JP2011177603A - Electrode well constituting pipe and method for producing the same - Google Patents
Electrode well constituting pipe and method for producing the same Download PDFInfo
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Abstract
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本発明は、汚染された土壌を原位置で浄化処理する工法において地盤に設置される電極井戸を構成する管材に関する。 The present invention relates to a pipe material constituting an electrode well installed on the ground in a method for purifying contaminated soil in situ.
重金属や有機化合物による土壌汚染が発見された場合の対策として、汚染された土壌を含む地盤を掘削して場外に持ち出す方法や固化剤で固めて原位置で不溶化する工法、汚染が広がらないように鋼板を地盤に打ち込んで原位置に封じ込める方法などが知られているが、地盤を掘削したり鋼板を打ち込んだりするのには大規模な工事が必要となり、また、これらの何れの方法も土壌の汚染そのものを除去するものではなく、場外に持ち出したとしても汚染された土壌は残存したままであり土壌を浄化する根本的な解決策とはなっていない。 As countermeasures when soil contamination by heavy metals or organic compounds is discovered, methods such as excavating the ground containing contaminated soil and taking it out of the field, solidifying it with a solidifying agent to insolubilize it in situ, and preventing contamination from spreading There are known methods of driving steel plates into the ground and confining them in place, but large-scale construction is required to excavate the ground and drive steel plates. It does not remove the pollution itself, and even if it is taken out of the field, the contaminated soil remains and is not a fundamental solution to purify the soil.
そこで、土壌の汚染を根本的に除去し、それも原位置で浄化する方法として、図3に示されるように、汚染された土壌を含む地盤に電極井戸と呼ばれる電極を埋設し、電極井戸内に注入された電解液を介して直流電流を流すことにより土壌のphを調節して地中に含まれる電荷を持つ性質の汚染物質をイオン化し、電解液中に溶け込んだ汚染物質イオンを回収して土壌を浄化する汚染土壌の原位置浄化技術(電気修復法)が実用化されつつある。 Therefore, as a method of fundamentally removing soil contamination and purifying it in situ, as shown in FIG. 3, an electrode called an electrode well is buried in the ground containing the contaminated soil, By adjusting the pH of the soil by flowing a direct current through the electrolyte injected into the soil, it ionizes the contaminants with the charge contained in the ground, and collects the contaminant ions dissolved in the electrolyte. In-situ purification technology (electric remediation method) for contaminated soil is being put into practical use.
この原位置浄化技術で地盤に埋設される電極井戸は、通水性を備えた円筒管の内部に電極を配し、電極に向かって移動する土壌中の汚染物質イオンを円筒管内に取り込み、電解液中に溶け込ませて管口からを回収することができるように構成されており、前記円筒管には周面に多数の孔を設けた合成樹脂管や、管壁が多孔質状のセラミック管或いはメッシュ状に形成されたもの、前記合成樹脂管の内周面を半透過性膜で覆った構造のものなどが利用されている(例えば特許文献1〜4参照)。 Electrode wells buried in the ground by this in-situ purification technology have an electrode placed inside a cylindrical tube with water permeability, take in pollutant ions in the soil moving toward the electrode into the cylindrical tube, It is constructed so that it can be dissolved in and recovered from the tube opening, and the cylindrical tube has a synthetic resin tube provided with a large number of holes in its peripheral surface, a ceramic tube having a porous tube wall, The thing formed in the mesh shape, the structure which covered the inner peripheral surface of the said synthetic resin pipe | tube with the semipermeable membrane, etc. are utilized (for example, refer patent documents 1-4).
電極井戸の円筒管として多数の通孔が空けられた合成樹脂管を用いた場合、円筒管内に注入した電解液が通孔から地中に漏出し易く、そのため円筒管内に電荷液を常時補充する必要があり、また、汚染物質イオンとともに土壌や塵埃の成分が円筒管内に入り込んで電解液中に溶け込んでしまい、汚染物質を回収する際に電解液中の汚染物質イオンとそれ以外のものとを分離する処理工程が必要となる。
円筒管として管壁が多孔質状やメッシュ状の管材を用いれば、電解液の漏出が少なく汚染物質イオンのみ管壁を透過させて回収することが可能であるが、これらのものは長尺に成形することが難しく、成形コストも高くならざるを得ない。電極井戸は浄化対象の土壌の深さに応じた深さに埋設する必要があるが、前記管材では数メートルに及ぶ長尺のものを成形することが難しく、管材同士を連結して長尺に構成することもできないため、浄化可能な深さも制限されてしまう。また、多孔質管やメッシュ管は、集中的な荷重に弱く、端部が欠けたり割れたりし易く、土圧によって押し潰されることともあるため、施工時の運搬や据え付け、埋設などの場面で取り扱いに細心の注意が必要であり、施工性が悪いという問題がある。
合成樹脂管の内周面を半透過性膜で覆った構造のものは、多孔質管などよりも施工性が良いものの、成形が難しく、且つコストが嵩み、半透過性膜が剥がれやすいなどの耐久性の点でも問題があり、実用性に欠ける。
When a synthetic resin tube with a large number of through holes is used as the cylindrical tube of the electrode well, the electrolyte injected into the cylindrical tube is likely to leak into the ground from the through hole, so that the charged liquid is always replenished into the cylindrical tube. In addition, the soil and dust components enter the cylindrical tube together with the contaminant ions and dissolve in the electrolyte, and when collecting the contaminants, the contaminant ions in the electrolyte and others A separate process step is required.
If a tube with a porous or meshed tube wall is used as the cylindrical tube, it is possible to collect only contaminant ions through the tube wall with little leakage of the electrolyte solution. Molding is difficult and the molding cost must be high. It is necessary to bury the electrode well at a depth corresponding to the depth of the soil to be purified, but it is difficult to form a long length of several meters with the above-mentioned pipe material. Since it cannot be constructed, the purifiable depth is limited. Porous pipes and mesh pipes are vulnerable to intensive loads, their ends are easily chipped and cracked, and may be crushed by earth pressure. Careful handling is required, and there is a problem that workability is poor.
The structure with the inner peripheral surface of the synthetic resin tube covered with a semipermeable membrane is better in workability than a porous tube, etc., but is difficult to mold and expensive, and the semipermeable membrane is easy to peel off. There is also a problem in terms of durability and lacks practicality.
本発明は従来技術の有するこのような問題点に鑑み、電解液を漏出させずに土中から汚染物質イオンのみを透過させて回収することができ、浄化化対象の土壌の深さに応じた長さのものに容易に構成可能で施工性に優れた電極井戸の構成管を得ることを課題とする。 In view of such a problem of the prior art, the present invention can be recovered by allowing only contaminant ions to permeate from the soil without leaking the electrolyte, and according to the depth of the soil to be purified. It is an object of the present invention to obtain an electrode well constituent tube that can be easily configured to have a long length and is excellent in workability.
前記課題を解決するための本発明は、汚染土壌の原位置浄化に用いる電極井戸構成管において、周面に複数の通孔が形成された硬質合成樹脂管の内周面に多孔質合成樹脂管の外周面を接合し密着させて構成してあることを特徴とする。 The present invention for solving the above-mentioned problems is a porous synthetic resin tube on the inner peripheral surface of a hard synthetic resin tube in which a plurality of through holes are formed on the peripheral surface in an electrode well constituting tube used for in-situ purification of contaminated soil. It is characterized in that the outer peripheral surfaces of the two are joined and brought into close contact with each other.
前記構成において、硬質合成樹脂管はJIS規格に沿って成形された、ポリ塩化ビニル或いはその他の樹脂材料からなる円筒管材を用いることが好ましい。
JIS規格品の管材を用いることで汎用の継手やキャップなどの付属品を利用して電極井戸を安価に構成することができ、また、前記継手で管材同士を連結し長さを調整するなどの加工を、浄化対象である土壌に応じ、施工現場において簡易且つフレキシブルに行うことが可能となる。
硬質合成樹脂管の周面に形成する複数の通孔は、電極に向かう汚染物質イオンを管内に効率的に取り込むことができ、且つ当該管材の剛性の低下を来さない範囲で、管壁の適宜な位置に適宜な形状で適宜な数を形成することができる。
In the above configuration, the rigid synthetic resin pipe is preferably a cylindrical pipe made of polyvinyl chloride or other resin material formed in accordance with JIS standards.
By using pipes of JIS standard products, electrode wells can be constructed at low cost using accessories such as general-purpose joints and caps, and the lengths of pipes can be adjusted by connecting the pipes with the joints. Processing can be performed easily and flexibly at the construction site according to the soil to be purified.
The plurality of through holes formed in the peripheral surface of the hard synthetic resin tube can efficiently take in the contaminant ions directed to the electrode into the tube and do not cause a decrease in the rigidity of the tube material. An appropriate number can be formed in an appropriate shape at an appropriate position.
多孔質合成樹脂管は、管壁が水の透過を最小とし、イオンの透過を許容する孔径に成形された多孔質円筒管材であり、超高分子量ポリエチレンを原料とする焼結成形品、例えば本出願人の製品である多孔質プラスチック成形体「フィルダス」(登録商標)を用いることが好ましい。
前記孔径であれば管内に注入された電解液が外部に漏出することがなく、他方、土中の汚染物質イオンは管壁を透過して管内に取り込まれ、電解液内に溶け込ますことができる。また、多孔質合成樹脂管は、原材料や成形条件を適宜に設定することで管壁の孔径を変え、濾過性能である透過率を適宜に設定することが可能である。
A porous synthetic resin tube is a porous cylindrical tube whose tube wall is formed in a pore diameter that minimizes water permeation and allows ion permeation, and is a sintered molded product made of ultrahigh molecular weight polyethylene, such as this It is preferable to use a porous plastic molded product “Fildas” (registered trademark) which is the product of the applicant.
If the pore size is as described above, the electrolyte injected into the tube will not leak to the outside. On the other hand, contaminant ions in the soil can be taken into the tube through the tube wall and dissolved in the electrolyte. . Moreover, the porous synthetic resin tube can change the hole diameter of a tube wall by setting a raw material and molding conditions suitably, and can set the transmittance | permeability which is filtration performance suitably.
前記構成の電極井戸構成管は、周面に通孔が形成された硬質合成樹脂管と、外径が硬質合成樹脂管の内側に圧密に嵌入し得る寸法に形成された多孔質合成樹脂管を用意し、両管を互いに管軸を揃えて並べた状態で硬質合成樹脂管の一端からその内部に多孔質合成樹脂管を押し込んで圧入し、硬質合成樹脂管の内周面に多孔質合成樹脂管の外周面を接合し密着させて一体化させることにより製造することができる。 The electrode well structure pipe having the above-described structure is composed of a hard synthetic resin pipe having a through hole formed in the peripheral surface and a porous synthetic resin pipe having an outer diameter that can be compactly fitted inside the hard synthetic resin pipe. Prepare and insert the porous synthetic resin tube into one end of the hard synthetic resin tube with the tube axes aligned and press-fitted into the inner surface of the hard synthetic resin tube. It can be manufactured by joining the outer peripheral surfaces of the tubes and bringing them into close contact with each other.
かかる電極井戸構成管は、一側の開口端に底蓋を被せて閉鎖した状態で、浄化対象の土壌を掘削して形成された竪穴の中に前記底蓋で閉鎖された側を下向きに挿入して埋設され、埋設された管内に棒状の電極を設置して電極井戸を構成する。
電極井戸は、浄化する土壌の地盤に陽・陰両極を一対として複数対が互いに適宜な間隔を空けて並設され、各々電極は電気ケーブルで浄化処理プラントの制御装置に接続され、管口には電解液を注水及び回収する電解液処理タンクに接続される。
Such an electrode well constituting tube is inserted with the bottom closed by the bottom lid in a pothole formed by excavating the soil to be purified, with the bottom end covered with a bottom lid and closed. Then, a rod-like electrode is installed in the buried tube to constitute an electrode well.
Electrode wells are arranged in parallel on the ground of the soil to be cleaned, with a pair of positive and negative electrodes spaced apart from each other at appropriate intervals.Each electrode is connected to the control device of the purification treatment plant with an electric cable and connected to the pipe port. Is connected to an electrolyte treatment tank for pouring and collecting the electrolyte.
本発明の電極井戸構成管によれば、周面に通孔が形成された硬質合成樹脂管の内部に多孔質合成樹脂管を圧入し、内外管の周面を密着接合させて構成してあるので、電解液は多孔質合成樹脂管の内部に貯留されて外部に漏出することがなく、一方、土壌中の汚染物質イオンは硬質合成樹脂管の通孔を通り、多孔質合成樹脂管の管壁を透過して当該構成管内部に入り込み、前記貯留された電解液に溶け込んで、電解液とともに確実に回収することが可能である。
多孔質合成樹脂管はその全体が硬質合成樹脂管に覆われて管内に保持されるので、施工現場に移送したり埋設したりするなどの取り扱い中に衝撃を受けたり押圧力がかかったりしても変形や割れなどの破損を来すことはなく、硬質合成樹脂管単体を取り扱う要領で取り扱うことができるので電極井戸の施工が簡便なものとなる。
また、JIS規格品の管材を用いているので、汎用の継手を用いて電極井戸構成管同士を接続して長さを調節するなど、電極井戸の加工を施工現場において簡易且つフレキシブルに行うことが可能となる。
According to the electrode well constituting pipe of the present invention, a porous synthetic resin pipe is press-fitted into a hard synthetic resin pipe having a through-hole formed in the peripheral surface, and the peripheral surfaces of the inner and outer pipes are tightly joined. Therefore, the electrolytic solution is stored inside the porous synthetic resin tube and does not leak to the outside. On the other hand, the contaminant ions in the soil pass through the through hole of the hard synthetic resin tube, and the tube of the porous synthetic resin tube. It is possible to penetrate the wall and enter the constituent tube, dissolve in the stored electrolyte, and be reliably recovered together with the electrolyte.
Since the entire porous synthetic resin pipe is covered with the hard synthetic resin pipe and held in the pipe, it is subject to impact and pressure during handling such as transferring to the construction site or burying it. However, it does not cause any damage such as deformation or cracking, and can be handled in the same way as handling a hard synthetic resin tube alone, so that the construction of the electrode well becomes simple.
In addition, since pipes of JIS standard products are used, electrode wells can be processed easily and flexibly at the construction site, such as adjusting the length by connecting the electrode well constituent tubes using general-purpose joints. It becomes possible.
本発明の好適な一実施形態を図面を参照して説明する。
図1は、本発明の一実施形態の電極井戸構成管を用いて構成された電極井戸を示しており、図中、符号1は電極井戸、2は電極井戸構成管、3は電極、4は底蓋をそれぞれ示している。
A preferred embodiment of the present invention will be described with reference to the drawings.
FIG. 1 shows an electrode well constructed by using an electrode well constituting tube according to an embodiment of the present invention. In the figure, reference numeral 1 is an electrode well, 2 is an electrode well constituting tube, 3 is an electrode, Each bottom lid is shown.
図示されるように、電極井戸構成管2は、周面に多数の通孔21aが形成された硬質合成樹脂管21の内側に多孔質合成樹脂管22を同軸に配置し、硬質合成樹脂管21の内周面に多孔質合成樹脂管22の外周面を密着接合し一体化させて構成してある。
As shown in the drawing, the electrode well constituting
詳しくは、硬質合成樹脂管21は、適宜な厚みの円筒管であり、その周面全体に亘り、円形に開口した通孔21aを周方向と長手方向に沿って所定間隔を空け複数列設して形成してある。多孔質合成樹脂管22は、その外径が硬質合成樹脂管21の内側に圧密に嵌入し得る寸法に形成された円筒管であり、その外周面を硬質合成樹脂管21の内周面全長に亘って密着接合させて、硬質合成樹脂管21の内側に一体に設置してある。
Specifically, the hard
このように構成される電極井戸構成管2は、図2に示されるように、周面に通孔21aを穿孔した硬質合成樹脂管21と多孔質合成樹脂管22の管軸Oを揃えた状態で、硬質合成樹脂管21の一端からその内部に多孔質合成樹脂管22を押し込んで圧入し、両管の内外周面を密着接合し一体化させることにより形成することができる。長尺な硬質合成樹脂管21の内部に、短尺な複数の多孔質合成樹脂管22を圧入し、内外周面を密着接合させて形成してもよい。
As shown in FIG. 2, the electrode well constituting
また、硬質合成樹脂管21としてJIS規格樹脂管を用いることで以下の作用効果を奏する。
この場合、例えば呼び径(内径)125mm、長さ1000mmのJIS規格の硬質合成樹脂管2を用い、予めその周面に空孔率が最低10%以上となるように円形やスリット形の通孔21aを形成しておき、一方、外径125mm、長さ1000mmの多孔質合成樹脂管22を準備し、これを前記硬質合成樹脂管21の一端から内部に圧入し、両管の内外周面を密着接合し一体化して、電極井戸構成管2を構成する複合管を完成させる。
この複合管を1ユニットとして、複数ユニットをJIS規格のソケットなどで接続すれば1m単位で長さを設定した電極井戸構成管2を形成することが可能である。電極井戸構成管2の最下部にJIS規格のキャップ(底蓋4)を取り付けて閉鎖するなど様々な規格品を簡易に使用することができる。
また、電気修復法において修復される対象部分以外、例えば地表からポンプまでといった配管経路などについても、JIS規格の汎用の樹脂管などを用い簡易且つフレキシブルに配管して構成可能であり、例えば分岐する配管経路も自在に構成することができる。
Further, the use of a JIS standard resin pipe as the hard
In this case, for example, a JIS standard hard
If this composite tube is used as one unit and a plurality of units are connected by a JIS standard socket or the like, it is possible to form the electrode well constituting
In addition, other than the target portion to be repaired in the electrical restoration method, for example, a piping route from the ground surface to the pump can be configured by simply and flexibly piping using a general-purpose resin pipe of JIS standard, for example, branching. The piping path can also be configured freely.
なお、硬質合成樹脂管21の周面に形成する通孔21aは、図示した形状に限定されず、細長いスリット状や帯状に開口したものなど適宜な形状とすることができる。また、通孔21aを形成する位置や数も適宜に設定可能である。
In addition, the through-
1 電極井戸、2 電極井戸構成管、21 硬質合成樹脂管、22 多孔質合成樹脂管、3 電極、4 底蓋、O 管軸
1 Electrode Well, 2 Electrode Well Constituent Tube, 21 Hard Synthetic Resin Tube, 22 Porous Synthetic Resin Tube, 3 Electrode, 4 Bottom Cover, O Tube Shaft
Claims (2)
周面に複数の通孔が形成された硬質合成樹脂管の内周面に多孔質合成樹脂管の外周面を接合一体化させて構成されていることを特徴とする電極井戸構成管。 In the electrode well construction pipe used for in-situ purification of contaminated soil,
An electrode well constituting tube characterized in that the outer peripheral surface of a porous synthetic resin tube is joined and integrated with the inner peripheral surface of a hard synthetic resin tube having a plurality of through holes formed in the peripheral surface.
周面に複数の通孔が形成された硬質合成樹脂管の内部に多孔質合成樹脂管を圧入し、前記硬質合成樹脂管の内周面に多孔質合成樹脂管の外周面を接合させて両管を一体化させることを特徴とする電極井戸構成管の製造方法。
In the manufacturing method of the electrode well constituent pipe used for in-situ purification of contaminated soil,
A porous synthetic resin tube is press-fitted into a hard synthetic resin tube having a plurality of through holes formed in the peripheral surface, and the outer peripheral surface of the porous synthetic resin tube is joined to the inner peripheral surface of the hard synthetic resin tube. A method for producing an electrode well-structured tube, wherein the tubes are integrated.
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2013104786A (en) * | 2011-11-14 | 2013-05-30 | Showa Denko Kk | Method for treating soil contaminated by radioactive cesium |
| CN103624076A (en) * | 2013-11-07 | 2014-03-12 | 江苏大学 | Remediation method of soil polluted by polybrominated diphenyl ethers |
| JP2014531978A (en) * | 2011-10-12 | 2014-12-04 | エンパイア テクノロジー ディベロップメント エルエルシー | Electrical repair method |
| KR101880197B1 (en) * | 2017-09-01 | 2018-07-20 | 고려대학교 세종산학협력단 | System and method for in situ removal of Hg from soil |
| CN114749476A (en) * | 2022-03-18 | 2022-07-15 | 中交天津港湾工程研究院有限公司 | Automatic cleaning system for soil electric remediation electrode and using method thereof |
-
2010
- 2010-02-26 JP JP2010041430A patent/JP2011177603A/en active Pending
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2014531978A (en) * | 2011-10-12 | 2014-12-04 | エンパイア テクノロジー ディベロップメント エルエルシー | Electrical repair method |
| JP2013104786A (en) * | 2011-11-14 | 2013-05-30 | Showa Denko Kk | Method for treating soil contaminated by radioactive cesium |
| CN103624076A (en) * | 2013-11-07 | 2014-03-12 | 江苏大学 | Remediation method of soil polluted by polybrominated diphenyl ethers |
| CN103624076B (en) * | 2013-11-07 | 2015-04-22 | 江苏大学 | Remediation method of soil polluted by polybrominated diphenyl ethers |
| KR101880197B1 (en) * | 2017-09-01 | 2018-07-20 | 고려대학교 세종산학협력단 | System and method for in situ removal of Hg from soil |
| CN114749476A (en) * | 2022-03-18 | 2022-07-15 | 中交天津港湾工程研究院有限公司 | Automatic cleaning system for soil electric remediation electrode and using method thereof |
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