JP2006225273A - Method for producing face washing agent using ionized alkaline water - Google Patents
Method for producing face washing agent using ionized alkaline water Download PDFInfo
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- JP2006225273A JP2006225273A JP2005037554A JP2005037554A JP2006225273A JP 2006225273 A JP2006225273 A JP 2006225273A JP 2005037554 A JP2005037554 A JP 2005037554A JP 2005037554 A JP2005037554 A JP 2005037554A JP 2006225273 A JP2006225273 A JP 2006225273A
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 31
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 15
- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 9
- 238000005406 washing Methods 0.000 title abstract description 4
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 claims abstract description 14
- 235000012239 silicon dioxide Nutrition 0.000 claims abstract description 14
- 235000019502 Orange oil Nutrition 0.000 claims abstract description 10
- 239000004006 olive oil Substances 0.000 claims abstract description 10
- 239000010502 orange oil Substances 0.000 claims abstract description 10
- 235000008390 olive oil Nutrition 0.000 claims abstract description 9
- 239000003349 gelling agent Substances 0.000 claims abstract description 8
- 239000002734 clay mineral Substances 0.000 claims abstract description 7
- 239000002274 desiccant Substances 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 7
- 230000001815 facial effect Effects 0.000 claims description 8
- 230000033116 oxidation-reduction process Effects 0.000 abstract description 9
- 238000002156 mixing Methods 0.000 abstract description 8
- 230000007794 irritation Effects 0.000 abstract description 5
- 238000003756 stirring Methods 0.000 abstract description 4
- 230000014759 maintenance of location Effects 0.000 abstract 1
- 239000002537 cosmetic Substances 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 230000003020 moisturizing effect Effects 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 235000019198 oils Nutrition 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- 206010040880 Skin irritation Diseases 0.000 description 2
- 206010000496 acne Diseases 0.000 description 2
- 230000000844 anti-bacterial effect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 239000002075 main ingredient Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 230000036556 skin irritation Effects 0.000 description 2
- 231100000475 skin irritation Toxicity 0.000 description 2
- 210000004243 sweat Anatomy 0.000 description 2
- 208000002874 Acne Vulgaris Diseases 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 206010013786 Dry skin Diseases 0.000 description 1
- 208000010201 Exanthema Diseases 0.000 description 1
- 241000207836 Olea <angiosperm> Species 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 230000000843 anti-fungal effect Effects 0.000 description 1
- 230000003110 anti-inflammatory effect Effects 0.000 description 1
- 229960001631 carbomer Drugs 0.000 description 1
- 239000000679 carrageenan Substances 0.000 description 1
- 235000010418 carrageenan Nutrition 0.000 description 1
- 229920001525 carrageenan Polymers 0.000 description 1
- 229940113118 carrageenan Drugs 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 201000005884 exanthem Diseases 0.000 description 1
- 230000029142 excretion Effects 0.000 description 1
- JEGUKCSWCFPDGT-UHFFFAOYSA-N h2o hydrate Chemical compound O.O JEGUKCSWCFPDGT-UHFFFAOYSA-N 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 206010037844 rash Diseases 0.000 description 1
- 230000028327 secretion Effects 0.000 description 1
- 230000005808 skin problem Effects 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 238000001256 steam distillation Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 description 1
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Abstract
Description
本発明は、皮膚への刺激感がなく、保湿感もあり、且つメイクを完全に落とすことのできる酸化還元電位の低いアルカリイオン水を用いた洗顔料の製造方法に関するものである。 The present invention relates to a method for producing a facial cleanser using alkaline ionized water having a low oxidation-reduction potential that does not irritate the skin, has a moisturizing feeling, and can completely remove makeup.
昨今の多種多様化する化粧品業界の進歩は目覚しく、新規原料や使用感のユニークな物など、常に新製品が発売されている。特に、メイク関係の化粧品では、水や汗にも強い「落ちにくいメイクアップ化粧品」が売れ筋商品となっている。しかし、メイクをするからには寝る前には落とさなければならず、結果としてその際使用するクレンジング剤(洗顔料)は、今までよりも作用の強い界面活性剤か、活性剤の配合量を増やしたもの等を使用せざるを得なかった。その為に肌への負担が大きくなり、刺激を感じたり、肌荒れを起こす事も少なくなかった。 Recent advances in the diversified cosmetics industry are remarkable, and new products such as new ingredients and unique ones that are used are always on the market. Especially for makeup-related cosmetics, “make-up cosmetics that are hard to fall off”, which are resistant to water and sweat, are popular products. However, in order to make up, it must be removed before going to bed. As a result, the cleansing agent (face wash) used at that time is a more active surfactant or more active agent than before. I had to use things. For this reason, the burden on the skin was increased, and it was not uncommon to feel irritation and rough skin.
そして、過去の特許文献を遡及検索すると、酸化還元電位が−200mV以下の電解水に界面活性剤を混合した化粧落とし用液が特開2004−131387号公報に開示されている。 And retrospective search of past patent documents discloses a makeup remover solution in which a surfactant is mixed with electrolyzed water having an oxidation-reduction potential of −200 mV or less.
前記特許文献1に開示された化粧落とし用液は、界面活性剤を用いているため、肌への負担が大きくなり、刺激を感じたり、肌荒れを起こすという問題があった。
Since the makeup remover disclosed in
本発明は、前記課題を解決すべくなされたもので、肌への負担が大きく、刺激を感じたり、肌荒れを起こす界面活性剤を用いることなく、酸化還元電位が−250mV〜−700mVの範囲で、且つpH8〜12の範囲のアルカリイオン水を原料水とし、これに主剤としてオレンジ油を配合すると共に、ジェル化剤として天然粘土鉱物由来のケイ酸(Na/Mg)、および不乾性剤として天然由来のオリーブ油をそれぞれ配合して混合攪拌して製造するアルカリイオン水を用いた洗顔料の製造方法を提供しようとするものである。 The present invention has been made in order to solve the above-mentioned problems. The burden on the skin is large, and the oxidation-reduction potential is in the range of −250 mV to −700 mV without using a surfactant that causes irritation or rough skin. In addition, alkaline ionized water having a pH in the range of 8 to 12 is used as raw water, and orange oil is blended therein as a main agent, and silicic acid derived from natural clay mineral (Na / Mg) as a gelling agent, and natural as a non-drying agent. It is an object of the present invention to provide a method for producing a facial cleanser using alkaline ionized water, which is produced by blending olive oils derived from each and mixing and stirring them.
本発明は、酸化還元電位が−250mV〜−700mVの範囲で、且つpH8〜12の範囲のアルカリイオン水を原料水とし、これに主剤としてオレンジ油を配合すると共に、ジェル化剤として天然粘土鉱物由来のケイ酸(Na/Mg)、および不乾性剤として天然由来のオリーブ油をそれぞれ配合して混合攪拌して製造することにより、上記課題を解決した。 The present invention uses an alkaline ionized water having an oxidation-reduction potential in the range of −250 mV to −700 mV and a pH of 8 to 12 as raw material water, and blends orange oil as a main ingredient, and a natural clay mineral as a gelling agent. The above-mentioned problem was solved by blending and mixing and stirring the derived silicic acid (Na / Mg) and naturally-derived olive oil as a non-drying agent.
本発明製造方法により得られた洗顔料は、アルカリイオン水のもつ殺菌効果だけでなく、柔軟作用による溶解作用がメイクの汚れ落としを補助し、天然由来のオレンジ油による優れた油分洗浄作用によって肌に刺激を与えることなく、落ちにくいメイクもすっきり落とすことができ、且つジェル化剤である天然粘土鉱物由来のケイ酸(Na/Mg)、および不乾性剤の天然由来のオリーブ油の作用によりメイクを落とした後も保湿感があり、肌に潤いを与える。また、本発明製造方法の原材料であるケイ酸(Na/Mg)、およびオリーブ油は100%天然原料であるため、肌にやさしいという効果を奏する。 The face wash obtained by the production method of the present invention has not only a bactericidal effect possessed by alkaline ionized water but also a dissolving action by a softening action that assists in removing makeup stains, and an excellent oil washing action by naturally derived orange oil. Makes makeup with the action of natural clay mineral-derived silicic acid (Na / Mg) as a gelling agent and naturally-occurring olive oil as a non-drying agent. There is a moisturizing feeling after dropping and moisturizes the skin. In addition, since silicic acid (Na / Mg) and olive oil, which are raw materials for the production method of the present invention, are 100% natural raw materials, they have the effect of being gentle to the skin.
本発明は、皮膚への刺激が皆無で、且つメイクを完全に落とすことができると共に、メイクを落とした後も保湿感があり、肌に潤いを与えることのできる洗顔料として、酸化還元電位が−250mV〜−700mVの範囲で、且つpH8〜12の範囲にあるアルカリイオン水を原料水とし、これに油性の汚れに対して優れた洗浄力をもつオレンジ油を主剤として配合すると共に、更にジェル化剤として肌にやさしい天然粘土鉱物由来のケイ酸(Na/Mg)、および不乾性剤として天然由来のオリーブ油をそれぞれ配合して製造されたものである。以下、本発明につき詳細に説明する。 The present invention has no skin irritation, can completely remove makeup, has a moisturizing feeling even after removing makeup, and has a redox potential as a facial wash that can moisturize the skin. The alkaline ionized water in the range of −250 mV to −700 mV and the pH of 8 to 12 is used as raw material water, and orange oil having an excellent detergency against oily dirt is blended as a main ingredient, and further gel is added. It is produced by blending natural clay mineral-derived silicic acid (Na / Mg), which is gentle to the skin as an agent, and natural-derived olive oil as a non-drying agent. Hereinafter, the present invention will be described in detail.
本発明の原料水となる酸化還元電位が−250mV〜−700mVの範囲で、且つpH8〜12の範囲にあるアルカリイオン水は、特に限定する必要はないが、市販されている電解装置、例えば、株式会社レドックス社製の3室型電解システムや日本トリム株式会社製の電解還元水整水器等を使用して生成する。また、例えば、酸化還元電位が−648mV、pHが9.4で、商品名「寿鶴」(鹿児島県の株式会社垂水温泉鶴田社製)として販売されている天然アルカリイオン水を使用することもできる。更に、この天然アルカリイオン水の外に、前記の範囲の酸化還元電位とpH値を有している、例えば、商品名「日田天領水」等の天然アルカリイオン水の使用も可能である。 The alkaline ionized water having an oxidation-reduction potential in the range of −250 mV to −700 mV and a pH of 8 to 12 as the raw material water of the present invention is not particularly limited. It is generated by using a three-chamber electrolysis system manufactured by Redox Co., Ltd. or an electrolytically reduced water water conditioner manufactured by Nippon Trim Co. In addition, for example, natural alkaline ionized water having an oxidation-reduction potential of −648 mV, pH of 9.4, and marketed as a trade name “Suzutsuru” (manufactured by Tarumi Onsen Tsuruta Co., Ltd., Kagoshima Prefecture) may be used. it can. Furthermore, in addition to this natural alkaline ionized water, natural alkaline ionized water having a redox potential and pH value in the above-mentioned range, such as the trade name “Hita Tenryosui”, can be used.
酸化還元電位が−250mV〜−700mVの範囲で、且つpH8〜12の範囲にあるアルカリイオン水は、肌に対して柔軟作用を有すると共に、殺菌作用を有し、そしてこの殺菌作用により、化粧品に防腐剤・抗菌剤の類を配合せずにすむため、肌刺激・肌あれ等の肌のトラブルを起こさない洗顔料の提供が可能である。また、前記アルカリイオン水は、肌に対する刺激性もほとんどなく、肌に塗布して24時間後の反応も確認したが、赤み・発疹・肌荒れ等はみられなかった。前記アルカリイオン水の作用から、本発明者はこれを本発明洗顔料の製造方法の原料水として採用した。 Alkaline ion water having an oxidation-reduction potential in the range of −250 mV to −700 mV and in the range of pH 8 to 12 has a softening action on the skin and a bactericidal action. Since it is not necessary to add preservatives and antibacterial agents, it is possible to provide a facial cleanser that does not cause skin problems such as skin irritation and rough skin. The alkaline ionized water had almost no irritation to the skin and was confirmed to react 24 hours after application to the skin, but no redness, rash, rough skin, etc. were observed. From the action of the alkaline ionized water, the present inventor has adopted this as raw water for the method for producing the facial cleanser of the present invention.
本発明の主剤となるオレンジ油は、オレンジの果皮から圧搾または水蒸気蒸留により採取される油で、油性の汚れに対して優れた洗浄力をもち、且つ肌からの過剰な分泌物や老廃物の排泄を促す作用、更には、にきびや吹き出物等に対する抗炎症作用や抗真菌作用を有している。 The orange oil used as the main agent of the present invention is an oil collected from orange peels by pressing or steam distillation, and has an excellent detergency against oily dirt, and it also contains excess secretions and waste products from the skin. It has an action to promote excretion, and further has an anti-inflammatory action and an antifungal action against acne and pimples.
本発明のジェル化剤となる天然粘土鉱物由来のケイ酸(Na/Mg)は、粘性と保水性を有しており、洗顔料をジェル状に保持するために採用するものである。更に、ケイ酸(Na/Mg)は、その成分特性により、使用前に洗顔料容器を振ることにより、ジェルの粘度の調整ができる。また、本発明において、不乾性剤として採用する天然由来のオリーブ油は、オリーブの完熟した実を圧搾して得る不乾性油で、その油膜を空気中にさらしても、乾燥して樹脂状に変化することのない特性を有しているため、メイクを落とした後も、ケイ酸(Na/Mg)の保湿性を保持すると共に、肌に潤いを与えることができるので、本発明において有利に採用することができる。 Silicic acid derived from natural clay mineral (Na / Mg), which serves as a gelling agent of the present invention, has viscosity and water retention, and is used to maintain the facial cleanser in a gel form. Furthermore, silicic acid (Na / Mg) can adjust the viscosity of a gel by shaking the face wash container before use due to its component characteristics. In the present invention, naturally-derived olive oil employed as a non-drying agent is a non-drying oil obtained by squeezing the ripe fruit of olives, and even if the oil film is exposed to air, it dries and changes to a resinous state. Since it has the characteristic that does not occur, it retains the moisturizing property of silicic acid (Na / Mg) even after the makeup is removed, and can moisturize the skin, so it is advantageously used in the present invention. can do.
次に、前記材料を用いて洗顔料を製造する好ましい配合比率を記述する。
ケイ酸(Na/Mg) 0.50〜4.00重量%
オレンジ油 0.50〜5.00重量%
オリーブ油 2.00〜5.00重量%
アルカリイオン水 残量
上記を混合攪拌して洗顔料とする。
Next, the preferable compounding ratio which manufactures a face wash using the said material is described.
Silicic acid (Na / Mg) 0.50-4.00% by weight
Orange oil 0.50-5.00% by weight
2.00 to 5.00% by weight of olive oil
Alkaline ion water
The above is mixed and stirred to obtain a face wash.
前記配合比率中、ケイ酸(Na/Mg)3.00重量%、オレンジ油2.00重量%、オリーブ油3.00重量%、アルカリイオン水92重量%を混合攪拌して得られた洗顔料を用いてテストした結果を、図1に示す写真により説明する。 A facial cleanser obtained by mixing and stirring 3.00% by weight of silicic acid (Na / Mg), 2.00% by weight of orange oil, 3.00% by weight of olive oil, and 92% by weight of alkaline ionized water in the above blending ratio. The results of testing using this will be described with reference to the photographs shown in FIG.
図1の(1)〜(5)は落ちにくいウォータープルーフのアイライナーで手の甲に少し太めに線を引いて、前記本発明製造方法によって得られた洗顔料で落とす行程写真である。図3の(1)は、前記アイライナーを手の甲に引いた状態、(2)は市販のクレンジングジェルを前記手の甲に引いたアイライナーの半分の部分まで塗布してなじませている状態、(3)は、前記市販のクレンジングジェルをなじませて、30秒後にマッサージするようにこするが、完全に落ちていない状態の写真である。(4)は、(3)の状態の手の甲に本発明製造方法によって得られた洗顔料を塗付した状態の写真であり、(5)は、前記本発明製造方法によって得られた洗顔料を塗布して、30秒程度なじませた後、軽くこするだけで完全にアイライナーを落とした状態を示す写真で、落とした後の肌にもしっとり感を与えることができた。 (1) to (5) in FIG. 1 are photographs of a process in which a slightly thick line is drawn on the back of the hand with a waterproof eyeliner that is hard to fall off, and the face wash is obtained with the face wash obtained by the production method of the present invention. (1) in FIG. 3 is a state in which the eyeliner is pulled on the back of the hand, (2) is a state in which a commercially available cleansing gel is applied to the half part of the eyeliner pulled on the back of the hand, and (3) ) Is a photograph of a state where the commercially available cleansing gel is applied and rubbed to massage after 30 seconds, but not completely dropped. (4) is a photograph of a state where the face wash obtained by the production method of the present invention is applied to the back of the hand in the state of (3), and (5) is a photo of the face wash obtained by the production method of the present invention. After applying and letting it fit for about 30 seconds, it was a photograph showing the state where the eyeliner had been completely removed by just rubbing it lightly.
前記図1の写真(1)〜(5)から、落ちにくいウォータープルーフのアイライナーを、前記本発明製造方法によって得られた洗顔料で、すべて落とすことができるということを立証することができた。なお、前記図1に示すようなテスト結果から、図示していないが、本発明製造方法によって得られた洗顔料で、前記ウォータープルーフのアイライナーより落とし易いと考えられる油性マジックインキ、口紅や、その他の化粧品についても、前記アイライナーと同様に、すべて落とすということが推測できる。 From the photographs (1) to (5) in FIG. 1, it was proved that the waterproof eyeliner that is hard to fall off can be removed with the face wash obtained by the production method of the present invention. . In addition, from the test results as shown in FIG. 1, although not shown, with the face wash obtained by the production method of the present invention, oily magic ink, lipstick, which is considered to be easier to remove than the waterproof eyeliner, It can be inferred that all other cosmetics will be removed as well as the eyeliner.
すなわち、図1に示すテスト結果から、前記本発明製造方法によって得られた洗顔料により、普通のメイクは勿論のこと、水や汗などにも強い落ちにくいメイクアップ化粧品であるウォータープルーフのアイライナーも、極めて簡単、確実、且つ迅速に落とすことができることが立証された。そして、前記テストは、ジェル化剤としてケイ酸(Na/Mg)を使用したもののみしかなされていないが、他の3つのジェル化剤であるカルボマー、カラギーナン、キサンタンガムは単なる肌への塗布を滑らか、且つ容易にするためのものであるので、これらを使用した場合についても、前記アルカリイオン水の外、主剤となる油性の汚れに対して優れた洗浄力をもつオレンジ油が必ず使用されているので、前記ケイ酸(Na/Mg)を使用したものと同様のメイクが落とし効果があるものであると推測できる。 That is, from the test results shown in FIG. 1, the waterproof eyeliner that is a makeup cosmetic that is resistant to water and sweat, as well as normal makeup, with the face wash obtained by the production method of the present invention. However, it has been proved that it can be removed very easily, reliably and quickly. In addition, the above test has only been made using silicic acid (Na / Mg) as a gelling agent, but the other three gelling agents, carbomer, carrageenan, and xanthan gum, are simply applied to the skin. In addition, even when these are used, orange oil having an excellent detergency against oily soil as the main agent is always used in addition to the alkaline ionized water. Therefore, it can be estimated that makeup similar to that using the above-mentioned silicic acid (Na / Mg) has a removing effect.
Claims (1)
An alkaline ionized water having a redox potential in the range of −250 mV to −700 mV and a pH of 8 to 12 is used as raw material water, and orange oil is blended therein as a main agent, and silicic acid derived from natural clay mineral as a gelling agent. A method for producing a facial cleanser using alkaline ionized water, wherein (Na / Mg) and natural-derived olive oil are blended and mixed and stirred as a non-drying agent.
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| JP (1) | JP2006225273A (en) |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2010077059A (en) * | 2008-09-25 | 2010-04-08 | Ai System Product:Kk | Percutaneous preparation |
| JP2011111436A (en) * | 2009-11-30 | 2011-06-09 | Aron World:Kk | Cosmetic composition using alkali ion water |
| JP2019077656A (en) * | 2017-10-26 | 2019-05-23 | 株式会社 ナチュラル | Production method of skin lotion or cosmetic comprising as raw material water, strong electrolytic alkaline reduction water in which reduction function is maintained for long term |
| JP7590848B2 (en) | 2020-10-05 | 2024-11-27 | 株式会社 アルマード | Gel-type cleansing cosmetics |
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| JPS6236310A (en) * | 1985-08-12 | 1987-02-17 | Seiken Kagaku Kk | Cleansing cosmetic |
| JPH06256792A (en) * | 1993-03-08 | 1994-09-13 | Honsyu Kosan Kk | Antimicrobial cleansing agent for medicinal use |
| JPH08509719A (en) * | 1993-04-30 | 1996-10-15 | スプリントベスト コーポレーション エヌ.ブイ. | Skin cleanser containing terpene solvent and corn meal scrubber |
| JPH11180849A (en) * | 1997-12-19 | 1999-07-06 | Lion Corp | Method for producing emulsified liquid containing clay mineral |
| JP2000103721A (en) * | 1998-09-30 | 2000-04-11 | Osaka Gas Co Ltd | Skin quality improver having alkali ion warm water |
| JP2002201491A (en) * | 2000-12-28 | 2002-07-19 | Noevir Co Ltd | Detergent composition |
| JP2002212591A (en) * | 2001-01-23 | 2002-07-31 | Biox:Kk | Detergent |
| JP2006169187A (en) * | 2004-12-17 | 2006-06-29 | Natural:Kk | Method for producing facial wash by using alkali ion water |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2010077059A (en) * | 2008-09-25 | 2010-04-08 | Ai System Product:Kk | Percutaneous preparation |
| JP2011111436A (en) * | 2009-11-30 | 2011-06-09 | Aron World:Kk | Cosmetic composition using alkali ion water |
| JP2019077656A (en) * | 2017-10-26 | 2019-05-23 | 株式会社 ナチュラル | Production method of skin lotion or cosmetic comprising as raw material water, strong electrolytic alkaline reduction water in which reduction function is maintained for long term |
| JP7045831B2 (en) | 2017-10-26 | 2022-04-01 | 株式会社 ナチュラル | A method for manufacturing cosmetics using strongly electrolytic alkaline reduced water that maintains the reducing function for a long period of time. |
| JP7590848B2 (en) | 2020-10-05 | 2024-11-27 | 株式会社 アルマード | Gel-type cleansing cosmetics |
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