JPH01178223A - Floor pad with dry finishing coat - Google Patents
Floor pad with dry finishing coatInfo
- Publication number
- JPH01178223A JPH01178223A JP200188A JP200188A JPH01178223A JP H01178223 A JPH01178223 A JP H01178223A JP 200188 A JP200188 A JP 200188A JP 200188 A JP200188 A JP 200188A JP H01178223 A JPH01178223 A JP H01178223A
- Authority
- JP
- Japan
- Prior art keywords
- floor
- floor pad
- aliphatic mono
- light metal
- synthetic resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920005989 resin Polymers 0.000 claims abstract description 14
- 239000011347 resin Substances 0.000 claims abstract description 14
- 239000000835 fiber Substances 0.000 claims abstract description 11
- 229920003002 synthetic resin Polymers 0.000 claims abstract description 9
- 239000000057 synthetic resin Substances 0.000 claims abstract description 9
- 229910052751 metal Inorganic materials 0.000 claims abstract description 8
- 239000002184 metal Substances 0.000 claims abstract description 8
- -1 aliphatic mono-carboxylic acid Chemical class 0.000 claims abstract description 6
- 125000001931 aliphatic group Chemical group 0.000 claims abstract description 5
- 239000011248 coating agent Substances 0.000 claims abstract description 5
- 229920002994 synthetic fiber Polymers 0.000 claims abstract description 3
- 239000012209 synthetic fiber Substances 0.000 claims abstract description 3
- 239000000839 emulsion Substances 0.000 claims abstract 2
- 229920001187 thermosetting polymer Polymers 0.000 claims description 7
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 claims description 6
- 239000004745 nonwoven fabric Substances 0.000 claims description 6
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 claims description 6
- 235000019359 magnesium stearate Nutrition 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 abstract description 10
- 235000021355 Stearic acid Nutrition 0.000 abstract description 7
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 abstract description 7
- 239000008117 stearic acid Substances 0.000 abstract description 7
- 239000000463 material Substances 0.000 abstract description 4
- 239000004744 fabric Substances 0.000 abstract description 3
- 238000000034 method Methods 0.000 abstract description 3
- 238000000576 coating method Methods 0.000 abstract description 2
- 238000013007 heat curing Methods 0.000 abstract 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 abstract 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 229910052749 magnesium Inorganic materials 0.000 abstract 1
- 239000011777 magnesium Substances 0.000 abstract 1
- 229910052725 zinc Inorganic materials 0.000 abstract 1
- 239000011701 zinc Substances 0.000 abstract 1
- 239000011230 binding agent Substances 0.000 description 8
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- 238000004140 cleaning Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 239000004593 Epoxy Substances 0.000 description 2
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 230000017525 heat dissipation Effects 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 238000004018 waxing Methods 0.000 description 2
- 229920000877 Melamine resin Polymers 0.000 description 1
- 239000004640 Melamine resin Substances 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 201000001880 Sexual dysfunction Diseases 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 238000006748 scratching Methods 0.000 description 1
- 230000002393 scratching effect Effects 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 230000003746 surface roughness Effects 0.000 description 1
Landscapes
- Cleaning Implements For Floors, Carpets, Furniture, Walls, And The Like (AREA)
- Brushes (AREA)
Abstract
Description
【発明の詳細な説明】
本発明はピル、建物等の床掃除及びワックス塗布等に使
用する回転式仕上げ用フロアパッドに関するものである
。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a rotary finishing floor pad used for cleaning and waxing floors of buildings, etc.
従来、この種のフロアパッドとしては、ポリエステル、
ナイロン等の合成繊維を素材とした不織布原反に、炭酸
カルシウム、シリカ等の無機系の充填剤、滑剤を含有し
たフェノール、エポキシ、ウレタン等の合成樹脂を含浸
加工されたものが使用されているが、近年フロアパッド
の回転掃除具の性能が良くなり、非常に高速で短時間く
処理出来る超高速ポリラシャ−の出現によ)、その高速
性に対するフロアパッドの性能が劣シ、摩擦抵抗の増大
による床面ワックスへの傷、フロアパッドの変形等、種
々問題点が発生している。この様な高速性能に対処すべ
く、原反に用いる繊維を太くし、摩擦熱の放熱効果を高
め丸ものが、改良品として市場に出廻っているが、繊維
が太く、繊維及び樹脂の滑性の問題よシ、床面ワックス
への傷(表面粗さ)の問題が解決されていないという欠
点がある。Conventionally, this type of floor pad has been made of polyester,
Nonwoven fabrics made from synthetic fibers such as nylon are impregnated with synthetic resins such as phenol, epoxy, and urethane containing inorganic fillers such as calcium carbonate and silica, and lubricants. However, in recent years, the performance of rotary cleaning tools for floor pads has improved, and with the advent of ultra-high-speed poly lashers that can process at very high speed and in a short time), the performance of floor pads has become inferior to that high speed, and frictional resistance has increased. Various problems have occurred, such as scratches on the floor wax and deformation of the floor pad. In order to cope with such high-speed performance, the fibers used in the raw fabric are made thicker to enhance the heat dissipation effect of frictional heat. Round products are now on the market as improved products, but the fibers are thicker and the fibers and resin are less slippery. In addition to the sexual problem, there is also the drawback that the problem of scratches (surface roughness) on the floor wax has not been resolved.
(問題点を解決するための手段) 本発明はこの様な現況に鑑み、超高速ポリ。(Means for solving problems) In view of the current situation, the present invention is an ultra-high-speed polygon.
シャーに十分に耐久性があり、しかも床表面への傷粗さ
(光沢度)にすぐれ、長期安定して作業の出来る乾式仕
上げ用フロアパッドを提供するものである。即ち本発明
はサイズコートに使用するフェノール、エポキシ、ウレ
タン等の熱硬化型合成樹脂にステアリン酸亜鉛、ステア
リン酸マグネッシウム等の脂肪族モノカルボン酸塩又は
脂肪族モノカルボン酸軽金属を、上記合成樹脂100部
に対し5〜50部含有させ、基材とする嵩高不織布に含
浸被覆せしめて構成することにより、該合成樹脂の滑性
を大巾に向上せしめた乾式仕上げ用のフロアパッドを得
ることによシ問題点を解消したものである。To provide a floor pad for dry finishing which has sufficient durability for shearing, has excellent scratch roughness (glossiness) on the floor surface, and allows stable work over a long period of time. That is, the present invention applies an aliphatic monocarboxylate salt or aliphatic monocarboxylic acid light metal such as zinc stearate or magnesium stearate to a thermosetting synthetic resin such as phenol, epoxy, or urethane used for the size coat. By containing 5 to 50 parts per 100 parts and impregnating and coating a bulky nonwoven fabric as a base material, it is possible to obtain a floor pad for dry finishing that greatly improves the slipperiness of the synthetic resin. This solves the problem.
乾式仕上げ用フロアパッドは、湿式フロアパッドでワッ
クス剥離剤を使用し、ワックスを剥離除去しながら床面
を研摩洗浄した後、乾式ワ、ジス塗布用パッドによ51
−4層にワックスを積み重ね塗布された次に使用される
ものであり、樹脂ワックスの焼き付は作用を付与するも
のである。従って仕上げ用フロアパッドに要求される性
能としては、繊維間の空隙を粗くし、放熱性を向上し、
繊維間の強度9反撥弾性等の物性は当然の事、床ワツク
ス面とフロアパッドの繊維、樹脂の滑性が最も重要であ
る。For dry finishing floor pads, use a wax remover with a wet floor pad, polish and clean the floor surface while peeling off the wax, and then use a dry waxing and dispensing pad to remove the wax.
-It is used after four layers of wax are applied, and the baking of the resin wax imparts its effect. Therefore, the performance required for finishing floor pads is to make the voids between the fibers coarser, improve heat dissipation,
Of course, physical properties such as interfiber strength 9 and rebound elasticity are the most important, but the slipperiness of the floor wax surface, the fibers of the floor pad, and the resin are the most important.
従って脂肪族モノカルボン酸塩又は脂肪族モノカルボン
酸軽金属を二次結合剤として用いる熱硬化型合成樹脂に
添加することが最も理にかなったものであることを見出
したものである。Therefore, it has been found that it is most logical to add an aliphatic monocarboxylic acid salt or a light metal aliphatic monocarboxylic acid to a thermosetting synthetic resin using as a secondary binder.
また、熱硬化屋樹脂100部に対し、ステアリン酸亜鉛
、ステアリン酸マグネッシウム等の脂肪族モノカルボン
酸塩、金属の添加量5〜50部としたのはSML漬部未
満では潤滑の効果なく目的が達成されず、50重薄部を
超えると添加したステアリン酸の脱落が生じるので好ま
しくない。In addition, the addition amount of aliphatic monocarboxylate salts such as zinc stearate, magnesium stearate, and metals is 5 to 50 parts per 100 parts of thermosetting resin. is not achieved, and if the amount exceeds 50 parts by weight, the added stearic acid will drop off, which is not preferable.
本発明は上記の構成としたことにより、仕上げ作業中、
摩擦熱によシ樹脂中に含有されたステアリン酸が軟化し
樹脂粒周囲を包含するので使用するに従って表面滑性が
向上し、理想的な乾式仕上げのワックス層が形成される
。The present invention has the above configuration, so that during finishing work,
The stearic acid contained in the resin softens due to frictional heat and surrounds the resin particles, so as it is used, the surface smoothness improves and a wax layer with an ideal dry finish is formed.
この様に一度合成樹脂粒周囲にステアリン酸によるワッ
クス層が形成されれば上記の如く安定した表面滑性が得
られ、床面ワックス層にキズをつけることなく非常に光
沢の出る仕上が出来る。In this way, once a wax layer of stearic acid is formed around the synthetic resin particles, stable surface smoothness can be obtained as described above, and a highly glossy finish can be achieved without scratching the floor wax layer.
又、本発明のフロアパッドは上記の如く、ステアリン酸
塩、ステアリン酸軽金属が摩擦熱による軟化溶融により
樹脂周囲にステアリン酸層が形成されるため、床用のワ
ックスが付着し難く、且、ステアリン酸層によりワック
ス剥離剤に対する抵抗も向上し、フロアパッドの劣化損
傷も殆んど生じない。In addition, as described above, in the floor pad of the present invention, a stearic acid layer is formed around the resin by softening and melting the stearate and the light metal stearate due to frictional heat, so that floor wax is difficult to adhere to, and the stearate is hard to adhere to. The acid layer also improves resistance to wax strippers and causes little deterioration damage to the floor pad.
以下本発明を実施例に基づき詳細に説明する。The present invention will be described in detail below based on examples.
ポリエステルiJ[430デニ一ルX38xlOO%ヲ
用イ、ランドマシーンによ)目付450 y/lxpの
ランドウェブを形成し、該ウェブの表裏面に下記に示す
配合の樹脂結合剤を散布して、ウェブの繊維間相互の仮
止めを行ない、目付6502を厚さ915部肩の基材嵩
高不織布を形成する。A land web with a basis weight of 450 y/lxp is formed using a land machine for polyester iJ [430 denier The fibers are temporarily fixed to each other to form a base bulky nonwoven fabric having a basis weight of 6502 and a thickness of 915 parts.
BBRラテックス 100部
メラミン樹脂 10部
触媒 1部
濃度 80%
次に下記に示す配合の熱硬化型樹脂結合剤を主体とする
二次結合剤(サイズコート剤)により含浸加工を行い、
乾燥加熱処理を施した。BBR latex 100 parts Melamine resin 10 parts Catalyst 1 part Concentration 80% Next, impregnation processing is performed with a secondary binder (size coating agent) mainly consisting of a thermosetting resin binder having the composition shown below.
A dry heat treatment was performed.
ウレタン樹脂 100部
ステアリン酸亜鉛 20部
顔 料 1部
M I!X K
濃度 65%
粘度 1000〜5oooaps
この様にして形成した本発明の乾式仕上げ用フロアパッ
ドfi+は目付180(l沿、厚さ261Mでちゃ、第
1図及び第2図に示す様に、基材嵩高不織布の構成繊維
(り1間相互をステアリン酸亜鉛粒子(3)を分散含有
する熱硬化型樹脂結合剤(ウレタン樹脂)(4)によシ
結合、被覆され構成されている。Urethane resin 100 parts Zinc stearate 20 parts Pigment 1 part MI! X K Concentration: 65% Viscosity: 1000 to 5ooooaps The constituent fibers of the bulky nonwoven fabric are bonded and coated with a thermosetting resin binder (urethane resin) (4) containing zinc stearate particles (3) dispersed therein.
比較例
次に比較例として実施例1で用いた基材嵩高不織布を原
反とし、二次結合剤として下記の二種の配合液にて夫々
含浸加工して、各々仕上少目付130(1/411.厚
さgfl+aのフロアパッドを得た。Comparative Example Next, as a comparative example, the bulky nonwoven fabric used in Example 1 was impregnated with the following two types of liquids as secondary binders, and the finished weight was 130 (1/2). 411. A floor pad with a thickness of gfl+a was obtained.
A配合
ウレタン樹脂 100部
顔料 1部
EK
B配合
ウレタン樹脂 100部
炭酸カルシウム lO部
KK
A%B配合共 濃度65%
粘度1000〜100OCPS
この様にして形成した3種類の乾式仕上げ用フロアパッ
ドを超高速ポリシャーに取シ付はテストを行った結果を
下表に示す。B-blended urethane resin 100 parts Pigment 1 part EK B-blended urethane resin 100 parts Calcium carbonate 10 parts KK A% B-blended Concentration 65% Viscosity 1000-100 OCPS Three types of dry finishing floor pads formed in this way were processed at ultra-high speed. The table below shows the results of a test for attaching the polisher to the polisher.
※ 試験片 外径 201
回転数 200 Or、p、m
〔発明の効果〕
本発明は上記の如く構成したから、テスト結果から明ら
かなる様に、高速回転時に於て表面摩擦抵抗が低くなり
、床面ワックス粗さも細かく光沢が向上する。また形態
変化も少なく形崩れが生じない。また床用ワックスの付
着も少なくなシ、いったん付着した床用ワックスも繊維
樹脂を包含しているステアリン酸の軟化ワックス層によ
って繊維、樹脂の剥離剤による劣化なく除去が可能であ
る為、洗浄後の形態変化がなく、常時安定した研摩洗浄
作業が可能となる等のυfれた効果を有する発明である
。* Test piece Outer diameter: 201 Number of revolutions: 200 Or, p, m [Effects of the invention] Since the present invention is constructed as described above, as is clear from the test results, the surface frictional resistance is low during high-speed rotation, and the floor The roughness of the surface wax is fine and the gloss is improved. In addition, there is little change in shape and the product does not lose its shape. In addition, there is less adhesion of floor wax, and once the floor wax has adhered, it can be removed without deterioration due to the fiber and resin remover due to the softening wax layer of stearic acid that contains fiber resin, so it can be removed after cleaning. This invention has excellent effects such as no change in shape and stable polishing and cleaning work at all times.
第1図は本発明の1%施例を示す乾式仕上げ用フロアパ
ッドの概略構成断面図、第2図は同第1図の部分拡大図
である。
(1)・・・フロアパッド、(2)・・・鷹維、(3)
・・・ステアリン酸亜鉛粒子、(4)・・・熱硬化型樹
脂結合剤(ウレタン樹脂)
第1図
第2図 。FIG. 1 is a schematic cross-sectional view of a floor pad for dry finishing showing a 1% embodiment of the present invention, and FIG. 2 is a partially enlarged view of FIG. 1. (1)...Floor pad, (2)...Takawei, (3)
... Zinc stearate particles, (4) ... Thermosetting resin binder (urethane resin) Fig. 1 Fig. 2.
Claims (1)
ジョンにより仮止めしてなる基材嵩高不織布に、ステア
リン酸亜鉛、ステアリン酸マグネッシウム等の脂肪族モ
ノカルボン酸塩又は脂肪族モノカルボン酸軽金属を、熱
硬化型樹脂100部(重量)に対し、5〜50部(重量
)含有させたサイズコート剤で含浸被覆せしめてなるこ
とを特徴とする乾式仕上用フロアパッド。An aliphatic monocarboxylate salt or an aliphatic monocarboxylic acid light metal such as zinc stearate or magnesium stearate is added to a base bulky nonwoven fabric made by temporarily fixing the fibers of a web made of synthetic fibers with a synthetic resin emulsion. A floor pad for dry finishing, characterized in that it is impregnated and coated with a size coating agent containing 5 to 50 parts (by weight) per 100 parts (by weight) of a thermosetting resin.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP200188A JPH01178223A (en) | 1988-01-08 | 1988-01-08 | Floor pad with dry finishing coat |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP200188A JPH01178223A (en) | 1988-01-08 | 1988-01-08 | Floor pad with dry finishing coat |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH01178223A true JPH01178223A (en) | 1989-07-14 |
Family
ID=11517186
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP200188A Pending JPH01178223A (en) | 1988-01-08 | 1988-01-08 | Floor pad with dry finishing coat |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH01178223A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1998011813A1 (en) * | 1996-09-23 | 1998-03-26 | The Procter & Gamble Company | A cleaning implement |
| WO1998023199A1 (en) * | 1996-11-26 | 1998-06-04 | The Procter & Gamble Company | A cleaning implement having controlled fluid absorbency |
| US6003191A (en) * | 1996-09-23 | 1999-12-21 | The Procter & Gamble Company | Cleaning implement |
| US6048123A (en) * | 1996-09-23 | 2000-04-11 | The Procter & Gamble Company | Cleaning implement having high absorbent capacity |
| US6101661A (en) * | 1997-03-20 | 2000-08-15 | The Procter & Gamble Company | Cleaning implement comprising a removable cleaning pad having multiple cleaning surfaces |
| JP2002085311A (en) * | 2000-09-11 | 2002-03-26 | Sakura Color Prod Corp | Dirt removing device |
| US8449197B2 (en) | 2003-12-01 | 2013-05-28 | Ntn Corporation | Bearing apparatus for a wheel of vehicle |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4955152A (en) * | 1972-09-26 | 1974-05-29 | ||
| JPS4955162A (en) * | 1972-05-12 | 1974-05-29 | ||
| JPS54160865A (en) * | 1978-06-10 | 1979-12-19 | Mtp Kasei Kk | Hydrophilic nonnwoven fabric and production and chemical duster material comprising nonnwoven fabric |
| JPS56151013A (en) * | 1980-01-16 | 1981-11-21 | Procter & Gamble | Washing article |
| JPS62152427A (en) * | 1985-12-24 | 1987-07-07 | 金井 宏之 | Nonwoven fabric cleaner |
-
1988
- 1988-01-08 JP JP200188A patent/JPH01178223A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4955162A (en) * | 1972-05-12 | 1974-05-29 | ||
| JPS4955152A (en) * | 1972-09-26 | 1974-05-29 | ||
| JPS54160865A (en) * | 1978-06-10 | 1979-12-19 | Mtp Kasei Kk | Hydrophilic nonnwoven fabric and production and chemical duster material comprising nonnwoven fabric |
| JPS56151013A (en) * | 1980-01-16 | 1981-11-21 | Procter & Gamble | Washing article |
| JPS62152427A (en) * | 1985-12-24 | 1987-07-07 | 金井 宏之 | Nonwoven fabric cleaner |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1998011813A1 (en) * | 1996-09-23 | 1998-03-26 | The Procter & Gamble Company | A cleaning implement |
| US6003191A (en) * | 1996-09-23 | 1999-12-21 | The Procter & Gamble Company | Cleaning implement |
| US6048123A (en) * | 1996-09-23 | 2000-04-11 | The Procter & Gamble Company | Cleaning implement having high absorbent capacity |
| US6601261B1 (en) * | 1996-09-23 | 2003-08-05 | The Procter & Gamble Company | Cleaning implement having high absorbent capacity |
| WO1998023199A1 (en) * | 1996-11-26 | 1998-06-04 | The Procter & Gamble Company | A cleaning implement having controlled fluid absorbency |
| US5960508A (en) * | 1996-11-26 | 1999-10-05 | The Proctor & Gamble Company | Cleaning implement having controlled fluid absorbency |
| US6045622A (en) * | 1996-11-26 | 2000-04-04 | The Procter & Gamble Company | Method of cleaning a hard surface using low levels of cleaning solution |
| US6101661A (en) * | 1997-03-20 | 2000-08-15 | The Procter & Gamble Company | Cleaning implement comprising a removable cleaning pad having multiple cleaning surfaces |
| US6766552B1 (en) | 1997-03-20 | 2004-07-27 | The Procter & Gamble Company | Cleaning implement comprising a removable cleaning pad having multiple cleaning surfaces |
| JP2002085311A (en) * | 2000-09-11 | 2002-03-26 | Sakura Color Prod Corp | Dirt removing device |
| US8449197B2 (en) | 2003-12-01 | 2013-05-28 | Ntn Corporation | Bearing apparatus for a wheel of vehicle |
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