JP2005213209A - Shampoo composition for dyed hair - Google Patents
Shampoo composition for dyed hair Download PDFInfo
- Publication number
- JP2005213209A JP2005213209A JP2004022710A JP2004022710A JP2005213209A JP 2005213209 A JP2005213209 A JP 2005213209A JP 2004022710 A JP2004022710 A JP 2004022710A JP 2004022710 A JP2004022710 A JP 2004022710A JP 2005213209 A JP2005213209 A JP 2005213209A
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- JP
- Japan
- Prior art keywords
- hair
- surfactant
- shampoo composition
- general formula
- carbon atoms
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 239000000203 mixture Substances 0.000 title claims abstract description 32
- 239000002453 shampoo Substances 0.000 title claims abstract description 20
- 239000002280 amphoteric surfactant Substances 0.000 claims abstract description 17
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- 125000004432 carbon atom Chemical group C* 0.000 claims description 12
- 238000004043 dyeing Methods 0.000 claims description 10
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 9
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- 229910052783 alkali metal Inorganic materials 0.000 claims description 6
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- 229930195712 glutamate Natural products 0.000 claims description 6
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Landscapes
- Cosmetics (AREA)
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Abstract
Description
本発明は、染髪剤組成物で処理し染色された毛髪を洗髪する場合に、色落ちを防止する効果を有し、低刺激で使用感に優れ、使用しやすい粘度を有する染色毛髪用シャンプー組成物に関する。 The present invention is a shampoo composition for dyeing hair which has an effect of preventing discoloration, has a low irritation, is excellent in use feeling, and has a viscosity that is easy to use when washing hair dyed by treatment with a hair dye composition. Related to things.
近年、中高年層の増加や白髪に悩む若年層の増加に伴い、白髪を自然な色に染髪したいという要望が高まりつつある。また若年層においては、ファッション上の理由から、黒髪を栗色系や褐色系の色合いにしたいという要求も高まってきている。このため、ヘアカラーやカラーリンス、カラートリートメント、カラームースなど数多くの商品が市販されている。このような商品は、毛髪に酸化染料や酸性染料などの直接染料を吸着させ、毛髪の色調を変化させる原理を利用しているため、日々の洗髪により染料の脱離や変色が生じ、染毛直後の色合いが長持ちしないという欠点がある。 In recent years, with the increase of middle-aged and older people and the increase of young people who suffer from gray hair, there is an increasing demand for hair coloring of natural white hair. In addition, for young people, there is a growing demand for black hair to have a maroon or brown shade for fashion reasons. For this reason, many products such as hair color, color rinse, color treatment, and color mousse are commercially available. Such products use the principle of changing the color tone of hair by adsorbing direct dyes such as oxidative dyes and acid dyes to the hair, so that the detachment and discoloration of the dyes occur due to daily hair washing, and hair dyeing There is a disadvantage that the color just after does not last long.
このような問題に対し、シャンプーに染料を配合し洗髪時に毛髪に染料を残留させて色を維持しようとする試みが数多くなされている(特許文献１、特許文献２、特許文献３等参照)。しかし、これらの提案はいずれも染色された毛髪に既に吸着されている染料の脱離や変色の防止には配慮を払っておらず、これらに着目した色落ち防止効果に優れた洗浄剤組成物についての提案は数が少ない。 In order to solve such problems, many attempts have been made to maintain the color by blending a dye into a shampoo and leaving the dye in the hair during hair washing (see Patent Document 1, Patent Document 2, Patent Document 3, etc.). However, none of these proposals pay attention to prevention of detachment or discoloration of dyes already adsorbed to the dyed hair, and the detergent composition is excellent in color fading prevention effect focusing on these. There are few proposals for.
特許文献４には染髪組成物で処理し染色された毛髪を洗髪する場合に、色落ちを防止することのできる染毛処理した毛髪用の洗浄剤組成物としてカルボン酸残基を有する界面活性剤を含有し、かつｐＨが３.０〜７.０である染毛処理した毛髪用洗浄剤組成物が提案されている。具体的なカルボン酸基を有する界面活性剤としてスルホコハク酸系界面活性剤、アシルグルタミン酸系界面活性剤、カルボキシベタイン系界面活性剤、アシル化ペプチド系界面活性剤が例示されている。しかしながら、これらの開示技術の色落ち防止効果は十分ではなく、さらなる改良が望まれていた。 Patent Document 4 discloses a surfactant having a carboxylic acid residue as a detergent composition for hair subjected to hair dyeing treatment capable of preventing color fading when washing hair dyed by treatment with the hair dye composition. And a hair-cleaning composition with a hair dyeing treatment having a pH of 3.0 to 7.0 has been proposed. Specific examples of surfactants having a carboxylic acid group include sulfosuccinic acid surfactants, acyl glutamic acid surfactants, carboxybetaine surfactants, and acylated peptide surfactants. However, the discoloration prevention effect of these disclosed techniques is not sufficient, and further improvement has been desired.
特許文献４よるカルボン酸基を有する界面活性剤、特にＮ−アシルグルタミン酸系界面活性剤、アシル化ペプチド系界面活性剤等のＮ−アシルアミノ酸系界面活性剤を含有する液体洗浄剤組成物は一般に増粘が困難であり、これらの改善が求められていた。一方特許文献５には、特定の無機塩を配合することによりＮ−アシルアミノ酸系界面活性剤を含有する液体洗浄剤組成物の粘度を上昇させる技術が記載されている。しかしながら、無機塩の配合により高分子コンディショニング剤の安定配合が困難になり、高分子コンディショニング剤の配合に制限が付く問題があった。
本発明が解決しようとする課題は、近年コンディショニング剤、セット剤として使用される頻度の高くなった高分子化合物との相溶性、低温安定性が良好で、染髪組成物で処理し染色された毛髪を処理することを目的とした、安全性が高く、使用感に優れ、各種高分子化合物との相溶性に優れ、使用し易い粘度を有する染色毛髪用シャンプー組成物を提供することである。 The problem to be solved by the present invention is a hair dyed by treatment with a hair dyeing composition, which has good compatibility with high-molecular compounds that have been used frequently as conditioning agents and set agents in recent years and has good low-temperature stability. It is intended to provide a shampoo composition for dyeing hair that has a high safety, excellent usability, excellent compatibility with various polymer compounds, and has a viscosity that is easy to use.
本発明者らは、Ｎ−アシルアミノ酸系界面活性剤と各種界面活性剤の組み合わせによる色落ち防止効果、相互作用による増粘を鋭意検討の結果、特定のアミドアミン型両性界面活性剤とＮ−アシルグルタミン酸塩型アニオン性界面活性剤を特定の比率で配合することにより優れた色落ち防止作用があることを見出し、更に特定のノニオン界面活性剤を同時に配合することにより、使用し易い粘度で良好な粘度安定性を有するシャンプー組成物が得られることを見出し本発明を完成した。 As a result of intensive studies on the anti-fading effect and thickening due to the interaction of the combination of an N-acylamino acid surfactant and various surfactants, the present inventors have determined that a specific amidoamine-type amphoteric surfactant and N-acyl. It has been found that there is an excellent anti-fading effect by blending a glutamate-type anionic surfactant at a specific ratio, and by blending a specific nonionic surfactant at the same time, the viscosity is easy to use and good. The present invention was completed by finding that a shampoo composition having viscosity stability was obtained.
即ち本発明は
一般式（１）
That is, the present invention relates to the general formula (1)
［式中Ｒ１ＣＯは炭素数６〜２２の脂肪酸残基、ｓは２又は３の整数、ｖ、ｗは互いに独立に１〜３の整数、Ｍ１はアルカリ金属又はアルカノールアミンを表す。］
で示されるアミドアミン型両性界面活性剤と、
一般式（２）
[Wherein R 1 CO represents a fatty acid residue having 6 to 22 carbon atoms, s represents an integer of 2 or 3, v and w each independently represent an integer of 1 to 3, and M 1 represents an alkali metal or an alkanolamine. ]
An amidoamine type amphoteric surfactant represented by
General formula (2)
[但し式中、Ｒ２ＣＯは炭素原子６〜２２個の脂肪酸残基を表し、Ｍ２は水素原子、アルカリ金属又はアルカノールアミンを表す。]
で示されるＮ−アシルグルタミン酸塩型アニオン性界面活性剤を含有し、
アミドアミン型両性界面活性剤とＮ−アシルグルタミン酸塩型アニオン性界面活性剤を純分換算１０〜２５％含有し、アミドアミン型両性界面活性剤とＮ−アシルグルタミン酸塩型アニオン性界面活性剤の比率が純分重量比で９：１〜５：５の範囲であり、ｐＨが７以下である染色毛髪用シャンプー組成物に関するものであり、
さらに、ノニオン界面活性剤成分として、ポリオキシエチレンセトステアリルヒドロキシミリスチレンエーテル及び／又はトリイソステアリン酸ポリオキシエチレンソルビタン（１６０E.O.）と一般式（３）
[Wherein, R 2 CO represents a fatty acid residue having 6 to 22 carbon atoms, and M 2 represents a hydrogen atom, an alkali metal or an alkanolamine. ]
An N-acyl glutamate type anionic surfactant represented by the formula:
Contains 10-25% of amidoamine type amphoteric surfactant and N-acylglutamate type anionic surfactant, and the ratio of amidoamine type amphoteric surfactant and N-acylglutamate type anionic surfactant is The present invention relates to a shampoo composition for dyeing hair having a pure weight ratio of 9: 1 to 5: 5 and a pH of 7 or less.
Further, as a nonionic surfactant component, polyoxyethylene cetostearyl hydroxymyristyl ether and / or polyoxyethylene sorbitan triisostearate (160E.O.) and general formula (3)
［式中Ｒ３ＣＯは炭素数１０〜１８の脂肪酸残基、Ｒ４は水素原子或いは一般式 [Wherein R 3 CO is a fatty acid residue having 10 to 18 carbon atoms, R 4 is a hydrogen atom or a general formula
で示される構造を有する。Ｒ５はメチル基又は水素原子を示し、ＡＯは炭素数２〜３のアルキレンオキシド基を表し、ｒは０〜５の整数である。］
で示されるアルカノールアミド型界面活性剤を含有する染色毛髪用シャンプー組成物に関するものである。
It has the structure shown by. R 5 represents a methyl group or a hydrogen atom, AO represents an alkylene oxide group having 2 to 3 carbon atoms, and r is an integer of 0 to 5. ]
It is related with the shampoo composition for dyeing hair containing the alkanolamide type | mold surfactant shown by these.
本発明の染色毛髪用シャンプー組成物は、クリアであり、適度な粘度を示し、低温安定性に優れ、染毛剤の色落ちに優れた効果を発揮する。 The shampoo composition for dyed hair of the present invention is clear, exhibits an appropriate viscosity, is excellent in low-temperature stability, and exhibits an excellent effect on discoloration of the hair dye.
本発明における第一成分は
一般式（１）
The first component in the present invention is represented by the general formula (1)
［式中Ｒ１ＣＯは炭素数６〜２２の脂肪酸残基、ｓは２又は３の整数、ｖ、ｗは互いに独立に１〜３の整数、Ｍ１はアルカリ金属又はアルカノールアミンを表す。］
で示されるアミドアミン型両性界面活性剤である。
[Wherein R 1 CO represents a fatty acid residue having 6 to 22 carbon atoms, s represents an integer of 2 or 3, v and w each independently represent an integer of 1 to 3, and M 1 represents an alkali metal or an alkanolamine. ]
Is an amidoamine type amphoteric surfactant.
アミドアミン型両性界面活性剤の好適例としては、例えばＮ−ラウロイル−Ｎ’−カルボキシメチル-Ｎ'−ヒドロキシエチルエチレンジアミンナトリウム、Ｎ−ミリストイル−Ｎ’−カルボキシメチル-Ｎ'−ヒドロキシエチルエチレンジアミンナトリウム、Ｎ−ヤシ脂肪酸−Ｎ’−カルボキシメチル-Ｎ'−ヒドロキシエチルエチレンジアミンナトリウム等が挙げられる。 Preferable examples of the amidoamine type amphoteric surfactant include, for example, N-lauroyl-N′-carboxymethyl-N′-hydroxyethylethylenediamine sodium, N-myristoyl-N′-carboxymethyl-N′-hydroxyethylethylenediamine sodium, N -Palm fatty acid-N'-carboxymethyl-N'-hydroxyethyl ethylenediamine sodium etc. are mentioned.
本発明の第二成分は一般式（２） The second component of the present invention is represented by the general formula (2)
[但し式中、Ｒ２ＣＯは炭素原子６〜２２個の脂肪酸残基を表し、Ｍ２は水素原子、アルカリ金属又はアルカノールアミンを表す。]
で示されるＮ−アシルグルタミン酸塩型アニオン性界面活性剤である。
[Wherein, R 2 CO represents a fatty acid residue having 6 to 22 carbon atoms, and M 2 represents a hydrogen atom, an alkali metal or an alkanolamine. ]
N-acyl glutamate type anionic surfactant represented by the formula:
Ｎ−アシルグルタミン酸塩型アニオン性界面活性剤の好適例としては、例えばＮ−ラウロイルアシルグルタミン酸モノナトリウム塩、Ｎ−椰子脂肪酸アシルグルタミン酸モノナトリウム塩、Ｎ−ラウロイルアシルグルタミン酸モノカリウム塩、Ｎ−ラウロイルアシルグルタミン酸モノトリエタノールアミン塩等が挙げられる。 Preferable examples of the N-acyl glutamate type anionic surfactant include, for example, N-lauroyl acyl glutamate monosodium salt, N-coconut fatty acid acyl glutamate monosodium salt, N-lauroyl acyl glutamate monopotassium salt, N-lauroyl acyl Examples include glutamic acid monotriethanolamine salt.
本発明において粘度調整及び起泡改善のために、ポリオキシエチレンセトステアリルヒドロキシミリスチレンエーテル及び／又はトリイソステアリン酸ポリオキシエチレンソルビタン（１６０E.O.）と一般式（３）で示されるアルカノールアミド型界面活性剤を併用して配合することができる。 In the present invention, in order to adjust viscosity and improve foaming, polyoxyethylene cetostearyl hydroxymyrstyrene ether and / or polyoxyethylene sorbitan triisostearate (160E.O.) and alkanolamide type represented by the general formula (3) A surfactant can be used in combination.
アルカノールアミド型界面活性剤は、一般式（３） The alkanolamide type surfactant has the general formula (3)
［式中Ｒ３ＣＯは炭素数１０〜１８の脂肪酸残基、Ｒ４は水素原子或いは一般式 [Wherein R 3 CO is a fatty acid residue having 10 to 18 carbon atoms, R 4 is a hydrogen atom or a general formula
で示される構造を有する。Ｒ５はメチル基乃至は水素原子を示し、ＡＯは炭素数２〜３のアルキレンオキシド基を表し、ｒは０〜５の整数である。］
で示される。
It has the structure shown by. R 5 represents a methyl group or a hydrogen atom, AO represents an alkylene oxide group having 2 to 3 carbon atoms, and r is an integer of 0 to 5. ]
Indicated by
一般式（３）で示されるアルカノールアミド型界面活性剤の好適例としては、例えばラウリン酸ジエタノールアミド、ミリスチン酸ジエタノールアミド、ヤシ脂肪酸ジエタノールアミド、ポリオキシエチレン（１）ヤシ脂肪酸モノエタノールアミド、ポリオキシプロピレン（１）ヤシ脂肪酸モノイソプロパノールアミド等が挙げられる。 Preferable examples of the alkanolamide surfactant represented by the general formula (3) include lauric acid diethanolamide, myristic acid diethanolamide, coconut fatty acid diethanolamide, polyoxyethylene (1) coconut fatty acid monoethanolamide, polyoxy Examples include propylene (1) coconut fatty acid monoisopropanolamide.
本発明シャンプー組成物においてはＮ−アシルグルタミン酸塩型アニオン性界面活性剤とアミドアミン型両性界面活性剤を合計で純分換算１０〜２５重量％含有する。より好ましくは１５〜２０重量％である。両者の総量が１０重量％未満では、起泡力、粘度等に問題が発生する可能性があり好ましくない。２５重量％を超えた場合は、液体状態を保てなくなる場合があり好ましくない。 In the shampoo composition of the present invention, the N-acylglutamate type anionic surfactant and the amidoamine type amphoteric surfactant are contained in a total amount of 10 to 25% by weight in terms of pure matter. More preferably, it is 15 to 20% by weight. If the total amount of both is less than 10% by weight, problems may occur in foaming power, viscosity, etc., which is not preferable. When it exceeds 25% by weight, the liquid state may not be maintained, which is not preferable.
本発明において、アミドアミン型の両性界面活性剤とＮ−アシルグルタミン酸塩型アニオン性界面活性剤の比率が純分重量比で９：１〜５：５の範囲であることが重要である。この範囲内にあることにより、染色毛に対する色落ち防止効果が最大になるのと同時に、ノニオン界面活性剤として、ポリオキシエチレンセトステアリルヒドロキシミリスチレンエーテル及び／又はトリイソステアリン酸ポリオキシエチレンソルビタン（１６０E.O.）と一般式（３）で示されるアルカノールアミド型界面活性剤を加えることにより、安定的に５００〜２０００ｍＰａｓの使用しやすい粘度をシャンプーに付与することが可能となる。これらのノニオン界面活性剤は、シャンプー組成物に０．５〜１０重量％の範囲で配合する。配合量は所望の粘度になるように調整するが、０．５重量％未満の配合量では、色落ち防止効果に影響はないが、粘度上昇はほとんどみられず好ましくない。また１０重量％を超えて配合すると、色落ち防止効果の低下が見られると同時に、シャンプー組成物の低温安定性が悪化する場合があり好ましくない。 In the present invention, it is important that the ratio of the amidoamine type amphoteric surfactant and the N-acyl glutamate type anionic surfactant is in the range of 9: 1 to 5: 5 in terms of pure weight ratio. By being in this range, the effect of preventing discoloration on the dyed hair is maximized, and at the same time, as nonionic surfactants, polyoxyethylene cetostearyl hydroxymyristyl ether and / or polyoxyethylene sorbitan triisostearate (160E .O.) And an alkanolamide-type surfactant represented by the general formula (3), it is possible to stably give an easily usable viscosity of 500 to 2000 mPas to the shampoo. These nonionic surfactants are blended in the shampoo composition in the range of 0.5 to 10% by weight. The blending amount is adjusted so as to have a desired viscosity. However, if the blending amount is less than 0.5% by weight, the effect of preventing color fading is not affected, but an increase in viscosity is hardly observed, which is not preferable. Moreover, when it mix | blends exceeding 10 weight%, while the fall of the color fading prevention effect is seen, the low temperature stability of a shampoo composition may deteriorate, and it is unpreferable.
本発明のシャンプー組成物のｐＨは７以下が好ましい。さらに好ましくは４.５〜６.５である。ｐＨが７より高いと、洗浄時の色落ち防止効果が得られない。ｐＨを調整に用いるｐＨ調整剤については特に限定されるものではないが、特にクエン酸、リンゴ酸、乳酸のようなヒドロキシカルボン酸、燐酸またはそれらのナトリウム塩、水酸化ナトリウム、トリエタノールアミンを用いることが好ましい。 The pH of the shampoo composition of the present invention is preferably 7 or less. More preferably, it is 4.5-6.5. If the pH is higher than 7, the effect of preventing color fading during washing cannot be obtained. The pH adjusting agent used for adjusting the pH is not particularly limited, but hydroxycarboxylic acids such as citric acid, malic acid, and lactic acid, phosphoric acid or their sodium salts, sodium hydroxide, and triethanolamine are particularly used. It is preferable.
本発明組成物には発明の効果を妨げない範囲で通常化粧品に用いられる他の成分を配合しても良い。通常化粧品に用いられる他の成分の好適例を示す。
カチオン化セルロース、カチオン化グァー等のコンディショニング剤。
メチルパラベン、プロピルパラベン、ブチルパラベン等の防腐剤。
塩化ベンザルコニウム，イソプロピルメチルフエノ−ル，レゾルシン，ジンクピリチオン，感光素１０１号，感光素２０１号，サリチル酸，サリチル酸ナトリウム，オクトピロツクス及びヒノキチオ−ル等の抗菌剤。
パラアミノ安息香酸、ホモメンチル−Ｎ−アセチルアントラニレ−ト等の紫外線吸収剤。
パントテン酸、アルギニン等の抗酸化剤。
グリチルリチン酸、アラントイン等の抗炎症剤。
アミノ変性シリコーン、ポリオキシアルキレン変性シリコーン、シリコーン油などのシリコーン誘導体。
エチレンジアミン四酢酸及びナトリウム塩、リン酸、クエン酸、アスコルビン酸、コハク酸、グルコン酸、ポリリン酸ナトリウム、メタリン酸ナトリウム等の金属封鎖剤。
茶エキス、アロエエキス、イチョウエキス、センブリエキス、ヨモギエキス、ニンニクエキス、オウゴンエキス、ローズマリーエキス、ヘチマエキス、胎盤抽出物、乳酸菌培養抽出物、海草エキス等の動植物抽出物。
色素、香料等があげられる。
You may mix | blend the other component normally used for cosmetics with this invention composition in the range which does not prevent the effect of invention. The suitable example of the other component normally used for cosmetics is shown.
Conditioning agents such as cationized cellulose and cationized guar.
Preservatives such as methylparaben, propylparaben and butylparaben.
Antibacterial agents such as benzalkonium chloride, isopropylmethylphenol, resorcin, zinc pyrithione, photosensitive element 101, photosensitive element 201, salicylic acid, sodium salicylate, octopirox and hinokitiol.
UV absorbers such as paraaminobenzoic acid and homomenthyl-N-acetylanthranylate.
Antioxidants such as pantothenic acid and arginine.
Anti-inflammatory agents such as glycyrrhizic acid and allantoin.
Silicone derivatives such as amino-modified silicone, polyoxyalkylene-modified silicone, and silicone oil.
Metal sequestering agents such as ethylenediaminetetraacetic acid and sodium salts, phosphoric acid, citric acid, ascorbic acid, succinic acid, gluconic acid, sodium polyphosphate and sodium metaphosphate.
Animal and plant extracts such as tea extract, aloe extract, ginkgo biloba extract, assembly extract, mugwort extract, garlic extract, rosemary extract, loofah extract, placenta extract, lactic acid bacteria culture extract, seaweed extract and the like.
Examples thereof include pigments and fragrances.
＜実施例１〜１０、比較例１〜５＞
次に本発明を実施例によりさらに詳細に説明する。実施例および比較例中の%は重量%を意味する。
<Examples 1 to 10, Comparative Examples 1 to 5>
Next, the present invention will be described in more detail with reference to examples. “%” In Examples and Comparative Examples means “% by weight”.
下記表１及び表２に従ってサンプル調整とその性能評価を行った。 Sample preparation and performance evaluation were performed according to Table 1 and Table 2 below.
各サンプルは表中の割合で各成分を攪拌装置の付いた容器に入れ、８０度まで攪拌昇温し、１０分熟成後、４０℃まで各サンプル共同じ攪拌速度を与えながら冷却してサンプルとした。
各種サンプルに対して以下の方法で低温安定性、粘度測定、色落ち防止効果の各種評価を行った。
Each sample is put in a container equipped with a stirrer at the ratio shown in the table, stirred and heated to 80 degrees, aged for 10 minutes, cooled to 40 ° C while giving the same stirring speed to each sample, did.
Various evaluations of low temperature stability, viscosity measurement, and color fading prevention effect were performed on the various samples by the following methods.
低温安定性
−５℃で１週間保存後の性状について測定、観察した
Low temperature stability- measured and observed for properties after storage for 1 week at 5 ° C
粘度測定
粘度はＢ型粘度計で測定した（東機産業（株）、ＴＶ−１０型粘度計、２５℃で測定）。
Viscosity measurement Viscosity was measured with a B-type viscometer (Toki Sangyo Co., Ltd., TV-10 viscometer, measured at 25C).
色落ち防止効果
白髪毛束（（株）ビューラックス製BM-W、長さ10cm、重さ1g）をPOE(3)ラウリルエーテル硫酸ナトリウム（花王（株）製、エマール20C）の2%水溶液で十分に洗浄した後、ヘアドライヤーで乾燥した。乾燥後の毛束を市販の染毛剤（（株）資生堂製、商品名：マシェリ ラスティングヘアカラー、色：シアーアッシュまたはスタイリッシュレッド）で、商品に指定されている方法で染色した後、十分に水洗し、ヘアドライヤーで乾燥した。容量100mlのサンプルビンに各シャンプー２．５ｇを蒸留水で100mlに希釈した溶液を注ぎ、乾燥後の染色済み毛束を詰めて、蓋で密閉した後、室温で７日震盪した。震盪終了後、蓋を開け、サンプルビン中の染色済み毛束を取り出した後、十分に水洗し、ヘアドライヤーで乾燥した。乾燥後の染色済み毛束を色差計（日本電色工業（株）製、Spectrophotometer SE 2000）で色差（ΔE）を測定した。ΔEの数値が小さいほど色落ち防止効果が高いと判断される。
Anti-fading effect White hair bundle (BM-W, manufactured by Beaulux Co., Ltd., 10cm in length, 1g in weight) with a 2% aqueous solution of POE (3) sodium lauryl ether sulfate (Eoal 20C, manufactured by Kao Corporation) After thoroughly washing, it was dried with a hair dryer. After drying the hair bundle with a commercially available hair dye (made by Shiseido Co., Ltd., trade name: masheri lasting hair color, color: sheer ash or stylish red) It was washed with water and dried with a hair dryer. A solution obtained by diluting 2.5 g of each shampoo to 100 ml with distilled water was poured into a sample bottle with a capacity of 100 ml, and the dyed hair bundle after drying was packed, sealed with a lid, and shaken at room temperature for 7 days. After the shaking, the lid was opened, the dyed hair bundle in the sample bottle was taken out, washed thoroughly with water and dried with a hair dryer. The color difference (ΔE) of the dyed hair bundle after drying was measured with a color difference meter (Nippon Denshoku Industries Co., Ltd., Spectrophotometer SE 2000). It is determined that the smaller the ΔE value, the higher the color fading prevention effect.
（注１）川研ファインケミカル（株）製、Ｎ−ヤシ脂肪酸−Ｎ’−カルボキシメチル-Ｎ'−ヒドロキシエチルエチレンジアミンナトリウム（脱塩品）、「ソフタゾリンＣＨ−Ｒ」
（注２）ライオン（株）製、アクリル系カチオン、「リポフローＭＮ」
（注３）東邦化学工業（株）製、カチオン化セルロース、「カチナールＨＣ−１００」
(Note 1) N-coconut fatty acid-N'-carboxymethyl-N'-hydroxyethylethylenediamine sodium (desalted product), "Softazoline CH-R", manufactured by Kawaken Fine Chemical Co., Ltd.
(Note 2) Made by Lion Co., Ltd., acrylic cation, “Lipoflow MN”
(Note 3) Toho Chemical Industries, Ltd., cationized cellulose, “Kachinar HC-100”
比較例５と他のサンプルの色落ち防止効果を比較すると、ラウロイルグルタミン酸ＴＥＡ塩と本発明によるアミドアミン型両性界面活性剤の組み合わせは色落ち防止効果に優れることが分かる。更に、実施例１〜３と比較例１〜４の色落ち防止効果の数値より、ラウロイルグルタミン酸ＴＥＡ塩と本発明によるアミドアミン型両性界面活性剤を組み合わせることにより、色落ち防止効果に相乗効果が認められ、特に本発明によるアミドアミン型両性界面活性剤とラウロイルグルタミン酸ＴＥＡ塩との混合比が９：１〜５：５の時、色落ち防止効果が強くなることが分かる。 Comparing the color fading prevention effect of Comparative Example 5 with other samples, it can be seen that the combination of lauroyl glutamic acid TEA salt and the amidoamine type amphoteric surfactant according to the present invention is excellent in the color fading prevention effect. Furthermore, from the numerical values of the color fading prevention effect of Examples 1 to 3 and Comparative Examples 1 to 4, a synergistic effect is observed in the color fading prevention effect by combining lauroyl glutamic acid TEA salt and the amidoamine type amphoteric surfactant according to the present invention. In particular, it can be seen that when the mixing ratio of the amidoamine type amphoteric surfactant according to the present invention and the lauroylglutamic acid TEA salt is 9: 1 to 5: 5, the color fading prevention effect is enhanced.
（注１）川研ファインケミカル（株）製、Ｎ−ヤシ脂肪酸−Ｎ’−カルボキシメチル-Ｎ'−ヒドロキシエチルエチレンジアミンナトリウム（脱塩品）、「ソフタゾリンＣＨ−Ｒ」
（注３）東邦化学工業（株）製、アクリル系カチオン、「カチナールＨＣ−１００」
（注４）川研ファインケミカル（株）製、ラウリン酸ジエタノールアミド、「アミゾールＬＤＥ」
（注５）川研ファインケミカル（株）製、ヤシ脂肪酸ジエタノールアミド、「アミゾールＣＤＥ」
（注６）川研ファインケミカル（株）製、ＰＯＰ（１）ヤシ脂肪酸モノイソプロパノールアミド、「アゼット１ＰＣ」
（注７）川研ファインケミカル（株）製、ヤシ脂肪酸モノエタノールアミド、「アゾールＣＭＥ」
（注８）ライオン（株）製、ポリオキシエチレンセトステアリルヒドロキシミリスチレンエーテル、「エルファコスGT282S」
（注９）花王（株）製、トリイソステアリン酸ポリオキシエチレンソルビタン（１６０E.O.）、「レオドールTW-IS399C」
(Note 1) N-coconut fatty acid-N'-carboxymethyl-N'-hydroxyethylethylenediamine sodium (desalted product), "Softazoline CH-R", manufactured by Kawaken Fine Chemical Co., Ltd.
(Note 3) Toho Chemical Industries, Ltd., acrylic cation, “Kachinar HC-100”
(Note 4) Kawaken Fine Chemical Co., Ltd., lauric acid diethanolamide, “Amizole LDE”
(Note 5) Kawaken Fine Chemical Co., Ltd., palm fatty acid diethanolamide, “Amizole CDE”
(Note 6) Made by Kawaken Fine Chemical Co., Ltd., POP (1) Palm fatty acid monoisopropanolamide, “AZET 1PC”
(Note 7) Made by Kawaken Fine Chemical Co., Ltd., palm fatty acid monoethanolamide, “Azole CME”
(Note 8) Polyoxyethylene cetostearyl hydroxymyristyl ether, “Lfacos GT282S”, manufactured by Lion Corporation
(Note 9) manufactured by Kao Corporation, polyisoethylene stearic acid polyoxyethylene sorbitan (160E.O.), “Leodol TW-IS399C”
表２において、表１の実験群で最も色落ち防止効果の優れたラウロイルグルタミン酸塩と特定のアミドアミン型両性の組み合わせを重量比率で０．２２：０．７８で一定とし、各種ノニオン界面活性剤を用いて増粘性を確認した。どのサンプルも色落ち防止効果が認められ、本発明のアミドアミン両性界面活性剤とラウロイルグルタミン酸塩との混合比が９：１〜５：５の時発生する色落ち防止効果は、ノニオン性界面活性剤の添加によって大きく変動しないことが分かる。 In Table 2, the combination of lauroyl glutamate and the specific amidoamine type amphoteric acid having the most excellent anti-fading effect in the experimental group of Table 1 is constant at a weight ratio of 0.22: 0.78, and various nonionic surfactants are used. Used to confirm the thickening. The anti-fading effect is recognized in all samples, and the anti-fading effect that occurs when the mixing ratio of the amidoamine amphoteric surfactant of the present invention to lauroyl glutamate is 9: 1 to 5: 5 is a nonionic surfactant. It can be seen that there is no significant variation with the addition of.
更にシャンプー組成物として低温安定性に優れ使用しやすい５００mPa・s以上の粘度を選る為には、分子量の小さいノニオン性界面活性剤だけではなくポリオキシエチレンセトステアリルヒドロキシミリスチレンエーテル及び／又はトリイソステアリン酸ポリオキシエチレンソルビタン（１６０E.O.）とノニオン界面活性剤を併用することが好ましいことが分かる。 Furthermore, in order to select a viscosity of 500 mPa · s or more which is excellent in low-temperature stability and easy to use as a shampoo composition, not only a nonionic surfactant having a low molecular weight but also polyoxyethylene cetostearyl hydroxymyrstyrene ether and / or It can be seen that it is preferable to use polyoxyethylene sorbitan isostearate (160E.O.) and a nonionic surfactant in combination.
本発明の染色毛髪用シャンプー組成物は、クリアであり、適度な粘度を示し、低温安定性に優れ、染毛剤の色落ち防止に優れた効果を発揮し有用である。 The shampoo composition for dyed hair of the present invention is clear, exhibits an appropriate viscosity, is excellent in low-temperature stability, and exhibits an effect of preventing discoloration of a hair dye and is useful.
Claims (2)
で示されるアミドアミン型両性界面活性剤と、
一般式（２）
で示されるＮ−アシルグルタミン酸塩型アニオン性界面活性剤を含有し、
アミドアミン型両性界面活性剤とＮ−アシルグルタミン酸塩型アニオン性界面活性剤を純分換算１０〜２５％含有し、アミドアミン型両性界面活性剤とＮ−アシルグルタミン酸塩型アニオン性界面活性剤の比率が純分重量比で９：１〜５：５の範囲であり、ｐＨが７以下である染色毛髪用シャンプー組成物。 General formula (1)
An amidoamine type amphoteric surfactant represented by
General formula (2)
An N-acyl glutamate type anionic surfactant represented by the formula:
Contains 10-25% of amidoamine type amphoteric surfactant and N-acylglutamate type anionic surfactant, and the ratio of amidoamine type amphoteric surfactant and N-acylglutamate type anionic surfactant is A shampoo composition for dyeing hair having a pure weight ratio of 9: 1 to 5: 5 and a pH of 7 or less.
で示されるアルカノールアミド型界面活性剤を含有する請求項１記載の染色毛髪用シャンプー組成物。 Further, as a nonionic surfactant component, polyoxyethylene cetostearyl hydroxymyristyl ether and / or polyoxyethylene sorbitan triisostearate (160E.O.) and general formula (3)
The shampoo composition for dyeing hair according to claim 1, comprising an alkanolamide-type surfactant represented by the formula:
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| JP2004022710A JP2005213209A (en) | 2004-01-30 | 2004-01-30 | Shampoo composition for dyed hair |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005255777A (en) * | 2004-03-10 | 2005-09-22 | New Japan Chem Co Ltd | Thickener composition, method for producing the same, and method for thickening by using the same |
| JP2011140464A (en) * | 2010-01-07 | 2011-07-21 | Kao Corp | Detergent contained in foamer container |
| WO2012117828A1 (en) * | 2011-02-28 | 2012-09-07 | ライオン株式会社 | Cleaning agent composition |
| JP2012523465A (en) * | 2009-04-09 | 2012-10-04 | コグニス・アイピー・マネージメント・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツング | Isosorbide monoester and its use in household applications |
-
2004
- 2004-01-30 JP JP2004022710A patent/JP2005213209A/en active Pending
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005255777A (en) * | 2004-03-10 | 2005-09-22 | New Japan Chem Co Ltd | Thickener composition, method for producing the same, and method for thickening by using the same |
| JP2012523465A (en) * | 2009-04-09 | 2012-10-04 | コグニス・アイピー・マネージメント・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツング | Isosorbide monoester and its use in household applications |
| JP2011140464A (en) * | 2010-01-07 | 2011-07-21 | Kao Corp | Detergent contained in foamer container |
| WO2012117828A1 (en) * | 2011-02-28 | 2012-09-07 | ライオン株式会社 | Cleaning agent composition |
| JP2012180384A (en) * | 2011-02-28 | 2012-09-20 | Lion Corp | Cleanser composition |
| KR101858291B1 (en) * | 2011-02-28 | 2018-05-15 | 라이온 가부시키가이샤 | Cleaning agent composition |
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