GB1476272A - Sintered particles of tetrafluoroethylene polymers and process for their preparation - Google Patents
Sintered particles of tetrafluoroethylene polymers and process for their preparationInfo
- Publication number
- GB1476272A GB1476272A GB764275A GB764275A GB1476272A GB 1476272 A GB1476272 A GB 1476272A GB 764275 A GB764275 A GB 764275A GB 764275 A GB764275 A GB 764275A GB 1476272 A GB1476272 A GB 1476272A
- Authority
- GB
- United Kingdom
- Prior art keywords
- polymer
- particles
- dispersion
- sintered particles
- sintering temperature
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000002245 particle Substances 0.000 title abstract 13
- 229920000642 polymer Polymers 0.000 title abstract 10
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 title abstract 5
- 238000005245 sintering Methods 0.000 abstract 6
- 239000006185 dispersion Substances 0.000 abstract 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 2
- 238000012674 dispersion polymerization Methods 0.000 abstract 2
- 239000004088 foaming agent Substances 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 239000002736 nonionic surfactant Substances 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- BOSAWIQFTJIYIS-UHFFFAOYSA-N 1,1,1-trichloro-2,2,2-trifluoroethane Chemical compound FC(F)(F)C(Cl)(Cl)Cl BOSAWIQFTJIYIS-UHFFFAOYSA-N 0.000 abstract 1
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 abstract 1
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 abstract 1
- 235000012501 ammonium carbonate Nutrition 0.000 abstract 1
- 239000001099 ammonium carbonate Substances 0.000 abstract 1
- 239000003945 anionic surfactant Substances 0.000 abstract 1
- VEFXTGTZJOWDOF-UHFFFAOYSA-N benzene;hydrate Chemical compound O.C1=CC=CC=C1 VEFXTGTZJOWDOF-UHFFFAOYSA-N 0.000 abstract 1
- 238000001816 cooling Methods 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 abstract 1
- POLCUAVZOMRGSN-UHFFFAOYSA-N dipropyl ether Chemical compound CCCOCCC POLCUAVZOMRGSN-UHFFFAOYSA-N 0.000 abstract 1
- YRIUSKIDOIARQF-UHFFFAOYSA-N dodecyl benzenesulfonate Chemical compound CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 YRIUSKIDOIARQF-UHFFFAOYSA-N 0.000 abstract 1
- 239000012530 fluid Substances 0.000 abstract 1
- 239000006260 foam Substances 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- HCDGVLDPFQMKDK-UHFFFAOYSA-N hexafluoropropylene Chemical group FC(F)=C(F)C(F)(F)F HCDGVLDPFQMKDK-UHFFFAOYSA-N 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 239000000155 melt Substances 0.000 abstract 1
- 239000003208 petroleum Substances 0.000 abstract 1
- -1 polytetrafluoroethylene Polymers 0.000 abstract 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 abstract 1
- 239000004810 polytetrafluoroethylene Substances 0.000 abstract 1
- 238000001556 precipitation Methods 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
- UBOXGVDOUJQMTN-UHFFFAOYSA-N trichloroethylene Natural products ClCC(Cl)Cl UBOXGVDOUJQMTN-UHFFFAOYSA-N 0.000 abstract 1
- 239000011800 void material Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/12—Powdering or granulating
- C08J3/122—Pulverisation by spraying
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/06—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2327/12—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
- C08J2327/18—Homopolymers or copolymers of tetrafluoroethylene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
- C08L27/18—Homopolymers or copolymers or tetrafluoroethene
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Abstract
1476272 Sintered particles of tetrafluoroethylene polymer MITSUI FLUOROCHEMICALS CO Ltd 24 Feb 1975 [26 Feb 1974] 7642/75 Heading C3C Sintered particles of a non-melt-fabricable tetrafluoroethylene polymer (i.e. having a melt viscosity at 380 C. of at least 1 x 10<SP>9</SP> poises) prepared by aq. dispersion polymerization and having an average particle size of 5-500 microns, a sphere factor (as defined) of 1À0-1À2 and containing at least one enclosed void which causes the particles to have a precipitation rate in trichloroethylene (as defined) of no greater than 20% are claimed. The sintered particles are made by (a) atomizing an aq. dispersion obtained from the aq. dispersion polymerization of tetrafluoroethylene and containing (i) 5-80% by wt. of unsintered non- melt-fabricable particles of the polymer, of average particle size 0À05-0À5 micron, (ii) 0À2-20% by wt. of the particles of a non- ionic or anionic surfactant having a b.p. less than the polymer sintering temperature and (iii) 0À2-20% by wt. of either a liquid foaming agent having a b.p. below the polymer sintering temperature and a water solubility of 15 gm./100 ml. or less at 25 C., or a solid foaming agent which decomposes at a temperature below the polymer sintering temperature, (b) heating the atomized dispersion at above the polymer sintering temperature in an inert atmosphere, (c) cooling the sintered particles below the polymer sintering temperature, and (d) recovering the sintered particles. In the examples mixtures of a non-ionic surfactant or dodecyl benzene sulphonate, water and trichloro-trifluoro-ethane, propyl ether, ammonium carbonate or petroleum ether were emulsified, optionally with an ultrasonic wave generator and added to an aqueous dispersion of polytetrafluoroethylene or a copolymer of tetrafluoroethylene and hexafluoropropylene, and the mixture was placed in tank 1 of Fig. 1 from which it was fed to a binary fluid nozzle 5 where it was atomized at outlet 6 with air from compressor 3 and sent via pipe 4 to nozzle 5. The atomized dispersion emerges into sintering chamber 9 where heated air from 7 enters via pipe 8 and foams the drops of the dispersion and sinters the polymer particles which are then cooled in 10 by cool air from pipe 11. The sintered particles are then sent to cyclone 12 and recovered in receiver 20.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2189674A JPS5313229B2 (en) | 1974-02-26 | 1974-02-26 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1476272A true GB1476272A (en) | 1977-06-10 |
Family
ID=12067861
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB764275A Expired GB1476272A (en) | 1974-02-26 | 1975-02-24 | Sintered particles of tetrafluoroethylene polymers and process for their preparation |
Country Status (7)
| Country | Link |
|---|---|
| JP (1) | JPS5313229B2 (en) |
| CA (1) | CA1050719A (en) |
| DE (1) | DE2508361C2 (en) |
| FR (1) | FR2262069B1 (en) |
| GB (1) | GB1476272A (en) |
| IT (1) | IT1033208B (en) |
| NL (1) | NL180395C (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2242431A (en) * | 1990-03-31 | 1991-10-02 | Gore & Ass | Porous PTFE structures |
| US5677031A (en) * | 1990-03-31 | 1997-10-14 | W. L. Gore & Associates, Inc. | Porous PTFE structures |
| EP1059333A4 (en) * | 1998-02-24 | 2002-01-30 | Asahi Glass Fluoropolymers Co | AQUEOUS POLYTETRAFLUOROETHYLENE DISPERSION COMPOSITION |
| EP1246875A4 (en) * | 1999-12-02 | 2005-12-14 | Lexmark Int Inc | NUTRIATION-RESISTANT INK COMPOSITIONS |
| CN113146881A (en) * | 2020-09-07 | 2021-07-23 | 江西理工大学南昌校区 | Polymer powder spheroidizing device and method for preparing spherical powder material |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2209821A1 (en) * | 1995-01-09 | 1996-07-18 | Charles E. Singleton | Lightweight hardened protective coating and method for making and using same |
-
1974
- 1974-02-26 JP JP2189674A patent/JPS5313229B2/ja not_active Expired
-
1975
- 1975-02-24 GB GB764275A patent/GB1476272A/en not_active Expired
- 1975-02-24 CA CA220,935A patent/CA1050719A/en not_active Expired
- 1975-02-25 IT IT7520675A patent/IT1033208B/en active
- 1975-02-25 FR FR7505781A patent/FR2262069B1/fr not_active Expired
- 1975-02-26 DE DE2508361A patent/DE2508361C2/en not_active Expired
- 1975-02-26 NL NLAANVRAGE7502295,A patent/NL180395C/en not_active IP Right Cessation
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2242431A (en) * | 1990-03-31 | 1991-10-02 | Gore & Ass | Porous PTFE structures |
| GB2242431B (en) * | 1990-03-31 | 1994-05-11 | Gore & Ass | Porous PTFE structures |
| US5677031A (en) * | 1990-03-31 | 1997-10-14 | W. L. Gore & Associates, Inc. | Porous PTFE structures |
| EP1059333A4 (en) * | 1998-02-24 | 2002-01-30 | Asahi Glass Fluoropolymers Co | AQUEOUS POLYTETRAFLUOROETHYLENE DISPERSION COMPOSITION |
| US6498207B1 (en) | 1998-02-24 | 2002-12-24 | Asahi Glass Fluoropolymers Co. Ltd. | Aqueous polytetrafluoroethylene dispersion composition |
| EP1359194A1 (en) * | 1998-02-24 | 2003-11-05 | Asahi Glass Fluoropolymers Co., Ltd. | Polytetrafluoroethylene aqueous dispersion composition |
| EP1246875A4 (en) * | 1999-12-02 | 2005-12-14 | Lexmark Int Inc | NUTRIATION-RESISTANT INK COMPOSITIONS |
| CN113146881A (en) * | 2020-09-07 | 2021-07-23 | 江西理工大学南昌校区 | Polymer powder spheroidizing device and method for preparing spherical powder material |
Also Published As
| Publication number | Publication date |
|---|---|
| NL7502295A (en) | 1975-08-28 |
| JPS5313229B2 (en) | 1978-05-09 |
| DE2508361C2 (en) | 1985-04-11 |
| FR2262069A1 (en) | 1975-09-19 |
| DE2508361A1 (en) | 1975-08-28 |
| NL180395C (en) | 1987-02-16 |
| FR2262069B1 (en) | 1979-03-02 |
| CA1050719A (en) | 1979-03-20 |
| IT1033208B (en) | 1979-07-10 |
| JPS50114447A (en) | 1975-09-08 |
| NL180395B (en) | 1986-09-16 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| PCNP | Patent ceased through non-payment of renewal fee |