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JP2011064976A - Display medium - Google Patents

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JP2011064976A
JP2011064976A JP2009216044A JP2009216044A JP2011064976A JP 2011064976 A JP2011064976 A JP 2011064976A JP 2009216044 A JP2009216044 A JP 2009216044A JP 2009216044 A JP2009216044 A JP 2009216044A JP 2011064976 A JP2011064976 A JP 2011064976A
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Prior art keywords
display
layer
substrate
display medium
bending
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Inventor
Mamoru Fujita
護 藤田
Taketo Hikiji
丈人 曳地
Masaaki Araki
雅昭 荒木
Koichi Haga
浩一 羽賀
Tadayoshi Ozaki
忠義 尾崎
Motohiko Sakamaki
元彦 酒巻
Hideo Kobayashi
英夫 小林
Kazuo Baba
和夫 馬場
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Fujifilm Business Innovation Corp
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Fuji Xerox Co Ltd
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Priority to JP2009216044A priority Critical patent/JP2011064976A/en
Publication of JP2011064976A publication Critical patent/JP2011064976A/en
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a display medium that ensures rigidity without degrading display characteristics as compared to a display medium having a coating member for coating a display area. <P>SOLUTION: The display medium 110 includes a pair of flexible substrates 10 and 20 that are disposed facing each other, a display layer 50 laminated between the pair of flexible substrates, and bending suppression means for suppressing bending of the substrates which is disposed only in a non-display region of at least one of the pair of flexible substrates. The bending suppression means is, for example, rod-shaped member 60A and 60B stuck on one of the substrates, or a hollow part, a convex part or a waveform part formed on one of the substrates. <P>COPYRIGHT: (C)2011,JPO&INPIT

Description

本発明は、表示媒体に関する。   The present invention relates to a display medium.

近年、液晶や有機エレクトロルミネッセンス素子等を用いた可撓性を有する表示媒体が種々開発されている。このような表示媒体は、例えば、樹脂フィルム上にITO(酸化インジウムスズ)などの透明電極のパターンを形成した一対の可撓性基板を用い、各電極が形成されている面をそれぞれ内側に向け、その対向する電極間に表示層を挟んで形成される。
例えば、光書き込み型の電子ペーパーでは書き込み装置との着脱が可能で、図8に示すようにそれぞれ光透過性を有する樹脂フィルム1,2に透明電極3,4が形成されている可撓性基板の間に有機光導電材料からなる光導電層5と、遮光層7と、液晶表示材料からなる液晶層6とが積層された表示層を挟み込むように構成されている。このような構成の光書き込み型の電子ペーパー100では、表裏の透明電極3,4に電圧を印加しながら光導電層5側の基板1から光を照射すると、光の強弱が瞬間的に液晶層6の反射濃度に変換されて基板2側に画像が表示される。
In recent years, various flexible display media using a liquid crystal, an organic electroluminescence element, or the like have been developed. Such a display medium uses, for example, a pair of flexible substrates in which a transparent electrode pattern such as ITO (indium tin oxide) is formed on a resin film, and the surface on which each electrode is formed faces inward. The display layer is sandwiched between the opposing electrodes.
For example, optical writing type electronic paper can be attached to and detached from a writing device. As shown in FIG. 8, a flexible substrate in which transparent electrodes 3 and 4 are formed on resin films 1 and 2 having optical transparency, respectively. A display layer in which a photoconductive layer 5 made of an organic photoconductive material, a light-shielding layer 7 and a liquid crystal layer 6 made of a liquid crystal display material are stacked is sandwiched therebetween. In the optical writing type electronic paper 100 having such a configuration, when light is irradiated from the substrate 1 on the photoconductive layer 5 side while applying a voltage to the transparent electrodes 3 and 4 on the front and back sides, the intensity of the light is instantaneously changed to the liquid crystal layer. 6 is converted to a reflection density of 6, and an image is displayed on the substrate 2 side.

樹脂フィルム1あるいは2の厚さを大きくした電子ペーパー、異方導電性層(部材)を樹脂フィルム1と2の間に挿入した電子ペーパーが提案されている(特許文献1参照)。
図8に示されるように電子ペーパー本体をカバーシート等の被覆部材8,9で覆って剛性を確保することが提案されている。
Electronic paper in which the thickness of the resin film 1 or 2 is increased and electronic paper in which an anisotropic conductive layer (member) is inserted between the resin films 1 and 2 have been proposed (see Patent Document 1).
As shown in FIG. 8, it has been proposed to secure rigidity by covering the electronic paper main body with covering members 8 and 9 such as a cover sheet.

例えば、薄板状の電子ペーパー本体と、熱可塑性フィルム基板に無機水蒸気バリア膜を積層して形成され、電子ペーパー本体を熱圧着により被覆する外装フィルム(被覆部材)と、熱圧着により外装フィルムが電子ペーパー本体の周縁角部に密着したときに外装フィルムに生じる応力を緩和する応力緩和部とを備えた電子ペーパーが提案されている(特許文献2参照)。また、可撓性を有する表示媒体及び表示媒体カバー(被覆部材)が、板ばねによって巻かれた状態で筐体に収容され、使用時には表示媒体と表示カバーが筐体から引き出されて板ばねによって固定される表示装置が提案されている(特許文献3参照)。   For example, a thin plate-shaped electronic paper main body, an exterior film (covering member) formed by laminating an inorganic water vapor barrier film on a thermoplastic film substrate, and covering the electronic paper main body by thermocompression bonding; There has been proposed an electronic paper including a stress relieving portion that relieves stress generated in an exterior film when the paper body is in close contact with the peripheral corner portion (see Patent Document 2). In addition, a flexible display medium and a display medium cover (covering member) are housed in a casing in a state of being wound by a leaf spring, and the display medium and the display cover are pulled out of the casing and used by the leaf spring in use. A fixed display device has been proposed (see Patent Document 3).

特開2001−92387号公報JP 2001-92387 A 特開2008−275684号公報JP 2008-275684 A 特表2008−530611号公報Special table 2008-530611 gazette

本発明は、表示領域を被覆する被覆部材を備えた表示媒体に比べ、表示特性を下げることなく剛性を確保した表示媒体を提供することを目的とする。   An object of the present invention is to provide a display medium that secures rigidity without deteriorating display characteristics as compared with a display medium that includes a covering member that covers a display area.

本発明では、以下の表示媒体が提供される。
請求項1の発明は、対向配置された一対の可撓性基板と、前記一対の可撓性基板の間に積層された表示層と、前記一対の可撓性基板のうち少なくとも一方の可撓性基板の非表示領域のみに設けられ、該基板の曲げを抑止する曲げ抑止手段と、を有する表示媒体である。
請求項2の発明は、前記曲げ抑止手段が、前記一方の可撓性基板に貼り付けた棒状部材、又は、前記一方の可撓性基板に形成した窪み部、凸部、もしくは波形部である請求項1に記載の表示媒体である。
請求項3の発明は、前記曲げ抑止手段が、前記一方の可撓性基板に形成した窪み部である請求項2に記載の表示媒体である。
請求項4の発明は、前記曲げ抑止手段が、表示領域を囲むように設けられている請求項1〜請求項3のいずれか一項に記載の表示媒体である。
請求項5の発明は、前記曲げ抑止手段が、表示領域を挟んで対向する位置に非対称の形状で設けられている請求項1〜請求項3のいずれか一項に記載の表示媒体である。
In the present invention, the following display medium is provided.
According to the first aspect of the present invention, at least one of the pair of flexible substrates, the display layer stacked between the pair of flexible substrates, and the flexible substrate is provided. A display medium having bending suppression means provided only in the non-display area of the conductive substrate and suppressing bending of the substrate.
According to a second aspect of the present invention, the bending suppressing means is a rod-shaped member attached to the one flexible substrate, or a depression, a convex, or a corrugated portion formed on the one flexible substrate. The display medium according to claim 1.
A third aspect of the present invention is the display medium according to the second aspect, wherein the bending restraining means is a recess formed in the one flexible substrate.
A fourth aspect of the present invention is the display medium according to any one of the first to third aspects, wherein the bending suppression means is provided so as to surround the display area.
A fifth aspect of the present invention is the display medium according to any one of the first to third aspects, wherein the bending suppression means is provided in an asymmetric shape at a position facing the display area across the display area.

請求項1に係る発明によれば、表示領域を被覆する被覆部材を備えた表示媒体に比べ、表示特性を下げることなく剛性を確保した表示媒体が提供される。
請求項2に係る発明によれば、より確実に剛性が高い表示媒体が提供される。
請求項3に係る発明によれば、基板に棒状部材を設ける場合や、予め凸部が形成された基板を用いる場合に比べ、厚みが薄く、複数枚積み重ねて保管する場合、表示媒体の窪み部に相当する凹凸が互いに合致するように重ねることで隙間なく重ねられる表示媒体が提供される。
請求項4に係る発明によれば、曲げ抑止手段が表示領域を囲むように設けられていない場合に比べ、より確実に剛性が高い表示媒体が提供される。
請求項5に係る発明によれば、曲げ抑止手段が表示領域を挟んで対称的に設けられている場合に比べ、左右の特定が容易な表示媒体が提供される。
According to the first aspect of the present invention, there is provided a display medium that secures rigidity without degrading display characteristics as compared with a display medium provided with a covering member that covers the display area.
According to the second aspect of the present invention, a display medium with higher rigidity is provided more reliably.
According to the third aspect of the present invention, when a bar-like member is provided on the substrate, or when a plurality of sheets are stacked and stored in comparison with the case where a substrate on which a convex portion is formed in advance is used, the depression portion of the display medium is used. A display medium is provided in which the projections and depressions corresponding to are overlapped with each other so as to coincide with each other.
According to the invention which concerns on Claim 4, compared with the case where a bending suppression means is not provided so that a display area may be enclosed, the display medium with higher rigidity is provided more reliably.
According to the invention which concerns on Claim 5, compared with the case where a bending suppression means is provided symmetrically on both sides of a display area, the display medium with which right and left specification is easy is provided.

本実施形態に係る表示媒体の構成の一例を示す概略図である。It is the schematic which shows an example of a structure of the display medium which concerns on this embodiment. 曲げ抑止手段の配置の他の例を示す概略図である。It is the schematic which shows the other example of arrangement | positioning of a bending suppression means. 曲げ抑止手段の配置の他の例を示す概略図である。It is the schematic which shows the other example of arrangement | positioning of a bending suppression means. 本実施形態に係る曲げ抑止手段の他の例を示す概略断面図である。It is a schematic sectional drawing which shows the other example of the bending suppression means which concerns on this embodiment. 本実施形態に係る曲げ抑止手段の他の例を示す概略断面図である。It is a schematic sectional drawing which shows the other example of the bending suppression means which concerns on this embodiment. 本実施形態に係る曲げ抑止手段の他の例を示す概略断面図である。It is a schematic sectional drawing which shows the other example of the bending suppression means which concerns on this embodiment. 本実施形態に係る曲げ抑止手段の他の例を示す概略断面図である。It is a schematic sectional drawing which shows the other example of the bending suppression means which concerns on this embodiment. 光書き込み型電子ペーパーを被覆部材で覆った表示媒体を示す概略図である。It is the schematic which shows the display medium which covered optical writing type electronic paper with the coating | coated member.

光書き込み型の電子ペーパーは、軽量で、可撓性を有し、書き換えを繰り返せる反面、可撓性を有するため応力が加わりやすい。しかし、例えば図8に示したように剛性を確保するための被覆部材8の厚みが大きいほど、光導電層5が光源から離れて解像度の低下が発生し易く、また、被覆部材9の厚みが大きいほど被覆部材9を通過する反射率も低下して、画像品質が低下する。特に拡散光を用いた面露光を使用する場合は光がさら被覆部材8内でさらに拡散して解像度の低下が顕著となる。一方、解像度の向上のために被覆部材の厚みを薄くすると剛性が保てず、例えば手で保持して画像や印字を正常に認識することは困難となる場合がある。
また剛性を確保するために、樹脂フィルム1の厚みを大きくした場合には、被覆部材8の厚みを大きくした場合と同様な問題が生じる。樹脂フィルム2の厚みを大きくした場合には、被覆部材9の厚みを大きくした場合と同様な問題が生じる。
さらに剛性を確保するために、新たな部材を挿入した場合には、書き込み時の印加電圧が上昇し、書き込み装置が大型化する場合がある。また製造上の工程が増え、製造コストが増大する場合がある。
Optical writing type electronic paper is lightweight and flexible, and can be rewritten repeatedly. However, since it has flexibility, stress is easily applied. However, for example, as shown in FIG. 8, the larger the thickness of the covering member 8 for securing rigidity, the more easily the photoconductive layer 5 is separated from the light source and the resolution is reduced. The larger the value, the lower the reflectance passing through the covering member 9 and the image quality is lowered. In particular, when surface exposure using diffused light is used, the light is further diffused in the covering member 8 and the resolution is significantly reduced. On the other hand, if the thickness of the covering member is reduced in order to improve the resolution, the rigidity cannot be maintained, and it may be difficult to normally recognize an image or print by holding it by hand.
Further, when the thickness of the resin film 1 is increased in order to ensure rigidity, the same problem as when the thickness of the covering member 8 is increased occurs. When the thickness of the resin film 2 is increased, the same problem as when the thickness of the covering member 9 is increased occurs.
Further, when a new member is inserted in order to ensure rigidity, the applied voltage at the time of writing increases, and the writing device may be enlarged. In addition, the manufacturing process may increase and the manufacturing cost may increase.

本実施形態に係る表示媒体は、対向配置されている一対の可撓性基板と、該一対の可撓性基板の間に積層された表示層と、該一対の可撓性基板のうち少なくとも一方の可撓性基板の非表示領域のみに設けられ、該基板の曲げを抑止する曲げ抑止手段と、を有する。
以下、実施形態について具体的に説明する。なお、実質的に同一の機能を有する部材については同じ符号を用い、説明を適宜省略する。
The display medium according to the present embodiment includes at least one of a pair of flexible substrates, a display layer stacked between the pair of flexible substrates, and the pair of flexible substrates. Bending restraining means provided only in the non-display area of the flexible substrate and restraining the bending of the substrate.
Hereinafter, embodiments will be specifically described. In addition, about the member which has the substantially same function, the same code | symbol is used and description is abbreviate | omitted suitably.

(1)第1実施形態
図1は、第1実施形態の表示媒体を概略的に示している。本実施形態に係る表示媒体110は、光書き込み型の電子ペーパーであり、光透過性を有する一対の可撓性基板10,20が対向配置されている。各基板10,20の表示層50側にはそれぞれ電極(不図示)が設けられている。2つの可撓性基板10,20の間には表示層として有機光導電材料を含む光導電層30と、液晶表示材料を含む液晶層40が積層されている。なお、光導電層30と液晶層40の間には例えば遮光層、などの機能層(不図示)が配置されていてもよい。
(1) First Embodiment FIG. 1 schematically shows a display medium according to a first embodiment. The display medium 110 according to the present embodiment is optical writing type electronic paper, and a pair of flexible substrates 10 and 20 having optical transparency are arranged to face each other. Electrodes (not shown) are respectively provided on the display layer 50 side of the substrates 10 and 20. Between the two flexible substrates 10 and 20, a photoconductive layer 30 including an organic photoconductive material and a liquid crystal layer 40 including a liquid crystal display material are stacked as a display layer. A functional layer (not shown) such as a light blocking layer may be disposed between the photoconductive layer 30 and the liquid crystal layer 40.

表示側の可撓性基板20には、基板10,20の曲げを抑止する曲げ抑止手段として非表示領域となる長手方向の両縁部に沿って棒状部材60A,60Bが貼り付けられている。このような構成の表示媒体110は、可撓性を確保しながら剛性もある程度確保されるとともに、剛性を確保するために被覆部材の厚みを厚くする場合に比べ、光導電層の書き込み解像度及び液晶層の反射率が向上して、表示特性が向上する。なお、表示特性の向上とは、例えば、表示むらが抑制されること、解像度が高いこと、反射率が高いこと、が挙げられる。
以下、各構成部材について具体的に説明する。
Bar-shaped members 60A and 60B are attached to the display-side flexible substrate 20 along both edges in the longitudinal direction serving as non-display areas as bending restraining means for restraining the bending of the substrates 10 and 20. The display medium 110 having such a configuration has a certain degree of rigidity while ensuring flexibility, and also has a higher resolution for writing the photoconductive layer and liquid crystal as compared with a case where the thickness of the covering member is increased in order to ensure rigidity. The reflectance of the layer is improved, and the display characteristics are improved. Note that the improvement of display characteristics includes, for example, suppression of display unevenness, high resolution, and high reflectance.
Hereinafter, each component will be specifically described.

<可撓性基板>
可撓性基板10,20としては、光透過性の樹脂フィルム(フィルム基板)が用いられる。具体的には、ポリエチレンテレフタレート、ポリスルホン、ポリエーテルスルホン、ポリカーボネート、ポリエチレンナフタレート等の高分子フィルムから構成されたものが用いられる。
なお、光書き込み型の電子ペーパーは、いわゆる表書き込み方式と裏書き込み方式がある。表書き込み方式では、例えば、表示側から、透明基板/液晶層/接着層/光導電層/遮光層/基板の順で積層された構成となり、非表示側の可撓性基板10は必ずしも光透過性を有する必要はない。一方、裏書き込み方式では、例えば、表示側から、透明基板/液晶層/接着層/遮光層/光導電層/透明基板の順で積層された構成となり、表裏両面の可撓性基板10,20は光透過性を有する基板を用いればよい。
<Flexible substrate>
As the flexible substrates 10 and 20, a light transmissive resin film (film substrate) is used. Specifically, those composed of a polymer film such as polyethylene terephthalate, polysulfone, polyethersulfone, polycarbonate, polyethylene naphthalate are used.
Note that optical writing type electronic paper includes a so-called front writing method and a reverse writing method. In the front writing method, for example, the transparent substrate / liquid crystal layer / adhesive layer / photoconductive layer / light-shielding layer / substrate are laminated in this order from the display side, and the flexible substrate 10 on the non-display side does not necessarily transmit light. It is not necessary to have sex. On the other hand, in the reverse writing method, for example, the transparent substrate / liquid crystal layer / adhesive layer / light-shielding layer / photoconductive layer / transparent substrate are laminated in this order from the display side. May be a substrate having optical transparency.

可撓性基板10,20の厚みは特に限定されないが、光書き込み側の基板10が厚過ぎると、特に面露光による書き込み時に解像度の低下を招くおそれがあり、表示側の基板20が厚過ぎると、液晶層40の反射率の低下を招くおそれがある。一方、カバーシート等の被覆部材を用いない場合は、外部からの衝撃から表示層50を保護するため、可撓性基板10,20自体、ある程度の強度が必要である。可撓性基板10,20の材質にもよるが、画質低下を抑制するとともに、表示層50を支持及び保護する強度、さらに、表示媒体の可撓性、軽量性等の観点から、可撓性基板10,20の厚みは、それぞれ例えば0.01mm以上0.5mm以下の範囲内とする。   The thickness of the flexible substrates 10 and 20 is not particularly limited. However, if the substrate 10 on the optical writing side is too thick, the resolution may be lowered particularly when writing by surface exposure. If the substrate 20 on the display side is too thick. There is a possibility that the reflectance of the liquid crystal layer 40 is lowered. On the other hand, when a covering member such as a cover sheet is not used, the flexible substrates 10 and 20 themselves need a certain degree of strength in order to protect the display layer 50 from an external impact. Although it depends on the material of the flexible substrates 10 and 20, it is flexible from the viewpoints of suppressing image quality deterioration, strength for supporting and protecting the display layer 50, and flexibility and lightness of the display medium. The thicknesses of the substrates 10 and 20 are each in the range of 0.01 mm to 0.5 mm, for example.

両基板10,20に設ける電極としては、光透過性の観点から、例えば、ITO(Indium Tin Oxide)を用いる。ITO以外にも、Auなどの金属薄膜、SnO、ZnOなどの酸化物、ポリピロールなどの導電性高分子の薄膜など、透光性の電気導電体を用いてもよい。各電極は、例えばスパッタリングによって樹脂フィルムの片面全体に形成される。印刷、CVD、蒸着などにより各電極を形成してもよい。
各電極の厚さは、例えば、10nm以上200nm以下の範囲内である。
As the electrodes provided on both the substrates 10 and 20, for example, ITO (Indium Tin Oxide) is used from the viewpoint of optical transparency. In addition to ITO, a light-transmitting electrical conductor such as a metal thin film such as Au, an oxide such as SnO 2 or ZnO, or a thin film of a conductive polymer such as polypyrrole may be used. Each electrode is formed on the entire surface of the resin film, for example, by sputtering. Each electrode may be formed by printing, CVD, vapor deposition, or the like.
The thickness of each electrode is, for example, in the range of 10 nm to 200 nm.

電極の形態及び駆動方式としては、例えば両電極共に各樹脂フィルム上で共通の電極とし、特開2003−140184号公報と特開2000−111942号公報とに記載の駆動方式が用いられる。あるいは、一対の電極の一方を表示媒体に表示する画像の各画素に共通の電極とし、他方を各画素に個別の電極とするセグメント駆動方式、両電極を互いに直交する方向に各々帯状に形成して、互いに対峙する位置を1つの画素に対応する領域とする単純マトリクス駆動方式、一方の電極を各画素に共通の電極とし、他方を互いに直交する帯状の走査電極及び信号電極からなるものとして、これにTFT等の能動素子を設けるアクティブマトリックス駆動方式等であってもよい。   As an electrode form and a driving method, for example, both electrodes are common electrodes on each resin film, and driving methods described in Japanese Patent Application Laid-Open Nos. 2003-140184 and 2000-111942 are used. Alternatively, one of a pair of electrodes is a common electrode for each pixel of an image displayed on a display medium, and the other is an individual electrode for each pixel. Both electrodes are formed in strips in directions perpendicular to each other. Thus, a simple matrix driving method in which the positions facing each other are regions corresponding to one pixel, one electrode is a common electrode for each pixel, and the other is composed of band-shaped scanning electrodes and signal electrodes orthogonal to each other, An active matrix driving system or the like in which an active element such as a TFT is provided may be used.

また、可撓性基板10,20には、ガス透過防止層(ガスバリア層)を設けることが望ましい。ガスバリア層は、水分や酸素の透過を抑制し、液晶層等の安定性を高める役割を有する。また、適宜、遮光層、密着力を向上させるためのアンカー層、絶縁層等、種々の機能層を設けてもよい。   The flexible substrates 10 and 20 are preferably provided with a gas permeation prevention layer (gas barrier layer). The gas barrier layer has a role of suppressing moisture and oxygen permeation and improving the stability of the liquid crystal layer and the like. Moreover, you may provide various functional layers suitably, such as a light shielding layer, the anchor layer for improving adhesive force, and an insulating layer.

ガスバリア層として、例えば酸化ケイ素・酸化アルミニウム系薄膜の形成には、真空蒸着法、スパッタリング法、イオンプレーティング法等の物理蒸着法、あるいはCVD等の化学蒸着法等が適宜用いられる。例えば真空蒸着法を採用する場合は、蒸着原料としてSiOとAlの混合物、あるいはSiOとAlの混合物等が用いられる。加熱には、抵抗加熱、誘導加熱、電子線加熱等が採用される。また、反応ガスとして酸素、窒素、水素、アルゴン、炭酸ガス、水蒸気等を導入したり、オゾン添加、イオンアシスト等の手段を用いた反応性蒸着を採用してもよい。
ガスバリア層の厚さは、例えば1nm以上500nm以下である。
For example, a vacuum deposition method, a sputtering method, a physical vapor deposition method such as an ion plating method, or a chemical vapor deposition method such as CVD is appropriately used for forming a silicon oxide / aluminum oxide thin film as the gas barrier layer. For example, when employing the vacuum evaporation method, a mixture of SiO 2 and Al, or a mixture of SiO 2 and Al 2 O 3 or the like is used as the deposition material. For heating, resistance heating, induction heating, electron beam heating or the like is employed. Alternatively, reactive vapor deposition using oxygen, nitrogen, hydrogen, argon, carbon dioxide gas, water vapor, or the like as a reactive gas, ozone addition, ion assist, or the like may be employed.
The thickness of the gas barrier layer is, for example, 1 nm or more and 500 nm or less.

<表示層>
表示層50は、表示媒体110の用途、目的等に応じて選択すればよい。例えば、光書き込み型の表示媒体とする場合は、両基板10,20の電極間に光導電層30と、遮光層と、液晶層40とが積層された構成の表示層50を設ける。
<Display layer>
The display layer 50 may be selected according to the use and purpose of the display medium 110. For example, in the case of an optical writing type display medium, a display layer 50 having a configuration in which a photoconductive layer 30, a light shielding layer, and a liquid crystal layer 40 are stacked is provided between the electrodes of both the substrates 10 and 20.

−光導電層−
光導電層30としては、(a)無機半導体材料として、アモルファス・シリコンや、ZnSe、CdSなどの化合物半導体からなる層、(b)有機半導体材料として、アントラセン、ポリビニルカルバゾールなどからなる層、(c)光照射によって電荷を発生する電荷発生材料及び電界によって電荷移動を生ずる電荷輸送材料の混合物や積層体からなるいわゆる有機光導電体層などが挙げられる。
-Photoconductive layer-
The photoconductive layer 30 includes: (a) a layer made of an amorphous semiconductor material such as amorphous silicon, ZnSe, or CdS as an inorganic semiconductor material; (b) a layer made of anthracene, polyvinylcarbazole, or the like as an organic semiconductor material; And a so-called organic photoconductor layer composed of a mixture or a laminate of a charge generation material that generates a charge by light irradiation and a charge transport material that generates a charge transfer by an electric field.

電荷発生材料としては、例えば、ペリレン系、フタロシアニン系、ビスアゾ系、ジチオピトケロピロール系、スクワリリウム系、アズレニウム系、チアピリリウム・ポリカーボネート系化合物などが挙げられる。また、電荷輸送材料としては、例えば、トリニトロフルオレン系、ポリビニルカルバゾール系、オキサジアゾール系、ピラリゾン系、ヒドラゾン系、スチルベン系、トリフェニルアミン系、トリフェニルメタン系、ジアミン系化合物や、LiClOを添加したポリビニルアルコ−ルやポリエチレンオキシドのようなイオン導電性材料などが、また電荷発生材と電荷輸送材との複合体として、積層体、混合物、マイクロカプセルなどが利用される。
光導電層30の厚さは、例えば1μm以上100μm以下の範囲とし、露光光照射時と露光光非照射時の抵抗比は大きい方が望ましい。
Examples of the charge generating material include perylene-based, phthalocyanine-based, bisazo-based, dithiopytochelopyrrole-based, squarylium-based, azurenium-based, and thiapyrylium / polycarbonate-based compounds. Examples of the charge transport material include trinitrofluorene-based, polyvinylcarbazole-based, oxadiazole-based, pyrarizone-based, hydrazone-based, stilbene-based, triphenylamine-based, triphenylmethane-based, diamine-based compounds, LiClO 4, and the like. A laminated body, a mixture, a microcapsule, or the like is used as an ion conductive material such as polyvinyl alcohol or polyethylene oxide to which is added, and as a composite of a charge generation material and a charge transport material.
The thickness of the photoconductive layer 30 is, for example, in the range of 1 μm or more and 100 μm or less, and it is desirable that the resistance ratio when the exposure light is irradiated and when the exposure light is not irradiated is large.

−遮光層−
遮光層は、非表示側からの透過光を遮光する目的で必要に応じて設けられ、外部光源等からなる読出光等の光や有機光導電体層を透過した露光光の波長の少なくとも一部を吸収し、電気抵抗が高い材料が用いられる。遮光層に必要な光学濃度は、光導電層の感度と読出光の強度に依存するため一概に限定されないが、少なくとも遮光すべき波長範囲において、望ましくは1以上、より望ましくは2以上である。また、遮光層の電気抵抗は、遮光層内の電流によって解像度の低下を引き起こさないように、少なくとも体積抵抗率で10Ω・cm以上とすることが望ましい。さらに、液晶層40に加わる分圧の変化分を大きくするためには、遮光層の静電容量が大きい程よいので、誘電率が大きく厚さが薄い方が望ましい。
遮光層の厚さは、例えば0.5μm以上3.0μm以下の範囲とする。
-Light shielding layer-
The light shielding layer is provided as necessary for the purpose of shielding the transmitted light from the non-display side, and at least a part of the wavelength of the exposure light transmitted through the organic photoconductor layer or the light such as the readout light from the external light source or the like A material having high electrical resistance is absorbed. The optical density required for the light shielding layer is not limited in general because it depends on the sensitivity of the photoconductive layer and the intensity of the readout light, but is preferably at least 1 and more preferably at least in the wavelength range to be shielded. The electrical resistance of the light shielding layer is preferably at least 10 8 Ω · cm in terms of volume resistivity so as not to cause a reduction in resolution due to current in the light shielding layer. Furthermore, in order to increase the change in the partial pressure applied to the liquid crystal layer 40, the larger the capacitance of the light shielding layer, the better. Therefore, it is desirable that the dielectric constant is large and the thickness is thin.
The thickness of the light shielding layer is, for example, in the range of 0.5 μm to 3.0 μm.

遮光層の素材は、黒色の素材であれば特に限定されるものではないが、例えば、以下のものが挙げられる。
1)カーボンブラック、アニリンブラックなどの有機顔料、CuO、MnO、Cr、Fe−Cr系顔料、Cu−Fe−Mn系顔料などの無機顔料などの黒色顔料を、アクリル樹脂、エポキシ樹脂、ポリエステル樹脂、ポリウレタン樹脂などの樹脂バインダ中に分散した黒色塗料
2)黒色染料で染色された樹脂
3)カーボンブラックなど黒色素材の蒸着膜
遮光層を水系塗料で形成する場合、そのバインダとしては水溶性樹脂、水/有機溶剤可溶樹脂、水系のエマルジョン・ディスパージョン・ラテックスなどが利用される。
The material of the light shielding layer is not particularly limited as long as it is a black material, and examples thereof include the following.
1) Organic pigments such as carbon black and aniline black, black pigments such as inorganic pigments such as CuO, MnO, Cr 2 O 3 , Fe—Cr pigments, Cu—Fe—Mn pigments, acrylic resins, epoxy resins, Black paint dispersed in resin binders such as polyester resin and polyurethane resin 2) Resin dyed with black dye 3) Vapor deposited film of black material such as carbon black When the light shielding layer is formed with water-based paint, the binder is water-soluble Resins, water / organic solvent-soluble resins, water-based emulsions, dispersions, and latexes are used.

−液晶層−
液晶層40には、例えばカイラルネマチック液晶(コレステリック液晶)をゼラチンバインダー中に分散させたPDLC(Polymer Network Liquid Crystal)構造が採用される。ただし、この構造に限ることなく、コレステリック液晶を隔壁を介し電極間距離を固定したセルに配置する方式やカプセル液晶化することにより実現してもよい。また、液晶もコレステリック液晶に限ることなく、スメクチックA液晶、ネマチック液晶、ディスコティック液晶などを利用してもよい。
-Liquid crystal layer-
For the liquid crystal layer 40, for example, a PDLC (Polymer Network Liquid Crystal) structure in which chiral nematic liquid crystal (cholesteric liquid crystal) is dispersed in a gelatin binder is employed. However, the present invention is not limited to this structure, and a cholesteric liquid crystal may be realized by a method in which a cholesteric liquid crystal is arranged in a cell having a fixed distance between electrodes through a partition wall or by a capsule liquid crystal. Further, the liquid crystal is not limited to the cholesteric liquid crystal, and a smectic A liquid crystal, a nematic liquid crystal, a discotic liquid crystal, or the like may be used.

液晶の光学的特性変化を補助する補助部材として、偏光板、位相差板、反射板などの受動光学部品と併用したり、液晶中に2色性色素を添加したりしてもよい。
液晶層40の厚さは、例えば1μm以上50μm以下の範囲とする。
As an auxiliary member that assists in changing the optical characteristics of the liquid crystal, it may be used in combination with a passive optical component such as a polarizing plate, a retardation plate, or a reflector, or a dichroic dye may be added to the liquid crystal.
The thickness of the liquid crystal layer 40 is, for example, in the range of 1 μm to 50 μm.

液晶材料としては、シアノビフェニル系、フェニルシクロヘキシル系、フェニルベンゾエート系、シクロヘキシルベンゾエート系、アゾメチン系、アゾベンゼン系、ピリミジン系、ジオキサン系、シクロヘキシルシクロヘキサン系、スチルベン系、トラン系など公知の液晶組成物が利用される。液晶材料には2色性色素などの色素、微粒子などの添加剤を加えてもよく、高分子マトリクス中に分散したものや、高分子ゲル化したものや、マイクロカプセル化したものでもよい。また、液晶は高分子、中分子、低分子のいずれでもよく、またこれらの混合物でもよい。   Liquid crystal materials include known liquid crystal compositions such as cyanobiphenyl, phenylcyclohexyl, phenylbenzoate, cyclohexylbenzoate, azomethine, azobenzene, pyrimidine, dioxane, cyclohexylcyclohexane, stilbene, and tolan. Is done. Additives such as dyes such as dichroic dyes and fine particles may be added to the liquid crystal material, and those dispersed in a polymer matrix, polymer gels, and microcapsules may be used. The liquid crystal may be a polymer, medium molecule, or low molecule, or a mixture thereof.

上記のような光導電層30と液晶層40とを有する表示層50とすれば、光導電層30に画像情報に対応する露光光を照射すると同時に、各可撓性基板10,20の電極に電圧を印加することで、メモリー性を有する液晶層40に画像パターンが記録される。この画像パターンは、外光を取り込んで反射させることで可視化される。   With the display layer 50 having the photoconductive layer 30 and the liquid crystal layer 40 as described above, the photoconductive layer 30 is irradiated with exposure light corresponding to image information, and at the same time, the electrodes of the flexible substrates 10 and 20 are applied. By applying a voltage, an image pattern is recorded on the liquid crystal layer 40 having a memory property. This image pattern is visualized by capturing external light and reflecting it.

<棒状部材>
曲げ抑止手段となる棒状部材60A,60Bは、非表示領域となる可撓性基板20の長手方向の両縁部に沿って接着剤、両面粘着テープ等を介して貼り付けられている。なお、本実施形態において「表示領域」とは可撓性基板の表示面からみて表示層が存在する領域と重なっている領域であり、画像、文字などの表示に供する領域を意味し、「非表示領域」とは可撓性基板の表示面からみて表示層が存在する領域と重なっていない領域のほか、可撓性基板の表示面からみて表示層が存在する領域と重なっていても画像、文字などの表示に供する必要のない領域を意味する。可撓性基板10,20の大きさにもよるが、例えば、基板20の各縁に沿って最外周から内側の30mm以内の領域を非表示領域とすればよい。
<Bar-shaped member>
The rod-shaped members 60A and 60B that serve as bending restraining means are attached via adhesives, double-sided adhesive tape, and the like along both longitudinal edges of the flexible substrate 20 that serves as a non-display area. In the present embodiment, the “display area” is an area that overlaps the area where the display layer is present when viewed from the display surface of the flexible substrate, and means an area for displaying images, characters, etc. The display area is an area that does not overlap the area where the display layer is present when viewed from the display surface of the flexible substrate, or an image that overlaps the area where the display layer is present when viewed from the display surface of the flexible substrate. It means an area that does not need to be used for displaying characters. Although depending on the size of the flexible substrates 10 and 20, for example, a region within 30 mm inside from the outermost periphery along each edge of the substrate 20 may be set as a non-display region.

本実施形態における棒状部材60A,60Bは半円又は半楕円形状の断面を有し、基板20の長手方向に沿って配置されているが、基板の曲げを抑止する硬度を有していれば、その材質、断面形状、長さ、幅等は限定されず、基板の材質、大きさ、形状などに応じて適宜選択すればよい。例えば、円形、多角形等の断面形状を有する棒状部材を用いてもよい。また、基板20の各辺において棒状部材が複数に分離又は分割された状態で設けられていても良い。   The rod-shaped members 60A and 60B in the present embodiment have a semicircular or semi-elliptical cross section and are arranged along the longitudinal direction of the substrate 20, but if they have a hardness that suppresses bending of the substrate, The material, cross-sectional shape, length, width, and the like are not limited, and may be appropriately selected according to the material, size, shape, and the like of the substrate. For example, a rod-shaped member having a cross-sectional shape such as a circle or a polygon may be used. Moreover, the rod-shaped member may be provided in a state of being separated or divided into a plurality on each side of the substrate 20.

棒状部材60A,60Bは、光透過性は要求されないため、基板の曲げを抑止する硬度を有していれば、棒状部材を構成する材料は特に限定されない。なお、曲げを抑止する観点から、可撓性基板20よりも硬度が高い材質を選択することが望ましい。例えば、アクリル、ポリプロピレン、ポリエチレンなどの汎用樹脂やエンジニアリングプラスチックなどの高分子材料のほか、鉄、アルミニウムなどの金属材料、木、セラミックなどを用いてもよい。   Since the rod-shaped members 60A and 60B are not required to transmit light, the material constituting the rod-shaped member is not particularly limited as long as it has a hardness that suppresses bending of the substrate. From the viewpoint of suppressing bending, it is desirable to select a material having a higher hardness than the flexible substrate 20. For example, a general-purpose resin such as acrylic, polypropylene, or polyethylene, or a polymer material such as engineering plastic, a metal material such as iron or aluminum, wood, or ceramic may be used.

棒状部材60A,60Bは、非表示領域であればどの部分に配置してもよく、例えば可撓性基板10,20が矩形であれば、長辺方向及び短辺方向のいずれかの1辺に設けることで曲げ抑止手段として機能する。例えば、基板20の長辺方向又は短辺方向の両縁に沿って表示領域を挟んで対向する位置にそれぞれ棒状部材60A,60Bを設ければ棒状部材60A,60Bが配置されている方向への曲げがより確実に抑制されることになる。   The rod-shaped members 60A and 60B may be arranged in any part as long as they are non-display areas. For example, if the flexible substrates 10 and 20 are rectangular, the rod-shaped members 60A and 60B are arranged on one side in either the long side direction or the short side direction. By providing, it functions as a bending suppression means. For example, if the rod-shaped members 60A and 60B are provided at positions facing each other across the display area along both the long side direction or the short side direction of the substrate 20, the direction in which the rod-shaped members 60A and 60B are arranged is provided. Bending is more reliably suppressed.

また、例えば、図2に示すように、表示領域70を囲むように長辺方向及び短辺方向の両縁に沿ってそれぞれ棒状部材60A,60B,60C,60Dを設けてもよい。この場合、四方にわたって剛性が付与され、曲げがより確実に抑制され、表示むらも抑制されることになる。   For example, as shown in FIG. 2, rod-shaped members 60 </ b> A, 60 </ b> B, 60 </ b> C, and 60 </ b> D may be provided along both edges in the long side direction and the short side direction so as to surround the display region 70. In this case, rigidity is provided in all directions, bending is more reliably suppressed, and display unevenness is also suppressed.

また、図3に示すように、棒状部材62,64が、表示領域70を挟んで対向する位置に非対称の形状で設けられていてもよい。可撓性基板20の両縁に沿って非対称の形状を有する棒状部材62,64が設けられていれば、例えば、電波による個体識別(RFID)用のタグ72を表示媒体の上下左右のいずれかに偏った位置に設けても、タグ72の位置を容易に特定することが可能となる。例えば、本実施形態に係る表示媒体を、光書き込みを行う装置に嵌め込んで書き込みを行う構成の場合、書き込み装置側に棒状部材62,64の差を認識できるような機構を設ければ、挿入方向を間違えて個体識別(RFID)用のタグ72が認識されないことが防止される。棒状部材62,64の差を認識できる機構として、挿入できないように確実に嵌合される形状にしても良いし、光センサーなどの形状を検出できる手段を光書き込み装置に設けて、間違った方向に挿入された場合エラー表示を行うようにしてもよい。   Further, as shown in FIG. 3, the rod-shaped members 62 and 64 may be provided in an asymmetric shape at positions facing each other with the display region 70 interposed therebetween. If rod-like members 62 and 64 having asymmetric shapes are provided along both edges of the flexible substrate 20, for example, an individual identification (RFID) tag 72 by radio waves is placed on either the upper, lower, left or right side of the display medium. Even if it is provided at a position deviated from the above, the position of the tag 72 can be easily specified. For example, in the case where the display medium according to the present embodiment is inserted into a device that performs optical writing and writing is performed, if a mechanism capable of recognizing the difference between the rod-like members 62 and 64 is provided on the writing device side, the display medium is inserted. It is possible to prevent the individual identification (RFID) tag 72 from being recognized in the wrong direction. As a mechanism capable of recognizing the difference between the rod-like members 62 and 64, it may be a shape that can be securely fitted so that it cannot be inserted, or a means that can detect the shape of an optical sensor or the like is provided in the optical writing device so that the wrong direction is obtained. An error may be displayed when it is inserted.

また、棒状部材62,64は、表示側の基板20に設けることに限定されず、光書き込み側の基板10に設けてもよいし、両基板10,20に設けてもよい。光書き込み装置側で棒状部材と干渉しないような設計にしてもよいが、簡単な構成とする場合には、棒状部材60A,60Bが邪魔にならないように書き込み方式(表書き込み方式又は裏書き込み方式)に応じて一方の基板側に設けることが望ましい。例えば、裏書き込み方式では、図1に示すように表示側の基板20の非表示領域のみに棒状部材60A,60Bを設けることで、光書き込み側の基板10からの書き込み時に棒状部材60A,60Bが邪魔になることが防止され、解像度がより確実に向上される。   Further, the rod-shaped members 62 and 64 are not limited to being provided on the display-side substrate 20, and may be provided on the optical writing-side substrate 10 or on both the substrates 10 and 20. The optical writing device may be designed so as not to interfere with the rod-shaped member, but in the case of a simple configuration, the writing method (front writing method or reverse writing method) is used so that the rod-shaped members 60A and 60B do not get in the way. Depending on the situation, it is desirable to provide it on one substrate side. For example, in the reverse writing method, as shown in FIG. 1, the rod-shaped members 60A and 60B are provided only in the non-display area of the display-side substrate 20, so that the rod-shaped members 60A and 60B can be used when writing from the substrate 10 on the optical writing side. It is prevented from getting in the way, and the resolution is more reliably improved.

曲げ抑止手段は棒状部材60A,60Bに限らず、他の形態を採用してもよい。以下に説明する各実施形態では、可撓性基板、電極、液晶層、光導電層、遮光層等については第1実施形態と同様であるので、適宜説明を省略する。また、曲げ抑止手段を設ける位置も棒状部材60A,60Bを設ける場合と同様に適用されるため、適宜説明を省略する。   The bending suppressing means is not limited to the rod-shaped members 60A and 60B, and other forms may be adopted. In each embodiment described below, a flexible substrate, an electrode, a liquid crystal layer, a photoconductive layer, a light shielding layer, and the like are the same as those in the first embodiment, and thus description thereof will be omitted as appropriate. Further, the position where the bending prevention means is provided is also applied in the same manner as the case where the rod-shaped members 60A and 60B are provided, and thus description thereof will be omitted as appropriate.

(2)第2実施形態
図4は、第2実施形態に係る表示媒体の厚さ方向の断面を概略的に示している。この表示媒体120は、表示側の可撓性基板20の長手方向の両縁に沿って凸部22A,22Bが設けられている。このような凸部22A,22Bが予め形成されている可撓性基板20を用いれば、凸部22A,22Bが曲げ抑止手段として機能する。なお、凸部22A,22Bの形状は図4に示すような半円形の断面形状を有するものに限らず、例えば、円形、多角形などの他の断面形状を有するものでもよい。
(2) Second Embodiment FIG. 4 schematically shows a cross section in the thickness direction of a display medium according to a second embodiment. The display medium 120 is provided with convex portions 22A and 22B along both longitudinal edges of the flexible substrate 20 on the display side. If the flexible board | substrate 20 with which such convex parts 22A and 22B are formed previously is used, convex parts 22A and 22B will function as a bending suppression means. The shape of the protrusions 22A and 22B is not limited to a semicircular cross-sectional shape as shown in FIG. 4, and may have another cross-sectional shape such as a circle or a polygon.

また、曲げ抑止手段となる凸部22A,22Bを設ける側は特に限定されず、書き込み側の基板10あるいは両基板10,20に凸部22A,22Bが形成されていてもよい。光書き込み装置側で凸部22A,22Bと干渉しないような設計にしてもよいが、簡単な構成とする場合には、書き込み側の基板側からの光書き込み時に凸部22A,22Bが邪魔になることを防ぐため、図4に示すように、光書き込み側の基板10は凸部の無い平坦な可撓性基板であり、表示側の基板10は長手方向の両縁に沿って凸部22A,22Bを有する可撓性基板を用いることが望ましい。
本実施形態に係る表示媒体120を製造する場合は、片面に凸部22A,22Bが予め形成された可撓性基板20を用い、対向配置される可撓性基板10,20の間に、第1電極、光導電層30、遮光層、液晶層40、及び第2電極が順次積層された構成となるように製造すればよい。
Further, the side on which the convex portions 22A and 22B serving as bending restraining means are provided is not particularly limited, and the convex portions 22A and 22B may be formed on the substrate 10 on the writing side or both the substrates 10 and 20. The optical writing device may be designed so as not to interfere with the convex portions 22A and 22B. However, in the case of a simple configuration, the convex portions 22A and 22B become an obstacle at the time of optical writing from the substrate side on the writing side. In order to prevent this, as shown in FIG. 4, the substrate 10 on the optical writing side is a flat flexible substrate having no projections, and the substrate 10 on the display side has projections 22A, 22A, It is desirable to use a flexible substrate having 22B.
When the display medium 120 according to the present embodiment is manufactured, the flexible substrate 20 in which the convex portions 22A and 22B are formed in advance on one side is used, and the first and second flexible substrates 10 and 20 are disposed between the flexible substrates 10 and 20. What is necessary is just to manufacture so that it may become the structure by which 1 electrode, the photoconductive layer 30, the light shielding layer, the liquid crystal layer 40, and the 2nd electrode were laminated | stacked one by one.

(3)第3実施形態
図5は、第3実施形態に係る表示媒体の厚さ方向の断面を概略的に示している。この表示媒体130では、可撓性基板10の長手方向の両縁に沿って窪み部12A,12Bが設けられている。この場合、窪み部12A,12Bが曲げ抑止手段として機能するため、被覆部材を設けなくてもある程度の剛性が付与されるとともに、画質低下が抑制されることになる。
本実施形態に係る表示媒体130を製造する場合は、例えば、可撓性基板10,20の少なくとも長手方向又は短手方向の両縁に沿って、表示層(光導電層30及び液晶層40)を設けずに非表示領域とし、必要に応じて接着剤等を介して両基板10,20を非表示領域となる両縁に沿って張り合わせ、両縁に沿って窪み部12A,12Bが形成されるようにプレス加工を行う。基板10,20間に接着剤を設けず、プレス加工とともに基板10,20同士を溶着させてもよい。
(3) Third Embodiment FIG. 5 schematically shows a cross section in the thickness direction of a display medium according to a third embodiment. In the display medium 130, recesses 12 </ b> A and 12 </ b> B are provided along both longitudinal edges of the flexible substrate 10. In this case, since the depressions 12A and 12B function as bending restraining means, a certain degree of rigidity is imparted and image quality deterioration is suppressed without providing a covering member.
In the case of manufacturing the display medium 130 according to the present embodiment, for example, the display layer (the photoconductive layer 30 and the liquid crystal layer 40) is provided along at least both the longitudinal or lateral edges of the flexible substrates 10 and 20. The non-display area is not provided, and if necessary, the two substrates 10 and 20 are bonded to each other along both edges of the non-display area via an adhesive or the like, and the recessed portions 12A and 12B are formed along both edges. Press work as shown. The adhesive may not be provided between the substrates 10 and 20, and the substrates 10 and 20 may be welded together with the pressing.

なお、可撓性基板10自体に窪み部12A,12Bを設ければ、基板に棒状部材60A,60Bを設ける場合や、予め凸部22A,22Bが形成された基板を用いる場合に比べて、複数枚積み重ねて保管する場合、厚みを薄く出来て保管スペースを少なく出来る。例えば媒体の上側で窪み部の凸部となるように積み重ねれば、その上に重なる媒体の下側が窪み部の凹部となるので、隙間なく重ねられる。   If the recesses 12A and 12B are provided on the flexible substrate 10 itself, a plurality of portions are provided as compared with the case where the rod-shaped members 60A and 60B are provided on the substrate or the case where the substrate on which the protrusions 22A and 22B are previously formed is used. When stacking and storing, the thickness can be reduced and the storage space can be reduced. For example, if stacking is performed so as to be the convex portion of the recessed portion on the upper side of the medium, the lower side of the medium overlapping therewith becomes the concave portion of the recessed portion, so that they are stacked without a gap.

(4)第4実施形態
図6は、第4実施形態に係る表示媒体の厚さ方向の断面を概略的に示している。この表示媒体140は、可撓性基板10,20の全面に表示層(光導電層30及び液晶層40)が設けられ、可撓性基板10,20は表示層30,40とともに長手方向の両縁に沿って窪み部12A,12Bが形成されている。本実施形態に係る表示媒体140も、窪み部12A,12Bが曲げ抑止手段として機能し、被覆部材を設けなくてもある程度の剛性が付与されるとともに、画質低下が抑制されることになる。
(4) Fourth Embodiment FIG. 6 schematically shows a cross section in the thickness direction of a display medium according to a fourth embodiment. In this display medium 140, display layers (the photoconductive layer 30 and the liquid crystal layer 40) are provided on the entire surfaces of the flexible substrates 10 and 20, and the flexible substrates 10 and 20 together with the display layers 30 and 40 are both in the longitudinal direction. Indentations 12A and 12B are formed along the edges. Also in the display medium 140 according to the present embodiment, the depressions 12A and 12B function as bending restraining means, and a certain degree of rigidity is imparted and image quality deterioration is suppressed without providing a covering member.

両基板10,20間の全面に表示層30,40が挟まれるように配置した後、プレス加工によって表示層30,40とともに窪み部12A,12Bを形成すればよい。なお、窪み部12A,12Bを設ける側は特に限定されないが、一方の基板側に設けた窪み部12A,12Bに応じて反対側の基板には凸部が形成されることになるため、光書き込み装置側で窪み部12と干渉しないような設計してもよいが、簡単な構成とする場合には、凸部が光書き込み時に邪魔にならないように、光書き込み側の基板10に窪み部12A,12Bを設けることが望ましい。   After arranging the display layers 30 and 40 so as to be sandwiched between the entire surfaces of the substrates 10 and 20, the depressions 12A and 12B may be formed together with the display layers 30 and 40 by pressing. Note that the side on which the recesses 12A and 12B are provided is not particularly limited, but a convex portion is formed on the opposite substrate in accordance with the recesses 12A and 12B provided on one substrate side. Although it may be designed so as not to interfere with the depression 12 on the apparatus side, in the case of a simple configuration, the depressions 12A, 12A and 12A are formed on the substrate 10 on the optical writing side so that the convex portion does not interfere with optical writing. It is desirable to provide 12B.

(5)第5実施形態
図7は、第5実施形態に係る表示媒体の厚さ方向の断面を概略的に示している。この表示媒体150は、可撓性基板10,20の両縁に沿って波形部14A,14Bが設けられている。可撓性基板10,20の非表示領域に設けた波形部14A,14Bも曲げ抑止手段として機能し、被覆部材を設けなくてもある程度の剛性が付与されるとともに、表示特性の低下が抑制されることになる。
本実施形態に係る表示媒体150を製造する場合は、必要に応じて可撓性基板10,20間に接着剤を付与して張り合わせ、非表示領域となる両縁に沿ってプレス加工によって波形部14A,14Bを形成すればよい。
(5) Fifth Embodiment FIG. 7 schematically shows a cross section in the thickness direction of a display medium according to a fifth embodiment. The display medium 150 is provided with corrugated portions 14A and 14B along both edges of the flexible substrates 10 and 20. The corrugated portions 14A and 14B provided in the non-display areas of the flexible substrates 10 and 20 also function as bending suppressing means, and a certain degree of rigidity is given without providing a covering member, and a decrease in display characteristics is suppressed. Will be.
When manufacturing the display medium 150 according to the present embodiment, an adhesive is applied between the flexible substrates 10 and 20 as necessary, and the corrugated portions are pressed by pressing along both edges that become non-display areas. 14A and 14B may be formed.

以上の説明では、光書き込み型の表示媒体(電子ペーパー)について主に説明したが、本発明はこれに限定されず、対向配置された可撓性基板間に、例えば、有機電界発光素子、マイクロカプセル等の表示層を設けて表示を行う表示媒体に適用してもよい。
また、例えば、電極をストライプ状に加工して単純マトリクス型の表示素子としてもよい。あるいは表示と反対側の面の基板上に薄膜トランジスタ、薄膜ダイオードなどの能動素子を設けてアクティブマトリクス駆動型の表示媒体としてもよい。
また、曲げ抑止手段も例示したものに限定されず、他の形態を採用してもよい。
In the above description, the optical writable display medium (electronic paper) has been mainly described. However, the present invention is not limited to this. For example, an organic electroluminescent element or a micro-device is provided between the flexible substrates opposed to each other. You may apply to the display medium which provides a display layer, such as a capsule, and displays.
Further, for example, the electrodes may be processed into a stripe shape to form a simple matrix display element. Alternatively, an active element such as a thin film transistor or a thin film diode may be provided on a substrate on the surface opposite to the display to form an active matrix drive type display medium.
Further, the bending suppressing means is not limited to the illustrated one, and other forms may be adopted.

10,20 可撓性基板
12A,12B 窪み部
14A,14B 波形部
22A,22B 凸部
30 光導電層
40 液晶層
50 表示層
60A,60B,60C,60D 棒状部材
62,64 棒状部材
70 表示領域
110,120,130,140,150 表示媒体
10, 20 Flexible substrate 12A, 12B Depression 14A, 14B Waveform 22A, 22B Convex 30 Photoconductive layer 40 Liquid crystal layer 50 Display layer 60A, 60B, 60C, 60D Bar-shaped member 62, 64 Bar-shaped member 70 Display area 110 , 120, 130, 140, 150 Display media

Claims (5)

対向配置された一対の可撓性基板と、
前記一対の可撓性基板の間に積層された表示層と、
前記一対の可撓性基板のうち少なくとも一方の可撓性基板の非表示領域のみに設けられ、該基板の曲げを抑止する曲げ抑止手段と、を有する表示媒体。
A pair of opposing flexible substrates;
A display layer laminated between the pair of flexible substrates;
A display medium, comprising: a bending suppression means that is provided only in a non-display area of at least one of the pair of flexible substrates and suppresses bending of the substrate.
前記曲げ抑止手段が、前記一方の可撓性基板に貼り付けた棒状部材、又は、前記一方の可撓性基板に形成した窪み部、凸部、もしくは波形部である請求項1に記載の表示媒体。   2. The display according to claim 1, wherein the bending suppression means is a rod-like member attached to the one flexible substrate, or a depression, a convex, or a corrugated portion formed on the one flexible substrate. Medium. 前記曲げ抑止手段が、前記一方の可撓性基板に形成した窪み部である請求項2に記載の表示媒体。   The display medium according to claim 2, wherein the bending prevention means is a depression formed in the one flexible substrate. 前記曲げ抑止手段が、表示領域を囲むように設けられている請求項1〜請求項3のいずれか一項に記載の表示媒体。   The display medium according to any one of claims 1 to 3, wherein the bending suppression means is provided so as to surround a display area. 前記曲げ抑止手段が、表示領域を挟んで対向する位置に非対称の形状で設けられている請求項1〜請求項3のいずれか一項に記載の表示媒体。   The display medium according to any one of claims 1 to 3, wherein the bending suppression means is provided in an asymmetric shape at positions facing each other across the display area.
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