GB1260798A - Method of improving the interfacial adhesion of inorganic fibre materials - Google Patents
Method of improving the interfacial adhesion of inorganic fibre materialsInfo
- Publication number
- GB1260798A GB1260798A GB31303/70A GB3130370A GB1260798A GB 1260798 A GB1260798 A GB 1260798A GB 31303/70 A GB31303/70 A GB 31303/70A GB 3130370 A GB3130370 A GB 3130370A GB 1260798 A GB1260798 A GB 1260798A
- Authority
- GB
- United Kingdom
- Prior art keywords
- silane
- dispersions
- inorganic
- fibre materials
- resins
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000463 material Substances 0.000 title abstract 7
- 239000000835 fiber Substances 0.000 title abstract 6
- 238000000034 method Methods 0.000 title abstract 2
- 239000006185 dispersion Substances 0.000 abstract 6
- 229920005989 resin Polymers 0.000 abstract 6
- 239000011347 resin Substances 0.000 abstract 6
- 229910000077 silane Inorganic materials 0.000 abstract 5
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 abstract 4
- 229920000642 polymer Polymers 0.000 abstract 4
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 abstract 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 abstract 3
- 239000007822 coupling agent Substances 0.000 abstract 3
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical class O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 abstract 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 abstract 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract 2
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 abstract 2
- 239000002131 composite material Substances 0.000 abstract 2
- 239000004744 fabric Substances 0.000 abstract 2
- 239000001023 inorganic pigment Substances 0.000 abstract 2
- -1 phenol derivatives dihydroxy-benzenes Chemical class 0.000 abstract 2
- 150000002989 phenols Chemical class 0.000 abstract 2
- 229920000647 polyepoxide Polymers 0.000 abstract 2
- 235000012239 silicon dioxide Nutrition 0.000 abstract 2
- 229920006337 unsaturated polyester resin Polymers 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- 239000004593 Epoxy Substances 0.000 abstract 1
- AHGFXGSMYLFWEC-UHFFFAOYSA-N [SiH4].CC(=C)C(O)=O Chemical compound [SiH4].CC(=C)C(O)=O AHGFXGSMYLFWEC-UHFFFAOYSA-N 0.000 abstract 1
- 239000000654 additive Substances 0.000 abstract 1
- 229910000019 calcium carbonate Inorganic materials 0.000 abstract 1
- 150000001844 chromium Chemical class 0.000 abstract 1
- 239000000806 elastomer Substances 0.000 abstract 1
- 150000002118 epoxides Chemical class 0.000 abstract 1
- 239000003822 epoxy resin Substances 0.000 abstract 1
- 239000003365 glass fiber Substances 0.000 abstract 1
- 229910010272 inorganic material Inorganic materials 0.000 abstract 1
- 239000011147 inorganic material Substances 0.000 abstract 1
- 150000007522 mineralic acids Chemical class 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 150000007524 organic acids Chemical class 0.000 abstract 1
- 150000001282 organosilanes Chemical class 0.000 abstract 1
- 229920001568 phenolic resin Polymers 0.000 abstract 1
- 239000005011 phenolic resin Substances 0.000 abstract 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 abstract 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 abstract 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- 229920002050 silicone resin Polymers 0.000 abstract 1
- 229920002379 silicone rubber Polymers 0.000 abstract 1
- 229920005992 thermoplastic resin Polymers 0.000 abstract 1
- 229920001187 thermosetting polymer Polymers 0.000 abstract 1
- 239000004408 titanium dioxide Substances 0.000 abstract 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 abstract 1
- 229920002554 vinyl polymer Polymers 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/24—Coatings containing organic materials
- C03C25/40—Organo-silicon compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
- C08J5/06—Reinforcing macromolecular compounds with loose or coherent fibrous material using pretreated fibrous materials
- C08J5/08—Reinforcing macromolecular compounds with loose or coherent fibrous material using pretreated fibrous materials glass fibres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/04—Ingredients treated with organic substances
- C08K9/06—Ingredients treated with organic substances with silicon-containing compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Manufacturing & Machinery (AREA)
- General Life Sciences & Earth Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Reinforced Plastic Materials (AREA)
Abstract
1,260,798. Laminates. VEB KOMBINAT TECHNISCHES GLAS ILMENAU. 29 June, 1970, No. 31303/70. Heading B5N. [Also in Division D1] Method for improving the interfacial adhesion of inorganic fibre materials, especially desized fabrics of glass fibre materials to resins, wherein inorganic fibre materials are treated with a solution of an epoxy silane and, for the production of composite materials, a resin specific coupling agent of the silane type, containing unsaturated radicals, is added to the resin. Vinyl or methacrylate silane is used as the silane in the case of the use of unsaturated polyester resins and epoxy-silane is used for epoxide or phenolic resins. The inorganic fibre materials may also be impregnated with a solution comprising an organo-silane, preferably containing unsaturated radicals, and a chromium salt of an organic and/or inorganic acid. To improve the wettability by the resin, the inorganic fibre materials are treated with coupling agents containing polymeric compounds and/or phenol derivatives and/or silicic acid compounds and/or inorganic pigments. It is possible to add, as polymeric compounds, water soluble and/or water dispersible polymers and as phenol derivatives dihydroxy-benzenes, and as silicic acid compounds aqueous dispersions of silicon dioxide and/or silicic acid ester dispersions and/or dispersions of condensed silicic acid esters, and as inorganic pigments titanium dioxide, calcium carbonate and antimony trioxide preferably in dispersed form. For the production of composite materials, the above treated inorganic fibre materials are impregnated with a resin either in pure form or modified with silane. Examples of polymeric compounds are polyvinyl pyrrolidone solutions, epoxide resin dispersions, dispersions of unsaturated polyester resins; examples of phenol derivatives are resorcinol, precondensates or condensates of resorcinol with formaldehyde as solutions or dispersions and examples of resins are thermosetting or thermoplastic resins and silicone resins or elastomers. The fabric of inorganic material is first desized, preferably thermally and then impregnated with mixtures of the described coupling agents and additives, whereupon it is dried and set at an elevated temperature.
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DD14118669A DD81191A3 (en) | 1969-07-14 | 1969-07-14 | |
| DE19702031592 DE2031592A1 (en) | 1969-07-14 | 1970-06-26 | Process for improving the interfacial adhesion for inorganic fiber materials, in particular desized flat structures made of glass fiber materials |
| GB31303/70A GB1260798A (en) | 1969-07-14 | 1970-06-29 | Method of improving the interfacial adhesion of inorganic fibre materials |
| FR707025969A FR2051736B1 (en) | 1969-07-14 | 1970-07-15 |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DD14118669A DD81191A3 (en) | 1969-07-14 | 1969-07-14 | |
| GB31303/70A GB1260798A (en) | 1969-07-14 | 1970-06-29 | Method of improving the interfacial adhesion of inorganic fibre materials |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1260798A true GB1260798A (en) | 1972-01-19 |
Family
ID=25747258
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB31303/70A Expired GB1260798A (en) | 1969-07-14 | 1970-06-29 | Method of improving the interfacial adhesion of inorganic fibre materials |
Country Status (4)
| Country | Link |
|---|---|
| DD (1) | DD81191A3 (en) |
| DE (1) | DE2031592A1 (en) |
| FR (1) | FR2051736B1 (en) |
| GB (1) | GB1260798A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2001048073A1 (en) * | 1999-12-28 | 2001-07-05 | Dsm N.V. | Reactive particles, curable composition comprising the same and cured products |
| CN103466964A (en) * | 2013-09-10 | 2013-12-25 | 西安友基复合材料有限公司 | Preparation method of wetting agent for E glass fishing rod gauze |
| CN107022119A (en) * | 2017-05-15 | 2017-08-08 | 北京化工大学 | A kind of preparation method of graphene/silicon dioxide/rubber composite |
| CN112941933A (en) * | 2021-02-04 | 2021-06-11 | 郑州市娅丽达服饰有限公司 | Fabric with visible and invisible patterns, garment designed and processed by fabric and processing method |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3603909A1 (en) * | 1986-02-07 | 1987-08-13 | Frenzelit Werke Gmbh & Co Kg | Glass fibres having improved heat resistance, and process for the production thereof |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2931739A (en) * | 1956-10-08 | 1960-04-05 | Owens Corning Fiberglass Corp | Plastics and laminates formed of glass fibers and epoxy resins |
| US2946701A (en) * | 1957-11-12 | 1960-07-26 | Dow Corning | Method of treating glass with epoxysilanes and their epoxy-amine adducts, and the articles made thereby |
| NL243936A (en) * | 1958-10-01 | 1900-01-01 | ||
| US3216971A (en) * | 1960-12-16 | 1965-11-09 | Monsanto Co | Laminated structures |
| FR1495136A (en) * | 1966-09-23 | 1967-09-15 | Owens Corning Fiberglass Corp | Method and means for reinforcing elastomeric products with glass fibers |
| FR1356819A (en) * | 1963-05-20 | 1964-03-27 | B T R Ind Ltd | Coating composition for glass fibers, its applications and resulting products |
| FR1460717A (en) * | 1964-09-30 | 1966-03-04 | Owens Corning Fiberglass Corp | glass fiber reinforced elastomers |
| US3488310A (en) * | 1967-02-24 | 1970-01-06 | Owens Corning Fiberglass Corp | Urea-melamine-formaldehyde resins |
| FR1527997A (en) * | 1967-04-21 | 1968-06-07 | Wimpfheimer & Bro A | Composite and laminated glass and resin products |
-
1969
- 1969-07-14 DD DD14118669A patent/DD81191A3/xx unknown
-
1970
- 1970-06-26 DE DE19702031592 patent/DE2031592A1/en active Pending
- 1970-06-29 GB GB31303/70A patent/GB1260798A/en not_active Expired
- 1970-07-15 FR FR707025969A patent/FR2051736B1/fr not_active Expired
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2001048073A1 (en) * | 1999-12-28 | 2001-07-05 | Dsm N.V. | Reactive particles, curable composition comprising the same and cured products |
| US6686047B2 (en) | 1999-12-28 | 2004-02-03 | Dsm N.V. | Reactive particles, curable composition comprising the same and cured products |
| CN103466964A (en) * | 2013-09-10 | 2013-12-25 | 西安友基复合材料有限公司 | Preparation method of wetting agent for E glass fishing rod gauze |
| CN103466964B (en) * | 2013-09-10 | 2016-01-20 | 西安友基复合材料有限公司 | The preparation method of E glass fishing rod cloth yarn treating compound |
| CN107022119A (en) * | 2017-05-15 | 2017-08-08 | 北京化工大学 | A kind of preparation method of graphene/silicon dioxide/rubber composite |
| CN112941933A (en) * | 2021-02-04 | 2021-06-11 | 郑州市娅丽达服饰有限公司 | Fabric with visible and invisible patterns, garment designed and processed by fabric and processing method |
| CN112941933B (en) * | 2021-02-04 | 2023-04-11 | 郑州市娅丽达服饰有限公司 | Fabric with visible and invisible patterns, garment designed and processed by fabric and processing method |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2051736A1 (en) | 1971-04-09 |
| DD81191A3 (en) | 1971-04-12 |
| DE2031592A1 (en) | 1971-03-25 |
| FR2051736B1 (en) | 1973-05-25 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| PCNP | Patent ceased through non-payment of renewal fee |