JP2025023134A - Foaming compound cream - Google Patents
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本発明は、リン酸塩とエステル交換油脂を実質的に含有しない起泡性コンパウンドクリーム、及び、それをホイップして得られるホイップドコンパウンドクリームに関する。 The present invention relates to a foaming compound cream that is substantially free of phosphates and transesterified fats and oils, and to a whipped compound cream obtained by whipping the foaming compound cream.
ホイップドクリームには、口溶けが良好で、かつ適度な硬さを維持することが求められている。また、該ホイップドクリームの原料となる起泡性クリームには、原液安定性、及びホイップ性が求められている。
また、ホイップドクリームに乳のコクや風味を付与したり、ホイップ性を上げることを目的に、生クリームを混合してホイップドコンパウンドクリームにすることが多々ある。
Whipped cream is required to have good meltability in the mouth and maintain a suitable hardness, while the whipping cream that is the raw material for the whipped cream is required to have good concentrate stability and whipping properties.
Furthermore, in order to impart a rich milk flavor and taste to the whipped cream or to improve whipping properties, fresh cream is often mixed in to produce a whipped compound cream.
従来、前記起泡性クリームの原料油脂としては、口溶けの観点からラウリン系油脂が多用されてきたが、ラウリン系油脂を多く含むクリームは起泡後の硬さの維持が難しく、ラウリン系油脂は価格の乱高下も激しい。また、溶解を開始してから終了するまでの温度帯が乳脂肪と異なっており、低く狭い。そのため、生クリームを配合したコンパウンドクリームにラウリン系油脂を配合すると、溶解のタイミングが2回に分かれ口溶けが不自然になってしまう。 Traditionally, lauric fats have been widely used as the raw material fat for the foaming cream from the viewpoint of meltability in the mouth, but creams containing a large amount of lauric fats have difficulty maintaining their hardness after whipping, and the price of lauric fats fluctuates greatly. In addition, the temperature range from the start to the end of melting is low and narrow, unlike that of milk fat. Therefore, when lauric fats are added to a compound cream containing fresh cream, the timing of melting is split into two, resulting in an unnatural melting in the mouth.
近年、ラウリン系油脂の代替として、安価で供給が安定しているパーム系油脂が使用されることがある。しかし、油脂中にパーム系油脂を多く配合すると粗大結晶を形成するため、原液安定性、ホイップ性、及びホイップ後の硬さが悪化し、口溶けも悪くなってしまう傾向がある。これらの点を改善するため起泡性クリームにリン酸塩やエステル交換油脂を配合することが行われているが、リン酸塩は苦味を呈する上に健康上好ましくなく、エステル交換油脂は製造コストが高く、コクを低下させたり、口溶けを悪化させる。 In recent years, palm-based fats, which are inexpensive and have a stable supply, have been used as an alternative to lauric fats. However, when palm-based fats are blended in large amounts in fats and oils, coarse crystals form, which deteriorate the stability of the original liquid, whipping properties, and hardness after whipping, and also tend to make the cream melt in the mouth. To improve these points, phosphates and interesterified fats have been blended into whipping creams, but phosphates have a bitter taste and are undesirable from a health perspective, and interesterified fats are expensive to produce, reduce the richness of the flavor, and make the cream melt in the mouth worse.
これまで、リン酸塩やトランス脂肪酸を実質的に含有せず、起泡後の保型性及び口溶けが良好なホイップドコンパウンドクリームが開示されている(特許文献1)が、当該ホイップドコンパウンドクリームはパーム系油脂が主体であるため、口溶けは、ラウリン系油脂を主体とするホイップドコンパウンドクリームに及ばず、また、ホイップ後の硬さが十分ではない。 A whipped compound cream that is substantially free of phosphates and trans fatty acids and has good shape retention and melt-in-the-mouth properties after whipping has been disclosed (Patent Document 1). However, because this whipped compound cream is mainly made of palm-based oils and fats, it does not melt in the mouth as well as whipped compound creams that are mainly made of lauric oils and fats, and the hardness after whipping is insufficient.
本発明の目的は、リン酸塩とエステル交換油脂を実質的に含有せず、ラウリン系油脂低含量且つパーム系油脂高含量であるにも関わらず、原液安定性とホイップ性が良好な起泡性コンパウンドクリーム、及び、それをホイップして得られ、口溶けが自然で、且つ早く、硬さが良好なホイップドコンパウンドクリームを提供することである。 The object of the present invention is to provide a foamable compound cream that is substantially free of phosphates and transesterified fats and oils, has a low content of lauric fats and a high content of palm fats, yet has good stock solution stability and whipping properties, and to provide a whipped compound cream obtained by whipping the foamable compound cream, which melts naturally and quickly in the mouth and has good hardness.
本発明者らは上記課題を解決するために鋭意研究を重ねた結果、リン酸塩とエステル交換油脂を実質的に含有せず、特定量の油脂を含み、該油脂中に特定量の乳脂肪と、C12以下の飽和脂肪酸を構成脂肪酸として特定量含み、特定の融点である油脂Aと、C16~C22の飽和脂肪酸を構成脂肪酸として特定量含み、且つS2Uを特定量含み特定の融点である油脂Bを特定量含み、さらに水相中に特定範囲のHLBで特定の飽和脂肪酸を構成脂肪酸として含む特定の乳化剤Aを特定量含む起泡性コンパウンドクリームは、ラウリン系油脂低含量且つパーム系油脂高含量であるにも関わらず、原液安定性とホイップ性が良好であり、その起泡性コンパウンドクリームをホイップして得られるホイップドコンパウンドクリームは、口溶けが自然で、且つ早く、硬さが良好であることを見出し、本発明を完成するに至った。 As a result of intensive research by the present inventors to solve the above-mentioned problems, they have found that a foamable compound cream which is substantially free of phosphates and interesterified oils and fats, contains a specific amount of oil or fat, in which the oil or fat contains a specific amount of milk fat, a specific amount of C12 or lower saturated fatty acids as constituent fatty acids and has a specific melting point, and a specific amount of oil or fat B which contains a specific amount of C16 to C22 saturated fatty acids as constituent fatty acids, a specific amount of S2U and has a specific melting point, and further contains a specific amount of a specific emulsifier A which contains a specific saturated fatty acid with a specific HLB range as a constituent fatty acid in an aqueous phase, has good concentrate stability and whipping properties despite having a low content of lauric fats and a high content of palm fats and fats, and a whipped compound cream obtained by whipping the foamable compound cream melts naturally and quickly in the mouth and has good hardness, thereby completing the present invention.
即ち、本発明の第一は、起泡性コンパウンドクリーム全体中、油脂含量が25~50重量%、リン酸塩含量が0.02重量%未満であり、
起泡性コンパウンドクリームの水相中に乳化剤Aを、起泡性コンパウンドクリーム全体中0.05~0.55重量%含有し、
前記油脂全体中、エステル交換油脂含量が1重量%未満、乳脂肪含量が3.5重量%以上且つ22.5重量%未満であり、
前記油脂の内、前記乳脂肪を除く油脂全体中、油脂A及び油脂Bの合計含量が80~100重量%であり、油脂B/(油脂A+油脂B)(重量比)が0.45~0.82である、
起泡性コンパウンドクリームに関する。
油脂A:C12以下の飽和脂肪酸を構成脂肪酸全体中40重量%以上含み、S2Uを油脂A全体中0重量%以上40重量%未満含み、上昇融点(但し、複数種の油脂のブレンド物である場合、前記上昇融点は、当該複数種の油脂の上昇融点の平均値を指す)が23~30℃の油脂。
油脂B:C16~C22の飽和脂肪酸を構成脂肪酸全体中40重量%以上含み、S2Uを油脂B全体中45~70重量%含み、上昇融点が23~30℃の油脂。
乳化剤A:HLBが2.8~6.2であり、C10~C22の飽和脂肪酸を構成脂肪酸全体中70~100重量%含むショ糖脂肪酸エステル及び/又はポリグリセリン脂肪酸エステル。
好ましくは、前記乳脂肪が生クリーム由来である。
本発明の第二は、前記起泡性コンパウンドクリームがホイップされたホイップドコンパウンドクリームに関する。
本発明の第三は、前記ホイップドコンパウンドクリームをサンド、ナッペ、フィリング、又はトッピングした食品に関する。
本発明の第四は、起泡性コンパウンドクリーム全体中、油脂含量が25~50重量%、リン酸塩含量が0.02重量%未満であり、前記油脂全体中、エステル交換油脂含量が1重量%未満である起泡性コンパウンドクリームの製造方法であって、
起泡性コンパウンドクリーム全体中、乳化剤A含量が0.05~0.55重量%となるように乳化剤Aを水に添加して撹拌しながら溶解した水相部に、前記油脂全体中、油脂Aと油脂Bの合計含量が62~96.5重量%且つ油脂B/(油脂A+油脂B)(重量比)が0.45~0.82となるように油脂A及び油脂Bを混合した油脂混合物を添加し、予備乳化した後、微細化し、さらに高圧処理して得た水中油型乳化油脂組成物に、前記油脂全体中の乳脂肪含量が3.5重量%以上且つ22.5重量%未満になるように生クリームを混合・撹拌することを特徴とする、起泡性コンパウンドクリームの製造方法に関する。
油脂A:C12以下の飽和脂肪酸を構成脂肪酸全体中40重量%以上含み、S2Uを油脂A全体中0重量%以上40重量%未満含み、上昇融点(但し、複数種の油脂のブレンド物である場合、前記上昇融点は、当該複数種の油脂の上昇融点の平均値を指す)が23~30℃の油脂。
油脂B:C16~C22の飽和脂肪酸を構成脂肪酸全体中40重量%以上含み、S2Uを油脂B全体中45~70重量%含み、上昇融点が23~30℃の油脂。
乳化剤A:HLBが2.8~6.2であり、C10~C22の飽和脂肪酸を構成脂肪酸全体中70~100重量%含むショ糖脂肪酸エステル及び/又はポリグリセリン脂肪酸エステル。
That is, the first aspect of the present invention is a foaming compound cream comprising a foaming compound cream having an oil content of 25 to 50% by weight and a phosphate content of less than 0.02% by weight,
The foaming compound cream contains an emulsifier A in an aqueous phase thereof in an amount of 0.05 to 0.55% by weight based on the total weight of the foaming compound cream,
In the total fats and oils, the interesterified fat content is less than 1% by weight, and the milk fat content is 3.5% by weight or more and less than 22.5% by weight,
Among the fats and oils, the total content of fats and oils A and B in the entire fats and oils excluding the milk fat is 80 to 100% by weight, and the weight ratio of fats and oils B/(fat and oil A + fat and oil B) is 0.45 to 0.82;
This relates to a foaming compound cream.
Oil and fat A: Oil and fat containing 40% by weight or more of saturated fatty acids of C12 or less in the total constituent fatty acids, containing 0% by weight or more and less than 40% by weight of S2U in the total oil and fat A, and having an ascending melting point (however, in the case of a blend of multiple types of oils and fats, the ascending melting point refers to the average value of the ascending melting points of the multiple types of oils and fats) of 23 to 30°C.
Fats and oils B: Fats and oils containing 40% by weight or more of C16 to C22 saturated fatty acids in the total constituent fatty acids, containing 45 to 70% by weight of S2U in the total constituent fatty acids B, and having an upward melting point of 23 to 30°C.
Emulsifier A: sucrose fatty acid ester and/or polyglycerin fatty acid ester having an HLB of 2.8 to 6.2 and containing 70 to 100% by weight of C 10 to C 22 saturated fatty acids based on the total amount of constituent fatty acids.
Preferably, the milk fat is derived from cream.
A second aspect of the present invention relates to a whipped compound cream obtained by whipping the foamable compound cream.
The third aspect of the present invention relates to a food product in which the whipped compound cream is used as a sandwich, a nappe, a filling, or a topping.
The fourth aspect of the present invention is a method for producing a foaming compound cream, the foaming compound cream having a total fat content of 25 to 50% by weight, a phosphate content of less than 0.02% by weight, and an interesterified fat content of less than 1% by weight of the total fat content,
The present invention relates to a method for producing a foamable compound cream, which comprises adding emulsifier A to water so that the emulsifier A content in the entire foamable compound cream is 0.05 to 0.55% by weight, stirring to dissolve the emulsifier in an aqueous phase, adding an oil/fat mixture of oils A and B so that the total content of oils A and B in the entire fats and oils is 62 to 96.5% by weight and the weight ratio of oil/fat B/(oil/fat A + oil/fat B) is 0.45 to 0.82, pre-emulsifying the resulting mixture, pulverizing the mixture, and subjecting the mixture to high pressure treatment to obtain an oil-in-water emulsified oil/fat composition, and mixing and stirring fresh cream with the resulting mixture so that the milk fat content in the entire fats and oils is 3.5% by weight or more and less than 22.5% by weight.
Oil and fat A: Oil and fat containing 40% by weight or more of saturated fatty acids of C12 or less in the total constituent fatty acids, containing 0% by weight or more and less than 40% by weight of S2U in the total oil and fat A, and having an ascending melting point (however, in the case of a blend of multiple types of oils and fats, the ascending melting point refers to the average value of the ascending melting points of the multiple types of oils and fats) of 23 to 30°C.
Fats and oils B: Fats and oils containing 40% by weight or more of C16 to C22 saturated fatty acids in the total constituent fatty acids, containing 45 to 70% by weight of S2U in the total constituent fatty acids B, and having an upward melting point of 23 to 30°C.
Emulsifier A: sucrose fatty acid ester and/or polyglycerin fatty acid ester having an HLB of 2.8 to 6.2 and containing 70 to 100% by weight of C 10 to C 22 saturated fatty acids based on the total amount of constituent fatty acids.
本発明に従えば、リン酸塩とエステル交換油脂を実質的に含有せず、ラウリン系油脂低含量且つパーム系油脂高含量であるにも関わらず、原液安定性とホイップ性が良好な起泡性コンパウンドクリーム、及び、それをホイップして得られ、口溶けが自然で、且つ早く、硬さが良好なホイップドコンパウンドクリームを提供することができる。 According to the present invention, it is possible to provide a foaming compound cream that is substantially free of phosphates and transesterified fats and oils, has a low content of lauric fats and a high content of palm fats, yet has good stock solution stability and whipping properties, and a whipped compound cream obtained by whipping the foaming compound cream, which melts naturally and quickly in the mouth and has good hardness.
以下、本発明につき、さらに詳細に説明する。本発明の起泡性コンパウンドクリームは、リン酸塩とエステル交換油脂を実質的に含有せず、特定量の油脂を含み、水相中に特定の乳化剤Aを特定量含み、乳脂肪と2種類の特定の油脂(油脂Aと油脂B)を特定量含むことを特徴とする。そして、前記起泡性コンパウンドクリームをホイップすることで、本発明のホイップドコンパウンドクリームを得ることができる。 The present invention will be described in more detail below. The foamable compound cream of the present invention is characterized in that it is substantially free of phosphates and transesterified fats and oils, contains a specific amount of fats and oils, contains a specific amount of a specific emulsifier A in the aqueous phase, and contains specific amounts of milk fat and two specific fats and oils (fat A and fat B). The whipped compound cream of the present invention can be obtained by whipping the foamable compound cream.
前記起泡性コンパウンドクリームに含まれるリン酸塩は、少なければ少ないほど良く、起泡性コンパウンドクリーム全体中0.02重量%未満が好ましく、0.01重量%未満がより好ましく、全く含まないことがさらに好ましい。前記リン酸塩としては、リン酸ナトリウム、メタリン酸ナトリウム等が例示でき、それらの群より選ばれる少なくとも1種を用いることができる。 The less phosphate contained in the foaming compound cream, the better, and it is preferably less than 0.02% by weight of the entire foaming compound cream, more preferably less than 0.01% by weight, and even more preferably none at all. Examples of the phosphate include sodium phosphate, sodium metaphosphate, etc., and at least one selected from this group can be used.
前記起泡性コンパウンドクリームは、油脂を起泡性コンパウンドクリーム全体中25~50重量%含有することが好ましい。より好ましくは30~45重量%であり、さらに好ましくは35~40重量%である。25重量%より少ないと、ホイップ性とホイップ後の硬さが悪い場合があり、50重量%より多いと、ホイップ後の口溶けが不自然になったり原液安定性が悪い場合がある。なお前記油脂には、少なくとも乳脂肪、油脂A及び油脂Bが含まれる。 The foaming compound cream preferably contains 25 to 50% by weight of fats and oils based on the total weight of the foaming compound cream. More preferably, it is 30 to 45% by weight, and even more preferably, it is 35 to 40% by weight. If it is less than 25% by weight, the whipping property and hardness after whipping may be poor, and if it is more than 50% by weight, the melting in the mouth after whipping may be unnatural and the stability of the original liquid may be poor. The fats and oils include at least milk fat, fat A, and fat B.
前記起泡性コンパウンドクリームに含まれるエステル交換油脂の含有量は少なければ少ないほど良く、前記起泡性コンパウンドクリームに含まれる油脂全体中1重量%未満が好ましく、0.5重量%未満がより好ましく、全く含まないことがさらに好ましい。エステル交換油脂の含有量が1重量%以上であると、コストがアップしたり、ホイップ性が悪化したり、ホイップ後の硬さや口溶けの自然さが損なわれる場合がある。 The less the content of transesterified fats in the foaming compound cream, the better; it is preferably less than 1% by weight of the total fats and oils contained in the foaming compound cream, more preferably less than 0.5% by weight, and even more preferably none at all. If the content of transesterified fats is 1% by weight or more, the cost may increase, the whipping properties may deteriorate, and the hardness after whipping and the naturalness of the melt-in-the-mouth texture may be impaired.
本発明においてエステル交換油脂とは、食用油脂をエステル交換反応して得られる油脂を指す。前記食用油脂としては菜種油、コーン油、綿実油、パーム油、パーム核油、ヤシ油、大豆油、ひまわり油、サフラワー油、オリーブ油等の植物性油脂や、牛脂、豚脂、魚油等の動物性油脂が例示でき、これらを硬化、分別、エステル交換等の加工処理を行ったものも用いることができる。前記エステル交換油脂の製法については特に限定なく、常法を用いて製造することができる。例えば、ナトリウムメチラートまたはナトリウムエチラートを原料油脂に対して0.01~1.0重量%添加してランダムエステル交換反応を起こす化学法や、リパーゼなどの酵素を用いてエステル交換を行なう酵素法などを適用できる。 In the present invention, the term "transesterified oils and fats" refers to oils and fats obtained by transesterifying edible oils and fats. Examples of the edible oils and fats include vegetable oils and fats such as rapeseed oil, corn oil, cottonseed oil, palm oil, palm kernel oil, coconut oil, soybean oil, sunflower oil, safflower oil, and olive oil, and animal oils and fats such as beef tallow, lard, and fish oil. These oils and fats may also be processed by hardening, fractionation, transesterification, and the like. There are no particular limitations on the method for producing the transesterified oils and fats, and they can be produced using conventional methods. For example, a chemical method in which 0.01 to 1.0% by weight of sodium methylate or sodium ethylate is added to the raw oil and fat to cause a random transesterification reaction, or an enzymatic method in which transesterification is performed using an enzyme such as lipase, can be used.
前記乳脂肪の含有量は、前記起泡性コンパウンドクリームに含まれる油脂全体中3.5重量%以上且つ22.5重量%未満が好ましい。3.5重量%より少ないとホイップ性が悪い場合があり、22.5重量%以上になると、原液安定性やホイップ性が悪くなったり、口溶けが遅くなる場合がある。前記乳脂肪の由来としては、生クリーム、バターミルクパウダー、バター、バターオイル、クリームチーズ、生乳、牛乳、全粉乳、濃縮乳、サワークリーム、無糖練乳、加糖練乳等が例示でき、それらの群より選ばれる少なくとも1種を原料として用いることができる。風味やホイップ後の硬さの観点では、乳脂肪の由来として生クリームを用いることが好ましい。 The content of the milk fat is preferably 3.5% by weight or more and less than 22.5% by weight of the total fats and oils contained in the foamable compound cream. If it is less than 3.5% by weight, whipping properties may be poor, and if it is 22.5% by weight or more, the stability of the concentrate and whipping properties may be poor, and melting in the mouth may be delayed. Examples of the origin of the milk fat include fresh cream, buttermilk powder, butter, butter oil, cream cheese, raw milk, cow's milk, whole milk powder, concentrated milk, sour cream, unsweetened condensed milk, sweetened condensed milk, etc., and at least one selected from these groups can be used as a raw material. From the viewpoint of flavor and hardness after whipping, it is preferable to use fresh cream as the origin of the milk fat.
前記生クリームは、乳等省令で定義される「生乳、牛乳または特別牛乳から乳脂肪分以外の成分を除去し、乳脂肪分が18.0%以上にしたもの」をいい、本発明においては、乳脂肪分が30~48%のものを使用することが、良好なホイップ性を得る観点から好ましい。 The fresh cream is defined in the Milk and Dairy Products Ordinance as "a product made by removing components other than milk fat from raw milk, cow's milk or special milk, resulting in a milk fat content of 18.0% or more." In the present invention, it is preferable to use cream with a milk fat content of 30 to 48% in order to obtain good whipping properties.
前記油脂Aは、C12以下の飽和脂肪酸を構成脂肪酸全体中40重量%以上含むことが好ましい。40重量%未満だと、口溶けが遅い場合がある。前記油脂Aの構成脂肪酸に含まれるC12以下の飽和脂肪酸の含量は構成脂肪酸全体中100重量%以下であればよい。 The fat A preferably contains 40% by weight or more of saturated fatty acids of C12 or less based on the total constituent fatty acids. If the content is less than 40% by weight, melting in the mouth may be slow. The content of saturated fatty acids of C12 or less included in the constituent fatty acids of the fat A may be 100% by weight or less based on the total constituent fatty acids.
前記油脂Aは、S2Uを油脂A全体中0重量%以上40重量%未満含むことが好ましく、0~20重量%がより好ましく、0~10重量%がさらに好ましい。40重量%以上であると、本発明の効果を奏しない場合がある。ここで、S2Uとは、1分子のグリセリンに、構成脂肪酸として、C16以上(好ましくはC24以下)の飽和脂肪酸Sが2分子、C16以上(好ましくはC24以下)の不飽和脂肪酸Uが1分子結合しているトリグリセリドのことをいい、S及びUの結合位置は限定されない。 The fat/oil A preferably contains S2U in an amount of 0% by weight or more and less than 40% by weight, more preferably 0 to 20% by weight, and even more preferably 0 to 10% by weight, based on the total weight of the fat/oil A. If the amount is 40% by weight or more, the effects of the present invention may not be achieved. Here, S2U refers to a triglyceride in which, as constituent fatty acids, two molecules of saturated fatty acid S having a C 16 or more (preferably C 24 or less) and one molecule of unsaturated fatty acid U having a C 16 or more (preferably C 24 or less) are bound to one molecule of glycerin, and the binding positions of S and U are not limited.
また、前記油脂Aの上昇融点は、23~30℃であることが好ましく、24~29℃がより好ましく、25~29℃がさらに好ましく、26~28℃が特に好ましい。23℃より低いと、ホイップ後の硬さを維持できない場合があり、30℃より高いと、ホイップ性及びホイップ後の硬さが悪くなったり、口溶けが遅くなる場合がある。 The slip melting point of the oil A is preferably 23 to 30°C, more preferably 24 to 29°C, even more preferably 25 to 29°C, and particularly preferably 26 to 28°C. If it is lower than 23°C, the hardness after whipping may not be maintained, and if it is higher than 30°C, the whipping properties and hardness after whipping may be poor, or melting in the mouth may be delayed.
前記油脂Aの種類としては、ラウリン系油脂が挙げられ、具体的にはヤシ油(上昇融点:24±1℃)やパーム核油(上昇融点:27±1℃)、パーム核オレイン(上昇融点:23±1℃)が例示でき、それらの群より選ばれる少なくとも1種を用いることができる。また、油脂Aが複数種の油脂をブレンドした混合油脂である場合は、当該混合油脂全体に含まれるC12以下の飽和脂肪酸含量及びS2U含量が前記含量の範囲に入り、且つ当該複数種の油脂の上昇融点の平均値が前記上昇融点の範囲に入っていれば良い。 The type of the fat A includes lauric fats, specifically, coconut oil (elevation melting point: 24±1° C.), palm kernel oil (elevation melting point: 27±1° C.), and palm kernel olein (elevation melting point: 23±1° C.), and at least one selected from these groups can be used. When the fat A is a mixed fat obtained by blending a plurality of types of fats and oils, it is sufficient that the saturated fatty acid content of C12 or less and the S2U content contained in the entire mixed fat and oil are within the above-mentioned ranges, and the average value of the elevating melting points of the plurality of types of fats and oils is within the above-mentioned ranges.
前記油脂Bは、C16~C22の飽和脂肪酸を構成脂肪酸全体中40重量%以上含むことが好ましい。40重量%未満だと、口溶けが遅い場合がある。前記油脂Bの構成脂肪酸に含まれるC16~C22の飽和脂肪酸の含量は構成脂肪酸全体中100重量%以下であればよい。 The fat B preferably contains 40% by weight or more of C16 - C22 saturated fatty acids based on the total constituent fatty acids. If the content is less than 40% by weight, melting in the mouth may be slow. The content of C16 - C22 saturated fatty acids contained in the constituent fatty acids of the fat B may be 100% by weight or less based on the total constituent fatty acids.
前記油脂Bは、S2Uを油脂B全体中45~70重量%含むことが好ましく、50~60重量%がより好ましい。45重量%より少ないとホイップ性とホイップ後の硬さが悪くなる場合があり、70重量%より多いと、原液安定性、ホイップ性、及びホイップ後の硬さが悪くなったり、口溶けが遅くなる場合がある。ここで、S2Uとは、1分子のグリセリンに、構成脂肪酸として、C16以上(好ましくはC24以下)の飽和脂肪酸Sが2分子、C16以上(好ましくはC24以下)の不飽和脂肪酸Uが1分子結合しているトリグリセリドのことをいい、S及びUの結合位置は限定されない。 The fat B preferably contains 45 to 70% by weight, more preferably 50 to 60% by weight, of S2U based on the total fat B. If the content is less than 45% by weight, the whipping property and hardness after whipping may deteriorate, and if the content is more than 70% by weight, the stability of the original liquid, the whipping property, and the hardness after whipping may deteriorate, or the melting in the mouth may be delayed. Here, S2U refers to a triglyceride in which, as constituent fatty acids, two molecules of saturated fatty acid S having a C16 or more (preferably C24 or less) and one molecule of unsaturated fatty acid U having a C16 or more (preferably C24 or less) are bound to one molecule of glycerin, and the binding positions of S and U are not limited.
また、油脂Bの上昇融点は、23~30℃であることが好ましく、24~29℃がより好ましく、25~29℃がさらに好ましく、26~28℃が特に好ましい。23℃より低いと、ホイップ後の硬さを維持できない場合があり、30℃より高いと、原液安定性、ホイップ性、及びホイップ後の硬さが悪くなったり、口溶けが遅くなる場合がある。 The melting point of the fat B is preferably 23 to 30°C, more preferably 24 to 29°C, even more preferably 25 to 29°C, and particularly preferably 26 to 28°C. If it is lower than 23°C, the hardness after whipping may not be maintained, and if it is higher than 30°C, the stability of the concentrate, whipping properties, and hardness after whipping may deteriorate, or melting in the mouth may be delayed.
前記油脂Bの種類としては、パーム系油脂が挙げられ、具体的にはパーム油(上昇融点:33±1℃)、パーム油中融点部(上昇融点:27±1℃)、パームオレイン(上昇融点:22±1℃)等が例示でき、それらの群より選ばれる少なくとも1種を用いることができる。また、油脂Bが複数種の油脂をブレンドした混合油脂である場合は、当該混合油脂全体に含まれるC16~C22の飽和脂肪酸含量及びS2U含量が前記含量の範囲に入り、且つ当該複数種の油脂の上昇融点の平均値が前記上昇融点の範囲に入っていれば良い。 Examples of the type of fat B include palm-based fats and oils, and specific examples include palm oil (elevation melting point: 33±1° C.), palm mid-melting point (elevation melting point: 27±1° C.), palm olein (elevation melting point: 22±1° C.), etc., and at least one selected from these groups can be used. When fat B is a mixed fat obtained by blending multiple types of fats and oils, it is sufficient that the C 16 to C 22 saturated fatty acid content and S2U content contained in the entire mixed fat and oil are within the above-mentioned ranges, and the average value of the elevation melting points of the multiple types of fats and oils is within the above-mentioned range.
なお、前記油脂A及び油脂Bの上昇融点の測定は、日本油化学会 基準油脂分析試験法に従い、自動上昇融点測定器を用いて実施すればよい。 The slip melting points of the fats and oils A and B may be measured using an automatic slip melting point measuring device in accordance with the standard method for analysis of fats and oils set forth by the Japan Oil Chemists' Society.
前記起泡性コンパウンドクリームに含まれる油脂の内、前記乳脂肪を除く油脂全体中、前記油脂A及び前記油脂Bの合計含有量は80~100重量%が好ましく、83~100重量%がより好ましく、88~100重量%がさらに好ましく、95~100重量%が特に好ましい。合計含有量が80重量%より少ないと、口溶けが遅い場合がある。 Of the fats and oils contained in the foaming compound cream, the total content of fats and oils A and B in the total fats and oils excluding the milk fat is preferably 80 to 100% by weight, more preferably 83 to 100% by weight, even more preferably 88 to 100% by weight, and particularly preferably 95 to 100% by weight. If the total content is less than 80% by weight, the melting in the mouth may be slow.
前記油脂B/(前記油脂A+前記油脂B)(重量比)は、0.45~0.82であることが好ましく、0.5~0.80がより好ましく、0.5~0.78がさらに好ましく、0.5~0.75が特に好ましい。前記比が0.45より小さいと、原液安定性、ホイップ性、ホイップ後の硬さが悪くなったり、口溶けが遅い場合があり、0.82より大きいと、原液安定性、ホイップ性、ホイップ後の硬さが悪化したり、口溶けが遅くなったり、口溶けの自然さが損なわれる場合がある。 The weight ratio of the oil/fat B/(the oil/fat A+the oil/fat B) is preferably 0.45 to 0.82, more preferably 0.5 to 0.80, even more preferably 0.5 to 0.78, and particularly preferably 0.5 to 0.75. If the ratio is less than 0.45, the stock solution stability, whipping properties, and hardness after whipping may deteriorate, or melting in the mouth may be slow, while if it is more than 0.82, the stock solution stability, whipping properties, and hardness after whipping may deteriorate, melting in the mouth may be slow, or the natural melting in the mouth may be impaired.
本発明の起泡性コンパウンドクリームの油脂としては、前記乳脂肪、油脂A、油脂B以外にも、それらの含有量が満たされており、本発明の効果を損なわなければ、必要に応じて更に別の油脂を含んでも良い。別の油脂としては、例えば、菜種油、コーン油、綿実油、大豆油、ひまわり油、サフラワー油、オリーブ油、米油、牛脂、豚脂、魚油等が挙げられる。 The fats and oils contained in the foamable compound cream of the present invention may include other fats and oils in addition to the milk fat, fat A, and fat B, as long as the content of these fats and oils is sufficient and does not impair the effects of the present invention. Examples of other fats and oils include rapeseed oil, corn oil, cottonseed oil, soybean oil, sunflower oil, safflower oil, olive oil, rice oil, beef tallow, lard, and fish oil.
前記起泡性コンパウンドクリームには、水分を起泡性コンパウンドクリーム全体中40~70重量%含有することが好ましく、45~70重量%であることがより好ましく、50~70重量%がさらに好ましく、55~70重量%が特に好ましい。40重量%より少ないと、ホイップ後のみずみずしさに欠けたり、原液安定性が悪い場合があり、70重量%より多いと、ホイップ性とホイップ後の硬さが悪かったり油のコクを感じ難くなる場合がある。 The foaming compound cream preferably contains 40 to 70% by weight of water, more preferably 45 to 70% by weight, even more preferably 50 to 70% by weight, and particularly preferably 55 to 70% by weight. If it contains less than 40% by weight, the freshness after whipping may be lacking and the stability of the concentrate may be poor, and if it contains more than 70% by weight, the whipping properties and hardness after whipping may be poor and the richness of the oil may be difficult to feel.
前記油脂含量と前記水分含量との重量比(油脂/水分)は0.4~1.2であることが好ましく、0.5~1.0であることがより好ましい。0.4未満であると起泡性が悪化する場合があり、1.2より大きいと原液安定性が悪化したり、水中油型乳化とならない場合がある。 The weight ratio of the oil content to the water content (oil/water) is preferably 0.4 to 1.2, and more preferably 0.5 to 1.0. If it is less than 0.4, the foaming properties may deteriorate, and if it is more than 1.2, the stability of the concentrate may deteriorate or oil-in-water emulsion may not be obtained.
前記乳化剤Aは、HLBが2.8~6.2であることが好ましく、3.5~5.5がより好ましい。HLBが2.8より低いと、原液安定性やホイップ後の硬さが悪化する場合があり、6.2より高いと、ホイップ性とホイップ後の硬さが悪化する場合がある。 The emulsifier A preferably has an HLB of 2.8 to 6.2, more preferably 3.5 to 5.5. If the HLB is lower than 2.8, the stability of the concentrate and the hardness after whipping may deteriorate, and if it is higher than 6.2, the whipping properties and the hardness after whipping may deteriorate.
前記乳化剤Aは、C10~C22の飽和脂肪酸を構成脂肪酸全体中70~100重量%含むショ糖脂肪酸エステル及び/又はポリグリセリン脂肪酸エステルであることが好ましい。C10~C22の飽和脂肪酸の合計量が70重量%より少ないと、口溶けが遅くなったり、乳化剤特有の異味が発現する場合がある。 The emulsifier A is preferably a sucrose fatty acid ester and/or a polyglycerin fatty acid ester containing 70 to 100% by weight of C10 to C22 saturated fatty acids based on the total amount of constituent fatty acids. If the total amount of C10 to C22 saturated fatty acids is less than 70% by weight, the emulsifier may dissolve slowly in the mouth or may have an unpleasant taste specific to the emulsifier.
前記乳化剤Aは、起泡性コンパウンドクリームの水相中に含まれる。乳化剤Aが水相に含まれず油相に含まれると、ホイップ性やホイップ後の硬さが悪化する場合がある。水相中の前記乳化剤Aの含有量は、起泡性コンパウンドクリーム全体中0.05~0.55重量%であることが好ましく、0.06~0.52重量%であることがより好ましく、0.08~0.3重量%であることがさらに好ましく、0.10~0.2重量%であることが特に好ましい。0.05重量%より少ないと、ホイップ性やホイップ後の硬さが悪化する場合があり、0.55重量%より多いと、ホイップ後の硬さが悪化する場合がある。 The emulsifier A is contained in the aqueous phase of the foaming compound cream. If emulsifier A is contained in the oil phase but not in the aqueous phase, the whipping properties and hardness after whipping may deteriorate. The content of emulsifier A in the aqueous phase is preferably 0.05 to 0.55% by weight of the entire foaming compound cream, more preferably 0.06 to 0.52% by weight, even more preferably 0.08 to 0.3% by weight, and particularly preferably 0.10 to 0.2% by weight. If it is less than 0.05% by weight, the whipping properties and hardness after whipping may deteriorate, and if it is more than 0.55% by weight, the hardness after whipping may deteriorate.
なお、乳化剤A以外にも、必要に応じて、HLBが6.0未満の乳化剤を油相に配合してもよいし、HLBが6.0以上の乳化剤を水相に配合してもよい。 In addition to emulsifier A, if necessary, an emulsifier with an HLB of less than 6.0 may be added to the oil phase, and an emulsifier with an HLB of 6.0 or more may be added to the aqueous phase.
しかし、不飽和脂肪酸の結合した乳化剤は異味を発現する場合があるため、風味を良くする観点から、不飽和脂肪酸の結合した乳化剤の含有量は少ないほど良く、起泡性コンパウンドクリーム全体中0.02重量%未満であることが好ましい。 However, since emulsifiers with bound unsaturated fatty acids may produce an unpleasant taste, from the viewpoint of improving the flavor, the lower the content of emulsifiers with bound unsaturated fatty acids, the better, and it is preferable for the content to be less than 0.02% by weight of the entire foaming compound cream.
本発明の起泡性コンパウンドクリームは、本発明の効果を損なわない範囲で、必要に応じて、増粘剤、糖類、乳固形分、呈味剤、着色料、香料、塩分、ビタミン類、ミネラル類、酸化防止剤、その他の食品成分、添加剤等を含有してもよい。 The foaming compound cream of the present invention may contain thickeners, sugars, milk solids, flavorings, colorants, fragrances, salt, vitamins, minerals, antioxidants, other food ingredients, additives, etc., as necessary, within the scope of not impairing the effects of the present invention.
前記起泡性コンパウンドクリームをホイップすることで、ホイップドコンパウンドクリームが得られる。得られるホイップドコンパウンドクリームは、様々な食品にトッピングしたり、ナッペしたり、フィリングしたり、サンドしたりして利用できる。前記食品としては、クリームパン、クリームサンド、サンドイッチ等のパン、ケーキ、シュー、オムレット、どら焼き等の菓子が挙げられる。 The whipped compound cream is whipped to obtain a whipped compound cream. The whipped compound cream obtained can be used as a topping, a coating, a filling, or a sandwich for various foods. Examples of such foods include breads such as cream buns, cream sandwiches, and sandwiches, as well as cakes, choux pastries, omelets, and dorayaki.
本発明の起泡性コンパウンドクリームの製造方法を以下に例示する。即ち、まず起泡性コンパウンドクリーム全体中、乳化剤A含量が0.05~0.55重量%となるように乳化剤Aを水に添加して撹拌しながら60℃以上に加熱して溶解し、起泡性コンパウンドクリーム全体中のリン酸塩含量を0.02重量%未満且つ水分含量を40~70重量%になるように調整した水相部を作製する。 The method for producing the foaming compound cream of the present invention is exemplified below. That is, emulsifier A is first added to water so that the content of emulsifier A in the entire foaming compound cream is 0.05 to 0.55% by weight, and the mixture is heated to 60°C or higher while stirring to dissolve, and an aqueous phase is prepared in which the phosphate content in the entire foaming compound cream is less than 0.02% by weight and the water content is 40 to 70% by weight.
次いで、油脂全体中における油脂Aと油脂Bの合計含有量が62~96.5重量%且つ油脂B/(油脂A+油脂B)(重量比)が0.45~0.82となるように油脂A及び油脂Bを混合し、必要に応じて他の油脂も混合して、起泡性コンパウンドクリーム全体中の油脂含量を25~50重量%且つ前記油脂全体中のエステル交換油脂含量を1重量%未満になるように調整した油脂混合物を前記水相部に添加し、予備乳化した後、微細化し、さらに高圧処理することにより、水中油型乳化油脂組成物を作製する。 Next, fats A and B are mixed so that the total content of fats A and B in the total fats is 62 to 96.5% by weight and the weight ratio of fats B/(fat A + fat B) is 0.45 to 0.82, and other fats are also mixed as necessary. The fat mixture is adjusted so that the fat content in the total foaming compound cream is 25 to 50% by weight and the transesterified fat content in the total fats is less than 1% by weight, and is added to the aqueous phase. The mixture is pre-emulsified, then pulverized and further treated under high pressure to produce an oil-in-water emulsified fat composition.
前記水中油型乳化油脂組成物に、前記油脂全体中の乳脂肪含量が3.5重量%以上且つ22.5重量%未満になるように生クリーム等の乳脂肪含有成分を混合・撹拌することで、本発明の起泡性コンパウンドクリームを得ることができる。 The foamable compound cream of the present invention can be obtained by mixing and stirring the oil-in-water emulsified oil composition with a milk fat-containing component such as fresh cream so that the milk fat content in the entire oil is 3.5% by weight or more and less than 22.5% by weight.
なお、前記生クリーム等の乳脂肪含有成分は、前記水相部の原料として他原料と混合し、そこへ前記油脂混合物を添加し、予備乳化した後、微細化し、さらに高圧処理して前記起泡性コンパウンドクリームを得ることもできる。 The milk fat-containing component such as the fresh cream can be mixed with other ingredients as the raw material for the aqueous phase, to which the oil mixture is added, pre-emulsified, then pulverized and further treated under high pressure to obtain the foamable compound cream.
以下に実施例を示し、本発明をより具体的に説明するが、本発明はこれらの実施例に何ら限定されるものではない。なお、実施例において「部」や「%」は重量基準である。 The present invention will be described in more detail below with reference to examples, but the present invention is not limited to these examples. In the examples, "parts" and "%" are by weight.
<製造例、実施例及び比較例で使用した原料>
1)(株)カネカ製「パーム核油」(C12以下の飽和脂肪酸:51.2重量%、上昇融点:27.4℃、ラウリン酸:44.9重量%、S2U:3.6重量%)
2)(株)カネカ製「パーム核硬化油」(C12以下の飽和脂肪酸:53.0重量%、上昇融点:40.3℃、ラウリン酸:46.4重量%、S2U:1.3重量%)
3)(株)カネカ製「パーム油中融点部」(C16~C22の飽和脂肪酸:53.7重量%、上昇融点:26.8℃、トランス脂肪酸:0.1重量%、総飽和脂肪酸:55.6重量%、S2U:65.8重量%)
4)(株)カネカ製「パームオレイン」(C16~C22の飽和脂肪酸:44.7重量%、上昇融点:21.9℃、トランス脂肪酸:0.2重量%、総飽和脂肪酸:45.9重量%、S2U:44.0重量%)
5)(株)カネカ製「パームエステル交換油」(パーム核とパーム油のエステル交換油、C16~C22の飽和脂肪酸:31.0重量%、上昇融点:27.5℃、S2U含:0重量%)
6)(株)カネカ製「ナタネ油」(C12以下の飽和脂肪酸:0重量%、C16~C22の飽和脂肪酸:6.5重量%、S2U:0重量%、融点は測定不可)
7)ADM(株)製「Yelkin TS」(不飽和脂肪酸:78.9重量%)
8)阪本薬品工業(株)製ポリグリセリン混酸エステル「SYグリスター CV-23」(不飽和脂肪酸:0.1重量%)
9)阪本薬品工業(株)製ポリグリセリンベヘン酸エステル「SYグリスターDDB-750」(HLB:2.5、不飽和脂肪酸:0.1重量%)
10)阪本薬品工業(株)製ポリグリセリンステアリン酸エステル「SYグリスター MS-3S」(HLB:8.4、不飽和脂肪酸:0.1重量%)
11)よつ葉乳業(株)製「ヨツバ脱脂粉乳」(乳脂肪分:0.7重量%)
12)Friesland Campina DMV社製「カゼインカリウムSPRAY」
13)HILMAR社製「ラクトース HILMAR FINE GRAIND」
14)阪本薬品工業(株)製ポリグリセリンステアリン酸エステル「SYグリスター TS-3S」(HLB:4.6、C10~C22の飽和脂肪酸:99.4重量%)
15)阪本薬品工業(株)製ポリグリセリンステアリン酸エステル「SYグリスターMS-5S」(HLB:11.6、C10~C22の飽和脂肪酸:99.8重量%)
16)(株)明治製「明治フレッシュクリーム43」(乳脂肪分:43重量%、水分:52.33重量%)
17)三菱ケミカルフーズ(株)製ショ糖ステアリン酸エステル「S-370」(HLB:3.0、C10~C22の飽和脂肪酸:100.0重量%)
18)阪本薬品工業(株)製「SYグリスター PS-5S」(HLB:4.5、C10~C22の飽和脂肪酸:99.6重量%)
19)三菱ケミカルフーズ(株)製ショ糖ステアリン酸エステル「S-570」(HLB:5.0、C10~C22の飽和脂肪酸:100.0重量%)
20)阪本薬品工業(株)製ポリグリセリンステアリン酸エステル「SYグリスター PS-3S」(HLB:2.6、C10~C22の飽和脂肪酸:99.8重量%)
21)太陽化学(株)製ポリグリセリンステアリン酸エステル「サンソフトQ18-B」(HLB:6.5、C10~C22の飽和脂肪酸:99.7重量%)
22)三菱ケミカルフーズ(株)製ショ糖ステアリン酸エステル「S-770」(HLB:7.0、C10~C22の飽和脂肪酸:100.0重量%)
23)阪本薬品工業(株)製ポリグリセリンオレイン酸エステル「SYグリスター MO-5S」(HLB:11.6、C10~C22の飽和脂肪酸:29.81重量%、不飽和脂肪酸:70重量%)
24)(株)カネカ製「パーム核オレイン」(C12以下の飽和脂肪酸:47.5重量%、上昇融点:23.0℃、ラウリン酸:40.5重量%、S2U:2.6重量%)
25)(株)カネカ製「パーム油中融点部」(C16~C22の飽和脂肪酸:64.2重量%、S2U:91.8重量%、上昇融点:31.3℃)
<Raw materials used in the Production Examples, Examples and Comparative Examples>
1) "Palm kernel oil" manufactured by Kaneka Corporation ( C12 or less saturated fatty acids: 51.2% by weight, melting point: 27.4°C, lauric acid: 44.9% by weight, S2U: 3.6% by weight)
2) "Hydrogenated Palm Kernel Oil" manufactured by Kaneka Corporation ( C12 or less saturated fatty acids: 53.0% by weight, melting point: 40.3°C, lauric acid: 46.4% by weight, S2U: 1.3% by weight)
3) "Palm oil mid-melting point fraction" manufactured by Kaneka Corporation ( C16 - C22 saturated fatty acids: 53.7% by weight, slip melting point: 26.8°C, trans fatty acids: 0.1% by weight, total saturated fatty acids: 55.6% by weight, S2U: 65.8% by weight)
4) "Palm Olein" manufactured by Kaneka Corporation ( C16 to C22 saturated fatty acids: 44.7% by weight, slip melting point: 21.9°C, trans fatty acids: 0.2% by weight, total saturated fatty acids: 45.9% by weight, S2U: 44.0% by weight)
5) "Palm interesterified oil" manufactured by Kaneka Corporation (interesterified oil of palm kernel and palm oil, C16 - C22 saturated fatty acid: 31.0% by weight, slip melting point: 27.5°C, S2U content: 0% by weight)
6) "Rapeseed oil" manufactured by Kaneka Corporation ( C12 or less saturated fatty acids: 0% by weight, C16 to C22 saturated fatty acids: 6.5% by weight, S2U: 0% by weight, melting point not measurable)
7) “Yelkin TS” manufactured by ADM Co., Ltd. (unsaturated fatty acid: 78.9% by weight)
8) Polyglycerol mixed acid ester "SY Glyster CV-23" (unsaturated fatty acid: 0.1% by weight) manufactured by Sakamoto Pharmaceutical Co., Ltd.
9) Polyglycerol behenate "SY Glystar DDB-750" (HLB: 2.5, unsaturated fatty acid: 0.1% by weight) manufactured by Sakamoto Pharmaceutical Co., Ltd.
10) Polyglycerol stearate "SY Glyster MS-3S" (HLB: 8.4, unsaturated fatty acid: 0.1% by weight) manufactured by Sakamoto Yakuhin Kogyo Co., Ltd.
11) Yotsuba skim milk powder (milk fat content: 0.7% by weight) manufactured by Yotsuba Milk Industry Co., Ltd.
12) "Casein Potassium SPRAY" manufactured by Friesland Campina DMV
13) HILMAR "Lactose HILMAR FINE GRAIN"
14) Polyglycerol stearate "SY Glyster TS-3S" (HLB: 4.6, C10 - C22 saturated fatty acids: 99.4% by weight) manufactured by Sakamoto Yakuhin Kogyo Co., Ltd.
15) Polyglycerol stearate "SY Glystar MS-5S" (HLB: 11.6, C10 - C22 saturated fatty acids: 99.8% by weight) manufactured by Sakamoto Yakuhin Kogyo Co., Ltd.
16) Meiji Fresh Cream 43 (Milk fat content: 43% by weight, moisture content: 52.33% by weight) manufactured by Meiji Co., Ltd.
17) Mitsubishi Chemical Foods Corporation, sucrose stearate "S-370" (HLB: 3.0, C10 - C22 saturated fatty acids: 100.0% by weight)
18) "SY Glystar PS-5S" manufactured by Sakamoto Pharmaceutical Co., Ltd. (HLB: 4.5, C10 - C22 saturated fatty acids: 99.6% by weight)
19) Mitsubishi Chemical Foods Corporation, sucrose stearate "S-570" (HLB: 5.0, C10 - C22 saturated fatty acids: 100.0% by weight)
20) Polyglycerol stearate "SY Glyster PS-3S" (HLB: 2.6, C10 - C22 saturated fatty acids: 99.8% by weight) manufactured by Sakamoto Yakuhin Kogyo Co., Ltd.
21) Polyglycerol stearate "Sunsoft Q18-B" (HLB: 6.5, C10 - C22 saturated fatty acids: 99.7% by weight) manufactured by Taiyo Kagaku Co., Ltd.
22) Mitsubishi Chemical Foods Corporation, sucrose stearate "S-770" (HLB: 7.0, C10 - C22 saturated fatty acids: 100.0% by weight)
23) Polyglycerol oleate "SY Glyster MO-5S" manufactured by Sakamoto Pharmaceutical Co., Ltd. (HLB: 11.6, C10 - C22 saturated fatty acids: 29.81% by weight, unsaturated fatty acids: 70% by weight)
24) "Palm kernel olein" manufactured by Kaneka Corporation ( C12 or less saturated fatty acids: 47.5% by weight, melting point: 23.0°C, lauric acid: 40.5% by weight, S2U: 2.6% by weight)
25) "Palm oil mid-melting point fraction" manufactured by Kaneka Corporation ( C16 - C22 saturated fatty acids: 64.2% by weight, S2U: 91.8% by weight, slip melting point: 31.3°C)
<原液安定性評価>
実施例・比較例で得られた起泡性コンパウンドクリームをガラスビーカーに60g取り分け、15℃で1時間静置した後、120rpmで撹拌し、増粘するまでの時間(ボテ時間)(分)を測定し、評価値とした。
<Evaluation of stock solution stability>
60 g of the foamable compound cream obtained in the Examples and Comparative Examples was dispensed into a glass beaker, left to stand at 15° C. for 1 hour, and then stirred at 120 rpm. The time (minutes) until the cream thickened was measured and used as the evaluation value.
<ホイップ性(オーバーラン)評価>
実施例・比較例で得られた起泡性コンパウンドクリームを、硬さが0.30Nになるまでホイップした時の体積あたりの含気率の計算値をオーバーラン(%)とした。
<Whipping (overrun) evaluation>
The foamable compound cream obtained in each of the Examples and Comparative Examples was whipped to a hardness of 0.30 N, and the calculated air content per volume was taken as overrun (%).
<ホイップ性(ホイップタイム)評価>
実施例・比較例で得られた起泡性コンパウンドクリームを、硬さが0.30Nになるまでホイップした時の時間(分、秒)を測定し、評価値とした。
<Whipability (whip time) evaluation>
The time (minutes, seconds) required for whipping each of the foaming compound creams obtained in the Examples and Comparative Examples until the hardness reached 0.30 N was measured and used as an evaluation value.
<ホイップ後の硬さ評価>
実施例・比較例で得られた硬さが0.30Nのホイップドコンパウンドクリームを室温にて30分間静置した後の最大荷重をレオナーで測定し、その変化を評価した。その際の評価は、下記の基準で行った。
5点:ホイップ後の硬さ変化が0.03N以上且つ0.06N以下
4点:ホイップ後の硬さ変化が0.02N以上0.03N未満、又は0.06Nより大きく0.07N以下
3点:ホイップ後の硬さ変化が0.01N以上0.02N未満、又は0.07Nより大きく0.09N以下
2点:ホイップ後の硬さ変化が0.09Nより大きく0.2N未満、又は-0.05N以上0.01N未満
1点:ホイップ後の硬さ変化が0.2N以上、又は-0.05N未満
<Evaluation of hardness after whipping>
The whipped compound creams with a hardness of 0.30 N obtained in the Examples and Comparative Examples were left to stand at room temperature for 30 minutes, after which the maximum load was measured using a Leonar and the change was evaluated. The evaluation was performed according to the following criteria.
5 points: change in hardness after whipping is 0.03N or more and 0.06N or less; 4 points: change in hardness after whipping is 0.02N or more and less than 0.03N, or more than 0.06N and less than 0.07N; 3 points: change in hardness after whipping is 0.01N or more and less than 0.02N, or more than 0.07N and less than 0.09N; 2 points: change in hardness after whipping is 0.09N or more and less than 0.2N, or -0.05N or more and less than 0.01N; 1 point: change in hardness after whipping is 0.2N or more, or less than -0.05N
<口溶け(早さ)評価>
実施例・比較例で得られたホイップドコンパウンドクリームを、熟練のパネラー10人が口に含み、5点満点で評価して、その平均点を評価点とした。その際の評価基準は、以下の通りであった。
5点:比較例3のホイップドクリームよりも極めて口溶けが早い
4点:比較例3のホイップドクリームよりも口溶けが早い
3点:比較例3のホイップドクリームと口溶けの早さが同等
2点:比較例3のホイップドクリームよりも口溶けが遅い
1点:比較的3のホイップドクリームよりも極めて口溶けが遅い
<Evaluation of melting speed>
The whipped compound creams obtained in the Examples and Comparative Examples were put into the mouths of 10 experienced panelists, who evaluated them on a scale of 1 to 5, and the average score was taken as the evaluation score. The evaluation criteria were as follows:
5 points: melts in the mouth much faster than the whipped cream of Comparative Example 3. 4 points: melts in the mouth much faster than the whipped cream of Comparative Example 3. 3 points: melts in the mouth at the same speed as the whipped cream of Comparative Example 3. 2 points: melts in the mouth slower than the whipped cream of Comparative Example 3. 1 point: melts in the mouth much slower than the whipped cream of Comparative Example 3.
<口溶け(自然さ)評価>
実施例・比較例で得られたホイップドコンパウンドクリームを、熟練のパネラー10人が口に含み、評価した結果を平均的に表した。その際の評価基準は、以下の通りであった。
○:口溶けを1回だけ感じる
△:口溶けを僅かに2回に分かれて感じる
×:口溶けを2回に分かれて感じる
<Evaluation of melt-in-the-mouth (naturalness)>
The whipped compound creams obtained in the Examples and Comparative Examples were put into the mouths of 10 experienced panelists, and the results were averaged. The evaluation criteria were as follows:
○: Melt in the mouth only once. △: Melt in the mouth is felt slightly in two separate times. ×: Melt in the mouth is felt in two separate times.
<総合評価>
評価した原液安定性(ボテ時間)、ホイップ性(オーバーラン、ホイップタイム)、ホイップ後の硬さ、口溶け(早さ、自然さ)の各評価を、以下の基準に従って、総合評価した。
A:ボテ時間30分以上、オーバーラン110%以上、ホイップタイム5~7分、ホイップ後の硬さの評価が5点、口溶け(早さ)の評価が4.5~5点、及び、口溶け(自然さ)の評価が○を満足するもの
B:Aの要件を満たさず、ボテ時間30分以上、オーバーラン110%以上、ホイップタイム5~7分、ホイップ後の硬さの評価が4点以上、口溶け(早さ)の評価が3.5点以上、及び、口溶け(自然さ)の評価が○又は△を満足するもの
C:A及びBの要件を満たさず、ボテ時間30分以上、オーバーラン110%以上、ホイップタイム5~7分、ホイップ後の硬さの評価が3点以上、口溶け(早さ)の評価が3.0点を超え、及び、口溶け(自然さ)の評価が○又は△を満足するもの
D:Eの要件を満たさず、ボテ時間20分以上30分未満、オーバーラン90%以上110%未満、ホイップタイム7分以上8分半未満、ホイップ後の硬さの評価が2点、及び、口溶け(早さ)の評価が2.0点以上3.0点以下からなる評価群より選ばれる少なくとも一つに該当するもの
E:ボテ時間20分未満、オーバーラン90%未満、ホイップタイム8分半以上、ホイップ後の硬さの評価が1点、口溶け(早さ)の評価が2.0点未満、及び口溶け(自然さ)の評価が×からなる評価群より選ばれる少なくとも一つに該当するもの
<Overall evaluation>
The evaluated ingredients stability (blotting time), whipping properties (overrun, whipping time), hardness after whipping, and melting in the mouth (quickness, naturalness) were evaluated and comprehensively rated according to the following criteria.
A: A dough time of 30 minutes or more, overrun of 110% or more, whipping time of 5 to 7 minutes, hardness after whipping rated at 5 points, melting in the mouth (speed) rated at 4.5 to 5 points, and melting in the mouth (naturalness) rated at ○. B: A dough time of 30 minutes or more, overrun of 110% or more, whipping time of 5 to 7 minutes, hardness after whipping rated at 4 points or more, melting in the mouth (speed) rated at 3.5 points or more, and melting in the mouth (naturalness) rated at ○ or △. C: A dough time of 30 minutes or more, overrun of 110% or more, whipping time of 5 to 7 minutes, hardness after whipping rated at 3 points or more, and melting in the mouth (speed) rated at ○ or △. D: Those that do not meet the requirements of E and fall into at least one of the following evaluation groups: a stuffing time of 20 to 30 minutes, an overrun of 90% to 110%, a whipping time of 7 to 8.5 minutes, a hardness rating of 2 after whipping, and a melt-in-the-mouth (speed) rating of 2.0 to 3.0 points. E: Those that fall into at least one of the following evaluation groups: a stuffing time of less than 20 minutes, an overrun of less than 90%, a whipping time of 8.5 minutes or more, a hardness rating of 1 after whipping, a melt-in-the-mouth (speed) rating of less than 2.0 points, and a melt-in-the-mouth (naturalness) rating of x.
(製造例A1)水中油型乳化油脂組成物A1の作製
表1の配合に従い、パーム核油:7.3重量部、パーム油中融点部(PMF):18.2重量部及びパームオレイン:11.5重量部の油脂混合物に、大豆レシチン:0.2重量部、ポリグリセリン混酸エステル:0.06重量部、ポリグリセリンベヘン酸エステル:0.03重量部を添加し、65℃で溶解して油相部を作製した。
(Production Example A1) Preparation of oil-in-water emulsified oil composition A1 According to the formulation in Table 1, to an oil mixture of 7.3 parts by weight of palm kernel oil, 18.2 parts by weight of palm mid fraction (PMF), and 11.5 parts by weight of palm olein, 0.2 part by weight of soybean lecithin, 0.06 part by weight of polyglycerol mixed acid ester, and 0.03 part by weight of polyglycerol behenate were added and dissolved at 65° C. to prepare an oil phase.
また別に、脱脂粉乳:3.7重量部、カゼインカリウム:0.5重量部、乳糖1.5重量部、ポリグリセリンステアリン酸エステル(乳化剤A、HLB:4.6、C10~C22の飽和脂肪酸:99.4重量%):0.15重量部、ポリグリセリンステアリン酸エステル(HLB:11.6、C10~C22の飽和脂肪酸:98.0重量%)0.05重量部を、表1の配合と最終的に同じになるように60℃以上の温水に溶解して水相部を作製した。 Separately, 3.7 parts by weight of skim milk powder, 0.5 parts by weight of potassium caseinate, 1.5 parts by weight of lactose, 0.15 parts by weight of polyglycerol stearate (emulsifier A, HLB: 4.6, C10 - C22 saturated fatty acids: 99.4% by weight), and 0.05 parts by weight of polyglycerol stearate (HLB: 11.6, C10 - C22 saturated fatty acids: 98.0% by weight) were dissolved in hot water of 60°C or higher to give a final composition identical to that in Table 1 to prepare an aqueous phase.
前記の油相部と水相部とを混合して20分以上予備乳化した後、高周速回転式乳化機(エム・テクニック(株)製「クレアミックス」)を用いて周速31.4m/sの回転速度で微細化した。次いで、高圧ホモジナイザーを用いて1段目:2.0MPa/2段目:1.0MPaの圧力で処理した後に、プレート式加熱機を用いて90℃まで予備加熱した後、UHT殺菌機(スチームインジェクション)を用いて142℃で4秒間殺菌処理した。次に、蒸発冷却せずにプレート式冷却機を用いて60℃まで冷却し、再び高圧ホモジナイザーを用いて1段目:9.0MPa/2段目:3.0MPaの圧力で処理し、その後、プレート式冷却機で5℃まで冷却したものを容器に充填し、5℃の冷蔵庫で48時間保管し、水中油型乳化油脂組成物A1を得た。 The oil phase and the water phase were mixed and pre-emulsified for 20 minutes or more, and then pulverized at a rotation speed of 31.4 m/s using a high-speed rotary emulsifier ("Clearmix" manufactured by M Technique Co., Ltd.). The mixture was then treated with a high-pressure homogenizer at a pressure of 2.0 MPa (first stage) and 1.0 MPa (second stage), preheated to 90°C using a plate heater, and sterilized at 142°C for 4 seconds using a UHT sterilizer (steam injection). The mixture was then cooled to 60°C using a plate cooler without evaporative cooling, and treated again with a high-pressure homogenizer at a pressure of 9.0 MPa (first stage) and 3.0 MPa (second stage), and then cooled to 5°C using a plate cooler. The mixture was then filled into a container and stored in a refrigerator at 5°C for 48 hours to obtain an oil-in-water emulsified oil composition A1.
(製造例A2)水中油型乳化油脂組成物A2の作製
表1に従って、パーム核油:11.1重量部、パーム油中融点部(PMF):15.9重量部及びパームオレイン:10.0重量部に変更した以外は、製造例A1と同様にして水中油型乳化油脂組成物A2を得た。
(Production Example A2) Preparation of oil-in-water emulsified oil composition A2 According to Table 1, the same procedure as in Production Example A1 was repeated, except that the amounts of palm kernel oil, palm mid fraction (PMF), and palm olein were changed to 11.1 parts by weight, 15.9 parts by weight, and 10.0 parts by weight, respectively, to obtain an oil-in-water emulsified oil composition A2.
(製造例A3)水中油型乳化油脂組成物A3の作製
表1に従って、パーム核油:18.5重量部、パーム油中融点部(PMF):11.3重量部及びパームオレイン:7.2重量部に変更した以外は、製造例A1と同様にして水中油型乳化油脂組成物A3を得た。
(Production Example A3) Preparation of oil-in-water emulsified oil composition A3 According to Table 1, the same procedure as in Production Example A1 was repeated, except that the amounts of palm kernel oil, palm mid fraction (PMF), and palm olein were changed to 18.5 parts by weight, 11.3 parts by weight, and 7.2 parts by weight, respectively, to obtain oil-in-water emulsified oil composition A3.
(製造例A4)水中油型乳化油脂組成物A4の作製
表1に従って、パーム核油:9.4重量部、パーム油中融点部(PMF):13.5重量部及びパームオレイン:8.5重量部に変更し、さらにその他の油脂として菜種油:5.6重量部を混合して油脂混合物とし、水量を調整した以外は、製造例A1と同様にして水中油型乳化油脂組成物A4を得た。
(Production Example A4) Preparation of oil-in-water emulsified oil composition A4 According to Table 1, the amounts of palm kernel oil, palm mid fraction (PMF), and palm olein were changed to 9.4 parts by weight, 13.5 parts by weight, and 8.5 parts by weight, respectively, and 5.6 parts by weight of rapeseed oil was further added as other oils and fats to prepare an oil-and-fat mixture, and the amount of water was adjusted, and the same procedure as in Production Example A1 was repeated to prepare oil-in-water emulsified oil composition A4.
(製造例A5)水中油型乳化油脂組成物A5の作製
表1に従って、パーム核油:9.0重量部、パーム油中融点部(PMF):12.9重量部及びパームオレイン:8.1重量部に変更し、水量を調整した以外は、製造例A1と同様にして水中油型乳化油脂組成物A5を得た。
(Production Example A5) Preparation of oil-in-water emulsified oil composition A5 An oil-in-water emulsified oil composition A5 was prepared in the same manner as in Production Example A1, except that the amounts of palm kernel oil, palm mid fraction (PMF), and palm olein were changed to 9.0 parts by weight, 12.9 parts by weight, and 8.1 parts by weight, and the amount of water was adjusted according to Table 1.
(製造例A6)水中油型乳化油脂組成物A6の作製
表1に従って、パーム核油:13.5重量部、パーム油中融点部(PMF):19.3重量部及びパームオレイン:12.2重量部に変更し、水量を調整した以外は、製造例A1と同様にして水中油型乳化油脂組成物A6を得た。
(Production Example A6) Preparation of oil-in-water emulsified oil composition A6 An oil-in-water emulsified oil composition A6 was obtained in the same manner as in Production Example A1, except that the amounts of palm kernel oil, palm mid fraction (PMF), and palm olein were changed to 13.5 parts by weight, 19.3 parts by weight, and 12.2 parts by weight, and the amount of water was adjusted according to Table 1.
(製造例B1)水中油型乳化油脂組成物B1の作製
表1に従って、パーム核油:3.7重量部、パーム油中融点部(PMF):20.4重量部及びパームオレイン:12.9重量部に変更した以外は、製造例A1と同様にして水中油型乳化油脂組成物B1を得た。
(Production Example B1) Preparation of oil-in-water emulsified oil composition B1 According to Table 1, the same procedure as in Production Example A1 was repeated, except that the amounts of palm kernel oil, palm mid fraction (PMF), and palm olein were changed to 3.7 parts by weight, 20.4 parts by weight, and 12.9 parts by weight, respectively, to obtain oil-in-water emulsified oil composition B1.
(製造例B2)水中油型乳化油脂組成物B2の作製
表1に従って、パーム核油:29.6重量部、パーム油中融点部(PMF):4.5重量部及びパームオレイン:2.9重量部に変更した以外は、製造例A1と同様にして水中油型乳化油脂組成物B2を得た。
(Production Example B2) Preparation of oil-in-water emulsified oil composition B2 According to Table 1, the same procedure as in Production Example A1 was repeated, except that the amounts of palm kernel oil, palm mid fraction (PMF), and palm olein were changed to 29.6 parts by weight, 4.5 parts by weight, and 2.9 parts by weight, respectively, to obtain oil-in-water emulsified oil composition B2.
(製造例B3)水中油型乳化油脂組成物B3の作製
表1に従って、混合油脂としてパーム油中融点部(PMF)とパームオレインは含まず、パーム核油:25.5重量部に変更し、さらにパーム核硬化油:4.0重量部、パームエステル交換油:7.5重量部を混合した以外は、製造例A1と同様にして水中油型乳化油脂組成物B3を得た。
(Production Example B3) Preparation of oil-in-water emulsified oil composition B3 According to Table 1, the procedure was the same as in Production Example A1, except that the mixed oil did not contain palm mid fraction (PMF) and palm olein, but was changed to 25.5 parts by weight of palm kernel oil, and further 4.0 parts by weight of palm kernel hardened oil and 7.5 parts by weight of palm interesterified oil were mixed in. Thus, oil-in-water emulsified oil composition B3 was obtained.
(実施例1)起泡性コンパウンドクリームA1及びホイップドコンパウンドクリームA1
製造例1で得られた水中油型乳化油脂組成物A1と生クリーム(乳脂肪分:43%)とを重量比95:5で混合することで起泡性コンパウンドクリームA1を得た。得られた起泡性コンパウンドクリームA1をカントーミキサー(関東混合機工業(株)製「CS型20」)に4kg入れ、品温を5℃に調整し、グラニュー糖320gを入れ、高速撹拌条件(380rpm)で硬さが0.30Nになるまでホイップし、ホイップドコンパウンドクリームA1を得た。得られた起泡性コンパウンドクリームA1とホイップドコンパウンドクリームA1の評価(原液安定性、ホイップ性(オーバーラン、ホイップタイム)、硬さ、口溶け(早さ、自然さ))を行い、それらの結果を表2にまとめた。
(Example 1) Foaming compound cream A1 and whipped compound cream A1
The oil-in-water emulsified oil composition A1 obtained in Production Example 1 was mixed with fresh cream (milk fat content: 43%) in a weight ratio of 95:5 to obtain a foamable compound cream A1. 4 kg of the obtained foamable compound cream A1 was placed in a Kanto mixer (Kanto Mixing Machinery Co., Ltd. "CS type 20"), the product temperature was adjusted to 5°C, 320 g of granulated sugar was added, and the mixture was whipped under high-speed stirring conditions (380 rpm) until the hardness reached 0.30 N to obtain a whipped compound cream A1. The obtained foamable compound cream A1 and whipped compound cream A1 were evaluated (stability of the original solution, whipping properties (overrun, whipping time), hardness, and melting in the mouth (fastness, naturalness)), and the results are summarized in Table 2.
(実施例2~6)起泡性コンパウンドクリームA2~A6及びホイップドコンパウンドクリームA2~A6
水中油型乳化油脂組成物A1を、水中油型乳化油脂組成物A2~A6に変えた以外は、実施例1と同様にして起泡性コンパウンドクリームA2~A6及びホイップドコンパウンドクリームA2~A6を得た。得られた起泡性コンパウンドクリームA2~A6とホイップドコンパウンドクリームA2~A6の評価(原液安定性、ホイップ性(オーバーラン、ホイップタイム)、硬さ、口溶け(早さ、自然さ))を行い、それらの結果を表2にまとめた。
(Examples 2 to 6) Foaming compound creams A2 to A6 and whipped compound creams A2 to A6
Except for changing the oil-in-water emulsified oil composition A1 to oil-in-water emulsified oil compositions A2 to A6, foamable compound creams A2 to A6 and whipped compound creams A2 to A6 were obtained in the same manner as in Example 1. The obtained foamable compound creams A2 to A6 and whipped compound creams A2 to A6 were evaluated (stock solution stability, whipping properties (overrun, whipping time), hardness, melting in the mouth (speed, naturalness)), and the results are summarized in Table 2.
(比較例1~3)起泡性コンパウンドクリームB1~B3及びホイップドコンパウンドクリームB1~B3
水中油型乳化油脂組成物A1を、水中油型乳化油脂組成物B1~B3に変えた以外は、実施例1と同様にして起泡性コンパウンドクリームB1~B3及びホイップドコンパウンドクリームB1~B3を得た。得られた起泡性コンパウンドクリームB1~B3とホイップドコンパウンドクリームB1~B3の評価(原液安定性、ホイップ性(オーバーラン、ホイップタイム)、硬さ、口溶け(早さ、自然さ))を行い、それらの結果を表2にまとめた。
(Comparative Examples 1 to 3) Foaming Compound Creams B1 to B3 and Whipped Compound Creams B1 to B3
Except for changing the oil-in-water emulsified oil composition A1 to oil-in-water emulsified oil compositions B1 to B3, foamable compound creams B1 to B3 and whipped compound creams B1 to B3 were obtained in the same manner as in Example 1. The obtained foamable compound creams B1 to B3 and whipped compound creams B1 to B3 were evaluated (stock solution stability, whipping properties (overrun, whipping time), hardness, melting in the mouth (speed, naturalness)), and the results are summarized in Table 2.
表2にまとめた結果より、以下のことがわかった。実施例1~3及び比較例1~2より、本発明の効果を奏するには油脂B/(油脂A+油脂B)(重量比)は0.45~0.82が好適であり、前記重量比を外れると、原液安定性やホイップ性が悪くなったり、ホイップ後の硬さや口溶けの早さ及び自然さが損なわれる場合があることが明らかとなった。また、実施例2、4及び比較例3より、乳脂肪を除く油脂全体中の油脂A及び油脂Bの合計含有量は80~100重量%が好適であり、前記合計含有量が80重量%を下回ると口溶けの早さが損なわれる場合があることが明らかとなり、実施例2、5~6より、起泡性コンパウンドクリーム全体中の油脂含有量が25~50重量%の範囲において本発明の効果を奏することが明らかとなった。 From the results summarized in Table 2, the following was found. From Examples 1 to 3 and Comparative Examples 1 and 2, it was revealed that in order to achieve the effects of the present invention, a weight ratio of 0.45 to 0.82 for fat B/(fat A + fat B) is preferable, and if the weight ratio is outside this range, the stability of the concentrate and whipping properties may deteriorate, and the hardness after whipping, the speed of melting in the mouth, and the naturalness may be impaired. Furthermore, from Examples 2 and 4 and Comparative Example 3, it was revealed that a total content of fat A and fat B in the entire fats and oils excluding milk fat is preferable to be 80 to 100% by weight, and if the total content is below 80% by weight, the speed of melting in the mouth may be impaired. From Examples 2 and 5 to 6, it was revealed that the effects of the present invention are achieved when the fat content in the entire foaming compound cream is in the range of 25 to 50% by weight.
(製造例A7)水中油型乳化油脂組成物A7の作製
表3に従って、製造例A2と全く同様にして、水中油型乳化油脂組成物A2と全く同じ水中油型乳化油脂組成物A7を作製した。
(Production Example A7) Preparation of oil-in-water emulsified oil composition A7 According to Table 3, an oil-in-water emulsified oil composition A7 that is exactly the same as the oil-in-water emulsified oil composition A2 was prepared in the same manner as in Production Example A2.
(製造例A8)水中油型乳化油脂組成物A8の作製
表3に従って、乳化剤Aであるポリグリセリンステアリン酸エステルの量を0.08重量部に変更し、水量を調整した以外は、製造例A2と同様にして水中油型乳化油脂組成物A8を得た。
(Production Example A8) Preparation of oil-in-water emulsified oil composition A8 Oil-in-water emulsified oil composition A8 was prepared in the same manner as in Production Example A2, except that the amount of emulsifier A (polyglycerol stearate) was changed to 0.08 parts by weight and the amount of water was adjusted according to Table 3.
(製造例A9)水中油型乳化油脂組成物A9の作製
表3に従って、乳化剤Aであるポリグリセリンステアリン酸エステルの量を0.50重量部に変更し、水量を調整した以外は、製造例A2と同様にして水中油型乳化油脂組成物A9を得た。
(Production Example A9) Preparation of oil-in-water emulsified oil composition A9 Oil-in-water emulsified oil composition A9 was prepared in the same manner as in Production Example A2, except that the amount of emulsifier A (polyglycerol stearate) was changed to 0.50 parts by weight and the amount of water was adjusted according to Table 3.
(製造例A10)水中油型乳化油脂組成物A10の作製
表3に従って、乳化剤Aとしてポリグリセリンステアリン酸エステル:0.15重量部に加えてショ糖ステアリン酸エステル:0.08重量部を添加し、水量を調整した以外は、製造例A2と同様にして水中油型乳化油脂組成物A10を得た。
(Production Example A10) Preparation of oil-in-water emulsified oil composition A10 According to Table 3, an oil-in-water emulsified oil composition A10 was prepared in the same manner as in Production Example A2, except that 0.15 parts by weight of polyglycerol stearate was added as emulsifier A, and 0.08 parts by weight of sucrose stearate was added, and the amount of water was adjusted.
(製造例A11)水中油型乳化油脂組成物A11の作製
表3に従って、乳化剤Aとしてポリグリセリンステアリン酸エステル:0.15重量部に加えてショ糖ステアリン酸エステル:0.15重量部を添加し、水量を調整した以外は、製造例A2と同様にして水中油型乳化油脂組成物A11を得た。
(Production Example A11) Preparation of oil-in-water emulsified oil composition A11 According to Table 3, an oil-in-water emulsified oil composition A11 was prepared in the same manner as in Production Example A2, except that 0.15 parts by weight of polyglycerol stearate was added as emulsifier A, and 0.15 parts by weight of sucrose stearate was added, and the amount of water was adjusted.
(製造例A12)水中油型乳化油脂組成物A12の作製
表3に従って、乳化剤Aとしてポリグリセリンステアリン酸エステル:0.15重量部に加えてショ糖ステアリン酸エステル:0.50重量部を添加し、水量を調整した以外は、製造例A2と同様にして水中油型乳化油脂組成物A12を得た。
(Production Example A12) Preparation of oil-in-water emulsified oil composition A12 According to Table 3, an oil-in-water emulsified oil composition A12 was prepared in the same manner as in Production Example A2, except that 0.15 parts by weight of polyglycerol stearate was added as emulsifier A, and 0.50 parts by weight of sucrose stearate was added, and the amount of water was adjusted.
(製造例B4)水中油型乳化油脂組成物B4の作製
表3に従って、乳化剤Aであるポリグリセリンステアリン酸エステルの量を0.03重量部に変更し、水量を調整した以外は、製造例A2と同様にして水中油型乳化油脂組成物B4を得た。
(Production Example B4) Preparation of oil-in-water emulsified oil composition B4 According to Table 3, the amount of emulsifier A (polyglycerol stearate) was changed to 0.03 parts by weight, and the amount of water was adjusted to obtain oil-in-water emulsified oil composition B4 in the same manner as in Production Example A2.
(製造例B5)水中油型乳化油脂組成物B5の作製
表3に従って、乳化剤Aであるポリグリセリンステアリン酸エステルの量を0.60重量部に変更し、水量を調整した以外は、製造例A2と同様にして水中油型乳化油脂組成物B5を得た。
(Production Example B5) Preparation of oil-in-water emulsified oil composition B5 According to Table 3, the amount of emulsifier A (polyglycerol stearate) was changed to 0.60 parts by weight, and the amount of water was adjusted to obtain oil-in-water emulsified oil composition B5 in the same manner as in Production Example A2.
(製造例B6)水中油型乳化油脂組成物B6の作製
表3に従って、乳化剤Aを水相に添加せずに、油相に添加した以外は、製造例A2と同様にして水中油型乳化油脂組成物B6を得た。
(Production Example B6) Preparation of oil-in-water emulsified oil composition B6 According to Table 3, an oil-in-water emulsified oil composition B6 was obtained in the same manner as in Production Example A2, except that emulsifier A was added to the oil phase rather than to the aqueous phase.
(実施例7)起泡性コンパウンドクリームA7及びホイップドコンパウンドクリームA7
製造例A7で得られた水中油型乳化油脂組成物A7と生クリーム(乳脂肪分:43%)とを重量比82:18で混合することで起泡性コンパウンドクリームA7を得た。得られた起泡性コンパウンドクリームA7をカントーミキサー(関東混合機工業(株)製「CS型20」)に4kg入れ、品温を5℃に調整し、グラニュー糖320gを入れ、高速撹拌条件(380rpm)で硬さが0.30Nになるまでホイップし、ホイップドコンパウンドクリームA7を得た。得られた起泡性コンパウンドクリームA7とホイップドコンパウンドクリームA7の評価(原液安定性、ホイップ性(オーバーラン、ホイップタイム)、硬さ、口溶け(早さ、自然さ))を行い、それらの結果を表4にまとめた。
(Example 7) Foaming Compound Cream A7 and Whipped Compound Cream A7
The oil-in-water emulsified oil composition A7 obtained in Production Example A7 was mixed with fresh cream (milk fat content: 43%) in a weight ratio of 82:18 to obtain a foaming compound cream A7. 4 kg of the obtained foaming compound cream A7 was placed in a Kanto mixer (Kanto Mixing Machinery Co., Ltd. "CS type 20"), the product temperature was adjusted to 5°C, 320 g of granulated sugar was added, and the mixture was whipped under high-speed stirring conditions (380 rpm) until the hardness reached 0.30 N to obtain a whipped compound cream A7. The obtained foaming compound cream A7 and the whipped compound cream A7 were evaluated (stability of the original solution, whipping properties (overrun, whipping time), hardness, and melting in the mouth (fastness, naturalness)), and the results are summarized in Table 4.
(実施例8~12)起泡性コンパウンドクリームA8~A12及びホイップドコンパウンドクリームA8~A12
水中油型乳化油脂組成物A7を、水中油型乳化油脂組成物A8~A12に変えた以外は、実施例7と同様にして起泡性コンパウンドクリームA8~A12及びホイップドコンパウンドクリームA8~A12を得た。得られた起泡性コンパウンドクリームA8~A12とホイップドコンパウンドクリームA8~A12の評価(原液安定性、ホイップ性(オーバーラン、ホイップタイム)、硬さ、口溶け(早さ、自然さ))を行い、それらの結果を表4にまとめた。
(Examples 8 to 12) Foaming compound creams A8 to A12 and whipped compound creams A8 to A12
Foamable compound creams A8 to A12 and whipped compound creams A8 to A12 were obtained in the same manner as in Example 7, except that the oil-in-water emulsified oil composition A7 was replaced with oil-in-water emulsified oil compositions A8 to A12. The obtained foamable compound creams A8 to A12 and whipped compound creams A8 to A12 were evaluated (stock solution stability, whipping properties (overrun, whipping time), hardness, melting in the mouth (speed, naturalness)), and the results are summarized in Table 4.
(比較例4~6)起泡性コンパウンドクリームB4~B6及びホイップドコンパウンドクリームB4~B6
水中油型乳化油脂組成物A7を、水中油型乳化油脂組成物B4~B6に変えた以外は、実施例7と同様にして起泡性コンパウンドクリームB4~B6及びホイップドコンパウンドクリームB4~B6を得た。得られた起泡性コンパウンドクリームB4~B6とホイップドコンパウンドクリームB4~B6の評価(原液安定性、ホイップ性(オーバーラン、ホイップタイム)、硬さ、口溶け(早さ、自然さ))を行い、それらの結果を表4にまとめた。
(Comparative Examples 4 to 6) Foaming Compound Creams B4 to B6 and Whipped Compound Creams B4 to B6
Except for changing the oil-in-water emulsified oil composition A7 to oil-in-water emulsified oil compositions B4 to B6, foamable compound creams B4 to B6 and whipped compound creams B4 to B6 were obtained in the same manner as in Example 7. The obtained foamable compound creams B4 to B6 and whipped compound creams B4 to B6 were evaluated (stability of original solution, whipping properties (overrun, whipping time), hardness, melting in the mouth (speed, naturalness)), and the results are summarized in Table 4.
表4にまとめた結果より、以下のことがわかった。実施例7~12及び比較例4~5より、本発明の効果を奏するには、乳化剤Aの含有量は起泡性コンパウンドクリーム全体中0.05~0.55重量%が好適であり、前記範囲を外れるとホイップ性が悪くなったり、ホイップ後の硬さが損なわれる場合があることが明らかとなった。また、実施例7及び比較例6より、本発明の効果を奏するには前記乳化剤Aを水相に配合することが好適であり、水相に配合せず油相に配合すると、ホイップ性が悪くなったり、ホイップ後の硬さが損なわれる場合があることが明らかとなった。 The results summarized in Table 4 reveal the following. From Examples 7 to 12 and Comparative Examples 4 and 5, it became clear that in order to achieve the effects of the present invention, the content of emulsifier A is preferably 0.05 to 0.55% by weight of the entire foaming compound cream, and that if it is outside this range, the whipping properties may deteriorate and the hardness after whipping may be impaired. Furthermore, from Example 7 and Comparative Example 6, it became clear that in order to achieve the effects of the present invention, it is preferable to incorporate emulsifier A into the aqueous phase, and that if it is incorporated into the oil phase rather than the aqueous phase, the whipping properties may deteriorate and the hardness after whipping may be impaired.
(製造例A13)水中油型乳化油脂組成物A13の作製
表5に従って、製造例A2,製造例A7と全く同様にして、水中油型乳化油脂組成物A2と全く同じ水中油型乳化油脂組成物A13を作製した。
(Production Example A13) Preparation of oil-in-water emulsified oil composition A13 According to Table 5, an oil-in-water emulsified oil composition A13 identical to the oil-in-water emulsified oil composition A2 was prepared in the same manner as in Production Examples A2 and A7.
(製造例A14)水中油型乳化油脂組成物A14の作製
表5に従って、乳化剤Aとしては、ポリグリセリンステアリン酸エステル(HLB:4.6):0.15重量部をショ糖ステアリン酸エステル(HLB:3.0):0.15重量部に変更した以外は、製造例A2と同様にして水中油型乳化油脂組成物A14を得た。
(Production Example A14) Preparation of oil-in-water emulsified oil composition A14 According to Table 5, the procedure was the same as in Production Example A2, except that as emulsifier A, 0.15 parts by weight of polyglycerol stearate (HLB: 4.6) was changed to 0.15 parts by weight of sucrose stearate (HLB: 3.0).
(製造例A15)水中油型乳化油脂組成物A15の作製
表5に従って、乳化剤Aとしては、ポリグリセリンステアリン酸エステル(HLB:4.6):0.15重量部をショ糖ステアリン酸エステル(HLB:5.0):0.15重量部に変更した以外は、製造例A2と同様にして水中油型乳化油脂組成物A15を得た。
(Production Example A15) Preparation of oil-in-water emulsified oil composition A15 According to Table 5, an oil-in-water emulsified oil composition A15 was prepared in the same manner as in Production Example A2, except that as emulsifier A, 0.15 parts by weight of polyglycerol stearate (HLB: 4.6) was replaced with 0.15 parts by weight of sucrose stearate (HLB: 5.0).
(製造例B7)水中油型乳化油脂組成物B7の作製
表5に従って、乳化剤Aであるポリグリセリンステアリン酸エステル(HLB:4.6):0.15重量部の代わりに、乳化剤Aに該当しないポリグリセリンステアリン酸エステル(HLB:2.6):0.15重量部を用いた以外は、製造例A2と同様にして水中油型乳化油脂組成物B7を得た。
(Production Example B7) Preparation of oil-in-water emulsified oil composition B7 According to Table 5, an oil-in-water emulsified oil composition B7 was prepared in the same manner as in Production Example A2, except that 0.15 parts by weight of polyglycerol stearate (HLB: 2.6), which does not fall under emulsifier A, was used in place of 0.15 parts by weight of polyglycerol stearate (HLB: 4.6), which is emulsifier A.
(製造例B8)水中油型乳化油脂組成物B8の作製
表5に従って、乳化剤Aであるポリグリセリン脂ステアリン酸エステル(HLB:4.6):0.15重量部の代わりに、乳化剤Aに該当しないポリグリセリンステアリン酸エステル(HLB:6.5):0.15重量部を用いた以外は、製造例A2と同様にして水中油型乳化油脂組成物B8を得た。
(Production Example B8) Preparation of oil-in-water emulsified oil composition B8 According to Table 5, an oil-in-water emulsified oil composition B8 was prepared in the same manner as in Production Example A2, except that 0.15 parts by weight of polyglycerol stearate (HLB: 6.5), which does not fall under emulsifier A, was used in place of 0.15 parts by weight of polyglycerol stearate (HLB: 4.6), which is emulsifier A.
(製造例B9)水中油型乳化油脂組成物B9の作製
表5に従って、乳化剤Aであるポリグリセリンステアリン酸エステル(HLB:4.6):0.15重量部の代わりに、乳化剤Aに該当しないショ糖ステアリン酸エステル(HLB:7.0):0.15重量部を用いた以外は、製造例A2と同様にして水中油型乳化油脂組成物B9を得た。
(Production Example B9) Preparation of oil-in-water emulsified oil composition B9 According to Table 5, an oil-in-water emulsified oil composition B9 was prepared in the same manner as in Production Example A2, except that 0.15 parts by weight of sucrose stearate (HLB: 7.0), which does not fall under emulsifier A, was used instead of 0.15 parts by weight of polyglycerol stearate (HLB: 4.6), which is emulsifier A.
(製造例B10)水中油型乳化油脂組成物B10の作製
表5に従って、乳化剤Aであるポリグリセリンステアリン酸エステル(HLB:4.6):0.15重量部の代わりに、乳化剤Aに該当しない、飽和脂肪酸量が少なく不飽和脂肪酸量が多いポリグリセリンオレイン酸エステル(HLB:11.6、C10~C22の飽和脂肪酸:29.81重量%、不飽和脂肪酸:70重量%):0.04重量部を用い、水量を調整した以外は、製造例A2と同様にして水中油型乳化油脂組成物B10を得た。
(Production Example B10) Preparation of oil-in-water emulsified oil composition B10 According to Table 5, oil-in-water emulsified oil composition B10 was prepared in the same manner as in Production Example A2, except that 0.04 parts by weight of a polyglycerol oleate ester (HLB: 11.6, C10 - C22 saturated fatty acids: 29.81 wt%, unsaturated fatty acids: 70 wt%) not corresponding to emulsifier A and having a low amount of saturated fatty acids and a high amount of unsaturated fatty acids was used in place of 0.15 parts by weight of polyglycerol stearate ester (HLB: 4.6), which is emulsifier A, and the amount of water was adjusted.
(実施例13)起泡性コンパウンドクリームA13及びホイップドコンパウンドクリームA13
製造例A13で得られた水中油型乳化油脂組成物A13と生クリーム(乳脂肪分:43%)とを重量比90:10で混合することで起泡性コンパウンドクリームA13を得た。得られた起泡性コンパウンドクリームA13をカントーミキサー(関東混合機工業(株)製「CS型20」)に4kg入れ、品温を5℃に調整し、グラニュー糖320gを入れ、高速撹拌条件(380rpm)で硬さが0.30Nになるまでホイップし、ホイップドコンパウンドクリームA13を得た。得られた起泡性コンパウンドクリームA13とホイップドコンパウンドクリームA13の評価(原液安定性、ホイップ性(オーバーラン、ホイップタイム)、硬さ、口溶け(早さ、自然さ))を行い、それらの結果を表6にまとめた。
(Example 13) Foaming Compound Cream A13 and Whipped Compound Cream A13
The oil-in-water emulsified oil composition A13 obtained in Production Example A13 was mixed with fresh cream (milk fat content: 43%) in a weight ratio of 90:10 to obtain a foaming compound cream A13. 4 kg of the obtained foaming compound cream A13 was placed in a Kanto mixer (Kanto Mixing Machinery Co., Ltd. "CS type 20"), the product temperature was adjusted to 5 ° C., 320 g of granulated sugar was added, and the mixture was whipped under high-speed stirring conditions (380 rpm) until the hardness reached 0.30 N to obtain a whipped compound cream A13. The obtained foaming compound cream A13 and the whipped compound cream A13 were evaluated (stability of the original solution, whipping properties (overrun, whipping time), hardness, and melting in the mouth (fastness, naturalness)), and the results are summarized in Table 6.
(実施例14,15)起泡性コンパウンドクリームA14~A15及びホイップドコンパウンドクリームA14~A15
水中油型乳化油脂組成物A13を、水中油型乳化油脂組成物A14~A15に変えた以外は、実施例13と同様にして起泡性コンパウンドクリームA14~A15及びホイップドコンパウンドクリームA14~A15を得た。得られた起泡性コンパウンドクリームA14~A15とホイップドコンパウンドクリームA14~A15の評価(原液安定性、ホイップ性(オーバーラン、ホイップタイム)、硬さ、口溶け(早さ、自然さ))を行い、それらの結果を表6にまとめた。
(Examples 14 and 15) Foaming compound creams A14 to A15 and whipped compound creams A14 to A15
Foamable compound creams A14 to A15 and whipped compound creams A14 to A15 were obtained in the same manner as in Example 13, except that oil-in-water emulsified oil composition A13 was changed to oil-in-water emulsified oil compositions A14 to A15. The obtained foamable compound creams A14 to A15 and whipped compound creams A14 to A15 were evaluated (stock solution stability, whipping properties (overrun, whipping time), hardness, melting in the mouth (speed, naturalness)), and the results are summarized in Table 6.
(比較例7~10)起泡性コンパウンドクリームB7~B10及びホイップドコンパウンドクリームB7~B10
水中油型乳化油脂組成物A13を、水中油型乳化油脂組成物B7~B10に変えた以外は、実施例13と同様にして起泡性コンパウンドクリームB7~B10及びホイップドコンパウンドクリームB7~B10を得た。得られた起泡性コンパウンドクリームB7~B10とホイップドコンパウンドクリームB7~B10の評価(原液安定性、ホイップ性(オーバーラン、ホイップタイム)、硬さ、口溶け(早さ、自然さ))を行い、それらの結果を表6にまとめた。
(Comparative Examples 7 to 10) Foaming Compound Creams B7 to B10 and Whipped Compound Creams B7 to B10
Foamable compound creams B7 to B10 and whipped compound creams B7 to B10 were obtained in the same manner as in Example 13, except that oil-in-water emulsified oil composition A13 was replaced with oil-in-water emulsified oil compositions B7 to B10. The obtained foamable compound creams B7 to B10 and whipped compound creams B7 to B10 were evaluated (stock solution stability, whipping properties (overrun, whipping time), hardness, melting in the mouth (speed, naturalness)), and the results are summarized in Table 6.
表6にまとめた結果より、以下のことがわかった。実施例13~15及び比較例7~9より、本発明の効果を奏するには、乳化剤AのHLBは2.8~6.2が好適であり、前記範囲を外れると、原液安定性やホイップ性が悪くなったり、ホイップ後の硬さが損なわれる場合があることが明らかとなった。また、実施例13及び比較例10より、乳化剤Aを配合せずに、不飽和脂肪酸量の多い乳化剤を配合すると、口溶けの早さが損なわれる上に異味を呈するため、風味を良くする観点では、起泡性コンパウンドクリーム全体中の、不飽和脂肪酸量の多い乳化剤の含有量は0.02重量%未満が好ましいことが明らかとなった。 From the results summarized in Table 6, the following was found. From Examples 13 to 15 and Comparative Examples 7 to 9, it was revealed that in order to achieve the effects of the present invention, the HLB of emulsifier A is preferably 2.8 to 6.2, and that if it is outside this range, the stability of the concentrate and whipping properties may deteriorate, and the hardness after whipping may be impaired. Furthermore, from Example 13 and Comparative Example 10, it was revealed that if an emulsifier with a high amount of unsaturated fatty acids is added without adding emulsifier A, the quick melting in the mouth is impaired and an unpleasant taste is exhibited, so from the perspective of improving the flavor, it is preferable that the content of the emulsifier with a high amount of unsaturated fatty acids in the entire foaming compound cream is less than 0.02% by weight.
更に、表4及び表6にまとめた結果より、以下のことがわかった。実施例7~15より、HLBが2.8~6.2であり、且つC10~C22の飽和脂肪酸を構成脂肪酸全体中70~100重量%含む乳化剤は、ポリグリセリン脂肪酸エステルとショ糖脂肪酸エステルのいずれであっても、また、両者を併用しても、本発明の効果を奏することが明らかとなった。 Furthermore, the results summarized in Tables 4 and 6 reveal the following: From Examples 7 to 15, it becomes clear that the emulsifier having an HLB of 2.8 to 6.2 and containing 70 to 100% by weight of C10 to C22 saturated fatty acids in the total constituent fatty acids can exhibit the effects of the present invention whether it is a polyglycerol fatty acid ester or a sucrose fatty acid ester, or both are used in combination.
(製造例A16)水中油型乳化油脂組成物A16の作製
表7に従って、パーム核油の含有量を10.5重量部に変更し、パーム核硬化油:0.6重量部を添加した以外は、製造例A2と同様にして水中油型乳化油脂組成物A16を得た。
(Production Example A16) Preparation of oil-in-water emulsified oil composition A16 According to Table 7, the oil-in-water emulsified oil composition A16 was prepared in the same manner as in Production Example A2, except that the content of palm kernel oil was changed to 10.5 parts by weight and 0.6 parts by weight of hardened palm kernel oil was added.
(製造例A17)水中油型乳化油脂組成物A17の作製
表7に従って、パーム核油の含有量を1.3重量部に変更し、パーム核オレイン:9.8重量部を添加した以外は、製造例A2と同様にして水中油型乳化油脂組成物A17を得た。
(Production Example A17) Preparation of oil-in-water emulsified oil composition A17 According to Table 7, the oil-in-water emulsified oil composition A17 was prepared in the same manner as in Production Example A2, except that the content of palm kernel oil was changed to 1.3 parts by weight and 9.8 parts by weight of palm kernel olein was added.
(製造例A18)水中油型乳化油脂組成物A18の作製
表7に従って、パーム油中融点部の含有量を8.6重量部に変更し、パームオレインの含有量を17.3重量部に変更した以外は、製造例A2と同様にして水中油型乳化油脂組成物A18を得た。
(Production Example A18) Preparation of oil-in-water emulsified oil composition A18 According to Table 7, the oil-in-water emulsified oil composition A18 was obtained in the same manner as in Production Example A2, except that the content of palm oil mid fraction was changed to 8.6 parts by weight and the content of palm olein was changed to 17.3 parts by weight.
(製造例A19)水中油型乳化油脂組成物A19の作製
表7に従って、パームオレインの含有量を11.8重量部に変更し、パーム油中融点部の種類を変えて且つ添加量を14.1重量部に変更した以外は、製造例A2と同様にして水中油型乳化油脂組成物A19を得た。
(Production Example A19) Preparation of oil-in-water emulsified oil composition A19 According to Table 7, the content of palm olein was changed to 11.8 parts by weight, the type of palm oil mid fraction was changed, and the added amount was changed to 14.1 parts by weight, and the same procedure as in Production Example A2 was repeated to prepare oil-in-water emulsified oil composition A19.
(製造例A20)水中油型乳化油脂組成物A20の作製
表7に従って、パーム核油の含有量を11.6重量部に変更し、パーム油中融点部の含有量を16.5重量部に変更し、パームオレインの含有量を10.4重量部に変更し、ポリグリセリン混酸エステル及び乳糖を配合せず、水量を調整した以外は、製造例A2と同様にして水中油型乳化油脂組成物A20を得た。
(Production Example A20) Preparation of oil-in-water emulsified oil composition A20 According to Table 7, the palm kernel oil content was changed to 11.6 parts by weight, the palm oil mid fraction content was changed to 16.5 parts by weight, the palm olein content was changed to 10.4 parts by weight, the polyglycerol mixed acid ester and lactose were not blended, and the amount of water was adjusted, and other than that, an oil-in-water emulsified oil composition A20 was obtained in the same manner as in Production Example A2.
(製造例B11)水中油型乳化油脂組成物B11の作製
表7に従って、パーム核油の含有量を10.9重量部に変更し、パーム油中融点部の含有量を15.6重量部に変更し、パームオレインの含有量を9.9重量部に変更し、パームエステル交換油:0.6重量部を添加した以外は、製造例A2と同様にして水中油型乳化油脂組成物B11を得た。
(Production Example B11) Preparation of oil-in-water emulsified oil composition B11 According to Table 7, the palm kernel oil content was changed to 10.9 parts by weight, the palm oil mid fraction content was changed to 15.6 parts by weight, the palm olein content was changed to 9.9 parts by weight, and 0.6 parts by weight of palm interesterified oil was added. Except for this, an oil-in-water emulsified oil composition B11 was obtained in the same manner as in Production Example A2.
(製造例B12)水中油型乳化油脂組成物B12の作製
表7に従って、パーム核油の含有量を8.0重量部に変更し、パーム核硬化油:3.1重量部を添加した以外は、製造例A2と同様にして水中油型乳化油脂組成物B12を得た。
(Production Example B12) Preparation of oil-in-water emulsified oil composition B12 According to Table 7, the oil-in-water emulsified oil composition B12 was prepared in the same manner as in Production Example A2, except that the content of palm kernel oil was changed to 8.0 parts by weight and 3.1 parts by weight of hardened palm kernel oil was added.
(製造例B13)水中油型乳化油脂組成物B13の作製
表7に従って、パームオレインを添加せず、パーム油中融点部(上昇融点:26.8℃)の含有量を1.9重量部に変更し、さらに、上昇融点が異なるパーム油中融点部(上昇融点:31.3℃):24.0重量部を添加した以外は、製造例A2と同様にして水中油型乳化油脂組成物B13を得た。
(Production Example B13) Preparation of oil-in-water emulsified oil composition B13 According to Table 7, oil-in-water emulsified oil composition B13 was obtained in the same manner as in Production Example A2, except that palm olein was not added, the content of palm oil mid fraction (ascent melting point: 26.8° C.) was changed to 1.9 parts by weight, and 24.0 parts by weight of palm oil mid fraction (ascent melting point: 31.3° C.) with a different ascent melting point was added.
(実施例16)起泡性コンパウンドクリームA16及びホイップドコンパウンドクリームA16
製造例A16で得られた水中油型乳化油脂組成物A16と生クリーム(乳脂肪分:43%)とを重量比90:10で混合することで起泡性コンパウンドクリームA16を得た。得られた起泡性コンパウンドクリームA16をカントーミキサー(関東混合機工業(株)製「CS型20」)に4kg入れ、品温を5℃に調整し、グラニュー糖320gを入れ、高速撹拌条件(380rpm)で硬さが0.30Nになるまでホイップし、ホイップドコンパウンドクリームA16を得た。得られた起泡性コンパウンドクリームA16とホイップドコンパウンドクリームA16の評価(原液安定性、ホイップ性(オーバーラン、ホイップタイム)、硬さ、口溶け(早さ、自然さ))を行い、それらの結果を表8にまとめた。
(Example 16) Foaming compound cream A16 and whipped compound cream A16
The oil-in-water emulsified oil composition A16 obtained in Production Example A16 was mixed with fresh cream (milk fat content: 43%) in a weight ratio of 90:10 to obtain a foamable compound cream A16. 4 kg of the obtained foamable compound cream A16 was placed in a Kanto mixer (Kanto Mixing Machinery Co., Ltd. "CS type 20"), the product temperature was adjusted to 5 ° C., 320 g of granulated sugar was added, and the mixture was whipped under high-speed stirring conditions (380 rpm) until the hardness reached 0.30 N to obtain a whipped compound cream A16. The obtained foamable compound cream A16 and the whipped compound cream A16 were evaluated (stability of the original solution, whipping properties (overrun, whipping time), hardness, and melting in the mouth (fastness, naturalness)), and the results are summarized in Table 8.
(実施例17~19)起泡性コンパウンドクリームA17~A19及びホイップドコンパウンドクリームA17~A19
水中油型乳化油脂組成物A16を、水中油型乳化油脂組成物A17~A19に変えた以外は、実施例16と同様にして起泡性コンパウンドクリームA17~A19及びホイップドコンパウンドクリームA17~A19を得た。得られた起泡性コンパウンドクリームA17~A19とホイップドコンパウンドクリームA17~A19の評価(原液安定性、ホイップ性(オーバーラン、ホイップタイム)、硬さ、口溶け(早さ、自然さ))を行い、それらの結果を表8にまとめた。
(Examples 17 to 19) Foaming compound creams A17 to A19 and whipped compound creams A17 to A19
Foamable compound creams A17 to A19 and whipped compound creams A17 to A19 were obtained in the same manner as in Example 16, except that oil-in-water emulsified oil composition A16 was replaced with oil-in-water emulsified oil compositions A17 to A19. The obtained foamable compound creams A17 to A19 and whipped compound creams A17 to A19 were evaluated (stock solution stability, whipping properties (overrun, whipping time), hardness, melting in the mouth (speed, naturalness)), and the results are summarized in Table 8.
(比較例11~13)起泡性コンパウンドクリームB11~B13及びホイップドコンパウンドクリームB11~B13
水中油型乳化油脂組成物A16を、水中油型乳化油脂組成物B11~B13に変えた以外は、実施例16と同様にして起泡性コンパウンドクリームB11~B13及びホイップドコンパウンドクリームB11~B13を得た。得られた起泡性コンパウンドクリームB11~B13とホイップドコンパウンドクリームB11~B13の評価(原液安定性、ホイップ性(オーバーラン、ホイップタイム)、硬さ、口溶け(早さ、自然さ))を行い、それらの結果を表8にまとめた。
(Comparative Examples 11 to 13) Foaming Compound Creams B11 to B13 and Whipped Compound Creams B11 to B13
Except for changing the oil-in-water emulsified oil composition A16 to oil-in-water emulsified oil compositions B11 to B13, foamable compound creams B11 to B13 and whipped compound creams B11 to B13 were obtained in the same manner as in Example 16. The obtained foamable compound creams B11 to B13 and whipped compound creams B11 to B13 were evaluated (stock solution stability, whipping properties (overrun, whipping time), hardness, melting in the mouth (speed, naturalness)), and the results are summarized in Table 8.
表8にまとめた結果より、以下のことがわかった。実施例13及び比較例11より、本発明の効果を奏するには油脂全体中のエステル交換油の含有量は1重量%未満が好適であり、1重量%以上では、ホイップ性が悪化したり、ホイップ後の硬さや口溶けの自然さが損なわれる場合があることが明らかとなった。また、実施例13、16~17及び比較例12より、本発明の効果を奏するには、C12以下の飽和脂肪酸を構成脂肪酸全体中40重量%以上含む油脂Aの上昇融点は23~30℃が好適であり、前記範囲を外れると、原液安定性、ホイップ性、及びホイップ後の硬さが悪くなったり、口溶けが遅くなる場合があることが明らかとなった。実施例13、18~19及び比較例13より、本発明の効果を奏するには、C16~C22の飽和脂肪酸を構成脂肪酸全体中40重量%以上含む油脂B全体中のS2U含有量は45~70重量%、油脂Bの上昇融点は23~30℃を満たすことが好適であり、前記範囲を外れると、原液安定性、ホイップ性、及びホイップ後の硬さが悪くなったり、口溶けが遅くなる場合があることが明らかとなった。 From the results summarized in Table 8, the following was found. From Example 13 and Comparative Example 11, it was revealed that in order to achieve the effects of the present invention, the content of interesterified oil in the entire fat and oil is preferably less than 1% by weight, and if it is 1% by weight or more, the whipping property may deteriorate, and the hardness after whipping and the naturalness of melting in the mouth may be impaired. Furthermore, from Examples 13, 16 to 17 and Comparative Example 12, it was revealed that in order to achieve the effects of the present invention, the slip melting point of fat and oil A containing 40% by weight or more of saturated fatty acids of C12 or less in the entire constituent fatty acids is preferably 23 to 30°C, and if it is outside the above range, the stock solution stability, whipping property, and hardness after whipping may deteriorate, and melting in the mouth may be delayed. From Examples 13, 18 to 19 and Comparative Example 13, it was revealed that in order to achieve the effects of the present invention, it is preferable that the S2U content in the entire fat B, which contains 40% by weight or more of C16 to C22 saturated fatty acids based on the total constituent fatty acids, is 45 to 70% by weight, and that the slip melting point of fat B is 23 to 30°C. If the above ranges are not met, the stability of the concentrate, whipping properties, and hardness after whipping may be deteriorated, and melting in the mouth may be delayed.
(比較例14,15)起泡性コンパウンドクリームB14~15及びホイップドコンパウンドクリームB14~15
水中油型乳化油脂組成物A2と生クリーム(乳脂肪分:43%)の配合比を、97.8:2.2(比較例14)、又は78.0:22.0(比較例15)に変えた以外は、実施例2と同様にして起泡性コンパウンドクリームB14~B15及びホイップドコンパウンドクリームB14~B15を得た。得られた起泡性コンパウンドクリームB14~B15とホイップドコンパウンドクリームB14~B15の評価(原液安定性、ホイップ性(オーバーラン、ホイップタイム)、硬さ、口溶け(早さ、自然さ))を行い、それらの結果を表9にまとめた。
(Comparative Examples 14 and 15) Foaming Compound Cream B14 to 15 and Whipped Compound Cream B14 to 15
Except for changing the blending ratio of the oil-in-water emulsified oil composition A2 to fresh cream (milk fat content: 43%) to 97.8:2.2 (Comparative Example 14) or 78.0:22.0 (Comparative Example 15), foamable compound creams B14 to B15 and whipped compound creams B14 to B15 were obtained in the same manner as in Example 2. The obtained foamable compound creams B14 to B15 and whipped compound creams B14 to B15 were evaluated (stability of the original solution, whipping properties (overrun, whipping time), hardness, melting in the mouth (speed, naturalness)), and the results are summarized in Table 9.
(実施例20)起泡性コンパウドクリームA20及びホイップドコンパウンドクリームA20
水中油型乳化油脂組成物A2の代わりに水中油型乳化油脂組成物A20を用い、生クリーム(乳脂肪分:43重量%)の配合比を90:10に変えた以外は、実施例2と同様にして起泡性コンパウンドクリームA20及びホイップドコンパウンドクリームA20を得た。得られた起泡性コンパウンドクリームA20とホイップドコンパウンドクリームA20の評価(原液安定性、ホイップ性(オーバーラン、ホイップタイム)、硬さ、口溶け(早さ、自然さ))を評価し、それらの結果を表9にまとめた。
(Example 20) Foaming compound cream A20 and whipped compound cream A20
Except for using oil-in-water emulsified oil composition A20 instead of oil-in-water emulsified oil composition A2 and changing the blending ratio of fresh cream (milk fat content: 43% by weight) to 90: 10, foamable compound cream A20 and whipped compound cream A20 were obtained in the same manner as in Example 2. The foamable compound cream A20 and whipped compound cream A20 obtained were evaluated (stability of original solution, whipping properties (overrun, whipping time), hardness, melting in the mouth (speed, naturalness)), and the results are summarized in Table 9.
表9にまとめた結果より、以下のことがわかった。実施例2、7、13、20及び比較例14~15より、本発明の効果を奏するには油脂全体中の乳脂肪含量が3.5重量%以上且つ22.5重量%未満が好適であり、前記範囲を下回るとホイップ性が悪化し、上回ると、原液安定性、及びホイップ性が悪化し、口溶けの早さが損なわれる場合があることが明らかとなった。
From the results summarized in Table 9, the following was found. From Examples 2, 7, 13, and 20 and Comparative Examples 14 to 15, it was revealed that in order to obtain the effects of the present invention, the milk fat content in the total oils and fats is preferably 3.5% by weight or more and less than 22.5% by weight, and if it is below this range, the whipping property deteriorates, and if it exceeds this range, the concentrate stability and whipping property deteriorate, and the quickness of melting in the mouth may be impaired.
「実施例1」の表記は実施例であるが、比較例の一つである。
(実施例1)起泡性コンパウンドクリームA1及びホイップドコンパウンドクリームA1
製造例1で得られた水中油型乳化油脂組成物A1と生クリーム(乳脂肪分:43%)とを重量比95:5で混合することで起泡性コンパウンドクリームA1を得た。得られた起泡性コンパウンドクリームA1をカントーミキサー(関東混合機工業(株)製「CS型20」)に4kg入れ、品温を5℃に調整し、グラニュー糖320gを入れ、高速撹拌条件(380rpm)で硬さが0.30Nになるまでホイップし、ホイップドコンパウンドクリームA1を得た。得られた起泡性コンパウンドクリームA1とホイップドコンパウンドクリームA1の評価(原液安定性、ホイップ性(オーバーラン、ホイップタイム)、硬さ、口溶け(早さ、自然さ))を行い、それらの結果を表2にまとめた。
Although the term "Example 1" refers to an example, it is one of the comparative examples.
(Example 1) Foaming compound cream A1 and whipped compound cream A1
The oil-in-water emulsified oil composition A1 obtained in Production Example 1 was mixed with fresh cream (milk fat content: 43%) in a weight ratio of 95:5 to obtain a foamable compound cream A1. 4 kg of the obtained foamable compound cream A1 was placed in a Kanto mixer (Kanto Mixing Machinery Co., Ltd. "CS type 20"), the product temperature was adjusted to 5°C, 320 g of granulated sugar was added, and the mixture was whipped under high-speed stirring conditions (380 rpm) until the hardness reached 0.30 N to obtain a whipped compound cream A1. The obtained foamable compound cream A1 and whipped compound cream A1 were evaluated (stability of the original solution, whipping properties (overrun, whipping time), hardness, and melting in the mouth (fastness, naturalness)), and the results are summarized in Table 2.
Claims (5)
起泡性コンパウンドクリームの水相中に乳化剤Aを、起泡性コンパウンドクリーム全体中0.05~0.55重量%含有し、
前記油脂全体中、エステル交換油脂含量が1重量%未満、乳脂肪含量が3.5重量%以上且つ22.5重量%未満であり、
前記油脂の内、前記乳脂肪を除く油脂全体中、油脂A及び油脂Bの合計含量が80~100重量%であり、油脂B/(油脂A+油脂B)(重量比)が0.45~0.82である、
起泡性コンパウンドクリーム。
油脂A:C12以下の飽和脂肪酸を構成脂肪酸全体中40重量%以上含み、S2Uを油脂A全体中0重量%以上40重量%未満含み、上昇融点(但し、複数種の油脂のブレンド物である場合、前記上昇融点は、当該複数種の油脂の上昇融点の平均値を指す)が23~30℃の油脂。
油脂B:C16~C22の飽和脂肪酸を構成脂肪酸全体中40重量%以上含み、S2Uを油脂B全体中45~70重量%含み、上昇融点が23~30℃の油脂。
乳化剤A:HLBが2.8~6.2であり、C10~C22の飽和脂肪酸を構成脂肪酸全体中70~100重量%含むショ糖脂肪酸エステル及び/又はポリグリセリン脂肪酸エステル。 The foaming compound cream has an oil content of 25 to 50% by weight and a phosphate content of less than 0.02% by weight.
The foaming compound cream contains an emulsifier A in an aqueous phase thereof in an amount of 0.05 to 0.55% by weight based on the total weight of the foaming compound cream,
In the total fats and oils, the interesterified fat content is less than 1% by weight, and the milk fat content is 3.5% by weight or more and less than 22.5% by weight,
Among the fats and oils, the total content of fats and oils A and B in the entire fats and oils excluding the milk fat is 80 to 100% by weight, and the weight ratio of fats and oils B/(fat and oil A + fat and oil B) is 0.45 to 0.82;
Foaming compound cream.
Oil and fat A: Oil and fat containing 40% by weight or more of saturated fatty acids of C12 or less in the total constituent fatty acids, containing 0% by weight or more and less than 40% by weight of S2U in the total oil and fat A, and having an ascending melting point (however, in the case of a blend of multiple types of oils and fats, the ascending melting point refers to the average value of the ascending melting points of the multiple types of oils and fats) of 23 to 30°C.
Fats and oils B: Fats and oils containing 40% by weight or more of C16 to C22 saturated fatty acids in the total constituent fatty acids, containing 45 to 70% by weight of S2U in the total constituent fatty acids B, and having an upward melting point of 23 to 30°C.
Emulsifier A: sucrose fatty acid ester and/or polyglycerin fatty acid ester having an HLB of 2.8 to 6.2 and containing 70 to 100% by weight of C 10 to C 22 saturated fatty acids based on the total amount of constituent fatty acids.
起泡性コンパウンドクリーム全体中、乳化剤A含量が0.05~0.55重量%となるように乳化剤Aを水に添加して撹拌しながら溶解した水相部に、前記油脂全体中、油脂Aと油脂Bの合計含量が62~96.5重量%且つ油脂B/(油脂A+油脂B)(重量比)が0.45~0.82となるように油脂A及び油脂Bを混合した油脂混合物を添加し、予備乳化した後、微細化し、さらに高圧処理して得た水中油型乳化油脂組成物に、前記油脂全体中の乳脂肪含量が3.5重量%以上且つ22.5重量%未満になるように生クリームを混合・撹拌することを特徴とする、起泡性コンパウンドクリームの製造方法。
油脂A:C12以下の飽和脂肪酸を構成脂肪酸全体中40重量%以上含み、S2Uを油脂A全体中0重量%以上40重量%未満含み、上昇融点(但し、複数種の油脂のブレンド物である場合、前記上昇融点は、当該複数種の油脂の上昇融点の平均値を指す)が23~30℃の油脂。
油脂B:C16~C22の飽和脂肪酸を構成脂肪酸全体中40重量%以上含み、S2Uを油脂B全体中45~70重量%含み、上昇融点が23~30℃の油脂。
乳化剤A:HLBが2.8~6.2であり、C10~C22の飽和脂肪酸を構成脂肪酸全体中70~100重量%含むショ糖脂肪酸エステル及び/又はポリグリセリン脂肪酸エステル。
A method for producing a foaming compound cream, the foaming compound cream having a fat content of 25 to 50% by weight, a phosphate content of less than 0.02% by weight, and an interesterified fat content of less than 1% by weight of the total fat content, comprising:
A method for producing a foamable compound cream, comprising adding emulsifier A to water so that the emulsifier A content in the entire foamable compound cream is 0.05 to 0.55% by weight, stirring to dissolve the emulsifier in the aqueous phase, adding an oil/fat mixture of oils A and B so that the total content of oils A and B in the entire fats and oils is 62 to 96.5% by weight and the weight ratio of oils B/(oils A + oils B) is 0.45 to 0.82, pre-emulsifying the mixture, pulverizing the mixture, and further treating the mixture under high pressure to obtain an oil-in-water emulsified oil/fat composition, and mixing and stirring fresh cream with the mixture so that the milk fat content in the entire fats and oils is 3.5% by weight or more and less than 22.5% by weight.
Oil and fat A: Oil and fat containing 40% by weight or more of saturated fatty acids of C12 or less in the total constituent fatty acids, containing 0% by weight or more and less than 40% by weight of S2U in the total oil and fat A, and having an ascending melting point (however, in the case of a blend of multiple types of oils and fats, the ascending melting point refers to the average value of the ascending melting points of the multiple types of oils and fats) of 23 to 30°C.
Fats and oils B: Fats and oils containing 40% by weight or more of C16 to C22 saturated fatty acids in the total constituent fatty acids, containing 45 to 70% by weight of S2U in the total constituent fatty acids B, and having an upward melting point of 23 to 30°C.
Emulsifier A: sucrose fatty acid ester and/or polyglycerin fatty acid ester having an HLB of 2.8 to 6.2 and containing 70 to 100% by weight of C 10 to C 22 saturated fatty acids based on the total amount of constituent fatty acids.
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