GB2079418A - Shot - Google Patents
Shot Download PDFInfo
- Publication number
- GB2079418A GB2079418A GB8022838A GB8022838A GB2079418A GB 2079418 A GB2079418 A GB 2079418A GB 8022838 A GB8022838 A GB 8022838A GB 8022838 A GB8022838 A GB 8022838A GB 2079418 A GB2079418 A GB 2079418A
- Authority
- GB
- United Kingdom
- Prior art keywords
- shot
- coating
- molybdenum disulphide
- cartridge
- shotgun
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 46
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 claims abstract description 42
- 229910052742 iron Inorganic materials 0.000 claims abstract description 23
- 239000011347 resin Substances 0.000 claims abstract description 17
- 229920005989 resin Polymers 0.000 claims abstract description 17
- 239000007788 liquid Substances 0.000 claims abstract description 12
- 238000004519 manufacturing process Methods 0.000 claims abstract description 7
- 238000000576 coating method Methods 0.000 claims description 42
- 239000011248 coating agent Substances 0.000 claims description 38
- 238000000034 method Methods 0.000 claims description 10
- 239000007767 bonding agent Substances 0.000 claims description 8
- 238000001723 curing Methods 0.000 claims description 6
- 239000000843 powder Substances 0.000 claims description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 2
- 239000000969 carrier Substances 0.000 claims description 2
- 229940125718 cold curing agent Drugs 0.000 claims description 2
- 238000005260 corrosion Methods 0.000 claims description 2
- 230000007797 corrosion Effects 0.000 claims description 2
- 230000008021 deposition Effects 0.000 claims description 2
- 238000010304 firing Methods 0.000 claims description 2
- 229910002804 graphite Inorganic materials 0.000 claims description 2
- 239000010439 graphite Substances 0.000 claims description 2
- 238000013007 heat curing Methods 0.000 claims description 2
- 229910052751 metal Inorganic materials 0.000 claims description 2
- 239000002184 metal Substances 0.000 claims description 2
- 230000009467 reduction Effects 0.000 claims description 2
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F42—AMMUNITION; BLASTING
- F42B—EXPLOSIVE CHARGES, e.g. FOR BLASTING, FIREWORKS, AMMUNITION
- F42B12/00—Projectiles, missiles or mines characterised by the warhead, the intended effect, or the material
- F42B12/72—Projectiles, missiles or mines characterised by the warhead, the intended effect, or the material characterised by the material
- F42B12/76—Projectiles, missiles or mines characterised by the warhead, the intended effect, or the material characterised by the material of the casing
- F42B12/80—Coatings
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F1/00—Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
- B22F1/10—Metallic powder containing lubricating or binding agents; Metallic powder containing organic material
- B22F1/102—Metallic powder coated with organic material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F1/00—Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
- B22F1/16—Metallic particles coated with a non-metal
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F42—AMMUNITION; BLASTING
- F42B—EXPLOSIVE CHARGES, e.g. FOR BLASTING, FIREWORKS, AMMUNITION
- F42B7/00—Shotgun ammunition
- F42B7/02—Cartridges, i.e. cases with propellant charge and missile
- F42B7/04—Cartridges, i.e. cases with propellant charge and missile of pellet type
- F42B7/046—Pellets or shot therefor
Landscapes
- Engineering & Computer Science (AREA)
- General Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Powder Metallurgy (AREA)
Abstract
In a shotgun cartridge having lead or iron shot, the shot is coated with molybdenum disulphide which may be bonded to the shot surface by resin. Preferably the molybdenum disulphide is applied from a liquid carrier and the shot is tumbled in the liquid followed by curing which may be at high temperature. Various advantages and benefits such as improved patterns of shot distribution, reduced damage to barrels and low cost production are described.
Description
SPECiFICATION
Improvements in shot for shotgun cartridges
This invention relates to improvements in shot for shotgun cartridges and has application to lead or iron shot.
According to this invention, in a cartridge for a shotgun, the shot of lead or iron is coated with molybdenum disulphide.
The coating of molybdenum disulphide provides a low friction surface on the shot which obviates the metal surface of the shot contacting the barrel of the shotgun in use. Thus, with lead shot, the deposition of lead in the barrel (known as leading) is avoided; and with iron shot, scoring of the barrel is avoided.
The application of a coating of molybdenum disulphide to the shot provides a simpler and less expensive solution to overcoming the problems, such as of leading and scoring which, at present have to be accommodated in special production techniques such as using graphite coated shot, wax coated drive wads, plastic shot cups, and the use of very soft iron.
The application of a coating of molybdenum
disulphide to the shot of a shotgun cartridge provides other advantages in performance of the cartridge such as improving patterns of shot distribution on firing of the cartridge. This arises from
reductions in deformation of the shot as pressure is
applied and as the shot is constrained by the choke
in the shotgun barrel. In addition, molybdenum
disulphide coated shot is less likely to ball under the condition when gas leaks past the drive wad.
The coating of molybdenum disulphide may be
applied to the lead or iron shot as a dry powder
coating, and the coating may be applied by tumbling the shot with powdrous molybdenum disulphide. It
is found that the dry powder bonds to the surface of the shot.
The coating of molybdenum disulphide is preferably applied to the shot from a liquid carrier which allows controlled thin coatings to be applied. The liquid carrier may be volatile liquid which comprises
resin bonding agents to bond the molybdenum disulphide to the surface of the shot.
The type of resin bonding agent may be varied, and can be a cold curing agent which cures at ambient temperatures on volatilisation of the carrier.
However, improved bonding may be achieved by employing hot curing resins.
The coating of molybdenum disulphide with a
resin bonding agent has particular advantages for
iron shot as the coating produces a corrosion resistant surface which overcomes certain problems
arisng in the use of iron shot.
In use of such liquid carriers for the molybdenum disulphide, the shot may be tumbled in a small quantity of the carrier until the shot is fully coated and subsequently becomes polished to give a smooth surface coated with molybdenum disulphide. With the use of ambient temperature curing resins, the shot may be tumbled until the shot is dry with the carrier having volatised. With high temperature curing resins, the shot may be subjected to
heat-curing after coating by tumbling.
It is found that only a very thin coating of
molybdenum disulphide is required. Coatings having a thickness from 0.000111 to 0.00038 have been found to be adequate.
Accordingly, the cost of applying the molybdenum disulphide coating is very low, and investment in plant for applying the coating by the preferred method of tumbling is also low, and these low costs more than offset the advantages to be achieved by this invention.
1. In a cartridge for a shotgun, the shot of lead or iron is coated with molybdenum disulphide.
2. In a cartridge for a shotgun according claim 1, the molybdenum disulphide coating is bonded by a resin to the surface of the shot.
3. In a cartridge for a shotgun according to claim 2, the coating is cured at high temperature.
4. In a cartridge for a shotgun according to any one of the preceding claims, the coating of molybdenum disulphide has a thickness within the range of 0.0001" to 0.0003".
5. A cartridge for a shotgun having lead or iron shot coated with molybdenum disulphide substantially as hereinbefore described.
6. A method of making a cartridge for a shot gun wherein the lead or iron shot is coated with molybdenum disulphide prior to filling and assembly of the cartridge.
7. The method according to claim 6 wherein the coating is applied by tumbling the shot in a liquid carrierforthe molybdenum disulphide.
8. The method according to claim 7 wherein the coating comprises a resin bonding agent.
9. The method according to claim 8 wherein the coating is cutted at high temperature.
10. The method of making lead or iron shot for use in a cartridge for a shotgun substantially as hereinbefore described.
**WARNING** end of DESC field may overlap start of CLMS **.
Claims (10)
1. In a cartridge for a shotgun, the shot of lead or iron is coated with molybdenum disulphide.
2. In a cartridge for a shotgun according claim 1, the molybdenum disulphide coating is bonded by a resin to the surface of the shot.
3. In a cartridge for a shotgun according to claim 2, the coating is cured at high temperature.
4. In a cartridge for a shotgun according to any one of the preceding claims, the coating of molybdenum disulphide has a thickness within the range of 0.0001" to 0.0003".
5. A cartridge for a shotgun having lead or iron shot coated with molybdenum disulphide substantially as hereinbefore described.
6. A method of making a cartridge for a shot gun wherein the lead or iron shot is coated with molybdenum disulphide prior to filling and assembly of the cartridge.
7. The method according to claim 6 wherein the coating is applied by tumbling the shot in a liquid carrierforthe molybdenum disulphide.
8. The method according to claim 7 wherein the coating comprises a resin bonding agent.
9. The method according to claim 8 wherein the coating is cutted at high temperature.
10. The method of making lead or iron shot for use in a cartridge for a shotgun substantially as hereinbefore described.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB8022838A GB2079418A (en) | 1980-07-11 | 1980-07-11 | Shot |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB8022838A GB2079418A (en) | 1980-07-11 | 1980-07-11 | Shot |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB2079418A true GB2079418A (en) | 1982-01-20 |
Family
ID=10514718
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB8022838A Withdrawn GB2079418A (en) | 1980-07-11 | 1980-07-11 | Shot |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB2079418A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1996021839A1 (en) * | 1995-01-11 | 1996-07-18 | David Bradley Taylor | Improvements in or relating to shot |
| WO1997025587A1 (en) * | 1996-01-10 | 1997-07-17 | David Bradley Taylor | Environmentally sealed shot |
| WO1999000468A1 (en) * | 1997-06-26 | 1999-01-07 | David Thomas Brown | Ballistics conditioning with molybdenum disulfide |
| US6173652B1 (en) | 1996-07-10 | 2001-01-16 | Bradley Taylor Holding Company Limited | Environmentally sealed shot |
| US6576598B2 (en) | 2001-08-22 | 2003-06-10 | David Thomas Brown | Ballistics conditioning |
-
1980
- 1980-07-11 GB GB8022838A patent/GB2079418A/en not_active Withdrawn
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1996021839A1 (en) * | 1995-01-11 | 1996-07-18 | David Bradley Taylor | Improvements in or relating to shot |
| WO1997025587A1 (en) * | 1996-01-10 | 1997-07-17 | David Bradley Taylor | Environmentally sealed shot |
| US6173652B1 (en) | 1996-07-10 | 2001-01-16 | Bradley Taylor Holding Company Limited | Environmentally sealed shot |
| WO1999000468A1 (en) * | 1997-06-26 | 1999-01-07 | David Thomas Brown | Ballistics conditioning with molybdenum disulfide |
| US6576598B2 (en) | 2001-08-22 | 2003-06-10 | David Thomas Brown | Ballistics conditioning |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| WAP | Application withdrawn, taken to be withdrawn or refused ** after publication under section 16(1) |