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JPH03292969A - Fire extinguishing methods and fire extinguishing equipment - Google Patents

Fire extinguishing methods and fire extinguishing equipment

Info

Publication number
JPH03292969A
JPH03292969A JP9486790A JP9486790A JPH03292969A JP H03292969 A JPH03292969 A JP H03292969A JP 9486790 A JP9486790 A JP 9486790A JP 9486790 A JP9486790 A JP 9486790A JP H03292969 A JPH03292969 A JP H03292969A
Authority
JP
Japan
Prior art keywords
fire extinguishing
water
polymer
extinguishing water
hose
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP9486790A
Other languages
Japanese (ja)
Inventor
Ryuhei Shizume
鎮目 龍平
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Osaka Organic Chemical Industry Co Ltd
Original Assignee
Osaka Organic Chemical Industry Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Osaka Organic Chemical Industry Co Ltd filed Critical Osaka Organic Chemical Industry Co Ltd
Priority to JP9486790A priority Critical patent/JPH03292969A/en
Publication of JPH03292969A publication Critical patent/JPH03292969A/en
Pending legal-status Critical Current

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  • Fire-Extinguishing Compositions (AREA)
  • Polymerisation Methods In General (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

PURPOSE:To reduce as small as possible the secondary disaster due to the overflow of fire extinguishing water in a fire by hosing the fire extinguishing water mixed with high water absorbing property polymer or adding the polymer to hosed fire extinguishing water. CONSTITUTION:One end of a polymer supply hose 5 is connected on the way of the absorbing side hose 2 of a fire extinguishing water pump 1 and the other end is connected to a container 4 containing high water absorbing property polymer 3. Negative pressure produced by a suction force of the fire extinguishing water pump 1 in the absorbing side hose 2 causes the high water absorbing property polymer 3 in the container 4 to be automatically sucked into the hose 2, mixed with water 8 in the hose 2 and hosed through the discharge side hose 6. The polymer grains have few water attached therebetween and substantially no stick after the water suction. Further, since the hosed fire extinguishing water is rapidly absorbed after fire fighting to prevent apparatus and wall surfaces from the intrusion of the fire extinguishing water and easily separated and slid down from the wall surfaces or the like, the recovering operation is facilitated so that the fire extinguishing water can easily be recovered by a suction type large-scaled cleaner or the like.

Description

【発明の詳細な説明】 産業上の利用分野 この発明は、消火方法とその消火方法に使用する消火装
置に関するものである。
DETAILED DESCRIPTION OF THE INVENTION Field of Industrial Application This invention relates to a fire extinguishing method and a fire extinguishing device used in the fire extinguishing method.

従来の技術 一般に、火災時の消火用水としては、水単体か消火用の
薬剤等を混入させた水が使用されている。
BACKGROUND OF THE INVENTION In general, water alone or water mixed with extinguishing agents is generally used as water for extinguishing fires.

この水単体または消火用薬剤混入水は、消火及び冷却を
目的として広く使用されている。
This water alone or water mixed with fire extinguishing agents is widely used for the purpose of extinguishing fires and cooling.

発明が解法しようとする課題。The problem that an invention attempts to solve.

上記消火用水の緊急時での確保は容易であり、また、一
般に経済的である。
Securing the above-mentioned fire extinguishing water in an emergency is easy and generally economical.

しかし、消火終了後においては、散水した消火用水が被
災物及びその周辺へ浸水し、周辺器物及び周辺家屋へ二
次的な被害をもたらしている。このために、精密機械の
場合は殆ど使用不可となって交換しなければならず、ま
た、建物についても大幅な修理改造が必要となり、その
経済的損失は甚大である。
However, after the fire has been extinguished, the sprayed fire extinguishing water floods the disaster-stricken property and its surroundings, causing secondary damage to surrounding property and surrounding houses. For this reason, most precision instruments become unusable and must be replaced, and buildings also require extensive repair and remodeling, resulting in enormous economic losses.

この発明は、このような火災時の消火用水の浸水による
二次災害を、できるだけ最小限に止めることを目的とす
るものである。
The purpose of this invention is to minimize secondary disasters caused by flooding of fire extinguishing water during a fire.

課題を解決するための手段 上記の目的を達成するための、この発明の消火方法は、
高吸水性ポリマーを消火水中に混入させて散水するか又
は放水された消火水中へ混入させることを特徴とする。
Means for Solving the Problems The fire extinguishing method of the present invention to achieve the above object is as follows:
The method is characterized in that the superabsorbent polymer is mixed into fire extinguishing water and sprinkled with water, or mixed into sprayed fire extinguishing water.

また、同じくこの発明の消火装置は、放水するか又は放
水された消火水中に高吸水性ポリマーを混入させること
を特徴とする。
Further, the fire extinguishing device of the present invention is also characterized in that it sprays water or mixes a superabsorbent polymer into the sprayed fire extinguishing water.

上記において、高吸水性ポリマーとしては、溶出率5%
以下、膨張率1.5倍以上の実質的にベタつきのない球
状のものが用いられる。
In the above, the superabsorbent polymer has an elution rate of 5%.
Hereinafter, a substantially non-sticky spherical material with an expansion rate of 1.5 times or more is used.

この発明において、消火水とは水車体のみならず消火用
薬剤を混入させた水を含む。
In this invention, fire extinguishing water includes not only the water wheel body but also water mixed with a fire extinguishing agent.

この発明に用いられる高吸水性ポリマーは、水に対する
溶出率が5%以下、好ましくは2%以下のものである。
The superabsorbent polymer used in this invention has a dissolution rate in water of 5% or less, preferably 2% or less.

また、この発明に用いる高吸水性ポリマーは、膨張倍率
が1,5倍以上、好ましくは2〜3倍で実質的にはベタ
つきのないポリマーである。ここで膨張倍率とは、吸水
後のポリマー容量/添加した水の容量で表わされる。
The superabsorbent polymer used in the present invention has an expansion ratio of 1.5 times or more, preferably 2 to 3 times, and is substantially non-sticky. Here, the expansion ratio is expressed as the polymer volume after water absorption/the volume of added water.

この発明に用いられる高吸水性ポリマーとじては、上記
性状を有するものであれば特に限定されないが、吸水能
が脱イオン水で50〜300倍であることが望ましい。
The superabsorbent polymer used in this invention is not particularly limited as long as it has the above-mentioned properties, but it is desirable that the water absorption capacity is 50 to 300 times that of deionized water.

吸水能は、吸水した脱イオン水の容量/ポリマー容量で
表される。
The water absorption capacity is expressed as the volume of deionized water absorbed/polymer volume.

また、この発明に用いる高吸水性ポリマーは球状であり
、ポリマー粒子の〔長径/短径〕比が1.5以下である
のが望ましい。
Further, it is desirable that the superabsorbent polymer used in the present invention is spherical, and the [longer diameter/breadth diameter] ratio of the polymer particles is 1.5 or less.

この発明に用いられる高吸水性ポリマーとしては、下記
に示す製造方法で得られたポリマーが好適に用いられる
As the superabsorbent polymer used in this invention, a polymer obtained by the production method shown below is preferably used.

すなわち、高分子分散剤を溶解した脂肪族炭化水素溶媒
中で、アクリル酸とそのアルカリ金属塩水溶液を分散し
、逆相懸濁重合させ、更に共沸脱水時、2個以上の官能
基を有する架橋剤で架橋せしめてなる高吸水性ポリマー
である。
That is, acrylic acid and its alkali metal salt aqueous solution are dispersed in an aliphatic hydrocarbon solvent in which a polymeric dispersant is dissolved, and subjected to reverse phase suspension polymerization. It is a super absorbent polymer that is crosslinked with a crosslinking agent.

上記製造方法のより詳細は、この発明の出願人が先に特
願昭63−38638号(特開平1−213307号)
として出願した特許出願中に詳しく記載されているので
、ここではその説明を省略するが、これに基づいて製造
されたものが、本出願人である大阪有機化学工業株式会
社より、「PQポリマーBL−100Jの商標で販売さ
れており、これをそのまま前記の方法で消火水中に混入
させることで実現できる。
More details of the above manufacturing method are disclosed in Japanese Patent Application No. 63-38638 (Japanese Unexamined Patent Publication No. 1-213307) by the applicant of the present invention.
As it is described in detail in the patent application filed as ``PQ Polymer BL'', the explanation will be omitted here. It is sold under the trademark -100J, and can be achieved by directly mixing it into fire extinguishing water using the method described above.

この発明では、好ましい高吸水性ポリマーとして、膨張
倍率が1゜5倍以上の球状のポリマーを用いることから
、吸水後のポリマー粒子間の付着水が少なく、粒子間の
空隙が大きい。そのため、粒子同士の付着力が小さく、
非常に滑り易い。これにより、実質的なベタつきがない
。しかも、水に対する溶出率が5%以下であることから
、放出された消火水を消火後に速やかに吸収して、消火
水が機器類や壁面に浸透するのを防止し、かつ、壁面等
から容易に分離し又滑落するので、回収作業が容易であ
り、吸引式の大型の掃除機等で容易に回収できる。
In this invention, since a spherical polymer with an expansion ratio of 1.5 times or more is used as a preferable superabsorbent polymer, there is little water adhering between polymer particles after water absorption, and the voids between the particles are large. Therefore, the adhesion force between particles is small,
Very slippery. As a result, there is virtually no stickiness. Moreover, since the elution rate with respect to water is less than 5%, it can quickly absorb the released fire extinguishing water after extinguishing the fire, prevent the extinguishing water from penetrating into equipment and walls, and easily remove it from walls, etc. Since it separates and slides down, it is easy to collect it, and it can be easily collected using a large suction type vacuum cleaner or the like.

なお、上記PQポリマーBL−100の性状は以下の通
りである。
The properties of the PQ polymer BL-100 are as follows.

外観    白色粉末 平均粒度  70〜150μm かさ比重  0.95〜1,00 含水率   5%以下 溶出率   2%以下 吸水能   脱イオン水 70〜200倍膨張倍率  
2〜3倍 耐熱温度  150〜200℃ 実施例 次に、この発明の方法及び装置の具体的な実施例を説明
すると、第1図では、消火水ポンプ(1)の吸い込み側
ホース(2)の途中にポリマー供給ホース(5)の一端
を接続し、その他端を、この発明の高吸水性ポリマー(
3)を収容した容器(4)へ接続したもので、消火水ポ
ンプ(1〕の吸引力によって発生する吸い込み側ホース
(2)内の負圧により、容器(4)内の高吸水性ポリマ
ー(3)がこのホース(2)へ自動的に吸い込まれ、そ
のホース(2)内で水(8)中へ混入されて吐出側ホー
ス(6)より放出される。(7)は、供給ホース(5)
の途中に設けた開閉弁である。
Appearance White powder Average particle size 70-150 μm Bulk specific gravity 0.95-1,00 Water content 5% or less Elution rate 2% or less Water absorption capacity Deionized water 70-200 times expansion ratio
2 to 3 times heat resistant temperature 150 to 200°C Example Next, a specific example of the method and apparatus of the present invention will be described. In FIG. Connect one end of the polymer supply hose (5) to the middle, and connect the other end to the super absorbent polymer (5) of the present invention.
The super absorbent polymer (3) in the container (4) is connected to the container (4) containing the super absorbent polymer ( 3) is automatically sucked into this hose (2), mixed into the water (8) within the hose (2), and discharged from the discharge hose (6). 5)
This is an on-off valve installed in the middle.

第2図は、逆に、吐出側ホース(6)先端の放水ノズル
(9)直前に、前記供給ホース(5)を接続したもので
あり、その作用は、第1図の場合と同じである。
In Fig. 2, on the other hand, the supply hose (5) is connected to the discharging hose (6) immediately before the water nozzle (9) at the tip, and its function is the same as in Fig. 1. .

第3図は、上記のように消火水ポンプ(1)のホース(
2)(6)へ接続することなく、供給ホース(5)の先
端に、ポリマー放出ノズルαQを取り付けて、消火水ポ
ンプ(1)の放水ノズル(8)より放出されろ水(8)
と同時に、火炎へ向けて放出させてその水(8)へ混入
させるものである。
Figure 3 shows the fire water pump (1) hose (
2) Attach the polymer discharge nozzle αQ to the tip of the supply hose (5) without connecting to (6), and the filtrate (8) is discharged from the water discharge nozzle (8) of the fire water pump (1).
At the same time, it is released toward the flame and mixed into the water (8).

発明者らの実験では、上記第1図と同じ方法で行ったと
ころ、消火水ポンプ(1)のホース(2)(6)中で混
合された水(5)とポリマー(3)が白い泡状となって
噴出し、消火能力には殆ど影響ないことが確かめられた
。また、その回収も前記のような大型掃除機で簡単に行
なうことができた。受木部の回収後の状況は、非常に良
好であった。
In the experiment conducted by the inventors in the same manner as shown in Fig. 1 above, the water (5) and polymer (3) mixed in the hoses (2) and (6) of the fire water pump (1) formed white foam. It was confirmed that there was almost no effect on the fire extinguishing ability. In addition, it could be easily collected using a large vacuum cleaner such as the one mentioned above. The condition of the wood receiving area after collection was very good.

発明の効果 以上のように、この発明の消火方法及び消火装置によれ
ば、消火水中に混入される高吸水性ポリマーが、消火後
の水を吸収してベタつきのないゲル状となり、機器類や
壁面或いは床面から吸水した水と共に容易に分離される
ので、それらの二次災害を防止して、経済的損失を最小
限に止めることができる。また、この発明の方法及び装
置では、消火水ポンプのホース中で混入させる場合には
、そのホースの途中にポリマー供給用のホースを接続す
るのみでよく、他方、放出した消火水中に混入させる場
合には、ポリマー放出装置を準備するだけで良いから、
既存の装置の大幅な改造が不要であり、比較的低コスト
で実施できるという効果がある。
Effects of the Invention As described above, according to the fire extinguishing method and fire extinguishing device of the present invention, the super absorbent polymer mixed in the fire extinguishing water absorbs the water after extinguishing the fire and becomes a non-sticky gel-like substance, which makes it easy to clean equipment and equipment. Since it is easily separated from the water absorbed from the wall or floor, secondary disasters can be prevented and economic losses can be minimized. Furthermore, in the method and apparatus of the present invention, when the polymer is mixed in the hose of the fire extinguishing water pump, it is only necessary to connect a hose for supplying the polymer to the middle of the hose.On the other hand, when the polymer is mixed into the discharged fire extinguishing water All you need to do is prepare a polymer release device.
This method has the advantage that it does not require major modification of existing equipment and can be implemented at relatively low cost.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図〜第3図は、それぞれこの発明の実施例を示す模
式図である。 (3)・・・高吸水性ポリマー、(8)・・・消火水。
FIGS. 1 to 3 are schematic diagrams showing embodiments of the present invention, respectively. (3)...Super absorbent polymer, (8)...Fire extinguishing water.

Claims (1)

【特許請求の範囲】 1、高吸水性ポリマーを消火水中に混入させて放水する
か又は放水された消火水中へ混入させることを特徴とす
る消火方法。 2、高吸水性ポリマーが溶出率5%以下、膨張率1.5
倍以上の実質的にベタつきのない球状である請求項1記
載の消火装置。 3、放水するか又は放水された消火水中に、高吸水性ポ
リマーを混入させることを特徴とする消火装置。 4、高吸水性ポリマーが溶出率5%以下、膨張率1.5
倍以上の実質的にベタつきのない球状である請求項3記
載の消火装置。
[Scope of Claims] 1. A fire extinguishing method characterized by mixing a super absorbent polymer into fire extinguishing water and discharging the same, or mixing it into the discharged fire extinguishing water. 2. Super absorbent polymer elution rate is 5% or less, expansion rate is 1.5
2. The fire extinguishing device according to claim 1, which has a substantially non-sticky spherical shape. 3. A fire extinguishing system characterized by spraying water or mixing a super absorbent polymer into the sprayed fire extinguishing water. 4. Super absorbent polymer elution rate is 5% or less, expansion rate is 1.5
4. The fire extinguishing device according to claim 3, which has a substantially non-sticky spherical shape.
JP9486790A 1990-04-09 1990-04-09 Fire extinguishing methods and fire extinguishing equipment Pending JPH03292969A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP9486790A JPH03292969A (en) 1990-04-09 1990-04-09 Fire extinguishing methods and fire extinguishing equipment

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP9486790A JPH03292969A (en) 1990-04-09 1990-04-09 Fire extinguishing methods and fire extinguishing equipment

Publications (1)

Publication Number Publication Date
JPH03292969A true JPH03292969A (en) 1991-12-24

Family

ID=14121997

Family Applications (1)

Application Number Title Priority Date Filing Date
JP9486790A Pending JPH03292969A (en) 1990-04-09 1990-04-09 Fire extinguishing methods and fire extinguishing equipment

Country Status (1)

Country Link
JP (1) JPH03292969A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0774279A1 (en) * 1995-11-14 1997-05-21 Stockhausen, Inc. Water additive and method for fire prevention and fire extinguishing
GR1002790B (en) * 1996-07-22 1997-10-17 Methods and products for extinguishing fires.
US7033526B2 (en) 2001-08-24 2006-04-25 National Starch And Chemical Investment Holding Corporation Fire retardant foam and gel compositions
JP2008518735A (en) * 2004-11-05 2008-06-05 バリケイド インターナショナル インコーポレイテッド How to prevent and / or extinguish a fire
CN103483752A (en) * 2012-10-08 2014-01-01 廊坊中安消防科技有限公司 Preparation method of superabsorbent resin used for high-molecular gel extinguishing agent, and extinguishing agent using superabsorbent resin

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0774279A1 (en) * 1995-11-14 1997-05-21 Stockhausen, Inc. Water additive and method for fire prevention and fire extinguishing
AU718417B2 (en) * 1995-11-14 2000-04-13 Stockhausen Gmbh & Co. Kg Water additive and method for fire prevention and fire extinguishing
GR1002790B (en) * 1996-07-22 1997-10-17 Methods and products for extinguishing fires.
WO1998003228A1 (en) * 1996-07-22 1998-01-29 Innoval Management Limited Method and products to face fires
US6209655B1 (en) 1996-07-22 2001-04-03 Innoval Management Limited Method and products to fight fires
AU732008B2 (en) * 1996-07-22 2001-04-12 Innoval Management Limited Method and products to face fires
EA001490B1 (en) * 1996-07-22 2001-04-23 Инновэл Менеджмент Лимитед Method and products to face fires
US7033526B2 (en) 2001-08-24 2006-04-25 National Starch And Chemical Investment Holding Corporation Fire retardant foam and gel compositions
JP2008518735A (en) * 2004-11-05 2008-06-05 バリケイド インターナショナル インコーポレイテッド How to prevent and / or extinguish a fire
CN103483752A (en) * 2012-10-08 2014-01-01 廊坊中安消防科技有限公司 Preparation method of superabsorbent resin used for high-molecular gel extinguishing agent, and extinguishing agent using superabsorbent resin

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