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JPH07144958A - Production of pottery having continuous pore by utilizing waste - Google Patents

Production of pottery having continuous pore by utilizing waste

Info

Publication number
JPH07144958A
JPH07144958A JP5311058A JP31105893A JPH07144958A JP H07144958 A JPH07144958 A JP H07144958A JP 5311058 A JP5311058 A JP 5311058A JP 31105893 A JP31105893 A JP 31105893A JP H07144958 A JPH07144958 A JP H07144958A
Authority
JP
Japan
Prior art keywords
sewage sludge
weight
utilizing waste
pottery
production
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP5311058A
Other languages
Japanese (ja)
Inventor
Shunichi Takahara
俊一 高原
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
OZAWA CONCRETE KOGYO KK
Original Assignee
OZAWA CONCRETE KOGYO KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by OZAWA CONCRETE KOGYO KK filed Critical OZAWA CONCRETE KOGYO KK
Priority to JP5311058A priority Critical patent/JPH07144958A/en
Publication of JPH07144958A publication Critical patent/JPH07144958A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/62204Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products using waste materials or refuse
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
    • C04B33/132Waste materials; Refuse; Residues
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
    • C04B33/132Waste materials; Refuse; Residues
    • C04B33/1324Recycled material, e.g. tile dust, stone waste, spent refractory material
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
    • C04B33/132Waste materials; Refuse; Residues
    • C04B33/135Combustion residues, e.g. fly ash, incineration waste
    • C04B33/1355Incineration residues
    • C04B33/1357Sewage sludge ash or slag
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/32Burning methods
    • C04B33/323Burning methods involving melting, fusion or softening
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/626Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
    • C04B35/62605Treating the starting powders individually or as mixtures
    • C04B35/62625Wet mixtures
    • C04B35/6263Wet mixtures characterised by their solids loadings, i.e. the percentage of solids
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B38/00Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00Technologies relating to the processing of minerals
    • Y02P40/60Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Dispersion Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Plasma & Fusion (AREA)
  • Physics & Mathematics (AREA)
  • Combustion & Propulsion (AREA)
  • Processing Of Solid Wastes (AREA)
  • Compositions Of Oxide Ceramics (AREA)

Abstract

PURPOSE:To produce a tile or a pottery block product having continuous pores by effectively utilizing waste such as slag obtd. by melting sewage sludge, ash obtd. by incinerating sewage sludge and sherd. CONSTITUTION:A mixture of 80-10wt.% slag obtd. by melting sewage sludge and/or ash obtd. by incinerating sewage sludge with 60-10wt.% of sherd, 30-10wt.% binder and 7-3wt.% water is molded and fired.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、下水道汚泥溶融スラグ
や下水道汚泥焼却灰やセルベン等の廃棄物を有効に再利
用し、連続空隙を有するタイルや陶製ブロック製品を作
製する、廃棄物利用による連続空隙を有する陶磁器の製
造方法に関する。
BACKGROUND OF THE INVENTION The present invention relates to the utilization of waste such as sewage sludge molten slag, waste sewage sludge incineration ash, and cerben to effectively produce tiles and ceramic block products having continuous voids. The present invention relates to a method for manufacturing a ceramic porcelain having continuous voids.

【0002】[0002]

【従来の技術】従来より陶磁器製品は、その用途に応じ
て厳選された粘土に陶石や長石、珪石を加えてなり、1
250℃以上の温度で焼成されるものであった。そし
て、この焼成温度を低下させるために、粘土に流紋石を
混合したり、或いは粘土に抗火石及びガラスカレットを
加えて素地とし、緻密なタイルやレンガとすることが一
般的である。
2. Description of the Related Art Ceramic products have heretofore been made by adding clay, feldspar, and silica stone to clay carefully selected according to their use.
It was baked at a temperature of 250 ° C. or higher. In order to lower the firing temperature, it is common to mix rhyolite with clay, or to add anti-firestone and glass cullet to clay to form a base material to form a dense tile or brick.

【0003】[0003]

【発明が解決しようとする課題】しかしながら、従来の
陶磁器製品は、前述のような限られた原材料を使用する
ため、国内資源は減少傾向にあり、国外からの輸入が増
加しつつあり、またコストが比較的高くならざるを得な
かった。
However, since the conventional ceramic products use the limited raw materials as described above, domestic resources tend to decrease, imports from abroad are increasing, and cost is low. Had to be relatively high.

【0004】一方、下水道汚泥溶融スラグや下水道汚泥
焼却灰は、他のスラグ(製鉄関連)、焼却灰(ゴミ処理
場)と同様、窯業原料としての再利用化促進が図られず
停滞状態にある。特に下水道汚泥溶融スラグや下水道汚
泥焼却灰は産出時期や場所、プラント毎に組成が一定で
はないため物性値が不画一であり、しかも鉄分が多く含
まれて焼成温度が低い。したがって、窯業原料としての
利用価値が見出せず再利用化が遅れ、処分方法として埋
戻し、又は土木用資材、コンクリート製品への利用など
二次加工せずに建設資材の一部分に使用されているに過
ぎず、大部分は処分に苦慮している現況である。
On the other hand, the sewage sludge molten slag and the sewage sludge incineration ash are stagnant because they cannot be promoted to be reused as a ceramic raw material like other slag (steel making-related) and incineration ash (garbage treatment plant). . In particular, the sewage sludge molten slag and the sewage sludge incineration ash have inconsistent physical properties because the composition is not constant at each production time, place, and plant, and moreover, they contain a large amount of iron and have a low firing temperature. Therefore, the utility value as a ceramic raw material is not found and the reuse is delayed, and it is used as a part of the construction material without back-processing as a disposal method or secondary processing such as use for civil engineering materials and concrete products. The current situation is that most of them are suffering from disposal.

【0005】[0005]

【課題を解決するための手段】本発明は上記に鑑み提案
されたもので、下水道汚泥溶融スラグ及び/又は下水道
汚泥焼却灰80〜10重量%と、セルベン60〜10重
量%と、粘結材30〜10重量%と、水分7〜3重量%
とを混合し、成型、焼成することを特徴とする廃棄物利
用による連続空隙を有する陶磁器の製造方法に関するも
のである。
SUMMARY OF THE INVENTION The present invention has been proposed in view of the above, and comprises 80 to 10% by weight of sewage sludge molten slag and / or sewage sludge incineration ash, 60 to 10% by weight of cerben, and a binder. 30 to 10% by weight and water 7 to 3% by weight
The present invention relates to a method for producing a ceramic porcelain having continuous voids by utilizing wastes, which comprises mixing, molding, and firing.

【0006】上記した本発明に用いる下水道汚泥溶融ス
ラグ、下水道汚泥焼却灰は、前述のように産業廃棄物と
して廃棄されていた。このような下水道汚泥溶融スラ
グ、下水道汚泥焼却灰を80〜10重量%添加するた
め、廃棄物を減量化することができる。この下水道汚泥
溶融スラグ、下水道汚泥焼却灰が80重量%より多くな
ると焼成時の物性変化が一定でないために生産管理が困
難となり、品質の安定化を図ることができない。また、
10重量%より少なくなると品質の安定化は図り易い
が、廃棄物の減量化はあまり期待できない。上記下水道
汚泥溶融スラグ、下水道汚泥焼却灰は粒径5mm以下の
ものを用いることが好ましい。
The above-mentioned sewage sludge molten slag and sewage sludge incineration ash used in the present invention have been discarded as industrial waste as described above. Since 80 to 10% by weight of such sewage sludge molten slag and sewage sludge incineration ash are added, the amount of waste can be reduced. If the content of the sewage sludge molten slag and the sewage sludge incineration ash is more than 80% by weight, the physical property change at the time of firing is not constant and the production control becomes difficult, and the quality cannot be stabilized. Also,
If the amount is less than 10% by weight, it is easy to stabilize the quality, but the reduction of the amount of waste cannot be expected so much. It is preferable to use the sewage sludge molten slag and the sewage sludge incineration ash having a particle size of 5 mm or less.

【0007】また、本発明に用いるセルベンは、碍石、
衛生陶器、タイル、瓦、レンガ等の廃材を破砕したもの
であり、60〜10重量%添加する。このセルベンが6
0重量%より多くなると品質の安定化は図り易いのでは
あるがその分だけ前記下水道汚泥溶融スラグ、下水道汚
泥焼却灰の添加量が低減して廃棄物の減量化が図れな
い。また、10重量%より少なくなると焼成温度が不安
定となって品質の安定化を図ることができない。上記セ
ルベンは粒径5mm以下のものを用いることが好まし
い。
Further, cerbene used in the present invention is porcelain,
Waste materials such as sanitary ware, tiles, roof tiles and bricks are crushed, and 60 to 10% by weight is added. This Selven is 6
If the amount is more than 0% by weight, it is easy to stabilize the quality, but the amount of the sewage sludge molten slag and the sewage sludge incineration ash is reduced correspondingly, and the amount of waste cannot be reduced. On the other hand, if it is less than 10% by weight, the firing temperature becomes unstable and the quality cannot be stabilized. It is preferable to use the selben having a particle diameter of 5 mm or less.

【0008】そして、上記各成分を粘結させる粘結材と
して粘土、長石、ガラス粉、ベントナイト、石灰、セリ
サイト、フライアッシュ等を30〜10重量%の範囲で
使用する。この場合、粘結材は30重量%より多くなる
と連続空隙の形成が困難となる。また、10重量%より
少なくなると粘結材としての効果が十分でなく製品特性
が得られない。上記粘結材は粒径1mm以下の粉末を用
いることが好ましい。
Clay, feldspar, glass powder, bentonite, lime, sericite, fly ash, etc. are used in the range of 30 to 10% by weight as a binder for binding the above components. In this case, if the binder is more than 30% by weight, it becomes difficult to form continuous voids. On the other hand, if it is less than 10% by weight, the effect as a binder is not sufficient and the product characteristics cannot be obtained. It is preferable to use a powder having a particle diameter of 1 mm or less as the binder.

【0009】上記3成分を素材原料とし、配合割合に応
じて秤量、混合し、さらに水分(化学糊の溶液)を7〜
3重量%添加して素地組成物とする。この素地組成物を
従来の陶磁器の製造方法と同様にプレス又は振動成型装
置を用いて成型し、1180〜1000℃の温度範囲で
焼成して所望の連続空隙を有する陶磁器を作製すること
ができる。
The above three components are used as raw materials, weighed and mixed according to the blending ratio, and the water content (chemical glue solution) is adjusted to 7 to 7.
A base composition is obtained by adding 3% by weight. This base composition can be molded by using a press or a vibration molding device in the same manner as in a conventional ceramics manufacturing method, and can be fired in a temperature range of 1180 to 1000 ° C to manufacture a ceramic having desired continuous voids.

【0010】[0010]

【実施例】【Example】

実施例;粒径3〜1mmの下水道汚泥溶融スラグ60重
量%と、粒径3〜1mmのセルベン25重量%と、粘結
材(セリサイト、粘土、石灰、ベントナイト)15重量
%とを混合し、水分4%を添加してプレス成型し、焼成
温度1170℃で焼成してブロック製品を得た。得られ
たブロック製品の物性値は、曲げ強度33.5kgf/
cm2 ,収縮率0.6%、空隙15〜10%、比重2.
5〜2.2の物性を有していた。
Example: Mixing 60% by weight of sewage sludge molten slag having a particle size of 3 to 1 mm, 25% by weight of cerben having a particle size of 3 to 1 mm, and 15% by weight of a binder (serisite, clay, lime, bentonite). , 4% of water was added, and the mixture was press-molded and fired at a firing temperature of 1170 ° C. to obtain a block product. The physical properties of the obtained block product are 33.5 kgf / bending strength.
cm 2 , shrinkage ratio 0.6%, voids 15 to 10%, specific gravity 2.
It had a physical property of 5 to 2.2.

【0011】以上本発明の実施例を示したが、本発明は
前記した実施例に限定されるものではなく、特許請求の
範囲に記載した構成を変更しない限りどのようにでも実
施することができる。
Although the embodiments of the present invention have been described above, the present invention is not limited to the above-mentioned embodiments and can be implemented in any manner as long as the configuration described in the claims is not changed. .

【0012】[0012]

【発明の効果】以上要するに本発明によれば、使用する
原材料である下水道汚泥溶融スラグ、下水道汚泥焼却
灰、セルベンが産業廃棄物であるため、廃棄物の再資源
化として有効で、廃棄物の減量化に貢献できる。
In summary, according to the present invention, since the raw materials used are sewage sludge molten slag, sewage sludge incineration ash, and cerben are industrial wastes, they are effective as resources for recycling wastes. It can contribute to weight reduction.

【0013】また、本発明は、生産設備として従来の設
備をそのまま使用することができるので、コストの低減
を図ることができ、実用的価値は極めて高いものとな
る。
Further, according to the present invention, since conventional equipment can be used as it is as production equipment, the cost can be reduced and the practical value is extremely high.

───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.6 識別記号 庁内整理番号 FI 技術表示箇所 B09B 3/00 303 D 303 L ─────────────────────────────────────────────────── ─── Continuation of the front page (51) Int.Cl. 6 Identification number Office reference number FI technical display location B09B 3/00 303 D 303L

Claims (1)

【特許請求の範囲】[Claims] 【請求項1】 下水道汚泥溶融スラグ及び/又は下水道
汚泥焼却灰80〜10重量%と、セルベン60〜10重
量%と、粘結材30〜10重量%と、水分7〜3重量%
とを混合し、成型、焼成することを特徴とする廃棄物利
用による連続空隙を有する陶磁器の製造方法。
1. Sewer sludge molten slag and / or sewage sludge incineration ash 80 to 10% by weight, selben 60 to 10% by weight, binder 30 to 10% by weight, and water 7 to 3% by weight.
A method for producing a ceramic porcelain having continuous voids by utilizing waste, characterized by mixing, and molding and firing.
JP5311058A 1993-11-18 1993-11-18 Production of pottery having continuous pore by utilizing waste Pending JPH07144958A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP5311058A JPH07144958A (en) 1993-11-18 1993-11-18 Production of pottery having continuous pore by utilizing waste

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP5311058A JPH07144958A (en) 1993-11-18 1993-11-18 Production of pottery having continuous pore by utilizing waste

Publications (1)

Publication Number Publication Date
JPH07144958A true JPH07144958A (en) 1995-06-06

Family

ID=18012611

Family Applications (1)

Application Number Title Priority Date Filing Date
JP5311058A Pending JPH07144958A (en) 1993-11-18 1993-11-18 Production of pottery having continuous pore by utilizing waste

Country Status (1)

Country Link
JP (1) JPH07144958A (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20010016559A (en) * 2000-12-20 2001-03-05 이성심 Tile products using sludge-burned ash
JP2002167262A (en) * 2000-11-27 2002-06-11 Ig Tech Res Inc Permeable block using asbestos-containing building material waste and sewage sludge incineration ash
KR20030065261A (en) * 2002-01-31 2003-08-06 주식회사 서울세라믹스 Tile Bonded Light-Weight Block Using Recycling Material
JP2005329400A (en) * 2004-04-22 2005-12-02 Daido Steel Co Ltd Method for stabilizing slag solidified product
KR101053658B1 (en) * 2010-12-10 2011-08-02 이현주 Plastic Brick Using Sewage Sludge Incineration Ash and Its Manufacturing Method
CN108840705A (en) * 2018-07-10 2018-11-20 黄河三角洲京博化工研究院有限公司 A kind of Yellow River Sand haydite and preparation method thereof

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002167262A (en) * 2000-11-27 2002-06-11 Ig Tech Res Inc Permeable block using asbestos-containing building material waste and sewage sludge incineration ash
KR20010016559A (en) * 2000-12-20 2001-03-05 이성심 Tile products using sludge-burned ash
KR20030065261A (en) * 2002-01-31 2003-08-06 주식회사 서울세라믹스 Tile Bonded Light-Weight Block Using Recycling Material
JP2005329400A (en) * 2004-04-22 2005-12-02 Daido Steel Co Ltd Method for stabilizing slag solidified product
KR101053658B1 (en) * 2010-12-10 2011-08-02 이현주 Plastic Brick Using Sewage Sludge Incineration Ash and Its Manufacturing Method
CN108840705A (en) * 2018-07-10 2018-11-20 黄河三角洲京博化工研究院有限公司 A kind of Yellow River Sand haydite and preparation method thereof

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