JPH04119930A - Production of colored remelted glass and coloring material for remelted glass - Google Patents
Production of colored remelted glass and coloring material for remelted glassInfo
- Publication number
- JPH04119930A JPH04119930A JP34424289A JP34424289A JPH04119930A JP H04119930 A JPH04119930 A JP H04119930A JP 34424289 A JP34424289 A JP 34424289A JP 34424289 A JP34424289 A JP 34424289A JP H04119930 A JPH04119930 A JP H04119930A
- Authority
- JP
- Japan
- Prior art keywords
- glass
- coloring material
- remelted
- fine powder
- colored
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000011521 glass Substances 0.000 title claims abstract description 62
- 239000000463 material Substances 0.000 title claims abstract description 44
- 238000004040 coloring Methods 0.000 title claims abstract description 18
- 238000004519 manufacturing process Methods 0.000 title claims description 12
- 239000000843 powder Substances 0.000 claims abstract description 29
- 238000002844 melting Methods 0.000 claims abstract description 5
- 230000008018 melting Effects 0.000 claims abstract description 5
- 238000010438 heat treatment Methods 0.000 claims abstract 3
- 239000000203 mixture Substances 0.000 claims description 9
- 239000003086 colorant Substances 0.000 abstract description 7
- 239000002245 particle Substances 0.000 abstract description 4
- 239000011435 rock Substances 0.000 abstract 1
- 239000000758 substrate Substances 0.000 description 10
- 229910000423 chromium oxide Inorganic materials 0.000 description 5
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 4
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 4
- 229910000428 cobalt oxide Inorganic materials 0.000 description 3
- 239000005357 flat glass Substances 0.000 description 3
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Inorganic materials O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 3
- -1 manganese dioxide compound Chemical class 0.000 description 3
- 229910044991 metal oxide Inorganic materials 0.000 description 3
- 150000004706 metal oxides Chemical class 0.000 description 3
- 239000004575 stone Substances 0.000 description 3
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 239000004566 building material Substances 0.000 description 2
- 229910052804 chromium Inorganic materials 0.000 description 2
- 239000011651 chromium Substances 0.000 description 2
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000006060 molten glass Substances 0.000 description 2
- 229910000480 nickel oxide Inorganic materials 0.000 description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 2
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 229910052814 silicon oxide Inorganic materials 0.000 description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 2
- 239000011787 zinc oxide Substances 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 1
- 239000004859 Copal Substances 0.000 description 1
- 241001137251 Corvidae Species 0.000 description 1
- 241000782205 Guibourtia conjugata Species 0.000 description 1
- 229910002090 carbon oxide Inorganic materials 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000009408 flooring Methods 0.000 description 1
- 239000006261 foam material Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000010438 granite Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000009499 grossing Methods 0.000 description 1
- 235000019239 indanthrene blue RS Nutrition 0.000 description 1
- UHOKSCJSTAHBSO-UHFFFAOYSA-N indanthrone blue Chemical compound C1=CC=C2C(=O)C3=CC=C4NC5=C6C(=O)C7=CC=CC=C7C(=O)C6=CC=C5NC4=C3C(=O)C2=C1 UHOKSCJSTAHBSO-UHFFFAOYSA-N 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 239000004579 marble Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 229910052596 spinel Inorganic materials 0.000 description 1
- 239000011029 spinel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Glass Compositions (AREA)
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
この発明は建材等に使用される表面光沢板材等のカラー
再溶融ガラスの製造方法およびそのガラス材料に関する
。DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) The present invention relates to a method for producing colored remelted glass such as a glossy surface board used as a building material and the glass material thereof.
（従来の技術）
例えば、表面にガラス様の光沢を有する内外装用建材と
して、事前に溶融して粒状に生成したガラス粒あるいは
フリット粒等のガラス材料を所定の型に導入して再度加
熱し再溶融して所定に板形状に成形したものが知られて
いる。この再溶融ガラスは必要に応じて表面研磨して壁
材として、あるいは研磨レベルを落してノンスリー、ブ
床材等として使用される。(Prior art) For example, glass materials such as glass grains or frit grains that have been melted into granules are introduced into a predetermined mold and reheated to be used as interior and exterior building materials with a glass-like luster on the surface. It is known that the material is melted and formed into a predetermined plate shape. This remelted glass can be used as a wall material after surface polishing if necessary, or as a non-sleeve, flooring material, etc. after being polished to a lower level.
しかるに、従来のこの種再溶融ガラスにあっては、ガラ
ス材料であるガラス粒が通常の透明板ガラスを粉砕分級
したものであり、また着色フリットはコスト高である等
の理由から、一般には無色透明のものがほとんどである
。また仮に、コスト等を度外視して着色ガラス粒あるい
は着色フリットを使用して再溶融ガラスを得たとしても
、該着色再溶融ガラスはあたかもペンキを塗ったような
深みのない単なる色ガラスとなるだけで、何ら趣きのあ
る天然石のような美しい表面を有するガラス材を得るこ
とはできなかった。However, in conventional remelted glass of this kind, the glass particles that are the glass material are made by crushing and classifying ordinary transparent plate glass, and colored frit is generally colorless and transparent because it is expensive. Most of them are. Furthermore, even if you disregard costs and obtain remelted glass by using colored glass particles or colored frit, the colored remelted glass will simply be colored glass with no depth, as if it had been painted. However, it has not been possible to obtain a glass material with a beautiful surface similar to that of natural stone.
さらに、前記のガラス粒あるいはフリ−２ト粒に顔料あ
るいは金属酸化物をブレンドして着色しようとする試み
も行なわれているが、着色材となる顔料あるいは金属酸
化物は溶融温度が高いため、ガラス再溶融温度である８
００〜１１００℃では溶融することなくガラス材料との
一体化ができず、従ってこの隙間部分に水分が浸透した
りあるいはもろくなったりして、十分な強度が得られな
いという欠点があった。Furthermore, attempts have been made to blend pigments or metal oxides into the glass grains or Friedite grains to color them, but since the pigments or metal oxides used as colorants have a high melting temperature, 8 which is the glass remelting temperature
At temperatures between 00 and 1,100° C., it does not melt and cannot be integrated with the glass material, resulting in water infiltration into the gaps or becoming brittle, resulting in insufficient strength.
（発明が解決しようとする課題）
そこで、この発明は上の問題をことごとく解決したカラ
ー再溶融ガラスの製造方法およびその再溶融ガラス用カ
ラー材を提案しようとするものである。この発明は、特
に、天然石のような美麗な外観を有するカラーガラスの
製造方法を提案するものである。また、この発明は、着
色材とガラス材料との強固な結合を図ることができるカ
ラーガラスの製造方法を提案するものである。(Problems to be Solved by the Invention) Therefore, it is an object of the present invention to propose a method for producing colored remelted glass and a coloring material for the remelted glass, which solves all of the above problems. This invention particularly proposes a method for producing colored glass that has a beautiful appearance similar to natural stone. Furthermore, the present invention proposes a method for manufacturing colored glass that can achieve a strong bond between a colorant and a glass material.
（課題を解決するための手段）
すなわち、ここで開示される第１の発明は、１〜５ｍｍ
程度の粒状ガラス基材と、０．１ｍｍ以下のガラス質微
粉と着色材とを混合したカラー材とを適宜の型内に挿入
し８００〜１１００℃で前記材料を加熱溶融して所定の
ガラス製品を製造することを特徴とするカラー再溶融ガ
ラスの製造方法に係る。(Means for solving the problem) That is, the first invention disclosed herein provides
A granular glass base material of about 1.0 mm or less and a coloring material made by mixing fine glass powder of 0.1 mm or less and a coloring material are inserted into an appropriate mold, and the materials are heated and melted at 800 to 1100 ° C. to form a specified glass product. The present invention relates to a method for producing colored remelted glass.
また第２の発明は、上記製造方法に使用される材料に関
し、０．１ｍｍ以下のガラス質微粉と着色材とを混合し
たことを特徴とする再溶融カラス用カラー材に係る。A second invention relates to a material used in the above-mentioned manufacturing method, and relates to a coloring material for remelting crows characterized by a mixture of glassy fine powder of 0.1 mm or less and a coloring material.
（作用）
上の製法発明においては、第２の発明のカラー再溶融ガ
ラス用カラー材が使用される。このカラー材は、０．１
ｍｍ以下のガラス質微粉と着色材とを混合したものであ
るが、これによれば、所定の色を発する着色材が０．１
ｍｍ以下のガラス質微粉と一緒に粒状ガラス基材の周囲
に配されるものであるから、カラス溶融温度で加熱され
たときには、粒状カラス基材とともに該ガラス質微粉も
溶融するので前記着色材を溶融カラス基材と効果的に一
体化することができるのである。従って粒状ガラス基材
の色彩の発色を極めて美麗に行なうことができるのであ
る。(Function) In the above manufacturing method invention, the color material for color remelting glass of the second invention is used. This color material is 0.1
It is a mixture of glassy fine powder of 0.1 mm or less and a coloring agent.
Since it is placed around the granular glass substrate together with the vitreous fine powder of 1 mm or less in size, when heated at the glass melting temperature, the vitreous fine powder melts together with the granular glass substrate. It can be effectively integrated with the molten glass substrate. Therefore, the granular glass substrate can be colored extremely beautifully.
（実施例）
以下添付の図面に従って実施例を説明すると、第１図は
この発明に係る再溶融ガラス構造を模式的に示した断面
図、第２図はこの発明製法の一例を示す断面図である。(Example) Examples will be described below with reference to the attached drawings. Figure 1 is a cross-sectional view schematically showing a remelted glass structure according to the present invention, and Figure 2 is a cross-sectional view showing an example of the manufacturing method of the present invention. be.
粒状ガラス基材２０は再溶融ガラスの基体を構成するも
ので、例えば、透明板ガラスあるいはフリットを粉砕し
て１〜５ｍｍ程度の粒径に分級して得られる。一般的に
は１〜２ ｍ ｍ程度の範囲のものが多用される。なお
、着色ガラスを使用してもよい。The granular glass substrate 20 constitutes a substrate of remelted glass, and is obtained, for example, by crushing transparent plate glass or frit and classifying it into particle sizes of about 1 to 5 mm. Generally, those having a diameter of about 1 to 2 mm are often used. Note that colored glass may also be used.
玉の粒状ガラス基材２０のためのカラー材２１としてガ
ラス質微粉２２および着色材２３の混合物が使用される
。A mixture of vitreous fine powder 22 and colorant 23 is used as coloring material 21 for the beaded granular glass substrate 20 .
ガラス質微粉２２は板ガラスあるいはフリットを粉砕し
て０．１ｍｍ以下としたもので、前記基材２１と同一の
材料が好ましく用いられる。なお、着色されていてもよ
いものである。The vitreous fine powder 22 is made by pulverizing plate glass or frit to a size of 0.1 mm or less, and the same material as the base material 21 is preferably used. Note that it may be colored.
着色材２３は公知の無機顔料および金属酸化物よりなる
。The coloring material 23 is made of a known inorganic pigment and metal oxide.
このガラス質微粉２２と着色材２３との混合比率はその
耐火度に合わせて決定される０次に混合比率と色との例
を記す。The mixing ratio of the glassy fine powder 22 and the coloring material 23 is determined according to its fire resistance.An example of the zero-order mixing ratio and color will be described below.
クロム・スズピンク
［２］＋ガラス賀微粉［８］
ゆレッド
けい酸シリコニウム［１］＋ガラス質微粉［９］噂ポワ
イト
酸化コバルト［０，２］＋ガラス賀微粉［９，８］四ブ
ルー
酸化クロム・酸化アルミニウムスビネルグリン［０，５
］＋カラス質微粉［９，５］ ＝＞グリーン酸化チタン
［１］＋ガラス質微粉［９コ中ベージユ
酸化クロム・酸化鉄拳酸化ニッケル・二酸化マンガン化
合物［０，３］ ＋ガラス質微粉［９，７］啼グレー
酸化クロム・酸化鉄・酸化ニッケル拳二酸化マンカン化
合物［１］ ＋ガラス質微粉［９］日ブラー、り
酸化コパル）−酸化アルミニウム・醇化亜鉛・酸化ケイ
素スピネル［１コ＋ガラス質微粉［９］中ブルー
酸化コバルト・酸化アルミニウム・酸化ケイ素・酸化亜
鉛・酸化クロム化合物［１］
＋ガラス質微粉［９］嗜ピーコツクブルーオだ、濃度を
必要とするときには次の配合で行なう。Chromium/tin pink [2] + Glass powder [8] Red silicone silicate [1] + Glass powder [9] Rumored poite cobalt oxide [0,2] + Glass powder [9,8] Tetrablue chromium oxide・Aluminum oxide Subinergrin [0,5
] + Glassy fine powder [9,5] => Green titanium oxide [1] + Glassy fine powder [9 Beige chromium oxide, iron oxide, nickel oxide, manganese dioxide compound [0,3] + Glassy fine powder [9, 7] Gray chromium oxide, iron oxide, nickel oxide, mankane dioxide compound [1] + vitreous fine powder [9] black oxide, copal oxide) - aluminum oxide, zinc oxide, silicon oxide spinel [1 + vitreous fine powder [9] Medium blue cobalt oxide, aluminum oxide, silicon oxide, zinc oxide, chromium oxide compound [1] + glassy fine powder [9] If a high concentration is required, use the following formulation.
けい酸シリコこラム［１］＋ガラス質微粉［１コ中ホワ
イト
酸化チタン［１］＋ガラス賀微粉［１］−ベージュ
クロム・スズピンク［１］＋ガラス質微粉［１］中レツ
ド
酸化クロム・酸化鉄・酸化ニー、ケル・二酸化マンガン
・酸化コバルト化合物［１］＋カラス質微粉［１］中ブ
ラツク
このガラス質微粉２２と着色材２３との混合物よりなる
カラー材２１は、前記粒状ガラス基材２０とともにガラ
ス材料Ｍとして、第２図のような例えば板状になるよう
に枠組された型５０内に導入される。そして、炉５１内
で公知の方法により８００〜１１００℃で加熱され、板
状のガラス製品に溶融成形される。＆お、同図の符号５
２はガラス製品の表面平滑度を出すためのステンレス板
蓋、６０はガラス製品のベース材となる発泡材である。Silicolam silicate [1] + Glassy fine powder [1] White titanium oxide [1] + Glassy fine powder [1] - Beige chromium/tin pink [1] + Glassy fine powder [1] Red chromium oxide/oxide A coloring material 21 made of a mixture of iron, carbon oxide, kel, manganese dioxide, and cobalt oxide compound [1] + glassy fine powder [1] is a mixture of the glassy fine powder 22 and a coloring material 23, which is a mixture of the granular glass base material 20 At the same time, the glass material M is introduced into a mold 50 framed in a plate shape, for example, as shown in FIG. Then, it is heated in a furnace 51 at 800 to 1100° C. by a known method to melt and form a plate-shaped glass product. &Oh, code 5 in the same figure
2 is a stainless steel plate lid for smoothing the surface of the glass product, and 60 is a foam material that will be the base material of the glass product.
（効果）
以上図示し説明したように、この発明によれば、所定の
色を発する着色材が０．１ｍｍ以下のガラス質微粉と一
緒に粒状ガラス基材の周囲に配されるものであるから、
ガラス溶融温度で加熱されたときには、ガラス基材とと
もに該ガラス質微粉も溶融し、前記着色材を溶融ガラス
基材と効果的に一体化することができる。従って、この
製法によって得られたガラス製品は深みのある、あたか
も大理石やみかげ石等の天然石のような重厚かつ豪華な
外観のカラーガラス表面を得ることができる。(Effects) As illustrated and explained above, according to the present invention, a coloring material that emits a predetermined color is arranged around a granular glass substrate together with glassy fine powder of 0.1 mm or less. ,
When heated at a glass melting temperature, the glass fine powder is melted together with the glass substrate, and the colorant can be effectively integrated with the molten glass substrate. Therefore, the glass product obtained by this manufacturing method can have a deep, colored glass surface with a solid and luxurious appearance, resembling natural stone such as marble or granite.
第１図はこの発明に係る再溶融ガラス構造を模式的に示
した断面図、第２図はこの発明製法の一例を示す断面図
である。
２０・・・粒状ガラス基材、２１・・・カラー材、２２
・・・ガラス質微粉、２３・・・着色材。
第
図
第
図
平成３年８月 ２ 日FIG. 1 is a cross-sectional view schematically showing a remelted glass structure according to the present invention, and FIG. 2 is a cross-sectional view showing an example of the manufacturing method of the present invention. 20... Granular glass base material, 21... Color material, 22
... Glassy fine powder, 23... Coloring material. Figure Figure August 2, 1991
Claims (1)
下のガラス質微粉と着色材とを混合したカラー材とを適
宜の型内に挿入し８００〜１１００℃で前記材料を加熱
溶融して所定のガラス製品を製造することを特徴とする
カラー再溶融ガラスの製造方法。 ２、０．１ｍｍ以下のガラス質微粉と着色材とを混合し
たことを特徴とする再溶融ガラス用カラー材。[Claims] 1. A granular glass base material of about 1 to 5 mm and a color material made of a mixture of fine glass powder of 0.1 mm or less and a coloring material are inserted into an appropriate mold and heated at 800 to 1100°C. A method for producing colored remelted glass, characterized in that a predetermined glass product is produced by heating and melting the above-mentioned materials. 2. A coloring material for remelted glass characterized by a mixture of glassy fine powder of 0.1 mm or less and a coloring material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP34424289A JPH04119930A (en) | 1989-12-30 | 1989-12-30 | Production of colored remelted glass and coloring material for remelted glass |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP34424289A JPH04119930A (en) | 1989-12-30 | 1989-12-30 | Production of colored remelted glass and coloring material for remelted glass |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH04119930A true JPH04119930A (en) | 1992-04-21 |
Family
ID=18367731
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP34424289A Pending JPH04119930A (en) | 1989-12-30 | 1989-12-30 | Production of colored remelted glass and coloring material for remelted glass |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH04119930A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111423125A (en) * | 2020-04-09 | 2020-07-17 | 惠州市彩玉微晶新材有限公司 | Processing technology and texture manufacturing method of full-melting metal ion coloring microcrystalline glass plate |
-
1989
- 1989-12-30 JP JP34424289A patent/JPH04119930A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111423125A (en) * | 2020-04-09 | 2020-07-17 | 惠州市彩玉微晶新材有限公司 | Processing technology and texture manufacturing method of full-melting metal ion coloring microcrystalline glass plate |
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