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HRP20020069A2 - Device for continuous fermentation of solid biological waste - Google Patents

Device for continuous fermentation of solid biological waste Download PDF

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Publication number
HRP20020069A2
HRP20020069A2 HRP20020069A HRP20020069A2 HR P20020069 A2 HRP20020069 A2 HR P20020069A2 HR P20020069 A HRP20020069 A HR P20020069A HR P20020069 A2 HRP20020069 A2 HR P20020069A2
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fermentation
waste
gas
biological waste
tube
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Tihomir Uljak
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Tihomir Uljak
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Priority to HRP20020069 priority Critical patent/HRP20020069A2/en
Priority to PCT/HR2003/000003 priority patent/WO2003062157A2/en
Priority to AU2003214483A priority patent/AU2003214483A1/en
Publication of HRP20020069A2 publication Critical patent/HRP20020069A2/en

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    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12MAPPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M21/00Bioreactors or fermenters specially adapted for specific uses
    • C12M21/04Bioreactors or fermenters specially adapted for specific uses for producing gas, e.g. biogas
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12MAPPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M23/00Constructional details, e.g. recesses, hinges
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12MAPPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M23/00Constructional details, e.g. recesses, hinges
    • C12M23/02Form or structure of the vessel
    • C12M23/18Open ponds; Greenhouse type or underground installations
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12MAPPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M23/00Constructional details, e.g. recesses, hinges
    • C12M23/36Means for collection or storage of gas; Gas holders
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12MAPPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M33/00Means for introduction, transport, positioning, extraction, harvesting, peeling or sampling of biological material in or from the apparatus
    • C12M33/16Screw conveyor
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/02Biological treatment
    • C02F11/04Anaerobic treatment; Production of methane by such processes

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • Zoology (AREA)
  • Genetics & Genomics (AREA)
  • Biochemistry (AREA)
  • Sustainable Development (AREA)
  • Microbiology (AREA)
  • Biotechnology (AREA)
  • General Engineering & Computer Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Clinical Laboratory Science (AREA)
  • Molecular Biology (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Fertilizers (AREA)
  • Apparatus Associated With Microorganisms And Enzymes (AREA)
  • Treatment Of Sludge (AREA)
  • Processing Of Solid Wastes (AREA)

Description

Područje na koje se izum odnosi The field to which the invention relates

Ovaj izum odnosi se na novu tehnologiju razgradnje krutog otpada biološkog podrijetla, postupkom kontinuirane fermentacije pri čemu nastaje energetski vrijedan plin metan koji se može koristiti za zagrijavanje prostorija ili proizvodnju električne energije. This invention relates to a new technology for the decomposition of solid waste of biological origin, through a process of continuous fermentation, which produces energy-valuable methane gas that can be used to heat rooms or produce electricity.

Tehnički problem Technical problem

Kod razgradnje krutog otpada biološkog porijekla postupkom fermentacije problem je što je postupak diskontinuiran. Otpad mora biti pokriven tako da u njega ne može prodrijeti zrak, a unutar njega se postavljaju drenažne cijevi koje prikupljaju proizvedene energetski vrijedne plinove. Problem je što taj proces diskontinuiran, tj. traje neko vrijeme, nakon čega se otpad mora izvaditi, drenažne cijevi ukloniti, a nakon toga cijeli postupak se mora ponoviti, što traži dosta rada i vremena. When breaking down solid waste of biological origin by fermentation, the problem is that the process is discontinuous. The waste must be covered so that air cannot penetrate into it, and drainage pipes are placed inside it to collect the energy-valuable gases produced. The problem is that this process is discontinuous, i.e. it lasts for some time, after which the waste must be removed, the drainage pipes must be removed, and then the whole process must be repeated, which requires a lot of work and time.

Stanje tehnike State of the art

Problem fermentacije krutog biološkog otpada kao što je kruti stajski gnoj, otpaci u pilanama i komunalni otpad bogat materijalom biološkog podrijetla rješava se tako da se prave velike hrpe otpada u koje se prilikom dodavanja otpada postavljaju drenažne cijevi kojima se prikupljaju energetski plinovi. Kad se gomila otpada naslaže do željene veličine otpad se pokriva tako da zrak ne može prodrijeti unutra, a i da nastali plinovi ne mogu otići nekontrolirano van. Fermentacija traje od nekoliko mjeseci do više godina, što ovisi o krupnoći otpadaka i njihovoj vlažnosti. Što je otpad sitniji i vlažniji to je fermentacija brža. Nakon završene fermentacije hrpa otpada se mora razgraditi, odložiti na drugo mjesto, te ponovno izgraditi. The problem of fermentation of solid biological waste such as solid manure, sawmill waste and municipal waste rich in material of biological origin is solved by making large piles of waste into which, when adding waste, drainage pipes are placed to collect energy gases. When the pile of waste is piled up to the desired size, the waste is covered so that air cannot penetrate inside, and that the resulting gases cannot escape uncontrolled. Fermentation lasts from several months to several years, which depends on the size of the waste and its humidity. The finer and wetter the waste, the faster the fermentation. After fermentation is complete, the pile of waste must be decomposed, disposed of in another place, and rebuilt.

Kod fermentacije stajskog gnojiva gnoj se puni u posebne komore unutar kojih se postavljaju drenažne cijevi, a kad se komora napuni potrebno ju je hermetički zatvoriti. Nakon nekoliko mjeseci kad postupak fermentacije završi komora se otvara i vadi se fermentirani gnoj. U hladnijim krajevima pri početku fermentacije masu je ponekad potrebno i zagrijati da bi otpočeo postupak fermentacije. During manure fermentation, the manure is filled into special chambers inside which drainage pipes are placed, and when the chamber is full, it must be hermetically sealed. After a few months, when the fermentation process is over, the chamber is opened and the fermented manure is taken out. In colder regions, at the beginning of fermentation, it is sometimes necessary to heat the mass in order to start the fermentation process.

Kod velikih deponija komunalnog smeća drenažne cijevi se postavljaju u slojevima, postupak fermentacije je vrlo spor, traje i do 30 godina, a nakon tog drenažne cijevi ostaju u deponiji. In large landfills for municipal waste, drainage pipes are laid in layers, the fermentation process is very slow, it lasts up to 30 years, and after that the drainage pipes remain in the landfill.

Izlaganje suštine izuma Presentation of the essence of the invention

Primarni cilj ove tehnologije je da se na malom prostoru, s vrlo malo ljudskog rada, odvija fermentacija biološkog otpada kontinuirano i brzo. The primary goal of this technology is that in a small space, with very little human work, the fermentation of biological waste takes place continuously and quickly.

Sekundarni cilj je omogućiti preradu komunalnog otpada bez prethodnog razdvajanja biološkog otpada od inertnog otpada. The secondary goal is to enable the processing of municipal waste without first separating biological waste from inert waste.

Daljnji cilj je omogućiti pročišćavanje biološki zagađenih otpadnih voda od suspendiranih čestica. A further goal is to enable purification of biologically polluted wastewater from suspended particles.

Prednosti tehnologije bit će prikazani u opisu koji slijedi. The advantages of the technology will be shown in the following description.

Uređaj za kontinuiranu fermentaciju krutog biološkog otpada obuhvaća konstrukciju koja se sastoji od tri dijela. Svježi biološki otpad dodaje se na prvi dio konstrukcije, ulaznu prostoriju, gdje se otpad potapa u vodu. Masa otpada i vode klizi prema dolje ukoso i postepeno ulazi u drugi dio konstrukcije koji izgleda kao ukoso položena cijev i u kojem se odvija proces fermentacije. Ova fermentacijska cijev je s gornje strane sužena tako da se pri vrhu ove fermentacijske cijevi koncentrira plin nastao u procesu fermentacije. Voda u koju je uronjen otpad služi kao brtva koja sprječava plin da nekontrolirano izlaz kroz ulaznu i izlaznu prostoriju, a također voda ubrzava proces fermentacije. Masa koja postepeno fermentira klizi prema dolje i dolazi u izlaznu prostoriju gdje elevator vadi fermentirani otpad. Koliko se fermentiranog otpada izvadi van toliku prostornu količinu svježeg otpada moguće je dodati u ulaznu prostoriju. Plin koji se koncentrira u gornjem dijelu fermentacijske cijevi, kroz plinsku cijev izlazi van pod tlakom koji ovisi o razlici u nivou vode(h) u fermentacijskoj cijevi i izvan nje. Plin se odvodi u rezervoar ili prema potrošačima i potrebno ga je održavati pod stalno, otprilike, jednakim tlakom. Ako se plin sporo odvodi tlak plina se može povećati tako da se nivo vode unutar fermentacijske cijevi spušta pa može doći do nekontroliranog oticanja plina kroz ulaznu i izlaznu prostoriju. Proces fermentacije odvija se u vodi tako da je fermentacija puno brža i traje nekoliko mjeseci, što ovisi i o krupnoći komada biootpada. U hladnijim krajevima na početku rada potrebno je masu lagano zagrijati i nakon toga toplina se stalno održava na potrebnom nivou. The device for continuous fermentation of solid biological waste includes a construction consisting of three parts. Fresh biological waste is added to the first part of the structure, the entrance room, where the waste is immersed in water. The mass of waste and water slides down diagonally and gradually enters the second part of the structure, which looks like a slanted pipe and where the fermentation process takes place. This fermentation tube is narrowed at the top so that the gas produced during the fermentation process is concentrated near the top of this fermentation tube. The water in which the waste is immersed serves as a seal that prevents the gas from escaping uncontrollably through the entrance and exit room, and also the water accelerates the fermentation process. The gradually fermenting mass slides down and comes to the exit room where the elevator takes out the fermented waste. As much fermented waste is taken out as much fresh waste can be added to the entrance room. The gas that is concentrated in the upper part of the fermentation tube exits through the gas tube under a pressure that depends on the difference in the level of water(s) in the fermentation tube and outside it. The gas is led to the reservoir or to the consumers and it is necessary to maintain it under constant, approximately equal pressure. If the gas is drained off slowly, the gas pressure can increase so that the water level inside the fermentation tube drops, which can lead to an uncontrolled flow of gas through the inlet and outlet rooms. The fermentation process takes place in water, so fermentation is much faster and lasts several months, which also depends on the size of the pieces of biowaste. In colder regions, at the beginning of work, it is necessary to warm the mass slightly and after that the heat is constantly maintained at the required level.

Ako je otpad čistiji i ima veći sadržaj biološkog otpada ukošenost treba biti manja, a ako u otpadu ima krupnijih komada inertnog otpada kosina dna treba biti veća. If the waste is cleaner and has a higher content of biological waste, the slope should be lower, and if there are larger pieces of inert waste in the waste, the slope of the bottom should be higher.

Kratki opis crteža Brief description of the drawing

Popratni crtež koji je uključen u opis i koji čini dio opisa izuma, prikazuje uzdužni presjek uređaja i pomaže kod objašnjenja tehnologije prerade. Na crtežu se vidi da se otpad i voda dodaju u ulaznu prostoriju(1), da smjesa otpada i vode klizi prema fermentacijskoj cijevi(2), i izlaznoj prostoriji(3), odakle se vadi elevatorom(5). Također se vidi da se plin nastao u procesu fermentacije skuplja u vrhu fermentacijske cijevi(2) gdje kroz plinsku cijev(4), odlazi dalje. The accompanying drawing, which is included in the description and forms part of the description of the invention, shows a longitudinal section of the device and helps to explain the processing technology. The drawing shows that waste and water are added to the entrance room (1), that the mixture of waste and water slides towards the fermentation tube (2), and the exit room (3), from where it is removed by an elevator (5). It can also be seen that the gas created in the fermentation process collects in the top of the fermentation tube (2) where it goes further through the gas tube (4).

Detaljan opis najmanje jednog od načina ostvarivanja izuma A detailed description of at least one way of realizing the invention

Upućujući na crtež, može se vidjeti da se uređaj za kontinuiranu fermentaciju krutog biološkog otpada sastoji od ulazne prostorije (1), u koju se dodaje svježi otpad. Ova ulazna prostorija ispunjena je vodom tako da se svježi otpad potapa u vodu. Potopljeni otpad se sliježe i postepeno klizi u fermentacijsku cijev (2), u kojoj se odvija proces fermentacije bez prisustva zraka. U fermentacijskoj cijevi uz postepenu fermentaciju masa i dalje polagano klizi prema izlaznoj prostoriji (3). Nakon nekoliko mjeseci fermentacije i laganog klizanja fermentirana masa ulazi u izlaznu prostoriju (3), gdje se vadi elevatorom (5). Brzina klizanja mase kroz čitav uređaj ovisi o tom koliko se masa brzo vadi. Prilikom vađenja potrebno je paziti da se ne vadi otpad u kojem još traje proces fermentacije, što se vidi po mjehurićima plina koji izbijaju na površinu vode u izlaznoj prostoriji. Ako se pojave mjehurići proces vađenja odmah treba prekinuti te nastaviti tek nakon nekoliko dana. Referring to the drawing, it can be seen that the device for continuous fermentation of solid biological waste consists of an entrance room (1), into which fresh waste is added. This entrance room is filled with water so that the fresh waste is immersed in the water. The submerged waste settles and gradually slides into the fermentation tube (2), where the fermentation process takes place without the presence of air. In the fermentation tube, with gradual fermentation, the mass continues to slide slowly towards the exit room (3). After several months of fermentation and gentle sliding, the fermented mass enters the exit room (3), where it is removed by an elevator (5). The speed at which the mass slides through the entire device depends on how quickly the mass is removed. When removing, care must be taken not to remove waste in which the fermentation process is still ongoing, which can be seen by the gas bubbles that rise to the surface of the water in the exit room. If bubbles appear, the extraction process should be stopped immediately and continued only after a few days.

Razina vode u ulaznoj prostoriji(1), i izlaznoj prostoriji (3), je ista i ona se treba održavati na uvijek istom nivou. Razina vode unutar fermentacijske cijevi (2), je niži zbog tog što se plinovi nastali u procesu fermentacije skupljaju pri vrhu cijevi i istiskuju vodu prema dolje. Ovdje voda služi kao brtva koja sprječava nekontrolirani izlazak proizvedenog plina. Što plina ima više, viši mu je i tlak te je razina tekućine u fermentacijskoj cijevi niža. Koliki je tlak ovisi o razlici u razini tekućine u fermentacijskoj cijevi i razine u ulaznoj i izlaznoj prostoriji. Pri određenom tlaku plin se mora ispuštati prema skladištu ili potrošačima kroz izlaznu plinsku cijev(4). Ako se plin ne bi odveo pri određenom tlaku razina tekućine u fermentacijskoj cijevi (2) bi se nastavila spuštati te bi plin počeo nekontrolirano isticati kroz ulaznu i izlaznu prostoriju. The water level in the entrance room (1) and the exit room (3) is the same and should always be maintained at the same level. The water level inside the fermentation tube (2) is lower because the gases created in the fermentation process collect at the top of the tube and push the water downwards. Here, the water serves as a seal that prevents the uncontrolled escape of the produced gas. The more gas there is, the higher its pressure and the lower the liquid level in the fermentation tube. The pressure depends on the difference in the liquid level in the fermentation tube and the level in the inlet and outlet rooms. At a certain pressure, the gas must be released towards the storage or consumers through the outlet gas pipe (4). If the gas was not removed at a certain pressure, the liquid level in the fermentation pipe (2) would continue to drop and the gas would begin to flow out uncontrollably through the entrance and exit rooms.

Način primjene izuma Method of application of the invention

Na taj način izum uređaja za kontinuiranu fermentaciju krutog biološkog otpada omogućuje korištenje različitog biološkog otpada za proizvodnju energetski vrijednog plina metana. In this way, the invention of a device for the continuous fermentation of solid biological waste enables the use of different biological waste for the production of energy-valuable methane gas.

Stajsko gnojivo je najbolji materijal za fermentaciju, a i fermentacija najbrže traje. Manure is the best material for fermentation, and fermentation lasts the fastest.

Komunalni otpad koji predstavlja veliki ekološki problem u gradovima možemo direktno prerađivati, bez prethodnog razdvajanja, ovom tehnologijom pad uvjetom da u njemu nema topivih kemijskih spojeva štetnih za anaerobne bakterije koje izazivaju proces fermentacije. Fermentira sav otpad koji može fermentirati, a preostali inertni otpad i plastike naknadno, ispiranjem, odvajamo od fermentiranog otpada. Municipal waste, which represents a major ecological problem in cities, can be processed directly, without prior separation, with this technology, provided that it does not contain soluble chemical compounds harmful to anaerobic bacteria that cause the fermentation process. It ferments all the waste that can ferment, and the remaining inert waste and plastics are subsequently separated from the fermented waste by washing.

Komunalni mulj i ostale otpadne vode (ako nisu zatrovane štetnim kemijskim spojevima) bogate biomaterijom možemo pročišćavati ovom tehnologijom tako da ulaznu prostoriju(1), ispunimo slamom, te kroz nju filtriramo mulj. Čim se površina slame popuni muljem dodajemo novi sloj slame ili sličnog materijala. Smjesa slame i mulja se potapa i sliježe prema dolje, a profiltrirana voda odlazi na stranu iz ulazne prostorije. Municipal sludge and other wastewater (if not poisoned with harmful chemical compounds) rich in biomass can be purified with this technology by filling the entrance room (1) with straw and filtering the sludge through it. As soon as the surface of the straw is filled with sludge, we add a new layer of straw or similar material. The mixture of straw and sludge sinks and settles down, and the filtered water goes to the side from the entrance room.

Claims (4)

1. Uređaj za kontinuiranu fermentaciju krutog biološkog otpada sastoji se od konstrukcije unutar koje se odvija, dodavanje biološkog otpada, fermentacija otpada, pretvaranje biootpada u fermentirani biootpad, te njegovo vađenje iz konstrukcije, a čitav proces naznačen time, omogućuje element, nazvan fermentacijska cijev(2) koja je koso položena, unutar koje se odvija proces fermentacije u vodu uronjenih krutih biootpadaka i koja u gornjem dijelu ima suženje koje onemogućuje nekontrolirano isticanje plina.1. The device for continuous fermentation of solid biological waste consists of a structure inside which the addition of biological waste, fermentation of waste, conversion of biowaste into fermented biowaste, and its removal from the structure takes place, and the entire process indicated by this is enabled by an element called a fermentation tube ( 2) which is slanted, inside which the fermentation process of solid bio-waste immersed in water takes place and which has a narrowing in the upper part that prevents the uncontrolled outflow of gas. 2. Uređaj za kontinuiranu fermentaciju krutog biološkog otpada prema zahtjevu 1, naznačen time, da u navedenu fermentacijsku cijev(2) otpadna masa klizi iz ulazne prostorije(1) u suženi, ulazni otvor fermentacijske cijevi(2).2. Device for continuous fermentation of solid biological waste according to claim 1, characterized by the fact that the waste mass slides into said fermentation pipe (2) from the entrance room (1) into the narrowed, entrance opening of the fermentation pipe (2). 3. Uređaj za kontinuiranu fermentaciju krutog biološkog otpada prema zahtjevu 1, naznačen time, da iz navedene fermentacijske cijevi(2) otpad klizi naniže prema izlazu na donjem kraju fermentacijske cijevi gdje se nalazi izlazna prostorija(3) iz koje se elevatorom(5) fermentirani otpad vadi van.3. A device for continuous fermentation of solid biological waste according to claim 1, characterized by the fact that from the said fermentation pipe (2) the waste slides downwards towards the exit at the lower end of the fermentation pipe where there is an exit room (3) from which the fermented takes the waste out. 4. Uređaj za kontinuiranu fermentaciju krutog biološkog otpada prema zahtjevu 1, naznačen time, da se u najvišoj točci fermentacijske cijevi(2) nalazi plinska cijev(4) kroz koji se odvodi plin nastao u procesu fermentacije.4. Device for continuous fermentation of solid biological waste according to claim 1, characterized by the fact that at the highest point of the fermentation tube (2) there is a gas tube (4) through which the gas produced in the fermentation process is discharged.
HRP20020069 2002-01-25 2002-01-25 Device for continuous fermentation of solid biological waste HRP20020069A2 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
HRP20020069 HRP20020069A2 (en) 2002-01-25 2002-01-25 Device for continuous fermentation of solid biological waste
PCT/HR2003/000003 WO2003062157A2 (en) 2002-01-25 2003-01-27 Unit for continous fermentation of hard biological waste
AU2003214483A AU2003214483A1 (en) 2002-01-25 2003-01-27 Unit for continous fermentation of hard biological waste

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HRP20020069 HRP20020069A2 (en) 2002-01-25 2002-01-25 Device for continuous fermentation of solid biological waste

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FR2480778A1 (en) * 1980-04-21 1981-10-23 Dedenon Jean Marie IMPROVEMENTS IN FACILITIES AND PROCESSES FOR THE PREPARATION OF COMBUSTIBLE GASES BY FERMENTATION
SE500845C2 (en) * 1989-05-30 1994-09-19 Vbb Konsult Ab Procedure for the recovery of combustible gas, soil and a fuel fraction from waste
CN1306497A (en) * 1998-06-23 2001-08-01 超级瓦斯有限公司 System for anaerobic treatment of fluid organic material
WO2001009280A2 (en) * 1999-07-30 2001-02-08 Bioelex Corporation Two-phase type methane fermentation reactor

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WO2003062157A3 (en) 2004-03-18
AU2003214483A1 (en) 2003-09-02
AU2003214483A8 (en) 2003-09-02
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