JP2000100568A - Organic light emitting device - Google Patents

Abstract

(57) [Summary] [PROBLEMS] In a doping method, improvement of color purity originally intended for a red organic light-emitting element and high efficiency are two sides of the same coin, and a conventional material has a low red purity, so a filter is required. There has been a problem that the use of such a device leads to a decrease in efficiency. SOLUTION: An organic light emitting layer 12 containing 10% by weight or more of a first fluorescent dye is provided on a hole transport layer 11, and an electron transport layer 13 further contains a second fluorescent dye, whereby a high red purity is obtained. A high-brightness organic light-emitting device is realized.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an organic light emitting device which is a display device used as a light emitting display or a backlight for a liquid crystal display.

[0002]

2. Description of the Related Art Electroluminescent (EL) panels have high visibility, excellent display capability, and high-speed response. In recent years, reports have been made on organic light-emitting devices using organic compounds as constituent materials (for example, see the related paper Applied Physics Letters, No. 51).
Vol. 1987, p. 913 (Applied Physics Letters, 51, 19)
87, P.913.))). This report describes an organic light emitting device having a structure in which an organic light emitting layer and a charge transport layer are laminated. We have developed a tris (8-quinolinol) aluminum complex (hereinafter, Alq) as a light emitting material.
It is an excellent luminescent substance that combines electron transport.

Further, Journal of Applied Physics, Vol. 65, p. 3610, 1989 (Journal
of Applied Physics, 65, 1989, p. 3610.), a device in which Alq forming an organic light emitting layer is doped with a coumarin derivative or a fluorescent dye such as DCM1, and the emission color changes by appropriate selection of the dye. Was found. Furthermore, it was clarified that the luminous efficiency was increased as compared with the undoped one.

Further, Japanese Patent Application Laid-Open No. 63-264692 discloses that the doping concentration is preferably 10-3 mol% or less, and rarely 1 mol% or more.
It is described that it is not necessary to use more than mol% of a fluorescent substance.

The conditions required for a fluorescent dye as a guest material include a large overlap between the absorption spectrum of the fluorescent dye and the emission spectrum of the host material (for example, Alq), a high fluorescence quantum yield, Good stability.

At present, there are still few luminescent materials satisfying all of these conditions, and particularly few red luminescent materials. Generally, in the doping method, the doping concentration and the luminous efficiency have an inversely proportional relationship. The efficiency is high when the doping concentration is low, and as the doping concentration increases, the efficiency decreases due to concentration quenching.

On the other hand, as described above, the overlap between the absorption spectrum of the fluorescent dye as a dopant and the emission spectrum of the host material determines the emission spectrum of the doped system. Therefore, the absorption intensity of the fluorescent dye is weak and all the emission of the host material is absorbed. When this is not possible, the light emission of the host material is added in addition to the light emission of the guest material. This phenomenon is particularly likely to occur when the doping concentration is low, resulting in color mixing. In addition, one of the characteristics of light emission of an organic compound is that the emission spectrum or the absorption spectrum has a wide half-value width because it has various energy levels. Therefore, when the absorption band of the guest material cannot cover the light emission of the host material, color mixing occurs as described above.

For example, in the drawing (FIG. 5) described in Japanese Patent Application Laid-Open No. 7-288184, together with the light emission of magnesium phthalocyanine, the light emission of Alq as a host material also appears. In such a case, since the color purity is reduced by the color mixture, to develop red color, for example, measures were taken by increasing the doping concentration (Asai, Onijima, Kishii, Tamura, Display and Imaging, 5 (4) 279) (199
7)).

Another method is disclosed in Japanese Patent Application Laid-Open No. H10-60427.
The publication describes that a color filter and / or a fluorescence conversion filter is disposed on the light extraction side to realize a high-luminance light-emitting element with high red purity.

Japanese Patent Application Laid-Open No. Hei 10-22073 discloses that an orange-based or red-based phosphor layer containing a green fluorescent dye is provided on the light extraction side of a green light-emitting element to provide a high-luminance, high-efficiency red organic layer. It describes that an EL light emitting device can be provided.

[0011]

However, in the conventional doping method, the improvement in color purity and the improvement in efficiency, which are originally intended for a red organic light-emitting device, are inextricably linked. For example, the above-described DCM as a red dye is an excellent material capable of realizing high efficiency in a low concentration region, but strictly emits yellow-red (orange) light. It must be used in the concentration region, and the efficiency is inevitably reduced.

FIG. 2 shows a relative visibility curve. In the yellow-red region, the relative luminous efficiency is relatively high and greatly contributes to the emission luminance, but the red purity is low. On the other hand, on the long-wavelength side, the red color becomes darker, but the relative luminous efficiency is lowered, so that the obtained luminance is slight. As described above, the deepening of red not only reduces the efficiency due to density quenching, but is disadvantageous also in terms of relative luminous efficiency.

Some red light-emitting materials can form a light-emitting layer independently without using a doping method. However, the diffusion of excitons generated cannot be sufficiently suppressed, or Alq forming the electron transport layer simultaneously emits light due to imbalance in carrier balance, so that the reduction in color purity cannot be avoided. . The use of filters, as used in liquid crystals and the like, has the problem of improving color purity but absorbing excess light, leading to a reduction in efficiency.

Further, since a fluorescent dye easily reacts with a hole transporting material such as a triphenylamine derivative and causes a wavelength shift, a blocking layer must be provided (Japanese Patent Application No. 10-159076).

[0015]

Therefore, we have combined light emission in the yellow-red region, which is advantageous for increasing brightness, and light emission in the red region, which is advantageous for darkening. Further, not only the organic light emitting layer but also the electron transporting layer can be made to absorb all the light emitted from the host material and improve the red color purity by using light emitting materials having different absorption bands, absorption intensities or emission wavelengths. The configuration was adopted. Further, by configuring the blocking layer, which had been laminated when using phenoxazone 9, with a red light-emitting material, it was possible to further increase the luminance and improve the red purity, and the above-mentioned problem was solved.

Specifically, the invention of claim 1 has at least a hole transport layer, an organic light emitting layer, and an electron transport layer between the positive electrode and the negative electrode, and any one of the layers has a light emission maximum in a yellow-red region. And a luminescent material having a luminescent maximum in the red region.

According to a second aspect of the present invention, at least an organic light emitting layer and an electron transport layer are provided between a positive electrode and a negative electrode, wherein the organic light emitting layer contains a first fluorescent substance, and the electron transport layer is a second fluorescent substance. It is characterized by containing two fluorescent substances.

According to a third aspect of the present invention, the first fluorescent substance contained in the organic light emitting layer is represented by a general formula (Chemical Formula 1) wherein R1 is hydrogen,
R2 and R3 represent hydrogen, alkyl, or bonded together to form a 6-membered ring,
The membered ring may be substituted with an alkyl group).

According to a fourth aspect of the present invention, the first fluorescent substance contained in the organic light emitting layer is represented by a general formula (Chemical Formula 2) (R1 and R2
Is hydrogen, alkyl, aryl, pyridyl,
R1 and R2 may be the same or different. n is 1 to 5
Is an integer. ).

According to a fifth aspect of the present invention, the ratio of the first fluorescent substance contained in the organic light emitting layer is 1 mol% or more.

According to a sixth aspect of the present invention, the second fluorescent substance contained in the electron transporting layer is 9-diethylamino-5-H-
It is composed of benzo [a] phenoxazin-5-one.

According to a seventh aspect of the present invention, the electron transport layer mainly contains tris (8-quinolinolato) aluminum.

The invention according to claim 8 has at least a hole transporting layer, an organic light emitting layer, and an electron transporting layer between the positive electrode and the negative electrode, wherein the organic light emitting layer is represented by the general formula (1) Wherein R1 represents hydrogen, alkyl, aryl, pyridyl, R2 and R3 are hydrogen, alkyl, or bonded together to form a 6-membered ring, and the 6-membered ring may be substituted with an alkyl group; The electron transport layer includes 9-diethylamino-5-H-benzo [a] phenoxazin-5-one as a second fluorescent substance.

According to a ninth aspect of the present invention, the first fluorescent substance contained in the organic light emitting layer is composed of 5,10,15,20-tetraphenyl-21H, 23H-porphine.

According to a tenth aspect of the present invention, the ratio of the first fluorescent substance contained in the organic light emitting layer is 1 mol% or more.

[0027] In the eleventh aspect of the present invention, the electron transporting layer mainly contains tris (8-quinolinolato) aluminum.

Further, the organic light emitting device of the present invention has at least a hole transport layer, an organic light emitting layer, and an electron transport layer between the positive electrode and the negative electrode, and the organic light emitting layer has a general formula as a first fluorescent substance. Wherein R 1 and R 2 are hydrogen, alkyl, aryl, or pyridyl, and R 1 and R 2 may be the same or different, and n is an integer of 1 to 5; The transport layer contains 9-diethylamino-5-H-benzo [a] phenoxazin-5-one as a second fluorescent substance.

According to a thirteenth aspect of the present invention, the first fluorescent substance contained in the organic light emitting layer is N, N'-di (2,6-di-
(t-butyl) phenyl-3,4,9,10-perylenebis (dicarboximide).

According to a fourteenth aspect, the ratio of the first fluorescent substance contained in the organic light emitting layer is 1 mol% or more.

According to a fifteenth aspect of the present invention, the electron transport layer mainly contains tris (8-quinolinolato) aluminum.

According to a sixteenth aspect of the present invention, the hole transport layer comprises at least a compound represented by the following general formula (3): wherein R1, R2, R
3, R4 and R5 may be the same or different;
R2 and R3 represent a hydrogen atom, a lower alkyl group or a lower alkoxy group, and R4 and R5 represent a hydrogen atom, a lower alkyl group,
(Representing a lower alkoxy group or a chlorine atom).

According to a seventeenth aspect, the hole transport layer contains at least N, N'-bis (4'-diphenylamino-4-biphenylyl) -N, N'-diphenylbenzidine.

The invention of claim 18 is that the hole transporting layer has at least a compound represented by the general formula (4) (wherein R1 and R2 may be the same or different, and include a hydrogen atom, a lower alkyl group,
A lower alkoxy group, a substituted or unsubstituted aryl group, and R3 represents a hydrogen atom, a lower alkyl group, a lower alkoxy group, or a chlorine atom).

According to a nineteenth aspect of the present invention, the hole transporting layer has at least N, N'-diphenyl-N, N'-bis (3-methylphenyl) -1,1'-biphenyl-4,4.
It contains 4'-diamine.

[0035]

Embodiments of the present invention will be described below. Tang et al. Led to the improvement of the characteristics of the organic light emitting device by forming a stacked structure in which the organic layer was separated in function,
Generally, an organic layer is formed by laminating at least two layers of a layer made of a hole transporting material and a layer made of an electron transporting material. In general, Alq is often used as an electron-transporting luminescent material because of its excellent transport properties and light-emitting properties for the electron transport layer, and many fluorescent dyes are doped into Alq in consideration of energy transfer from Alq. And an organic light emitting layer. The excited singlet state in the fluorescent emission of the dye easily follows a non-radiation path due to the influence of heat, vibration, or the formation of a complex or an aggregate. Further, depending on the increase in the concentration of the dye, a phenomenon called concentration quenching also occurs.
For this reason, the doping concentration of the fluorescent dye is as described in
1 mol% as described in US Pat.
These are rarely used.

However, the porphyrin-based compound represented by the general formula (Chemical Formula 1) constituting the organic light emitting layer of the present invention emits light even in a low concentration region, but has a higher emission intensity in a high concentration region of 10% or more. It can be increased, or even 100%. Particularly preferred materials include 5,10,15,20-tetraphenyl-
21H, 23H-porphine or 5,10,15,2
0-tetrapyridyl-21H and 23H-porphine are mentioned.

Further, a metal complex in which two hydrogens of an imino group at the center of the chemical formula (1) are released and coordinated to a metal may be used.

As another preferable material constituting the organic light emitting layer of the present invention, a perylene dye represented by the general formula (Formula 2) can be mentioned.

Particularly preferred materials include N, N'-di (2,6-di-t-butyl) phenyl-3,4,9,1
0-perylene bis (dicarboximide).

The thickness of the organic light emitting layer may be a thickness sufficient for the dye to emit light, preferably 1 to 30 nm, more preferably 5 to 20 nm.

The constituent materials of the electron transport layer of the present invention include:
Tris (8-quinolinolato) aluminum is preferred.
Another example is tris (4-methyl-8-quinolinolato)
Metal complexes such as aluminum, 3- (2'-benzothiazolyl) -7-diethylaminocoumarin and the like can be mentioned.
The electron transport layer preferably has a thickness of 10 to 1000 nm.

As the fluorescent substance added together with the material constituting the electron transport layer, a material different from the fluorescent substance contained in the organic light emitting layer is preferable. When the electron transport layer constituting material is a luminescent substance, it is desired that the luminescent band of the luminescent substance and the absorption band of the added fluorescent substance have a large overlap.

Specifically, 9-diethylamino-5-H
Phenoxazones such as -benzo [a] phenoxazin-5-one, and dicyanomethylenepyran dyes such as 4-dicyanmethylene-2-methyl-6- (p-dimethylaminostyryl) -4H-pyran Is mentioned.

In particular, for a material such as phenoxazones, which easily forms a complex or the like by interaction with a triphenylamine-based hole transporting material, not only the complex formation with the light emitting layer can be prevented, but also the formation of a complex can be prevented.
The spectrum of the red light emitting region can be increased, and the red purity can be improved.

Further, the addition of a fluorescent dye to the electron transporting layer efficiently converts the wavelength of light emitted from an electron transporting material such as Alq caused by holes or excitons passing through the organic light emitting layer into a long wavelength region. Therefore, high brightness can be achieved.

The chromaticity is determined by a combination of emission spectra emitted from each dye. The combination of the maximum emission wavelength 625 nm of phenoxazone and the porphyrin compound 660 nm described in the claims of the present invention showed an optimal red color. When it appears on the short wavelength side as short as 600 nm as in DCM, it is preferable to combine it with a dye that emits red light on the longer wavelength side.

Next, a more detailed description will be given with reference to the drawings. FIG. 1 is a schematic cross-sectional view of the organic light emitting device of the present invention.
After the hole transport layer 11 is formed, an organic light emitting layer 12 containing a first fluorescent dye is formed, and an electron transport layer 13 in which a second fluorescent dye and a host material are co-deposited is formed. The dye contained in the electron transport layer 13 may be the whole or a part adjacent to the organic light emitting layer 12. Third,
A fourth plurality of dyes may be added to the organic light emitting layer 12 or the electron transport layer 13.

Next, for the hole transport layer in the present invention, a derivative having triphenylamine as a basic skeleton is preferable as a constituent material. For example, JP-A-7-126
No. 615, a tetraphenylbenzidine compound,
Triphenylamine trimer and benzidine dimer are exemplified. Also, various triphenyldiamine derivatives described in JP-A-8-48656 or JP-A-7-659.
No. 58, the MTPD (commonly known as TPD) may be used. Particularly, a triphenylamine tetramer described in Japanese Patent Application No. 9-341238 is preferable.

Regarding each of the organic layers of the organic light emitting layer, the electron transport layer, and the hole transport layer, it is desirable to form a homogeneous film in an amorphous state, and it is preferable to form the film by a vacuum evaporation method. Furthermore, by forming each layer continuously in a vacuum, by preventing impurities from adhering to the interface between each layer, it is possible to improve characteristics such as lower operating voltage, higher efficiency, and longer life. it can. Further, when forming each of these layers by a vacuum deposition method, when a plurality of compounds are contained in one layer, it is preferable to separately co-deposit each boat containing the compounds by individually controlling the temperature, but it is preferable to deposit a mixture in advance. You may. Further, as other film forming methods, a solution coating method, Langmuir Blodget (L
The method B) can be used. In the solution coating method, each compound may be dispersed in a matrix material such as a polymer.

The organic light emitting device can emit surface light by making at least one electrode transparent or translucent. Usually, an ITO (indium tin oxide) film is often used for an anode serving as a hole injection electrode.
Other examples include tin oxide, Ni, Au, Pt, and Pd. For the purpose of improving the transparency or reducing the resistivity of the ITO film, a film forming method such as sputtering, electron beam evaporation, or ion plating is employed. The film thickness is determined from the required sheet resistance value and the visible light transmittance. However, since the driving current density is relatively high in the organic light emitting device, it is necessary to reduce the sheet resistance value by 10%.
It is often used with a thickness of 0 nm or more.

The cathode as an electron injection electrode has Tang.
In many cases, an alloy of a metal having a low work function and a low electron injection barrier, such as an MgAg alloy or an AlLi alloy, and a metal having a relatively large work function and being stable is used. Further, a metal having a low work function may be formed on the organic layer side, and a metal having a large work function may be thickly laminated for the purpose of protecting the metal having a low work function, such as Li / Al or LiF / Al.
Such a laminated electrode can be used. For forming these cathodes, a vapor deposition method or a sputtering method is preferable.

The substrate only needs to be capable of supporting the organic light emitting element in which the above-mentioned thin films are laminated, and may be a transparent or translucent material so as to take out the luminescence generated in the organic layer. Glass or polyester or other resin film.

Next, a more detailed description will be given based on specific embodiments. An element was manufactured based on the configuration in FIG.

Example 1 N, N'-bis (4'-diphenylamino-4-) was formed on a glass substrate on which ITO was formed.
A hole transport layer of (biphenylyl) -N, N'-diphenylbenzidine having a thickness of 50 nm is formed. Subsequently, 5,10,15,20-tetraphenyl-21H, 23H-porphine was deposited to a thickness of 10 nm as an organic light emitting layer. Tris (8-quinolinolato) as the electron transport layer
Using aluminum as a host material, 1% by weight of 9-diethylamino-5-H-benzo [a] phenoxazine-5
When doping with on was performed and a film thickness of 10 nm was obtained, deposition of only the dopant was stopped, and only the host material was changed to 30 nm.
An electron transporting layer was formed by vapor deposition. Finally, a negative electrode made of an AlLi alloy was formed.

The device was evaluated by applying a DC voltage to it.
In addition to nm, a maximum wavelength of 625 nm from the dopant contained in the electron transport layer was observed, and a red light emitting device was obtained. The chromaticity coordinates are (x, y) = (0.67, 0.33)
Met. Regarding the luminous efficiency, 1.5 cd / A equivalent to that of the undoped green light-emitting device was obtained in consideration of the relative luminous efficiency.

Example 2 In forming the organic light emitting layer of Example 1, 5,10,15,20-tetraphenyl-2 was used.
Instead of 1H, 23H-porphine, N, N'-di (2,6-di-t-butyl) phenyl-3,4,9,1
An organic light-emitting device was produced in the same manner as in Example 1 except that 0-perylenebis (dicarboximide) was used. When a DC voltage was applied to the device to evaluate the device, it was found that, in addition to the emission maximum wavelength of 680 nm, which is the emission from the organic emission layer, the maximum wavelength of 625 nm from the dopant contained in the electron transport layer.
Was observed, and a red light emitting device was obtained. The luminous efficiency is 1.
2 cd / A was obtained. The chromaticity coordinates are (x, y) =
(0.67, 0.34).

Example 3 In forming the organic light emitting layer of Example 1, 5,10,15,20-tetraphenyl-2 was used.
5,10,1 instead of 1H, 23H-porphine
Using 5,20-tetrapyridyl-21H, 23H-porphine, 1% by weight of 9-
Instead of diethylamino-5-H-benzo [a] phenoxazin-5-one, 0.5% by weight of 4-dicyanmethylene-2-methyl-6- (p-dimethylaminostyryl) -4H-pyran was used. An organic light-emitting device was produced in the same manner as in Example 1 except that the device was used. When a DC voltage was applied to the device and the device was evaluated, a maximum wavelength of 730 nm from the organic light emitting layer and a maximum wavelength of 600 nm from the dopant contained in the electron transport layer were observed in addition to the maximum emission wavelength of 730 nm. Was done.

The luminous efficiency was 2.0 cd / A, which was equivalent to that of an undoped green light-emitting device. The chromaticity coordinates are (x, y)
= (0.66, 0.34).

Comparative Example 1 N, N'-bis (4'-diphenylamino-4-) was formed on a glass substrate on which ITO was formed.
A light emitting layer is formed following the formation of a hole transport layer having a thickness of 50 nm made of (biphenylyl) -N, N'-diphenylbenzidine. The light emitting layer was doped with 0.8% by weight of 9-diethylamino-5-H-benzo [a] phenoxazin-5-one using tris (8-quinolinolato) aluminum as a host material to obtain a film thickness of 20 nm. At this point, evaporation of only the dopant was stopped, and only the host material was evaporated to a thickness of 30 nm to form an electron transporting layer.

Finally, a negative electrode made of an AlLi alloy was formed. When a DC voltage was applied to this element and evaluated,
Emission of 600 nm from the complex formed by TPD and phenoxazone 9 was observed, shifted from the intrinsic wavelength of the dopant, and the EL emission color was orange. The chromaticity coordinates were (x, y) = (0.50, 0.40).

(Comparative Example 2) Between the hole transport layer and the light emitting layer of Comparative Example 1, a 1 nm tris (8
(Quinolinolato) An organic light-emitting device was produced in the same manner as in Comparative Example 1 except that aluminum was formed. When a DC voltage was applied to the device to evaluate the device, emission of 625 nm from phenoxazone was observed, the EL emission color was red, and the chromaticity coordinates were (x, y) = (0.65, 0.35).
Met.

Comparative Example 3 In forming the organic light emitting layer of Comparative Example 1, 0.8% by weight of 9-diethylamino-5-H was used.
-In place of benzo [a] phenoxazin-5-one,
20% by weight of 5,10,15,20-tetraphenyl-
An organic light-emitting device was produced in the same manner as in Comparative Example 1 except that 21H and 23H-porphine were used. The device was evaluated by applying a DC voltage to it.
In addition to nm and 722 nm, emission of 520 nm from the host material Alq was observed, the EL emission color was yellow-green, and the chromaticity coordinates were (x, y) = (0.41, 0.5).
1).

[0063]

As described above, according to the present invention, the light emission of the host material can be reduced by using light-emitting materials having different absorption bands, absorption intensities or emission wavelengths in the electron transport layer as well as in the organic light-emitting layer. Absorption and improvement in red purity can be realized.

Further, when phenoxazone 9 is used, a higher luminance and a higher red purity can be realized by using a red light-emitting layer as the constituting blocking layer.

[Brief description of the drawings]

FIG. 1 is a cross-sectional view of an organic light emitting device according to an embodiment of the present invention.

FIG. 2 is a characteristic diagram showing a relative luminosity curve.

[Explanation of symbols]

 11 hole transport layer 12 organic light emitting layer 13 electron transport layer

 ──────────────────────────────────────────────────続 き Continuing from the front page (72) Inventor Tetsuya Sato 1006 Kazuma Kadoma, Osaka Prefecture Inside Matsushita Electric Industrial Co., Ltd. 72) Inventor Toru Kawase 1006 Kazuma Kadoma, Kadoma City, Osaka Prefecture F-term in Matsushita Electric Industrial Co., Ltd. (reference) 3K007 AB02 AB04 CA01 CB01 DA00 DB03 EB00 FA01

Claims (19)

[Claims] 1. A luminescent material having at least a hole transport layer, an organic luminescent layer, and an electron transport layer between a positive electrode and a negative electrode, and a luminescent material having a luminescent maximum in a yellow-red region and a luminescent maximum in a red region. An organic light-emitting device comprising a light-emitting material having the formula: 2. An organic light-emitting layer comprising at least an organic light-emitting layer and an electron transport layer between a positive electrode and a negative electrode, wherein the organic light-emitting layer contains a first fluorescent substance and the electron transport layer contains a second fluorescent substance. An organic light-emitting device, comprising: 3. A method according to claim 1, wherein the first fluorescent substance contained in the organic light emitting layer has the following general formula: (R1 represents hydrogen, alkyl, aryl, pyridyl,
R2 and R3 are hydrogen, alkyl, or bonded together to form a 6-membered ring, and the 6-membered ring may be substituted with an alkyl group.
The organic light-emitting device according to claim 2, wherein 4. A method according to claim 1, wherein the first fluorescent substance contained in the organic light emitting layer has the following general formula: (R1 and R2 are any of hydrogen, alkyl, aryl and pyridyl, and R1 and R2 may be the same or different, and n is an integer of 1 to 5). The organic light-emitting device as described in the above. 5. The organic light emitting device according to claim 2, wherein the ratio of the first fluorescent substance contained in the organic light emitting layer is 1 mol% or more. 6. The organic substance according to claim 2, wherein the second fluorescent substance contained in the electron transport layer is 9-diethylamino-5-H-benzo [a] phenoxazin-5-one. Light emitting element. 7. An electron transport layer according to claim 2, wherein said electron transport layer mainly comprises tris (8-quinolinolato) aluminum.
An organic light-emitting device according to any one of claims 1 to 6. 8. An organic light emitting device having at least a hole transporting layer, an organic light emitting layer, and an electron transporting layer between a positive electrode and a negative electrode, wherein the organic light emitting layer is represented by the following general formula (1) as a first fluorescent substance. R1 represents hydrogen, alkyl, aryl, pyridyl, R2 and R3 are hydrogen, alkyl, or bonded together to form a 6-membered ring, wherein the 6-membered ring may be substituted with an alkyl group); The electron transport layer has 9-diethylamino-5-H-benzo [a] as the second fluorescent substance.
An organic light-emitting device comprising phenoxazin-5-one. 9. The method according to claim 9, wherein the first fluorescent substance is 5, 10, 15,
The organic light emitting device according to claim 8, wherein the organic light emitting device is 20-tetraphenyl-21H, 23H-porphine. 10. The organic light emitting device according to claim 8, wherein a ratio of the first fluorescent substance contained in the organic light emitting layer is 1 mol% or more. 11. The organic light-emitting device according to claim 8, wherein said electron transport layer mainly contains tris (8-quinolinolato) aluminum. 12. An organic light-emitting device having at least a hole transport layer, an organic light-emitting layer, and an electron transport layer between a positive electrode and a negative electrode, wherein the organic light-emitting layer is represented by the general formula (2) as a first fluorescent substance. R1 and R2 are any of hydrogen, alkyl, aryl and pyridyl, and R1 and R2 may be the same or different, and n is an integer of 1 to 5), and the electron transporting layer is 9-diethylamino-5-H-benzo [a] phenoxazine-
An organic light emitting device comprising 5-one. 13. The method according to claim 13, wherein the first fluorescent substance is N, N'-di (2,6-di-t-butyl) phenyl-3,4,9,1.
13. The organic light emitting device according to claim 12, wherein the organic light emitting device is 0-perylene bis (dicarboximide). 14. The organic light emitting device according to claim 12, wherein a ratio of the first fluorescent substance contained in the organic light emitting layer is 1 mol% or more. 15. The organic light-emitting device according to claim 12, wherein the electron transport layer mainly contains tris (8-quinolinolato) aluminum. 16. The method according to claim 16, wherein the hole transport layer has at least the following general formula: (Wherein R1, R2, R3, R4, and R5 may be the same or different; R1, R2, and R3 represent a hydrogen atom, a lower alkyl group, or a lower alkoxy group; R4 and R5 represent a hydrogen atom or a lower alkyl group; The organic light-emitting device according to any one of claims 8 to 15, wherein the organic light-emitting device is a compound represented by the following formula: 17. The method according to claim 17, wherein the hole transport layer comprises at least N,
The organic light-emitting device according to any one of claims 8 to 15, comprising N'-bis (4'-diphenylamino-4-biphenylyl) -N, N'-diphenylbenzidine. 18. The method according to claim 18, wherein the hole transport layer has at least the following general formula: (Wherein R 1 and R 2 may be the same or different and represent a hydrogen atom, a lower alkyl group, a lower alkoxy group, a substituted or unsubstituted aryl group, and R 3 represents a hydrogen atom, a lower alkyl group, a lower alkoxy group, or 9. A compound represented by the formula:
16. The organic light-emitting device according to any one of items 15 to 15. 19. The method according to claim 19, wherein the hole transport layer comprises at least N,
The organic compound according to any one of claims 8 to 15, wherein the organic compound contains N'-diphenyl-N, N'-bis (3-methylphenyl) -1,1'-biphenyl-4,4'-diamine. Light emitting element.