JP2006282510A - Makeup cosmetic - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a makeup cosmetic smoothly slipping, spreading and forming a uniform cosmetic film on skin during use and affording a bright finish with transparency. <P>SOLUTION: The makeup cosmetic is obtained by formulating the following ingredients (A) and (B). (A) composite powder which is prepared by laminating and coating a flaky substrate with at least two layers of coloring layers having ≥2 refractive index and has a light scattering layer having 1.3-1.8 refractive index between the coloring layers or in the outermost layer and (B) flaky platy powder having ≥30 aspect ratio. The coloring layers in the composite powder of the ingredient (A) are two or more kinds selected from titanium oxide, iron oxide and zinc oxide. The makeup cosmetic comprises the light scattering layer in the composite powder of the ingredient (A) which is one or more kinds selected from silicic acid anhydride and aluminum oxide. <P>COPYRIGHT: (C)2007,JPO&INPIT

Description

  The present invention is a composite powder obtained by laminating and coating at least two colored layers having a refractive index of 2 or more on a flaky substrate, and the refractive index is 1.3 to 1. between the colored layers or the outermost layer. The present invention relates to a makeup cosmetic comprising a composite powder having a light scattering layer of 8 and a flaky powder having an aspect ratio of 30 or more. The present invention relates to a makeup cosmetic that gives a uniform cosmetic film on the skin and gives a transparent and bright finish.

In recent years, technologies for blending various pearl agents have been developed in order to obtain a three-dimensional effect for cosmetic effects. (For example, refer to Patent Documents 1 and 2) However, cosmetics containing an amount sufficient to obtain a three-dimensional effect have a problem that the smooth feeling of use is impaired.
Moreover, the technique of mix | blending spherical powder in order to provide a smooth feeling of use to cosmetics is disclosed (for example, patent document 3, 4).

JP 2001-270805 A JP 2002-154927 A JP 2003-277217 A JP 2004-083423 A

  However, although these techniques improve the smooth feeling of use, there is a problem that the transparent feeling is lost and an unnatural cosmetic film is formed.

  For this reason, there has been a demand for the development of a cosmetic that maintains the three-dimensional effect, and that spreads smoothly during use, becomes a uniform cosmetic film on the skin, and gives a transparent and bright finish.

  In view of this situation, the present inventor has intensively studied, and as a result, is a composite powder obtained by laminating at least two kinds of colored layers having a refractive index of 2 or more on a flaky substrate, between the colored layers or in the outermost layer. A makeup cosmetic that can solve the above problems by using a composite powder having a light scattering layer having a refractive index of 1.3 to 1.8 and a flaky powder having an aspect ratio of 30 or more. And the present invention was completed.

That is, the present invention includes the following components (A) and (B):
(A) A composite powder obtained by laminating and coating at least two colored layers having a refractive index of 2 or more on a flaky substrate, and having a refractive index of 1.3 to 1.8 between the colored layers or the outermost layer. A composite powder (B) having a light scattering layer is blended with a flaky powder having an aspect ratio of 30 or more, while maintaining a three-dimensional effect and having a smooth spread and transparency It provides makeup cosmetics with a bright finish.

  Further, the present invention provides the makeup cosmetic, wherein the colored layer in the composite powder of component (A) is at least two selected from titanium oxide, iron oxide, and zinc oxide.

  In the composite powder of component (A), the light scattering layer is at least one selected from silicic anhydride and aluminum oxide.

  Furthermore, 1 to 50 mass% of the powder of the component (A) is blended, and any one of the above makeup cosmetics is provided.

  The makeup cosmetic composition of the present invention is excellent in the effect of spreading smoothly when used, forming a uniform cosmetic film on the skin, and having a bright and transparent finish.

  The component (A) used in the present invention is a composite powder obtained by laminating and coating at least two colored layers having a refractive index of 2 or more on a flaky substrate, and the refractive index between the colored layers or the outermost layer. Is a composite powder having a light scattering layer of 1.3 to 1.8, and is a component that enhances the three-dimensional effect in cosmetics. The flaky substrate is not particularly limited as long as it is a flaky powder usually used in cosmetics. For example, mica, sericite, synthetic mica, synthetic sericite, aluminum silicate, silicate Magnesium, magnesium aluminum silicate, cleaved talc, plate-like silicic acid, plate glass, plate-like aluminum oxide, plate-like kaolin, plate-like boron nitride, plate-like bismuth oxychloride, etc., one or two of these More than seeds can be used. The average particle size (value obtained by laser diffraction particle size distribution measurement, hereinafter simply referred to as “average particle size”) of the flaky substrate of component (A) is preferably 1 to 100 μm, and preferably 3 to 50 μm. Is more preferable. When the average particle size is within this range, a composite powder having a good smooth spread can be obtained. The aspect ratio of the flaky substrate is preferably 30 or more from the viewpoint of spreading and spreading.

  The colored layer of the component (A) is a powder layer having a refractive index of 2 or more. Examples of such powders include titanium oxide, zinc oxide, iron tetroxide, ferrous oxide, and ferric oxide. , Iron oxyhydroxide, ferric hydroxide, sintered iron oxide / titanium oxide, iron-doped titanium oxide, low-order titanium oxide, lithium cobalt titanate, ultramarine, bitumen, chromium oxide, chromium hydroxide, carbon black, Examples thereof include inorganic powders such as manganese violet, organic powders such as organic tar dyes and natural dyes, and one or more of these can be used. In addition, it is preferable to select titanium oxide, iron oxide, or zinc oxide from these powders because the effect of enhancing the stereoscopic effect becomes better.

  Next, the light scattering layer of the component (A) is a powder layer having a refractive index of 1.3 to 1.8. Examples of such powder include aluminum oxide, silicic anhydride, magnesium oxide, oxidation Examples include inorganic powders such as zirconium, magnesium carbonate, calcium carbonate, and magnesium fluoride, and organic powders such as polyamide, acrylic resin, and polyurethane. One or more of these can be used. In addition, it is preferable to select silicic acid anhydride and aluminum oxide from these powders because the light scattering effect becomes better. Furthermore, when the light scattering layer of the component (A) is the outermost layer, it is preferably laminated so as to form minute irregularities on the surface. By forming minute irregularities on the surface, scattering of light is promoted, and reflection on the powder surface is suppressed, thereby making it possible to reduce glare and unnatural luster.

  The composite powder of component (A) is a composite powder obtained by laminating and coating at least two colored layers having a refractive index of 2 or more on a flaky substrate, and the refractive index is between the colored layers or the outermost layer. Although it is a composite powder having a light scattering layer of 1.3 to 1.8, specifically, (1) a first colored layer is coated on a flaky substrate, and then a light scattering layer is coated. Further, a composite powder in which a second colored layer is laminated and coated (2) A flaky substrate is coated with the first colored layer, then the second colored layer is coated, and a light scattering layer is further laminated and coated Composite powder etc. are mentioned.

  Each colored layer coated on the flaky substrate in the composite powder of component (A) preferably has a thickness of 5 to 200 nm. And it is preferable that 5-50 mass parts of each colored layer is coat | covered with respect to 100 mass parts of flaky base materials.

  In the composite powder of component (A), the light scattering layer coated on the flaky substrate preferably has a thickness of 10 to 100 nm. And it is preferable to cover 3-20 mass parts of light scattering layers with respect to 100 mass parts of flaky base materials.

The composite powder of component (A) is a pigment called a so-called flip-flop, color flop or the like whose color changes depending on the viewing angle because it has at least two or more kinds of colored layers. In addition, the composite powder of component (A) has an ab hue defined by JIS Z 8729 (color display method—L ^* a ^* b ^* color system and L ^* u ^* v ^* color system) 5.3. The difference between the maximum value and the minimum value of the angle h _ab (h _MAX −h _MIN ) is 10 ° to 180 ° (however, when this value exceeds 180 °, 360 ° − (h _MAX −h _MIN ) is 10 It is preferable that the ratio between the maximum value and the minimum value of the lightness L ^* specified in 4 of JIS Z 8729 is 1.0 to 2.0.

The ab hue angle _hab and the lightness L ^* are obtained by applying a composite powder to a sticky surface of a highly smooth transparent double-sided tape affixed to white paper, and using a three-dimensional variable angle spectrophotometer (Murakami Color). Using GCMS-4) manufactured by Technical Research Laboratory, the light receiving angle is changed from -80 ° to 80 ° at an incident angle of 45 °, and measurements are made at intervals of 5 °. In the present invention, the difference h _MAX -h _MIN between the maximum value h _MAX and the minimum value h _MIN of h _ab at this time is obtained and evaluated. Further, the ratio L ^* _MAX / L ^* _MIN between the maximum value L ^* _MAX and the minimum value L ^* _MIN of the lightness L ^* was obtained and evaluated. The difference h _MAX −h _MIN between the maximum value h _MAX and the minimum value h _MIN of h _ab increases as the color changes depending on the viewing angle, and the smaller the ratio L ^* _MAX / L ^* _MIN , the lower the gloss. Means.

  Such composite powders of component (A) are commercially available, for example, "RELIEF COLOR RED", "RELIEF COLOR YELLOW", "RELIEF COLOR BLUE", "RELIEF COLOR BEIGE" Etc.).

  The composite powder of component (A) may be used after surface treatment with a known treating agent such as a fluorine compound, silicone compound, metal soap, wax, surfactant, oil or fat, hydrocarbon.

  The blending amount of the component (A) in the makeup cosmetic of the present invention is not particularly limited, but is preferably 1 to 50% by mass (hereinafter simply referred to as “%”), and further 5 to 20%. % Is particularly preferred. If the blending amount is within this range, the smooth stretch spread at the time of use is good, it becomes a highly uniform cosmetic film, and further, it is good from the viewpoint of makeup sustainability and stability over time, and stereoscopic effect. can get. Moreover, these composite powders can use 1 type (s) or 2 or more types as needed.

  The component (B) used in the present invention is a flaky powder having an aspect ratio of 30 or more, which is used for ordinary cosmetics. More specifically, the average particle diameter (plate diameter) is 1 to 50 μm, the average The thickness of 0.02 to 1.5 μm in combination with the component (A) is used to form a uniform makeup film having a smooth and bright finish with a transparent finish in combination with the component (A). It is an ingredient. Examples of such flaky powder include natural minerals such as mica and sericite, synthetic mica, synthetic sericite, plate-like silica, plate-like alumina, plate-like barium sulfate, boron nitride and other inorganic powders and plates. And organic powders such as methyl methacrylate. Among these, synthetic mica is most preferable in terms of smooth spreading, transparency, and a uniform and natural makeup film. The flaky powder can be used alone or in combination of two or more. In addition, you may use a component (B) surface-treating by well-known processing agents, such as a fluorine compound, a silicone compound, metal soap, wax, surfactant, fats and oils, and a hydrocarbon.

  Although the compounding quantity of the component (B) in the makeup cosmetics of this invention is not specifically limited, 1-50% is preferable in the whole quantity, and also 5-40% is especially preferable. When the blending amount is within this range, it is possible to obtain a cosmetic with a better spread in use, uniformity of the decorative film, and a bright finish with transparency.

  In addition to the above essential components, the makeup cosmetic of the present invention usually contains oils, powders other than components (A) and (B), surfactants, water-soluble polymers as components contained in cosmetics. Water, alcohol and other aqueous components, trimethylsiloxysilicic acid and other oil-soluble film formers, paraoxybenzoic acid derivatives, phenoxyethanol and other preservatives, sugars, UV absorbers, moisturizers, antibacterial agents, perfumes, salts, antioxidants Agent, pH adjuster, chelating agent, refreshing agent, anti-inflammatory agent, skin beautifying agent (whitening agent, cell activator, rough skin improving agent, blood circulation promoter, skin astringent, antiseborrheic agent, etc.), vitamins, amino acids , Nucleic acids, hormones, enzymes such as lipase and protease, various drugs such as resorcin and sulfur, dyes, fragrances, inclusion compounds and the like can be appropriately blended within a range not impairing the effects of the present invention.

  Oils that can be blended in the present invention include hydrocarbons, regardless of properties such as solid oils, semi-solid oils, liquid oils, volatile oils and the like of animal oils, vegetable oils, synthetic oils and the like that are commonly used in cosmetics. Oils, waxes, hardened oils, ester oils, fatty acids, higher alcohols, silicone oils, fluorine-based oils, lanolin derivatives, oily gelling agents, and the like. Specifically, hydrocarbons such as liquid paraffin, squalane, petroleum jelly, polyethylene wax, ethylene / propylene copolymer, paraffin wax, montan wax, Fischer-Tropsch wax, polyisobutylene, polybutene, ceresin wax, ozokerite wax, mole, Oils such as olive oil, castor oil, mink oil, macadamian nut oil, waxes such as beeswax, gay wax, carnauba wax, candelilla wax, jojoba oil, glyceryl trioctanoate, polyglyceryl diisostearate, diglyceryl triisostearate, Glyceryl tribehenate, cetyl 2-ethylhexanoate, isopropyl myristate, isopropyl palmitate, octyldodecyl myristate, pentaerythrodiphosphate Esters, esters such as neopentyl glycol dioctanoate, cholesterol fatty acid esters, phytosterol fatty acid esters, fatty acids such as stearic acid, lauric acid, myristic acid, behenic acid, isostearic acid, oleic acid, stearyl alcohol, cetyl alcohol, lauryl alcohol , Higher alcohols such as oleyl alcohol, isostearyl alcohol, behenyl alcohol, dimethylpolysiloxane, methylphenylpolysiloxane, decamethylcyclopentasiloxane, octamethylcyclotetrasiloxane, high degree of polymerization methylphenylpolysiloxane, polyoxy-modified organopolysiloxane, Cross-linked polyether-modified methylpolysiloxane, methacryl-modified polysiloxane, stearyl-modified methylpolysiloxane Sun, oleyl-modified methylpolysiloxane, behenyl-modified methylpolysiloxane, polyvinylpyrrolidone-modified methylpolysiloxane, high degree of polymerization dimethylpolysiloxane, polyoxyalkylene-alkylmethylpolysiloxane-methylpolysiloxane copolymer, alkoxy-modified polysiloxane, crosslinking Type organopolysiloxane, silicones such as fluorine-modified polysiloxane, fluorine oils such as perfluorodecane, perfluorooctane, perfluoropolyether, lanolin, lanolin acetate, lanolin fatty acid isopropyl, lanolin derivatives such as lanolin alcohol, sucrose Oily gelling agents such as fatty acid ester, starch fatty acid ester, aluminum isostearate, calcium stearate, 12-hydroxystearic acid These can be used alone or in combination of two or more.

  As powders other than the components (A) and (B) that can be blended in the present invention, a spherical shape, a needle-like shape, a fume shape, etc., as long as the powder is used as a powder generally used in cosmetics It is not particularly limited by the particle size such as fine particles and pigment grade, the particle structure such as porous and non-porous, etc., inorganic powders, glitter powders, organic powders, pigment powders, metal powders And composite powders. Specific examples include white inorganic pigments such as titanium oxide, zinc oxide, cerium oxide, and barium sulfate, bengara, yellow iron oxide, black iron oxide, carbon black, titanium / titanium oxide sintered product, chromium oxide, hydroxide Colored inorganic pigments such as chrome, bituminous, ultramarine, talc, muscovite, phlogopite, saucite, biotite, synthetic mica, sericite (sericite), synthetic sericite, kaolin, silicon carbide, bentonite, smectite, aluminum oxide , Magnesium oxide, zirconium oxide, antimony oxide, siliceous earth, aluminum silicate, magnesium aluminum silicate, calcium silicate, barium silicate, magnesium silicate, calcium carbonate, hydroxyapatite, boron nitride, etc. Titanium oxide-coated mica, titanium oxide-coated bismuth oxychloride, acid Luminous powders such as iron mica titanium, bitumen-treated mica titanium, carmine-treated mica titanium, organic low molecular weight powders such as zinc stearate and N-acyl lysine, natural organic powders such as silk powder and cellulose powder, red 201, red 202, red 205, red 226, red 228, orange 203, orange 204, blue 404, yellow 401 organic pigment powder, red 3, red 104, red 106, orange 205, yellow 4, yellow 5, green 3, blue 1, etc., organic pigment powder such as zirconium, barium or aluminum lake, or metal powder such as aluminum powder, gold powder, silver powder, Fine titanium oxide coated mica titanium, fine zinc oxide coated mica titanium, barium sulfate coated mica titanium, titanium oxide containing silicon dioxide, zinc oxide containing silicon dioxide, etc. Goko body and the like, these can be used alone or in combination.

  In the present invention, a surfactant is preferably blended for the purpose of an emulsifier, a dispersant, a wetting agent, and the like. Any surfactant that can be blended is any surfactant that is commonly used in cosmetics. And nonionic surfactants, anionic surfactants, cationic surfactants, amphoteric surfactants and the like. Specifically, as the nonionic surfactant, glycerin fatty acid ester and its alkylene glycol adduct, polyglycerin fatty acid ester and its alkylene glycol adduct, propylene glycol fatty acid ester and its alkylene glycol adduct, sorbitan fatty acid ester and Its alkylene glycol adduct, fatty acid ester of sorbitol and its alkylene glycol adduct, polyalkylene glycol fatty acid ester, sucrose fatty acid ester, polyoxyalkylene alkyl ether, glycerin alkyl ether, polyoxyethylene alkylphenyl ether, polyoxyethylene hydrogenated castor oil Lanolin alkylene glycol adduct, polyoxyalkylene modified silicone, glycerin modified silicone, poly Glycerin-modified silicone and the like, these can be used from one or more suitably. Anionic surfactants include fatty acids such as stearic acid and lauric acid and their inorganic and organic salts, alkylbenzene sulfates, alkyl sulfonates, α-olefin sulfonates, dialkyl sulfosuccinates, α-sulfonated fatty acids. Salt, acylmethyl taurate, N-methyl-N-alkyl taurate, polyoxyethylene alkyl ether sulfate, polyoxyethylene alkyl phenyl ether sulfate, alkyl phosphate, polyoxyethylene alkyl ether phosphate, polyoxyethylene alkyl Examples thereof include phenyl ether phosphate, N-acyl amino acid salt, N-acyl-N-alkyl amino acid salt, o-alkyl substituted malate, alkylsulfosuccinate, and the like, and one or more of these may be used as appropriate. it can. Examples of the cationic surfactant include alkylamine salts, polyamines and alkanolamine fatty acid derivatives, alkyl quaternary ammonium salts, cyclic quaternary ammonium salts, and the like. One or more of these can be used as appropriate. Examples of amphoteric surfactants include N, N-dimethyl-N-alkyl-N-carboxylmethyl ammonium betaine, N, N-dialkylaminoalkylene carboxylic acid, N, N, N-trialkyl-N-sulfoalkylene ammonium betaine. N, N-dialkyl-N, N-bis (polyoxyethylene sulfate) ammonium betaine, 2-alkyl-1-hydroxyethyl-1-carboxymethylimidazolinium betaine, and the like, one or two of these The above can be used.

  The aqueous component may be any component as long as it is soluble in water and water. In addition to water, for example, lower alcohols such as ethyl alcohol and butyl alcohol, propylene glycol, 1,3-butylene glycol, dipropylene glycol And glycols such as polyethylene glycol, glycerols such as glycerin, diglycerin and polyglycerin, and plant extracts such as aloe vera, witch hazel, hamamelis, cucumber, lemon, lavender and rose. Examples of water-soluble polymers include guar gum, sodium chondroitin sulfate, sodium hyaluronate, gum arabic, sodium alginate, carrageenan, and other semi-synthetic materials such as methyl cellulose, hydroxyethyl cellulose, carboxymethyl cellulose, carboxyvinyl polymer, Synthetic compounds such as alkyl-added carboxyvinyl polymer, polyvinyl alcohol, polyvinyl pyrrolidone, sodium polyacrylate and the like can be mentioned. Other moisturizing agents such as protein, mucopolysaccharide, collagen, elastin, keratin and the like can also be contained.

  Examples of the antioxidant include α-tocopherol and ascorbic acid. Examples of the beauty component include vitamins, anti-inflammatory agents and herbal medicines. Examples of the preservative include paraoxybenzoic acid ester and phenoxyethanol.

  Examples of the ultraviolet absorber include benzophenone, PABA, cinnamic acid, salicylic acid, 4-tert-butyl-4'-methoxydibenzoylmethane, oxybenzone, and the like.

  Examples of the dosage form of the makeup cosmetic of the present invention include a powder dosage form, an oil-in-water emulsifier type, a water-in-oil emulsifier type, an oil-based dosage form, an aqueous dosage form, and a solvent type. Examples of the form include powder, solid, cream, gel, liquid, mousse, and spray. The makeup cosmetic of the present invention can be applied to any of foundations, concealers, white powder, eye shadows, blushers, makeup bases, beauty nails and the like.

  EXAMPLES Next, although an Example is given and this invention is demonstrated still in detail, this invention is not limited at all by these.

Examples 1 to 6 and Comparative Examples 1 to 3: Powdered solid foundations Powdered solid foundations having the formulations shown in Tables 1 and 2 below were prepared by the production method shown below, and "Elongation at Use" , “Three-dimensional effect”, “uniformity of decorative film”, and “bright finish feeling with transparency” were evaluated by the following evaluation methods and criteria, and the results are also shown in Table 1.

(Production method)
A: Components (1) to (16) are uniformly dispersed with a Henschel mixer (manufactured by Mitsui Miike).
B: Components (17) to (21) are heated to 60 ° C. and mixed.
C: While A is stirred with a Henschel mixer, B and component (22) are added and dispersed uniformly.
D: C is pulverized with a pulverizer.
E: D was filled in a metal pan and compression molded to obtain a powdered solid foundation.

Ask 20 panelists specializing in cosmetics to use the solid powder foundations of the above examples and comparative examples using a sponge, and a. “Smooth extension and spread during use”, b. “Stereoscopic effect”, c. For “uniformity of makeup film” and d. “Transparent and bright finish”, each of them is evaluated according to the following criteria, with a score of 7 for each foundation. This was judged according to the four-step criteria.
Absolute Evaluation Criteria (Score): (Evaluation)
6: Very good 5: Good 4: Somewhat good 3: Normal 2: Somewhat bad 1: Bad 0: Very bad

4-step criteria (Judgment): (Average score)
◎: More than 5 points: Very good ○: More than 3 points, 5 points or less: Good △: More than 1 point, 3 points or less: Slightly poor ×: 1 point or less: Bad

As is clear from the results in Tables 1 and 2, the powder solid foundations of Examples 1 to 6 are more smooth and spread, compared to the powder solid foundations of Comparative Examples 1 to 5, and the three-dimensional effect. Excellent in all aspects of uniformity and bright finish with transparency.
On the other hand, Comparative Example 1 in which component (A) was not blended was inferior in a three-dimensional effect and a bright finish feeling with transparency, and in Comparative Example 2 using mica titanium instead of component (A), the three-dimensional effect In Comparative Example 3 in which the component (B) was not blended, smooth elongation spread, uniformity of the decorative film, and a bright finish with a transparent feeling were not obtained. Comparative Example 4 containing 30 or less flaky powder was unsatisfactory in terms of smooth stretch and spread, uniformity of the decorative film, and a bright finish with transparency, and a spherical powder was used instead of Component B. In Comparative Example 5, a bright finish with a uniform and transparent decorative film was not obtained.

  Example 7: Oil-in-water foundation (cream)

(Ingredient) (%)
1. Stearic acid 3.0
2. Lipophilic glyceryl monostearate 2.5
3. Cetanol 1.5
4). Polyethylene glycol monolaurate 2.5
5. Liquid paraffin 8.0
6). Isopropyl myristate 5.0
7). Octyl methoxycinnamate 2.0
8). Propyl paraoxybenzoate 0.1
9. Purified water remaining amount 10. Bentonite 1.0
11. Triethanolamine 1.2
12 Sorbitol 3.0
13. Methyl paraoxybenzoate 0.2
14 Titanium oxide 8.0
15. Sericite (component B: average particle size 10 μm, aspect ratio 40) 5.0
16. Component (A) composite powder (Note 1) 5.0
17. Bengala 0.5
18. Yellow iron oxide 2.0
19. Black iron oxide 0.2

(Production method)
A. Components (14) to (19) are mixed.
B. Ingredient (9) is heated to 80 ° C. and ingredient (10) is added to swell.
C. Add components (11) to (13) to B and mix.
D. Add A to C, heat to 80 ° C. and mix. (Aqueous phase).
E. (1) to (8) are heated to 80 ° C. and dissolved. (Oil phase).
F. E is added to D to emulsify, and the mixture is stirred and cooled to 35 ° C.
G. F was filled in a container to obtain an oil-in-water type foundation.
The oil-in-water foundation obtained as described above was an oil-in-water foundation with a bright finish with good spread and a three-dimensional effect, and a uniform and transparent cosmetic film.

Example 8: Water-in-oil foundation (milky liquid)
(Ingredient) (%)
1. Component (A) composite powder (Note 1) 10.0
2. Bengala 0.5
3. Yellow iron oxide 2.0
4). Black iron oxide 0.2
5. Titanium oxide 5.0
6). Sericite (component B: average particle size 10 μm, aspect ratio 50) 5.0
7). Synthetic phlogopite (component B: average particle size 12 μm, aspect ratio 40) 5.0
8). Inulin stearate 1.0
9. Neopentyl glycol dicaprate 15.0
10. Decamethylcyclopentasiloxane 20.0
11. Octyl methoxycinnamate 3.0
12 Perfume appropriate amount13. Polyoxyethylene methyl polysiloxane copolymer (Note 8) 2.0
14 Nylon powder 1.0
15. Methyl paraoxybenzoate 0.1
16. Ethanol 7.0
17. Sodium chloride 0.2
18. Dipropylene glycol 1.0
19. Purified water remaining amount (Note 8) KF-6019 (manufactured by Shin-Etsu Chemical Co., Ltd.)

(Production method)
A. Components (8) to (9) are dissolved by heating at 70 ° C.
B. Add components (1) to (7) to A and mix and disperse with a roll mill.
C. Components (15) to (19) are mixed and dissolved, and component (14) is added and mixed and dispersed.
D. Add components (10) to (13) to A and mix.
E. Add B to D and emulsify and mix.
F. D was filled into a container to obtain a water-in-oil type foundation.
The water-in-oil foundation obtained as described above was a brightly-finished water-in-oil foundation having good elongation and spread, a three-dimensional effect, and a uniform and transparent cosmetic film.

Example 9: White powder (component) (%)
1. Component (A) composite powder (Note 1) 20.0
2. Talc 30.0
3. Synthetic phlogopite (component B: average particle size 12 μm, aspect ratio 50) 30.0
4). Sericite (component B: average particle size 10 μm, aspect ratio 40 6.0)
5. 5. Kaolin remaining amount Titanium oxide 3.0
7). Zinc myristate 2.0
8). Bengala 0.1
9. Yellow iron oxide 0.4
10. Squalane 1.0
11. Octyl methoxycinnamate 2.0
12 Methyl paraoxybenzoate 0.3
13. Perfume

(Production method)
A. Components (1) to (9) are mixed with a Henschel mixer (Mitsui Miike).
B. Ingredients (10) to (13) are mixed and added to A while stirring with a Henschel mixer and mixed uniformly.
C. B is pulverized with a pulverizer.
D. C was filled into a metal pan and compression molded to obtain a powdery white powder.
The powdered white powder obtained as described above was a bright white powder having a good finish, having a three-dimensional effect, and having a uniform and transparent decorative film.

Example 10: Eye shadow (solid powder)
(Ingredient) (%)
1. Component (A) composite powder (Note 9) 30.0
2. 2. Silicone-treated synthetic phlogopite (component B: average particle size 12 μm, aspect ratio 50) Silicone-treated titanium oxide 0.5
4). Silicone treated bengara 0.1
5. Silicone-treated yellow iron oxide 0.3
6). Silicone-treated black iron oxide 0.05
7). Silicone treatment ultramarine 2.0
8). Silicone-treated red 202 No. 1.0
9. Nylon powder 2.0
10. Silicone resin powder 2.0
11. Plate-like barium sulfate (component B: average particle size 15 μm, aspect ratio 50) 10.0
12 Boron nitride (component B: average particle size 7 μm, aspect ratio 50) 5.0
13. Organically modified hectorite 0.5
14 Liquid paraffin 3.0
15. Octyl methoxycinnamate 2.0
16. White petrolatum 1.0
17. Cross-linked polyether-modified silicone 0.5
18. Methylpolysiloxane 2.5
19. Methyl paraoxybenzoate 0.3
20. Perfume appropriate amount (Note 9) RELIEF COLOR BLUE (manufactured by Catalyst Kasei Kogyo Co., Ltd.)

(Production method)
A. Components (1) to (12) are mixed with a Henschel mixer.
B. Components (13) to (20) are roll-milled and then added to A and mixed with stirring with a Henschel mixer.
C. 65 parts by mass of light isoparaffin is added to 100 parts by mass of B to form a slurry.
D. C was filled in a metal pan and dried to obtain a powdered solid eyeshadow.
The eye shadow obtained as described above was a bright eye shadow that had a good stretch and spread, a three-dimensional effect, a uniform decorative film, and a transparent finish.

Example 11: Blusher (powder solid)
(Ingredient) (%)
1. Silicone-treated synthetic phlogopite (component B: average particle size 12 μm, aspect ratio 50) 25.0
2. Silicone-treated sericite (component B: average particle size 10 μm, aspect ratio 40) 20.0
3. 3. Silicone-treated talc remaining amount Silicone-treated titanium oxide 1.0
5. Silicone treated bengara 0.05
6). Silicone-treated yellow iron oxide 1.0
7). Silicone-treated black iron oxide 0.05
8). Silicone-treated red 226 0.5
9. Component (A) composite powder (Note 10) 20.0
10. Methyl paraoxybenzoate 0.3
11. Squalane 3.0
12 Glyceryl tri-2-ethylhexylate 2.0
13. Octyl methoxycinnamate 2.0
14 Heavy hydrogenated polybutene 1.0
15. Perfume appropriate amount (Note 10) RELIEF COLOR RED (manufactured by Catalyst Kasei Kogyo Co., Ltd.)

(Production method)
A. Components (1) to (9) are mixed with a Henschel mixer.
B. Ingredients (10) to (14) are heated and mixed at 50 ° C., and ingredient (15) is added and added to A while stirring with a Henschel mixer.
C. B is pulverized with a pulverizer.
D. C was compression-molded into a metal pan to obtain a powdered solid blusher.
The blusher obtained as described above was a bright blusher with a well-extended spread, a three-dimensional effect, and a uniform and transparent makeup film.

Example 12: Oily solid foundation (component) (%)
1. Polyethylene wax 1.0
2. Hydrogenated rosin acid pentaerythrityl 1.0
3. Carnauba wax 1.0
4). Ceresin wax 2.0
5. (Dimethicone / Vinyl Dimethicone) Copolymer 2.0
6). Dimethicone 6.0
7). Isocetyl octoate 5.0
8). Octyl methoxycinnamate 5.0
9. Titanium oxide 20.0
10. 10. Sericite (component B: average particle size 10 μm, aspect ratio 40) Bengala 0.3
12 Yellow iron oxide 1.5
13. Black iron oxide 0.1
14 Component (A) composite powder (Note 1) 20.0
15. Nylon powder (Note 3) 5.0
16. Synthetic phlogopite (component B: average particle size 12 μm, aspect ratio 50) 10.0
17. Cellulose acetate (Note 11) 10.0
18. Methyl paraoxybenzoate 0.3
(Note 11) Cellflow TA-25 (manufactured by Chisso Corporation)

(Production method)
A. Components (1) to (8) are heated and dissolved at 105 ° C., (9) to (13) are added, and the mixture is dispersed by a roll mill.
B. A is heated to 80 ° C., components (14) to (18) are added, and mixed uniformly with a planetary mixer.
C. B was heated and filled in a metal pan at 80 ° C. and rapidly cooled to obtain an oily solid foundation.
The oily solid foundation obtained as described above was an oily solid foundation having a bright finish with a good spread, a three-dimensional effect, and a uniform and transparent decorative film.
more than

Claims (4)

The following components (A) and (B);
(A) A composite powder obtained by laminating and coating at least two colored layers having a refractive index of 2 or more on a flaky substrate, and having a refractive index of 1.3 to 1.8 between the colored layers or the outermost layer. A makeup powder comprising a composite powder (B) having a light scattering layer and a flaky powder having an aspect ratio of 30 or more. The makeup cosmetic according to claim 1, wherein the colored layer in the composite powder of component (A) is at least two selected from titanium oxide, iron oxide, and zinc oxide. 3. The makeup cosmetic according to claim 1, wherein the light scattering layer in the composite powder of component (A) is at least one selected from silicic anhydride and aluminum oxide. The makeup cosmetic according to any one of claims 1 to 3, wherein 1 to 50 mass% of the composite powder of the component (A) is blended.