JP2005314358A - Make up remover composition - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To obtain a make up remover composition having good properties in use and a good feeling use, showing good make up removal even against a make up cosmetic having a high water resistance and oil resistance and showing a high make up maintenance, e.g. the make up cosmetic containing a fluorine compound. <P>SOLUTION: This make up remover composition contains (A) a silicone polymer having a specific 3-dimensional crosslinking structure and (B) an organopolysiloxane containing a fluoroalkyl group, and further the make up remover composition contains (C) vaporizable liquid oil. <P>COPYRIGHT: (C)2006,JPO&NCIPI

Description

  The present invention relates to a makeup remover composition, and more specifically, it contains a silicone polymer having a specific three-dimensional cross-linked structure and a fluoroalkyl group-containing organopolysiloxane, and has high water resistance and oil resistance and is difficult to drop. Makeup cosmetics also relate to a makeup remover composition that can be removed smoothly.

  Various functional materials are applied to make-up cosmetics in order to improve the longevity of makeup. Specifically, makeup cosmetics in which a silicone compound having high water resistance is blended as a part of a powder surface treatment agent or oil, or a fluorine compound having high oil resistance is blended effectively. There are also many. On the other hand, cleansing compositions composed of ethylene oxide-added polypropylene glycol surfactants and imidazolinium betaines, which are commonly used as cleaning agents, spread the makeup cosmetics to spread around when wiped off. There is a problem in that the usability is poor, and especially in the makeup cosmetics with a long makeup, the makeup cosmetics themselves are poorly dropped. Therefore, as shown in the following documents (see Patent Documents 1 to 6), surfactants such as fatty acid monoethanolamide surfactants, dialkyl phosphates, ethylene oxide-added polypropylene glycol surfactants, oils and silicones The combination of oil has been used to improve make-up cosmetics (hereinafter sometimes referred to simply as “make-up removal”) and improved usability, but it is a fluorine compound with particularly high water and oil repellency. In regard to cosmetics with high water resistance and oil resistance blended with, the makeup removal and usability were not always satisfactory.

Japanese Patent Application No. 6-332522 Japanese Patent Application No. 7-218220 Japanese Patent Application No. 7-341008 Japanese Patent Application No. 7-343198 Japanese Patent Application No. 9-126269 Japanese Patent Application No. 9-355834

  Accordingly, the object of the present invention is to provide good makeup removal and use even for makeup cosmetics having high water resistance and oil resistance and having a long makeup, for example, makeup cosmetics containing a fluorine compound. An object of the present invention is to provide a makeup remover composition having good properties and usability.

  In view of the above problems, the present inventors have conducted extensive research, and as a result, a makeup remover composition containing a silicone polymer having a specific three-dimensional crosslinked structure and a fluoroalkyl group-containing organopolysiloxane has an appropriate viscosity. It has been found that it has excellent usability, has high water resistance and oil resistance, and has high affinity with makeup cosmetics that are difficult to be removed, and can be removed smoothly. Furthermore, it has been found that by using a volatile liquid oil in combination, an excellent makeup remover composition with reduced oiliness and stickiness can be obtained, and the present invention has been completed.

That is, the present invention includes the following components (A) to (B):
(A) Organohydrogenpolysiloxane represented by the following general formula (1) R ¹ _a H _b SiO _{(4-ab) / 2} (1)
And organopolysiloxane R ¹ _c R ² _d SiO _{(4-cd) / 2} (2) represented by the following general formula (2):
A silicone having a three-dimensional cross-linking structure, characterized in that it can contain penta-3,3,3-trifluoropropylpentamethylcyclopentasiloxane that is insoluble in an organic solvent and has the same mass or more as its own weight. Polymers wherein R ¹ may be the same or different and each is a substituted or unsubstituted monovalent hydrocarbon group having 1 to 20 carbon atoms and having no aliphatic unsaturated bond, 11 to 60 mol% is a monovalent hydrocarbon group which is a fluorine-substituted monovalent hydrocarbon group, R ² is a monovalent hydrocarbon group having 2 to 10 carbon atoms having a terminal vinyl group, and a is 1.0 2.3, b is 0.001 to 1.0, c is 1.0 to 2.3, d is 0.001 to 1.0, and 1.5 ≦ a + b ≦ 2.6. 5 ≦ c + d ≦ 2.6 is satisfied. ]
(B) The present invention relates to a makeup remover composition containing a fluoroalkyl group-containing organopolysiloxane. Moreover, the component (B) relates to a makeup remover composition that is a fluoroalkyl group-containing organopolysiloxane represented by the general formula (3). Furthermore, the present invention relates to a makeup remover composition containing component (C) volatile liquid oil, and further, light liquid isoparaffin, octamethylcyclohexane, wherein component (C) is selected from isohexadecane, isododecane and mixtures thereof. Organopolysiloxane selected from cyclic dimethylpolysiloxane selected from tetrasiloxane, decamethylcyclopentasiloxane and dodecamethylcyclohexasiloxane, octamethyltrisiloxane, decamethyltetrasiloxane, dodecamethylpentasiloxane, heptamethyloctyltrisiloxane It is related with the makeup remover composition which is 1 type, or 2 or more types.

  The makeup remover composition of the present invention has a high affinity with a makeup cosmetic that is highly resistant to water and oil, and can be removed smoothly, and is easy to take on the hand. It also has good usability and usability, such as reduced oiliness and stickiness.

Hereinafter, the present invention will be described in detail.
The specific silicone polymer of component (A) used in the present invention is compatible with makeup cosmetics with high water resistance and oil resistance, but has a poor affinity with general oils used in cosmetics. In order to stably blend the fluoroalkyl group-containing organopolysiloxane of component (B), which is difficult to be stably blended into cosmetics, into makeup cosmetics, and to facilitate the production of cosmetics containing component (B) Further, it is used for the purpose of improving the feeling of use, such as controlling the spread of spread when applied to the skin, and suppressing the oiliness and stickiness. Component (A) is an organohydrogenpolysiloxane represented by the following general formula (1) R ¹ _a H _b SiO _{(4-ab) / 2} (1)
And organopolysiloxane R ¹ _c R ² _d SiO _{(4-cd) / 2} (2) represented by the following general formula (2):
A silicone having a three-dimensional crosslinked structure, characterized in that it can contain penta-3,3,3-trifluoropropylpentamethylcyclopentasiloxane that is insoluble in an organic solvent and has the same mass or more as its own weight. A polymer is shown. [In the formula, R ¹ may be the same or different and each represents a substituted or unsubstituted monovalent hydrocarbon group having 1 to 20 carbon atoms and having no aliphatic unsaturated bond, 60 mol% is a monovalent hydrocarbon group which is a fluorine-substituted monovalent hydrocarbon group, R ² is a monovalent hydrocarbon group having 2 to 10 carbon atoms having a terminal vinyl group, and a is from 1.0 to 2 .3, b is 0.001 to 1.0, c is 1.0 to 2.3, d is 0.001 to 1.0, and 1.5 ≦ a + b ≦ 2.6, 1.5 ≦ c + d ≦ 2.6 is satisfied. ]
Specific examples of R ¹ include methyl groups, ethyl groups, propyl groups, butyl groups, pentyl groups, hexyl groups, heptyl groups, octyl groups, nonyl groups, decyl groups and other alkyl groups, cyclopentyl groups, cyclohexyl groups, and the like. Examples thereof include aryl groups such as saturated alicyclic hydrocarbon groups, phenyl groups, and tolyl groups, fluorine-substituted alkyl groups such as trifluoropropyl groups, nonafluorohexyl groups, and heptadecylfluorodecyl groups. And trifluoropropyl groups are preferred.

It is essential that 11 to 60 mol% of the organic group R ¹ is a fluorine-substituted monovalent hydrocarbon group. If it is less than 11 mol%, the affinity of the component (B) for the fluoroalkyl group-containing organopolysiloxane becomes poor, and if it exceeds 60 mol%, it is difficult to produce the organohydrogenpolysiloxane represented by the general formula (1). become. A preferred range is 20 to 50 mol%.

Specific examples of R ² include a vinyl group, an allyl group, a butenyl group, a pentenyl group, a hexenyl group, a heptenyl group, an octenyl group, a nonenyl group, and a decenyl group, and a vinyl group and an allyl group are particularly desirable.

  a represents 1.0 to 2.3, and when a is smaller than 1.0, the degree of crosslinking becomes too high, and therefore penta-3,3,3-trifluoropropylpentamethylcyclopentasiloxane having the same mass or more as its own weight is required. If it is not greater than 2.3, the degree of crosslinking is too low, and it is difficult to form a three-dimensional crosslinked structure. A more preferable range is 1.2 to 2.1.

  b is 0.001 to 1.0, and if b is less than 0.001, the degree of crosslinking becomes too low, so that it is difficult to form a three-dimensional crosslinked structure, and if it exceeds 1.0, the degree of crosslinking increases. Therefore, it cannot contain penta-3,3,3-trifluoropropylpentamethylcyclopentasiloxane having the same mass or more as its own weight. A more preferable range is 0.005 to 0.5.

  c represents 1.0 to 2.3, and when c is smaller than 1.0, the degree of crosslinking becomes too high, so that penta-3,3,3-trifluoropropylpentamethylcyclopentasiloxane having the same mass or more as its own weight is added. If it is greater than 2.3, the degree of cross-linking is too low, making it difficult to form a three-dimensional cross-linked structure. A more preferable range is 1.2 to 2.1.

  d is 0.001 to 1.0. If d is less than 0.001, the degree of crosslinking is too low, so that it is difficult to form a three-dimensional crosslinked structure. If d exceeds 1.0, the degree of crosslinking is increased. Therefore, it cannot contain penta-3,3,3-trifluoropropylpentamethylcyclopentasiloxane having the same mass or more as its own weight. A more preferable range is 0.005 to 0.5.

  The organohydrogenpolysiloxane represented by the general formula (1) and the organopolysiloxane represented by the general formula (2) may be linear, branched or cyclic, but the polymerization reaction proceeds smoothly. For this purpose, it is preferably linear or mainly linear and partially containing branched units.

  In order to obtain the specific silicone polymer of the component (A) used in the present invention, an organohydrogenpolysiloxane represented by the general formula (1) and an organopolysiloxane represented by the general formula (2) (For example, chloroplatinic acid, alcohol-modified chloroplatinic acid, chloroplatinic acid-vinylsiloxane complex, etc.) or a rhodium compound may be reacted at room temperature or under heating (about 50 ° C. to 120 ° C.). When carrying out the reaction, it may be carried out without a solvent, or an organic solvent may be used if necessary. Specific examples of the organic solvent include aliphatic alcohols such as methanol, ethanol, 2-propanol and butanol, aromatic hydrocarbons such as benzene, toluene and xylene, aliphatics such as n-pentane, n-hexane and cyclohexane or Examples thereof include alicyclic hydrocarbons, halogenated hydrocarbons such as dichloromethane, chloroform and carbon tetrachloride, and ketone solvents such as acetone and methyl ethyl ketone. However, for use as a cosmetic application, no solvent, ethanol, or 2-propanol is preferable.

  The specific silicone polymer of component (A) has a three-dimensional crosslinked structure and is insoluble in organic solvents. The organic solvent mentioned here is an aliphatic organic solvent such as linear or branched pentane, hexane, dodecane, hexadecane or octadecane, an aromatic organic solvent such as benzene, toluene or xylene, methanol, ethanol or propanol. In addition to various organic solvents such as alcohol organic solvents such as butanol, hexanol and decanol, halogenated organic solvents such as chloroform and carbon tetrachloride, ketone organic solvents such as acetone and methyl ethyl ketone, low viscosity dimethylpolysiloxane, methyl Examples thereof include silicone compounds such as phenyl polysiloxane and cyclic dimethyl polysiloxane. In addition, the specific silicone polymer of component (A) used in the present invention is characterized in that it may contain penta-3,3,3-trifluoropropylpentamethylcyclopentasiloxane having the same mass or more as its own weight.

  The specific silicone polymer of component (A) can be used singly or in combination of two or more depending on the purpose, and the blending amount is not particularly limited, but is 0.01 to 40 mass in the makeup remover composition. % (Hereinafter referred to as “%”) is preferable, and 0.1 to 30% is more preferable. Within this range, the makeup remover containing the component (B) can be easily manufactured and can be stably blended, and the makeup has excellent usability such as control of spread and spread, suppression of oiliness and stickiness. This is preferable because an up remover composition can be obtained.

  The fluoroalkyl group-containing organopolysiloxane of component (B) used in the present invention is used to improve the makeup removal effect because it is well-suited to makeup cosmetics with high water resistance and oil resistance as described above. It is done. The component (B) fluoroalkyl group-containing organopolysiloxane is an organopolysiloxane having at least one fluoroalkyl group in the molecule as an organic group. Specific examples of the fluoroalkyl group include fluorine-substituted alkyl groups such as a trifluoropropyl group, a nonafluorohexyl group, and a heptadecylfluorodecyl group, with a trifluoropropyl group being particularly preferred.

The fluoroalkyl group-containing organopolysiloxane of the component (B) is preferably a fluoroalkyl group-containing organopolysiloxane having a viscosity at 25 ° C. of 200 mm ² / s or less, particularly preferably 20 to 180 mm ² / s. If it is this range, while being good in affinity with the specific silicone polymer of a component (A), while being familiar with the makeup cosmetics adhering to skin, it will become much better, and further makeup It is preferable because improvement in dropping is obtained.

  The fluoroalkyl group-containing organopolysiloxane of component (B) may be linear, branched or cyclic, but in general, from the viscosity and affinity with the specific silicone polymer of component (A) A fluoroalkyl group-containing organopolysiloxane represented by the formula (3) is particularly preferred.

[In formula, p is an integer of 4-6. ]

  Specifically, as a linear thing, FL-100, X-22-819, X-22-820, X-22-821, X-22-822 (made by Shin-Etsu Chemical Co., Ltd.), FS-1265 (Toray Dow Corning). Examples of cyclic compounds include those described in JP-A-09-268110. For example, trifluoropropylcyclotetrasiloxane / trifluoropropylcyclopentasiloxane (KF) under the INCI name (International Nomenclature Cosmetic Labeling Names). -5002: manufactured by Shin-Etsu Chemical Co., Ltd.).

  In the present invention, the specific silicone polymer of component (A) can be kneaded with the fluoroalkyl group-containing organopolysiloxane of component (B) to obtain a paste-like composition. By preparing a composition in which the component (A) and the component (B) are kneaded in advance, the handling during the production of the makeup cosmetic is improved. As a result, the above-described makeup removal effect, usability, and feeling of use are improved. It is preferable because a stable makeup remover composition is obtained.

  In order to obtain the paste-like composition, a normal stirrer may be used, but it is preferable to perform a kneading treatment under a shearing force. This is because a specific silicone polymer has a three-dimensional crosslinked structure insoluble in an organic solvent, so that it does not dissolve uniformly in the fluoroalkyl group-containing organopolysiloxane of component (B), and has sufficient dispersibility under shear force. This is because a paste-like composition having a smooth appearance can be obtained. The kneading treatment can be performed with, for example, a three-roll, two-roll, sand grinder, colloid mill, high-viscosity mixer, Gaurin homogenizer, disper, etc., preferably a method using a three-roll, high-viscosity mixer, and disper. preferable.

  The blending amount of the obtained paste-like composition in the makeup remover composition is usually 0.1 to 90%, preferably 1 to 70%. If it is this range, the makeup remover composition which is excellent in the effect of makeup removal, and is excellent in usability and stability can be obtained. Moreover, when manufacturing a paste-form composition, 5: 95-50: 50 is preferable and, as for mass ratio of a component (A) and a component (B), More preferably, it is 10: 90-30: 70. If it is this range, the stability and usability of a makeup remover composition will improve more.

  The makeup remover composition of the present invention may further contain component (C) volatile liquid oil. The volatile liquid oil of component (C) used in the present invention has a low viscosity and is well-suited to makeup cosmetics. Further, it is effectively used to relieve oiliness and stickiness after use. The volatile liquid oil of component (C) used in the present invention is not particularly limited as long as it is used in cosmetics, but specific silicone polymer of component (A) and fluoroalkyl group-containing organopolypropylene of component (B). In consideration of the suitability for blending with siloxane, a cyclic dimethylpolysiloxane selected from light liquid isoparaffin, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane and dodecamethylcyclohexasiloxane selected from isohexadecane, isododecane and mixtures thereof. Organopolysiloxanes selected from siloxane, octamethyltrisiloxane, decamethyltetrasiloxane, dodecamethylpentasiloxane, and heptamethyloctyltrisiloxane are preferred. These volatile liquid oils can be used singly or in combination. In addition, the blending amount of these volatile liquid oils into the makeup remover composition is usually 0.01 to 40.0%, and it is easy to control oiliness, stickiness, stability and viscosity. From the above, it is preferably 0.1 to 30.0%.

  In the makeup remover composition of the present invention, in addition to the above-mentioned components, components that are used in ordinary cosmetics within a range that does not interfere with the effects of the present invention, water, alcohols, water-soluble polymers, film forming agents, Surfactant, powder, resin, UV absorber, moisturizer, antiseptic, antibacterial agent, fragrance, salt, antioxidant, pH adjuster, chelating agent, refreshing agent, anti-inflammatory agent, skin cleansing agent (whitening agent Cell activators, skin roughness improving agents, blood circulation promoters, skin astringents, antiseborrheic agents, etc.), vitamins, amino acids, nucleic acids, hormones, inclusion compounds and the like can be added.

The makeup remover composition of the present invention can be appropriately selected from liquid, emulsion, solid, paste, gel and other forms, and can be used with any method of use such as wiping or washing off. It can also be used for removers.
The makeup remover composition of the present invention is produced by a method for producing a normal cosmetic, and the production method is not limited.

  Hereinafter, although a synthesis example and the Example which applied it are given and demonstrated regarding this invention, this invention is not limited at all by these.

Synthesis Example 1 Silicone Polymer 1
In the reactor, the following average composition formula (4)

118 parts by weight of an organohydrogenpolysiloxane represented by the following average composition formula (5)

175 parts by weight of a vinyl-modified organopolysiloxane represented by the following formula was added, 0.1 part by weight of a divinyltetramethyldisiloxane solution containing 2% by weight of chloroplatinic acid was added, and the internal temperature was maintained at 70 to 80 ° C., followed by stirring for 2 hours. An elastic silicone polymer 1 was obtained.

Synthesis Example 2 Silicone polymer 2
In the reactor, the following average composition formula (6)

567 parts by weight of the organohydrogenpolysiloxane represented by the formula:

955 parts by weight of a vinyl-modified organopolysiloxane represented by the formula (1) was added, 0.1 part by weight of a divinyltetramethyldisiloxane solution containing 2% by weight of chloroplatinic acid was added, and the internal temperature was maintained at 70 to 80 ° C. under reduced pressure. The mixture was stirred for a time to obtain a silicone polymer 2 having elasticity.

Production Example 1 Preparation of Paste Composition 1 20 parts by weight of the silicone polymer 1 of Synthesis Example 1 and tetra-3,3,3-trifluoropropyltetramethylcyclotetrasiloxane / penta-3,3,3-tri A semitransparent paste-like composition having thixotropic properties by mixing 80 parts by weight of a fluoropropylpentamethylcyclopentasiloxane mixture (1/1 weight ratio, viscosity 60 mm ² / s) and sufficiently kneading with three rolls. 1 was obtained. This pasty composition 1 was excellent in stability, and separation of oily components and drainage were not observed even after one month at 50 ° C.

Production Example 2 Preparation of Pasty Composition 2 30 parts by weight of the silicone polymer 2 of Synthesis Example 2 and the following average composition formula (8)

A semitransparent paste-like composition 2 having thixotropy is prepared by mixing 70 parts by weight of a fluoroallyl group-containing organopolysiloxane oil (viscosity 150 mm ² / s) represented by Obtained. This pasty composition 2 was excellent in stability, and separation of oily components and drainage were not observed even after one month at 50 ° C.

Examples 1-3 and Comparative Examples 1-3 Makeup remover (wipe-off type)
A makeup remover composition having the composition shown in Table 1 was prepared, and the feeling of use and usability were evaluated according to the following methods.

(Evaluation methods)
A professional panel of 20 women conducts a usage test and is quick to apply with makeup cosmetics (commercially available long-lasting lipstick), easy to remove, lack of oiliness when used, and sticky to the back skin Each panel member gave an evaluation based on the following absolute evaluation and assigned a score, and the average value was calculated from the total score of all the panel members for each sample, and judged according to the following four-step criteria. The obtained results are also shown in Table 1.

(Absolute evaluation)
(Score): (Evaluation)
6: Very good 5: Good 4: Somewhat good 3: Normal 2: Somewhat bad 1: Bad 0: Very bad (4 step criteria)
(Average score): (Judgment)
More than 5 points: Very good: ◎
3 points to 5 points or less: Good: ○
More than 1 point and 3 points or less: Somewhat bad: △
1 point or less: Defect: ×

(Stability evaluation)
Each sample was set at 40 ° C., and the appearance after one month was visually observed and evaluated.
(Criteria)
○: No change in appearance Δ: Slight change in texture and appearance
X: Separation and aggregation are clearly observed.

(Production method)
A: Components 1 to 6 are mixed uniformly.
B: Components 7 to 10 are added to A and mixed uniformly.

  As is apparent from the results in Table 1, the wipe-off type makeup remover (Examples 1 to 3) of the present invention has a high water resistance and oil resistance and is easy to remove with the long lasting lipstick, and the lipstick is also removed. It was excellent in usability and usability, such as no oiliness during use and no skin stickiness after wiping. On the other hand, Comparative Examples 1 to 3 in which the specific silicone polymer of component (A) and the fluoroalkyl group-containing organopolysiloxane of component (B) are not used are inferior in all the evaluation items. It was inferior to ease. Further, in Comparative Example 3 in which perfluoropolyether which is a fluorine compound was added, the temporal stability was not good.

Examples 4 to 5 and Comparative Examples 4 to 5 Makeup remover (wash-out type)
A wash-off type makeup remover having the composition shown in Table 2 was prepared, and a use test was conducted by a professional panel of 20 women according to the evaluation method described above. / O Liquid Foundation) was evaluated according to the following methods for ease of removal, ease of removal, lack of oiliness during use, lack of oiliness during use, and non-stickiness of the back skin. The stability evaluation was also performed according to the aforementioned criteria. The obtained results are also shown in Table 2.

(Production method)
A: Components 1 to 3 and components 7 and 8 are mixed uniformly.
B: Components 4 to 6 and components 9 to 11 are mixed uniformly.
C: A and B are mixed uniformly.

  As is apparent from the results in Table 2, the wash-off type makeup remover of the present invention (Examples 4 to 5) is easy to take, has high water resistance and oil resistance, and is familiar with the W / O liquid foundation. It was fast and excellent in usability and feeling of use, such as non-sticky skin after washing. In particular, those containing light liquid isoparaffin, which is the volatile liquid oil of component (C) of Example 5, were superior in terms of lack of oiliness during use and stickiness of the back skin. On the other hand, Comparative Examples 4 to 5 in which the specific silicone polymer of component (A) and the fluoroalkyl group-containing organopolysiloxane of component (B) are not used are inferior in most evaluations, but it is particularly easy to drop the W / O liquid foundation. It was inferior. Further, in Comparative Example 5 containing only the fluoroalkyl group-containing organopolysiloxane of the component (B), the temporal stability was not good.

Example 6 Makeup Remover (Lotion Type)
(Ingredient) (%)
1. Glycerin 30.0
2. 1,3-butylene glycol 30.0
3. Polyethylene glycol 400 20.0
4). Polyoxyethylene (60) hydrogenated castor oil 8.0
5). Light liquid isoparaffin * 8 3.0
6). Pasty composition 1 (Production Example 1) 0.5
7). Preservative appropriate amount 8. Perfume appropriate amount 9. Purified water remaining amount * 8: IP solvent 1620 (manufactured by Idemitsu Petrochemical Co., Ltd.)

(Production method)
A: Components 3 to 4 and 9 are mixed and dissolved by heating.
B: Components 5 to 6 are mixed.
C: A, B, components 1-2, and components 7-8 were stirred and mixed to obtain a lotion type makeup remover.
The lotion type make-up remover of the present invention, when taken on cotton and made into makeup cosmetics, is particularly familiar with long-lasting type makeup cosmetics, has good makeup removal, and is washed off. The skin had no stickiness and was refreshing and excellent in usability and usability.

Example 7 Makeup Remover (Gel Type)
(Ingredient) (%)
1. Glycerin 20.0
2. 1,3-butylene glycol 10.0
3. Polyethylene glycol 1500 5.0
4). Ethanol 5.0
5). Acrylic acid and alkyl acrylate (C10-30)
Copolymer * 9 0.3
6). Triethanolamine 0.3
7). Pasty composition 2 (Production Example 2) 10.0
8). Heptamethyloctyltrisiloxane * 10 5.0
9. Preservative appropriate amount10. Perfume proper amount11. Purified water remaining * 9: Carbopol 1342 (manufactured by Goodrich Chemical)
* 10: SILSOFT 034 (Nihon Unicar)

(Production method)
A: Component 3 and component 11 are mixed and dissolved by heating.
B: Components 7 to 10 are mixed.
C: After stirring and mixing A with components 1-2 and 4-5, component 6 is added and mixed.
D: B was added to C and mixed with stirring to obtain a gel-type makeup remover.
The gel-type makeup remover of the present invention is easy to take, especially with the long lasting type makeup cosmetics, has good makeup removal, and the skin after wiping is not sticky and refreshing It was excellent in usability and usability.

Example 8 Makeup Remover (Cream Type)
(Ingredient) (%)
1. Stearic acid 2.0
2. Cetanol 5.0
3. Liquid paraffin 20.0
4). Glyceryl trioctanoate 10.0
5). Partially crosslinked dimethylpolysiloxane / decamethylcyclopentasiloxane mixture * 11 5.0
6). Pasty composition 1 (Production Example 1) 5.0
7.1,3-Butylene glycol 10.0
8). Glycerol monostearate 2.0
9. Polyoxyethylene (20) sorbitan monostearate 2.0
10. Potassium hydroxide 0.1
11. Preservative appropriate amount 12. Perfume appropriate amount13. Purified water remaining amount * 11: KSG-15 (manufactured by Shin-Etsu Chemical Co., Ltd.)

(Production method)
A: Components 1 to 4 are heated and dissolved, then components 5 to 6, components 8 to 9, and components 11 to 12 are added and mixed uniformly, and adjusted to 80 ° C.
B: Components 7, 10, and 13 are mixed uniformly and adjusted to 80 ° C.
C: After emulsification while adding A to B, the mixture was cooled to obtain a cream type makeup remover.
The cream-type makeup remover of the present invention is easy to take, especially with the long lasting type makeup cosmetics, has good makeup removal, and the skin after wiping off has no stickiness and is moderate It was moist and excellent in usability and usability.

Example 9 Oil cleansing (ingredient) (%)
Cetyl 1.2-ethylhexanoate 20.0
2. (Behenic acid / eicosanedioic acid) glyceryl * 12 3.0
3. (Palmitic acid / 2-ethylhexanoic acid) dextrin * 13 2.0
4). Pasty composition 2 (Production Example 2) 2.0
5). Dodecamethylpentasiloxane * 14 5.0
6). Polyoxyethylene trioleate (20) sorbitan 5.0
7). Light liquid isoparaffin * 15 5.0
8). 8. Liquid paraffin remaining Perfume appropriate amount * 12: Nomucoat HK-G (Nisshin Oilio Co., Ltd.)
* 13: Leopard TT (Chiba Flour Mills)
* 14: KF-96L-2cs (manufactured by Shin-Etsu Chemical Co., Ltd.)
* 15: IP solvent 2028 (made by Idemitsu Petrochemical Co., Ltd.)

(Production method)
A: Components 1 to 9 are heated and dissolved, mixed uniformly, and then cooled to obtain oil cleansing.
The oil cleansing of the present invention is gel-like and easy to take, especially with the long lasting type makeup cosmetics, has good makeup removal, and the skin after wiping is oily and sticky It was excellent in usability and usability.

Claims (4)

The following components (A) to (B):
(A) Organohydrogenpolysiloxane represented by the following general formula (1) R ¹ _a H _b SiO _{(4-ab) / 2} (1)
And organopolysiloxane R ¹ _c R ² _d SiO _{(4-cd) / 2} (2) represented by the following general formula (2):
A silicone having a three-dimensional cross-linking structure, characterized in that it can contain penta-3,3,3-trifluoropropylpentamethylcyclopentasiloxane that is insoluble in an organic solvent and has the same mass or more as its own weight. Polymers wherein R ¹ may be the same or different and each is a substituted or unsubstituted monovalent hydrocarbon group having 1 to 20 carbon atoms and having no aliphatic unsaturated bond, 11 to 60 mol% is a monovalent hydrocarbon group which is a fluorine-substituted monovalent hydrocarbon group, R ² is a monovalent hydrocarbon group having 2 to 10 carbon atoms having a terminal vinyl group, and a is 1.0 2.3, b is 0.001 to 1.0, c is 1.0 to 2.3, d is 0.001 to 1.0, and 1.5 ≦ a + b ≦ 2.6. 5 ≦ c + d ≦ 2.6 is satisfied. ]
(B) A makeup remover composition containing a fluoroalkyl group-containing organopolysiloxane. The component (B) fluoroalkyl group-containing organopolysiloxane according to claim 1 is represented by the following general formula (3):
[In formula, p is an integer of 4-6. ]
The makeup remover composition according to claim 1. Furthermore, the makeup remover composition of Claim 1 or 2 containing a component (C) volatile liquid oil. Component (C) Cyclic dimethylpolysiloxane in which the volatile liquid oil is selected from light liquid isoparaffin selected from isohexadecane, isododecane and mixtures thereof, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane and dodecamethylcyclohexasiloxane The makeup remover composition according to claim 3, selected from one or more of organopolysiloxanes selected from siloxane, octamethyltrisiloxane, decamethyltetrasiloxane, dodecamethylpentasiloxane, and heptamethyloctyltrisiloxane.