JP2000138095A - Manufacture of light emitting device - Google Patents
Manufacture of light emitting deviceInfo
- Publication number
- JP2000138095A JP2000138095A JP11231218A JP23121899A JP2000138095A JP 2000138095 A JP2000138095 A JP 2000138095A JP 11231218 A JP11231218 A JP 11231218A JP 23121899 A JP23121899 A JP 23121899A JP 2000138095 A JP2000138095 A JP 2000138095A
- Authority
- JP
- Japan
- Prior art keywords
- substrate
- light emitting
- light
- depositing
- deposited
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
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- 150000004322 quinolinols Chemical class 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229910052701 rubidium Inorganic materials 0.000 description 1
- IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 description 1
- YYMBJDOZVAITBP-UHFFFAOYSA-N rubrene Chemical compound C1=CC=CC=C1C(C1=C(C=2C=CC=CC=2)C2=CC=CC=C2C(C=2C=CC=CC=2)=C11)=C(C=CC=C2)C2=C1C1=CC=CC=C1 YYMBJDOZVAITBP-UHFFFAOYSA-N 0.000 description 1
- 239000005368 silicate glass Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001256 stainless steel alloy Inorganic materials 0.000 description 1
- PJANXHGTPQOBST-UHFFFAOYSA-N stilbene Chemical class C=1C=CC=CC=1C=CC1=CC=CC=C1 PJANXHGTPQOBST-UHFFFAOYSA-N 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
- AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Inorganic materials O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- QKTRRACPJVYJNU-UHFFFAOYSA-N thiadiazolo[5,4-b]pyridine Chemical class C1=CN=C2SN=NC2=C1 QKTRRACPJVYJNU-UHFFFAOYSA-N 0.000 description 1
- NZFNXWQNBYZDAQ-UHFFFAOYSA-N thioridazine hydrochloride Chemical class Cl.C12=CC(SC)=CC=C2SC2=CC=CC=C2N1CCC1CCCCN1C NZFNXWQNBYZDAQ-UHFFFAOYSA-N 0.000 description 1
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 1
- 229910001887 tin oxide Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 150000001651 triphenylamine derivatives Chemical class 0.000 description 1
- 229910021642 ultra pure water Inorganic materials 0.000 description 1
- 239000012498 ultrapure water Substances 0.000 description 1
- 238000007738 vacuum evaporation Methods 0.000 description 1
- 229940102001 zinc bromide Drugs 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
Landscapes
- Electroluminescent Light Sources (AREA)
- Devices For Indicating Variable Information By Combining Individual Elements (AREA)
Abstract
Description
【0001】[0001]
【発明の属する技術分野】本発明は、電気エネルギーを
光に変換できる素子の製造方法であって、表示素子、フ
ラットパネルディスプレイ、バックライト、照明、イン
テリア、標識、看板、電子写真機、光信号発生器などの
分野に利用可能な発光素子の製造方法に関するものであ
る。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for manufacturing an element capable of converting electric energy into light, and relates to a display element, a flat panel display, a backlight, lighting, an interior, a sign, a sign, an electrophotographic device, and an optical signal. The present invention relates to a method for manufacturing a light emitting element that can be used in a field such as a generator.
【0002】[0002]
【従来の技術】負極から注入された電子と正極から注入
された正孔が両極に挟まれた有機蛍光体内で再結合する
際に発光する有機積層薄膜発光素子の研究が近年活発に
行われている。この素子は、薄型、低駆動電圧下での高
輝度発光、蛍光材料を選ぶことによる多色発光が特徴で
ある。2. Description of the Related Art In recent years, active research has been conducted on organic thin-film light emitting devices that emit light when electrons injected from a negative electrode and holes injected from a positive electrode recombine in an organic phosphor sandwiched between both electrodes. I have. This element is characterized by thinness, high luminance light emission under a low driving voltage, and multicolor light emission by selecting a fluorescent material.
【0003】有機積層薄膜素子が高輝度に発光すること
は、コダック社のC.W.Tangらによって初めて示
された(Appl.Phys.Lett.51(12)
21、p.913、1987)。コダック社の提示した
有機積層薄膜発光素子の代表的な構成は、ITOガラス
基板上に正孔輸送性のジアミン化合物、発光層であり、
電子輸送性も併せ持った8−ヒドロキシキノリンアルミ
ニウム、そして負極としてMg:Agを順次設けたもの
であり、10V程度の駆動電圧で1000カンデラ/平
方メートルの緑色発光が可能であった。現在の有機積層
薄膜発光素子は、上記の素子構成要素の他に、電子輸送
層を別に設けているものなど構成を変えているものもあ
るが、基本的にはコダック社の構成を踏襲している。ま
た、最近では耐久性の向上のために封止が行われたり、
封止の前に保護層が設けられる場合もある。[0003] It is known from Kodak's C.I. W. Tang et al. (Appl. Phys. Lett. 51 (12)
21, p. 913, 1987). A typical configuration of the organic laminated thin-film light emitting device presented by Kodak Company is a hole transporting diamine compound and a light emitting layer on an ITO glass substrate,
8-Hydroxyquinoline aluminum, which also has an electron transporting property, and Mg: Ag as a negative electrode were sequentially provided, and green light emission of 1000 candela / m 2 was possible at a driving voltage of about 10 V. The current organic laminated thin-film light-emitting device has a different configuration, such as a device provided with an electron transport layer, in addition to the above-described device components, but basically follows the configuration of Kodak. I have. In recent years, sealing has been performed to improve durability,
A protective layer may be provided before sealing.
【0004】ところで有機積層薄膜発光素子(以下発光
素子とする)の薄膜形成方法であるが、抵抗加熱蒸着
法、電子ビーム蒸着法などの乾式製膜系と、ディップコ
ーティング法、スピンキャスト法などの湿式製膜系に大
別することが出来る。しかし湿式製膜系は大気中で操作
されることから、異物が混入しやすい、水分などが界面
に吸着するなど発光素子の特性に悪影響を及ぼしやす
い。一方乾式製膜法は上記のような弊害がなく、良好な
薄膜が得られることなどから、一般的に薄膜形成過程の
すべてあるいは一部に乾式製膜系を用いることが、発光
素子の発光効率や耐久性などの諸特性面から好ましいと
されている。A method of forming a thin film of an organic laminated thin film light emitting device (hereinafter referred to as a light emitting device) includes a dry film forming system such as a resistance heating evaporation method and an electron beam evaporation method, and a dip coating method and a spin casting method. It can be broadly divided into wet film forming systems. However, since the wet film forming system is operated in the atmosphere, foreign matters are easily mixed in, and moisture and the like are easily adsorbed to the interface, and thus the characteristics of the light emitting element are easily adversely affected. On the other hand, the dry film forming method does not have the above-mentioned adverse effects, and a good thin film can be obtained. Therefore, it is generally necessary to use a dry film forming system for all or a part of the thin film forming process. It is considered to be preferable in terms of various characteristics such as durability and durability.
【0005】ここで発光素子を構成する発光を司る物質
の層の厚みに関しては、抵抗値などにもよるので限定は
できないが、10〜1000nmの間から選ぶことが出
来る。非常に薄い膜を積層していくので、厚みムラは発
光素子に重大な悪影響を及ぼす。具体的には抵抗のばら
つきによる発光ムラが生じたり、ひどい場合は薄い部分
に電界が集中することにより素子が破壊され、短絡によ
る非発光部分の発生や発光効率の低下が引き起こされ
る。また破壊された部分から水分などが進入し、非発光
部分が拡大して耐久性にも影響を与える。Here, the thickness of the layer of the substance which controls light emission of the light emitting element is not limited because it depends on the resistance value and the like, but can be selected from the range of 10 to 1000 nm. Since a very thin film is laminated, the thickness unevenness has a serious adverse effect on the light emitting device. Specifically, light emission unevenness occurs due to variation in resistance, and in severe cases, an electric field concentrates on a thin portion, thereby destroying the element, causing a non-light emitting portion due to a short circuit and a reduction in luminous efficiency. In addition, moisture or the like enters from the destroyed portion, and the non-light-emitting portion expands, affecting the durability.
【0006】発光素子の製造過程に乾式製膜系を用いた
場合、蒸着物は点状の蒸着源から放射状に一様に飛散す
る。これに対して一般的な基板は平面状であるので、場
所によって蒸着源からの距離が異なり厚みムラが生じて
しまう。そこで膜厚ムラを防ぐために、これまでにも基
板を回転などで移動させることで、厚みムラを平均化す
る工夫が成されてきた。この手法は有効ではあったが、
生産性を考えて複数の基板で同時に素子を作製したり、
基板が大型化してくるようになると、十分満足できるも
のではなくなってきた。厚みムラは発光を司る層だけで
なく、電極や保護層にも悪影響を及ぼす。When a dry film forming system is used in the manufacturing process of the light emitting device, the deposits are uniformly scattered radially from a point-like deposition source. On the other hand, since a general substrate is flat, the distance from the evaporation source varies depending on the location, and thickness unevenness occurs. Therefore, in order to prevent the film thickness unevenness, a device for moving the substrate by rotation or the like to equalize the thickness unevenness has been made. While this technique worked,
In consideration of productivity, devices can be manufactured simultaneously on multiple substrates,
As substrates have become larger, they have become less than satisfactory. The thickness unevenness has an adverse effect not only on the layer that controls light emission but also on the electrodes and the protective layer.
【0007】また、乾式製膜系におけるパターン加工は
シャドーマスクを利用して行われることが多いが、微細
なパターンに対応するには、開口部に挟まれたマスク部
分は糸状に細くなり、強度が不足するために、パターン
形状の精度が悪化する傾向にある。そこで開口部の変形
を防ぐための補強線を設けたシャドーマスクが利用され
るようになったが、補強線によって陰となる部分が生
じ、蒸着パターンが分断されてしまい、特に電極の形成
においては、導通が取れなくなってしまう。これは補強
線を蒸着面より浮かせることで、蒸着物の回り込み現象
を利用し、ある程度は防止されるようになったが、効果
的に蒸着物を回り込ませる方法が望まれている。Further, pattern processing in a dry film forming system is often performed using a shadow mask. However, in order to cope with a fine pattern, the mask portion sandwiched between the openings becomes thin like a thread, and the strength is reduced. , The accuracy of the pattern shape tends to deteriorate. Therefore, a shadow mask provided with a reinforcing line for preventing deformation of the opening has come to be used.However, a shadowed portion is generated by the reinforcing line, and the vapor deposition pattern is divided, particularly in forming an electrode. , Conduction cannot be obtained. This can be prevented to some extent by utilizing the wraparound phenomenon of the deposit by floating the reinforcing wire from the deposition surface, but a method of effectively wrapping the deposit is desired.
【0008】[0008]
【発明が解決しようとする課題】本発明は、かかる従来
技術の問題を解決し、厚みムラがなく、均一な発光の得
られる発光素子の製造方法を提供することを目的とする
ものである。SUMMARY OF THE INVENTION It is an object of the present invention to solve the problems of the prior art and to provide a method for manufacturing a light emitting device capable of obtaining uniform light emission without thickness unevenness.
【0009】[0009]
【課題を解決するための手段】本発明は上記目的を達成
するための、正極と負極の間に発光を司る物質が存在
し、電気エネルギーにより発光する素子において、製造
過程に同一材料を2箇所以上の蒸着源から蒸着させる工
程を含むことを特徴とする発光素子の製造方法とするも
のである。According to the present invention, there is provided an element which emits light by electric energy between a positive electrode and a negative electrode. A method for manufacturing a light-emitting element, comprising the step of vapor deposition from the vapor deposition source described above.
【0010】[0010]
【発明の実施の形態】本発明における正極は、光を取り
出すために透明であれば、酸化錫、酸化インジウム、酸
化錫インジウム(ITO)などの導電性金属酸化物、あ
るいは、金、銀、クロムなどの金属、ヨウ化銅、硫化銅
などの無機導電性物質、ポリチオフェン、ポリピロー
ル、ポリアニリンなどの導電性ポリマなど特に限定され
るものでないが、ITOガラスやネサガラスを用いるこ
とが望ましく、特にITOガラスを用いることが望まし
い。透明電極の抵抗は素子の発光に十分な電流が供給で
きればよいので限定されないが、素子の消費電力の観点
からは低抵抗であることが望ましい。例えば300Ω/
□以下のITOガラス基板であれば素子電極として機能
するが、現在では10Ω/□程度の基板の供給も可能に
なっていることから、20Ω/□以下の低抵抗の基板を
使用することが特に望ましい。ITOの厚みは抵抗値に
合わせて任意に選ぶ事ができるが、通常100〜300
nmの間で用いられることが多い。また、ガラス基板は
ソーダライムガラス、無アルカリガラスなどが用いら
れ、また厚みも機械的強度を保つのに十分な厚みがあれ
ばよいので、0.7mm以上あれば十分である。ガラス
の材質については、ガラスからの溶出イオンが少ない方
がよいので無アルカリガラスの方が好ましいが、SiO
2などのバリアコートを施したソーダライムガラスも市
販されているのでこれを使用できる。ガラス以外の基板
を用いる場合でも、透明で封止効果の高いものであれば
構わない。ITOガラス基板はよく洗浄されていること
が望ましく、またよく乾燥されていることが望ましい。BEST MODE FOR CARRYING OUT THE INVENTION A positive electrode according to the present invention is made of a conductive metal oxide such as tin oxide, indium oxide, indium tin oxide (ITO), or gold, silver, chromium, if it is transparent to extract light. Such metals, copper iodide, inorganic conductive substances such as copper sulfide, and conductive polymers such as polythiophene, polypyrrole, and polyaniline are not particularly limited. However, it is preferable to use ITO glass or Nesa glass. It is desirable to use. The resistance of the transparent electrode is not limited as long as a current sufficient for light emission of the element can be supplied, but is preferably low from the viewpoint of power consumption of the element. For example, 300Ω /
If it is an ITO glass substrate of □ or less, it functions as an element electrode, but it is now possible to supply a substrate of about 10 Ω / □, so it is particularly preferable to use a low-resistance substrate of 20 Ω / □ or less. desirable. The thickness of the ITO can be arbitrarily selected according to the resistance value.
Often used between nm. Further, as the glass substrate, soda lime glass, non-alkali glass or the like is used, and the thickness only needs to be sufficient to maintain the mechanical strength. As for the material of the glass, alkali-free glass is preferred because it is better that ions eluted from the glass are small.
Soda lime glass having a barrier coat such as No. 2 is also commercially available and can be used. Even when a substrate other than glass is used, any substrate may be used as long as it is transparent and has a high sealing effect. It is desirable that the ITO glass substrate be well cleaned and well dried.
【0011】本発明における発光を司る物質の構成は、
1)正孔輸送材料/発光材料、2)正孔輸送材料/発光
材料/電子輸送材料、3)発光材料/電子輸送材料、そ
して、4)以上の組合わせ物質を一層に混合した形態、
のいずれであってもよい。即ち、上記1)〜3)の多層
積層構造の他に、4)のように発光材料単独または発光
材料と正孔輸送材料、あるいは発光材料と正孔輸送材料
および電子輸送材料を含む層を一層設けるだけでもよ
い。発光材料はホスト材料のみでも、ホスト材料とドー
パント材料の組み合わせでも、いずれであってもよい。
また、ドーパント材料はホスト材料の全体に含まれてい
ても、部分的に含まれていても、いずれであってもよ
い。ドーパント材料は積層されていても、分散されてい
ても、いずれであってもよい。In the present invention, the structure of the substance that controls light emission is as follows:
1) a hole transporting material / a light emitting material, 2) a hole transporting material / a light emitting material / an electron transporting material, 3) a light emitting material / an electron transporting material, and 4) a form in which a combination of the above substances is mixed.
Any of these may be used. That is, in addition to the multilayered structures 1) to 3), a layer containing a luminescent material alone or a luminescent material and a hole transporting material, or a layer containing a luminescent material, a hole transporting material and an electron transporting material as in 4) is further provided. It may just be provided. The light emitting material may be either a host material alone or a combination of a host material and a dopant material.
In addition, the dopant material may be included in the entire host material, partially, or may be included. The dopant material may be stacked, dispersed, or the like.
【0012】本発明における正孔輸送材料としては、電
界を与えられた電極間において正極からの正孔を効率良
く輸送することが必要で、正孔注入効率が高く、注入さ
れた正孔を効率良く輸送することが望ましい。そのため
にはイオン化ポテンシャルが小さく、しかも正孔移動度
が大きく、さらに安定性に優れ、トラップとなる不純物
が製造時および使用時に発生しにくい物質であることが
要求される。このような条件を満たす物質として、特に
限定されるものではないが、ビスカルバゾリル誘導体、
TPD、m−MTDATA、α−NPDなどのトリフェ
ニルアミン誘導体、ピラゾリン誘導体、スチルベン系化
合物、ヒドラゾン系化合物、オキサジアゾール誘導体や
フタロシアニン誘導体に代表される複素環化合物、ポリ
ビニルカルバゾール、ポリシランなどの既知の正孔輸送
材料を使用できる。これらの正孔輸送材料は単独でも用
いられるが、異なる正孔輸送材料と積層または混合して
使用しても構わない。The hole transporting material in the present invention is required to efficiently transport holes from the positive electrode between the electrodes to which an electric field is applied, and has a high hole injection efficiency. Good transport is desirable. For that purpose, it is required that the ionization potential be small, the hole mobility be large, the stability be further improved, and impurities serving as traps be hardly generated during production and use. The substance satisfying such conditions is not particularly limited, but is a biscarbazolyl derivative,
Known triphenylamine derivatives such as TPD, m-MTDATA, α-NPD, pyrazoline derivatives, stilbene compounds, hydrazone compounds, heterocyclic compounds represented by oxadiazole derivatives and phthalocyanine derivatives, polyvinyl carbazole, polysilane and the like Hole transport materials can be used. These hole transport materials may be used alone or may be laminated or mixed with different hole transport materials.
【0013】本発明における発光材料の内、ホスト材料
としては特に限定されるものではないが、以前から発光
体として知られていたアントラセンやピレンなどの縮合
環誘導体、トリス(8−キノリノラト)アルミニウムを
始めとする金属キレート化オキシノイド化合物、ビスス
チリルアントラセン誘導体やジスチリルベンゼン誘導体
などのビススチリル誘導体、テトラフェニルブタジエン
誘導体、クマリン誘導体、オキサジアゾール誘導体、ピ
ロロピリジン誘導体、ペリノン誘導体、シクロペンタジ
エン誘導体、オキサジアゾール誘導体、チアジアゾロピ
リジン誘導体、ポリマー系では、ポリフェニレンビニレ
ン誘導体、ポリパラフェニレン誘導体、そして、ポリチ
オフェン誘導体などが使用できる。Among the luminescent materials in the present invention, the host material is not particularly limited, but tris (8-quinolinolato) aluminum, a condensed ring derivative such as anthracene or pyrene, which has been known as a luminescent material before, may be used. Metal chelated oxinoid compounds, bisstyryl derivatives such as bisstyrylanthracene derivatives and distyrylbenzene derivatives, tetraphenylbutadiene derivatives, coumarin derivatives, oxadiazole derivatives, pyrrolopyridine derivatives, perinone derivatives, cyclopentadiene derivatives, oxadiazole For derivatives, thiadiazolopyridine derivatives, and polymer systems, polyphenylenevinylene derivatives, polyparaphenylene derivatives, and polythiophene derivatives can be used.
【0014】ホスト材料に添加するドーパント材料とし
ては特に限定されるものではないが、具体的には従来か
ら知られている、ペリレン、ルブレンなどの縮合環誘導
体、キナクリドン誘導体、フェノキサゾン660、DC
M1、ペリノン、クマリン誘導体などがそのまま使用で
きる。これらのドーパント材料は単独でも、異なるドー
パント材料と併用しても構わない。The dopant material to be added to the host material is not particularly limited, but specific examples thereof include condensed ring derivatives such as perylene and rubrene, quinacridone derivatives, phenoxazone 660, DC
M1, perinone, coumarin derivatives and the like can be used as they are. These dopant materials may be used alone or in combination with different dopant materials.
【0015】本発明における電子輸送性材料としては、
電界を与えられた電極間において負極からの電子を効率
良く輸送することが必要で、電子注入効率が高く、注入
された電子を効率良く輸送することが望ましい。そのた
めには電子親和力が大きく、しかも電子移動度が大き
く、さらに安定性に優れ、トラップとなる不純物が製造
時および使用時に発生しにくい物質であることが要求さ
れる。このような条件を満たす物質として、8−ヒドロ
キシキノリンアルミニウムに代表されるキノリノール誘
導体金属錯体、トロポロン金属錯体、フラボノール金属
錯体、ペリレン誘導体、ペリノン誘導体、ナフタレン、
クマリン誘導体、オキサジアゾール誘導体、アルダジン
誘導体、ビススチリル誘導体、ピラジン誘導体、フェナ
ントロリン誘導体などがあるが特に限定されるものでは
ない。これらの電子輸送材料は単独でも用いられるが、
異なる電子輸送材料と積層または混合して使用しても構
わない。As the electron transporting material in the present invention,
It is necessary to efficiently transport electrons from the negative electrode between the electrodes to which an electric field is applied, and it is desirable that the electron injection efficiency is high and the injected electrons are transported efficiently. For this purpose, it is required that the material has a high electron affinity, a high electron mobility, a high stability, and a small amount of impurities serving as traps during production and use. Materials satisfying such conditions include quinolinol derivative metal complexes represented by 8-hydroxyquinoline aluminum, tropolone metal complexes, flavonol metal complexes, perylene derivatives, perinone derivatives, naphthalene,
There are coumarin derivatives, oxadiazole derivatives, aldazine derivatives, bisstyryl derivatives, pyrazine derivatives, phenanthroline derivatives, and the like, but are not particularly limited. Although these electron transport materials are used alone,
They may be laminated or mixed with different electron transport materials.
【0016】本発明における負極は、電子を効率よく、
発光を司る物質に注入できる物質であれば特に限定され
ない。一般的には白金、金、銀、銅、鉄、錫、アルミニ
ウム、インジウム、リチウム、ナトリウム、カリウム、
カルシウム、マグネシウムなどがあげられる。電子注入
効率を上げて素子特性を向上させるためには、リチウ
ム、ナトリウム、カリウム、カルシウム、マグネシウム
などの低仕事関数金属が有効である。しかし、これらの
低仕事関数金属は一般に不安定であるので、安定な金属
との合金あるいは積層構造にするのが望ましい。あるい
は発光を司る物質にドーピングする方法も有効である。The negative electrode of the present invention efficiently converts electrons,
The substance is not particularly limited as long as it can be injected into the substance that controls light emission. Generally, platinum, gold, silver, copper, iron, tin, aluminum, indium, lithium, sodium, potassium,
Examples include calcium and magnesium. In order to increase the electron injection efficiency and improve the device characteristics, a low work function metal such as lithium, sodium, potassium, calcium, and magnesium is effective. However, since these low work function metals are generally unstable, it is desirable to form an alloy or a laminated structure with the stable metal. Alternatively, a method of doping a substance which controls light emission is also effective.
【0017】本発明における発光素子は封止をしても構
わない。また、その前に発光素子を保護するために保護
層を設けても構わない。保護層の材料としては、白金、
金、銀、銅、鉄、錫、鉛、アルミニウム、チタン、ニッ
ケル、インジウムなどの金属、またはこれらの金属を用
いた合金、そしてシリカ、チタニア、アルミナ、酸化マ
グネシウム、酸化イットリウム、酸化ゲルマニウム、酸
化ニッケル、酸化バリウム、酸化カルシウム、酸化鉄な
どの金属酸化物、フッ化マグネシウム、フッ化リチウ
ム、フッ化アルミニウム、フッ化カルシウムなどの金属
フッ化物、フッ素系樹脂などの樹脂類などがあげられる
が、特に限定されるものではない。The light emitting device of the present invention may be sealed. Before that, a protective layer may be provided to protect the light-emitting element. Platinum,
Metals such as gold, silver, copper, iron, tin, lead, aluminum, titanium, nickel, and indium, or alloys using these metals, and silica, titania, alumina, magnesium oxide, yttrium oxide, germanium oxide, and nickel oxide , Barium oxide, calcium oxide, metal oxides such as iron oxide, magnesium fluoride, lithium fluoride, aluminum fluoride, metal fluorides such as calcium fluoride, resins such as fluororesins, and the like. It is not limited.
【0018】本発明における封止の方法は封止材による
容器内に発光素子を入れて接着剤で封止する方法や、発
光素子が形成された基板と薄板状の封止材で挟み込んで
接着剤で封止する方法などがあげられるが、特に限定さ
れるものではない。The method of sealing in the present invention is a method in which a light emitting element is put in a container made of a sealing material and sealed with an adhesive, or a method in which the light emitting element is bonded to a substrate on which the light emitting element is formed by sandwiching it with a thin sealing material. Examples include a method of sealing with an agent, but the method is not particularly limited.
【0019】封止材は発光素子に水分が侵入するのを防
止するものであれば、特に制限されるものではない。具
体的にはソーダ石灰ガラス、硼硅酸塩ガラス、硅酸塩ガ
ラス、シリカガラス、無蛍光ガラス、石英、セラミック
スなどの無機物や、ステンレス、アルミニウム合金など
の金属、フッ素系樹脂、アクリル系樹脂、ポリカーボネ
ート系樹脂、エポキシ系樹脂、ポリエステル系樹脂、ポ
リアミド系樹脂、ポリスチレン系樹脂、ポリエチレン系
樹脂、ポリプロピレン系樹脂、ポリオレフィン系樹脂、
シリコーン系樹脂などの樹脂類があげられる。The sealing material is not particularly limited as long as it prevents moisture from entering the light emitting element. Specifically, soda-lime glass, borosilicate glass, silicate glass, silica glass, non-fluorescent glass, quartz, inorganic substances such as ceramics, metals such as stainless steel and aluminum alloy, fluorine resin, acrylic resin, Polycarbonate resin, epoxy resin, polyester resin, polyamide resin, polystyrene resin, polyethylene resin, polypropylene resin, polyolefin resin,
Examples include resins such as silicone resins.
【0020】封止に用いる接着剤は封止効果を有するも
のであれば特に制限されるものではない。具体的には、
エポキシ樹脂系接着剤、アクリレート樹脂系接着剤など
を用いることができる。また、光硬化性樹脂接着剤、熱
硬化性樹脂接着剤、嫌気性樹脂接着剤などを用いること
ができる。The adhesive used for sealing is not particularly limited as long as it has a sealing effect. In particular,
An epoxy resin-based adhesive, an acrylate resin-based adhesive, or the like can be used. In addition, a photocurable resin adhesive, a thermosetting resin adhesive, an anaerobic resin adhesive, or the like can be used.
【0021】発光素子と封止材の間には吸着剤を含んで
も構わない。吸着剤は封止後において外部から侵入する
水分を吸着するものであれば特に限定されるものではな
い。具体的には、活性アルミナ、珪藻土、活性炭、五酸
化リン、過塩素酸マグネシウム、水酸化カリウム、硝酸
カルシウム、臭化カルシウム、酸化カルシウム、酸化バ
リウム、炭酸バリウム、塩化亜鉛、臭化亜鉛、無水硫酸
銅などの無機化合物、リチウム、ベリリウム、カリウ
ム、ナトリウム、マグネシウム、ルビジウム、ストロン
チウム、カルシウムなど金属およびその合金、アクリル
系やメタクリル系吸水ポリマーなどがあげられる。An adsorbent may be included between the light emitting element and the sealing material. The adsorbent is not particularly limited as long as it adsorbs moisture that enters from outside after sealing. Specifically, activated alumina, diatomaceous earth, activated carbon, phosphorus pentoxide, magnesium perchlorate, potassium hydroxide, calcium nitrate, calcium bromide, calcium oxide, barium oxide, barium carbonate, zinc chloride, zinc bromide, sulfuric anhydride Examples include inorganic compounds such as copper, metals such as lithium, beryllium, potassium, sodium, magnesium, rubidium, strontium, and calcium and alloys thereof, and acrylic and methacrylic water-absorbing polymers.
【0022】本発明における発光素子の薄膜形成方法は
特に限定されるものではなく、ディップコーティング
法、スピンキャスト法、分子積層法、電解重合法などの
湿式製膜法も一部では用いることができるが、乾式製膜
法が特性面で好ましいので、薄膜形成過程の全部あるい
は少なくとも一部で用いられる。乾式製膜法としては、
抵抗加熱蒸着法、電子ビーム蒸着法、イオンプレーティ
ング法、スパッタリング法、CVD法などがあげられる
が、抵抗加熱蒸着法、電子ビーム蒸着法、スパッタリン
グ法が容易に利用できる。The method for forming a thin film of a light emitting device in the present invention is not particularly limited, and a wet film forming method such as a dip coating method, a spin casting method, a molecular laminating method, and an electrolytic polymerization method can be partially used. However, since the dry film forming method is preferable in terms of characteristics, it is used in all or at least a part of the thin film forming process. As a dry film forming method,
Examples thereof include a resistance heating evaporation method, an electron beam evaporation method, an ion plating method, a sputtering method, and a CVD method, and the resistance heating evaporation method, the electron beam evaporation method, and the sputtering method can be easily used.
【0023】ここで広い基板面へ蒸着する場合の膜厚の
均一性について、蒸着源が1個の場合を図1に示す。便
宜上、紙面に垂直方向については無視して、左右方向の
膜厚ムラを考える。図1の下のように理想的には蒸着物
2は蒸着源3から均一に放射状に放出される。すなわち
蒸着源に近い程多くの蒸着物は堆積することになる。基
板1は平面であるため蒸着源との距離は中心部は近く端
部は遠くなるので、模式的には図1の上に示すような膜
厚分布となる。すなわち中心から離れた基板端部では中
心部より膜厚がかなり薄くなってしまう。FIG. 1 shows the uniformity of the film thickness when vapor deposition is performed on a wide substrate surface in the case where one vapor deposition source is used. For the sake of convenience, the film thickness non-uniformity in the left-right direction is considered, ignoring the direction perpendicular to the paper. Ideally, the deposit 2 is uniformly and radially emitted from the deposition source 3 as shown in the lower part of FIG. That is, the closer to the deposition source, the more deposited material is deposited. Since the substrate 1 is a flat surface, the distance from the deposition source is closer to the center and closer to the end, so that the film thickness distribution is schematically shown in the upper part of FIG. That is, the film thickness at the end of the substrate away from the center is considerably smaller than at the center.
【0024】膜厚ムラを減らすためには基板中心部と蒸
着源の距離と基板端部と蒸着源との距離との差が無視で
きる程、基板と蒸着源との距離をとる手段もあるが、装
置の大型化が必要となり、また蒸着源から放出された蒸
着物を有効に活用することができなくなってしまう。In order to reduce the film thickness unevenness, there is a means for increasing the distance between the substrate and the vapor deposition source so that the difference between the distance between the substrate center and the vapor deposition source and the distance between the substrate end and the vapor deposition source can be ignored. In addition, it is necessary to increase the size of the apparatus, and it is not possible to effectively use the deposits discharged from the deposition source.
【0025】そこで本発明においては乾式で製膜される
層の全部あるいは一部は、薄膜形成時の厚みムラを防ぐ
ために、同一材料が2箇所以上の蒸着源から蒸着され
る。例えば図2の下に示したように4つの蒸着源3を配
置する場合を考えると、蒸着物2はそれぞれの蒸着源か
ら分散して堆積するので、厚みムラは解消される、膜厚
分布は模式的には図2上に示したようになる。すなわち
中心から離れた基板端部においても、中心部に近い膜厚
を得ることができる。また図3の下に示したように4つ
の蒸着源3を配置し、さらに両端の蒸着源3の蒸着速度
を上げてやることで上手くバランスをとってやると、さ
らに厚みムラは解消され、膜厚分布は模式的には図3の
上に示すようになる。このことから蒸着源はそれぞれ独
立に制御されることが好ましい。蒸着源の制御は特に限
定されるものではないが、膜厚モニターや電源を独立さ
せることで行うことができ、また補正板を設けることに
よって制御しても構わない。複数の制御方法を組み合わ
せることも可能である。Therefore, in the present invention, the same material is vapor-deposited from two or more vapor deposition sources on all or a part of a layer formed by a dry method in order to prevent thickness unevenness when forming a thin film. For example, considering the case where four evaporation sources 3 are arranged as shown in the lower part of FIG. 2, since the evaporation object 2 is dispersedly deposited from each of the evaporation sources, thickness unevenness is eliminated. This is schematically as shown in FIG. That is, a film thickness close to the center can be obtained even at the end of the substrate away from the center. When four evaporation sources 3 are arranged as shown in the lower part of FIG. 3 and the evaporation rate of the evaporation sources 3 at both ends is further increased to achieve a good balance, the thickness unevenness is further eliminated, and the film thickness is reduced. The thickness distribution is schematically as shown in the upper part of FIG. For this reason, it is preferable that the evaporation sources be controlled independently. Although the control of the evaporation source is not particularly limited, it can be performed by making the film thickness monitor and the power source independent, or may be controlled by providing a correction plate. It is also possible to combine a plurality of control methods.
【0026】また、その効果をより大きくするために基
板を移動させながら蒸着することが好ましい。基板を移
動させることで、膜厚ムラを均一化するためである。基
板の移動方法に特に制限はないが、蒸着源に平行方向の
一方向のみあるいは往復および往復の繰返しの移動、多
角形の辺や円周、楕円周に沿った移動などがあげられ
る。移動は直線的でも蛇行しても、折れ線的でも構わな
い。蒸着は真空中で行われるので移動させる空間が大き
くないことが望ましく、蒸着装置中でコンパクトにかつ
充分な移動をさせるためには基板を回転させる方法が好
ましい。回転速度に特に制限はないが、蒸着中に少なく
とも一回転以上することが好ましい。また、回転速度は
一定であっても変化させてもよく、断続的に回転させて
も、反転をさせても構わない。蒸着源と基板の回転軸に
ついても特に制限を受けるものではないが、回転軸上に
基板と蒸着源が同時に重ならないようにするのが好まし
い。基板は自転しても公転しても、また自転しながら公
転しても構わない。相対的に移動していることが肝要で
あるので本質的には基板を固定して蒸着源を移動させて
も構わない。In order to further increase the effect, it is preferable to perform the vapor deposition while moving the substrate. This is to make the film thickness unevenness uniform by moving the substrate. The method of moving the substrate is not particularly limited, and examples thereof include a movement in only one direction parallel to the evaporation source or a reciprocating and reciprocating movement, a movement along a polygonal side, a circumference, and an ellipse. The movement may be linear, meandering, or polygonal. Since the vapor deposition is performed in a vacuum, it is desirable that the space to be moved is not large. In order to move the substrate compactly and sufficiently in the vapor deposition apparatus, a method of rotating the substrate is preferable. The rotation speed is not particularly limited, but is preferably at least one rotation during vapor deposition. Further, the rotation speed may be constant or changed, and may be intermittently rotated or reversed. The rotation axis of the deposition source and the substrate is not particularly limited, but it is preferable that the substrate and the deposition source do not overlap on the rotation axis at the same time. The substrate may be rotated, revolved, or revolved while rotating. Since it is important that they move relatively, the substrate may be essentially fixed and the evaporation source may be moved.
【0027】蒸着速度は特に制限されるものではない
が、通常の行われる蒸着速度である1秒間あたり100
分の1nm程度〜30nm程度で蒸着することができ
る。また前述のとおり蒸着源それぞれの蒸着速度は同じ
であっても異なっていても構わない。蒸着速度は一般的
に蒸着温度を上げることである程度速くすることができ
るが、蒸着温度を上げることは蒸着物へ分解等の影響を
与えることが懸念される。同一材料を2箇所以上の蒸着
源から蒸着させる工程は、蒸着源の温度を上げずに蒸着
速度を速めることで必要な膜厚を形成する時間を短縮す
ることも可能となり、生産性の面からも効果的である。The deposition rate is not particularly limited, but may be 100% per second, which is a normal deposition rate.
It can be deposited at a thickness of about 1 nm to about 30 nm. Further, as described above, the evaporation rates of the evaporation sources may be the same or different. In general, the deposition rate can be increased to some extent by increasing the deposition temperature. However, there is a concern that increasing the deposition temperature may affect the deposited material such as decomposition. In the step of depositing the same material from two or more deposition sources, the time required to form a required film thickness can be reduced by increasing the deposition rate without increasing the temperature of the deposition source, and from the viewpoint of productivity. Is also effective.
【0028】蒸着源のお互いの配置、基板との位置関係
等については特に制限はなく、蒸着速度等の蒸着時の他
のパラメータと、結果的に膜厚ムラを抑えるようにバラ
ンスを調整するのが好ましい。蒸着源と基板との距離は
それぞれ同じであっても異なっていてもよく、蒸着源は
片寄って配置されていても平均的に配置されていても構
わない。平均的に配置する方法では、点対称や線対称等
特に制限されるものはなく、正三角形や正方形等の正多
角形の頂点に配置したり、円周上に配置する方法、等間
隔の線分や升目状に配置する方法等があげられるが、特
に限定されるものではない。There is no particular limitation on the mutual arrangement of the evaporation sources, the positional relationship with the substrate, and the like. The balance is adjusted so that other parameters during evaporation, such as the evaporation speed, and as a result, the film thickness unevenness is suppressed. Is preferred. The distances between the evaporation source and the substrate may be the same or different, and the evaporation sources may be arranged offset or averagely. In the method of averaging, there is no particular limitation such as point symmetry and line symmetry, such as arranging at the vertices of a regular polygon such as an equilateral triangle or square, arranging on a circumference, equally spaced lines Although a method of arranging in a minute or square shape can be mentioned, it is not particularly limited.
【0029】蒸着源へ蒸着物質を供給する方法について
は特に制限するものではなく、バッチ式でも、連続的に
供給しても構わない。The method for supplying the deposition material to the deposition source is not particularly limited, and may be a batch type or a continuous supply.
【0030】また、蒸着源についてはその材質、形状と
も特に限定されるものではなく、タングステン、モリブ
デン、タンタル、ニオブ製等のフィラメント、バスケッ
トやボート等、また、アルミナやBN製等のルツボ等が
使用できる。The material and shape of the evaporation source are not particularly limited, and filaments such as tungsten, molybdenum, tantalum and niobium, baskets and boats, and crucibles such as alumina and BN can be used. Can be used.
【0031】基板の配置数に特に制限はなく、1枚だけ
セットしても複数枚をセットしても、多面取りを行って
も構わない。基板の蒸着源に対する傾きについては特に
限定されるものではなく、並行でも傾きを有していても
構わない。基板のサイズに特に限定はないが、基板サイ
ズが大きかったり、小さいサイズでも多面取りをして一
度に広い面積に蒸着するような場合に本発明の効果は大
きい。There is no particular limitation on the number of substrates to be arranged, and one substrate may be set, a plurality of substrates may be set, or multiple substrates may be formed. The inclination of the substrate with respect to the deposition source is not particularly limited, and may be parallel or inclined. The size of the substrate is not particularly limited, but the effect of the present invention is great when the substrate size is large, or when the substrate is multi-panned and vapor-deposited on a large area at once.
【0032】発光素子を構成する各層の内、発光を司る
物質においては、抵抗のばらつきによる発光ムラが生じ
たり、ひどい場合は薄い部分に電界が集中することによ
り素子が破壊され、短絡による非発光部分の発生や発光
効率の低下が引き起こされたり、破壊された部分から水
分などが進入し、非発光部分が拡大して耐久性にも影響
を与えるなど、厚みムラが発光素子に与える影響が大き
いことから、逆に効果が最も大きい。電極においても厚
みムラは発光ムラや断線などの弊害をもたらすので効果
的であり、保護層においても厚みムラは体積変化による
歪みを生じさせるのでやはり効果的である。また本発明
の蒸着方法は、発光材料を用いた発光部分形成、電極形
成のいずれでも好適に用いられるが、発光部分の形成に
とってより効果が大きい。Among the layers constituting the light emitting element, in the substance which controls light emission, uneven light emission occurs due to variation in resistance, and in severe cases, the element is destroyed due to concentration of an electric field on a thin portion, and non-light emission due to short circuit occurs. The thickness unevenness has a large effect on the light-emitting element, such as the occurrence of a portion or a decrease in luminous efficiency, or the invasion of moisture or the like from the destroyed portion, and the non-light-emitting portion expands and affects the durability. Therefore, the effect is the largest. The thickness unevenness of the electrode is also effective because it causes adverse effects such as light emission unevenness and disconnection, and the thickness unevenness of the protective layer is also effective because it causes distortion due to volume change. In addition, the vapor deposition method of the present invention is suitably used for both formation of a light emitting portion using a light emitting material and formation of an electrode, but is more effective for forming a light emitting portion.
【0033】本発明における発光素子のパターン形成に
は、特に限定されないが、シャドーマスクを用いること
が好ましい。微細なパターンに対応するために、開口部
の変形を防ぐための補強線を設けたシャドーマスクを利
用することがさらに好ましい。ここで、補強線を設けた
シャドーマスクを利用して負極を形成する場合には、本
発明の蒸着方法は非常に効果的である。補強線シャドー
マスクは補強線によって陰となる部分が生じ、蒸着パタ
ーンが分断されてしまうという問題がある。これを回避
するために、補強線を蒸着面より浮かせることで、蒸着
物の回り込み現象を利用される。本発明の蒸着方法は、
効果的に蒸着物が回り込む方法であるので、より効果が
大きい。上記に加えて、補強線による厚みムラの影響は
配線抵抗にも大きく影響するので、本発明は効果的であ
る。The pattern formation of the light emitting element in the present invention is not particularly limited, but it is preferable to use a shadow mask. In order to cope with a fine pattern, it is more preferable to use a shadow mask provided with a reinforcing line for preventing deformation of the opening. Here, when forming a negative electrode using a shadow mask provided with a reinforcing wire, the vapor deposition method of the present invention is very effective. The reinforcing line shadow mask has a problem that a shadowed portion is generated by the reinforcing line and the vapor deposition pattern is divided. In order to avoid this, the wraparound phenomenon of the deposited material is used by floating the reinforcing wire from the deposition surface. The deposition method of the present invention,
The method is more effective because the deposited material is effectively wrapped around. In addition to the above, the present invention is effective because the effect of thickness unevenness due to the reinforcing wire greatly affects the wiring resistance.
【0034】本発明における電気エネルギーとは主に直
流電流を指すが、パルス電流や交流電流を用いることも
可能である。電流値および電圧値は特に制限はないが、
素子の消費電力、寿命を考慮すると、できるだけ低いエ
ネルギーで最大の輝度が得られるようにするべきであ
る。The electric energy in the present invention mainly refers to a direct current, but it is also possible to use a pulse current or an alternating current. The current value and voltage value are not particularly limited,
In consideration of the power consumption and life of the device, it is necessary to obtain the maximum brightness with the lowest possible energy.
【0035】本発明の発光素子はマトリクスまたはセグ
メント方式、あるいはその両者を組み合わせることによ
って表示するディスプレイを構成することが好ましい。It is preferable that the light emitting device of the present invention constitutes a display for displaying by a matrix or segment system or a combination of both.
【0036】本発明におけるマトリクスは、表示のため
の画素が格子状に配置されたものをいい、画素の集合で
文字や画像を表示する。画素の形状、サイズは用途によ
って決まる。例えばパソコン、モニター、テレビの画像
および文字表示には、通常、一辺が300μm以下の四
角形の画素が用いられるし、表示パネルのような大型デ
ィスプレイの場合は、一辺がmmオーダーの画素を用い
ることになる。モノクロ表示の場合は、同じ色の画素を
配列すればよいが、カラー表示の場合には赤、緑、青の
画素を並べて表示させる。この場合典型的にはデルタタ
イプとストライプタイプがある。尚、本発明における発
光素子は、赤、緑、青色発光が可能であるので、前記表
示方法を用いれば、マルチカラーまたはフルカラー表示
もできる。そして、このマトリクスの駆動方法として
は、線順次駆動方法やアクティブマトリックスのどちら
でもよい。線順次駆動の方が構造が簡単という利点があ
るが、動作特性を考慮するとアクティブマトリックスの
方が優れる場合があるので、これも用途により使い分け
ることが必要である。The matrix according to the present invention refers to a matrix in which pixels for display are arranged in a lattice, and displays a character or an image by a set of pixels. The shape and size of the pixel depend on the application. For example, for the display of images and characters on personal computers, monitors, televisions, and the like, generally square pixels with a side of 300 μm or less are used, and in the case of a large display such as a display panel, pixels with a side on the order of mm are used. Become. In the case of monochrome display, pixels of the same color may be arranged, but in the case of color display, red, green and blue pixels are displayed side by side. In this case, there are typically a delta type and a stripe type. Note that the light-emitting element of the present invention can emit red, green, and blue light, so that multi-color or full-color display can be performed by using the display method. The matrix may be driven by either a line-sequential driving method or an active matrix. The line-sequential driving has the advantage of a simpler structure, but the active matrix is sometimes superior in consideration of the operating characteristics. Therefore, it is necessary to use this depending on the application.
【0037】本発明におけるセグメントタイプは、予め
決められた情報を表示するようにパターンを形成し、決
められた領域を発光させる。例えば、デジタル時計や温
度計における時刻や温度表示、オーディオ機器や電磁調
理器などの動作状態表示、自動車のパネル表示などがあ
げられる。そして、前記マトリクス表示とセグメント表
示は同じパネルの中に共存していてもよい。In the segment type according to the present invention, a pattern is formed so as to display predetermined information, and a predetermined area emits light. For example, there are a time display and a temperature display on a digital clock or a thermometer, an operation state display of an audio device, an electromagnetic cooker, or the like, and a panel display of an automobile. The matrix display and the segment display may coexist in the same panel.
【0038】本発明の発光素子はバックライトとしても
好ましく用いられる。本発明におけるバックライトは、
主に自発光しない表示装置の視認性を向上させる目的に
使用され、液晶表示装置、時計、オーディオ装置、自動
車パネル、表示板、標識などに使用される。特に液晶表
示装置、中でも薄型化が課題となっているパソコン用途
のバックライトとしては、従来方式のものが蛍光灯や導
光板からなっているため薄型化が困難であることを考え
ると、本発明におけるバックライトは薄型、軽量が特徴
になる。The light emitting device of the present invention is also preferably used as a backlight. The backlight in the present invention,
It is mainly used for improving the visibility of a display device that does not emit light, and is used for a liquid crystal display device, a clock, an audio device, an automobile panel, a display panel, a sign, and the like. In particular, as for the backlight for liquid crystal display devices, particularly for personal computer applications where thinning is an issue, the present invention is considered to be difficult because the conventional type is made of a fluorescent lamp or a light guide plate, and it is difficult to make it thin. Is characterized by its thinness and light weight.
【0039】[0039]
【実施例】以下、実施例および比較例をあげて本発明を
説明するが、本発明はこれらの例によって限定されるも
のではない。 実施例1 ITO透明導電膜を150nm堆積させたガラス基板
(旭硝子社製、15Ω/□、電子ビーム蒸着品)を23
0×150mmに切断、フォトリソグラフィ法によって
300μmピッチ(残り幅270μm)×640本のス
トライプ状にパターン加工した。得られた基板をアセト
ン、セミコクリン56で各々15分間超音波洗浄してか
ら、超純水で洗浄した。続いてイソプロピルアルコール
で15分間超音波洗浄してから熱メタノールに15分間
浸漬させて乾燥させた。この基板を素子を作製する直前
に1時間UV−オゾン処理し、真空蒸着装置内に設置し
て、装置内の真空度が5×10-4Pa以下になるまで排
気した。蒸着源(タングステン製ボート)を2箇所にセ
ットし、基板を回転させながら、抵抗加熱法によって、
まず正孔輸送材料として4,4’−ビス(N−(m−ト
リル)−N−フェニルアミノ)ビフェニルを150nm
蒸着し、同様に蒸着源を2箇所にセットして、電子輸送
性発光層として、トリスキノリノラートアルミニウム
(III)を100nmの厚さに蒸着した。ここで言う
膜厚は水晶発振式膜厚モニター表示値である。次に48
0本の250μmの開口部(残り幅50μm、300μ
mピッチに相当)を設けたシャドーマスクを、真空中で
ITOストライプに直交するようにマスク交換し、シャ
ドーマスクとITO基板が密着するように裏面から磁石
で固定した。シャドーマスクのマスク部分の厚さは10
0μmであり、マスク部分のITO基板密着面と反対側
には幅40μm、厚さ35μm、対向する二辺の間隔が
200μmの正六角形構造から成るメッシュ状の補強線
が形成されている。ITO基板との隙間はマスク部分の
厚さの100μmとなる。陰極としてマグネシウムを5
0nm、アルミニウムを1μm蒸着して640×480
ドットマトリクス素子を作製した。本素子をマトリクス
駆動させたところ、輝度ムラは15%で文字表示でき
た。The present invention will be described below with reference to examples and comparative examples, but the present invention is not limited to these examples. Example 1 A glass substrate (15 Ω / □, manufactured by Asahi Glass Co., electron beam evaporation product) on which an ITO transparent conductive film was deposited to a thickness of 150 nm
It was cut into 0 × 150 mm and patterned by photolithography into 300 μm pitch (remaining width 270 μm) × 640 stripes. The obtained substrate was subjected to ultrasonic cleaning with acetone and semicocrine 56 for 15 minutes each, and then with ultrapure water. Subsequently, the substrate was subjected to ultrasonic cleaning with isopropyl alcohol for 15 minutes, immersed in hot methanol for 15 minutes, and dried. This substrate was subjected to UV-ozone treatment for one hour immediately before the device was manufactured, placed in a vacuum evaporation apparatus, and evacuated until the degree of vacuum in the apparatus became 5 × 10 −4 Pa or less. Set the evaporation source (tungsten boat) at two places, rotate the substrate, and use the resistance heating method.
First, 150 nm of 4,4′-bis (N- (m-tolyl) -N-phenylamino) biphenyl was used as a hole transport material.
In the same manner, vapor deposition sources were set at two places, and trisquinolinolate aluminum (III) was vapor deposited to a thickness of 100 nm as an electron transporting light emitting layer. The film thickness referred to here is a value indicated by a crystal oscillation type film thickness monitor. Then 48
0 openings of 250 μm (remaining width 50 μm, 300 μm
The shadow mask provided with (equivalent to m pitches) was exchanged in a vacuum so as to be orthogonal to the ITO stripe, and was fixed with a magnet from the back surface so that the shadow mask and the ITO substrate were in close contact with each other. The thickness of the mask part of the shadow mask is 10
A mesh-like reinforcing line having a regular hexagonal structure having a width of 40 μm, a thickness of 35 μm, and a distance between two opposing sides of 200 μm is formed on the side of the mask portion opposite to the ITO substrate contact surface. The gap with the ITO substrate is 100 μm, which is the thickness of the mask portion. 5 magnesium as cathode
0 nm, 1 μm of aluminum is deposited and 640 × 480
A dot matrix device was manufactured. When this device was driven in a matrix, characters could be displayed at a luminance unevenness of 15%.
【0040】実施例2 陰極のマグネシウムとアルミニウムも蒸着源を2箇所に
して蒸着した以外は実施例と全く同様に作製した素子を
マトリクス駆動させたところ、輝度ムラは11%で文字
表示できた。Example 2 Magnesium and aluminum for the cathode were also driven in a matrix exactly as in the example except that the vapor deposition was performed using two vapor deposition sources, and a luminance display of 11% was achieved.
【0041】比較例1 すべての蒸着源を1箇所にして蒸着を行った以外は実施
例1と全く同様にして作製した素子を駆動させたとこ
ろ、表示ムラは32%であった。Comparative Example 1 An element manufactured in exactly the same manner as in Example 1 except that evaporation was performed using one evaporation source at one location was driven. As a result, display unevenness was 32%.
【0042】[0042]
【発明の効果】本発明は、厚みムラがなく、均一な発光
の得られる発光素子の製造方法を提供できるものであ
る。According to the present invention, it is possible to provide a method for manufacturing a light-emitting element capable of obtaining uniform light emission without thickness unevenness.
【図1】1個の蒸着源による膜厚不均一性の概略図。FIG. 1 is a schematic diagram of film thickness non-uniformity due to one evaporation source.
【図2】4個の等蒸着速度の蒸着源による膜厚均一性の
概略図。FIG. 2 is a schematic diagram of film thickness uniformity by four evaporation sources at an equal evaporation rate.
【図3】4個の不等蒸着速度の蒸着源による膜厚均一性
の概略図。FIG. 3 is a schematic diagram of film thickness uniformity by four evaporation sources having different evaporation rates.
1 基板 2 蒸着物 3 蒸着源 DESCRIPTION OF SYMBOLS 1 Substrate 2 Deposit 3 Deposition source
Claims (7)
し、電気エネルギーにより発光する素子において、製造
過程に同一材料を2箇所以上の蒸着源から蒸着させる工
程を含むことを特徴とする発光素子の製造方法。1. A device which emits light by electric energy, wherein a substance responsible for light emission is present between a positive electrode and a negative electrode, the manufacturing process comprising a step of depositing the same material from two or more deposition sources. A method for manufacturing a light-emitting element.
とする請求項1記載の発光素子の製造方法。2. The method according to claim 1, wherein said material is a substance which controls light emission.
スクを用いる工程を含むことを特徴とする請求項1記載
の発光素子の製造方法。3. The method according to claim 1, further comprising the step of using a shadow mask provided with reinforcing lines for pattern formation.
を特徴とする請求項1〜3のいずれか記載の発光素子の
製造方法。4. The method according to claim 1, wherein the evaporation sources are independently controlled.
とを特徴とする請求項1〜4のいずれか記載の発光素子
の製造方法。5. The method according to claim 1, wherein the substrate on which the deposition material is deposited is moving.
とを特徴とする請求項1〜5のいずれか記載の発光素子
の製造方法。6. The method according to claim 1, wherein the substrate on which the deposition material is deposited is rotating.
メント方式によって表示するディスプレイであることを
特徴とする請求項1〜6のいずれか記載の発光素子の製
造方法。7. The method for manufacturing a light emitting device according to claim 1, wherein the light emitting device is a display for displaying in a matrix and / or a segment system.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP11231218A JP2000138095A (en) | 1998-08-26 | 1999-08-18 | Manufacture of light emitting device |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10-240333 | 1998-08-26 | ||
| JP24033398 | 1998-08-26 | ||
| JP11231218A JP2000138095A (en) | 1998-08-26 | 1999-08-18 | Manufacture of light emitting device |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JP2000138095A true JP2000138095A (en) | 2000-05-16 |
Family
ID=26529757
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP11231218A Pending JP2000138095A (en) | 1998-08-26 | 1999-08-18 | Manufacture of light emitting device |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2000138095A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001313169A (en) * | 2000-05-01 | 2001-11-09 | Nec Corp | Manufacturing method of organic EL display |
| KR100340732B1 (en) * | 2000-05-26 | 2002-06-20 | 천웅기 | Heating crucible of apparatus for depositing a organic materials |
| JP2007123285A (en) * | 2002-07-19 | 2007-05-17 | Lg Electron Inc | Deposition source for organic electroluminescent film deposition |
| KR100934073B1 (en) * | 2002-07-04 | 2009-12-24 | 독키 가부시키가이샤 | Deposition equipment and thin film manufacturing method |
| WO2017149985A1 (en) * | 2016-03-04 | 2017-09-08 | ソニー株式会社 | Organic electroluminescent element and method for manufacturing organic electroluminescent element |
| CN113042757A (en) * | 2021-04-27 | 2021-06-29 | 天津清研智束科技有限公司 | Prevent vibration material disk device of coating by vaporization |
| CN115275034A (en) * | 2016-06-30 | 2022-11-01 | 三星显示有限公司 | Organic light emitting device including electron transport layer and method of manufacturing the same |
-
1999
- 1999-08-18 JP JP11231218A patent/JP2000138095A/en active Pending
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001313169A (en) * | 2000-05-01 | 2001-11-09 | Nec Corp | Manufacturing method of organic EL display |
| KR100340732B1 (en) * | 2000-05-26 | 2002-06-20 | 천웅기 | Heating crucible of apparatus for depositing a organic materials |
| KR100934073B1 (en) * | 2002-07-04 | 2009-12-24 | 독키 가부시키가이샤 | Deposition equipment and thin film manufacturing method |
| JP2007123285A (en) * | 2002-07-19 | 2007-05-17 | Lg Electron Inc | Deposition source for organic electroluminescent film deposition |
| WO2017149985A1 (en) * | 2016-03-04 | 2017-09-08 | ソニー株式会社 | Organic electroluminescent element and method for manufacturing organic electroluminescent element |
| CN108701772A (en) * | 2016-03-04 | 2018-10-23 | 索尼公司 | Organic electroluminescent element and method for manufacturing organic electroluminescent element |
| US10727448B2 (en) | 2016-03-04 | 2020-07-28 | Sony Corporation | Organic electro-luminescence device, and method of manufacturing organic electro-luminescence device |
| CN115275034A (en) * | 2016-06-30 | 2022-11-01 | 三星显示有限公司 | Organic light emitting device including electron transport layer and method of manufacturing the same |
| CN113042757A (en) * | 2021-04-27 | 2021-06-29 | 天津清研智束科技有限公司 | Prevent vibration material disk device of coating by vaporization |
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