JPH08301740A - Stock solution for hydrogen peroxide-containing foamy aerosol cosmetic - Google Patents
Stock solution for hydrogen peroxide-containing foamy aerosol cosmeticInfo
- Publication number
- JPH08301740A JPH08301740A JP12916895A JP12916895A JPH08301740A JP H08301740 A JPH08301740 A JP H08301740A JP 12916895 A JP12916895 A JP 12916895A JP 12916895 A JP12916895 A JP 12916895A JP H08301740 A JPH08301740 A JP H08301740A
- Authority
- JP
- Japan
- Prior art keywords
- hydrogen peroxide
- hair
- agent
- stock solution
- aerosol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 title claims abstract description 96
- 239000000443 aerosol Substances 0.000 title claims abstract description 32
- 239000002537 cosmetic Substances 0.000 title abstract description 23
- 239000011550 stock solution Substances 0.000 title abstract description 14
- DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229960004585 etidronic acid Drugs 0.000 claims abstract description 9
- 239000006260 foam Substances 0.000 claims description 16
- 239000012141 concentrate Substances 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 abstract description 26
- 230000003472 neutralizing effect Effects 0.000 abstract description 17
- 239000007800 oxidant agent Substances 0.000 abstract description 9
- 239000000975 dye Substances 0.000 abstract description 3
- 239000004480 active ingredient Substances 0.000 abstract description 2
- 230000003647 oxidation Effects 0.000 abstract description 2
- 238000007254 oxidation reaction Methods 0.000 abstract description 2
- 239000000118 hair dye Substances 0.000 description 10
- 239000000203 mixture Substances 0.000 description 9
- 238000000354 decomposition reaction Methods 0.000 description 8
- 238000012360 testing method Methods 0.000 description 8
- 239000003381 stabilizer Substances 0.000 description 7
- 230000007797 corrosion Effects 0.000 description 6
- 238000005260 corrosion Methods 0.000 description 6
- 238000002474 experimental method Methods 0.000 description 6
- 230000001590 oxidative effect Effects 0.000 description 6
- CPJSUEIXXCENMM-UHFFFAOYSA-N phenacetin Chemical compound CCOC1=CC=C(NC(C)=O)C=C1 CPJSUEIXXCENMM-UHFFFAOYSA-N 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- 239000003915 liquefied petroleum gas Substances 0.000 description 5
- 239000003921 oil Substances 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 4
- 238000004043 dyeing Methods 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 3
- 238000002845 discoloration Methods 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 244000005700 microbiome Species 0.000 description 3
- 229960003893 phenacetin Drugs 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- 238000004061 bleaching Methods 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 230000009545 invasion Effects 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- 239000003755 preservative agent Substances 0.000 description 2
- 230000002335 preservative effect Effects 0.000 description 2
- 238000007789 sealing Methods 0.000 description 2
- 239000003352 sequestering agent Substances 0.000 description 2
- 239000002453 shampoo Substances 0.000 description 2
- 230000000087 stabilizing effect Effects 0.000 description 2
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- 206010013642 Drooling Diseases 0.000 description 1
- 239000004909 Moisturizer Substances 0.000 description 1
- 208000008630 Sialorrhea Diseases 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- LFYJSSARVMHQJB-QIXNEVBVSA-N bakuchiol Chemical compound CC(C)=CCC[C@@](C)(C=C)\C=C\C1=CC=C(O)C=C1 LFYJSSARVMHQJB-QIXNEVBVSA-N 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000004042 decolorization Methods 0.000 description 1
- 239000007854 depigmenting agent Substances 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940126534 drug product Drugs 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000005562 fading Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 230000007794 irritation Effects 0.000 description 1
- 239000008263 liquid aerosol Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 230000001333 moisturizer Effects 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 235000014593 oils and fats Nutrition 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- 238000010979 pH adjustment Methods 0.000 description 1
- 239000000825 pharmaceutical preparation Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000003380 propellant Substances 0.000 description 1
- 238000007788 roughening Methods 0.000 description 1
- 210000004761 scalp Anatomy 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Landscapes
- Cosmetics (AREA)
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は、パーマネントウェーブ
用中和剤、毛髪脱色剤、染毛剤の酸化剤等として使用さ
れる過酸化水素含有泡状エアゾール化粧料用原液に関す
る。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a hydrogen peroxide-containing foam aerosol cosmetics undiluted solution used as a neutralizing agent for permanent waves, a hair decolorizing agent, an oxidizing agent for hair dyes and the like.
【０００２】[0002]
【従来の技術】パーマネントウェーブ用中和剤、毛髪脱
色剤、染毛剤の酸化剤等は、過酸化水素の酸化作用によ
る機能を利用しており、パーマネントウェーブ用中和
剤、毛髪脱色剤、あるいは染毛剤の酸化剤としての用途
に応じて医薬部外品として配合量が許可されている最大
量６．０重量％までの過酸化水素を配合、調製した過酸
化水素含有化粧料が使用されている。2. Description of the Prior Art Neutralizing agents for permanent waves, hair decolorizing agents, oxidizing agents for hair dyes, etc. utilize the function of the oxidizing action of hydrogen peroxide. Alternatively, hydrogen peroxide-containing cosmetics prepared by blending hydrogen peroxide up to a maximum amount of 6.0% by weight, which is permitted as a quasi drug depending on the use of the hair dye as an oxidant, is used. Has been done.
【０００３】過酸化水素を配合、調製した化粧料のほと
んどは液状もしくはクリーム状であるため、特に直接毛
髪上に塗布するパーマネントウェーブ用中和剤や毛髪脱
色剤においては、毛髪への塗布量が分かりにくく、また
塗布むらが発生し易く、さらに垂れ落ちによる頭皮や顔
面等への悪影響を及ぼす等のことから、取り扱いには習
熟した技術が必要とされている。Most of the cosmetics prepared by blending hydrogen peroxide are liquid or creamy. Therefore, in the case of a permanent wave neutralizing agent or a hair decolorizing agent which is applied directly onto the hair, the amount applied to the hair is very small. Since it is difficult to understand, uneven application is likely to occur, and the dripping and the like have an adverse effect on the scalp, the face, and the like, a technique familiar with handling is required.
【０００４】また、パーマネントウェーブ用中和剤、毛
髪脱色剤、染毛剤の酸化剤等は、使用するたびごとに、
製品容器から専用の塗布容器等に小分けして利用してい
るため、容器口からの微生物の侵入による２字汚染が発
生し、酸化剤成分が分解することによる製剤の機能の低
下の問題もあった。In addition, a neutralizing agent for permanent wave, a hair decolorizing agent, an oxidizing agent for a hair dye, etc. are used each time they are used.
Since the product container is used by subdividing it into a dedicated coating container, etc., there is a problem that the function of the drug product deteriorates due to the decomposition of the oxidizer component due to the 2-character contamination caused by the invasion of microorganisms from the container mouth It was
【０００５】かかる実情に鑑み、本発明者らは、密閉性
を有することにより微生物の侵入による２字汚染の懸念
が無く、また泡状で使用することによる泡の大きさによ
って使用量を視覚的に認知し易く、かつ垂れ落ちが少な
く、しかも毛髪への塗布を均一に行なうことのできる泡
状エアゾール型の過酸化水素含有化粧料について、着目
した。In view of the above situation, the inventors of the present invention have no fear of two-character contamination due to the invasion of microorganisms due to the hermeticity, and the amount used can be visually determined depending on the size of the bubbles when used in the form of bubbles. Attention was paid to a foamy aerosol-type hydrogen peroxide-containing cosmetic composition which is easy to recognize, and which can be applied to hair evenly, with less drooling.
【０００６】しかしながら、エアゾール型のこの種の化
粧料は、当該化粧料中に含まれている過酸化水素が、温
度、ｐＨ、容器内の金属粉、微生物等によって容易に分
解するため、容器が膨張、破壊する危険性を有してい
る。特にエアゾール製剤の場合には一般のプラスチック
容器等とは異なり完全な密封性が得られるため、化粧料
中に含まれている過酸化水素の分解によって発生する酸
素が容器内の内圧の上昇を即座にもたらし、容器を破壊
させる危険性がより大きい。However, in this type of aerosol type cosmetics, hydrogen peroxide contained in the cosmetics is easily decomposed by temperature, pH, metal powder in the container, microorganisms, etc. There is a risk of expansion and destruction. Especially in the case of an aerosol formulation, unlike ordinary plastic containers, complete sealing is obtained, so oxygen generated by the decomposition of hydrogen peroxide contained in cosmetics immediately increases the internal pressure in the container. And the risk of destroying the container is greater.
【０００７】したがって、パーマネントウェーブ用中和
剤、毛髪用脱色剤、染毛剤の酸化剤等の調製の際には、
過酸化水素の分解を抑制するために、過酸化水素の安定
化剤、ｐＨ調整剤、金属イオン封鎖剤、保存剤等を配合
しなければならない。Therefore, when preparing a neutralizing agent for permanent wave, a decolorizing agent for hair, an oxidizing agent for a hair dye, etc.,
In order to suppress the decomposition of hydrogen peroxide, a stabilizer for hydrogen peroxide, a pH adjuster, a sequestering agent, a preservative and the like must be added.
【０００８】過酸化水素の安定化剤としてはフェナセチ
ンが有効であるが、これは水難溶性であるために水系の
製剤に対してはそのまま利用することができなく、例え
ば、油分及び非イオン界面活性剤と共に分散、乳化させ
たものが知られている（特公昭４７−３８９７３号公
報）。Although phenacetin is effective as a stabilizer for hydrogen peroxide, it cannot be used as it is for aqueous preparations because it is poorly soluble in water. For example, oil and nonionic surface active agents are used. It is known that the agent is dispersed and emulsified with the agent (Japanese Patent Publication No. 47-38973).
【０００９】また、この水難溶性のフェナセチンを安定
剤として配合した製剤においても、長期間の経過後には
微量とはいえ過酸化水素の分解が避けられないため、発
生したガスを逃がすための機構を設けた容器にする必要
があるとの指摘もある（特公平１−１１２８４号公
報）。In addition, even in the preparation containing the poorly water-soluble phenacetin as a stabilizer, decomposition of hydrogen peroxide is inevitable even after a long period of time, but a mechanism for releasing generated gas is provided. It is also pointed out that it is necessary to use the container provided (Japanese Patent Publication No. 11-11284).
【００１０】[0010]
【発明が解決しようとする課題】ところで、前述の特公
昭４７−３８９７３号公報にも記載されている通り、水
難溶性のフェナセチン等の安定化剤を油分及び非イオン
界面活性剤と共に分散、乳化させ、さらに化粧料に必要
な量の過酸化水素を含有させた製剤は、安定化剤の分
散、乳化のために多量の油分及び非イオン界面活性剤を
必要とすることから、常温においては殆ど流動性の無い
ゲル状態になる。By the way, as described in Japanese Patent Publication No. 47-38973, the stabilizing agent such as poorly water-soluble phenacetin is dispersed and emulsified together with an oil component and a nonionic surfactant. In addition, since a formulation containing hydrogen peroxide in an amount necessary for cosmetics requires a large amount of oil and a nonionic surfactant for dispersing and emulsifying the stabilizer, it is almost fluid at room temperature. It becomes a gel state with no property.
【００１１】したがって、クリーム状の製剤に調合する
等の場合には好都合であるが、常温下で缶内に充填する
ことが必要なエアゾール用原液としては利用し得ないの
が実情である。Therefore, although it is convenient when it is prepared into a cream-form preparation, it cannot be used as a stock solution for aerosol which needs to be filled in a can at room temperature.
【００１２】また、前述の特公平１−１１２８４号公報
に指摘されているように、長期経過において発生する微
量ガスを逃がすような機構を備えた容器にすることは、
加圧密閉を特徴とするエアゾール容器では極めて困難で
ある。Further, as pointed out in Japanese Patent Publication No. 1-11284 mentioned above, the use of a container equipped with a mechanism for releasing a trace amount of gas generated over a long period of time is
It is extremely difficult to use an aerosol container characterized by pressure sealing.
【００１３】このような状況のもとに本発明者は鋭意検
討を重ねた結果、ヒドロキシエタンジホスホン酸の配合
が、製剤中の過酸化水素の安定化に対して有効であり、
長期経過後においても過酸化水素の分解による内圧の上
昇がなく、かつ、該ヒドロキシエタンジホスホン酸が水
可溶性であるため、水難溶性の過酸化水素安定化剤を配
合する際の液粘度の上昇原因になっている多量の油分及
び界面活性剤の添加が必要でなく、一般的な泡状エアゾ
ール化粧料用原液を調製する際に使用される量の油分及
び界面活性剤の使用量の範囲で十分に製剤化し得ること
を見出し、本発明を完成するに至った。Under the circumstances, the present inventor has conducted extensive studies, and as a result, the incorporation of hydroxyethanediphosphonic acid is effective for stabilizing hydrogen peroxide in the preparation,
No increase in internal pressure due to decomposition of hydrogen peroxide even after a long period of time, and since the hydroxyethanediphosphonic acid is water-soluble, increase in liquid viscosity when adding a sparingly water-soluble hydrogen peroxide stabilizer It is not necessary to add a large amount of oil and surfactant that cause the problem, and within the range of the amount of oil and surfactant used when preparing a general foamable aerosol cosmetic concentrate. They have found that they can be sufficiently formulated, and have completed the present invention.
【００１４】[0014]
【課題を解決するための手段】上記課題は、以下の本発
明によって解決される。すなわち本発明は、過酸化水素
０．５〜６．０重量％と、ヒドロキシエタンジホスホン
酸０．００５〜２．０重量％とを含有することを特徴と
する過酸化水素含有泡状エアゾール化粧料用原液からな
る。The above-mentioned problems can be solved by the present invention described below. That is, the present invention contains 0.5 to 6.0% by weight of hydrogen peroxide and 0.005 to 2.0% by weight of hydroxyethanediphosphonic acid, and hydrogen peroxide-containing foam aerosol cosmetics. It consists of a stock solution.
【００１５】前記構成による本発明の過酸化水素含有泡
状エアゾール化粧料用原液において、過酸化水素には過
酸化水素水が利用される。In the hydrogen peroxide-containing undiluted solution for aerosol aerosol cosmetics of the present invention having the above structure, hydrogen peroxide is used as hydrogen peroxide.
【００１６】本発明の過酸化水素含有泡状エアゾール化
粧料用原液の一般的な組成は、過酸化水素及びヒドロキ
シエタンジホスホン酸に、例えば、油脂、ロウ類、炭化
水素、高級脂肪酸、高級アルコール、エステル類、シリ
コーン油、界面活性剤、高分子化合物、紫外線吸収剤、
酸化防止剤、金属イオン封鎖剤、保存剤、保湿剤、香料
等を添加し、さらにｐＨ調製用の有機酸や無機酸により
ｐＨ２．０〜４．０程度に調整したものである。The general composition of the hydrogen peroxide-containing foam aerosol cosmetics concentrate of the present invention comprises hydrogen peroxide and hydroxyethanediphosphonic acid, for example, oils and fats, waxes, hydrocarbons, higher fatty acids and higher alcohols. , Ester, silicone oil, surfactant, polymer compound, UV absorber,
An antioxidant, a sequestering agent, a preservative, a moisturizer, a fragrance, etc. are added, and the pH is adjusted to about 2.0 to 4.0 with an organic acid or an inorganic acid for pH adjustment.
【００１７】本発明の過酸化水素含有泡状エアゾール化
粧料用原液には、液粘度の上昇を起こさない程度の配合
量の水難溶性の過酸化水素安定剤を配合してもよいこと
は勿論である。It is a matter of course that the hydrogen peroxide-containing foam aerosol cosmetics undiluted solution of the present invention may contain a sparingly water-soluble hydrogen peroxide stabilizer in an amount such that the viscosity of the liquid does not increase. is there.
【００１８】過酸化水素含有泡状エアゾール化粧料用原
液中における過酸化水素の量が０．５重量％未満になる
と、使用目的であるパーマネントウェーブ用中和剤、毛
髪脱色剤、あるいは染毛剤の酸化剤としての酸化機能が
不足するようになる。また６．０重量％を超えると、使
用時における手指等への刺激や漂白が起こるようにな
る。When the amount of hydrogen peroxide in the undiluted solution for foamy aerosol cosmetics containing hydrogen peroxide is less than 0.5% by weight, a neutralizing agent for permanent wave, a hair decolorizing agent, or a hair dye, which is the intended purpose, is used. The oxidative function as an oxidant becomes insufficient. On the other hand, if it exceeds 6.0% by weight, irritation and bleaching of fingers and the like will occur during use.
【００１９】さらに、過酸化水素含有泡状エアゾール化
粧料用原液中におけるヒドロキシエタンジホスホン酸の
量が０．００５重量％未満になると、該ヒドロキシエタ
ンジホスホン酸による過酸化水素の安定化作用が不十分
になる。また、このヒドロキシエタンジホスホン酸の量
が２．０重量％を超えると、原液のｐＨが経時的に変動
するために、原液のｐＨを２．０〜４．０程度に調整す
ることが困難になり、原液のｐＨがより酸性側に移行す
るため、原液を充填する缶の耐食性に問題を生ずるよう
になる。Further, when the amount of hydroxyethanediphosphonic acid in the hydrogen peroxide-containing foam aerosol stock solution is less than 0.005% by weight, the hydroxyethanediphosphonic acid has a stabilizing effect on hydrogen peroxide. Becomes insufficient. When the amount of hydroxyethanediphosphonic acid exceeds 2.0% by weight, the pH of the stock solution varies with time, and it is difficult to adjust the pH of the stock solution to about 2.0 to 4.0. As a result, the pH of the stock solution shifts to a more acidic side, which causes a problem in the corrosion resistance of the can filled with the stock solution.
【００２０】本発明の過酸化水素含有泡状エアゾール化
粧料用原液は、エアゾール缶内に噴射剤である液化石油
ガス、あるいは任意の割合で配合した液化石油ガスとジ
メチルエテルとの混合ガス等と共に充填され、泡状エア
ゾールタイプのパーマネントウェーブ用中和剤、毛髪用
脱色剤、染毛剤の酸化剤等として利用されるもので、一
般的なエアゾールタイプの製剤と同様に、過酸化水素含
有泡状エアゾール化粧料用原液１００重量部に対して、
液化石油ガス、あるいは任意の割合で配合した液化石油
ガスとジメチルエテルとの混合ガス３〜２０重量部程度
を充填して製剤にする。The stock solution of hydrogen peroxide-containing foam aerosol cosmetics of the present invention is used together with liquefied petroleum gas which is a propellant in an aerosol can, or a mixed gas of liquefied petroleum gas and dimethyl ether mixed at an arbitrary ratio. Used as a foaming aerosol type neutralizing agent for permanent wave, depigmenting agent for hair, oxidizing agent for hair dye, etc., like the general aerosol type formulation, it contains hydrogen peroxide containing foam. 100 parts by weight of liquid aerosol cosmetics concentrate,
Liquefied petroleum gas or a mixed gas of liquefied petroleum gas and dimethyl ether mixed at an arbitrary ratio is filled in an amount of about 3 to 20 parts by weight to prepare a preparation.
【００２１】[0021]
【実施例】以下、本発明の過酸化水素含有泡状エアゾー
ル化粧料用原液の具体的な組成を実施例に基づいて説明
する。EXAMPLES The specific composition of the hydrogen peroxide-containing foam aerosol concentrate according to the present invention will be described below with reference to Examples.
【００２２】実施例１〜実施例３ ［表１］の所定欄に記載されている組成（重量部）によ
る本発明の実施例品からなる３種類の過酸化水素含有泡
状エアゾール化粧料用原液を得た。Examples 1 to 3 Three kinds of hydrogen peroxide-containing foam aerosol cosmetics undiluted solution consisting of the products of Examples of the present invention having the composition (parts by weight) described in the predetermined column of [Table 1]. Got
【００２３】[0023]
【表１】 [Table 1]
【００２４】比較例１〜比較例２ ［表２］の所定欄に記載されている組成（重量部）によ
る比較のための２種類の過酸化水素含有泡状エアゾール
化粧料用原液を得た。Comparative Examples 1 to 2 Two types of hydrogen peroxide-containing foam aerosol cosmetic stock solutions for comparison were prepared according to the composition (parts by weight) described in the predetermined column of [Table 2].
【００２５】[0025]
【表２】 [Table 2]
【００２６】比較例３〜比較例４ ［表３］の所定欄に記載されている組成（重量部）によ
る比較のための２種類の過酸化水素含有泡状エアゾール
化粧料用原液を得た。Comparative Examples 3 to 4 Two types of hydrogen peroxide-containing foam aerosol cosmetic stock solutions for comparison were prepared according to the compositions (parts by weight) described in the predetermined columns of [Table 3].
【００２７】[0027]
【表３】 [Table 3]
【００２８】実験１ 各実施例及び比較例の過酸化水素含有泡状エアゾール化
粧料用原液９５．０ｇと液化石油ガス５．０ｇとを、直
径４０ｍｍ、高さ１１８ｍｍのアルミニウム製エアゾー
ル缶（容量１３２ｍｌ）に充填し、泡状エアゾール型の
パーマネントウェーブ用中和剤を得た。Experiment 1 95.0 g of hydrogen peroxide-containing foam aerosol stock solution and 5.0 g of liquefied petroleum gas of each Example and Comparative Example were charged into an aluminum aerosol can with a diameter of 40 mm and a height of 118 mm (volume: 132 ml). ) To obtain a foaming aerosol type neutralizing agent for permanent wave.
【００２９】得られた各パーマネントウェーブ用中和剤
の充填缶を、４５℃の雰囲気中に９０日間放置した後、
各缶内の過酸化水素安定性及び２５℃における缶内の圧
力上昇を測定した。また、缶の耐久性を、黙視による缶
の腐食状況によって判定した。各結果を［表４］及び
［表５］に示す。The obtained filled cans of the neutralizing agent for permanent wave were left for 90 days in an atmosphere of 45 ° C.,
The stability of hydrogen peroxide in each can and the pressure rise in the can at 25 ° C were measured. Further, the durability of the can was judged by the corrosive condition of the can with the naked eye. The results are shown in [Table 4] and [Table 5].
【００３０】なお、過酸化水素安定性は、沃素滴定法に
よって過酸化水素の分解量を測定し、○・・・・分解量が２
％未満、△・・・・分解量が２％以上〜５％未満、×・・・・分
解量が５％以上、で表示した。The stability of hydrogen peroxide was determined by measuring the amount of decomposition of hydrogen peroxide by the iodine titration method.
%, Δ ... Decomposition amount is 2% or more and less than 5%, × ... Decomposition amount is 5% or more.
【００３１】缶内の圧力上昇は、ブルドン管隔膜式圧力
計による２５℃における缶内の圧力測定の結果を、○・・
・・０．１ｋｇ／ｃｍ2 Ｇ未満、△・・・・０．１ｋｇ／ｃｍ
2 Ｇ以上〜０．５ｋｇ／ｃｍ2 Ｇ未満、×・・・・０．５ｋ
ｇ／ｃｍ2 Ｇ以上、で表示した。The pressure rise in the can was measured by measuring the pressure in the can at 25 ° C. with a Bourdon tube diaphragm type pressure gauge.
·· 0.1kg / cm less than 2 G, △ ···· 0.1kg / cm
2 G or more and less than 0.5 kg / cm 2 G, × ... 0.5 k
It was displayed as g / cm 2 G or more.
【００３２】また、缶の耐久性は、○・・・・腐食を確認で
きない、×・・・・腐食を確認できる、で表示した。Further, the durability of the can is indicated by ◯ ... Corrosion cannot be confirmed, X ... Corrosion can be confirmed.
【００３３】実験２ 長さ２０ｃｍの３ｇの試験用の毛髪を、市販のパーマネ
ントウエーブ用還元剤にて還元処理を行なった後、これ
を直径２０ｍｍのパーマネントウェーブ用支持具に巻き
付けてから、実験１による保存試験後のパーマネントウ
ェーブ用中和剤のそれぞれ２ｇを塗布し、２０分間放置
することにより、該パーマネントウェーブ用中和剤の中
和能を試験した。Experiment 2 3 g of test hair having a length of 20 cm was subjected to a reducing treatment with a commercially available reducing agent for permanent wave, and the hair was wound around a support for permanent wave having a diameter of 20 mm. 2 g of each neutralizing agent for permanent wave after the storage test was applied and left for 20 minutes to test the neutralizing ability of the neutralizing agent for permanent wave.
【００３４】中和能は、中和工程の終了後に、パーマネ
ントウェーブ用支持具より外した試験用毛髪を洗浄、乾
燥し、ウェーブの掛かり具合を目視によって評価した。
結果を、［表４］及び［表５］に併記する。The neutralizing ability was evaluated by visually observing the degree of wave application after washing and drying the test hair removed from the permanent wave support after the neutralization step.
The results are also shown in [Table 4] and [Table 5].
【００３５】なお、この中和能の評価結果は、○・・・・毛
髪に十分なウェーブが得られた、△・・・・毛髪に十分なウ
ェーブが得られたが、使用時に手や指が脱色したり荒れ
たりして、使用上の問題があった、×・・・・毛髪に実用上
問題の無いウェーブが得られなかった、（−）・・・・腐食
によって缶に穴が開いたために評価不能、で表示した。The evaluation results of the neutralizing ability are as follows: ○ ・ ・ ・ ・ Sufficient wave was obtained on the hair, △ ・ ・ ・ ・ ・ ・ Sufficient wave was obtained on the hair There was a problem in use due to decolorization and roughening, × ・ ・ ・ ・ Waves that were not practically problematic on hair could not be obtained, (-) ・ ・ ・ Corrosion caused holes in the can Because it was impossible to evaluate, it was displayed as.
【００３６】実験３ 実験２で使用したパーマネントウェーブ用中和剤の充填
缶を、そのまま泡状エアゾールタイプの毛髪脱色剤とし
て使用し、長さ１０ｃｍの２ｇの試験用の毛髪に１日に
１回、各泡状エアゾールタイプの毛髪脱色剤のそれぞれ
を２ｇ宛塗布し、毛髪の脱色性を測定した。結果を［表
４］及び［表５］に併記する。Experiment 3 The filled can of neutralizing agent for permanent wave used in Experiment 2 was used as it was as a foam aerosol type hair decolorizing agent, and once a day was applied to 2 g of test hair having a length of 10 cm. Then, 2 g of each foam-type aerosol-type hair decolorizing agent was applied, and the decolorizing property of the hair was measured. The results are also shown in [Table 4] and [Table 5].
【００３７】なお、毛髪の脱色性は、◎・・・・使用後３日
目で毛髪の脱色傾向が認められる、○・・・・使用後７日目
で毛髪の脱色傾向が認められる、△・・・・使用後３日目に
脱色傾向が認められるが、使用時に手や指が脱色してし
まい、使用上の問題がある、×・・・・使用後２０日目でも
毛髪の脱色傾向が認められない、（−）・・・・腐食によっ
て缶に穴が開いたために評価不能、で表示した。The bleaching properties of the hair are as follows: ⋅ ∙: Decoloring tendency of the hair is recognized 3 days after use, ∙: Decoloring tendency of the hair is recognized 7 days after use, △・ ・ ・ ・ Discoloration tendency is observed on the 3rd day after use, but there is a problem in use because the hands and fingers are discolored during use. × ・ ・ ・ ・ ・ ・ Discoloration tendency of hair even on the 20th day after use Was not observed, (-) ... was not evaluated because a hole was formed in the can due to corrosion.
【００３８】実験４ 市販されている２剤型液状染毛剤の染料ベース２ｇを計
り取ると共に、実験２で使用したパーマネントウェーブ
用中和剤の充填缶を、そのまま泡状エアゾールタイプの
染毛剤の酸化剤として用い、各々その４ｇを前記染料ベ
ース２ｇと混ぜ合せ、直ちに長さ１０ｃｍの３ｇの試験
用の毛髪に塗布し、４０℃にて１５分間放置したときの
染毛の度合いから、染毛剤の酸化能を試験した。結果を
［表４］及び［表５］に併記する。Experiment 4 While weighing 2 g of a dye base of a commercially available two-pack type liquid hair dye, the filling can of the neutralizing agent for permanent wave used in Experiment 2 was directly used as a foam aerosol type hair dye. 4g of each of them was mixed with 2g of the above dye base and immediately applied to 3g of test hair having a length of 10cm, which was dyed from the degree of hair dyeing when left at 40 ° C for 15 minutes. The oxidizing ability of the hair agent was tested. The results are also shown in [Table 4] and [Table 5].
【００３９】なお、染毛剤の酸化能は、○・・・・毛髪に十
分な染色が得られ、市販のシャンプーによる連続１０回
の洗浄試験によっても、毛髪の褪色が認められない、△
・・・・毛髪に十分な染色が得られたが、市販のシャンプー
による連続１０回未満の洗浄試験によって毛髪の褪色が
認められる、×・・・・毛髪に十分な染色が得られない、
（−）・・・・腐食によって缶に穴が開いたために評価不
能、で表示した。The oxidative ability of the hair dye is ◯ ... Sufficient dyeing is obtained on the hair, and no fading of the hair is observed even after 10 consecutive washing tests with a commercial shampoo.
.... Sufficient dyeing was obtained on the hair, but discoloration of the hair was recognized by a washing test with a commercially available shampoo less than 10 times in succession. × ... Sufficient dyeing was not obtained on the hair.
(-) ...- Cannot be evaluated because a hole was formed in the can due to corrosion.
【００４０】[0040]
【表４】 [Table 4]
【００４１】[0041]
【表５】 [Table 5]
【００４２】[0042]
【発明の効果】本発明の過酸化水素含有泡状エアゾール
化粧料用原液は、酸化有効成分である過酸化水素の安定
性において優れた特性を有することから、高品質の過酸
化水素含有泡状エアゾール化粧料用原液になる。INDUSTRIAL APPLICABILITY The hydrogen peroxide-containing foam aerosol concentrate according to the present invention has excellent characteristics in stability of hydrogen peroxide, which is an active ingredient for oxidation. It becomes an undiluted solution for aerosol cosmetics.
───────────────────────────────────────────────────── フロントページの続き (72)発明者 千田 敦 千葉県柏市松ケ崎276−１ ─────────────────────────────────────────────────── ─── Continuation of the front page (72) Inventor Atsushi Senda 276-1 Matsugasaki, Kashiwa City, Chiba Prefecture
Claims (1)
ヒドロキシエタンジホスホン酸０．００５〜２．０重量
％とを含有することを特徴とする過酸化水素含有泡状エ
アゾール化粧料用原液。1. Hydrogen peroxide of 0.5 to 6.0% by weight,
Hydroxyethanediphosphonic acid 0.005 to 2.0% by weight is contained, and a hydrogen peroxide-containing foam aerosol concentrate is prepared.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP12916895A JPH08301740A (en) | 1995-04-28 | 1995-04-28 | Stock solution for hydrogen peroxide-containing foamy aerosol cosmetic |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP12916895A JPH08301740A (en) | 1995-04-28 | 1995-04-28 | Stock solution for hydrogen peroxide-containing foamy aerosol cosmetic |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH08301740A true JPH08301740A (en) | 1996-11-19 |
Family
ID=15002829
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP12916895A Pending JPH08301740A (en) | 1995-04-28 | 1995-04-28 | Stock solution for hydrogen peroxide-containing foamy aerosol cosmetic |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH08301740A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1138316A3 (en) * | 2000-04-01 | 2002-02-13 | GOLDWELL GmbH | Process and composition for oxidative dyeing of human keratinic fibres |
| WO2001072271A3 (en) * | 2000-03-27 | 2002-03-21 | Procter & Gamble | Stable alkaline hair bleaching and coloring compositions and method for use thereof |
| WO2001072272A3 (en) * | 2000-03-27 | 2002-05-23 | Procter & Gamble | Stable alkaline hair bleaching compositions and method for use thereof |
| GB2386068A (en) * | 2001-03-20 | 2003-09-10 | Procter & Gamble | Oxidative treatment of hair with reduced hair damage |
-
1995
- 1995-04-28 JP JP12916895A patent/JPH08301740A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2001072271A3 (en) * | 2000-03-27 | 2002-03-21 | Procter & Gamble | Stable alkaline hair bleaching and coloring compositions and method for use thereof |
| WO2001072272A3 (en) * | 2000-03-27 | 2002-05-23 | Procter & Gamble | Stable alkaline hair bleaching compositions and method for use thereof |
| EP1138316A3 (en) * | 2000-04-01 | 2002-02-13 | GOLDWELL GmbH | Process and composition for oxidative dyeing of human keratinic fibres |
| GB2386068A (en) * | 2001-03-20 | 2003-09-10 | Procter & Gamble | Oxidative treatment of hair with reduced hair damage |
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