the emulsion in the gel-like, aqueous phase dripped into it.

According to the invention Use of the cosmetic according to the invention Preparation as foamable Cleaning preparation.

Especially is the use of the cosmetic preparation according to the invention as a shampoo, shower gel, washing lotion and / or bath according to the invention.

The The following examples are intended to illustrate the compositions according to the invention without but it is intended that the invention be accorded these examples restrict. The numerical values in the examples mean percentages by weight on the total weight of the respective preparations.

It can thereby sample recipes from the prescription A -gelbildnerhaltige Surfactant Preparations - with Recipes from Recipe Judgment B - Emulsion Type - or from the prescription C-surfactant emulsions used become.

One Part can be colorless and partly colored or white. It can also combines clear and emulsion-like or colored emulsions become.

Recipe judgment A shower gel

Recipe judgment A shower gel

Recipe B -Emulsion O / W emulsions

O / W emulsions

O / W emulsions

Foamy O / W emulsions:

hydrodispersions

gel creams

Solid-state emulsions

shower emulsion

W / O emulsions,

W / O emulsions,

W / S emulsions

W / S emulsions

W / O emulsions,

W / O emulsions,

Silicone in water emulsion

Claims (15)

Cosmetic preparation that is formed out a) a transparent or translucent gel-like aqueous phase containing polyacrylate thickener and / or Carrageenan thickener as well b) droplets floating in this aqueous phase, taking the droplets be formed from a cosmetic emulsion. Cosmetic preparation according to claim 1, characterized characterized in that the concentration of polyacrylate thickener in the gel-shaped, aqueous Phase from 0.5 to 5.0% by weight, based on the total weight the gel-shaped, aqueous Phase, is. Cosmetic preparation according to one of the preceding Claims, characterized in that the concentration of carrageenan thickener in the gel, aqueous Phase from 0.01 to 2% by weight, based on the total weight of gel, aqueous Phase, is. Cosmetic preparation according to one of the preceding Claims, characterized in that as polyacrylate thickener acrylate-alkyl acrylate copolymers be used. Cosmetic preparation according to one of the preceding Claims, characterized in that the gel-like aqueous phase comprises surfactants in a Concentration of 1 to 30% by weight, based on the total weight the gel-shaped, aqueous Phase, contains. Cosmetic preparation according to one of the preceding Claims, characterized in that the gel-like aqueous phase is sodium lauryl ether sulfate contains. Cosmetic preparation according to one of the preceding Claims, characterized in that the gel-like, aqueous phase has a yield point from 0.5 Pa to 40 Pa. Cosmetic preparation according to one of the preceding Claims, characterized in that the emulsion droplets have a flow limit from 0.5 Pa to 300 Pa. Cosmetic preparation according to one of the preceding Claims, characterized in that the gel-like, aqueous phase has a tan δ value of 0.02 to 0.8. Cosmetic preparation according to one of the preceding Claims, characterized in that the emulsion droplets have a tan δ of 0.01 to 0.8. Cosmetic preparation according to one of the preceding Claims, characterized in that the emulsion droplets in the form of an O / W emulsion available. Cosmetic preparation according to one of the preceding Claims, characterized in that the droplet-shaped emulsion has one or more Emulsifiers / emulsifier chosen from the group i) glyceryl stearate citrate, ii) Cetearyl alcohol + PEG-40 hydrogenated castor oil + Sodium cetearyl sulfate + glyceryl stearate, iii) polyglyceryl-3-methyl glucose distearate, iv) stearic acid, v) potassium cetyl phosphate, vi) glyceryl monostearate contains. Cosmetic preparation according to one of the preceding Claims, characterized in that the gelatinous aqueous phase and / or the emulsion droplets are colored. Cosmetic preparation according to one of the preceding Claims, characterized in that it consists of a transparent storage container Glass or plastic is stored. Process for the preparation of a cosmetic preparation according to one of the preceding claims, characterized that the emulsion in the gel, aqueous Phase is dropped into it.