JP2004002445A - Hair dye composition - Google Patents
Hair dye composition Download PDFInfo
- Publication number
- JP2004002445A JP2004002445A JP2003187962A JP2003187962A JP2004002445A JP 2004002445 A JP2004002445 A JP 2004002445A JP 2003187962 A JP2003187962 A JP 2003187962A JP 2003187962 A JP2003187962 A JP 2003187962A JP 2004002445 A JP2004002445 A JP 2004002445A
- Authority
- JP
- Japan
- Prior art keywords
- poe
- hair
- weight
- dyeing
- hair dye
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000118 hair dye Substances 0.000 title claims abstract description 25
- 239000000203 mixture Substances 0.000 title claims abstract description 17
- 150000003839 salts Chemical class 0.000 claims abstract description 16
- MGLZGLAFFOMWPB-UHFFFAOYSA-N 2-chloro-1,4-phenylenediamine Chemical compound NC1=CC=C(N)C(Cl)=C1 MGLZGLAFFOMWPB-UHFFFAOYSA-N 0.000 claims abstract description 7
- ISCYHXYLVTWDJT-UHFFFAOYSA-N 2-[4-amino-n-(2-hydroxyethyl)anilino]ethanol Chemical compound NC1=CC=C(N(CCO)CCO)C=C1 ISCYHXYLVTWDJT-UHFFFAOYSA-N 0.000 claims abstract description 5
- PLIKAWJENQZMHA-UHFFFAOYSA-N 4-aminophenol Chemical compound NC1=CC=C(O)C=C1 PLIKAWJENQZMHA-UHFFFAOYSA-N 0.000 claims description 8
- CWLKGDAVCFYWJK-UHFFFAOYSA-N 3-aminophenol Chemical compound NC1=CC=CC(O)=C1 CWLKGDAVCFYWJK-UHFFFAOYSA-N 0.000 claims description 6
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 claims description 6
- HDGMAACKJSBLMW-UHFFFAOYSA-N 4-amino-2-methylphenol Chemical compound CC1=CC(N)=CC=C1O HDGMAACKJSBLMW-UHFFFAOYSA-N 0.000 claims description 5
- RAUWPNXIALNKQM-UHFFFAOYSA-N 4-nitro-1,2-phenylenediamine Chemical compound NC1=CC=C([N+]([O-])=O)C=C1N RAUWPNXIALNKQM-UHFFFAOYSA-N 0.000 claims description 4
- YGRFRBUGAPOJDU-UHFFFAOYSA-N 5-(2-hydroxyethylamino)-2-methylphenol Chemical compound CC1=CC=C(NCCO)C=C1O YGRFRBUGAPOJDU-UHFFFAOYSA-N 0.000 claims description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 4
- HVHNMNGARPCGGD-UHFFFAOYSA-N 2-nitro-p-phenylenediamine Chemical compound NC1=CC=C(N)C([N+]([O-])=O)=C1 HVHNMNGARPCGGD-UHFFFAOYSA-N 0.000 claims description 3
- 229940018563 3-aminophenol Drugs 0.000 claims description 3
- 239000004215 Carbon black (E152) Substances 0.000 claims description 3
- 229930195733 hydrocarbon Natural products 0.000 claims description 3
- 150000002430 hydrocarbons Chemical class 0.000 claims description 3
- QXYMVUZOGFVPGH-UHFFFAOYSA-N picramic acid Chemical compound NC1=CC([N+]([O-])=O)=CC([N+]([O-])=O)=C1O QXYMVUZOGFVPGH-UHFFFAOYSA-N 0.000 claims description 3
- FBMQNRKSAWNXBT-UHFFFAOYSA-N 1,4-diaminoanthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C(N)=CC=C2N FBMQNRKSAWNXBT-UHFFFAOYSA-N 0.000 claims description 2
- PHTDHFYUHFJDJW-UHFFFAOYSA-N 1-amino-4-methylanthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C(N)=CC=C2C PHTDHFYUHFJDJW-UHFFFAOYSA-N 0.000 claims description 2
- ZFIQGRISGKSVAG-UHFFFAOYSA-N 4-methylaminophenol Chemical compound CNC1=CC=C(O)C=C1 ZFIQGRISGKSVAG-UHFFFAOYSA-N 0.000 claims description 2
- 230000001590 oxidative effect Effects 0.000 abstract description 6
- 238000004040 coloring Methods 0.000 abstract 1
- 230000007547 defect Effects 0.000 abstract 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 42
- 238000004043 dyeing Methods 0.000 description 39
- -1 2-nitro-p-phenylene Chemical group 0.000 description 26
- 235000014113 dietary fatty acids Nutrition 0.000 description 16
- 239000000194 fatty acid Substances 0.000 description 16
- 229930195729 fatty acid Natural products 0.000 description 16
- 230000000694 effects Effects 0.000 description 11
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 9
- 229960003237 betaine Drugs 0.000 description 9
- 239000003240 coconut oil Substances 0.000 description 9
- 235000019864 coconut oil Nutrition 0.000 description 9
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 9
- 238000013329 compounding Methods 0.000 description 8
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 description 7
- 150000004665 fatty acids Chemical class 0.000 description 7
- 239000002202 Polyethylene glycol Substances 0.000 description 6
- 229920001214 Polysorbate 60 Polymers 0.000 description 6
- 239000000975 dye Substances 0.000 description 6
- 229920001223 polyethylene glycol Polymers 0.000 description 6
- 239000008213 purified water Substances 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 5
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 5
- 125000000217 alkyl group Chemical group 0.000 description 5
- 239000004359 castor oil Substances 0.000 description 5
- 235000019438 castor oil Nutrition 0.000 description 5
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 5
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 239000007800 oxidant agent Substances 0.000 description 5
- 239000011734 sodium Substances 0.000 description 5
- 229910052708 sodium Inorganic materials 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 4
- 239000004166 Lanolin Substances 0.000 description 4
- NOPFSRXAKWQILS-UHFFFAOYSA-N docosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 description 4
- 235000019388 lanolin Nutrition 0.000 description 4
- 229940039717 lanolin Drugs 0.000 description 4
- CPJSUEIXXCENMM-UHFFFAOYSA-N phenacetin Chemical compound CCOC1=CC=C(NC(C)=O)C=C1 CPJSUEIXXCENMM-UHFFFAOYSA-N 0.000 description 4
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 4
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 4
- HLZKNKRTKFSKGZ-UHFFFAOYSA-N tetradecan-1-ol Chemical compound CCCCCCCCCCCCCCO HLZKNKRTKFSKGZ-UHFFFAOYSA-N 0.000 description 4
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 3
- FFJCNSLCJOQHKM-CLFAGFIQSA-N (z)-1-[(z)-octadec-9-enoxy]octadec-9-ene Chemical compound CCCCCCCC\C=C/CCCCCCCCOCCCCCCCC\C=C/CCCCCCCC FFJCNSLCJOQHKM-CLFAGFIQSA-N 0.000 description 3
- LEEDMQGKBNGPDN-UHFFFAOYSA-N 2-methylnonadecane Chemical compound CCCCCCCCCCCCCCCCCC(C)C LEEDMQGKBNGPDN-UHFFFAOYSA-N 0.000 description 3
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 3
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 3
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 3
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 3
- 239000005642 Oleic acid Substances 0.000 description 3
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 3
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 3
- 235000011114 ammonium hydroxide Nutrition 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 229940082500 cetostearyl alcohol Drugs 0.000 description 3
- 229960000541 cetyl alcohol Drugs 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 3
- 229940057995 liquid paraffin Drugs 0.000 description 3
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 3
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- OULAJFUGPPVRBK-UHFFFAOYSA-N tetratriacontyl alcohol Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCO OULAJFUGPPVRBK-UHFFFAOYSA-N 0.000 description 3
- DSEKYWAQQVUQTP-XEWMWGOFSA-N (2r,4r,4as,6as,6as,6br,8ar,12ar,14as,14bs)-2-hydroxy-4,4a,6a,6b,8a,11,11,14a-octamethyl-2,4,5,6,6a,7,8,9,10,12,12a,13,14,14b-tetradecahydro-1h-picen-3-one Chemical compound C([C@H]1[C@]2(C)CC[C@@]34C)C(C)(C)CC[C@]1(C)CC[C@]2(C)[C@H]4CC[C@@]1(C)[C@H]3C[C@@H](O)C(=O)[C@@H]1C DSEKYWAQQVUQTP-XEWMWGOFSA-N 0.000 description 2
- KMCFMEHSEWDYKG-UHFFFAOYSA-N (4-azaniumylphenyl)-bis(2-hydroxyethyl)azanium;sulfate Chemical compound OS(O)(=O)=O.NC1=CC=C(N(CCO)CCO)C=C1 KMCFMEHSEWDYKG-UHFFFAOYSA-N 0.000 description 2
- ZORQXIQZAOLNGE-UHFFFAOYSA-N 1,1-difluorocyclohexane Chemical compound FC1(F)CCCCC1 ZORQXIQZAOLNGE-UHFFFAOYSA-N 0.000 description 2
- WNWHHMBRJJOGFJ-UHFFFAOYSA-N 16-methylheptadecan-1-ol Chemical compound CC(C)CCCCCCCCCCCCCCCO WNWHHMBRJJOGFJ-UHFFFAOYSA-N 0.000 description 2
- XZIIFPSPUDAGJM-UHFFFAOYSA-N 6-chloro-2-n,2-n-diethylpyrimidine-2,4-diamine Chemical compound CCN(CC)C1=NC(N)=CC(Cl)=N1 XZIIFPSPUDAGJM-UHFFFAOYSA-N 0.000 description 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 2
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical compound [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 2
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- IYFATESGLOUGBX-YVNJGZBMSA-N Sorbitan monopalmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O IYFATESGLOUGBX-YVNJGZBMSA-N 0.000 description 2
- HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 description 2
- 239000004147 Sorbitan trioleate Substances 0.000 description 2
- PRXRUNOAOLTIEF-ADSICKODSA-N Sorbitan trioleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](OC(=O)CCCCCCC\C=C/CCCCCCCC)[C@H]1OC[C@H](O)[C@H]1OC(=O)CCCCCCC\C=C/CCCCCCCC PRXRUNOAOLTIEF-ADSICKODSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 150000005215 alkyl ethers Chemical class 0.000 description 2
- 239000003945 anionic surfactant Substances 0.000 description 2
- YCIMNLLNPGFGHC-UHFFFAOYSA-N catechol Chemical compound OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 description 2
- DTPCFIHYWYONMD-UHFFFAOYSA-N decaethylene glycol Polymers OCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO DTPCFIHYWYONMD-UHFFFAOYSA-N 0.000 description 2
- XGZRAKBCYZIBKP-UHFFFAOYSA-L disodium;dihydroxide Chemical compound [OH-].[OH-].[Na+].[Na+] XGZRAKBCYZIBKP-UHFFFAOYSA-L 0.000 description 2
- 229960000735 docosanol Drugs 0.000 description 2
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- 229940075507 glyceryl monostearate Drugs 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 2
- 239000000543 intermediate Substances 0.000 description 2
- 239000001788 mono and diglycerides of fatty acids Substances 0.000 description 2
- 229940043348 myristyl alcohol Drugs 0.000 description 2
- 229940115453 n,n-bis(2-hydroxyethyl)-p-phenylenediamine sulfate Drugs 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- ZPIRTVJRHUMMOI-UHFFFAOYSA-N octoxybenzene Chemical compound CCCCCCCCOC1=CC=CC=C1 ZPIRTVJRHUMMOI-UHFFFAOYSA-N 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 235000019198 oils Nutrition 0.000 description 2
- 229960003893 phenacetin Drugs 0.000 description 2
- 235000021317 phosphate Nutrition 0.000 description 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 2
- XOJVVFBFDXDTEG-UHFFFAOYSA-N pristane Chemical compound CC(C)CCCC(C)CCCC(C)CCCC(C)C XOJVVFBFDXDTEG-UHFFFAOYSA-N 0.000 description 2
- WQGWDDDVZFFDIG-UHFFFAOYSA-N pyrogallol Chemical compound OC1=CC=CC(O)=C1O WQGWDDDVZFFDIG-UHFFFAOYSA-N 0.000 description 2
- FSYKKLYZXJSNPZ-UHFFFAOYSA-N sarcosine Chemical compound C[NH2+]CC([O-])=O FSYKKLYZXJSNPZ-UHFFFAOYSA-N 0.000 description 2
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- 235000010265 sodium sulphite Nutrition 0.000 description 2
- 229940035044 sorbitan monolaurate Drugs 0.000 description 2
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- 235000011076 sorbitan monostearate Nutrition 0.000 description 2
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- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 229940012831 stearyl alcohol Drugs 0.000 description 2
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- CUNWUEBNSZSNRX-RKGWDQTMSA-N (2r,3r,4r,5s)-hexane-1,2,3,4,5,6-hexol;(z)-octadec-9-enoic acid Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO.OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO.CCCCCCCC\C=C/CCCCCCCC(O)=O.CCCCCCCC\C=C/CCCCCCCC(O)=O.CCCCCCCC\C=C/CCCCCCCC(O)=O CUNWUEBNSZSNRX-RKGWDQTMSA-N 0.000 description 1
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 1
- WZCQRUWWHSTZEM-UHFFFAOYSA-N 1,3-phenylenediamine Chemical compound NC1=CC=CC(N)=C1 WZCQRUWWHSTZEM-UHFFFAOYSA-N 0.000 description 1
- JPPRXACMNPYJNK-UHFFFAOYSA-N 1-docosoxydocosane Chemical compound CCCCCCCCCCCCCCCCCCCCCCOCCCCCCCCCCCCCCCCCCCCCC JPPRXACMNPYJNK-UHFFFAOYSA-N 0.000 description 1
- CMCBDXRRFKYBDG-UHFFFAOYSA-N 1-dodecoxydodecane Chemical compound CCCCCCCCCCCCOCCCCCCCCCCCC CMCBDXRRFKYBDG-UHFFFAOYSA-N 0.000 description 1
- UUWJHAWPCRFDHZ-UHFFFAOYSA-N 1-dodecoxydodecane;phosphoric acid Chemical compound OP(O)(O)=O.CCCCCCCCCCCCOCCCCCCCCCCCC UUWJHAWPCRFDHZ-UHFFFAOYSA-N 0.000 description 1
- FDCJDKXCCYFOCV-UHFFFAOYSA-N 1-hexadecoxyhexadecane Chemical compound CCCCCCCCCCCCCCCCOCCCCCCCCCCCCCCCC FDCJDKXCCYFOCV-UHFFFAOYSA-N 0.000 description 1
- UQOXSYQRUXKNQH-UHFFFAOYSA-N 1-hexadecoxyhexadecane;phosphoric acid Chemical compound OP(O)(O)=O.CCCCCCCCCCCCCCCCOCCCCCCCCCCCCCCCC UQOXSYQRUXKNQH-UHFFFAOYSA-N 0.000 description 1
- HBXWUCXDUUJDRB-UHFFFAOYSA-N 1-octadecoxyoctadecane Chemical compound CCCCCCCCCCCCCCCCCCOCCCCCCCCCCCCCCCCCC HBXWUCXDUUJDRB-UHFFFAOYSA-N 0.000 description 1
- IFBDFMPSOCGRKA-UHFFFAOYSA-N 1-octadecoxyoctadecane;phosphoric acid Chemical compound OP(O)(O)=O.CCCCCCCCCCCCCCCCCCOCCCCCCCCCCCCCCCCCC IFBDFMPSOCGRKA-UHFFFAOYSA-N 0.000 description 1
- 239000000263 2,3-dihydroxypropyl (Z)-octadec-9-enoate Substances 0.000 description 1
- ZDSCFBCGDDCJFZ-UHFFFAOYSA-N 2-(methylamino)ethanesulfonic acid;sodium Chemical compound [Na].CNCCS(O)(=O)=O ZDSCFBCGDDCJFZ-UHFFFAOYSA-N 0.000 description 1
- FECNOIODIVNEKI-UHFFFAOYSA-N 2-[(2-aminobenzoyl)amino]benzoic acid Chemical class NC1=CC=CC=C1C(=O)NC1=CC=CC=C1C(O)=O FECNOIODIVNEKI-UHFFFAOYSA-N 0.000 description 1
- FWIJLRSOBQIWFM-UHFFFAOYSA-N 2-[1-(2-hydroxyethyl)-2-undecyl-4,5-dihydroimidazol-1-ium-1-yl]acetate Chemical compound CCCCCCCCCCCC1=NCC[N+]1(CCO)CC([O-])=O FWIJLRSOBQIWFM-UHFFFAOYSA-N 0.000 description 1
- GWEBEJYKXBMRJL-UHFFFAOYSA-N 2-[bis(2-hydroxyethyl)amino]ethanol;1-dodecoxydodecane;sulfuric acid Chemical compound OS(O)(=O)=O.OCCN(CCO)CCO.CCCCCCCCCCCCOCCCCCCCCCCCC GWEBEJYKXBMRJL-UHFFFAOYSA-N 0.000 description 1
- DUMAFWZFOOOEPH-UHFFFAOYSA-N 2-[bis(2-hydroxyethyl)amino]ethanol;dodecyl benzenesulfonate Chemical compound OCCN(CCO)CCO.CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 DUMAFWZFOOOEPH-UHFFFAOYSA-N 0.000 description 1
- HVYJSOSGTDINLW-UHFFFAOYSA-N 2-[dimethyl(octadecyl)azaniumyl]acetate Chemical compound CCCCCCCCCCCCCCCCCC[N+](C)(C)CC([O-])=O HVYJSOSGTDINLW-UHFFFAOYSA-N 0.000 description 1
- CDAWCLOXVUBKRW-UHFFFAOYSA-N 2-aminophenol Chemical class NC1=CC=CC=C1O CDAWCLOXVUBKRW-UHFFFAOYSA-N 0.000 description 1
- XULHFMYCBKQGEE-UHFFFAOYSA-N 2-hexyl-1-Decanol Chemical compound CCCCCCCCC(CO)CCCCCC XULHFMYCBKQGEE-UHFFFAOYSA-N 0.000 description 1
- MUHFRORXWCGZGE-KTKRTIGZSA-N 2-hydroxyethyl (z)-octadec-9-enoate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCCO MUHFRORXWCGZGE-KTKRTIGZSA-N 0.000 description 1
- RFVNOJDQRGSOEL-UHFFFAOYSA-N 2-hydroxyethyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCO RFVNOJDQRGSOEL-UHFFFAOYSA-N 0.000 description 1
- NFCPRRWCTNLGSN-UHFFFAOYSA-N 2-n-phenylbenzene-1,2-diamine Chemical class NC1=CC=CC=C1NC1=CC=CC=C1 NFCPRRWCTNLGSN-UHFFFAOYSA-N 0.000 description 1
- LEACJMVNYZDSKR-UHFFFAOYSA-N 2-octyldodecan-1-ol Chemical compound CCCCCCCCCCC(CO)CCCCCCCC LEACJMVNYZDSKR-UHFFFAOYSA-N 0.000 description 1
- TVIMZSOUQXNWHO-UHFFFAOYSA-N 2-tetradecanoylglycerol Chemical compound CCCCCCCCCCCCCC(=O)OC(CO)CO TVIMZSOUQXNWHO-UHFFFAOYSA-N 0.000 description 1
- CVZYWFZBNHBFDS-UHFFFAOYSA-N 3-(dodecylamino)propanoate;tris(2-hydroxyethyl)azanium Chemical compound OCCN(CCO)CCO.CCCCCCCCCCCCNCCC(O)=O CVZYWFZBNHBFDS-UHFFFAOYSA-N 0.000 description 1
- BLCZXLGRKKRKJJ-UHFFFAOYSA-N 3-amino-2-nitrophenol Chemical class NC1=CC=CC(O)=C1[N+]([O-])=O BLCZXLGRKKRKJJ-UHFFFAOYSA-N 0.000 description 1
- RZRNAYUHWVFMIP-GDCKJWNLSA-N 3-oleoyl-sn-glycerol Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@H](O)CO RZRNAYUHWVFMIP-GDCKJWNLSA-N 0.000 description 1
- ATVJXMYDOSMEPO-UHFFFAOYSA-N 3-prop-2-enoxyprop-1-ene Chemical compound C=CCOCC=C ATVJXMYDOSMEPO-UHFFFAOYSA-N 0.000 description 1
- LIFHMKCDDVTICL-UHFFFAOYSA-N 6-(chloromethyl)phenanthridine Chemical compound C1=CC=C2C(CCl)=NC3=CC=CC=C3C2=C1 LIFHMKCDDVTICL-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- ZSQAETBIVMCCPM-UHFFFAOYSA-N C(CCCCCCCCCCC)C(C[Na])(N)N Chemical compound C(CCCCCCCCCCC)C(C[Na])(N)N ZSQAETBIVMCCPM-UHFFFAOYSA-N 0.000 description 1
- LODOPTLNGAVOKL-UHFFFAOYSA-M CCCCCCCCCCCCC(C1)N=C(CC)[N+]1(CC([O-])=O)OCC([O-])=O.[Na+].[Na+] Chemical compound CCCCCCCCCCCCC(C1)N=C(CC)[N+]1(CC([O-])=O)OCC([O-])=O.[Na+].[Na+] LODOPTLNGAVOKL-UHFFFAOYSA-M 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
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- 239000004471 Glycine Substances 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- AOMUHOFOVNGZAN-UHFFFAOYSA-N N,N-bis(2-hydroxyethyl)dodecanamide Chemical compound CCCCCCCCCCCC(=O)N(CCO)CCO AOMUHOFOVNGZAN-UHFFFAOYSA-N 0.000 description 1
- QZXSMBBFBXPQHI-UHFFFAOYSA-N N-(dodecanoyl)ethanolamine Chemical compound CCCCCCCCCCCC(=O)NCCO QZXSMBBFBXPQHI-UHFFFAOYSA-N 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-N Propionic acid Chemical class CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 1
- BIDSFSTZTNAIIH-UHFFFAOYSA-M S(=O)(=O)(O)C(C(=O)[O-])CC(=O)O.[Na+].S(=O)(=O)(O)C(C(=O)O)CC(=O)O Chemical compound S(=O)(=O)(O)C(C(=O)[O-])CC(=O)O.[Na+].S(=O)(=O)(O)C(C(=O)O)CC(=O)O BIDSFSTZTNAIIH-UHFFFAOYSA-M 0.000 description 1
- 108010077895 Sarcosine Proteins 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- VBIIFPGSPJYLRR-UHFFFAOYSA-M Stearyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C VBIIFPGSPJYLRR-UHFFFAOYSA-M 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical class OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 150000001242 acetic acid derivatives Chemical class 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 125000005037 alkyl phenyl group Chemical group 0.000 description 1
- 125000005526 alkyl sulfate group Chemical group 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 125000005211 alkyl trimethyl ammonium group Chemical group 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 229940024606 amino acid Drugs 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- BTBJBAZGXNKLQC-UHFFFAOYSA-N ammonium lauryl sulfate Chemical compound [NH4+].CCCCCCCCCCCCOS([O-])(=O)=O BTBJBAZGXNKLQC-UHFFFAOYSA-N 0.000 description 1
- 229940063953 ammonium lauryl sulfate Drugs 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 235000010323 ascorbic acid Nutrition 0.000 description 1
- 239000011668 ascorbic acid Substances 0.000 description 1
- 229960005070 ascorbic acid Drugs 0.000 description 1
- 235000013871 bee wax Nutrition 0.000 description 1
- 239000012166 beeswax Substances 0.000 description 1
- OCBHHZMJRVXXQK-UHFFFAOYSA-M benzyl-dimethyl-tetradecylazanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 OCBHHZMJRVXXQK-UHFFFAOYSA-M 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- WOWHHFRSBJGXCM-UHFFFAOYSA-M cetyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)C WOWHHFRSBJGXCM-UHFFFAOYSA-M 0.000 description 1
- FOCAUTSVDIKZOP-UHFFFAOYSA-N chloroacetic acid Chemical compound OC(=O)CCl FOCAUTSVDIKZOP-UHFFFAOYSA-N 0.000 description 1
- 229940106681 chloroacetic acid Drugs 0.000 description 1
- 150000001860 citric acid derivatives Chemical class 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- AOLMPVPUFVWGPN-UHFFFAOYSA-N diazanium;1-dodecoxydodecane;sulfate Chemical compound [NH4+].[NH4+].[O-]S([O-])(=O)=O.CCCCCCCCCCCCOCCCCCCCCCCCC AOLMPVPUFVWGPN-UHFFFAOYSA-N 0.000 description 1
- ZCPCLAPUXMZUCD-UHFFFAOYSA-M dihexadecyl(dimethyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCC ZCPCLAPUXMZUCD-UHFFFAOYSA-M 0.000 description 1
- IQDGSYLLQPDQDV-UHFFFAOYSA-N dimethylazanium;chloride Chemical compound Cl.CNC IQDGSYLLQPDQDV-UHFFFAOYSA-N 0.000 description 1
- REZZEXDLIUJMMS-UHFFFAOYSA-M dimethyldioctadecylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC REZZEXDLIUJMMS-UHFFFAOYSA-M 0.000 description 1
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical class C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 description 1
- PXEDJBXQKAGXNJ-QTNFYWBSSA-L disodium L-glutamate Chemical compound [Na+].[Na+].[O-]C(=O)[C@@H](N)CCC([O-])=O PXEDJBXQKAGXNJ-QTNFYWBSSA-L 0.000 description 1
- 229940079886 disodium lauryl sulfosuccinate Drugs 0.000 description 1
- WODOUQLMOIMKAL-FJSYBICCSA-L disodium;(2s)-2-(octadecanoylamino)pentanedioate Chemical compound [Na+].[Na+].CCCCCCCCCCCCCCCCCC(=O)N[C@H](C([O-])=O)CCC([O-])=O WODOUQLMOIMKAL-FJSYBICCSA-L 0.000 description 1
- SMVRDGHCVNAOIN-UHFFFAOYSA-L disodium;1-dodecoxydodecane;sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O.CCCCCCCCCCCCOCCCCCCCCCCCC SMVRDGHCVNAOIN-UHFFFAOYSA-L 0.000 description 1
- KHIQYZGEUSTKSB-UHFFFAOYSA-L disodium;4-dodecoxy-4-oxo-3-sulfobutanoate Chemical compound [Na+].[Na+].CCCCCCCCCCCCOC(=O)C(S(O)(=O)=O)CC([O-])=O.CCCCCCCCCCCCOC(=O)C(S(O)(=O)=O)CC([O-])=O KHIQYZGEUSTKSB-UHFFFAOYSA-L 0.000 description 1
- FXPVUWKFNGVHIZ-UHFFFAOYSA-L disodium;dodecyl sulfate Chemical compound [Na+].[Na+].CCCCCCCCCCCCOS([O-])(=O)=O.CCCCCCCCCCCCOS([O-])(=O)=O FXPVUWKFNGVHIZ-UHFFFAOYSA-L 0.000 description 1
- 239000004664 distearyldimethylammonium chloride (DHTDMAC) Substances 0.000 description 1
- DDXLVDQZPFLQMZ-UHFFFAOYSA-M dodecyl(trimethyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCC[N+](C)(C)C DDXLVDQZPFLQMZ-UHFFFAOYSA-M 0.000 description 1
- SYELZBGXAIXKHU-UHFFFAOYSA-N dodecyldimethylamine N-oxide Chemical compound CCCCCCCCCCCC[N+](C)(C)[O-] SYELZBGXAIXKHU-UHFFFAOYSA-N 0.000 description 1
- XJWSAJYUBXQQDR-UHFFFAOYSA-M dodecyltrimethylammonium bromide Chemical compound [Br-].CCCCCCCCCCCC[N+](C)(C)C XJWSAJYUBXQQDR-UHFFFAOYSA-M 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 235000019197 fats Nutrition 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 229940049906 glutamate Drugs 0.000 description 1
- 229930195712 glutamate Natural products 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 125000003976 glyceryl group Chemical group [H]C([*])([H])C(O[H])([H])C(O[H])([H])[H] 0.000 description 1
- 229940093915 gynecological organic acid Drugs 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- 150000003840 hydrochlorides Chemical class 0.000 description 1
- 150000003893 lactate salts Chemical class 0.000 description 1
- ILRSCQWREDREME-UHFFFAOYSA-N lauric acid amide propyl betaine Natural products CCCCCCCCCCCC(N)=O ILRSCQWREDREME-UHFFFAOYSA-N 0.000 description 1
- 229940031957 lauric acid diethanolamide Drugs 0.000 description 1
- 125000000400 lauroyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000004200 microcrystalline wax Substances 0.000 description 1
- 235000019808 microcrystalline wax Nutrition 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- RZRNAYUHWVFMIP-UHFFFAOYSA-N monoelaidin Natural products CCCCCCCCC=CCCCCCCCC(=O)OCC(O)CO RZRNAYUHWVFMIP-UHFFFAOYSA-N 0.000 description 1
- 235000013923 monosodium glutamate Nutrition 0.000 description 1
- AXKVOSSFZLZIDC-UHFFFAOYSA-N n,n-diaminoaniline Chemical class NN(N)C1=CC=CC=C1 AXKVOSSFZLZIDC-UHFFFAOYSA-N 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 1
- DVEKCXOJTLDBFE-UHFFFAOYSA-N n-dodecyl-n,n-dimethylglycinate Chemical compound CCCCCCCCCCCC[N+](C)(C)CC([O-])=O DVEKCXOJTLDBFE-UHFFFAOYSA-N 0.000 description 1
- GSGDTSDELPUTKU-UHFFFAOYSA-N nonoxybenzene Chemical compound CCCCCCCCCOC1=CC=CC=C1 GSGDTSDELPUTKU-UHFFFAOYSA-N 0.000 description 1
- HLERILKGMXJNBU-UHFFFAOYSA-N norvaline betaine Chemical compound CCCC(C([O-])=O)[N+](C)(C)C HLERILKGMXJNBU-UHFFFAOYSA-N 0.000 description 1
- LYRFLYHAGKPMFH-UHFFFAOYSA-N octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(N)=O LYRFLYHAGKPMFH-UHFFFAOYSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- HPEOAUXDEAEVHA-UHFFFAOYSA-N octadecyl 2-(dimethylamino)acetate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CN(C)C HPEOAUXDEAEVHA-UHFFFAOYSA-N 0.000 description 1
- 229940055577 oleyl alcohol Drugs 0.000 description 1
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000006072 paste Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- ZZYXNRREDYWPLN-UHFFFAOYSA-N pyridine-2,3-diamine Chemical class NC1=CC=CN=C1N ZZYXNRREDYWPLN-UHFFFAOYSA-N 0.000 description 1
- 229940079877 pyrogallol Drugs 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 229940043230 sarcosine Drugs 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 229940080236 sodium cetyl sulfate Drugs 0.000 description 1
- 229940073490 sodium glutamate Drugs 0.000 description 1
- KSAVQLQVUXSOCR-UHFFFAOYSA-M sodium lauroyl sarcosinate Chemical compound [Na+].CCCCCCCCCCCC(=O)N(C)CC([O-])=O KSAVQLQVUXSOCR-UHFFFAOYSA-M 0.000 description 1
- JXKPEJDQGNYQSM-UHFFFAOYSA-M sodium propionate Chemical compound [Na+].CCC([O-])=O JXKPEJDQGNYQSM-UHFFFAOYSA-M 0.000 description 1
- 235000010334 sodium propionate Nutrition 0.000 description 1
- 239000004324 sodium propionate Substances 0.000 description 1
- 229960003212 sodium propionate Drugs 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- IWIUXJGIDSGWDN-UQKRIMTDSA-M sodium;(2s)-2-(dodecanoylamino)pentanedioate;hydron Chemical compound [Na+].CCCCCCCCCCCC(=O)N[C@H](C([O-])=O)CCC(O)=O IWIUXJGIDSGWDN-UQKRIMTDSA-M 0.000 description 1
- WPVMVUZSNJGLSB-UHFFFAOYSA-N sodium;2-(1-undecyl-4,5-dihydroimidazol-1-ium-1-yl)ethanol Chemical compound [Na+].CCCCCCCCCCC[N+]1(CCO)CCN=C1 WPVMVUZSNJGLSB-UHFFFAOYSA-N 0.000 description 1
- GGHPAKFFUZUEKL-UHFFFAOYSA-M sodium;hexadecyl sulfate Chemical compound [Na+].CCCCCCCCCCCCCCCCOS([O-])(=O)=O GGHPAKFFUZUEKL-UHFFFAOYSA-M 0.000 description 1
- NWZBFJYXRGSRGD-UHFFFAOYSA-M sodium;octadecyl sulfate Chemical compound [Na+].CCCCCCCCCCCCCCCCCCOS([O-])(=O)=O NWZBFJYXRGSRGD-UHFFFAOYSA-M 0.000 description 1
- 229960005078 sorbitan sesquioleate Drugs 0.000 description 1
- 229940032094 squalane Drugs 0.000 description 1
- SFVFIFLLYFPGHH-UHFFFAOYSA-M stearalkonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 SFVFIFLLYFPGHH-UHFFFAOYSA-M 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical class [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- 229940080117 triethanolamine sulfate Drugs 0.000 description 1
- SZEMGTQCPRNXEG-UHFFFAOYSA-M trimethyl(octadecyl)azanium;bromide Chemical compound [Br-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C SZEMGTQCPRNXEG-UHFFFAOYSA-M 0.000 description 1
- AQLJVWUFPCUVLO-UHFFFAOYSA-N urea hydrogen peroxide Chemical compound OO.NC(N)=O AQLJVWUFPCUVLO-UHFFFAOYSA-N 0.000 description 1
- 229940099259 vaseline Drugs 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Landscapes
- Cosmetics (AREA)
Abstract
Description
【０００１】
【発明の属する技術分野】
本発明は染毛剤組成物に関するもので、染め上がりおよび深色性に優れている染毛剤組成物に関するものである。
【０００２】
【従来の技術】
従来、染毛剤としては酸化染料中間体を含有する第１剤と酸化剤を含有する第２剤よりなる二剤型の酸化染毛剤が広く利用されている。この染毛剤は無色の低分子の酸化染料中間体を毛髪中に浸透させ、髪の中で酸化重合を行なわせることにより色素を生成させ毛髪を染着するものである。これらの染毛剤は要望に応じた種々の色調に毛髪を染毛することができ、しかも、その染毛力も優れているので非常に便利なものであり、広く利用されていた。
【０００３】
【発明が解決しようとする課題】
しかしながら、上記酸化染毛剤を用いた場合、深みのある色調でないため染色力が弱く、しかも染毛したことが第三者にわかるような不自然な染め上がりとなるという欠点があった。
【０００４】
本発明は、上記課題を解決し、染め上がりおよび深色性に優れた染毛剤組成物を提供することを目的とする。
【０００５】
【課題を解決するための手段】
すなわち、本発明の趣旨は、（ａ）Ｎ，Ｎ−ビス（２−ヒドロキシエチル）−ｐ−フェニレンジアミンまたはその塩、および（ｂ）２−クロル−ｐ−フェニレンジアミンまたはその塩からなることを特徴とする染毛剤組成物にある。
【０００６】
以下、本発明の構成について詳細に説明する。
【０００７】
本発明において（ａ）群成分として使用されるのは、Ｎ，Ｎ−ビス（２−ヒドロキシエチル）−ｐ−フェニレンジアミンおよびその塩である。（ａ）群成分の配合量は０．０１〜１５重量％であり、０．０１重量％よりも少ないと十分な染毛効果が得られず、１５重量％を越えても、その効果は変わらず経済的ではない。
なお、配合量の下限については、０．１重量％が好ましく、０．１重量％以上配合することにより、より優れた染毛効果が得られる。上限については、１０重量％が好ましく、１０重量％を越えた場合は染毛効果の上昇は少なくなる。
【０００８】
（ａ）群成分と共に、（ｂ）群成分として、２−クロル−ｐ−フェニレンジアミンまたはその塩を含有することにより、染め上がりおよび深色性を向上させることができる。（ｂ）群成分の配合量は０．０１〜１０重量％であり、０．０１重量％よりも少ないと十分な染め上がりおよび深色性が得られず、１０重量％を越えても、その効果は変わらず経済的ではない。なお、配合量の下限については、０．１重量％が好ましく、０．１重量％以上配合することにより、より優れた染め上がりおよび深色性が得られる。上限については、５重量％が好ましく、５重量％を越えた場合は染め上がりおよび深色性の上昇は少なくなる。
【０００９】
（ａ）群成分と（ｂ）群成分の重量比はａ：ｂ＝１：０．０１〜１０であると、より優れた染め上がりおよび深色性が得られる。さらにａ：ｂ＝１：０．１〜８の範囲が染め上がりおよび深色性の点で一層好ましい。
【００１０】
さらに（ｃ）群成分として、ｐ−アミノフェノール、ｐ−アミノ−ｏ−クレゾール、ｍ−アミノフェノール、レゾルシン、ｐ−メチルアミノフェノール、４−ニトロ−ｏ−フェニレンジアミン、２−ニトロ−ｐ−フェニレンジアミン、ピクラミン酸、５−（２−ヒドロキシエチルアミノ）−２−メチルフェノール、１−アミノ−４−メチルアントラキノン、１，４−ジアミノアントラキノンおよびこれらの塩をからなる群から選ばれる少なくとも１種以上を含有することにより、染色性および堅牢性を向上させることができる。これらの中でもｐ−アミノ−ｏ−クレゾール、４−ニトロ−ｏ−フェニレンジアミン、２−ニトロ−ｐ−フェニレンジアミン、ピクラミン酸、５−（２−ヒドロキシエチルアミノ）−２−メチルフェノールおよびこれらの塩が染色性および堅牢性の点でさらに優れた効果が得られるので特に好ましい。その配合量は０．０１〜１０重量％であり、０．０１重量％よりも少ないと十分な染色性および堅牢性が得られず、１０重量％を越えても、その効果は変わらず経済的ではない。なお、配合量の下限については、０．１重量％が好ましく、０．１重量％以上配合することにより、より優れた染色性および堅牢性が得られる。上限については、５重量％が好ましく、５重量％を越えた場合は染色性および堅牢性の上昇は少なくなる。なお、（ａ）〜（ｃ）群成分の塩としては、例えば、有機酸の塩あるいは無機酸の塩、すなわち、硫酸塩、塩酸塩、リン酸塩、酢酸塩、プロピオン酸塩、乳酸塩、クエン酸塩等が挙げられる。
【００１１】
（ａ）群成分、（ｂ）群成分および（ｃ）群成分の重量比はａ：ｂ：ｃ＝１：０．０１〜１０：０．０１〜５であると、より優れた染色性および堅牢性が得られる。さらにａ：ｂ：ｃ＝１：０．１〜８：０．０２〜３の範囲が染色性および堅牢性の点で一層好ましい。
【００１２】
さらに、（ｄ）群成分として高級アルコールおよび／または炭化水素を加えると、安定性、染毛操作性（例えば毛髪への塗布のしやすさ、垂れ落ちない、混合操作の容易さなど）、染色性および堅牢性の点で優れた効果が得られる。その配合量は３〜３０重量％であり、３重量％よりも少ないと十分な安定性、染毛操作性、染色性および堅牢性が得られず、３０重量％を越えても、その効果は変わらず経済的ではない。なお、配合量の下限については、５重量％が好ましく、５重量％以上配合することにより、より優れた安定性、染毛操作性、染色性および堅牢性の効果が得られる。上限については、２０重量％が好ましく、２０重量％を越えた場合は安定性、染毛操作性、染色性および堅牢性の効果の上昇は少なくなる。
【００１３】
高級アルコールとしては、例えば、ラウリルアルコール、ミリスチルアルコール、セチルアルコール、ステアリルアルコール、セトステアリルアルコール、ベヘニルアルコール、イソステアリルアルコール、オレイルアルコール、２−ヘキシルデカノール、２−オクチルドデカノールなどが挙げられる。これらの中でも特に安定性の点から直鎖高級飽和アルコールであるラウリルアルコール、ミリスチルアルコール、セチルアルコール、ステアリルアルコール、セトステアリルアルコール、ベヘニルアルコールが好ましい。
【００１４】
炭化水素としては、例えば、パラフィン、流動パラフィン、流動イソパラフィン、軽質流動パラフィン、軽質流動イソパラフィン、重質流動イソパラフィン、ワセリン、スクワラン、セレシン、マイクロクリスタリンワックス、オゾケライト、プリスタンなどが挙げられる。
【００１５】
さらに（ｅ）群成分として次に挙げる界面活性剤を少なくとも１種以上加えると染色性及び堅牢性の点で優れた効果が得られる。例えば、アニオン性界面活性剤としては次のものが挙げられる。
【００１６】
１．硫酸エステル塩
１−１）アルキル硫酸エステル塩ラウリル硫酸ナトリウム、ラウリル硫酸トリエタノールアミン、ラウリル硫酸アンモニウム、セチル硫酸ナトリウム、ステアリル硫酸ナトリウムなど
１−２）アルキル及びアルキルアリルエーテル硫酸エステル塩ポリオキシエチレン（以下、ＰＯＥと略す。）ラウリルエーテル硫酸ナトリウム、ＰＯＥラウリルエーテル硫酸トリエタノールアミン、ＰＯＥラウリルエーテル硫酸アンモニウム、ＰＯＥアルキルエーテル硫酸ナトリウム、ＰＯＥアルキルエーテル硫酸トリエタノールアミン、ＰＯＥアルキルエーテル硫酸ジエタノールアミン、ＰＯＥアルキルエーテル硫酸アンモニウムなど
１−３）高級脂肪酸エステル塩の硫酸エステル塩硬化ヤシ油脂肪酸グリセリル硫酸ナトリウムなど
１−４）高級脂肪酸アルキロールアミドの硫酸エステル塩
１−５）硫酸化油硫酸化ヒマシ油など
２．リン酸エステル塩ＰＯＥラウリルエーテルリン酸、ＰＯＥオレイルエーテルリン酸、ＰＯＥセチルエーテルリン酸、ＰＯＥステアリルエーテルリン酸、ＰＯＥアルキルエーテルリン酸、ＰＯＥアルキルフェニルエーテルリン酸、およびその塩（ナトリウム塩、トリエタノールアミン塩）など
３．スルホン酸塩
３−１）α−オレフィンスルホン酸塩
３−２）高級脂肪酸エステルのスルホン酸塩
３−３）高級脂肪酸アミドのスルホン酸塩ヤシ油脂肪酸メチルタウリンナトリウム、ラウロイルロチルタウリンナトリウムなど
３−４）アルキルベンゼンスルホン酸塩ドデシルベンゼンスルホン酸トリエタノールアミンなど
３−５）スルホコハク酸塩スルホコハク酸ナトリウム、スルホコハク酸ラウリル二ナトリウム、ＰＯＥスルホコハク酸二ナトリウム、ＰＯＥスルホコハク酸ラウリル二ナトリウム、スルホコハク酸ＰＯＥラウロイルエタノールアミドエステル二ナトリウム、ウンデシレノイルアミドエチルスルホコハク酸二ナトリウムなど４．カルボン酸塩
４−１）高級脂肪酸とアミノ酸の縮合物ラウロイルサルコシンナトリウムなどのＮ−アシルサルコシン塩、Ｎ−ラウロイル−Ｌ−グルタミン酸ナトリウム、Ｎ−ステアロイル−Ｌ−グルタミン酸二ナトリウム、Ｎ−ミリストイル−Ｌ−グルタミン酸ナトリウムなどＮ−アシルグルタミン酸塩
４−２）脂肪酸石鹸オレイン酸、ステアリン酸、ラウリン酸、パルミチン酸などのナトリウム塩、カリウム塩、トリエタノールアミン塩あるいはアンモニウム塩
【００１７】
また、非イオン性界面活性剤としては次のものが挙げられる。
１．ＰＯＥアルキルエーテルＰＯＥセチルエーテル、ＰＯＥステアリルエーテル、ＰＯＥベヘニルエーテル、ＰＯＥオレイルエーテル、ＰＯＥラウリルエーテルなど
２．ＰＯＥアルキルアリルエーテルＰＯＥノニルフェニルエーテル、ＰＯＥオクチルフェニルエーテルなど
３．ＰＯＥソルビタン脂肪酸エステルモノオレイン酸ＰＯＥソルビタン、モノステアリン酸ＰＯＥソルビタン、モノパルミチン酸ＰＯＥソルビタン、モノラウリン酸ＰＯＥソルビタン、トリオレイン酸ＰＯＥソルビタンなど
４．ＰＯＥグリセリルモノ脂肪酸エステルモノステアリン酸ＰＯＥグリセリン、モノミリスチン酸ＰＯＥグリセリンなど
５．ＰＯＥソルビトール脂肪酸エステルテトラオレイン酸ＰＯＥソルビット、ヘキサステアリン酸ＰＯＥソルビット、モノラウリン酸ＰＯＥソルビット、ＰＯＥソルビットミツロウなど
６．ヒマシ油、硬化ヒマシ油誘導体ＰＯＥ硬化ヒマシ油、ＰＯＥヒマシ油など
７．ＰＯＥ脂肪酸エステルモノオレイン酸ポリエチレングリコール、モノステアリン酸ポリエチレングリコール、モノラウリン酸ポリエチレングリコールなど
８．高級脂肪酸グリセリンエステル親油型モノオレイン酸グリセリン、親油型モノステアリン酸グリセリン、自己乳化型モノステアリン酸グリセリンなど
９．ソルビタン脂肪酸エステルモノオレイン酸ソルビタン、セスキオレイン酸ソルビタン、トリオレイン酸ソルビタン、モノステアリン酸ソルビタン、モノパルミチン酸ソルビタン、モノラウリン酸ソルビタンなど
１０．ラノリン誘導体ＰＯＥラノリン、ＰＯＥラノリンアルコール、ＰＯＥソルビトールラノリンなど
１１．アルキロールアミドラウリン酸ジエタノールアミド、ヤシ油脂肪酸ジエタノールアミドなど
１２．ＰＯＥ脂肪酸アミドＰＯＥステアリン酸アミドなど
１３．ショ糖脂肪酸エステル
１４．アルキルアミンオキシドジメチルラウリルアミンオキシドなど
【００１８】
・ また、両性界面活性剤としてはカルボン酸型、硫酸エステル型、スルホン酸型、リン酸エステル型などが挙げられ、例えば、２−アルキル−Ｎ−カルボキシメチル−Ｎ−ヒドロキシエチルイミダゾリニウムベタイン、ラウリルジメチルアミノ酢酸ベタイン、ウンデシノイル−カルボキシメトキシエチルカルボキシメチルイミダゾリニウムベタインナトリウム、ウンデシルヒドロキシエチルイミダゾリニウムベタインナトリウム、ウンデシル−Ｎ−ヒドロキシエチル−Ｎ−カルボキシメチルイミダゾリニウムベタイン、塩酸アルキルジアミノエチルグリシン液、ステアリルジヒドロキシエチルベタイン、ステアリルジメチルアミノ酢酸ベタイン、ステアリルジメチルベタインナトリウム液、ビス（ステアリル−Ｎ−ヒドロキシエチルイミダゾリン）クロル酢酸錯体、ヤシ油アルキル−Ｎ−カルボキシエチル−Ｎ−ヒドロキシエチルイミダゾリニウムベタインナトリウム、ヤシ油アルキル−Ｎ−カルボキシエトキシエチル−Ｎ−カルボキシエチルイミダゾリニウムジナトリウムヒドロキシド、ヤシ油アルキル−Ｎ−カルボキシメトキシエチル−Ｎ−カルボキシエチルイミダゾリニウムジナトリウムヒドロキシド、ヤシ油アルキル−Ｎ−カルボキシメトキシエチル−Ｎ−カルボキシエチルイミダゾリニウムジナトリウムラウリル硫酸、ヤシ油アルキルベタイン、ヤシ油脂肪酸アミドプロピルベタイン、ヤシ油脂肪酸−Ｎ−カルボキシメトキシエチル−Ｎ−カルボキシエチルイミダゾリニウムベタインナトリウム、ラウリルアミノプロピオン酸トリエタノールアミン、β−ラウリルアミノプロピオン酸ナトリウム、ラウリルＮ−カルボキシメトキシエチル−Ｎ−カルボキシメチルイミダゾリニウムジナトリウムドデカノイルサルコシン、ラウリルジアミノエチルグリシンナトリウム、ラウリン酸アミドプロピルベタイン液等が挙げられる。
【００１９】
また、カチオン性界面活性剤としては、下記（１）式に示す一般式で表されるものが用いられる。
例えば、塩化アルキルトリメチルアンモニウム、塩化ラウリルトリメチルアンモニウム、塩化セチルトリメチルアンモニウム、臭化セチルトリメチルアンモニウム、塩化ステアリルトリメチルアンモニウム、臭化ステアリルトリメチルアンモニウム、臭化ラウリルトリメチルアンモニウム、塩化ジアルキルジメチルアンモニウム、塩化ジセチルジメチルアンモニウム、塩化ジステアリルジメチルアンモニウム、塩化ジココイルジメチルアンモニウム、塩化ミリスチルジメチルベンジルアンモニウム、塩化ステアリルジメチルベンジルアンモニウムなどが挙げられる。
【００２０】
【化１】
【００２１】
その配合量は、０．０１〜４０重量％であり、０．０１重量％よりも少ないと十分な染色性および堅牢性が得られず、４０重量％を越えても、その効果は変わらず経済的ではない。なお、配合量の下限については、０．１重量％が好ましく、０．１重量％以上配合することにより、より優れた染色性および堅牢性が得られる。上限については、３０重量％が好ましく、３０重量％を越えた場合は染色性および堅牢性の上昇は少なくなる。特に、アニオン性界面活性剤及び／又は非イオン性界面活性剤を用いると染色性、堅牢性の点でより優れた効果が得られる。また、（ｄ）群成分と（ｅ）群成分の重量比はｄ：ｅ＝１：０．１〜１０であると、より優れた染色性と堅牢性が得られる。
【００２２】
その他の酸化染料中間体としては、パラフェニレンジアミン類、パラトルイレンジアミン類、アミノフェノール類、アミノニトロフェノール類、ジフェニルアミン類、ジアミノフェニルアミン類、Ｎ−フェニルフェニレンジアミン類、ジアミノピリジン類等およびそれらの塩類が挙げられる。その配合量は例えば、染毛剤組成物の全重量に対して０．０１〜１０重量％程度である。また、カップラーとして、ピロガロール、カテコール、メタフェニレンジアミン等を配合することができる。また、「医薬部外品原料規格」（１９９１年６月発行，薬事日報社）に収載されたものを用いることができる。更に、グリセリン、プロピレングリコール、ポリエチレングリコール等の保湿剤、亜硫酸塩、アスコルビン酸等の安定剤、カルボキシメチルセルロース、キサンタンガム等の増粘剤、アンモニア、アルカノールアミン等のアルカリ剤、香料などを必要に応じて適宜、配合することができる。
【００２３】
一方、酸化剤としては、過酸化水素、過酸化尿素等を含有し、また、フェナセチン、ＥＤＴＡ等の安定剤、界面活性剤、油脂類、高級アルコール、酸、ｐＨ調整剤、香料などを必要に応じて適宜、配合することができる。
【００２４】
この染毛剤を使用する場合は、染毛処理の直前に染毛剤組成物と酸化剤とを混合して染毛液を調製し、毛髪に塗布する。剤型は液状、クリーム、ゲル、ペーストなどが挙げられるが、これらの中でもクリーム状のものが、染毛時の毛髪への付着性がよく、染色性および堅牢性の点で好ましい。また、徐染性タイプとすれば、２〜数回染毛操作を繰り返すことにより、人に気づかれずに徐々に白髪を目立たなくさせることができる。
【００２５】
【実施例】
＜実施例１および比較例１，２＞
【００２６】
【表１】
酸化剤 重量％
過酸化水素水（３５％） １５．０
ＥＤＴＡ ０．５
セタノール ２．０
ラウリル硫酸ナトリウム ０．５
フェナセチン ０．１
精製水で１００％にする。
【００２８】
＜評価方法＞１０名のパネラーから採取した毛束を、上記の染毛剤組成剤と酸化剤を１：１で混合した染毛液で染色し、染め上がりおよび深色性について下記の基準により評価し、最も多い評価を表１に示した。
・ 染め上がり
○…光沢のある自然な、まろやかな染め上がり
△…やや光沢のない不自然な、まろやかさに欠ける染め上がり
×…光沢のない不自然な、まろやかさに欠ける染め上がり
・ 深色性
○…深みのある色調に染まる。
△…やや深みのある色調に染まる。
×…あまり深みがない。
【００２９】
実施例２ 重量％
Ｎ，Ｎ−ビス（２−ヒドロキシエチル）−ｐ−フェニレンジアミン硫酸塩４．０
２−クロル−ｐ−フェニレンジアミン ０．８
ｐ−アミノ−ｏ−クレゾール ０．２
２−ニトロ−ｐ−フェニレンジアミン ０．２
ポリオキシエチレン（１０）オレイルエーテル １５．０
セトステアリルアルコール ８．０
流動パラフィン ２．０
２８％アンモニア水 ｐＨ９とする量
精製水で１００％にする。実施例１と同様に染毛すると、実施例１と同様に優れた染め上がりおよび深色性が得られた。
【００３０】
【００３１】
【００３２】
実施例５ 重量％
Ｎ，Ｎ−ビス（２−ヒドロキシエチル）−ｐ−フェニレンジアミン硫酸塩２．０
２−クロル−ｐ−フェニレンジアミン １．０
ｐ−アミノフェノール ０．５
レゾルシン ０．５
ｐ−アミノ−ｏ−クレゾール ０．５
４−ニトロ−ｏ−フェニレンジアミン ０．５
ポリオキシエチレン（１０）オクチルフェニルエーテル １０．０
ステアリルアルコール ８．０
メチルフェニルポリシロキサン ５．０
オレイン酸 ５．０
ポリエチレングリコール ２０．０
亜硫酸ナトリウム ０．５
２８％アンモニア水 ｐＨ９．５とする量
精製水で１００％にする。実施例１と同様に染毛すると、実施例１と同様に優れた染め上がりおよび深色性が得られた。
【００３３】
実施例６ 重量％
Ｎ，Ｎ−ビス（２−ヒドロキシエチル）−ｐ−フェニレンジアミン ３．０
２−クロル−ｐ−フェニレンジアミン １．０
ｐ−アミノフェノール ０．５
ｍ−アミノフェノール ０．５
５−（２−ヒドロキシエチルアミノ）−２−メチルフェノール ０．３
オレイン酸 ５．０
ポリエチレングリコール ２０．０
亜硫酸ナトリウム ０．５
２８％アンモニア水 ｐＨ９．５とする量
精製水で１００％にする。実施例１と同様に染毛すると、実施例１と同様に優れた染め上がりおよび深色性が得られた。
【００３４】
【発明の効果】
以上のように本発明の染毛剤組成物は、染め上がりおよび深色性に優れている。[0001]
TECHNICAL FIELD OF THE INVENTION
The present invention relates to a hair dye composition, and more particularly to a hair dye composition having excellent dyeing and deep coloration.
[0002]
[Prior art]
Conventionally, as a hair dye, a two-part type oxidative hair dye comprising a first agent containing an oxidation dye intermediate and a second agent containing an oxidant has been widely used. This hair dye is a dye that causes a colorless, low-molecular weight oxidation dye intermediate to penetrate into the hair and causes oxidative polymerization in the hair to form a pigment to dye the hair. These hair dyes are very convenient because they can dye hair into various colors according to demand and have excellent hair dyeing power, and have been widely used.
[0003]
[Problems to be solved by the invention]
However, when the above-mentioned oxidative hair dye is used, there is a drawback that the dyeing power is weak because the color tone is not deep, and the dyeing becomes unnatural so that a third party can know that the hair has been dyed.
[0004]
An object of the present invention is to solve the above-mentioned problems and to provide a hair dye composition having excellent dyeing and deep coloration.
[0005]
[Means for Solving the Problems]
That is, the gist of the present invention is to consist of (a) N, N-bis (2-hydroxyethyl) -p-phenylenediamine or a salt thereof, and (b) 2-chloro-p-phenylenediamine or a salt thereof. Characteristic hair dye composition.
[0006]
Hereinafter, the configuration of the present invention will be described in detail.
[0007]
In the present invention, N, N-bis (2-hydroxyethyl) -p-phenylenediamine and salts thereof are used as the component (a). (A) The compounding amount of the group component is 0.01 to 15% by weight. If the amount is less than 0.01% by weight, a sufficient hair dyeing effect cannot be obtained. Even if the amount exceeds 15% by weight, the effect is not changed. Not economical.
The lower limit of the amount is preferably 0.1% by weight, and by blending 0.1% by weight or more, a more excellent hair dyeing effect can be obtained. The upper limit is preferably 10% by weight, and if it exceeds 10% by weight, the increase in the hair dyeing effect is reduced.
[0008]
By containing 2-chloro-p-phenylenediamine or a salt thereof as the (b) group component together with the (a) group component, dyeing and deep coloration can be improved. The compounding amount of the component (b) is from 0.01 to 10% by weight. If the amount is less than 0.01% by weight, sufficient dyeing and deep color cannot be obtained. Is not as economical as ever. The lower limit of the compounding amount is preferably 0.1% by weight, and by adding 0.1% by weight or more, more excellent dyeing and deep coloration can be obtained. As for the upper limit, 5% by weight is preferable, and when it exceeds 5% by weight, the dyeing up and the increase in deep color are reduced.
[0009]
When the weight ratio of the (a) group component and the (b) group component is a: b = 1: 0.01 to 10, more excellent dyeing and deep coloration can be obtained. Further, the range of a: b = 1: 0.1 to 8 is more preferable in terms of dyeing and deep color.
[0010]
Further, as the component (c), p-aminophenol, p-amino-o-cresol, m-aminophenol, resorcinol, p-methylaminophenol, 4-nitro-o-phenylenediamine, 2-nitro-p-phenylene At least one selected from the group consisting of diamines, picramic acid, 5- (2-hydroxyethylamino) -2-methylphenol, 1-amino-4-methylanthraquinone, 1,4-diaminoanthraquinone and salts thereof The dyeability and the fastness can be improved by containing. Among them, p-amino-o-cresol, 4-nitro-o-phenylenediamine, 2-nitro-p-phenylenediamine, picramic acid, 5- (2-hydroxyethylamino) -2-methylphenol and salts thereof Is particularly preferable since a more excellent effect can be obtained in terms of dyeability and fastness. The compounding amount is from 0.01 to 10% by weight. If the amount is less than 0.01% by weight, sufficient dyeing property and fastness cannot be obtained. is not. The lower limit of the amount is preferably 0.1% by weight, and by blending 0.1% by weight or more, more excellent dyeability and fastness can be obtained. The upper limit is preferably 5% by weight, and if it exceeds 5% by weight, the increase in dyeability and fastness decreases. The salts of the components (a) to (c) include, for example, salts of organic acids or salts of inorganic acids, that is, sulfates, hydrochlorides, phosphates, acetates, propionates, lactates, and the like. Citrates and the like can be mentioned.
[0011]
When the weight ratio of the (a) group component, the (b) group component and the (c) group component is a: b: c = 1: 0.01 to 10: 0.01 to 5, more excellent dyeability and Robustness is obtained. Further, the range of a: b: c = 1: 0.1 to 8: 0.02 to 3 is more preferable in view of dyeability and fastness.
[0012]
Furthermore, when a higher alcohol and / or hydrocarbon is added as the component (d), stability, hair dyeing operability (for example, ease of application to hair, no dripping, easy mixing operation, etc.), dyeing Excellent effects are obtained in terms of properties and fastness. The compounding amount is 3 to 30% by weight. If the amount is less than 3% by weight, sufficient stability, hair dyeing operability, dyeing property and fastness cannot be obtained. Not as economical as ever. The lower limit of the compounding amount is preferably 5% by weight, and by adding 5% by weight or more, more excellent effects of stability, hair dyeing operability, dyeability and fastness can be obtained. The upper limit is preferably 20% by weight, and if it exceeds 20% by weight, the effects of stability, hair dyeing operability, dyeing properties and fastness are less increased.
[0013]
Examples of the higher alcohol include lauryl alcohol, myristyl alcohol, cetyl alcohol, stearyl alcohol, cetostearyl alcohol, behenyl alcohol, isostearyl alcohol, oleyl alcohol, 2-hexyldecanol, and 2-octyldodecanol. Among them, particularly preferred are straight chain higher saturated alcohols such as lauryl alcohol, myristyl alcohol, cetyl alcohol, stearyl alcohol, cetostearyl alcohol and behenyl alcohol from the viewpoint of stability.
[0014]
Examples of the hydrocarbon include paraffin, liquid paraffin, liquid isoparaffin, light liquid paraffin, light liquid isoparaffin, heavy liquid isoparaffin, vaseline, squalane, ceresin, microcrystalline wax, ozokerite, and pristane.
[0015]
Further, when at least one of the following surfactants is added as the component (e), excellent effects can be obtained in terms of dyeability and fastness. For example, the following are mentioned as anionic surfactant.
[0016]
1. Sulfate ester 1-1) Alkyl sulfate sodium lauryl sulfate, triethanolamine lauryl sulfate, ammonium lauryl sulfate, sodium cetyl sulfate, sodium stearyl sulfate, etc. 1-2) Alkyl and alkyl allyl ether sulfate polyoxyethylene (hereinafter, referred to as POE.) Lauryl ether sodium sulfate, POE lauryl ether triethanolamine sulfate, POE lauryl ether ammonium sulfate, POE alkyl ether sodium sulfate, POE alkyl ether triethanolamine sulfate, POE alkyl ether diethanolamine sulfate, POE alkyl ether ammonium sulfate, etc. 3) Sulfuric acid ester salt of higher fatty acid ester hardened coconut oil fatty acid sodium glyceryl sulfate 1-4) Sulfates of grade fatty alkylol amide 1-5) 2 such as sulfated oils sulfated castor oil. Phosphate salt POE lauryl ether phosphoric acid, POE oleyl ether phosphoric acid, POE cetyl ether phosphoric acid, POE stearyl ether phosphoric acid, POE alkyl ether phosphoric acid, POE alkyl phenyl ether phosphoric acid, and salts thereof (sodium salt, triethanol 2. amine salts) and the like. Sulfonate 3-1) α-olefin sulfonate 3-2) Sulfonate of higher fatty acid ester 3-3) Sulfonate of higher fatty acid amide Coconut oil fatty acid Sodium methyltaurine, sodium lauroylrotyltaurine, etc. 4) Alkylbenzenesulfonate dodecylbenzenesulfonate triethanolamine, etc. 3-5) Sulfosuccinate sodium sulfosuccinate, disodium lauryl sulfosuccinate, disodium POE sulfosuccinate, disodium lauryl POE sulfosuccinate, POE lauroylethanolamide sulfosuccinate 3. disodium ester and disodium undecylenoylamidosulfosuccinate; Carboxylates 4-1) Condensates of higher fatty acids and amino acids N-acyl sarcosine salts such as sodium lauroyl sarcosine, sodium N-lauroyl-L-glutamate, disodium N-stearoyl-L-glutamate, N-myristoyl-L- N-acyl glutamate such as sodium glutamate 4-2) Fatty acid soap Sodium salt, potassium salt, triethanolamine salt or ammonium salt such as oleic acid, stearic acid, lauric acid and palmitic acid
The following are examples of the nonionic surfactant.
1. 1. POE alkyl ether POE cetyl ether, POE stearyl ether, POE behenyl ether, POE oleyl ether, POE lauryl ether, etc. 2. POE alkyl allyl ether POE nonyl phenyl ether, POE octyl phenyl ether, etc. 3. POE sorbitan fatty acid ester POE sorbitan monooleate, POE sorbitan monostearate, POE sorbitan monopalmitate, POE sorbitan monolaurate, POE sorbitan trioleate, etc. 4. POE glyceryl monofatty acid ester POE glycerin monostearate, POE glycerin monomyristate, etc. 5. POE sorbitol fatty acid ester POE sorbite tetraoleate, POE sorbite hexastearate, POE sorbite monolaurate, POE sorbit beeswax, etc. 6. Castor oil, hydrogenated castor oil derivatives POE hydrogenated castor oil, POE castor oil, etc. 7. POE fatty acid ester polyethylene glycol monooleate, polyethylene glycol monostearate, polyethylene glycol monolaurate, etc. 8. Higher fatty acid glycerin esters such as lipophilic glyceryl monooleate, lipophilic glyceryl monostearate, and self-emulsifying glyceryl monostearate. 9. Sorbitan fatty acid esters such as sorbitan monooleate, sorbitan sesquioleate, sorbitan trioleate, sorbitan monostearate, sorbitan monopalmitate and sorbitan monolaurate. 10. Lanolin derivatives POE lanolin, POE lanolin alcohol, POE sorbitol lanolin, etc. 11. alkylolamide lauric acid diethanolamide, coconut oil fatty acid diethanolamide, etc. 12. POE fatty acid amide POE stearic acid amide and the like 13. sucrose fatty acid ester Alkylamine oxide dimethyl laurylamine oxide, etc.
-Examples of the amphoteric surfactant include a carboxylic acid type, a sulfate type, a sulfonic acid type, and a phosphate type, for example, 2-alkyl-N-carboxymethyl-N-hydroxyethylimidazolinium betaine, Betaine lauryl dimethylaminoacetate, sodium undecinoyl-carboxymethoxyethylcarboxymethylimidazolinium betaine, sodium undecylhydroxyethylimidazolinium betaine, undecyl-N-hydroxyethyl-N-carboxymethylimidazolinium betaine, alkyldiaminoethylglycine hydrochloride Solution, stearyl dihydroxyethyl betaine, betaine stearyl dimethylaminoacetate, sodium stearyl dimethyl betaine solution, bis (stearyl-N-hydroxyethyl imidazo Phosphorus) chloroacetic acid complex, coconut oil alkyl-N-carboxyethyl-N-hydroxyethylimidazolinium betaine sodium, coconut oil alkyl-N-carboxyethoxyethyl-N-carboxyethylimidazolinium disodium hydroxide, coconut oil alkyl -N-carboxymethoxyethyl-N-carboxyethylimidazolinium disodium hydroxide, coconut oil alkyl-N-carboxymethoxyethyl-N-carboxyethylimidazolinium disodium lauryl sulfate, coconut oil alkyl betaine, coconut fatty acid amide Propyl betaine, coconut oil fatty acid-N-carboxymethoxyethyl-N-carboxyethylimidazolinium betaine sodium, triethanolamine laurylaminopropionate, β-laurylamino Sodium propionate, lauryl N- carboxymethoxy ethyl -N- carboxymethyl imidazolinium disodium dodecanoyl sarcosine, lauryl di aminoethyl sodium glycine, lauric acid amide propyl betaine solution and the like.
[0019]
As the cationic surfactant, those represented by the following general formula (1) are used.
For example, alkyltrimethylammonium chloride, lauryltrimethylammonium chloride, cetyltrimethylammonium chloride, cetyltrimethylammonium bromide, stearyltrimethylammonium chloride, stearyltrimethylammonium bromide, lauryltrimethylammonium bromide, dialkyldimethylammonium chloride, dicetyldimethylammonium chloride , Distearyl dimethyl ammonium chloride, dicocoyl dimethyl ammonium chloride, myristyl dimethyl benzyl ammonium chloride, stearyl dimethyl benzyl ammonium chloride and the like.
[0020]
Embedded image
[0021]
The compounding amount is from 0.01 to 40% by weight. If the amount is less than 0.01% by weight, sufficient dyeability and fastness cannot be obtained. Not a target. The lower limit of the amount is preferably 0.1% by weight, and by blending 0.1% by weight or more, more excellent dyeability and fastness can be obtained. The upper limit is preferably 30% by weight, and if it exceeds 30% by weight, the increase in dyeing properties and fastness is reduced. In particular, when an anionic surfactant and / or a nonionic surfactant is used, more excellent effects can be obtained in terms of dyeability and fastness. Further, when the weight ratio of the component (d) to the component (e) is d: e = 1: 0.1 to 10, more excellent dyeability and fastness can be obtained.
[0022]
Other oxidation dye intermediates include paraphenylenediamines, paratoluylenediamines, aminophenols, aminonitrophenols, diphenylamines, diaminophenylamines, N-phenylphenylenediamines, diaminopyridines and the like. Salts. The compounding amount is, for example, about 0.01 to 10% by weight based on the total weight of the hair dye composition. Further, pyrogallol, catechol, metaphenylenediamine and the like can be blended as a coupler. Further, those listed in "Quasi-drug raw material standards" (published in June 1991, Yakuji Nippo) can be used. Further, humectants such as glycerin, propylene glycol and polyethylene glycol, sulfites, stabilizers such as ascorbic acid, carboxymethyl cellulose, thickeners such as xanthan gum, ammonia, alkali agents such as alkanolamines, fragrances and the like as required. It can be appropriately blended.
[0023]
On the other hand, as the oxidizing agent, it contains hydrogen peroxide, urea peroxide, etc., and also requires stabilizers such as phenacetin and EDTA, surfactants, fats and oils, higher alcohols, acids, pH adjusters, and fragrances. They can be blended as appropriate.
[0024]
When this hair dye is used, a hair dye composition is prepared by mixing a hair dye composition and an oxidizing agent immediately before the hair dyeing treatment, and applied to the hair. Examples of the dosage form include liquid, cream, gel, paste and the like. Among them, cream-like one is preferable in terms of good adhesion to hair at the time of hair dyeing, dyeing property and fastness. In addition, if the dye is of the slow-dyeing type, the gray hair can be gradually made inconspicuous without recognizing the person by repeating the hair dyeing operation two to several times.
[0025]
【Example】
<Example 1 and Comparative Examples 1 and 2>
[0026]
[Table 1]
Oxidant weight%
Hydrogen peroxide solution (35%) 15.0
EDTA 0.5
Cetanol 2.0
Sodium lauryl sulfate 0.5
Phenacetin 0.1
Make up to 100% with purified water.
[0028]
<Evaluation method> Hair bundles collected from 10 panelists were dyed with a hair dye solution in which the above-mentioned hair dye composition and oxidizing agent were mixed at a ratio of 1: 1. Dyeing and deep color were evaluated according to the following criteria. Table 1 shows the most frequent evaluations.
・ Dyeing ○… Smooth, natural, mellow dyeing △… Slightly glossy, unnatural, lacking mellow dyeing ×: Unsmooth, unnatural, mellow lacking dyeing • Deep color ○: Deep Dyes in a certain color.
Δ: Slightly deep color tone.
×: Not very deep.
[0029]
Example 2% by weight
N, N-bis (2-hydroxyethyl) -p-phenylenediamine sulfate 4.0
2-chloro-p-phenylenediamine 0.8
p-Amino-o-cresol 0.2
2-nitro-p-phenylenediamine 0.2
Polyoxyethylene (10) oleyl ether 15.0
Cetostearyl alcohol 8.0
Liquid paraffin 2.0
28% aqueous ammonia Make up to 100% with purified water to adjust the pH to 9. When hair was dyed in the same manner as in Example 1, excellent dyeing and deep-colored properties were obtained as in Example 1.
[0030]
[0031]
[0032]
Example 5% by weight
N, N-bis (2-hydroxyethyl) -p-phenylenediamine sulfate 2.0
2-chloro-p-phenylenediamine 1.0
p-aminophenol 0.5
Resorcinol 0.5
p-amino-o-cresol 0.5
4-nitro-o-phenylenediamine 0.5
Polyoxyethylene (10) octyl phenyl ether 10.0
Stearyl alcohol 8.0
Methylphenyl polysiloxane 5.0
Oleic acid 5.0
Polyethylene glycol 20.0
Sodium sulfite 0.5
28% aqueous ammonia Make up to 100% with purified water to adjust the pH to 9.5. When hair was dyed in the same manner as in Example 1, excellent dyeing and deep-colored properties were obtained as in Example 1.
[0033]
Example 6% by weight
N, N-bis (2-hydroxyethyl) -p-phenylenediamine 3.0
2-chloro-p-phenylenediamine 1.0
p-aminophenol 0.5
m-aminophenol 0.5
5- (2-hydroxyethylamino) -2-methylphenol 0.3
Oleic acid 5.0
Polyethylene glycol 20.0
Sodium sulfite 0.5
28% ammonia water Make up to 100% with purified water to adjust the pH to 9.5. When hair was dyed in the same manner as in Example 1, excellent dyeing and deep-colored properties were obtained as in Example 1.
[0034]
【The invention's effect】
As described above, the hair dye composition of the present invention is excellent in dyeing and deep color.
Claims (5)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2003187962A JP2004002445A (en) | 2003-06-30 | 2003-06-30 | Hair dye composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2003187962A JP2004002445A (en) | 2003-06-30 | 2003-06-30 | Hair dye composition |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP6082387A Division JPH07267835A (en) | 1994-03-28 | 1994-03-28 | Hair coloring composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JP2004002445A true JP2004002445A (en) | 2004-01-08 |
Family
ID=30438404
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2003187962A Pending JP2004002445A (en) | 2003-06-30 | 2003-06-30 | Hair dye composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2004002445A (en) |
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2003
- 2003-06-30 JP JP2003187962A patent/JP2004002445A/en active Pending
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