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JP5831213B2 - Secondary battery, vehicle - Google Patents

Secondary battery, vehicle Download PDF

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Publication number
JP5831213B2
JP5831213B2 JP2011284272A JP2011284272A JP5831213B2 JP 5831213 B2 JP5831213 B2 JP 5831213B2 JP 2011284272 A JP2011284272 A JP 2011284272A JP 2011284272 A JP2011284272 A JP 2011284272A JP 5831213 B2 JP5831213 B2 JP 5831213B2
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case
secondary battery
current collecting
electrode
main body
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JP2013134892A (en
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元章 奥田
元章 奥田
尚也 横町
尚也 横町
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Toyota Industries Corp
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Toyota Industries Corp
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

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  • Secondary Cells (AREA)
  • Sealing Battery Cases Or Jackets (AREA)
  • Cell Separators (AREA)
  • Connection Of Batteries Or Terminals (AREA)

Description

本発明は、二次電池、及び二次電池を搭載した車両に関する。   The present invention relates to a secondary battery and a vehicle equipped with the secondary battery.

従来から、二次電池としては、リチウムイオン二次電池やニッケル水素二次電池などが知られている。このような二次電池は、例えば絶縁性を有するセパレータを介在させた状態で電極シート(電極)を捲回して電極体(電極群)を形成し、この電極体をケースに収納した構成とされている。そして、二次電池では、電極体の電極シートと接合される集電部材を設けるとともに、この集電部材をケースから突出するように設けられる電極端子に対して電気的に接続している(例えば特許文献1)。   Conventionally, lithium ion secondary batteries and nickel metal hydride secondary batteries are known as secondary batteries. Such a secondary battery has, for example, a configuration in which an electrode body (electrode group) is formed by winding an electrode sheet (electrode) with an insulating separator interposed, and the electrode body is housed in a case. ing. And in a secondary battery, while providing the current collection member joined with the electrode sheet | seat of an electrode body, this current collection member is electrically connected with respect to the electrode terminal provided so that it may protrude from a case (for example, Patent Document 1).

特開2003−249423号公報JP 2003-249423 A

ところで、二次電池では、環境温度や充放電に伴う電極体の発熱に起因して、その性能が低下する可能性がある。このため、従来から二次電池では、ケースの外側に熱交換媒体(熱媒体)を流すことで温度調節を行い、このような性能低下を抑制することが行われている。特許文献1の二次電池では、集電部材が電極端子に接続されていることから、集電部材を介して電極体とケースとの間で熱交換が行われ得る。しかしながら、二次電池の性能低下を抑制する観点からは、電極体とケースとの熱交換の効率をさらに高め、温度調節を速やかに行うことが期待されていた。   By the way, in the secondary battery, the performance may be deteriorated due to the heat generation of the electrode body accompanying the environmental temperature or charging / discharging. For this reason, in a conventional secondary battery, temperature adjustment is performed by flowing a heat exchange medium (heat medium) outside the case, and such performance degradation is suppressed. In the secondary battery of Patent Document 1, since the current collecting member is connected to the electrode terminal, heat exchange can be performed between the electrode body and the case via the current collecting member. However, from the viewpoint of suppressing the performance deterioration of the secondary battery, it has been expected that the efficiency of heat exchange between the electrode body and the case is further increased and the temperature is adjusted quickly.

この発明は、上記従来技術に存在する問題点に着目してなされたものであり、その目的は、温度調節を好適に行うことができる二次電池、及び車両を提供することにある。   The present invention has been made paying attention to the problems existing in the prior art, and an object of the present invention is to provide a secondary battery and a vehicle capable of suitably adjusting the temperature.

上記課題を解決するために、請求項1に記載の発明は、セパレータを間に挟んだ状態で絶縁された正極シートと負極シートが層状構造をなした電極群をケースに収容してなる二次電池であって、平板部と、前記平板部と前記電極群とを接続する接続部とを有し、導電材よりなる集電部材を備え、前記平板部の一方の面は前記ケースの内面との間に絶縁材からなるシートを介した状態又は前記ケースの内面に形成された絶縁材からなる絶縁層を介した状態で前記ケースと熱的に連結し、他方の面には前記接続部が電気的及び熱的に連結しており、前記ケースは金属からなり、前記ケースは、底部及び前記底部の周囲より立設される壁部を有する有底筒状をなして前記電極群を収容する本体部材を含み、前記平板部における前記ケースの内面と合わさる面は、前記壁部の内面に合わさる状態で配置され、前記壁部の内面と合わさる面における前記本体部材の底部側には、前記本体部材の底部に向かって前記電極群側に傾斜するテーパ部が設けられていることを要旨とする。ここで「熱的に連結」とは、相互に熱交換が行われ得る状態を指すものとし、直接、連結されているか否かを問わないものとする。 In order to solve the above-mentioned problem, the invention according to claim 1 is a secondary battery comprising a case in which an electrode group in which a positive electrode sheet and a negative electrode sheet that are insulated with a separator sandwiched therebetween has a layered structure is housed in a case. a battery, comprising: a flat plate portion, a connecting portion for connecting the electrode group and said plate comprises a current collecting member made of a conductive material, one face of said plate inner surface of the front Symbol case Between the case and an insulating layer made of an insulating material formed on the inner surface of the case, and is connected to the case on the other surface. Are electrically and thermally connected , the case is made of metal, and the case has a bottomed cylindrical shape having a bottom portion and a wall portion erected from the periphery of the bottom portion, and accommodates the electrode group. A main body member that is aligned with the inner surface of the case in the flat plate portion. And a taper that is inclined toward the electrode group toward the bottom of the main body member on the bottom surface side of the main body member on the surface that meets the inner surface of the wall portion. The gist is that the section is provided . Here, “thermally connected” indicates a state in which heat exchange can be performed, and it does not matter whether or not they are directly connected.

これによれば、平板部の一方の面はケースの内面との間に絶縁材からなるシートを介した状態又はケースの内面に形成された絶縁材からなる絶縁層を介した状態でケースと熱的に連結し、他方の面には接続部が電気的及び熱的に連結している。このため、接続部が連結された他方の面で集電部材(平板部)をケースと熱的に連結させる構成と比較して、より広い面積で集電部材をケースと熱的に連結させることが可能となる。これにより、電極群とケースとの熱交換の効率を高め、温度調節を速やかに行うことができる。したがって、温度調節を好適に行うことができる。また、平板部は本体部材の壁部の内面に合わさる状態で配置され、さらに壁部の内面と合わさる面における本体部材の底部側には、本体部材の底部に向かって電極群側に傾斜するテーパ部が設けられている。このため、接続部と電極群とを接続させた状態で、電極群を集電部材とともに本体部材に収納する際、テーパ部によってガイドされることで、電極群の挿入性を向上させることができる。 According to this, the case in the state one surface of which an insulating layer made of an insulating material formed on the inner surface of the state or case through the sheet made of an insulating material between the inner surface of the to case flat portion And a connecting portion is electrically and thermally connected to the other surface. For this reason, compared with the structure which connects a current collection member (flat plate part) with a case thermally with the other surface where the connection part was connected, a current collection member is thermally connected with a case in a wider area. Is possible. Thereby, the efficiency of heat exchange with an electrode group and a case can be improved, and temperature control can be performed rapidly. Therefore, temperature adjustment can be suitably performed. Further, the flat plate portion is arranged in a state of being fitted to the inner surface of the wall portion of the main body member, and further, a taper that is inclined toward the electrode group side toward the bottom portion of the main body member on the bottom side of the main body member in the surface mating with the inner surface of the wall portion. Is provided. For this reason, when the electrode group is housed in the main body member together with the current collecting member in a state where the connection portion and the electrode group are connected, the insertion property of the electrode group can be improved by being guided by the tapered portion. .

請求項2に記載の発明は、請求項1に記載の二次電池において、前記平板部における前記ケースの内面と合わさる面と、前記ケースの内面との間には、絶縁材からなるシートが介在されていることを要旨とする。これによれば、集電部材とケースとの絶縁性を確保しつつ、電極群とケースとの熱交換の効率を高めることができる。   According to a second aspect of the present invention, in the secondary battery according to the first aspect, a sheet made of an insulating material is interposed between a surface of the flat plate portion that meets the inner surface of the case and an inner surface of the case. It is a summary. According to this, it is possible to increase the efficiency of heat exchange between the electrode group and the case while ensuring the insulation between the current collecting member and the case.

請求項に記載の発明は、車両において、請求項1または2に記載の二次電池を搭載したことを要旨とする。これによれば、二次電池として温度調節を好適に行うことができることから、環境温度や充放電に伴う電極体の発熱に起因する性能低下を抑制し、例えば二次電池の交換頻度が高くなったり、1回の満充電で利用可能な電力量が低下したりすることを抑制できる。 The gist of the invention described in claim 3 is that the secondary battery according to claim 1 or 2 is mounted in a vehicle. According to this, since temperature adjustment can be suitably performed as a secondary battery, performance degradation due to environmental temperature and heat generation of the electrode body due to charge / discharge is suppressed, and for example, the replacement frequency of the secondary battery is increased. Moreover, it can suppress that the electric energy which can be utilized by one full charge falls.

本発明によれば、温度調節を好適に行うことができる。   According to the present invention, temperature adjustment can be suitably performed.

リチウムイオン二次電池を模式的に示す部分断面図。The fragmentary sectional view which shows a lithium ion secondary battery typically. (a)は、リチウムイオン二次電池を模式的に示す左側面図、(b)は、(a)に示すA−A線部分拡大断面図。(A) is the left view which shows a lithium ion secondary battery typically, (b) is the AA line partial expanded sectional view shown to (a). 別の実施形態におけるリチウムイオン二次電池を模式的に示す部分拡大断面図。The partial expanded sectional view which shows typically the lithium ion secondary battery in another embodiment. (a)は、別の実施形態におけるリチウムイオン二次電池を模式的に示す断面図、(b)は、同じく左側面図。(A) is sectional drawing which shows typically the lithium ion secondary battery in another embodiment, (b) is a left view similarly.

以下、本発明を具体化した一実施形態を図1及び図2にしたがって説明する。
図1に示すように、リチウムイオン二次電池(以下、単に「二次電池」と示す)10は、全体として扁平な略立方体状をなすケース11を備えている。ケース11は、扁平な有底略四角筒状に形成された本体部材12、及び本体部材12の開口部を覆う(密閉する)ように、本体部材12に組み付けられる略矩形平板状をなす蓋部材13から形成されている。本体部材12、及び蓋部材13は、何れも金属(例えばステンレスやアルミニウムなど)から形成されている。以下、説明の便宜のため、図1で矢印Y1に示すケース11の長手方向を左右方向と示し、矢印Y2に示すケース11の高さ方向を上下方向と示す。また、図2(a)で矢印Y3に示すケース11の短手方向を前後方向と示す。
Hereinafter, an embodiment embodying the present invention will be described with reference to FIGS. 1 and 2.
As shown in FIG. 1, a lithium ion secondary battery (hereinafter simply referred to as “secondary battery”) 10 includes a case 11 having a flat, generally cubic shape as a whole. The case 11 includes a main body member 12 formed in a flat bottomed substantially square cylinder shape, and a lid member having a substantially rectangular flat plate shape that is assembled to the main body member 12 so as to cover (seal) the opening of the main body member 12. 13. The main body member 12 and the lid member 13 are both made of metal (for example, stainless steel or aluminum). Hereinafter, for convenience of explanation, the longitudinal direction of the case 11 indicated by the arrow Y1 in FIG. 1 is indicated as the left-right direction, and the height direction of the case 11 indicated by the arrow Y2 is indicated as the up-down direction. In addition, the short direction of the case 11 indicated by the arrow Y3 in FIG.

図1に示すように、蓋部材13には、蓋部材13の上面から略円柱状をなす正極端子15及び負極端子16が上方に向かって突出するように設けられている。また、蓋部材13の下面(内面)には、導電材(導電体)としての金属(本実施形態ではアルミニウム)からなり、正極端子15と電気的に接続された集電端子17の基端(一端)が固定されている。また、蓋部材13の下面(内面)には、導電材(導電体)としての金属(本実施形態では銅)からなり、負極端子16と電気的に接続された集電端子18の基端(一端)が固定されている。本実施形態では、集電端子17,18が集電部材となる。   As shown in FIG. 1, the lid member 13 is provided with a positive electrode terminal 15 and a negative electrode terminal 16 that are formed in a substantially columnar shape from the upper surface of the lid member 13 so as to protrude upward. Further, the lower surface (inner surface) of the lid member 13 is made of a metal (aluminum in the present embodiment) as a conductive material (conductor), and is connected to the positive terminal 15 at the base end ( One end) is fixed. Further, the lower surface (inner surface) of the lid member 13 is made of a metal (copper in the present embodiment) as a conductive material (conductor), and is connected to the negative terminal 16 at the base end ( One end) is fixed. In the present embodiment, the current collecting terminals 17 and 18 are current collecting members.

また、ケース11には、全体として左右方向(ケース11の長手方向)に沿って延びる扁平な形状に形成された電極群としての電極体23が、絶縁材(絶縁体)からなるシート(絶縁性フィルム)で形成された絶縁袋11aに包まれた状態で収納されている。なお、図1〜図4において、絶縁袋11aは、本体部材12より僅かに薄い程度の厚さで図示されているが、実際には本体部材12よりも遥かに薄くその厚さを無視(略無視)出来る程度に形成されている。   In addition, in the case 11, an electrode body 23 as an electrode group formed in a flat shape extending along the left-right direction (longitudinal direction of the case 11) as a whole is a sheet (insulating material) made of an insulating material (insulator). The film is stored in an insulating bag 11a formed of a film. 1 to 4, the insulating bag 11 a is shown to be slightly thinner than the main body member 12, but in fact, it is much thinner than the main body member 12 and ignores the thickness (substantially omitted). It is formed to the extent possible.

電極体23は、セパレータ(隔膜)27を間に介在させて、長尺の矩形シート状をなす正極シートとしての正電極シート28、及び長尺の矩形シート状をなす負極シートとしての負電極シート29を渦まき状に捲回することにより積層して形成されている。即ち、電極体23では、セパレータ27を間に挟んだ状態で絶縁された正電極シート28と負電極シート29が層状構造をなしている。正電極シート28は、金属箔(本実施形態ではアルミニウム箔)に、正極活物質を塗布して形成されている一方で、負電極シート29は、金属箔(本実施形態では銅箔)に負極活物質を塗布して形成されている。セパレータ27は、絶縁性を有する樹脂材料(例えばポリエチレンなど)からなる長尺の多孔性シートとされている。なお、電極体23では、最内周、及び最外周にセパレータ27が配置されている。   The electrode body 23 has a separator (diaphragm) 27 interposed therebetween, a positive electrode sheet 28 as a positive electrode sheet having a long rectangular sheet shape, and a negative electrode sheet as a negative electrode sheet having a long rectangular sheet shape. It is formed by laminating 29 by winding in a spiral shape. That is, in the electrode body 23, the positive electrode sheet 28 and the negative electrode sheet 29 insulated with the separator 27 interposed therebetween have a layered structure. The positive electrode sheet 28 is formed by applying a positive electrode active material to a metal foil (in this embodiment, an aluminum foil), while the negative electrode sheet 29 is formed in a metal foil (in this embodiment, a copper foil) with a negative electrode. It is formed by applying an active material. The separator 27 is a long porous sheet made of an insulating resin material (for example, polyethylene). In the electrode body 23, separators 27 are disposed on the innermost periphery and the outermost periphery.

また、正電極シート28には、その左端から一定幅で正電極シート28の長手方向に延びるように、正極活物質が塗布されていない非塗布領域28aが設定されているとともに、負電極シート29には、その右端から一定幅で負電極シート29の長手方向に延びるように、負極活物質が塗布されていない非塗布領域29aが設定されている。そして、本実施形態の電極シート28,29は、活物質が塗布された塗布領域Tを重ね合わせた状態で電極シート28,29が捲回されている。これにより、電極体23の左端部には正電極シート28の金属箔が積層された正電極リード24が形成される一方で、右端部には負電極シート29の金属箔が積層された負電極リード25が形成されている。なお、正電極リード24及び負電極リード25において、金属箔の間には、セパレータ27が介在されていない。そして、正電極リード24は、前述した集電端子17の先端(一端)と電気的に接続されている一方で、負電極リード25は、前述した集電端子18の先端(一端)と電気的に接続されている。また、ケース11の内部には、液体状やゲル状の図示しない電解質が充填され、満たされている。   In addition, the positive electrode sheet 28 is provided with a non-coated region 28a to which a positive electrode active material is not applied so as to extend in the longitudinal direction of the positive electrode sheet 28 with a constant width from the left end thereof, and a negative electrode sheet 29. The non-application area | region 29a in which the negative electrode active material is not apply | coated is set so that it may extend in the longitudinal direction of the negative electrode sheet 29 with a fixed width from the right end. And the electrode sheets 28 and 29 of this embodiment are wound in the state which piled up the application | coating area | region T with which the active material was apply | coated. Thereby, the positive electrode lead 24 in which the metal foil of the positive electrode sheet 28 is laminated is formed on the left end portion of the electrode body 23, while the negative electrode in which the metal foil of the negative electrode sheet 29 is laminated on the right end portion. Leads 25 are formed. In the positive electrode lead 24 and the negative electrode lead 25, the separator 27 is not interposed between the metal foils. The positive electrode lead 24 is electrically connected to the tip (one end) of the current collecting terminal 17, while the negative electrode lead 25 is electrically connected to the tip (one end) of the current collecting terminal 18. It is connected to the. The case 11 is filled with a liquid or gel electrolyte (not shown).

以下、本実施形態の二次電池10において特徴的な集電端子17,18について詳細に説明する。
なお、本実施形態において、集電端子17及び集電端子18は、その形状が左右対称とされている。また、集電端子17と正電極シート28(正電極リード24)との接合構造、及び集電端子18と負電極シート29(負電極リード25)との接合構造は、左右対称とされている。したがって、以下の説明では、主に集電端子17、及び集電端子17と正電極シート28との接合構造についてのみ詳しく説明し、集電端子18、及び集電端子18と負電極シート29との接合構造については、同一符号を付すなどしてその説明を簡略化する。
Hereinafter, the characteristic current collecting terminals 17 and 18 in the secondary battery 10 of this embodiment will be described in detail.
In the present embodiment, the current collecting terminal 17 and the current collecting terminal 18 are symmetrical in shape. The joining structure of the current collecting terminal 17 and the positive electrode sheet 28 (positive electrode lead 24) and the joining structure of the current collecting terminal 18 and the negative electrode sheet 29 (negative electrode lead 25) are symmetrical. . Therefore, in the following description, only the current collecting terminal 17 and the junction structure between the current collecting terminal 17 and the positive electrode sheet 28 will be described in detail, and the current collecting terminal 18, the current collecting terminal 18 and the negative electrode sheet 29 will be described in detail. The description of the joint structure is simplified by attaching the same reference numerals.

集電端子17は、左右方向に沿って延びる矩形平板状をなし正極端子15と電気的に接続される連結部30、及び左右方向における連結部30の外側端(ここでは左端部)から下方へ垂下された略矩形平板状をなす平板部としての垂下部31を備えている。図1及び図2に示すように、垂下部31は、その電極体23とは反対側に配置された外側面31aが、本体部材12において底部12aの周囲に設けられた(立設された)壁部のうち左壁部12bの内壁面に対向するように配置されている。即ち、垂下部31の外側面31aは、ケース11の内面にあわさる状態、より詳しくは本体部材12における左壁部12bの内面に合わさる状態で配置されている。   The current collecting terminal 17 has a rectangular flat plate shape extending in the left-right direction, and is connected downward to the connecting portion 30 electrically connected to the positive electrode terminal 15 and the outer end (here, the left end portion) of the connecting portion 30 in the left-right direction. A hanging portion 31 as a flat plate portion having a substantially rectangular flat plate shape is provided. As shown in FIGS. 1 and 2, the drooping portion 31 has an outer surface 31 a disposed on the side opposite to the electrode body 23 provided (standing) on the body member 12 around the bottom portion 12 a. It arrange | positions so that the inner wall surface of the left wall part 12b may be opposed among wall parts. That is, the outer side surface 31 a of the hanging portion 31 is arranged in a state where it is in contact with the inner surface of the case 11, more specifically, in a state where it is aligned with the inner surface of the left wall portion 12 b in the main body member 12.

また、垂下部31は、外側面31aの全面(略全面)が絶縁袋11aを介して左壁部12bの内壁面に接触(密着)されるように、左壁部12bに沿って延びるように配置されている。即ち、絶縁袋11aは、ケース11の内壁面(内面)と垂下部31の外側面31aとの間に挟持される。このため、集電端子17において、垂下部31の外側面31aは、絶縁袋11aに密着されているとともに、絶縁袋11aは、ケース11の内壁面(内面)に密着されている。なお、外側面31aは、平坦(平滑)に形成されている。このように、垂下部31の外側面31aと、ケース11の内面との間には、絶縁袋11aが介在されている。   The hanging portion 31 extends along the left wall portion 12b so that the entire surface (substantially the entire surface) of the outer side surface 31a is in contact (contacted) with the inner wall surface of the left wall portion 12b via the insulating bag 11a. Has been placed. That is, the insulating bag 11 a is sandwiched between the inner wall surface (inner surface) of the case 11 and the outer surface 31 a of the hanging portion 31. For this reason, in the current collecting terminal 17, the outer surface 31 a of the hanging portion 31 is in close contact with the insulating bag 11 a, and the insulating bag 11 a is in close contact with the inner wall surface (inner surface) of the case 11. The outer surface 31a is formed flat (smooth). As described above, the insulating bag 11 a is interposed between the outer surface 31 a of the hanging portion 31 and the inner surface of the case 11.

また、図2(a)に示すように、垂下部31は、その前後方向に沿った大きさが左壁部12bの内壁面における前後方向に沿った大きさより僅かに小さく、且つその上下方向に沿った大きさが左壁部12bの内壁面における上下方向に沿った大きさの約3分の2程度の大きさに形成されている。また、垂下部31は、その前後方向に沿った大きさが電極体23(正電極リード24)の前後方向に沿った大きさより大きく形成されているとともに、その上下方向に沿った大きさが電極体23(正電極リード24)の上下方向に沿った大きさの3分の2程度の大きさに形成されている。このため、垂下部31は、左側面視において電極体23(正電極リード24)の半分以上を覆うように形成されている。そして、本実施形態の垂下部31は、電極体23とケース11(本体部材12)との間に介在(介挿)されている。   Further, as shown in FIG. 2A, the hanging portion 31 has a size along the front-rear direction slightly smaller than a size along the front-rear direction on the inner wall surface of the left wall portion 12b, and in the up-down direction. The size along the upper wall of the left wall portion 12b is about two-thirds of the size along the vertical direction. The drooping portion 31 is formed such that the size along the front-rear direction is larger than the size along the front-rear direction of the electrode body 23 (positive electrode lead 24), and the size along the vertical direction is the electrode. The body 23 (positive electrode lead 24) is formed to have a size of about two thirds of the size along the vertical direction. Therefore, the drooping portion 31 is formed so as to cover more than half of the electrode body 23 (positive electrode lead 24) in the left side view. The drooping portion 31 of the present embodiment is interposed (inserted) between the electrode body 23 and the case 11 (main body member 12).

また、図1及び図2に示すように、垂下部31の外側面31aにおいて本体部材12の底部12a側には、本体部材12の底部12aに向かって電極体23側に傾斜するテーパ部32が設けられている。テーパ部32は、その下端部(先端部)が垂下部31に連設された連設部(基部)よりも左右方向の内側(ここでは右方)へ位置するように、正面視で直線状に傾斜するように形成されている。即ち、テーパ部32は、本体部材12の底部12aに向かって、左壁部12bから離間するように傾斜している。なお、テーパ部32の前後方向に沿った大きさは、垂下部31の前後方向に沿った大きさと同一(略同一)に形成されている。   As shown in FIGS. 1 and 2, a taper portion 32 that is inclined toward the electrode body 23 toward the bottom portion 12 a of the main body member 12 is formed on the outer surface 31 a of the hanging portion 31 on the bottom portion 12 a side of the main body member 12. Is provided. The tapered portion 32 is linear in a front view so that the lower end portion (tip portion) is located on the inner side in the left-right direction (here, on the right side) than the connecting portion (base portion) connected to the hanging portion 31. It is formed so as to be inclined. That is, the taper portion 32 is inclined toward the bottom portion 12a of the main body member 12 so as to be separated from the left wall portion 12b. The size of the tapered portion 32 along the front-rear direction is the same (substantially the same) as the size of the hanging portion 31 along the front-rear direction.

また、図2に示すように、垂下部31において、電極体23側に配置される内側面31bには、この内側面31bから左右方向における内側(ここでは右方)へ向かって延びる略矩形壁状をなす一対の接合部35,36が設けられている。本実施形態の接合部35,36は、同一形状(略同一形状)に形成されているとともに、相互に対向して対をなし、さらに相互に平行となるように配置されている。   As shown in FIG. 2, in the hanging portion 31, the inner side surface 31 b disposed on the electrode body 23 side has a substantially rectangular wall extending from the inner side surface 31 b toward the inner side in the left-right direction (here, the right side). A pair of joint portions 35 and 36 having a shape are provided. The joint portions 35 and 36 of the present embodiment are formed in the same shape (substantially the same shape), are opposed to each other, are paired, and are arranged so as to be parallel to each other.

各接合部35,36は、電極体23の正電極リード24の間に挿入するように配置されている。接合部35,36には、超音波接合や溶接などにより、正電極リード24が接合され、これにより集電端子17と正電極リード24とが電気的に接続される。なお、集電端子17と同様に、本実施形態の集電端子18は、その垂下部31の外側面31aが絶縁袋11aを介して(介在させて)右壁部12cの内壁面(内面)に接するように配置されている。したがって、集電端子17における垂下部31の外側面31aから、集電端子18における垂下部31の外側面31a迄の長さは、本体部材12の左壁部12bと右壁部12cとの離間距離よりも僅かに小さい長さ(略同一長さ)に設定されている。このように、接合部35,36は、各集電端子17,18における垂下部31と電極体23とを接続する接続部となる。   Each of the joint portions 35 and 36 is disposed so as to be inserted between the positive electrode leads 24 of the electrode body 23. The positive electrode lead 24 is bonded to the bonding portions 35 and 36 by ultrasonic bonding or welding, whereby the current collecting terminal 17 and the positive electrode lead 24 are electrically connected. As with the current collecting terminal 17, the current collecting terminal 18 of the present embodiment has an outer surface 31 a of the hanging portion 31 via an insulating bag 11 a (intervening) and an inner wall surface (inner surface) of the right wall portion 12 c. It is arranged to touch. Therefore, the length from the outer surface 31a of the drooping portion 31 of the current collecting terminal 17 to the outer surface 31a of the drooping portion 31 of the current collecting terminal 18 is the distance between the left wall portion 12b and the right wall portion 12c of the main body member 12. The length is set slightly smaller than the distance (substantially the same length). As described above, the joint portions 35 and 36 serve as connection portions that connect the hanging portions 31 and the electrode bodies 23 in the current collecting terminals 17 and 18.

次に、二次電池10の製造方法について説明する。
図1に示すように、セパレータ27を介在させて電極シート28,29を渦まき状に捲回して積層した後、さらに前後方向からプレス(圧縮)することにより扁平な形状に成形して電極体23を得る。このとき、電極シート28,29は、活物質の塗布領域Tを重ね合わせるとともに、この塗布領域Tに対応させてセパレータ27を介在させた状態で捲回する。これにより、電極体23の左端部には、正電極リード24が形成され、電極体23の右端部には、負電極リード25が形成される。また、電極体23を得る工程とは別の工程において集電端子17,18を得る(用意する)。
Next, a method for manufacturing the secondary battery 10 will be described.
As shown in FIG. 1, after the electrode sheets 28 and 29 are wound and laminated with a separator 27 interposed therebetween, they are further pressed (compressed) in the front-rear direction to form a flat shape. 23 is obtained. At this time, the electrode sheets 28 and 29 are wound in a state where the application regions T of the active material are overlapped and the separators 27 are interposed so as to correspond to the application regions T. As a result, a positive electrode lead 24 is formed at the left end portion of the electrode body 23, and a negative electrode lead 25 is formed at the right end portion of the electrode body 23. Further, the current collecting terminals 17 and 18 are obtained (prepared) in a process different from the process of obtaining the electrode body 23.

そして、電極体23の正電極リード24は、超音波接合や溶接などにより接合部35,36に接合され、集電端子17と電気的に接続される。同様に、電極体23の負電極リード25は、超音波接合や溶接などにより接合部35,36に接合され、集電端子18と電気的に接続される。   The positive electrode lead 24 of the electrode body 23 is joined to the joint portions 35 and 36 by ultrasonic joining or welding, and is electrically connected to the current collecting terminal 17. Similarly, the negative electrode lead 25 of the electrode body 23 is joined to the joint portions 35 and 36 by ultrasonic joining or welding and is electrically connected to the current collecting terminal 18.

その後、集電端子17には正極端子15が電気的に接続される一方で、集電端子18には負極端子16が接続される。次に、集電端子17及び集電端子18が接合された電極体23を、絶縁袋11aに収納するとともに、上方から本体部材12に挿入する。このとき、電極体23は、テーパ部32が絶縁袋11aを介して本体部材12の開口縁部や、各壁部12b,12cに接触することで左右方向の略中央に位置するようにガイドされる。したがって、本体部材12に対する電極体23の挿入性を向上させることができる。また、電極体23の挿入時に、電極体23が本体部材12に接触することで破損してしまうことを抑制できる。   Thereafter, the positive terminal 15 is electrically connected to the current collecting terminal 17, while the negative terminal 16 is connected to the current collecting terminal 18. Next, the electrode body 23 to which the current collecting terminal 17 and the current collecting terminal 18 are joined is housed in the insulating bag 11a and is inserted into the main body member 12 from above. At this time, the electrode body 23 is guided so that the tapered portion 32 is positioned at the approximate center in the left-right direction by contacting the opening edge of the main body member 12 and the wall portions 12b and 12c via the insulating bag 11a. The Therefore, the insertability of the electrode body 23 into the main body member 12 can be improved. Further, it is possible to prevent the electrode body 23 from being damaged due to contact with the main body member 12 when the electrode body 23 is inserted.

そして、本体部材12には、正極端子15及び負極端子16を上面から突出させつつ蓋部材13が組み付けられるとともに、最終的に電解質が充填されて二次電池10が完成される。   Then, the lid member 13 is assembled to the main body member 12 with the positive electrode terminal 15 and the negative electrode terminal 16 protruding from the upper surface, and finally, the electrolyte is filled to complete the secondary battery 10.

次に、二次電池10の作用について説明する。
まず、正極端子15及び負極端子16を介した充放電に伴う発熱により、電極体23の温度が二次電池10(ケース11)の外部を流れる熱交換媒体(熱媒体)より高くなった場合について説明する。
Next, the operation of the secondary battery 10 will be described.
First, a case where the temperature of the electrode body 23 becomes higher than the heat exchange medium (heat medium) flowing outside the secondary battery 10 (case 11) due to heat generated by charging / discharging through the positive terminal 15 and the negative terminal 16. explain.

この場合、図2(b)に示すように、電極体23で発生した熱は、電極シート28,29の主に金属箔を伝わって電極リード24に伝達されるとともに、さらに正電極リード24から集電端子17の接合部35,36に伝達される(矢印Yaに示す)。そして、集電端子17に伝達された熱は、垂下部31の外側面31aから絶縁袋11aを介してケース11(本体部材12)に伝達される。そして、ケース11に伝達された熱は、ケース11の外側を流れる熱交換媒体(熱媒体)との間における熱交換により放熱される(矢印Ybに示す)。なお、電極体23で発生した熱は、同様に負電極リード25及び集電端子18からもケース11(本体部材12)に伝達され、放熱される。このようにして、本実施形態の二次電池10では、内部に収納した電極体23を速やかに冷却することができる。   In this case, as shown in FIG. 2 (b), the heat generated in the electrode body 23 is transmitted to the electrode lead 24 mainly through the metal foil of the electrode sheets 28 and 29, and further from the positive electrode lead 24. It is transmitted to the joint portions 35 and 36 of the current collecting terminal 17 (indicated by the arrow Ya). The heat transmitted to the current collecting terminal 17 is transmitted from the outer surface 31a of the hanging part 31 to the case 11 (main body member 12) through the insulating bag 11a. The heat transferred to the case 11 is dissipated by heat exchange with the heat exchange medium (heat medium) flowing outside the case 11 (indicated by an arrow Yb). The heat generated in the electrode body 23 is similarly transmitted from the negative electrode lead 25 and the current collecting terminal 18 to the case 11 (main body member 12) and radiated. Thus, in the secondary battery 10 of this embodiment, the electrode body 23 accommodated inside can be rapidly cooled.

次に、低温環境下などにおいて、電極体23の温度が二次電池10(ケース11)の外部を流れる熱交換媒体(熱媒体)よりも低くなった場合について説明する。
この場合、熱交換媒体(熱媒体)からケース11(本体部材12)に伝達された熱は、絶縁袋11aを介して垂下部31の外側面31aから集電端子17に伝達される。そして、集電端子17に伝達された熱は、接合部35,36から正電極リード24に伝達されるとともに、電極シート28,29の主に金属箔を伝って電極体23に伝達される。なお、熱交換媒体からケース11(本体部材12)に伝達された熱は、同様に負電極リード25及び集電端子18からも電極体23に伝達される。このようにして、本実施形態の二次電池10では、内部に収納した電極体23を速やかに加温(加熱)することができる。
Next, the case where the temperature of the electrode body 23 becomes lower than the heat exchange medium (heat medium) flowing outside the secondary battery 10 (case 11) in a low temperature environment or the like will be described.
In this case, the heat transmitted from the heat exchange medium (heat medium) to the case 11 (main body member 12) is transmitted from the outer surface 31a of the hanging part 31 to the current collecting terminal 17 via the insulating bag 11a. The heat transmitted to the current collecting terminal 17 is transmitted from the joint portions 35 and 36 to the positive electrode lead 24 and is transmitted to the electrode body 23 mainly through the metal foil of the electrode sheets 28 and 29. The heat transmitted from the heat exchange medium to the case 11 (main body member 12) is also transmitted from the negative electrode lead 25 and the current collecting terminal 18 to the electrode body 23. Thus, in the secondary battery 10 of this embodiment, the electrode body 23 accommodated in the inside can be quickly heated (heated).

以上のように、本実施形態の二次電池10において、集電端子17,18は、垂下部31において接合部35,36が設けられた面とは反対側の外側面31aでケース11(本体部材12)と熱的に連結(結合)されている。より詳しくは、各集電端子17,18において、垂下部31の一方の面(外側面31a)はケース11の内壁面(内面)との間に絶縁袋11aを介した状態でケース11と熱的に連結し、他方の面(内側面31b)には接合部35,36が電気的及び熱的に連結している。   As described above, in the secondary battery 10 according to the present embodiment, the current collecting terminals 17 and 18 are connected to the case 11 (main body) on the outer surface 31a opposite to the surface where the joint portions 35 and 36 are provided in the hanging portion 31. It is thermally connected (coupled) to the member 12). More specifically, in each current collecting terminal 17, 18, one surface (outer surface 31 a) of the hanging portion 31 is in contact with the inner surface (inner surface) of the case 11 with the insulating bag 11 a interposed between the case 11 and the heat. The joints 35 and 36 are electrically and thermally connected to the other surface (inner side surface 31b).

このため、接合部35,36を設けた面でケースと熱的に連結(結合)させる構成と比較して、垂下部31とケース11との接触面積を広くすることができる。即ち、より広い面積で集電端子17,18とケース11とを熱的に連結させることが可能となる。これにより、電極体23とケース11との熱交換の効率をさらに高め、温度調節を速やかに行うことができる。   For this reason, the contact area of the hanging part 31 and the case 11 can be widened compared with the structure thermally connected (coupled) with the case on the surface provided with the joint portions 35 and 36. That is, the current collecting terminals 17 and 18 and the case 11 can be thermally connected in a wider area. Thereby, the efficiency of heat exchange between the electrode body 23 and the case 11 can be further increased, and the temperature can be adjusted quickly.

したがって、上記実施形態によれば、以下のような効果を得ることができる。
(1)垂下部31の一方の面(外側面31a)はケース11の内面との間に絶縁材からなる絶縁袋11aを介した状態でケース11と熱的に連結し、他方の面(内側面31b)には接合部35,36が電気的及び熱的に連結している。このため、接合部35,36が設けられた面(外側面31a)で集電端子17,18とケース11とを熱的に連結させる構成と比較して、より広い面積で集電端子17,18とケース11とを熱的に連結させることが可能となる。これにより、電極体23とケース11との熱交換の効率を高め、温度調節を速やかに行うことができる。したがって、温度調節を好適に行うことができる。
Therefore, according to the above embodiment, the following effects can be obtained.
(1) One surface (outer surface 31a) of the hanging portion 31 is thermally connected to the case 11 with an insulating bag 11a made of an insulating material between the inner surface of the case 11 and the other surface (inner Joints 35, 36 are electrically and thermally connected to the side surface 31b). For this reason, compared with the structure which connects the current collection terminals 17 and 18 and the case 11 thermally with the surface (outer surface 31a) in which the junction parts 35 and 36 were provided, the current collection terminals 17 and 18 in a wider area. 18 and the case 11 can be thermally connected. Thereby, the efficiency of heat exchange with the electrode body 23 and the case 11 can be improved, and temperature control can be performed rapidly. Therefore, temperature adjustment can be suitably performed.

(2)各集電端子17,18において、垂下部31の外側面31aと、ケース11の内面との間には、絶縁袋11aが介在されている。したがって、集電端子17,18とケース11との絶縁性を確保しつつ、電極体23とケース11との熱交換の効率を高めることができる。   (2) In each current collecting terminal 17, 18, an insulating bag 11 a is interposed between the outer surface 31 a of the hanging part 31 and the inner surface of the case 11. Therefore, the efficiency of heat exchange between the electrode body 23 and the case 11 can be enhanced while ensuring the insulation between the current collecting terminals 17 and 18 and the case 11.

(3)集電端子17の垂下部31は本体部材12の左壁部12bに対向するように配置され、さらに垂下部31の外側面31aにおいて本体部材12の底部12a側には、底部12aに向かって電極体23側へ傾斜するテーパ部32が設けられている。集電端子18についても同様である。このため、接合部35,36と電極体23とを接合(接続)させた状態で、電極体23を集電端子17,18とともに本体部材12に収納する際、テーパ部32によって電極体23がガイドされることで、電極体23の挿入性を向上させることができる。   (3) The hanging portion 31 of the current collecting terminal 17 is disposed so as to face the left wall portion 12b of the main body member 12, and further on the outer surface 31a of the hanging portion 31 on the bottom portion 12a side of the main body member 12, the bottom portion 12a. A tapered portion 32 that is inclined toward the electrode body 23 is provided. The same applies to the current collecting terminal 18. Therefore, when the electrode body 23 is housed in the main body member 12 together with the current collecting terminals 17 and 18 in a state in which the joint portions 35 and 36 and the electrode body 23 are joined (connected), the electrode body 23 is moved by the taper portion 32. By being guided, the insertability of the electrode body 23 can be improved.

(4)垂下部31は、電極体23とケース11との間に介在(介挿)されている。このため、各電極リード24,25の先端が絶縁袋11aに接触することがなく、集電端子17,18とケース11(絶縁袋11a)とが接触するまで、離間距離を小さくすることができる。より詳しく説明すると、図2(b)に示すように、各電極リード24,25の先端には、接合部35,36に接合させる際に金属箔が寄り合わされることによって、金属箔のエッジ24aが形成される。例えば、前述した特許文献1のように、電極体23(各電極リード24,25の先端)とケース11との間に垂下部31を介在させない構成では、エッジ24aが絶縁袋11aに接触しないように、集電端子17,18とケース11(絶縁袋11a)とを離間させる必要があった。このため、特許文献1では、二次電池10内部にデッドスペースが生じ、二次電池の小型化の妨げとなっていた。これに対して、本実施形態の二次電池10では、このような問題を好適に解決し、二次電池10内部におけるデッドスペースを削減して二次電池10を小型化し得る。   (4) The hanging portion 31 is interposed (inserted) between the electrode body 23 and the case 11. Therefore, the tip of each electrode lead 24, 25 does not contact the insulating bag 11a, and the separation distance can be reduced until the current collecting terminals 17, 18 and the case 11 (insulating bag 11a) are in contact. . More specifically, as shown in FIG. 2B, the metal foil is brought into contact with the tips of the electrode leads 24 and 25 when being joined to the joint portions 35 and 36, whereby the edge 24a of the metal foil. Is formed. For example, in the configuration in which the hanging portion 31 is not interposed between the electrode body 23 (tips of the electrode leads 24 and 25) and the case 11 as in Patent Document 1 described above, the edge 24a does not contact the insulating bag 11a. In addition, it is necessary to separate the current collecting terminals 17 and 18 from the case 11 (insulating bag 11a). For this reason, in Patent Document 1, a dead space is generated inside the secondary battery 10, which hinders downsizing of the secondary battery. On the other hand, in the secondary battery 10 of this embodiment, such a problem is solved suitably, the dead space in the secondary battery 10 inside can be reduced, and the secondary battery 10 can be reduced in size.

(5)特に、本実施形態において垂下部31は、接合部35,36と各電極リード24,25との接合部分(エッジ24a)、及びケース11の間に介在(介挿)されている。したがって、エッジ24aと絶縁袋11aとの接触を好適に防止することができる。   (5) In particular, in the present embodiment, the drooping portion 31 is interposed (inserted) between the joint portion (edge 24 a) between the joint portions 35 and 36 and the electrode leads 24 and 25 and the case 11. Therefore, the contact between the edge 24a and the insulating bag 11a can be suitably prevented.

(6)また、各垂下部31の外側面31aにおいて、側面視で接合部35,36と対応する部分は、絶縁袋11aを介した状態でケース11に熱的に連結されている。したがって、接合部35,36とケース11との熱交換の効率をさらに高めることができる。   (6) Moreover, in the outer side surface 31a of each hanging part 31, the part corresponding to the junction parts 35 and 36 by the side view is thermally connected with the case 11 via the insulating bag 11a. Therefore, the efficiency of heat exchange between the joint portions 35 and 36 and the case 11 can be further increased.

実施形態は前記に限定されるものではなく、例えば、次のように具体化してもよい。
・ 図3に示すように、正電極リード24を接合部35,36の間に挿入するように接合させてもよい。集電端子18及び負電極リード25についても同様に変更できる。
The embodiment is not limited to the above, and may be embodied as follows, for example.
As shown in FIG. 3, the positive electrode lead 24 may be joined so as to be inserted between the joint portions 35 and 36. The current collector terminal 18 and the negative electrode lead 25 can be similarly changed.

・ 図4(a)及び図4(b)に示すように、集電端子17のテーパ部32は、その下端部(先端部)が正電極リード24の先端より内側に挿入されるように形成してもよい。集電端子18についても同様に変更できる。このように構成することで、電極体23を本体部材12に挿入する際に、テーパ部32の下端部が本体部材12の開口縁部に引っ掛かることを抑制し、より挿入性を向上させることができる。なお、本別例においては、電極体23とケース11との間に垂下部31が介挿されていない領域が多くなるが、接合部35,36が設けられた面で集電端子17,18とケース11とを熱的に連結させる構成と比較して、集電端子17,18とケース11との接触面積を広くできる。   As shown in FIG. 4A and FIG. 4B, the tapered portion 32 of the current collecting terminal 17 is formed so that the lower end portion (tip portion) is inserted inside the tip end of the positive electrode lead 24. May be. The current collecting terminal 18 can be similarly changed. By comprising in this way, when inserting the electrode body 23 in the main body member 12, it can suppress that the lower end part of the taper part 32 is caught in the opening edge part of the main body member 12, and can improve insertability more. it can. In this example, the area where the hanging part 31 is not inserted between the electrode body 23 and the case 11 increases, but the current collecting terminals 17 and 18 are provided on the surface where the joints 35 and 36 are provided. The contact area between the current collecting terminals 17 and 18 and the case 11 can be widened as compared with the configuration in which the case 11 and the case 11 are thermally connected.

・ ケース11(本体部材12及び蓋部材13)の内面に絶縁材(絶縁性樹脂など)からなる絶縁層を形成してもよい。この場合には、絶縁袋11aを省略し、垂下部31の外側面31aをケース11(本体部材12)の内面に当接させてもよい。   An insulating layer made of an insulating material (insulating resin or the like) may be formed on the inner surface of the case 11 (the main body member 12 and the lid member 13). In this case, the insulating bag 11a may be omitted, and the outer surface 31a of the hanging part 31 may be brought into contact with the inner surface of the case 11 (main body member 12).

・ 集電端子17,18には、1つ、あるいは3つ以上の接合部を設けてもよい。
・ 集電端子17,18からテーパ部32を省略してもよい。この場合、集電端子17,18は、垂下部31の上下方向に沿った大きさが電極体23の上下方向に沿った大きさより大きくなるように形成してもよい。即ち、集電端子17,18は、側面視において電極体23が垂下部31で覆われるように(含まれるように)形成してもよい。さらに、垂下部31は、左壁部12bや右壁部12cの内壁面に対応した大きさに形成し、各内壁面の全面にわたって接触させるように形成してもよい。
The current collecting terminals 17 and 18 may be provided with one or three or more joint portions.
The taper portion 32 may be omitted from the current collecting terminals 17 and 18. In this case, the current collecting terminals 17 and 18 may be formed such that the size along the vertical direction of the hanging portion 31 is larger than the size along the vertical direction of the electrode body 23. That is, the current collecting terminals 17 and 18 may be formed so that the electrode body 23 is covered (included) by the hanging part 31 in a side view. Furthermore, the drooping portion 31 may be formed to have a size corresponding to the inner wall surface of the left wall portion 12b or the right wall portion 12c so as to be in contact with the entire inner wall surface.

・ 垂下部31、及びテーパ部32は、側面視において楕円形や五角形をなす平板状に形成してもよい。また、テーパ部32は、正面視で電極体23側に湾曲する円弧状に形成してもよい。   The drooping portion 31 and the tapered portion 32 may be formed in a flat plate shape that is elliptical or pentagonal in a side view. Moreover, you may form the taper part 32 in the circular arc shape curved to the electrode body 23 side by front view.

・ 導電体(金属)から形成されておれば、集電端子17,18の材料を適宜変更してもよい。
・ 電極体23は、セパレータ27を介在させて、電極シート28,29を蛇腹状に折り曲げて積層してもよく、複数の正電極シート28、及び複数の負電極シート29を重ね合わせるように積層してもよい。
-As long as it is formed from a conductor (metal), the material of the current collecting terminals 17 and 18 may be appropriately changed.
The electrode body 23 may be laminated by folding the electrode sheets 28 and 29 into a bellows shape with a separator 27 interposed therebetween, and the plurality of positive electrode sheets 28 and the plurality of negative electrode sheets 29 are laminated. May be.

・ ケース11は、全体として扁平な楕円形状に形成してもよい。この場合、本体部材12は、有底の略楕円筒状に形成するとともに、集電端子17,18の垂下部31は、本体部材12の内壁面に沿って平面視で弧をなすように形成するとよい。また、ケース11は、円柱状や直方体状など、扁平な形状でなくてもよい。   The case 11 may be formed in a flat oval shape as a whole. In this case, the main body member 12 is formed in a substantially oval cylindrical shape with a bottom, and the hanging parts 31 of the current collecting terminals 17 and 18 are formed so as to form an arc along the inner wall surface of the main body member 12 in plan view. Good. Further, the case 11 may not have a flat shape such as a cylindrical shape or a rectangular parallelepiped shape.

・ 電極体23は、電極シート28,29の幅方向が上下方向に沿うようにケース11に収納されていてもよい。この場合、電極体23の左上端部に正電極リード24を形成し、電極体23の右上端部に負電極リード25を形成する。   The electrode body 23 may be stored in the case 11 so that the width direction of the electrode sheets 28 and 29 is along the vertical direction. In this case, the positive electrode lead 24 is formed at the upper left end portion of the electrode body 23, and the negative electrode lead 25 is formed at the upper right end portion of the electrode body 23.

・ 二次電池10はニッケル水素二次電池として具体化してもよい。
・ 上記実施形態の二次電池10を車両(例えば産業車両や乗用車両など)に搭載し、車両に装備された発電機により充電する一方で、二次電池10から供給する電力によりエアコン用のコンプレッサや、車輪を駆動するための電動モータ、或いはカーナビゲーションシステムなどの電装品を駆動してもよい。これによれば、二次電池10として温度調節を好適に行うことができることから、環境温度や充放電に伴う電極体23の発熱に起因する性能低下を抑制し、例えば二次電池10の交換頻度が高くなったり、1回の満充電で利用可能な電力量が低下したりすることを抑制できる。
The secondary battery 10 may be embodied as a nickel hydride secondary battery.
-The secondary battery 10 of the above embodiment is mounted on a vehicle (for example, an industrial vehicle or a passenger vehicle) and is charged by a generator mounted on the vehicle, while the compressor for an air conditioner is supplied with electric power supplied from the secondary battery 10 Alternatively, an electric motor for driving the wheels or an electrical component such as a car navigation system may be driven. According to this, since the temperature adjustment can be suitably performed as the secondary battery 10, the performance deterioration due to the heat generation of the electrode body 23 due to the environmental temperature and charging / discharging is suppressed, for example, the replacement frequency of the secondary battery 10. It is possible to prevent the amount of power that can be used from being reduced or the amount of power that can be used from being fully charged once.

以下、上記実施形態から把握できる技術的思想について追記する。
(イ)前記テーパ部は、前記本体部材の底部側が前記正極シート又は前記負極シートの間に挿入されていることを特徴とする請求項3に記載の二次電池。
Hereinafter, a technical idea that can be grasped from the above embodiment will be additionally described.
(B) The secondary battery according to claim 3, wherein the tapered portion is inserted between the positive electrode sheet or the negative electrode sheet on the bottom side of the main body member.

(ロ)前記平板部は、前記電極体と前記ケースの間に介在されていることを特徴とする請求項1〜3、及び技術的思想イのいずれか1項に記載の二次電池。   (B) The secondary battery according to any one of claims 1 to 3, and the technical idea (a), wherein the flat plate portion is interposed between the electrode body and the case.

10…リチウムイオン二次電池(二次電池)、11…ケース、11a…絶縁袋(シート)、12…本体部材、12a…底部、12b…左壁部、12c…右壁部、17,18…集電端子(集電部材)、23…電極体(電極群)、27…セパレータ、28…正電極シート(正極シート)、29…負電極シート(負極シート)、31…垂下部(平板部)、31a…外側面、31b…内側面、32…テーパ部、35,36…接合部(接続部)。   DESCRIPTION OF SYMBOLS 10 ... Lithium ion secondary battery (secondary battery), 11 ... Case, 11a ... Insulation bag (sheet), 12 ... Main body member, 12a ... Bottom part, 12b ... Left wall part, 12c ... Right wall part, 17, 18 ... Current collecting terminal (current collecting member), 23 ... Electrode body (electrode group), 27 ... Separator, 28 ... Positive electrode sheet (positive electrode sheet), 29 ... Negative electrode sheet (negative electrode sheet), 31 ... Hanging part (flat plate part) , 31a ... outer surface, 31b ... inner surface, 32 ... tapered portion, 35,36 ... joint portion (connecting portion).

Claims (3)

セパレータを間に挟んだ状態で絶縁された正極シートと負極シートが層状構造をなした電極群をケースに収容してなる二次電池であって、
平板部と、前記平板部と前記電極群とを接続する接続部とを有し、導電材よりなる集電部材を備え、
前記平板部の一方の面は前記ケースの内面との間に絶縁材からなるシートを介した状態又は前記ケースの内面に形成された絶縁材からなる絶縁層を介した状態で前記ケースと熱的に連結し、他方の面には前記接続部が電気的及び熱的に連結しており、
前記ケースは金属からなり、
前記ケースは、底部及び前記底部の周囲より立設される壁部を有する有底筒状をなして前記電極群を収容する本体部材を含み、
前記平板部における前記ケースの内面と合わさる面は、前記壁部の内面に合わさる状態で配置され、前記壁部の内面と合わさる面における前記本体部材の底部側には、前記本体部材の底部に向かって前記電極群側に傾斜するテーパ部が設けられていることを特徴とする二次電池。
A secondary battery comprising a case in which an electrode group in which a positive electrode sheet and a negative electrode sheet that are insulated with a separator sandwiched therebetween has a layered structure is housed in a case,
A flat plate portion, and a connecting portion that connects the flat plate portion and the electrode group, and includes a current collecting member made of a conductive material,
The case and the heat in the state on one surface of which an insulating layer made of an insulating material formed on the inner surface of the state or the case via a sheet made of an insulating material between the inner surface of the front SL case said plate Connected to the other surface, the connecting portion is electrically and thermally connected to the other surface ,
The case is made of metal,
The case includes a main body member that accommodates the electrode group in a bottomed cylindrical shape having a bottom portion and a wall portion erected from the periphery of the bottom portion,
A surface of the flat plate portion that is aligned with the inner surface of the case is disposed in a state of being aligned with the inner surface of the wall portion, and a bottom surface side of the main body member that faces the inner surface of the wall portion faces the bottom portion of the main body member. And a tapered portion inclined toward the electrode group side .
前記平板部における前記ケースの内面と合わさる面と、前記ケースの内面との間には、絶縁材からなるシートが介在されていることを特徴とする請求項1に記載の二次電池。   2. The secondary battery according to claim 1, wherein a sheet made of an insulating material is interposed between a surface of the flat plate portion that meets the inner surface of the case and an inner surface of the case. 請求項1または2に記載の二次電池を搭載したことを特徴とする車両。 Vehicle, characterized in that mounting the secondary battery according to claim 1 or 2.
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