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JP2002029944A - Additive for hair treatment agent, hair treatment agent to which this additive is added - Google Patents

Additive for hair treatment agent, hair treatment agent to which this additive is added

Info

Publication number
JP2002029944A
JP2002029944A JP2000214240A JP2000214240A JP2002029944A JP 2002029944 A JP2002029944 A JP 2002029944A JP 2000214240 A JP2000214240 A JP 2000214240A JP 2000214240 A JP2000214240 A JP 2000214240A JP 2002029944 A JP2002029944 A JP 2002029944A
Authority
JP
Japan
Prior art keywords
hair
additive
treatment agent
hair treatment
agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2000214240A
Other languages
Japanese (ja)
Inventor
Shigeki Matsumoto
重樹 松本
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
NATURAN INTERNATIONAL CO Ltd
Original Assignee
NATURAN INTERNATIONAL CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by NATURAN INTERNATIONAL CO Ltd filed Critical NATURAN INTERNATIONAL CO Ltd
Priority to JP2000214240A priority Critical patent/JP2002029944A/en
Publication of JP2002029944A publication Critical patent/JP2002029944A/en
Pending legal-status Critical Current

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Abstract

(57)【要約】 【課題】 頭皮や手・指への刺激や、人体へのアレルギ
ーが少なく、染毛、パーマネント効果が高く、更に染
毛、パーマネント後の感触も優れた添加剤、およびこの
添加剤が添加された染毛剤、パーマネントウェーブ剤を
提供する。 【解決手段】 発酵過程を経て得られた毛髪処理剤用の
添加剤であって、主成分として全成分中、質量比で糖質
を80〜99%含有し、残部に微量成分としてナトリウ
ム、カリウム、マグネシウム、燐、およびタンパク質を
含有し、前記糖質がグルコース、麦芽糖およびこれらの
誘導体により構成されている毛髪処理剤用添加剤、およ
び染毛剤、パーマネントウェーブ剤とした。
(57) [Summary] [Problem] An additive which is less irritating to the scalp, hands and fingers, less allergic to the human body, has high hair dyeing and permanent effects, and is also excellent in hair dyeing and feeling after permanent. Provided are a hair dye and a permanent waving agent to which an additive has been added. SOLUTION: This is an additive for a hair treatment agent obtained through a fermentation process, which contains 80 to 99% by weight of a saccharide as a main component in all components, and sodium and potassium as a minor component in the remainder. , Magnesium, phosphorus, and a protein, wherein the carbohydrate is composed of glucose, maltose and derivatives thereof, and is used as a hair treatment additive, a hair dye, and a permanent waving agent.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、発酵過程を経て得
られた毛髪処理剤用添加剤、この添加剤が添加された毛
髪処理剤に関するものである。
TECHNICAL FIELD The present invention relates to an additive for a hair treatment agent obtained through a fermentation process, and a hair treatment agent to which the additive is added.

【0002】[0002]

【従来の技術】酸化染毛剤は永久染毛剤の中で最も広く
使用されているもので、染毛剤中の酸化染料が毛髪中に
浸透して酸化重合し、発色することにより毛髪を化学的
に染着するので染毛効果が持続することが特徴である。
酸化染毛剤の剤型としては、酸化染料を含む第1剤と、
酸化剤を含む第2剤とを用時混合して用いる2剤型が多
いが、粉末剤で用時水と混合して用いる1剤型や、3剤
以上の多剤型もある。
2. Description of the Related Art Oxidative hair dyes are the most widely used among permanent hair dyes. Oxidative dyes in hair dyes penetrate into hair, oxidatively polymerize, and develop color to form hair. The feature is that the hair dyeing effect lasts because it is chemically dyed.
As the dosage form of the oxidation hair dye, a first agent containing an oxidation dye,
There are many two-part types that are used by mixing them with a second agent containing an oxidizing agent when used, but there are also one-part types that are used by mixing with water at the time of powdering and multi-part types that are three or more.

【0003】何れにしても、酸化染毛剤は酸化重合反応
によって化学的に毛髪を染毛する。この酸化重合はかな
り激しい反応であり、地肌や、毛髪が損傷を受け易く、
染毛中にかゆみや、痛みを感じたり、染毛後の髪が切れ
毛や枝毛になりやすくなったり、パサついたりするとい
う問題を有していた。
In any case, the oxidative hair dye chemically dyes the hair by an oxidative polymerization reaction. This oxidative polymerization is a very violent reaction, and the skin and hair are easily damaged,
There have been problems that itching and pain are felt during hair dyeing, that the hair after hair dyeing is liable to be cut or split, and that the hair is dull.

【0004】酸化染毛剤は、強いアルカリ性で使用され
るので、毛髪や皮膚に悪影響を与えるばかりでなく、ア
レルギーを生じさせたり、発癌性や貧血症の危険があ
る。酸性染毛剤は、タール系色素の染毛性が劣るので高
い染料濃度で使用されるため、頭皮や手・指に付着した
ものは落ちにくい一方、染毛後数回の洗髪で退色してし
まうという欠点があった。他に染毛色素として知られて
いる天然色素は、染毛効果や経時安定性が悪いという欠
点があった。
[0004] Since oxidative hair dyes are used in a strongly alkaline condition, they not only adversely affect hair and skin, but also cause allergies, carcinogenicity and anemia. Acid hair dyes are used at a high dye concentration because of the inferior hair dyeing properties of tar dyes.Thus, those that adhere to the scalp or hands and fingers are difficult to remove, but fade after several hair washing after hair dyeing. There was a disadvantage that it would. Other natural dyes known as hair dyes have the drawback of poor hair dyeing effect and stability over time.

【0005】また、このような染毛剤を使用する美容師
などにおいても、手肌の荒れ、湿疹、かゆみなどの症状
を生じる場合があり、何らかの対策が望まれているが、
所望の染毛効果を維持したままこのような症状を有効に
抑制する手段がないのが現状である。また、同様の問題
がパーマネントウェーブ剤においても生じている。
[0005] In addition, even hairdressers using such hair dyes may cause symptoms such as rough skin, eczema and itching, and some measures are desired.
At present, there is no means to effectively suppress such symptoms while maintaining the desired hair dyeing effect. A similar problem also occurs with permanent waving agents.

【0006】ヘアカラーは、特に若年層の間でファッシ
ョンとして流行しており、使用する需要者の数が急激に
増大している。そして、このようなヘアカラーによる害
は社会問題にまで発展しており、早急な解決策が望まれ
ている。
[0006] Hair colors are becoming fashionable, especially among young people, and the number of consumers who use them is increasing rapidly. The harm caused by such hair coloring has developed into a social problem, and an urgent solution is desired.

【0007】[0007]

【発明が解決しようとする課題】本発明の目的は、頭皮
や手・指への刺激や、人体へのアレルギーが少なく、染
毛、パーマネント効果が高く、更に染毛、パーマネント
後の感触も優れた添加剤、およびこの添加剤が添加され
た染毛剤、パーマネントウェーブ剤を提供することであ
る。
SUMMARY OF THE INVENTION An object of the present invention is to reduce irritation to the scalp, hands and fingers and allergy to the human body, to have high hair dyeing and permanent effects, and to further improve hair dyeing and feeling after permanent. And a hair dye and a permanent waving agent to which the additive is added.

【0008】[0008]

【課題を解決するための手段】上記課題は以下の構成に
より達成される。 (1) パパイヤを原料とする発酵過程を経て得られた
毛髪処理剤用の添加剤であって、主成分として全成分
中、質量比で糖質を80〜99%含有し、残部に微量成
分としてナトリウム、カリウム、マグネシウム、燐、お
よびタンパク質を含有し、前記糖質がグルコース、麦芽
糖およびこれらの誘導体により構成されている毛髪処理
剤用添加剤 (2) 上記(1)の毛髪処理剤用添加剤が添加された
毛髪処理剤。 (3) 酸化染毛剤である上記(2)の毛髪処理剤。 (4) パーマネントウェーブ剤である上記(2)の毛
髪処理剤。
The above object is achieved by the following constitution. (1) An additive for a hair treatment agent obtained through a fermentation process using papaya as a raw material, containing 80 to 99% by mass of a carbohydrate as a main component in all components and a trace component in the balance (2) an additive for a hair treatment agent according to the above (1), wherein the additive comprises sodium, potassium, magnesium, phosphorus, and a protein, and the carbohydrate is composed of glucose, maltose, and derivatives thereof. A hair treatment agent to which an agent has been added. (3) The hair treatment agent according to the above (2), which is an oxidative hair dye. (4) The hair treatment agent according to the above (2), which is a permanent wave agent.

【0009】[0009]

【発明の実施の形態】以下、本発明の実施の形態につい
て説明する。本発明の毛髪処理剤用添加剤は、パパイヤ
を原料とする発酵過程を経て得られた毛髪処理剤用の添
加剤であって、主成分として全成分中、質量比で糖質を
80〜99%、特に90〜99%含有し、残部に微量成
分としてナトリウム、カリウム、マグネシウム、燐、お
よびタンパク質を含有し、前記糖質がグルコース、麦芽
糖およびこれらの誘導体により構成されているものであ
る。
Embodiments of the present invention will be described below. The additive for a hair treatment agent of the present invention is an additive for a hair treatment agent obtained through a fermentation process using papaya as a raw material. %, Especially 90 to 99%, with the balance containing sodium, potassium, magnesium, phosphorus and protein as trace components, and the carbohydrate is composed of glucose, maltose and derivatives thereof.

【0010】このように、パパイヤを原料とする発酵過
程を経て得られ、上記の組成を有する添加剤を染毛剤や
パーマネントウエーブ剤に添加することにより、頭皮や
手・指への刺激や、人体へのアレルギーを抑制し、染
毛、パーマネント効果を高く維持し、更に染毛、パーマ
ネント後の感触も優れた染毛剤、パーマネントウエーブ
剤とすることができる。なお、パパイヤの健康食品とし
ての効果は知られているが、添加剤としての効果は知ら
れていない。
[0010] As described above, by adding an additive obtained through a fermentation process using papaya as a raw material and having the above composition to a hair dye or a permanent wave agent, irritation to the scalp, hands and fingers, A hair dye and a permanent wave agent which suppresses allergy to the human body, maintains a high hair dyeing and permanent effect, and also has excellent hair dyeing and a feeling after permanent treatment. In addition, the effect of papaya as a health food is known, but the effect as an additive is not known.

【0011】本発明の添加剤は、パパイヤ、食用酵母、
乳酸菌、プローテアーゼ、デキストロスを主原料とし、
例えば図1に示すように、以下の工程により得ることが
できる。
The additives of the present invention include papaya, edible yeast,
Lactic acid bacteria, protease, dextrose as the main raw materials,
For example, as shown in FIG. 1, it can be obtained by the following steps.

【0012】先ず、原料の果実(S1)、つまりパパイ
ヤ(Carica Papaya Linn)をマッシュする(S2)。す
なわち、つぶして練り上げる。そこにブドウ糖(グルコ
ース)を添加して(S3)、容器に入れて密封し、発酵
・分解を起こさせる(S4)。発酵・分解に要する期日
は室温等によって異なるが5〜10日位である。温度は
15〜45℃が良く最適は35℃前後である。発酵・分
解が終了すると、濾過工程1で濾過し(S5)、それを
沈殿物(S6)と上澄み液(S12)とに分ける。な
お、原料のパパイヤは、同様な作用効果を奏する果実で
あれば、他のもので代用することも可能である。
First, the raw material fruit (S1), that is, papaya (Carica Papaya Linn) is mashed (S2). That is, it is crushed and kneaded. Glucose (glucose) is added thereto (S3), put in a container, sealed, and fermented / decomposed (S4). The date required for fermentation / decomposition varies depending on room temperature and the like, but is about 5 to 10 days. The temperature is preferably from 15 to 45 ° C, and most preferably about 35 ° C. When the fermentation / decomposition is completed, the solution is filtered in a filtration step 1 (S5), and is separated into a precipitate (S6) and a supernatant (S12). The raw material papaya can be replaced with another fruit as long as it has the same effect.

【0013】次いで、沈殿物(S6)にはブドウ糖、イ
ースト菌、乳酸菌を添加して(S7)10〜15日間発
酵させる(S8)。乳酸菌としては、例えばラクトバチ
ルス・アシドフィルス等が挙げられ、これらを上記沈殿
物に0.01〜0.07%質量程度加え、25〜40
℃、好ましくは37〜38℃で、好ましくは攪拌しなが
ら発酵を行う。
Next, glucose, yeast and lactic acid bacteria are added to the precipitate (S6) (S7) and fermented for 10 to 15 days (S8). Lactic acid bacteria include, for example, Lactobacillus acidophilus and the like, and these are added to the precipitate in an amount of about 0.01 to 0.07% by mass and 25 to 40%.
The fermentation is carried out at a temperature of C, preferably 37-38C, preferably with stirring.

【0014】次いで、発酵させた物質を濾過工程2で濾
過し、残査を取り除いたものを、さらに濾過工程3で濾
過する(S9)。一方、濾過工程1で濾過された物質の
上澄み液(S12)を再度濾過工程4で濾過して(S1
3)、ブドウ糖、イースト菌、乳酸菌を添加して発酵さ
せる(S14)。その際の添加量、発酵条件は上記と同
様でよい。
Next, the fermented substance is filtered in the filtration step 2 and the residue is removed, and the residue is filtered in the filtration step 3 (S9). On the other hand, the supernatant (S12) of the substance filtered in the filtration step 1 is again filtered in the filtration step 4 (S1).
3), glucose, yeast and lactic acid bacteria are added and fermented (S14). The amount of addition and fermentation conditions at that time may be the same as described above.

【0015】次に、この発酵させた物質を、濾過工程程
3で得られた物質に混ぜて味噌酵素を加えて(S16)
24時間培養(発酵)する(S17)。培養した後、ブ
ドウ糖を添加し(S18)、数週間熱成(発酵)して
(S19)、半乾燥品にする(S20)。その際の添加
量、発酵条件は上記と同様でよい。
Next, the fermented substance is mixed with the substance obtained in the filtration step 3, and miso enzyme is added (S16).
Culture (fermentation) for 24 hours (S17). After culturing, glucose is added (S18), and thermogenized (fermented) for several weeks (S19) to obtain a semi-dried product (S20). The amount of addition and fermentation conditions at that time may be the same as described above.

【0016】これをさらに乾燥させたものが、本発明の
添加剤で、やや黄みがかった乳白色の顆粒状である。
The further dried product is the additive of the present invention and is a slightly yellowish milky white granule.

【0017】上記添加剤の成分は、全成分を100とし
たときの質量比で、糖質を80〜99%、特に90〜9
9%含有し、微量成分としてナトリウム、カリウム、マ
グネシウム、燐、およびタンパク質を残部に含有し、前
記糖質がグルコースを主成分とし、これに僅かに麦芽
糖、およびこれらの誘導体が含有されている。
The components of the above-mentioned additives are 80 to 99%, especially 90 to 9%, of saccharides by mass ratio when all components are 100.
9%, sodium, potassium, magnesium, phosphorus, and protein as trace components in the balance, glucose as a main component, slightly maltose, and derivatives thereof.

【0018】このようにして得られた添加剤は、好まし
くは0.05〜70質量%、より好ましくは0.1〜5
0質量%、特に0.5〜30質量%、染毛剤、パーマネ
ントウエーブ剤に添加することにより、上述のような優
れた効果を得ることができる。
The additive thus obtained is preferably 0.05 to 70% by mass, more preferably 0.1 to 5% by mass.
By adding 0% by mass, particularly 0.5 to 30% by mass to a hair dye and a permanent wave agent, the above-described excellent effects can be obtained.

【0019】また、添加剤は、溶解性に優れ、染毛剤、
パーマネントウエーブ剤に速やかに、完全に溶解し、こ
れによる染毛剤、パーマネントウエーブ剤自体の色や匂
いの変化は生じない。この添加剤を水に溶解させた場合
のpHは、6〜7の中性を示す。
The additives are excellent in solubility, hair dyes,
It is rapidly and completely dissolved in the permanent waving agent, so that the color and odor of the hair dye and the permanent waving agent do not change. The pH when this additive is dissolved in water indicates neutrality of 6 to 7.

【0020】添加される染毛剤としては、パラフェニレ
ンジアミン、パラアミノフェノールなどの酸化染料を成
分とする酸化染毛剤が好ましく、特にアミン系の染毛剤
が好ましい。このような染毛剤に本発明の添加剤を添加
することにより、酸化染毛剤特有の刺激を緩和し、人体
に優しい染毛剤とすることができる。
The hair dye to be added is preferably an oxidative hair dye containing an oxidative dye such as paraphenylenediamine or para-aminophenol, and more preferably an amine-based hair dye. By adding the additive of the present invention to such a hair dye, the stimulus peculiar to the oxidative hair dye can be reduced, and a hair dye that is gentle to the human body can be obtained.

【0021】添加されるパーマネントウエーブ剤として
は、一般的にパーマネントウェーブ剤として用いられて
いるものであれば特に限定されるものではないが、2剤
型のものが好ましい。2剤型のパーマネントウエーブ剤
は、第1剤を毛髪に処理させた後、第2剤を別に処理す
る方法が多く採られている。第1剤はチオグリコール酸
塩、チオ乳酸塩、システインなどを代表とする還元剤を
含有し、その還元力により毛髪中のジスルフィド結合を
切断する。また第2剤は過酸化水素、臭素酸塩などを代
表とする酸化剤を含有し、その酸化力により、還元剤に
よって切断されたジスルフィド結合を再結合させ、目的
とするウェーブを形成させている。
The permanent wave agent to be added is not particularly limited as long as it is generally used as a permanent wave agent, but a two-part type is preferred. As the two-part permanent wave agent, a method of treating the hair with the first agent and then treating the second agent separately is often used. The first agent contains a reducing agent typified by thioglycolate, thiolactate, cysteine, etc., and cleaves disulfide bonds in the hair by its reducing power. The second agent contains an oxidizing agent typified by hydrogen peroxide, bromate and the like, and the oxidizing power of the second agent recombines the disulfide bonds cut by the reducing agent to form a desired wave. .

【0022】このため、ジスルフィド結合の切断は、そ
の後の酸化剤による再結合だけでは修復不可能な損傷を
毛髪に与え、また、施術後の毛髪はつやがなく、パサつ
いた感触を示し、しかもクシ通りが悪いが、本発明の添
加剤を添加することにより、これらの症状を抑制するこ
とができる。
For this reason, the cleavage of the disulfide bond causes damage to the hair that cannot be repaired only by the subsequent recombination with an oxidizing agent, and the hair after the treatment has a dull and silky feel. Although the combability is poor, these symptoms can be suppressed by adding the additive of the present invention.

【0023】本発明の添加剤を用いることにより、特に
以下のような優れた効果を得ることができる。 (1)ヘアカラー(染毛剤)の発色を妨げることなく、
毛髪をダメージから保護することができる。 (2)染色時のピリピリといった皮膚への刺激を抑制す
ることができる。 (3)染色後の毛髪の粗れやぱさつきを抑制する。 (4)髪にコシ・艶・サラサラ感がでる。 (5)クシ通りがよくセットしやすくなる。 (6)一度に何度か重ねて染色することができる。 (7)パーマネント処理と染色処理が連続して行える。 (8)ヘナ染料を用いたのと同様なトリートメント効果
が得られる。
By using the additive of the present invention, the following excellent effects can be obtained. (1) Without disturbing the color development of hair color (hair dye)
Hair can be protected from damage. (2) It is possible to suppress irritation to the skin such as tingling during dyeing. (3) Suppresses hair roughness and roughness after dyeing. (4) The hair has a firm, glossy, and smooth feeling. (5) It becomes easy to set the comb as well. (6) It can be repeatedly dyed several times at a time. (7) Permanent processing and dyeing processing can be performed continuously. (8) The same treatment effect as when using a henna dye is obtained.

【0024】[0024]

【発明の効果】以上のように本発明によれば、頭皮や手
・指への刺激や、人体へのアレルギーが少なく、染毛、
パーマネント効果が高く、更に染毛、パーマネント後の
感触も優れた添加剤、およびこの添加剤が添加された染
毛剤、パーマネントウェーブ剤を提供することができ
る。
As described above, according to the present invention, irritation to the scalp, hands and fingers and allergy to the human body are reduced,
It is possible to provide an additive which has a high permanent effect and further has excellent hair dyeing and feeling after permanent, and a hair dye and a permanent waving agent to which the additive is added.

【図面の簡単な説明】[Brief description of the drawings]

【図1】本発明の添加剤の製造工程を示したフローチャ
ートである。
FIG. 1 is a flowchart showing a process for producing an additive of the present invention.

Claims (4)

【特許請求の範囲】[Claims] 【請求項1】 パパイヤを原料とする発酵過程を経て得
られた毛髪処理剤用の添加剤であって、 主成分として全成分中、質量比で糖質を80〜99%含
有し、残部に微量成分としてナトリウム、カリウム、マ
グネシウム、燐、およびタンパク質を含有し、 前記糖質がグルコース、麦芽糖およびこれらの誘導体に
より構成されている毛髪処理剤用添加剤。
1. An additive for a hair treatment agent obtained through a fermentation process using papaya as a raw material, comprising 80 to 99% by mass of a carbohydrate as a main component in all components and a balance in the remainder. An additive for a hair treatment agent, comprising sodium, potassium, magnesium, phosphorus and protein as trace components, wherein the carbohydrate is composed of glucose, maltose and derivatives thereof.
【請求項2】 請求項1の毛髪処理剤用添加剤が添加さ
れた毛髪処理剤。
2. A hair treatment agent to which the additive for a hair treatment agent according to claim 1 is added.
【請求項3】 酸化染毛剤である請求項2の毛髪処理
剤。
3. The hair treatment agent according to claim 2, which is an oxidative hair dye.
【請求項4】 パーマネントウェーブ剤である請求項2
の毛髪処理剤。
4. A permanent wave agent.
Hair treatment agent.
JP2000214240A 2000-07-14 2000-07-14 Additive for hair treatment agent, hair treatment agent to which this additive is added Pending JP2002029944A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2000214240A JP2002029944A (en) 2000-07-14 2000-07-14 Additive for hair treatment agent, hair treatment agent to which this additive is added

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2000214240A JP2002029944A (en) 2000-07-14 2000-07-14 Additive for hair treatment agent, hair treatment agent to which this additive is added

Publications (1)

Publication Number Publication Date
JP2002029944A true JP2002029944A (en) 2002-01-29

Family

ID=18709853

Family Applications (1)

Application Number Title Priority Date Filing Date
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Country Status (1)

Country Link
JP (1) JP2002029944A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6660773B2 (en) * 2000-03-20 2003-12-09 Teva Pharmaceutical Industries, Ltd. Processes for preparing 6-hydroxy-3,4-dihydroquinolinone, cilostazol and N-(4-methoxyphenyl)3-chloropropionamide
JP2013511512A (en) * 2009-11-19 2013-04-04 アモーレパシフィック コーポレイション Composition for alleviating skin irritation with dyes

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6660773B2 (en) * 2000-03-20 2003-12-09 Teva Pharmaceutical Industries, Ltd. Processes for preparing 6-hydroxy-3,4-dihydroquinolinone, cilostazol and N-(4-methoxyphenyl)3-chloropropionamide
US6967209B2 (en) * 2000-03-20 2005-11-22 Teva Pharmaceutical Industries Ltd. Processes for preparing 6-hydroxy-3,4-dihydroquinolinone, cilostazol and N-(4-methoxyphenyl)-3-chloropropionamide
JP2013511512A (en) * 2009-11-19 2013-04-04 アモーレパシフィック コーポレイション Composition for alleviating skin irritation with dyes

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