JPH06100894A - Detergent composition - Google Patents
Detergent compositionInfo
- Publication number
- JPH06100894A JPH06100894A JP3356951A JP35695191A JPH06100894A JP H06100894 A JPH06100894 A JP H06100894A JP 3356951 A JP3356951 A JP 3356951A JP 35695191 A JP35695191 A JP 35695191A JP H06100894 A JPH06100894 A JP H06100894A
- Authority
- JP
- Japan
- Prior art keywords
- butyl ether
- detergent composition
- group
- polyoxypropylene
- polyoxyethylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 22
- 239000003599 detergent Substances 0.000 title claims abstract description 20
- -1 polyoxypropylene butyl ether Polymers 0.000 claims abstract description 51
- 239000002280 amphoteric surfactant Substances 0.000 claims abstract description 8
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 claims abstract description 6
- 238000004140 cleaning Methods 0.000 claims description 4
- 125000000542 sulfonic acid group Chemical group 0.000 claims description 4
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 3
- 125000002270 phosphoric acid ester group Chemical group 0.000 claims description 3
- 125000006353 oxyethylene group Chemical group 0.000 claims description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 2
- 150000001450 anions Chemical class 0.000 claims 2
- 150000001875 compounds Chemical class 0.000 abstract 1
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 17
- 229920001451 polypropylene glycol Polymers 0.000 description 15
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 12
- 235000014113 dietary fatty acids Nutrition 0.000 description 8
- 239000000194 fatty acid Substances 0.000 description 8
- 229930195729 fatty acid Natural products 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 7
- 238000011156 evaluation Methods 0.000 description 6
- 150000004665 fatty acids Chemical class 0.000 description 5
- 229910019142 PO4 Inorganic materials 0.000 description 4
- 239000010452 phosphate Substances 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000007796 conventional method Methods 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 2
- POJWUDADGALRAB-UHFFFAOYSA-N allantoin Chemical compound NC(=O)NC1NC(=O)NC1=O POJWUDADGALRAB-UHFFFAOYSA-N 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 2
- 229940078492 ppg-17 Drugs 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 230000001953 sensory effect Effects 0.000 description 2
- 125000001273 sulfonato group Chemical class [O-]S(*)(=O)=O 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- PSBDWGZCVUAZQS-UHFFFAOYSA-N (dimethylsulfonio)acetate Chemical compound C[S+](C)CC([O-])=O PSBDWGZCVUAZQS-UHFFFAOYSA-N 0.000 description 1
- 229940058015 1,3-butylene glycol Drugs 0.000 description 1
- POJWUDADGALRAB-PVQJCKRUSA-N Allantoin Natural products NC(=O)N[C@@H]1NC(=O)NC1=O POJWUDADGALRAB-PVQJCKRUSA-N 0.000 description 1
- KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical compound NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- 239000004129 EU approved improving agent Substances 0.000 description 1
- 239000004378 Glycyrrhizin Substances 0.000 description 1
- 239000004909 Moisturizer Substances 0.000 description 1
- NIPNSKYNPDTRPC-UHFFFAOYSA-N N-[2-oxo-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 NIPNSKYNPDTRPC-UHFFFAOYSA-N 0.000 description 1
- 206010040880 Skin irritation Diseases 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 229960000458 allantoin Drugs 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 229960003237 betaine Drugs 0.000 description 1
- 235000019437 butane-1,3-diol Nutrition 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- DTPCFIHYWYONMD-UHFFFAOYSA-N decaethylene glycol Polymers OCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO DTPCFIHYWYONMD-UHFFFAOYSA-N 0.000 description 1
- 229940009662 edetate Drugs 0.000 description 1
- 235000019441 ethanol Nutrition 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 235000019197 fats Nutrition 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 229930195712 glutamate Natural products 0.000 description 1
- LPLVUJXQOOQHMX-UHFFFAOYSA-N glycyrrhetinic acid glycoside Natural products C1CC(C2C(C3(CCC4(C)CCC(C)(CC4C3=CC2=O)C(O)=O)C)(C)CC2)(C)C2C(C)(C)C1OC1OC(C(O)=O)C(O)C(O)C1OC1OC(C(O)=O)C(O)C(O)C1O LPLVUJXQOOQHMX-UHFFFAOYSA-N 0.000 description 1
- 229960004949 glycyrrhizic acid Drugs 0.000 description 1
- UYRUBYNTXSDKQT-UHFFFAOYSA-N glycyrrhizic acid Natural products CC1(C)C(CCC2(C)C1CCC3(C)C2C(=O)C=C4C5CC(C)(CCC5(C)CCC34C)C(=O)O)OC6OC(C(O)C(O)C6OC7OC(O)C(O)C(O)C7C(=O)O)C(=O)O UYRUBYNTXSDKQT-UHFFFAOYSA-N 0.000 description 1
- 235000019410 glycyrrhizin Nutrition 0.000 description 1
- LPLVUJXQOOQHMX-QWBHMCJMSA-N glycyrrhizinic acid Chemical compound O([C@@H]1[C@@H](O)[C@H](O)[C@H](O[C@@H]1O[C@@H]1C([C@H]2[C@]([C@@H]3[C@@]([C@@]4(CC[C@@]5(C)CC[C@@](C)(C[C@H]5C4=CC3=O)C(O)=O)C)(C)CC2)(C)CC1)(C)C)C(O)=O)[C@@H]1O[C@H](C(O)=O)[C@@H](O)[C@H](O)[C@H]1O LPLVUJXQOOQHMX-QWBHMCJMSA-N 0.000 description 1
- 150000002462 imidazolines Chemical class 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000001333 moisturizer Effects 0.000 description 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 150000003904 phospholipids Chemical class 0.000 description 1
- 239000002453 shampoo Substances 0.000 description 1
- 230000036556 skin irritation Effects 0.000 description 1
- 231100000475 skin irritation Toxicity 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 229940117986 sulfobetaine Drugs 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2068—Ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Cosmetics (AREA)
- Detergent Compositions (AREA)
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は、使用感の優れた洗浄剤
組成物に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a detergent composition having an excellent feeling in use.
【０００２】[0002]
【従来の技術及び発明が解決しようとする課題】従来か
ら、高級脂肪酸塩、Ｎ−アシルグルタミン酸塩、ポリオ
キシエチレンアルキルエーテル硫酸塩等の界面活性剤を
主成分とする洗浄剤が検討されている。ところが、高級
脂肪酸塩は、アルカリ性であるために肌への負荷がかか
り好ましくなく、Ｎ−アシルグルタミン酸塩はすすぎ易
さに劣り、ポリオキシエチレンアルキルエーテル硫酸塩
は皮膚刺激性、すすぎ易さに劣るという問題点があっ
た。そこでこれらの点を改良するために、両性界面活性
剤を配合することが試みられている。2. Description of the Related Art Conventionally, detergents containing a surfactant such as higher fatty acid salt, N-acylglutamate, polyoxyethylene alkyl ether sulfate and the like as a main component have been studied. . However, since the higher fatty acid salt is alkaline, it is not preferable because it imposes a load on the skin, N-acyl glutamate is inferior in rinsing ease, and polyoxyethylene alkyl ether sulfate is inferior in skin irritation and rinsing ease. There was a problem. Therefore, in order to improve these points, it has been attempted to add an amphoteric surfactant.
【０００３】しかしながら、この組合せからなる洗浄剤
組成物は、泡立ち及び洗浄性の点ではほぼ満足されるも
のであるが、使用感において充分に優れたもの（手指等
の皮膚のかさかさ感、つっぱり感がない）はなかった。However, the detergent composition comprising this combination is almost satisfactory in terms of foaming and detergency, but has a sufficiently excellent feeling in use (feeling that the skin of fingers and the like is bulky or taut. There was no).
【０００４】本発明者らは、このような事情に鑑み鋭意
検討を重ねた結果、後記特定の本発明の洗浄剤組成物の
使用感が良好である（手指等の皮膚のかさかさ感、つっ
ぱり感が少ない）ことを見出し、本発明を完成した。As a result of intensive investigations in view of such circumstances, the present inventors have found that the specific detergent composition of the present invention described below has a good feeling in use (the bulkiness of the skin of fingers and the like, the feeling of tightness). However, the present invention has been completed.
【０００５】即ち、本発明の目的は、使用感が良好な洗
浄剤組成物を提供することにある。That is, an object of the present invention is to provide a detergent composition having a good feeling in use.
【０００６】[0006]
【課題を解決するための手段】上述の目的は、アニオン
界面活性剤の一種又は二種以上と、両性界面活性剤の一
種又は二種以上と、ポリオキシプロピレンブチルエーテ
ル及びポリオキシエチレンポリオキシプロピレンブチル
エーテルの群から選択される一種又は二種以上とを含有
する洗浄剤組成物によって達成される。Means for Solving the Problems The above-mentioned objects are one or more anionic surfactants, one or more amphoteric surfactants, polyoxypropylene butyl ether and polyoxyethylene polyoxypropylene butyl ether. It is achieved by a detergent composition containing one or more selected from the group of
【０００７】以下、本発明の構成について詳述する。本
発明に用いられるアニオン界面活性剤としては、カルボ
キシル基、硫酸エステル基、スルホン酸基、リン酸エス
テル基を分子内に一種又は二種以上有するもので、カル
ボキシル基を有するものとしてはアルキルエーテルカル
ボン酸塩、アミノ酸と脂肪酸の縮合物のＮ−アシルアミ
ノ酸塩等、スルホン酸基を有するものとしてはアルカン
スルホン酸塩、アルカンスルホコハク酸塩、アルキルア
リル及びアルキルナフタレンスルホン酸塩、Ｎ−アシル
スルホン酸塩、ホルマリン縮合系スルホン酸塩等、硫酸
エステル基を有するものとしてはアルキル硫酸エステル
塩、アルキルエーテル硫酸塩、アルキルアリールエーテ
ル硫酸塩、高級脂肪酸アミド硫酸塩等、リン酸エステル
基を有するものとしてはアルキルリン酸エステル塩、エ
ーテルリン酸エステル塩、アルキルアリールエーテルリ
ン酸エステル塩、高級脂肪酸アミドリン酸塩等を挙げる
ことができ、これらの中から一種又は二種以上が任意に
選択される。The structure of the present invention will be described in detail below. The anionic surfactant used in the present invention has one or more kinds of carboxyl groups, sulfuric acid ester groups, sulfonic acid groups, and phosphoric acid ester groups in the molecule. Acid salts, N-acyl amino acid salts of condensates of amino acids and fatty acids, and those having a sulfonic acid group include alkane sulfonates, alkane sulfosuccinates, alkylallyl and alkylnaphthalene sulfonates, N-acyl sulfonates. , Formalin condensed sulfonates and the like, those having a sulfate ester group, such as alkyl sulfate ester salts, alkyl ether sulfates, alkylaryl ether sulfates, higher fatty acid amide sulfates, and those having a phosphate ester group are alkyl Phosphate ester salt, ether phosphate Ether salts, alkyl aryl ether phosphate salts, may be mentioned higher fatty amide phosphate salts, etc., one or two or more can be arbitrarily selected from these.
【０００８】本発明に用いられる両性界面活性剤として
は、アミドプロピルベタイン、カルボキシベタイン、ス
ルホベタイン、アミノカルボン酸、イミダゾリン誘導
体、アミンオキシド、リン脂質、３級窒素あるいは４級
窒素を含むリン酸エステル等を挙げることができ、これ
らの中から一種又は二種以上が任意に選択できる。As the amphoteric surfactant used in the present invention, amidopropyl betaine, carboxybetaine, sulfobetaine, aminocarboxylic acid, imidazoline derivative, amine oxide, phospholipid, tertiary nitrogen or quaternary nitrogen-containing phosphate ester. And the like, and one or two or more of these can be arbitrarily selected.
【０００９】本発明に用いられるアニオン界面活性剤の
配合量は、洗浄剤組成物中５〜３０重量％が好ましく、
さらに好ましくは１０〜２５重量％である。本発明に用
いられる両性界面活性剤の配合量は、洗浄剤組成物中
０．５〜２０重量％が好ましく、さらに好ましくは５〜
１５重量％である。アニオン界面活性剤と両性界面活性
剤との合計の配合量は、洗浄剤組成物中５．５〜５０重
量％が好ましく、さらに好ましくは１０〜３０重量％で
ある。The amount of the anionic surfactant used in the present invention is preferably 5 to 30% by weight in the detergent composition,
More preferably, it is 10 to 25% by weight. The content of the amphoteric surfactant used in the present invention is preferably 0.5 to 20% by weight, more preferably 5 to 20% by weight in the detergent composition.
It is 15% by weight. The total content of the anionic surfactant and the amphoteric surfactant in the detergent composition is preferably 5.5 to 50% by weight, more preferably 10 to 30% by weight.
【００１０】本発明に用いられるポリオキシプロピレン
ブチルエーテルあるいはポリオキシエチレンポリオキシ
プロピレンブチルエーテルのオキシエチレン鎖長は０か
ら４５、オキシプロピレン鎖長は２から６０である。例
えば、ポリオキシプロピレン（２）ブチルエーテル、ポ
リオキシプロピレン（４）ブチルエーテル、ポリオキシ
プロピレン（１７）ブチルエーテル、ポリオキシプロピ
レン（３３）ブチルエーテル、ポリオキシプロピレン
（４０）ブチルエーテル、ポリオキシプロピレン（５
２）ブチルエーテル、ポリオキシプロピレン（５３）ブ
チルエーテル、ポリオキシエチレン（２）ポリオキシプ
ロピレン（２）ブチルエーテル、ポリオキシエチレン
（３）ポリオキシプロピレン（３４）ブチルエーテル、
ポリオキシエチレン（５）ポリオキシプロピレン（５）
ブチルエーテル、ポリオキシエチレン（１０）ポリオキ
シプロピレン（７）ブチルエーテル、ポリオキシエチレ
ン（９）ポリオキシプロピレン（１０）ブチルエーテ
ル、ポリオキシエチレン（１７）ポリオキシプロピレン
（１７）ブチルエーテル、ポリオキシエチレン（２０）
ポリオキシプロピレン（１５）ブチルエーテル、ポリオ
キシエチレン（３０）ポリオキシプロピレン（３０）ブ
チルエーテル、ポリオキシエチレン（４５）ポリオキシ
プロピレン（３３）ブチルエーテル、ポリオキシエチレ
ン（３７）ポリオキシプロピレン（３８）ブチルエーテ
ル等を挙げることができる。尚、括弧内の数字は平均付
加モル数を示す。The polyoxypropylene butyl ether or polyoxyethylene polyoxypropylene butyl ether used in the present invention has an oxyethylene chain length of 0 to 45 and an oxypropylene chain length of 2 to 60. For example, polyoxypropylene (2) butyl ether, polyoxypropylene (4) butyl ether, polyoxypropylene (17) butyl ether, polyoxypropylene (33) butyl ether, polyoxypropylene (40) butyl ether, polyoxypropylene (5
2) butyl ether, polyoxypropylene (53) butyl ether, polyoxyethylene (2) polyoxypropylene (2) butyl ether, polyoxyethylene (3) polyoxypropylene (34) butyl ether,
Polyoxyethylene (5) Polyoxypropylene (5)
Butyl ether, polyoxyethylene (10) polyoxypropylene (7) butyl ether, polyoxyethylene (9) polyoxypropylene (10) butyl ether, polyoxyethylene (17) polyoxypropylene (17) butyl ether, polyoxyethylene (20)
Polyoxypropylene (15) butyl ether, polyoxyethylene (30) polyoxypropylene (30) butyl ether, polyoxyethylene (45) polyoxypropylene (33) butyl ether, polyoxyethylene (37) polyoxypropylene (38) butyl ether, etc. Can be mentioned. The numbers in parentheses indicate the average number of moles added.
【００１１】本発明に用いられるポリオキシプロピレン
ブチルエーテルあるいはポリオキシエチレンポリオキシ
プロピレンブチルエーテルの配合量は、単独又は両方の
合計量として洗浄剤組成物中０．２〜５重量％が好まし
く、さらに好ましくは１〜２重量％である。The amount of polyoxypropylene butyl ether or polyoxyethylene polyoxypropylene butyl ether used in the present invention is preferably 0.2 to 5% by weight in the detergent composition, either alone or as a total amount of both, and more preferably. It is 1-2% by weight.
【００１２】本発明の洗浄剤組成物には、上記必須成分
の他に所望により通常用いられる他の成分を適宜加える
ことができる。他の成分として、ヤシ油脂肪酸ジエタノ
ールアミド、グリセリン脂肪酸エステル、ポリオキシエ
チレンアルキルエーテル等の非イオン界面活性剤、脂肪
酸エチレングリコール等のパール光沢剤、エデト酸塩等
のキレート剤、グリセリン、ソルビトール、マルチトー
ル、１，３−ブチレングリコール等の保湿剤や脂肪酸、
高級アルコール、油脂等の過脂肪剤、メチルセルロー
ス、カルボキシビニルポリマ−等の水溶性高分子、カチ
オン化セルロース等の使用性向上剤、さらにグリチルリ
チン、アラントイン、各種ビタミン等の薬剤を挙げるこ
とができる。[0012] In addition to the above-mentioned essential components, other components which are usually used can be appropriately added to the detergent composition of the present invention. As other components, coconut oil fatty acid diethanolamide, glycerin fatty acid ester, nonionic surfactant such as polyoxyethylene alkyl ether, pearlescent agent such as fatty acid ethylene glycol, chelating agent such as edetate, glycerin, sorbitol, multi Moisturizers and fatty acids such as tall and 1,3-butylene glycol,
Examples include superfatting agents such as higher alcohols and fats and oils, water-soluble polymers such as methylcellulose and carboxyvinyl polymers, usability improving agents such as cationized cellulose, and agents such as glycyrrhizin, allantoin and various vitamins.
【００１３】本発明の洗浄剤組成物は、頭髪、皮膚及び
台所洗剤等に適用できる。さらに、メーキャップ化粧料
の洗浄にも有用である。The detergent composition of the present invention can be applied to hair, skin, kitchen detergent and the like. Furthermore, it is also useful for cleaning makeup cosmetics.
【００１４】[0014]
【実施例】次に実施例を挙げて本発明を詳細に説明する
が、本発明はこれらに限定されるものではない。配合量
は、重量％である。実施例に先立ち、評価方法について
述べる。EXAMPLES The present invention will now be described in detail with reference to examples, but the present invention is not limited thereto. The blending amount is% by weight. Prior to the examples, the evaluation method will be described.
【００１５】 使用後の官能テスト 官能パネラー１０名による洗浄テストを行い、皮膚のか
さかさ感、つっぱり感の有無等の使用後感を表１に準じ
て評価した。尚、かさかさ感、つっぱり感の少ないもの
を良好とした。評価結果は、実施例及び比較例を官能パ
ネラー１０名が評価し、それそれの評価点の平均値を求
め、その平均値を表２に準じて、○、△、×の記号で示
した。Sensory test after use A cleaning test was conducted by 10 sensory panelists, and the feeling after use such as the presence or absence of bulkiness and tightness of the skin was evaluated according to Table 1. Those having less bulkiness and tightness were considered good. The evaluation results were evaluated by 10 functional panelists of the Examples and Comparative Examples, and the average value of the evaluation points thereof was calculated. The average values are shown by the symbols ◯, Δ, and X according to Table 2.
【００１６】[0016]
【表１】 [Table 1]
【００１７】[0017]
【表２】 [Table 2]
【００１８】実施例１−３，比較例１ 表３に示す処方でシャンプーを常法により調製した。評
価結果を表３に示す。表３から明らかなように本発明の
実施例１−３は比較例１に比べて使用感（手指等皮膚の
つっぱり感、かさかさ感）の全ての点において優れてい
た。Example 1-3, Comparative Example 1 Shampoos having the formulations shown in Table 3 were prepared by a conventional method. The evaluation results are shown in Table 3. As is clear from Table 3, Examples 1-3 of the present invention were superior to Comparative Example 1 in all points of use (tightness and bulkiness of skin such as fingers).
【００１９】[0019]
【表３】 [Table 3]
【００２０】実施例４〜６，比較例２ 表４に示す処方で液体洗顔料を常法により調製した。評
価結果を表４に示す。表４から明らかなように本発明の
実施例４−６は比較例２に比べて使用感（手指等皮膚の
つっぱり感、かさかさ感）の全ての点において優れてい
た。Examples 4 to 6 and Comparative Example 2 Liquid cleansers having the formulations shown in Table 4 were prepared by a conventional method. The evaluation results are shown in Table 4. As is clear from Table 4, Examples 4-6 of the present invention were superior to Comparative Example 2 in all the points of use (tightness and bulkiness of skin such as fingers).
【００２１】[0021]
【表４】 [Table 4]
【００２２】実施例７〜９，比較例３ 表５に示す処方で家庭用（台所）洗剤を常法により調製
した。評価結果を表５に示す。表５から明らかなように
本発明の実施例７〜９は比較例３に比べて使用感（手指
等皮膚のつっぱり感、かさかさ感）の全ての点において
優れていた。Examples 7 to 9 and Comparative Example 3 Household (kitchen) detergents having the formulations shown in Table 5 were prepared by a conventional method. The evaluation results are shown in Table 5. As is clear from Table 5, Examples 7 to 9 of the present invention were superior to Comparative Example 3 in all the points of use (tightness and bulkiness of skin such as fingers).
【００２３】[0023]
【表５】 [Table 5]
【００２４】[0024]
【発明の効果】以上記載のとおり、本発明は、手指等の
皮膚のかさかさ感、つっぱり感が少ないという点で使用
感の良好な洗浄剤組成物を提供するものである。Industrial Applicability As described above, the present invention provides a detergent composition having a good feeling in use in that the bulkiness and tightness of the skin such as fingers are small.
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.5 識別記号 庁内整理番号 ＦＩ 技術表示箇所 //(Ｃ１１Ｄ 10/02 1:04 1:12 1:34 1:88 7:26） ─────────────────────────────────────────────────── ─── Continuation of the front page (51) Int.Cl. 5 Identification code Office reference number FI technical display area // (C11D 10/02 1:04 1:12 1:34 1:88 7:26)
Claims (4)
と、両性界面活性剤の一種又は二種以上と、ポリオキシ
プロピレンブチルエーテル及びポリオキシエチレンポリ
オキシプロピレンブチルエーテルの群から選択される一
種又は二種以上とを含有することを特徴とする洗浄剤組
成物。1. An anionic surfactant, one or more, an amphoteric surfactant, one or more, and one or two selected from the group of polyoxypropylene butyl ether and polyoxyethylene polyoxypropylene butyl ether. A cleaning composition comprising at least one species.
がカルボキシル基、硫酸エステル基、スルホン酸基、リ
ン酸エステル基である請求項１記載の洗浄剤組成物。2. The detergent composition according to claim 1, wherein the hydrophilic anion portion of the anionic surfactant is a carboxyl group, a sulfuric acid ester group, a sulfonic acid group or a phosphoric acid ester group.
ルボキシル基、スルホン酸基、リン酸エステル基である
請求項１記載の洗浄剤組成物。3. The detergent composition according to claim 1, wherein the hydrophilic anion portion of the amphoteric surfactant is a carboxyl group, a sulfonic acid group or a phosphoric acid ester group.
びポリオキシエチレンポリオキシプロピレンブチルエー
テルのオキシエチレン基付加モル数が０から４５、オキ
シプロピレン基付加モル数が２から６０である請求項１
記載の洗浄剤組成物。4. The number of moles of oxyethylene group addition of polyoxypropylene butyl ether and polyoxyethylene polyoxypropylene butyl ether is 0 to 45, and the number of moles of oxypropylene group addition is 2 to 60.
The cleaning composition described.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3356951A JPH06100894A (en) | 1991-12-24 | 1991-12-24 | Detergent composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3356951A JPH06100894A (en) | 1991-12-24 | 1991-12-24 | Detergent composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH06100894A true JPH06100894A (en) | 1994-04-12 |
Family
ID=18451601
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP3356951A Pending JPH06100894A (en) | 1991-12-24 | 1991-12-24 | Detergent composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH06100894A (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5786319A (en) * | 1995-07-18 | 1998-07-28 | Diversey Lever, Inc. | Concentrated aqueous degreasing cleanser |
| JP2002302425A (en) * | 2001-04-02 | 2002-10-18 | Kanebo Ltd | Intermediate treating agent for permanent wave |
| WO2003028672A1 (en) * | 2001-09-28 | 2003-04-10 | Shiseido Co., Ltd. | Base for external preparations for the skin and cosmetics containing the same |
| JP2007177164A (en) * | 2005-12-28 | 2007-07-12 | Kao Corp | Aqueous cleaning composition |
| US7625574B2 (en) | 2001-09-28 | 2009-12-01 | Shiseido Research Center | Skin treatment composition |
| JP2016088864A (en) * | 2014-10-31 | 2016-05-23 | ポーラ化成工業株式会社 | Skin cleanser |
| JP2016088865A (en) * | 2014-10-31 | 2016-05-23 | ポーラ化成工業株式会社 | Film removal composition |
| JP2017114805A (en) * | 2015-12-24 | 2017-06-29 | クラシエホームプロダクツ株式会社 | Cleanser composition |
-
1991
- 1991-12-24 JP JP3356951A patent/JPH06100894A/en active Pending
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5786319A (en) * | 1995-07-18 | 1998-07-28 | Diversey Lever, Inc. | Concentrated aqueous degreasing cleanser |
| JP2002302425A (en) * | 2001-04-02 | 2002-10-18 | Kanebo Ltd | Intermediate treating agent for permanent wave |
| WO2003028672A1 (en) * | 2001-09-28 | 2003-04-10 | Shiseido Co., Ltd. | Base for external preparations for the skin and cosmetics containing the same |
| US7625574B2 (en) | 2001-09-28 | 2009-12-01 | Shiseido Research Center | Skin treatment composition |
| US8153142B2 (en) | 2001-09-28 | 2012-04-10 | Shiseido Co., Ltd. | Skin treatment composition |
| JP2007177164A (en) * | 2005-12-28 | 2007-07-12 | Kao Corp | Aqueous cleaning composition |
| JP2016088864A (en) * | 2014-10-31 | 2016-05-23 | ポーラ化成工業株式会社 | Skin cleanser |
| JP2016088865A (en) * | 2014-10-31 | 2016-05-23 | ポーラ化成工業株式会社 | Film removal composition |
| JP2017114805A (en) * | 2015-12-24 | 2017-06-29 | クラシエホームプロダクツ株式会社 | Cleanser composition |
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