ITUA20163932A1 - Complesso osso-azotato di ferro, sistema catalitico comprendente detto complesso osso-azotato di ferro e procedimento per la (co)polimerizzazione di dieni coniugati - Google Patents

Complesso osso-azotato di ferro, sistema catalitico comprendente detto complesso osso-azotato di ferro e procedimento per la (co)polimerizzazione di dieni coniugati

Info

Publication number: ITUA20163932A1
Authority: IT; Italy
Prior art keywords: azotate; bone; iron; complex; polymerization
Prior art date: 2016-05-30

Application number

ITUA2016A003932A

Other languages

English (en)

Inventor

Guido Pampaloni

Anna Sommazzi

Giovanni Ricci

Francesco Masi

Giuseppe Leone

Original Assignee

Versalis Spa

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2016-05-30

Filing date

2016-05-30

Publication date

2017-11-30

2016-05-30 Application filed by Versalis Spa filed Critical Versalis Spa

2016-05-30 Priority to ITUA2016A003932A priority Critical patent/ITUA20163932A1/it

2017-05-29 Priority to CN201780026611.5A priority patent/CN109071719B/zh

2017-05-29 Priority to US16/300,597 priority patent/US20190374932A1/en

2017-05-29 Priority to BR112018074845-5A priority patent/BR112018074845B1/pt

2017-05-29 Priority to CA3016659A priority patent/CA3016659A1/en

2017-05-29 Priority to EA201891812A priority patent/EA037267B1/ru

2017-05-29 Priority to KR1020187028725A priority patent/KR102383025B1/ko

2017-05-29 Priority to PCT/IB2017/053142 priority patent/WO2017208128A1/en

2017-11-30 Publication of ITUA20163932A1 publication Critical patent/ITUA20163932A1/it

2018-09-06 Priority to ZA2018/05991A priority patent/ZA201805991B/en

2018-09-26 Priority to SA518400113A priority patent/SA518400113B1/ar

2021-03-17 Priority to US17/204,570 priority patent/US11872548B2/en

Classifications

- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/20—Carbonyls
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/04—Nickel compounds
- C07F15/045—Nickel compounds without a metal-carbon linkage
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/02—Iron compounds
- C07F15/025—Iron compounds without a metal-carbon linkage
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F136/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F136/02—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F136/04—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
- C08F36/06—Butadiene
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
- C08F36/08—Isoprene
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/52—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from boron, aluminium, gallium, indium, thallium or rare earths
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/70—Iron group metals, platinum group metals or compounds thereof
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/70—Iron group metals, platinum group metals or compounds thereof
- C08F4/7001—Iron group metals, platinum group metals or compounds thereof the metallic compound containing a multidentate ligand, i.e. a ligand capable of donating two or more pairs of electrons to form a coordinate or ionic bond
- C08F4/7003—Bidentate ligand
- C08F4/7004—Neutral ligand
- C08F4/7008—NO
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/70—Iron group metals, platinum group metals or compounds thereof
- C08F4/7001—Iron group metals, platinum group metals or compounds thereof the metallic compound containing a multidentate ligand, i.e. a ligand capable of donating two or more pairs of electrons to form a coordinate or ionic bond
- C08F4/708—Tetra- or multi-dentate ligand
- C08F4/7081—Neutral ligand
- C08F4/7083—ONNO
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/30—Complexes comprising metals of Group III (IIIA or IIIB) as the central metal
- B01J2531/31—Aluminium
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
- B01J2531/842—Iron
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
- B01J2531/847—Nickel

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Health & Medical Sciences (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Inorganic Chemistry (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Catalysts (AREA)

ITUA2016A003932A 2016-05-30 2016-05-30 Complesso osso-azotato di ferro, sistema catalitico comprendente detto complesso osso-azotato di ferro e procedimento per la (co)polimerizzazione di dieni coniugati ITUA20163932A1 (it)

Priority Applications (11)

Application Number	Priority Date	Filing Date	Title
ITUA2016A003932A ITUA20163932A1 (it)	2016-05-30	2016-05-30	Complesso osso-azotato di ferro, sistema catalitico comprendente detto complesso osso-azotato di ferro e procedimento per la (co)polimerizzazione di dieni coniugati
EA201891812A EA037267B1 (ru)	2016-05-30	2017-05-29	Оксоазотсодержащий комплекс железа, каталитическая система, включающая указанный оксоазотсодержащий комплекс железа, и способ (со)полимеризации сопряженных диенов
US16/300,597 US20190374932A1 (en)	2016-05-30	2017-05-29	Oxo-nitrogenated iron complex, catalytic system comprising said oxo-nitrogenated iron complex and process for the (co)polymerization of conjugated dienes
BR112018074845-5A BR112018074845B1 (pt)	2016-05-30	2017-05-29	Complexo de ferro oxo-nitrogenado, sistema catalítico compreendendo o referido complexo de ferro oxo-nitrogenado e processo para a (co)polimerização de dienos conjugados
CA3016659A CA3016659A1 (en)	2016-05-30	2017-05-29	Oxo-nitrogenated iron complex, catalytic system comprising said oxo-nitrogenated iron complex and process for the (co)polymerization of conjugated dienes
CN201780026611.5A CN109071719B (zh)	2016-05-30	2017-05-29	氧代氮化铁络合物、包含其的催化体系以及用于共轭二烯的(共)聚合的工艺
KR1020187028725A KR102383025B1 (ko)	2016-05-30	2017-05-29	옥소-질화된 철 착물, 상기 옥소-질화된 철 착물을 포함하는 촉매 시스템, 및 컨쥬게이션된 디엔의 (공)중합을 위한 방법
PCT/IB2017/053142 WO2017208128A1 (en)	2016-05-30	2017-05-29	Oxo-nitrogenated iron complex, catalytic system comprising said oxo-nitrogenated iron complex and process for the (co)polymerization of conjugated dienes
ZA2018/05991A ZA201805991B (en)	2016-05-30	2018-09-06	Oxo-nitrogenated iron complex, catalytic system comprising said oxo-nitrogenated iron complex and process for the (co)polymerization of conjugated dienes
SA518400113A SA518400113B1 (ar)	2016-05-30	2018-09-26	نظام حفزي يشتمل على معقد حديد معالج بالأوكسونيتروجين
US17/204,570 US11872548B2 (en)	2016-05-30	2021-03-17	Oxo-nitrogenated iron complex, catalytic system comprising said oxo-nitrogenated iron complex and process for the (co)polymerization of conjugated dienes

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
ITUA2016A003932A ITUA20163932A1 (it)	2016-05-30	2016-05-30	Complesso osso-azotato di ferro, sistema catalitico comprendente detto complesso osso-azotato di ferro e procedimento per la (co)polimerizzazione di dieni coniugati

Publications (1)

Publication Number	Publication Date
ITUA20163932A1 true ITUA20163932A1 (it)	2017-11-30

Family

ID=57045300

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
ITUA2016A003932A ITUA20163932A1 (it)	2016-05-30	2016-05-30	Complesso osso-azotato di ferro, sistema catalitico comprendente detto complesso osso-azotato di ferro e procedimento per la (co)polimerizzazione di dieni coniugati

Country Status (10)

Country	Link
US (2)	US20190374932A1 (it)
KR (1)	KR102383025B1 (it)
CN (1)	CN109071719B (it)
BR (1)	BR112018074845B1 (it)
CA (1)	CA3016659A1 (it)
EA (1)	EA037267B1 (it)
IT (1)	ITUA20163932A1 (it)
SA (1)	SA518400113B1 (it)
WO (1)	WO2017208128A1 (it)
ZA (1)	ZA201805991B (it)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US10981846B1 (en) *	2019-08-16	2021-04-20	The United States Of America, As Represented By The Secretary Of The Navy	Producing cyclic fuels from conjugated diene

Citations (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US6160063A (en) *	1999-12-30	2000-12-12	Bridgestone Corporation	Iron-based catalyst for producing binary cis-1,4-/1,2-polybutadiene
US6211313B1 (en) *	1999-11-12	2001-04-03	Bridgestone Corporation	Iron-based catalyst composition and process for producing conjugated diene polymers

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
PL276385A1 (en)	1987-01-30	1989-07-24	Exxon Chemical Patents Inc	Method for polymerization of olefines,diolefins and acetylene unsaturated compounds
IT1231774B (it)	1989-08-03	1991-12-21	Enichem Anic Spa	Catalizzatore e procedimento per la polimerizzazione e per la copolimerizzazione di alfa olefine.
US5064802A (en)	1989-09-14	1991-11-12	The Dow Chemical Company	Metal complex compounds
CA2024830A1 (en)	1989-09-29	1991-03-30	Richard E. Campbell, Jr.	Process for preparation of syndiotactic vinyl aromatic polymers
ATE137770T1 (de)	1989-10-10	1996-05-15	Fina Technology	Metallocenkatalysator mit lewissäure und alkylaluminium
DE69124255T3 (de)	1990-06-22	2005-10-06	Exxon Chemical Patents Inc.	Aluminiumfreie monocyclopentadienyl-metallocenkatalysatoren für olefinpolymerisation
JPH06501047A (ja)	1990-09-14	1994-01-27	エクソン・ケミカル・パテンツ・インク	制御されたタクチシティーのポリ−α−オレフィンを製造するためのイオン触媒
US5189192A (en)	1991-01-16	1993-02-23	The Dow Chemical Company	Process for preparing addition polymerization catalysts via metal center oxidation
US5721185A (en)	1991-06-24	1998-02-24	The Dow Chemical Company	Homogeneous olefin polymerization catalyst by abstraction with lewis acids
US5258475A (en)	1991-07-12	1993-11-02	Mobil Oil Corporation	Catalyst systems for polymerization and copolymerization of olefins
US6180734B1 (en)	1998-10-14	2001-01-30	Bridgestone Corporation	Process for producing syndiotactic 1,2-polybutadiene and iron-based catalyst compositions for use therein
US6277779B1 (en)	1998-10-14	2001-08-21	Bridgestone Corporation	Process and iron-based catalyst composition for the production of syndiotactic 1,2-polybutadiene
US6284702B1 (en)	1998-10-14	2001-09-04	Bridgestone Corporation	Iron-based catalyst composition and process for producing syndiotactic 1,2-polybutadiene
GB0112023D0 (en) *	2001-05-17	2001-07-11	Bp Chem Int Ltd	Polymerisation catalyst
GB0305927D0 (en) *	2003-03-14	2003-04-23	Ic Innovations Ltd	Compound
CA2767053C (en)	2009-07-10	2014-10-14	Graphic Packaging International, Inc.	Package for containers
ITMI20122201A1 (it) *	2012-12-20	2014-06-21	Versalis Spa	Complesso osso-azotato di cobalto, sistema catalitico comprendente detto complesso osso-azotato e procedimento per la (co)polimerizzazione di dieni coniugati

2016
- 2016-05-30 IT ITUA2016A003932A patent/ITUA20163932A1/it unknown
2017
- 2017-05-29 US US16/300,597 patent/US20190374932A1/en not_active Abandoned
- 2017-05-29 CN CN201780026611.5A patent/CN109071719B/zh active Active
- 2017-05-29 KR KR1020187028725A patent/KR102383025B1/ko active Active
- 2017-05-29 CA CA3016659A patent/CA3016659A1/en active Pending
- 2017-05-29 EA EA201891812A patent/EA037267B1/ru not_active IP Right Cessation
- 2017-05-29 WO PCT/IB2017/053142 patent/WO2017208128A1/en not_active Ceased
- 2017-05-29 BR BR112018074845-5A patent/BR112018074845B1/pt active IP Right Grant
2018
- 2018-09-06 ZA ZA2018/05991A patent/ZA201805991B/en unknown
- 2018-09-26 SA SA518400113A patent/SA518400113B1/ar unknown
2021
- 2021-03-17 US US17/204,570 patent/US11872548B2/en active Active

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US6211313B1 (en) *	1999-11-12	2001-04-03	Bridgestone Corporation	Iron-based catalyst composition and process for producing conjugated diene polymers
US6160063A (en) *	1999-12-30	2000-12-12	Bridgestone Corporation	Iron-based catalyst for producing binary cis-1,4-/1,2-polybutadiene

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
DATABASE CA [online] CHEMICAL ABSTRACTS SERVICE, COLUMBUS, OHIO, US; SAKAYORI, TAKAFUMI ET AL: "Radical polymerization reaction of styrene-based monomers catalyzed by iron complexes bearing .beta.-aminoketonato ligand", XP002763775, retrieved from STN Database accession no. 2015:940732 *

Also Published As

Publication number	Publication date
WO2017208128A1 (en)	2017-12-07
CN109071719A (zh)	2018-12-21
EA037267B1 (ru)	2021-03-01
WO2017208128A8 (en)	2018-11-01
CA3016659A1 (en)	2017-12-07
SA518400113B1 (ar)	2021-10-26
US20190374932A1 (en)	2019-12-12
US11872548B2 (en)	2024-01-16
BR112018074845B1 (pt)	2022-08-30
KR20190015189A (ko)	2019-02-13
KR102383025B1 (ko)	2022-04-04
US20210245145A1 (en)	2021-08-12
BR112018074845A2 (pt)	2019-03-19
EA201891812A1 (ru)	2019-06-28
CN109071719B (zh)	2021-07-30
ZA201805991B (en)	2019-12-18

Publication	Publication Date	Title
IT201600105714A1 (it)	2018-04-20	Procedimento per la preparazione di (co)polimeri di dieni coniugati in presenza di un sistema catalitico comprendente un complesso piridilico di ferro(iii)
EP3528716A4 (en)	2020-10-14	OSTEOTOMY SYSTEMS, DEVICES AND METHODS
EP3386440A4 (en)	2019-11-13	DEVICES, SYSTEMS AND METHOD FOR FORMING A HEADLOCK RING
EP3595629A4 (en)	2021-01-06	NON-VIRAL, NON-CATIONIC NANOPARTICLES AND RELATED USES
EP3439412A4 (en)	2019-10-30	METHOD FOR CONFIGURING AND SENDING A PREAMBLE AND APPROPRIATE DEVICES
WO2015179658A3 (en)	2016-01-21	Anti-gpc3 antibodies and immunoconjugates
HK1253348A1 (zh)	2019-06-14	用於遗传变异的非侵入性评估的方法和过程
DK3515918T3 (da)	2021-07-12	Fremgangsmåde til fremstilling af 2-exo-(2-methylbenzyloxy)-1-methyl-4-isopropyl-7-oxabicyclo[2.2.1]heptan
BR112016024946A2 (pt)	2018-06-26	sistema, dispositivo e método de estabelecimento de comunicação.
FR3044663B1 (fr)	2017-12-29	Copolymere monofonctionnel ou telechelique de 1,3-butadiene et d'ethylene.
IT201600105530A1 (it)	2018-04-20	Procedimento per la preparazione di polibutadiene 1,2 sindiotattico in presenza di un sistema catalitico comprendente un complesso piridilico di ferro
EP3734470A4 (en)	2020-12-16	DESTINATION PROPOSAL SYSTEM, PROPOSAL SYSTEM AND PROPOSAL PROCESS
PL3277421T3 (pl)	2019-10-31	Katalizator odwodornienia i sposób stosowania tego katalizatora
ZA201802338B (en)	2019-07-31	Vanadium pyridine-imine complex, catalytic system comprising said vanadium pyridine-immine complex and a (co) polymerization process of conjugated dienes
PL3596443T3 (pl)	2025-05-12	Urządzenia, systemy i sposoby do analizowania gazu rozpuszczonego
ZA202001610B (en)	2021-08-25	Bis-imine titanium complex, catalytic system comprising said bis-imine titanium complex and process for the (co)polymerization of conjugated dienes
IT201700057307A1 (it)	2018-11-26	Sistema ip-gpio, apparecchiatura e procedimento corrispondenti
PL3237463T3 (pl)	2020-06-29	Okso-nitrowany kompleks wanadowy, układ katalityczny zawierający ten okso-nitrowany kompleks wanadowy i sposób (co)polimeryzacji sprzężonych dienów
IT201700006307A1 (it)	2018-07-20	Complesso osso-azotato di ferro, sistema catalitico comprendente detto complesso osso-azotato di ferro e procedimento per la (co)polimerizzazione di dieni coniugati
ITUA20163932A1 (it)	2017-11-30	Complesso osso-azotato di ferro, sistema catalitico comprendente detto complesso osso-azotato di ferro e procedimento per la (co)polimerizzazione di dieni coniugati
ZA201707224B (en)	2019-05-29	Nitrogen titanium complex, catalytic system comprising said nitrogen titanium complex and process for the (co)polymerization of conjugated dienes
ZA201807579B (en)	2021-05-26	Catalyst for the hydroformylation of olefins, and use thereof
ZA201701180B (en)	2018-11-28	Phosphinic vanadium complex, catalytic system comprising said phosphinic vanadium complex and process for the (co) polymerization of conjugated dienes
DK3601295T3 (da)	2021-08-02	Fremgangsmåde til fremstilling af 2-exo-(2-methylbenzyloxy)-1-methyl-4-isopropyl-7-oxabicyclo[2.2.1]heptan
GB201615271D0 (en)	2016-10-26	Proximity detection utilising location beacons