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EP0492258A1 - Support temporaire à transfert et procédé pour sa production - Google Patents

Support temporaire à transfert et procédé pour sa production Download PDF

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Publication number
EP0492258A1
EP0492258A1 EP91121115A EP91121115A EP0492258A1 EP 0492258 A1 EP0492258 A1 EP 0492258A1 EP 91121115 A EP91121115 A EP 91121115A EP 91121115 A EP91121115 A EP 91121115A EP 0492258 A1 EP0492258 A1 EP 0492258A1
Authority
EP
European Patent Office
Prior art keywords
melt adhesive
hot
carrier
thermo
release composite
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP91121115A
Other languages
German (de)
English (en)
Inventor
Josef Dr. C/O Kufner Textilwerke Gmbh Hefele
Wolfgang Dr. Bühlmeyer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kufner Textilwerke GmbH
Original Assignee
Kufner Textilwerke GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kufner Textilwerke GmbH filed Critical Kufner Textilwerke GmbH
Publication of EP0492258A1 publication Critical patent/EP0492258A1/fr
Withdrawn legal-status Critical Current

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Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06Q—DECORATING TEXTILES
    • D06Q1/00—Decorating textiles
    • D06Q1/12—Decorating textiles by transferring a chemical agent or a metallic or non-metallic material in particulate or other form, from a solid temporary carrier to the textile
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B44—DECORATIVE ARTS
    • B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C1/00—Processes, not specifically provided for elsewhere, for producing decorative surface effects
    • B44C1/16—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like
    • B44C1/165—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like for decalcomanias; sheet material therefor
    • B44C1/17—Dry transfer
    • B44C1/1712—Decalcomanias applied under heat and pressure, e.g. provided with a heat activable adhesive

Definitions

  • the invention relates to a thermo-release composite consisting of a surface-stable support and a flat plastic layer, with the aid of which it is possible to transfer image motifs to other substrates, preferably to textiles and to finished articles of clothing, such as the chest area of t-shirts. and a method for producing such a thermal release composite.
  • DE-OS 1 771 863 describes a method in which on a base, e.g. on art paper, images produced on a new base, for example on a textile material, are transferred.
  • a base e.g. on art paper
  • images produced on a new base for example on a textile material
  • an intermediate underlay in the form of a laminate is used, which consists of the following layers: a carrier layer, a detachable middle layer, a clear lacquer layer and a glue layer.
  • the main disadvantage of this method is the inaccuracy of the image transmission. The washing and cleaning resistance is also poor.
  • the difficulties of inaccurate image transmission are to be avoided by covering the ink layer covering the image with an adhesive layer, then pressing a sheet coated with glue with the adhesive side against the ink layer, after which the sheet is left behind Glue on the ink layer is peeled off and an intermediate base consisting of a clear lacquer layer, an adhesive layer that is easily detachable from the clear lacquer layer and a base layer is pressed onto the glue, then the original base is removed from the ink layer and the intermediate base with the ink layer thereon applied to the new base and finally the base layer is removed from the clear coat.
  • the process is cumbersome and uneconomical.
  • GB-PS 423 727 has also described the transfer of images from a first surface to a second.
  • the starting motif with a Treated liquid that softens the surface of an intermediate carrier. After the transfer to this intermediate carrier, the original motif can then be transferred to the actual document. This process is also cumbersome. It is also disadvantageous that solvent is necessary.
  • DE-PS 27 57 630 describes a method according to which the motifs generated in a printing process using soft printing inks are transferred from a flexible original base, for example a printed paper, to a new base, the motif being applied by applying a liquid is detached from the original document. The new pad is wetted with the color-dissolving liquid and pressed against the original pad. Finally, the original document is separated from the new one. Disadvantages are the use of solvents, the limitation of the process to photocopies, the low resistance to washing and cleaning, and the poor color quality or brilliance. The motifs fade when printing on textiles. Improved wash resistance on textiles is obtained by the process of DE-OS 3 732 489.
  • the motifs are produced with wash-resistant paint or paint with a wash-resistant additive.
  • this process cannot do without solvents, with which the surface hardened by the abovementioned additive is broken up, so that the color can penetrate into the textile.
  • the paint is then oxidatively cured by atmospheric oxygen.
  • plastic films are used for the transfer of image motifs from a transfer carrier to a preferably textile substrate in an environmentally friendly manner Laminate paper.
  • the sheet-like plastic film produced, for example, by melt extrusion and the sheet-like transfer carrier are usually pulled off two separate supply rolls and laminated together.
  • the commercially available laminate composites have the disadvantage that, due to the high pressures that are required during lamination, the film is anchored too strongly on the paper, which has the consequence that, after the image has been transferred, a split within the plastic film when the backing paper is peeled off occurs and thus only part of the film mass is transferred and also the backing paper can only be removed when hot.
  • the film splitting results in poor contour sharpness and poor color quality or brilliance.
  • expensive plastic material is discarded.
  • the need to peel the backing paper while it is hot is a hindrance. If you peel off after cooling, the backing paper splits. Part of the backing paper remains inseparably attached to the substrate, and the hot stripping technique cannot be used for large motifs.
  • the carrier after the transfer of the image motif, the carrier should be removable even in the cooled state without risk of splitting the carrier or the plastic layer.
  • the transferred image motifs should have a high color brilliance, good sharpness of contours and good resistance to washing and cleaning, so that the image does not fade or hardly occurs after washing.
  • thermo-release composite consisting of a surface-stable carrier and a flat plastic layer applied thereon, with the aid of which it is possible to transfer image motifs to substrates, in particular textiles, which is characterized in that the carrier is coated with hot-melt adhesive powder, which is present in an even distribution and is sintered on and compacted in a film-like manner for taking the picture motif thereon.
  • the film-like hot melt adhesive layer preferably has only a weak adhesion to the carrier.
  • the adhesive force of the hot-melt adhesive layer is set in such a way that after transfer of the image motif under the influence of pressure and temperature to other flat substrates and after cooling, it detaches completely from the carrier and is peeled off with a tensile force of 10 to 250 cN / 5 cm can be.
  • thermo-release composite from a surface-stable carrier pretreated with anti-adhesive agent and a plastic layer applied thereon for receiving image motifs and their transfer to flat substrates, such as clothing, textiles, foams, foils, natural and artificial leather, metal, glass, porcelain, wood, artificial surfaces created, which is characterized in that Hot melt adhesive powder is applied to a moist base coat of the carrier or powder-containing paste directly on the carrier, is evenly distributed and dried, and is sintered and compacted like a film.
  • the non-pasted hot melt adhesive powder can be sprinkled onto a moist base coat applied to the carrier, uniformly distributed, dried, sintered and compressed.
  • the generated thermo-release composite consists of the carrier and the compressed hot-melt adhesive layer on top of it, which can be easily and completely transferred to other substrates alone or with image motifs.
  • antiadhesive papers which are supposed to have a weight of 40 to 120 g / m 2, preferably 60-100 g / m 2, can advantageously be used as area-stable supports. These transfer papers are pretreated on one or both sides with antiadhesive agents which have a good release action, which is preferably achieved by applying crosslinkable silicones or simple or complex fatty acid salts.
  • the backing papers used must also have sufficient wet strength so that there is no tendency to curl and ripple on contact with the preferably used aqueous dispersions or suspensions which make up the base coat mixture or the coated powder-containing paste.
  • the selection of the backing paper also depends on the desired weak adhesive strength of the applied hot melt adhesive layer. It is particularly favorable if the weak adhesive strength after the complete transfer process in the cooled state is in the range from 10 to 250 cN / 5 cm, preferably 10 to 150 cN / 5 cm.
  • the plastic layer is advantageously formed on the carrier paper by sprinkling fine-grained hot-melt adhesive powders onto a moist base coat applied to the carrier, to which the powder adheres and which produces the desired weak adhesion.
  • a paste containing hot-melt adhesive powder without using a base coat.
  • the base layer for example, an aqueous-pasty dispersion of addition-crosslinkable polysiloxanes can be used, which can have a solids content of 3 to 30%, preferably 4 to 20% and also has a relatively strong anti-adhesive effect in the dried state.
  • the use of such a base layer is particularly expedient or necessary when the anti-adhesive effect of the pretreated carrier is not sufficient to completely detach the hot-melt adhesive layer in the cold, for example sometimes when the pretreatment of the carrier has been carried out with simple or complex fatty acid salts.
  • the base layer can or should also consist of thickened pastes which, when dried, have no anti-adhesive effect. If, for example, the carrier is provided with a largely closed silicone coating, non-repellent, thickened pastes can be applied as a base coat, which only contain water and water-soluble thickener. It can also contain plasticizers be included. They can also contain antiblocking agents, such as paraffin dispersions.
  • the task of the moist base coat is, on the one hand, to adhere the hot-melt adhesive product sprinkled on, on the other hand, in coordination with the pretreatment of the backing paper, to achieve good detachability from the backing paper of the surface-compacted hot-melt adhesive layer formed in the subsequent process steps after its transfer process to another substrate.
  • the desired weak adhesive strength of the hot-melt adhesive layer on the backing paper should reach such an extent that the work processes when rolling and smoothing, winding, cutting, transporting and providing image motifs are survived without detachment until the transfer process.
  • the viscosity of the base coat used is to be adjusted by adding thickener in such a way that optimum spreadability is obtained with the desired application amount.
  • the surface spread of the primer should be between 3 and 8 g / m2 when wet.
  • other substances can also be used, for example aqueous thickenings of finely dispersed simple or complex salts of fatty acids, thickenings of fluorocarbon resins, of fatty acid condensation products, etc.
  • a powder-grain fraction is expediently used which has a particle size of 0 to 160 ⁇ , preferably 0 to 80 ⁇ , and particularly preferably 0 to 50 ⁇ having.
  • the use of this fine grain area ensures that a closed hot melt adhesive layer can be formed, the coating weight of which is from about 9 to 40 g / m2, preferably from 9 to 30 g / m2 or also from 14 to 30 g / m2, particularly preferably from 9 to 15 g / m2 is enough.
  • the finer the grain fraction used in the specified range the lower the coating weight when the layer is just closed, the softer the grip and the more homogeneous the printed image appears on the textile substrate when an elastic substrate stretches, without changing any other quality characteristics .
  • the hot-melt adhesive powder is coarser, the coating weight exceeds the specified limit values when the layer is formed, which has the consequence that the handle on the textile substrate becomes too hard and the layer visibly breaks open under tensile stresses of an elastic textile substrate.
  • Materials based on copolyamides, copolyesters, polyethylene vinyl acetates and polyurethanes or mixtures thereof can be considered as hot melt adhesives.
  • Copolyester powders have proven to be particularly suitable for textile applications which have a high resistance to washing and a satisfactory resistance to dry cleaning. In order to achieve a uniform formation of the hot melt adhesive layer and a good covering of the textile fibers during the transfer process, powders with a high melt flow under the influence of temperature are expediently used.
  • These are preferably powders which have a melting range between 95 and 140 ° C, preferably between 100 and 130 ° C, and a melt index according to DIN 53 735 at 160 ° C and a stamp pressure of 21.6 N, from 35 to 150 g / 10 have min.
  • the powders can contain suitable plasticizers in order to achieve a softer feel and an improved coating of the fibers of textile substrates.
  • the plasticizers can already be contained in the delivery state of the powder. They can also be added later. In the case of the latter, it is particularly important to note that the plasticizers added are incorporated in such a way that the plasticizer penetrates the powder grains largely homogeneously. This is achieved through an intensive mixing process and a subsequent tempering.
  • the plasticizers should be selected and dosed so that the resistance to washing and dry cleaning is not impaired in textile applications.
  • Plasticizers based on toluenesulfonamides such as o, p-toluenesulfonamides and their N-substituents, have proven particularly suitable for this.
  • dicyclohexyl phthalate which is finely ground, is also used as a powder.
  • thermo-release composite on textile substrates
  • wetting agents can be added to the hot-melt adhesive powders, which further support the penetration of the hot-melt adhesive layer into the substrate during ironing. This also reduces the phenomenon that the hot-melt adhesive layer transferred to the substrate is applied as a closed-surface structure. Rather, the hot-melt adhesive layer envelops the individual fibers of the substrates and penetrates into the substrate surface in such a way that the closed-surface, break-prone character of the hot-melt adhesive layer is lost, which gives the impression of a homogeneous image even when stretched elastic textile substrate is preserved.
  • the hot-melt adhesive layer can be given a matt appearance. In this way, an undesirable gloss can be avoided, especially when used on textiles.
  • matting agents for example, finely dispersed titanium dioxide, silicon dioxide or aluminum oxide can be used, which have been produced by flame decomposition of the corresponding chlorides.
  • the matting agent in an amount of approx. 1 - 3%, the luminosity of the transferred color motif is not or hardly impaired.
  • the hot-melt adhesive powder it is also possible to add larger amounts of approximately 10-20% of covering pigments, such as titanium dioxide pigment, to the hot-melt adhesive powder and then to sprinkle the most homogeneous possible mixture of pigment and hot-melt adhesive powder onto the surface-applied base coat.
  • covering pigments such as titanium dioxide pigment
  • the manufacturing methodology is the same as for the spreading of unpigmented hot-melt adhesive powder, but the later application is different. While the pigment-free hot melt adhesive layer can be placed directly on the intended surface substrate after application of the image motif, when using the pigmented hot melt adhesive layer, this layer must first be transferred to an intermediate carrier be made from which it is then applied to the intended surface substrate.
  • pigments can also be introduced into the hot melt adhesive layer.
  • a special feature is the introduction of pearlescent pigments and metal powders, which are also to be mixed as homogeneously as possible with the hot-melt adhesive powder before sprinkling.
  • the hot-melt adhesive layer applied and compacted by rolling with a thin dispersion top coat, which should also be meltable and at least water-resistant.
  • the dispersion top coat can consist, for example, of non-crosslinking polyurethanes, poly (meth) acrylic acid esters or polyvinyl acetates.
  • the spread further compresses to the closed film, and in addition, such a spread has proven to be advantageous in some cases when it is passed through copiers, since fewer disturbances occur.
  • the spread with thickening agents can contain plasticizers and pigments.
  • Plasticizers are indicated to reduce the melt temperature and melt viscosity of the spread, and the addition of pigment may be useful to increase the opacity of the hot melt adhesive layer.
  • thermo-release composites which essentially consists of scraping a viscous-pasty, moist base layer onto a wet-strength, surface-stable carrier paper treated with anti-adhesive agent, onto which a fine-grained, optionally matting agent or pigments is applied containing hot melt adhesive powder is sprinkled, and that the excess of powder not adhering to this base layer is removed again.
  • a press smoothing unit the powder anchored and sintered to the dried base layer is rolled into a homogeneous layer and compacted like a film.
  • FIGS. 1 to 3 show a thermal release composite according to the invention.
  • a textile carrier (1) on which there is a base coat (2) on which compacted and sintered hot melt adhesive powder (3), optionally containing matting agent or pigment, on which the image motif (4) is located.
  • a further thermal release composite is shown in FIG. 2, an intermediate carrier (5) being used.
  • the base coat on the anti-adhesive backing paper is carried out in the application zone (A).
  • the backing paper (2) presented by the unwinding device (1) is guided over a spreading table (3).
  • the base coat paste (5) placed in front of the squeegee (4) is metered by means of a rubber squeegee (4) arranged on the spreading table (3).
  • the backing paper (2), which is coated with the base coat (5), then passes through a pair of rollers, which consists of two steel rollers or a steel roller and a rubber roller and by means of its contact pressure the coating amount of the base coat is evened out and regulated.
  • a tangential scraper blade (7) which carries out a vibration movement transverse to the direction of the web, serves to further even out the base coat and prevents possible streaking.
  • the melt adhesive powder is sprinkled in excess on the still wet base coat by means of a scattering unit (8).
  • the spreading unit is a common device consisting of a powder hopper and a slowly rotating spreading roller. The powder is scattered from the spreader roller onto the base line with a brush roller. The hot melt adhesive powder should be sufficiently free-flowing. The spread rate is controlled by the speed of rotation of the spreading roller.
  • Scattering can be assisted if necessary by applying an electrostatic field to charge the powder and enclose it in the base coat.
  • a rapidly rotating beater roller (9) follows behind the scattering device and acts against the Bottom of the backing paper (2) strikes and improves the anchoring of the powder.
  • the vibration of the carrier paper creates a complete homogenization of the powder application across the entire width of the goods.
  • a blow-suction device is arranged downstream of the beater roller (9) to remove the non-anchored excess powder. With two air nozzles (10) and (10 ') blowing against each other, which are transverse to the running direction, the excess powder is sucked off via the suction device (11). The extracted powder is collected and reused.
  • the drying zone (D) which usually consists of a convection drying channel.
  • the base coat is dried and the powder is fixed.
  • the dryer temperatures are between 100 and 150 ° C. With a 5-field dryer and a speed of 30 m / min, the temperature is around 130 ° C.
  • the material web lies loosely on the moving conveyor belt of the dryer.
  • the intermediate product now passes directly from the sintering zone (E) to the smoothing zone (F), which usually consists of one Pressure roller pair exists and which is run through by the intermediate product at high pressure.
  • the hot melt adhesive layer is calendered smooth.
  • the pair of rollers consists of two steel rollers or one steel roller and one rubber roller. Both rolls are cooled.
  • the steel roller which comes into contact with the hot melt adhesive layer, is covered with a thin anti-adhesive layer, preferably made of silicone, in order to avoid deposits, caking or detachment of the hot melt adhesive layer.
  • a thin anti-adhesive layer preferably made of silicone
  • the contacting steel roller can also have a matt surface.
  • thermal release composite according to the invention is further described with the following examples.
  • Avabond 30 E can be used directly, it is advantageous to add plasticizer when using Platherm M 1400.
  • the coating weight is around 9 - 15 g / m2 and with a grain size of 0 to 80 ⁇ m around 20 - 30 g / m2.
  • a well distributed mixture is issued 90 parts by weight of Platherm M 1400 (0-80 ⁇ ) and 10 parts by weight of o, p-toluenesulfonamide powder (0-20 ⁇ ) forth.
  • the premix which is very well distributed using a high-speed mixer, is sieved through a sieve with a mesh size of 125 ⁇ m and annealed in a plastic bag at 90 ° C for 24 hours. After cooling, sieve through a 125 ⁇ sieve.
  • the melt index of the powder has risen over 100 g / 10 min.
  • Necanil LN ethoxylated alkylphenol, BASF
  • methanol ethoxylated alkylphenol, BASF
  • copolyester powder 5 parts by weight of the solution added.
  • Intensive mixing is carried out in the high-speed mixer. It is allowed to dry in air or at a mild temperature in a dryer and then sieved through a 125 ⁇ sieve.
  • Highly disperse silica is used, which has been produced by flame decomposition of silicon tetrachloride. The additional amount is approx. 1 to 3%. Very intensive mixing is required.
  • a thermal release composite according to the invention tailored to DIN A 4 is provided with a color image motif over the entire area in a color copier on the hot-melt adhesive side.
  • the image motif is placed with the hot-melt adhesive side on the chest area or the back of a T-shirt and placed under a plate press with the top plate set to 160 ° C and the bottom plate to 100 ° C.
  • the press is closed with a pressure of 400 cN / cm2 for 15 s.
  • the fixation composite made of T-shirt and thermal release composite is removed from the press and allowed to cool. After cooling, the backing paper is removed from the t-shirt.
  • the image is now fixed on the t-shirt.
  • the carrier paper can be removed very easily after cooling, but also beforehand in the heat, without splitting the paper and without splitting the hot-melt adhesive layer.
  • the hot melt adhesive layer completely transferred to the t-shirt lost its surface character when transferred.
  • the fibers of the t-shirt surface are covered with the hot-melt adhesive and the picture motif.
  • the transferred image motif has high color brilliance and sharpness of contours.
  • thermo-release composite A special feature of the thermo-release composite according to the invention can be observed when the non-transferred hot-melt adhesive layer is peeled off from the backing paper: the hot-melt adhesive layer, which is initially easily removable as a film, breaks open when stretched, apparently at contact zones on the original grain surfaces. Obviously, this phenomenon has no discernible disadvantage in the area of application of the composite.
  • a thermal release composite cut to DIN A4 size is provided with a picture motif on the entire surface of the hot melt adhesive in a black and white or color copier.
  • the motif to be transferred is punched out of it.
  • the die-cut is placed in a fixing press together with an intermediate carrier.
  • the spread was dried at 150 ° C and condensed.
  • the pigmented hot-melt adhesive layer provided with the image motif is transferred to the spread side (7) of the intermediate carrier (5).
  • the adhesion of the hot melt adhesive layer on the intermediate carrier is higher than on the base silicone paper carrier.
  • the original backing paper is removed.
  • the image motif (4) is now located directly on the intermediate carrier (5) and is covered by the pigment-containing hot-melt adhesive film (6) (FIG. 2).
  • the intermediate carrier with the image motif and pigment-containing hot-melt adhesive film is now placed on the intended flat structure, film side to the flat substrate.
  • transfer to the intended surface substrate now takes place at 160 ° C top plate temperature, 100 ° C bottom plate temperature, 400 p / cm2 pressure and 15 s fixing time.
  • the picture motif is now again on the outside. Underneath is the transferred pigment-containing hot melt adhesive layer, which covers the colored background of the fabric and does not allow it to show through.
  • the IRIODINE pearlescent pigment from example 6b is used. All manufacturing conditions are otherwise the same as in example (II).
  • the hot melt adhesive layer containing IRIODIN also covers the colored surface and gives the image a mother-of-pearl, silvery deep shine.
  • the thermal release composite according to the invention is particularly suitable for black and white or colored image motifs
  • Usual printing processes such as high pressure or flexographic printing, planographic printing or offset printing, gravure printing or squeegee printing and screen printing, or else by color copiers, thermal printers, laser printers, inkjet printers, etc., have been applied to clothing, textiles, foams, natural and synthetic leather, metal To transfer glass, porcelain, wood, plastic surfaces, foils or other substrates.
  • the transferred image motifs are characterized by their high color brilliance, soft feel and good wash and cleaning resistance.
  • a special feature of the subject matter according to the invention is that the carrier can be removed even after it has cooled down after the image motif has been transferred to the substrate under the action of heat and pressure.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Decoration By Transfer Pictures (AREA)
  • Laminated Bodies (AREA)
  • Adhesives Or Adhesive Processes (AREA)
EP91121115A 1990-12-27 1991-12-09 Support temporaire à transfert et procédé pour sa production Withdrawn EP0492258A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP90125599 1990-12-27
EP90125599A EP0491991A1 (fr) 1990-12-27 1990-12-27 Support temporaire à transfert et son procédé de préparation

Publications (1)

Publication Number Publication Date
EP0492258A1 true EP0492258A1 (fr) 1992-07-01

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EP90125599A Withdrawn EP0491991A1 (fr) 1990-12-27 1990-12-27 Support temporaire à transfert et son procédé de préparation
EP91121115A Withdrawn EP0492258A1 (fr) 1990-12-27 1991-12-09 Support temporaire à transfert et procédé pour sa production

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0649753A1 (fr) * 1993-10-01 1995-04-26 Canon Kabushiki Kaisha Milieu de transfert d'encre et méthode pour la formation d'images utilisant ledit milieu
EP1884830A1 (fr) * 2006-08-04 2008-02-06 Sony Deutschland GmbH Méthode d'application d'un matériau sur une surface
ITMI20081446A1 (it) * 2008-08-01 2010-02-02 Kuei Srl Procedimento decorativo per pelli, cuoio e derivati
CN101429841B (zh) * 2007-11-06 2011-05-11 洛阳鑫德安全玻璃技术有限公司 2mm丝印强化玻璃与木板相结合的橱柜门板生产工艺
CH703183A1 (de) * 2010-05-26 2011-11-30 Berner Fachhochschule Biel Architektur Holz Und Bau Einrichtung zum blasenfreien Beschichten von Holz und Holzwerkstoffen sowie anderen porösen Werkstoffen mit Pulverlacken oder anderen strahlungshärtenden Beschichtungen.
WO2016196747A1 (fr) * 2015-06-02 2016-12-08 Avery Dennison Retail Information Services, Llc Étiquette à transfert thermique imprimée numériquement
US12307925B2 (en) 2020-07-31 2025-05-20 Illinois Tool Works Inc. Hybrid heat transfer label assemblies

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Publication number Priority date Publication date Assignee Title
DE4320141A1 (de) * 1993-06-17 1994-12-22 Iduso Gmbh Vierlagige Verbundfolie mit dem Aufbau Papier-Silikon-Kunststoff-Metall
ES2069488B1 (es) * 1993-07-12 1998-05-01 Ponce Ovejero M Luisa Procedimiento para la impresion de imagenes en color sobre superficies de piel.
US6652928B2 (en) * 1998-01-28 2003-11-25 Canon Kabushiki Kaisha Image-transfer medium for ink-jet printing, production process of transferred image, and cloth with transferred image formed thereon
ES2232249B1 (es) * 2002-10-17 2006-10-16 Antonio Gomez Arroyo Metodo de impresion grafica sobre madera.
CN112871561B (zh) * 2021-03-11 2025-06-10 常州富烯科技股份有限公司 氧化石墨烯膜生产系统

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2306087A1 (fr) * 1975-04-03 1976-10-29 Marler E T Ltd Perfectionnements aux transferts d'images
DE3022744A1 (de) * 1979-07-19 1981-02-19 Barta Franz Kg Markierungsmaterial in der art von abziehbildern zur anbringung einer markierung, eines bildes o.dgl. an einem textilen gegenstand
DE3015510A1 (de) * 1980-04-23 1981-10-29 Printec Gesellschaft für Siebdruck, Beflockung und Sportbekleidung mbH, 6908 Wiesloch Transferteil zum applizieren eines dessins, verfahren zu seiner herstellung und verwendung

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2306087A1 (fr) * 1975-04-03 1976-10-29 Marler E T Ltd Perfectionnements aux transferts d'images
DE3022744A1 (de) * 1979-07-19 1981-02-19 Barta Franz Kg Markierungsmaterial in der art von abziehbildern zur anbringung einer markierung, eines bildes o.dgl. an einem textilen gegenstand
DE3015510A1 (de) * 1980-04-23 1981-10-29 Printec Gesellschaft für Siebdruck, Beflockung und Sportbekleidung mbH, 6908 Wiesloch Transferteil zum applizieren eines dessins, verfahren zu seiner herstellung und verwendung

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0649753A1 (fr) * 1993-10-01 1995-04-26 Canon Kabushiki Kaisha Milieu de transfert d'encre et méthode pour la formation d'images utilisant ledit milieu
EP1884830A1 (fr) * 2006-08-04 2008-02-06 Sony Deutschland GmbH Méthode d'application d'un matériau sur une surface
WO2008014845A1 (fr) * 2006-08-04 2008-02-07 Sony Deutschland Gmbh Procédé de dépôt d'un matériau sur un substrat
US7964054B2 (en) 2006-08-04 2011-06-21 Sony Deutschland Gmbh Method of applying a material on a substrate
CN101429841B (zh) * 2007-11-06 2011-05-11 洛阳鑫德安全玻璃技术有限公司 2mm丝印强化玻璃与木板相结合的橱柜门板生产工艺
ITMI20081446A1 (it) * 2008-08-01 2010-02-02 Kuei Srl Procedimento decorativo per pelli, cuoio e derivati
CH703183A1 (de) * 2010-05-26 2011-11-30 Berner Fachhochschule Biel Architektur Holz Und Bau Einrichtung zum blasenfreien Beschichten von Holz und Holzwerkstoffen sowie anderen porösen Werkstoffen mit Pulverlacken oder anderen strahlungshärtenden Beschichtungen.
WO2016196747A1 (fr) * 2015-06-02 2016-12-08 Avery Dennison Retail Information Services, Llc Étiquette à transfert thermique imprimée numériquement
US9799238B2 (en) 2015-06-02 2017-10-24 Avery Dennison Retail Information Services, Llc Digitally printed heat transfer label
US12307925B2 (en) 2020-07-31 2025-05-20 Illinois Tool Works Inc. Hybrid heat transfer label assemblies

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