JPH06293630A - Cleansing agent composition having pearly luster - Google Patents
Cleansing agent composition having pearly lusterInfo
- Publication number
- JPH06293630A JPH06293630A JP10743793A JP10743793A JPH06293630A JP H06293630 A JPH06293630 A JP H06293630A JP 10743793 A JP10743793 A JP 10743793A JP 10743793 A JP10743793 A JP 10743793A JP H06293630 A JPH06293630 A JP H06293630A
- Authority
- JP
- Japan
- Prior art keywords
- composition
- surfactant
- alkyl
- general formula
- alkali metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 23
- 239000002932 luster Substances 0.000 title abstract description 10
- 239000003599 detergent Substances 0.000 title abstract 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 18
- 150000002148 esters Chemical class 0.000 claims abstract description 10
- 239000004094 surface-active agent Substances 0.000 claims abstract description 9
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 8
- 239000002253 acid Substances 0.000 claims abstract description 6
- 229910052783 alkali metal Inorganic materials 0.000 claims abstract description 6
- 150000001340 alkali metals Chemical group 0.000 claims abstract description 6
- 125000003342 alkenyl group Chemical group 0.000 claims abstract description 6
- 229910052700 potassium Inorganic materials 0.000 claims abstract description 4
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 4
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 3
- SUMDYPCJJOFFON-UHFFFAOYSA-N isethionic acid Chemical compound OCCS(O)(=O)=O SUMDYPCJJOFFON-UHFFFAOYSA-N 0.000 claims abstract 3
- -1 phosphate ester Chemical class 0.000 claims description 11
- 239000003945 anionic surfactant Substances 0.000 claims description 8
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 7
- 239000000194 fatty acid Substances 0.000 claims description 7
- 229930195729 fatty acid Natural products 0.000 claims description 7
- 125000004432 carbon atom Chemical group C* 0.000 claims description 6
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 5
- 229910019142 PO4 Inorganic materials 0.000 claims description 5
- 150000004665 fatty acids Chemical class 0.000 claims description 5
- 239000010452 phosphate Substances 0.000 claims description 5
- 239000000126 substance Substances 0.000 claims description 4
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 2
- 239000001257 hydrogen Substances 0.000 claims description 2
- 238000005187 foaming Methods 0.000 abstract description 17
- 239000002563 ionic surfactant Substances 0.000 abstract 4
- 229910003202 NH4 Inorganic materials 0.000 abstract 1
- 150000002500 ions Chemical class 0.000 abstract 1
- 238000011156 evaluation Methods 0.000 description 5
- 230000001815 facial effect Effects 0.000 description 5
- 239000011734 sodium Substances 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000010998 test method Methods 0.000 description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- 206010040880 Skin irritation Diseases 0.000 description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 235000019864 coconut oil Nutrition 0.000 description 2
- 239000003240 coconut oil Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 239000006071 cream Substances 0.000 description 2
- ANLFRXGAWNYDEJ-UHFFFAOYSA-L disodium;ethyl phosphate Chemical compound [Na+].[Na+].CCOP([O-])([O-])=O ANLFRXGAWNYDEJ-UHFFFAOYSA-L 0.000 description 2
- 230000036556 skin irritation Effects 0.000 description 2
- 231100000475 skin irritation Toxicity 0.000 description 2
- 241000251468 Actinopterygii Species 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical class CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- FPVVYTCTZKCSOJ-UHFFFAOYSA-N Ethylene glycol distearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCOC(=O)CCCCCCCCCCCCCCCCC FPVVYTCTZKCSOJ-UHFFFAOYSA-N 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000004166 Lanolin Chemical class 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- MEESPVWIOBCLJW-KTKRTIGZSA-N [(z)-octadec-9-enyl] dihydrogen phosphate Chemical compound CCCCCCCC\C=C/CCCCCCCCOP(O)(O)=O MEESPVWIOBCLJW-KTKRTIGZSA-N 0.000 description 1
- LLMKYCFOJYMFAA-UHFFFAOYSA-N [Na].C(CCCCCCCCCCC)(=O)OCC Chemical compound [Na].C(CCCCCCCCCCC)(=O)OCC LLMKYCFOJYMFAA-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 229960003237 betaine Drugs 0.000 description 1
- 229940073609 bismuth oxychloride Drugs 0.000 description 1
- 229920006317 cationic polymer Polymers 0.000 description 1
- HEUAXSYUYZUAJZ-UHFFFAOYSA-L dipotassium;ethyl phosphate Chemical compound [K+].[K+].CCOP([O-])([O-])=O HEUAXSYUYZUAJZ-UHFFFAOYSA-L 0.000 description 1
- QSLLXQPOVJSDAY-UHFFFAOYSA-L dipotassium;tetradecyl phosphate Chemical compound [K+].[K+].CCCCCCCCCCCCCCOP([O-])([O-])=O QSLLXQPOVJSDAY-UHFFFAOYSA-L 0.000 description 1
- YVIGPQSYEAOLAD-UHFFFAOYSA-L disodium;dodecyl phosphate Chemical compound [Na+].[Na+].CCCCCCCCCCCCOP([O-])([O-])=O YVIGPQSYEAOLAD-UHFFFAOYSA-L 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 125000004494 ethyl ester group Chemical group 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- ZUVCYFMOHFTGDM-UHFFFAOYSA-N hexadecyl dihydrogen phosphate Chemical compound CCCCCCCCCCCCCCCCOP(O)(O)=O ZUVCYFMOHFTGDM-UHFFFAOYSA-N 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 description 1
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 description 1
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 description 1
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 description 1
- 230000001939 inductive effect Effects 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- 229940039717 lanolin Drugs 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- BWOROQSFKKODDR-UHFFFAOYSA-N oxobismuth;hydrochloride Chemical compound Cl.[Bi]=O BWOROQSFKKODDR-UHFFFAOYSA-N 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 229920002545 silicone oil Chemical class 0.000 description 1
- 238000013112 stability test Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
Landscapes
- Cosmetics (AREA)
- Detergent Compositions (AREA)
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は、皮膚に対する作用が温
和で、優れた起泡力を有し、安定性の良好なパール光沢
を有する洗顔料組成物に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a face wash composition having a mild action on the skin, an excellent foaming power, and a pearly luster with good stability.
【０００２】[0002]
【従来の技術及び発明が解決しようとする課題】従来、
洗顔剤用の界面活性剤として、アルキル硫酸塩，ポリオ
キシエチレンアルキルエーテル硫酸エステル塩及びα−
オレフィンスルホン酸塩などのアニオン界面活性剤が広
く使われている。しかし、これらアニオン界面活性剤
は、程度の差はあるがいずれも皮膚刺激性を誘発すると
いう欠点を有している。2. Description of the Related Art Conventionally, the problems to be solved by the invention
Alkyl sulfates, polyoxyethylene alkyl ether sulfates and α-
Anionic surfactants such as olefin sulfonates are widely used. However, all of these anionic surfactants have the drawback of inducing skin irritation to varying degrees.
【０００３】また従来より、高級感の付与を目的に、天
然の魚燐箔を配合することや、オキシ塩化ビスマス，雲
母やチタン等のパール系顔料を配合すること等が知られ
ているが、原料が高価，耐光性や安全性に問題がある，
保存中にパール剤が沈降する等種々の欠点を有してい
る。また、エチレングリコールジステアレートはパール
光沢剤として広く使用されているが、４０〜５０℃程度
の温度で溶融溶解し、外観を著しく損なう等の欠点を有
している。Further, it has been conventionally known to add natural fish phosphorus foil or to add pearl pigments such as bismuth oxychloride, mica and titanium for the purpose of imparting a high-class feeling. Raw materials are expensive, there are problems with light resistance and safety,
It has various drawbacks such as the pearlescent agent settling during storage. Further, although ethylene glycol distearate is widely used as a pearly luster agent, it has a drawback that it melts and dissolves at a temperature of about 40 to 50 ° C. and significantly impairs the appearance.
【０００４】そこで本発明者らは上記の事情に鑑み、鋭
意研究した結果、特定の脂肪酸組成を有するエチレング
リコールジ脂肪酸エステルと、イセチオネート型陰イオ
ン界面活性剤と、リン酸エステル型陰イオン界面活性剤
または両性リン酸エステル型界面活性剤とを含有する洗
顔剤組成物が、皮膚に対する作用が温和で、優れた起泡
力を有し、安定性の良好なパール光沢を有する洗顔料組
成物となることを見出し、本発明を完成した。In view of the above circumstances, the inventors of the present invention have conducted extensive studies and as a result, have found that ethylene glycol difatty acid ester having a specific fatty acid composition, an isethionate-type anionic surfactant, and a phosphate ester-type anionic surfactant. A facial cleanser composition containing an agent or an amphoteric phosphate-type surfactant, has a mild action on the skin, has an excellent foaming power, and has a stable pearly luster cleansing composition. The present invention has been completed and the present invention has been completed.
【０００５】即ち、本発明は皮膚に対する作用が温和
で、優れた起泡力を有し、安定性の良好なパール光沢を
有する洗顔料組成物を提供することを目的とするもので
ある。That is, an object of the present invention is to provide a face wash composition having a mild action on the skin, an excellent foaming power, and a stable pearly luster.
【０００６】[0006]
【課題を解決するための手段】上記目的を達成する本発
明は、脂肪酸組成がＣ14が２０〜８０％、Ｃ16が０〜８
０％、Ｃ18が０〜８０％、ただしＣ16とＣ18の合計量が
２０〜８０％のエチレングリコールジ脂肪酸エステル
と、一般式（Ａ）According to the present invention for achieving the above object, the fatty acid composition is such that C 14 is 20 to 80% and C 16 is 0 to 8.
Ethylene glycol difatty acid ester of 0%, C 18 is 0 to 80%, but the total amount of C 16 and C 18 is 20 to 80%, and general formula (A)
【化４】 （式中、Ｒは炭素数７〜１９のアルキル基またはアルケ
ニル基、Ｍはアルカリ金属，ＮＨ4 又はアルカノールア
ンモニウムイオンを示す。）で表されるイセチオネート
型陰イオン界面活性剤と、一般式（Ｂ）[Chemical 4] (Wherein R represents an alkyl or alkenyl group having 7 to 19 carbon atoms, M represents an alkali metal, NH 4 or alkanol ammonium ion), and an isethionate-type anionic surfactant represented by the general formula (B )
【化５】 （式中、Ｒは炭素数１０〜１８のアルキル基またはアル
ケニル基を表す。Ｂ1 は水素又はＮａ，Ｋ，ＮＨ4 ，も
しくはアルカノールアンモニウムイオンを表す。）で表
されるリン酸エステル型陰イオン界面活性剤または、一
般式（Ｃ）[Chemical 5] (In the formula, R represents an alkyl group or an alkenyl group having 10 to 18 carbon atoms. B 1 represents hydrogen or Na, K, NH 4 , or an alkanol ammonium ion.) Surfactant or general formula (C)
【化６】 （式中、Ｒは炭素数１０〜１８のアルキル基、Ｍはアル
カリ金属を表す。）で表される両性リン酸エステル型界
面活性剤とを含有することを特徴とする、パール光沢を
有する洗顔料組成物である。[Chemical 6] (Wherein R represents an alkyl group having 10 to 18 carbon atoms, and M represents an alkali metal), and an amphoteric phosphate ester type surfactant is contained. It is a food composition.
【０００７】本発明で使用する、エチレングリコールジ
脂肪酸エステルの配合量は、一般的には３〜２０重量％
であり、好ましくは７〜１３重量％である。配合量が３
重量％未満では、良好で安定なパール光沢が得られにく
く、２０重量％を超えると起泡力が劣る傾向がある。The amount of ethylene glycol difatty acid ester used in the present invention is generally 3 to 20% by weight.
And preferably 7 to 13% by weight. Compounding amount is 3
When it is less than 20% by weight, it is difficult to obtain a good and stable pearly luster, and when it exceeds 20% by weight, the foaming power tends to be poor.
【０００８】本発明における前記一般式（Ａ）で表され
るイセチオネート型陰イオン界面活性剤としては、ヤシ
油脂肪酸エチルエステルスルホン酸ナトリウム（ＹＳ−
Ｎａと略記する）、ラウリン酸エチルエステルスルホン
酸ナトリウム（ＬＳ−Ｎａと略記する）、ヤシ油脂肪酸
エチルエステルスルホン酸トリエタノールアミン（ＹＳ
−Ｔと略記する）等が好ましい。The isethionate-type anionic surfactant represented by the general formula (A) in the present invention includes sodium coconut oil fatty acid ethyl ester sulfonate (YS-).
Na), sodium lauric acid ethyl ester sulfonate (abbreviated as LS-Na), coconut oil fatty acid ethyl ester sulfonic acid triethanolamine (YS)
(Abbreviated as -T) and the like are preferable.
【０００９】本発明における前記一般式（Ｂ）で表され
るリン酸エステル型陰イオン界面活性剤としては、ラウ
リルリン酸ナトリウム，ミリスチルリン酸カリウム，パ
ルミチルリン酸アンモニウム，オレイルリン酸トリエタ
ノールアミン等が好ましい。As the phosphoric acid ester type anionic surfactant represented by the general formula (B) in the present invention, sodium lauryl phosphate, potassium myristyl phosphate, ammonium palmityl phosphate, triethanolamine oleyl phosphate and the like are preferable. .
【００１０】本発明における前記一般式（Ｃ）で表され
る両性リン酸エステル型界面活性剤としては、２−（Ｎ
−（２−ヒドロキシテトラドデシル）−Ｎ−メチルアミ
ノ）エチルリン酸ナトリウム，２−（Ｎ−（２−ヒドロ
キシドデシル）−Ｎ−メチルアミノ）エチルリン酸カリ
ウム，２−（Ｎ−（２−ヒドロキシヘキサデシル）−Ｎ
−メチルアミノ）エチルリン酸カリウム，２−（Ｎ−
（２−ヒドロキシオクタデシル）−Ｎ−メチルアミノ）
エチルリン酸ナトリウム，２−（Ｎ−（２−ヒドロキシ
エイコシル）−Ｎ−メチルアミノ）エチルリン酸カリウ
ム等がある。The amphoteric phosphate ester type surfactant represented by the general formula (C) in the present invention includes 2- (N
-(2-Hydroxytetradodecyl) -N-methylamino) ethyl phosphate sodium, 2- (N- (2-hydroxydodecyl) -N-methylamino) ethyl phosphate potassium, 2- (N- (2-hydroxyhexadecyl) ) -N
-Methylamino) ethyl phosphate potassium, 2- (N-
(2-hydroxyoctadecyl) -N-methylamino)
Examples include sodium ethyl phosphate, potassium 2- (N- (2-hydroxyeicosyl) -N-methylamino) ethyl phosphate, and the like.
【００１１】本発明の洗顔料組成物の成分である前記一
般式（Ａ），（Ｂ）または（Ｃ）の界面活性剤の配合量
は、一般式（Ａ）は９〜３０重量％、（Ｂ）または
（Ｃ）は１〜１５重量％、ただし一般式（Ａ）と（Ｂ）
または（Ｃ）の合計量は洗顔料組成物全量中１０〜４５
重量％が好ましい。一般式（Ａ）と（Ｂ）または（Ｃ）
の合計量が１０重量％未満では、充分な起泡力が得られ
にくく、４５重量％を超えると均一で安定な組成物を得
ることが困難となる。The amount of the surfactant represented by the general formula (A), (B) or (C) as a component of the facial cleansing composition of the present invention is 9 to 30% by weight in the general formula (A), B) or (C) is 1 to 15% by weight, provided that the general formulas (A) and (B)
Alternatively, the total amount of (C) is 10 to 45 in the total amount of the face wash composition.
Weight percent is preferred. General formula (A) and (B) or (C)
If the total amount is less than 10% by weight, it is difficult to obtain sufficient foaming power, and if it exceeds 45% by weight, it becomes difficult to obtain a uniform and stable composition.
【００１２】本発明のパール状光沢を有する洗顔料は、
液状、ジェル状、クリーム状に適用されるが、特にクリ
ーム状において本発明の効果が充分発揮される。The face wash having pearly luster of the present invention is
It is applied in a liquid form, a gel form, or a cream form, and the effect of the present invention is sufficiently exhibited particularly in the cream form.
【００１３】尚、本発明の洗顔料組成物には、上記必須
成分の他に、洗顔料組成物に常用されている成分や、添
加剤を配合することも可能である。例えば、高級アルコ
ール、シリコン油、ラノリン誘導体、蛋白誘導体、ポリ
エチレングリコールの脂肪酸エステル類等の油性成分、
脂肪酸アルカノールアミド、ポリオキシエチレンアルキ
ルエーテル及びアルキルアミンオキシド等の非イオン性
界面活性剤、アルキルアミドプロピルベタイン等の両性
界面活性剤、ヒドロキシプロピルメチルセルロース、ヒ
ドロキシエチルセルロース等の水溶性高分子、カチオン
性高分子〔ポリマーＪＲ（ユニオンカーバイドコーポレ
ーション社製）、ポリコートＮＨ（ヘンケル社製）マー
コート５５０（メルク社）、ガフカット７５５Ｎ（ＧＡ
Ｆ社製）等〕、殺菌剤、酸化防止剤、紫外線吸収剤、ｐ
Ｈ調整剤、色素及び香料等を、本発明の効果を損なわな
い範囲で適宜配合できる。In addition to the above-mentioned essential components, the facial cleansing composition of the present invention may contain components or additives that are commonly used in facial cleansing compositions. For example, higher alcohol, silicone oil, lanolin derivative, protein derivative, oily component such as fatty acid ester of polyethylene glycol,
Nonionic surfactants such as fatty acid alkanolamides, polyoxyethylene alkyl ethers and alkylamine oxides, amphoteric surfactants such as alkylamidopropyl betaine, water-soluble polymers such as hydroxypropylmethyl cellulose and hydroxyethyl cellulose, cationic polymers [Polymer JR (Union Carbide Corporation), Polycoat NH (Henkel) Mercoat 550 (Merck), Gaff Cut 755N (GA
Company F), etc.], bactericide, antioxidant, ultraviolet absorber, p
H regulators, dyes, fragrances and the like can be appropriately added within a range that does not impair the effects of the present invention.
【００１４】[0014]
【実施例】次に実施例によって本発明を更に詳細に説明
する。なお、効果の測定は以下の評価法によった。The present invention will be described in more detail with reference to examples. The effect was measured by the following evaluation method.
【００１５】（１）泡立ち試験法 ロスマイルス試験法に準じて起泡力を測定した。但し、
試料は２％水溶液（ＣａＣＯ3 ５０ｐｐｍ人工硬水使
用）で温度４０℃である。 評価記号 評価基準 ◎：泡立ちが極めて良好、起泡力２５０ｍｍ以上 ○：泡立ちが良好、起泡力２１０ｍｍ以上，２５０ｍｍ
未満 △：泡立ちが普通、起泡力１７０ｍｍ以上、２１０ｍｍ
未満 ×：泡立ちが不良、起泡力１７０ｍｍ未満(1) Foaming test method The foaming force was measured according to the Loss Miles test method. However,
The sample is a 2% aqueous solution (using CaCO 3 50 ppm artificial hard water) at a temperature of 40 ° C. Evaluation symbol Evaluation criteria ◎: Very good foaming, foaming power of 250 mm or more ○: Good foaming, foaming power of 210 mm or more, 250 mm
Less than Δ: Foaming is normal, foaming power is 170 mm or more, 210 mm
Less than x: Poor foaming, foaming power less than 170 mm
【００１６】（２）手荒れ試験法（皮膚刺激性） 各試料につき、男女各５名、合計１０名のパネラーを用
い、左右どちらか一方の手を、試料濃度５％、温度３５
℃の水溶液に、他方の手を同温度の水に１０分間浸漬す
る操作を１日当たり２回、２日間続けて行い、左右の手
の肌の荒れ状態の差を肉眼で判定した。 評価記号 評価基準 ◎：手荒れ性著しく弱い １０人中０〜１名 ○：手荒れ性やや弱い １０人中２〜４名 △：手荒れ性やや強い １０人中５〜７名 ×：手荒れ性著しく強い １０人中８〜１０名(2) Hand roughness test method (skin irritation) For each sample, 5 male and 5 female panelists, totaling 10 persons, using one of the left and right hands, sample concentration 5%, temperature 35
An operation of immersing the other hand in water having the same temperature for 10 minutes in an aqueous solution at 0 ° C. was performed twice a day for two consecutive days, and the difference between the rough skin conditions of the left and right hands was visually determined. Evaluation symbol Evaluation criteria ◎: Hand roughness is extremely weak 0 to 1 out of 10 ○: Hand roughness is slightly weak 2 to 4 out of 10 △: Hand roughness is slightly strong 5 to 7 out of 10 ×: Hand roughness is extremely strong 10 8 to 10 people
【００１７】（３）保存安定性試験 温度４５℃の恒温室に放置し、パール状外観の有無（日
数）を観察した（肉眼にて判定した）。(3) Storage stability test The sample was left in a thermostatic chamber at a temperature of 45 ° C., and the presence or absence (number of days) of a pearly appearance was observed (visually determined).
【００１８】実施例１〜６、比較例１〜４ 表１及び表２に示す配合組成物のパール光沢を有する洗
顔料組成物を通常の方法で調整し、上記試験を行い表３
にその結果を示した。Examples 1 to 6 and Comparative Examples 1 to 4 The face wash compositions having a pearly luster of the compounding compositions shown in Tables 1 and 2 were prepared by the usual method, and the above test was conducted.
The results are shown in.
【００１９】[0019]
【表１】 [Table 1]
【００２０】[0020]
【表２】 [Table 2]
【００２１】[0021]
【表３】 [Table 3]
【００２２】実施例１〜６より明らかなように、本発明
の成分を用いた洗顔剤組成物はいずれも優れた性能を示
していた。一方、必須成分のいずれかを欠いた比較例１
〜４は、いずれも劣った性能を示し、本発明の目的を達
成出来なかった。As is clear from Examples 1 to 6, all the facial cleansing compositions using the components of the present invention showed excellent performance. On the other hand, Comparative Example 1 lacking any of the essential components
Nos. 4 to 4 all showed inferior performance and could not achieve the object of the present invention.
【００２３】[0023]
【発明の効果】以上記載のごとく、本発明が、皮膚に対
する作用が温和で、優れた起泡力を有し、安定性の良好
なパール光沢を有する洗顔料組成物を提供することは明
らかである。As described above, it is apparent that the present invention provides a face wash composition having a mild action on the skin, an excellent foaming power and a pearly luster with good stability. is there.
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.5 識別記号 庁内整理番号 ＦＩ 技術表示箇所 Ｃ１１Ｄ 1:28 1:34） ─────────────────────────────────────────────────── ─── Continuation of the front page (51) Int.Cl. 5 Identification code Office reference number FI technical display location C11D 1:28 1:34)
Claims (1)
が０〜８０％、Ｃ18が０〜８０％、ただしＣ16とＣ18の
合計量が２０〜８０％のエチレングリコールジ脂肪酸エ
ステルと、 一般式（Ａ） 【化１】 （式中、Ｒは炭素数７〜１９のアルキル基またはアルケ
ニル基、Ｍはアルカリ金属，ＮＨ4 又はアルカノールア
ンモニウムイオンを示す。）で表されるイセチオネート
型陰イオン界面活性剤と、 一般式（Ｂ） 【化２】 （式中、Ｒは炭素数１０〜１８のアルキル基またはアル
ケニル基を表す。Ｂ1 は水素又はＮａ，Ｋ，ＮＨ4 ，も
しくはアルカノールアンモニウムイオンを表す。）で表
されるリン酸エステル型陰イオン界面活性剤または、 一般式（Ｃ） 【化３】 （式中、Ｒは炭素数１０〜１８のアルキル基、Ｍはアル
カリ金属を表す。）で表される両性リン酸エステル型界
面活性剤とを含有することを特徴とする、パール光沢を
有する洗顔料組成物。1. A fatty acid composition having a C 14 content of 20 to 80% and a C 16 content.
Is 0 to 80%, C 18 is 0 to 80%, but the total amount of C 16 and C 18 is 20 to 80%, and an ethylene glycol difatty acid ester of the general formula (A) (Wherein R represents an alkyl group or alkenyl group having 7 to 19 carbon atoms, M represents an alkali metal, NH 4 or alkanol ammonium ion), and an isethionate type anionic surfactant represented by the general formula (B ) [Chemical 2] (In the formula, R represents an alkyl group or an alkenyl group having 10 to 18 carbon atoms. B 1 represents hydrogen or Na, K, NH 4 , or an alkanol ammonium ion.) Surfactant or general formula (C) (Wherein R represents an alkyl group having 10 to 18 carbon atoms, and M represents an alkali metal), and an amphoteric phosphate ester type surfactant is contained. Composition.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10743793A JP3119967B2 (en) | 1993-04-08 | 1993-04-08 | Facial cleansing composition having pearl luster |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10743793A JP3119967B2 (en) | 1993-04-08 | 1993-04-08 | Facial cleansing composition having pearl luster |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH06293630A true JPH06293630A (en) | 1994-10-21 |
| JP3119967B2 JP3119967B2 (en) | 2000-12-25 |
Family
ID=14459130
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP10743793A Expired - Fee Related JP3119967B2 (en) | 1993-04-08 | 1993-04-08 | Facial cleansing composition having pearl luster |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3119967B2 (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1996021424A3 (en) * | 1994-12-30 | 1996-10-10 | Rhone Poulenc Inc | Mild cold pearlizing concentrates |
| JP2002544325A (en) * | 1999-05-07 | 2002-12-24 | コグニス・ドイチュラント・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツング・ウント・コムパニー・コマンディットゲゼルシャフト | Pearl brightener concentrate |
| US7268106B2 (en) * | 2002-06-14 | 2007-09-11 | Kao Corporation | Aqueous liquid detergent composition |
-
1993
- 1993-04-08 JP JP10743793A patent/JP3119967B2/en not_active Expired - Fee Related
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1996021424A3 (en) * | 1994-12-30 | 1996-10-10 | Rhone Poulenc Inc | Mild cold pearlizing concentrates |
| US5925604A (en) * | 1994-12-30 | 1999-07-20 | Rhodia Inc. | Mild cold pearlizing concentrates |
| JP2002544325A (en) * | 1999-05-07 | 2002-12-24 | コグニス・ドイチュラント・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツング・ウント・コムパニー・コマンディットゲゼルシャフト | Pearl brightener concentrate |
| US7268106B2 (en) * | 2002-06-14 | 2007-09-11 | Kao Corporation | Aqueous liquid detergent composition |
Also Published As
| Publication number | Publication date |
|---|---|
| JP3119967B2 (en) | 2000-12-25 |
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