JPS5869569A - DIY transparent gel body - Google Patents

Abstract

(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.

Description

[Detailed description of the invention] The invention relates to decorative DIY transparent gel bodies.

In the past, gel-based air fresheners were stored in opaque containers, so the appearance was hardly aesthetically pleasing, and the gel-based air fresheners were often stored in opaque containers. However, this method has the disadvantage that it does not reduce the change over time of 1.721, and the 1.721 gel blended in the 1.721 gel decreases over time, resulting in a decrease in the product value. was.

The present invention has been made as a result of intensive research to eliminate the above-mentioned drawbacks of the conventional technology.In other words, the present invention is a DIY transparent gel body that is stored in a suitable container and used. A DIY transparent gel body with decorative properties, characterized in that it can be produced using gel body material I water.

(1) 1 to 5 pieces of transparent gel body material (I) IY transparent gel body number with decorative properties as described in claim 1, characterized in that it is packaged and cut.

As mentioned above, on the one hand, the present invention is a DIY method in which the user mixes the mixture appropriately at the time of use, so it combines the pleasure of making and the pleasure of viewing.
It is possible to use decorations of your choice, it is possible to change the appearance of the product over time during distribution, and if water is not attached, that is, if the user prepares only water separately, the packaging form is better. It can be made small and lightweight, and the cost can be reduced.On the other hand, since it is made of a transparent gel, which is not found in conventional products, decorations such as fresh flowers, artificial flowers, or imitation fruits can be placed inside. However, it is completely different from conventional fragrances, and has many features such as being able to enrich human emotions not only olfactory but also visually, making it even more valuable as a product.

The transparent gel material used in the invention consists of a combination of super absorbent synthetic resin A, turben) B, a substance volatile at room temperature, and a surfactant C1, and one example of the combination is ■A + J3 C, ■A1B-1-CL),
■A, B -1-CD, ■ABC, ■AB+C can be raised. (2), (2), and (2) use the supplied water, or the user simply adds water at the time of use, and the DIY transparent gel of the present invention works. The transparent gel (4) of the present invention can be obtained by simply opening the previously packaged product, placing it in a suitable container, and mixing.

In the present invention, the superabsorbent synthetic resin that is a component of the transparent gel material is a polymerizable monophosphor that is water-soluble or becomes water-soluble by hydrolysis in polysaccharides such as starch and cellulone, for example, Acrylic acid, methacrylic acid, acrylate, tutaacrylate, acrylic ester,
Methacrylic acid, acrylamide, methacrylic acid amide, acrylonitrile, methacrylonitrile,
Hydrophilic polymers obtained by graft polymerization of maleic acid, sulfonated nutyrene, polyvinylpyridine, etc., or oligomers or cooligomers thereof, and hydrophilic polymers hydrolyzed as necessary after craft polymerization, or
Crosslinking of hydrophilic polymers such as polyethylene oxide, polyethylene oxide 1, polyvinylpyrrolidone, nulphonated polystyrene, polyvinifrepyridine, polyacrylate, polyacrylic acid amide, polymethacrylic acid salt, polymethacrylic acid amide, etc. ~ 11 frames A material that is three-dimensionally polymerized can be used.

Examples of the crosslinking agent include ethylene glycol, trimethylolpropane, glycerin, polyoxyethylene glycol, polyoxypropylene glycol, etc. or triacrylic acid or methacrylic acid ester/I/ ! tt, unsaturated polyesters obtained by reacting the polyols with unsaturated acids such as maleic acid, bisacrylamides such as N,N-methylolated acrylamide, and reacting polyepoxides with acrylic acid or methacrylic acid. Di- or triacrylic acid or methacrylic acid esters obtained by reacting polyiso-5-cyanates such as tolylene diisocyanate and hexamethylene diisocyanate 1 with hydroxyethyl acrylate or hydroxyethyl methacrylate. carbamyl esters of acids or diacrylic acids I;
Examples include allylated starch, allylated cellulose, etc., which can optionally be crosslinked under certain reaction conditions such as methylolated acrylamide, methylolated methacrylamide, glyoxal, phthalic acid, adipic acid, ethylene glycol, etc. Difunctional compounds or polyvalent metal compounds such as calcium oxide, zinc diacetate, etc. can also be used.

The superabsorbent synthetic resin obtained in this way does not emit an undesirable odor as an aromatic substance when mixed with an aqueous solution or emulsion of a fragrance, and when gelled, Any transparent material can be used as the DIY transparent body 9 material according to the present invention.

In this regard, the room temperature volatile substances include various substances that have been traditionally used for purposes such as insecticidal, sterilizing, attracting, repelling, insect repelling, mold-proofing, fragrance, and deodorizing. Can be used.

1. Insecticide oa-cyano-3-phenoxybenzyl 2.2.8.8
-Tetrameth! Resichloropropanecarboxylate al-I tenyl-2-methyl-2-pentenyl 2゜2,
8.8-te1-lanotylcyclopropane rupoxylate ol-ethynyl-2-methyl-2-pentenyl 2゜2-
Dinotyl-8-(z,'2'-dichloroviny/I/)-
Cyclopropane-l-carboxylate o1-ethynyl-2-methyl-2-bentail 2゜2-dimethyl-8-
(2'-methyl-1'-prope=1)-cycloglopanka! Levoxylate 7-o D, DVP 2, Pest Repellent 0 Dimethyl Phthalate 02, 8.4.5. -Binu (△2-butylene)-tetrahydrofuran 02, 8.4.5-Binu (△2-butylene)-tetrahydrofurfuryl alcohol ON, N-diethyl-m-toluamide 0 Cagrilic acid diethylamide '2. ．． (,4,5-bis-2-butylene)-tetrahydrofurfural 0 S-n-propyl-isocincomeronate 0 2M butylstyryl ketone 0 nonyl nutyryl. K1, N, N-10 pylacetanilide 02-ethyl-1,3-hexanedio-! 8-0 succinic acid ester/l/(e.g. dibutyl succinate, dibutyl succinate 07 toxymethyl o2-butoxyethyl!1 no 2-furfridene acetate O dibutyl phthalate 0te1-rahydrothiophene O β-su) 7-7 Diallyl disulfide 0 bis(dimethylthiocarbamoyl)dis? Refid 3, fungicide O parachloromethacrylenol O ethyl realcorshi 4, insect repellent O paradichlorpenzole O V gunou 0 naphthalene 5 deodorizer (deodorant) 0 lauryl methacrylate, geranyl crotonate, Acetophenone millimethiacetate, paramethylacetophenone benzaldehyde, benzyl acetate, benzyl propionate, amyl cinnamic alcohol, anisic aldehyde, diphenyl oxide, methyl benzoate, ethyl benzoate, methyl phenylacetate, ethyl phenylacetate, neolin, safrole , Cedau sodo oil, Seta mustard oil,
Citronella oil, Lavantene oil, Pettigrain oil, Lemon Granine oil.

6. Natural fragrances include animal fragrances such as java incense, eineko incense, and dragon tang incense, avinis oil, ajokun oil, almond oil, angelica late oil, pagel oil, bergamotu oil, birch oil, boa burrose oil, and cypress oil. Oil, cananga oil, kapungkam, caraway oil, cardamom oil, cassia oil, celery oil, cinnamon oil, citronella oil, konjac oil, coriander oil, cuvep oil, cumin oil, camphor oil, dill oil, estgolan oil, neelika oil, fennel oil, garlic oil, ginger oil, gray 7'' oil, hop oil, juniper perilla oil, laurel leaf ura, lemon oil, lemon granule oil, lovage oil, Maine oil, nutmeg oil, mandarin Contains vegetable flavorings such as oil, tangerine oil, apricot oil, peppermint oil, orange blossom oil, onion oil, pepper oil, orange oil, sage oil, star anise oil, turpentine oil, wormwood oil, and wanilla bean equinutrate.

Artificial fragrances are synthetic or extracted fragrances, such as hydrocarbons such as pinene and limonene, alcohols such as linalool, geraniol, citronellol, menthol, forneol, pensyl alcohol, anise alcohol, and β-hue-7-lethyl alcohol. − Phenols such as, annenol, eugenol, etc.
n-butyglyaldehyde, isobuty! Realdehyde, hexyl-realdehyde, heptylaldehyde, n-nonylaldehyde, nonajenal, cyto-aldehyde, citronellal, benzaldehyde, cinnamic aldehyde, heli-aldehyde, vanillin, etc., methyl amyl ketone, Ketones such as methyl nonyl ketone, diacetyl, acetyl propionyl, acetyl butyryl, carvone, menthone, camphor, a±tophenone, P-methylacetophenone, ionone, amylbutyrolactone, ethyl methylphenylglycidate, r- Lactones or oxides such as Irelactone, coumarin, cineole, methylformate, inglobilformate, linary? Reformate, ethylpyruvate, octyl acetate, menthyl acetate, benzyl acetate, cinnamyl 12-acetate, butyl propionate, isoamyl acetate, isopropyl isoacetate, geranyl isovalerate, caproic acid, butyl heptyl, caprylic acid octyl, heptinecaleponate, ethyl perahagonate,
Methine octyne carboxylate, isoane capric acid,
Methyl laurate, ethyl myristate, ethyl benzoate, benzoic acid, methyl phenylacetate, butyl phenylacetate, methyl cinnamate, cinnamyl cinnamate, methyl salicylate, ethyl anisate, methyl anthranilate, ethyl pyruvate, Contains ethers such as ethyl α-butyl butyrate.

Only one type of fragrance may be used, or it may be a combination of two or more types.

Along with perfumes, volatile retention agents such as patch lily oil, modulators such as eugenol +/, and various other ingredients used in the f+h perfumery industry may be added.

In the present invention, the decorative bodies that may be accommodated in the container along with the transparent gel body as necessary include fresh flowers, artificial flowers, imitations, fish such as Chinese cabbage, imitations, animals such as Chinese cabbage, imitation plants, imitation fruits, etc. Vines exemplify ornamental objects alone or in combination. Furthermore, as general decorations, sequins, pear powder, and aurora film can be used alone or in combination with the above. By using these, the ornamental properties and decorative properties of the transparent gel body can be further enhanced.

The decorative body may be provided with legs, a stand, nylon thread, etc. in advance or during use.

It is preferable that the legs and stand should be of a size that does not interfere with the viewing or decoration when placed in a suitable container, and should be of the minimum size and form possible, or should be of good transparency, and should be as small as possible. It is best to choose a color that is inconspicuous. By providing the legs and the stand, there is an advantage that it is possible to prevent the decorative object from falling over when it is placed in the storage body, and to make it possible to store it in a desired state.

In accordance with the present invention, the amount of the super absorbent synthetic resin is about 50 to 01% by weight, preferably about 10% by weight, when added to water such as a perfume aqueous solution, and within this range. Even if it exceeds, it can be increased or decreased depending on conditions such as gelation time. However, if the proportion of super absorbent synthetic fat-resistant resin is too high, it will take too much time to form a gel, and if it is too small, the fluidity of the gel will increase and the container may be blown away. This is not desirable as it may sometimes cause accidents such as leakage.

In addition, in order to improve the strength and persistence of odor, improve transparency, and shorten gel formation time, alcohols such as ethanol and methanol, and/or propylene glycol, 15-glycerin, etc. Polyhydric alcohols and the like can also be added. The amount of these acids added is desirably about 0.5 to 50% by weight based on water; if the amount of added acid is too large, gel formation tends to be insufficient, which is not preferred. However, if you want to extend the gelation time,
The above alcohols and polyhydric alcohols may not be used.

Furthermore, an emulsifier can be added to disperse the fragrance.

Emulsifiers are not particularly limited as long as they are transparent, but generally include fatty acid salts, higher alcohol sulfate esters/L' salts, alkylbenzene sulfonates, alkyl phosphates, alkylamine salts, and polyoxyethylene alkyls. A cationic, anionic or neutral surfactant such as amine, sorbitan mononutearate, sorbitan trioleate, etc. is used and emulsified using a homogenizer or the like. The number of emulsifiers used is generally 16
- Approximately 0.5-10.0% of water.

In the present invention, the shape of the container is arbitrary as long as it can accommodate the transparent gel body, and any shape can be selected in advance or upon use as long as it has at least a transparent portion. For example, bags, packs, cycle pipes, cylindrical, conical, prismatic, pyramidal, spherical, pot-shaped, tube-shaped containers, etc. that can be hung, hung, or placed on top of each other. can be exemplified.

As the container to be attached in advance, a container with a scale indicating a constant water level, a stain-proof container treated with silicone oil, a combination container thereof, a large assembled container, a large hanging container, etc. can be used. In this case, since it is attached in advance, the storage body has the advantage that it can also be used as a container for transporting and packaging the transparent gel material. In the following, non-inventive embodiments will be described in detail.

Example 1 Pre-mixed fragrance solution in a 200 ml transparent container [400 g of glycerin, 2.0 g of polyoxyethylene lauryl ether and fragrance FG-1 (manufactured by Kobayashi Perfume ■)
8.6 g), and then starch acrylic acid graft polymer (Sunwet IM-300 (Sanyo Chemical Industries 11)
After adding 6.99 (manufactured by U) and stirring and dispersing, boiled water 14
8 g was added and left at room temperature for about 30 minutes to obtain a gel-like transparent aromatic substance.

Example 2 A mixture prepared in advance in a 200 wt transparent glass container [1.6 g of acrylic polymer Aqua Keep 4S (manufactured by Seitetsu Kagaku Kogyo II!ll), ethyl cellosolve 40
, 0 g, polyoxyethylene oleyl ether 2.0
9 and fragrance D-6 (Kobayashi fragrance +1!1li) 6.9g)
After stirring and dispersing, add 150g of tap water and bring to a boil.
It was stored at 0 to 0°C for about 24 hours to obtain a gel-like transparent aromatic substance.

Example 3 A mixture prepared in advance in a 200 ml transparent glass container [sodium polyacrylate crosslinked product Aqua IJ]
yri CA (Nippon Shokubai Kagaku Kogyo special product 2.49, polyethylene glyco-/I/300.40.0 g polyoxyethylene noni! lephenyl ether 2.0 g, and fragrance Q
14 (Kobayashi Fragrance ##) 2.0g) and stirred for several minutes, the air in the system was completely degassed and packaged water 15
4 g was added and allowed to stand at room temperature for about 80 minutes to obtain a gel-like transparent aromatic substance.

Example 4 200m1CD3fl light tx u Rg jc approx. 80'
After adding 148 g of boiling water, add the pre-blended mixture [vinyl alcohol/acrylate copolymer Numikakel (Sumitomo Chemical ■1llR) 4. Of, ethylene glycol 40. After shaking well, 2.0 g of polyoxyethylene 00 sorbicun 19-monolaureto, and 6.0 g of the fragrance Osmanthus Bamboo 9 (manufactured by Kobayashi Perfume @ J) were added, and the mixture was left to cool at room temperature for about 1 hour to form a gel. A transparent aromatic body was obtained.

Example 5 149 g of water was placed in a 200 liter transparent Brafchick container, the air inside the container was completely removed and the lid was removed, and the pre-blended mixture [isoprene maleic acid copolymer KI Gel Kuraraisoban GH (
Shake well 8.2 g of Kuraray Isoprene Chemical/L/40.0 Q, 2.0 g of polyoxyethylene polyoxypropylene cetyl ether, and the fragrance Hydrangea A 8 (Kobayashi Perfumery Special) 5,69). After adding the liquid, insert 5 to 7 small artificial flowers into the liquid.
After standing for about 30 minutes at room temperature, a gel-like transparent and decorative aromatic body was obtained.

=20 Example 6゜Propylene glycol 6 in a 200 liter transparent glass container
, Of and modified polyacrylic acid soda (manufactured by Showa Denko @3)
After adding 40 g of the fragrance aqueous solution [Propylenc! J: ]-le 40
．． Og, polyoxyethylene nonylphenyleniter 2
0g, Fragrance DN-159 (Kobayashi Fragrance Special) 4. Of1'
, and 144 ml of water] were added, one artificial flower was inserted into this liquid, and the mixture was left to stand at room temperature for about 30 minutes to obtain a gel-like transparent aromatic body with decorative properties.

Example 7 Polymer solvent mixture [modified polyacrylonitrile!] pre-mixed and packaged in a 200 ml transparent container. After adding 6.0 g of Reespenok (Japanese Exnulan ff) and 40.0 iF of ethylene glycol dimethyl ether, 8.0 g of a fragrance aqueous solution [polyoxyethylene monostearate] was packaged to completely remove air from the system.
, fragrance IU-7 (Kobayashi fragrance special product) 6, Og, and water 14
5 g) was added, two glass ornamental fish were inserted into this liquid, and the mixture was left to stand at room temperature for about 30 minutes to obtain a gel-like transparent aromatic body with decorative properties.

Example 8 146 g of tap water was placed in a 200 ml transparent container, and a fragrance liquid [polyoxyethylene hydrogenated castor oil 8. After dissolving AA-12 (Kobayashi Perfume Specialty) 5.09), pre-mixed and packaged polymer solvent mixture [ethylene glycol dimethyl ether 400g, modified starch WAS (manufactured by Nichijo Kagaku ■) 6.
One Planutinok doll was inserted into the solution and stored at -10 to OCT for about 24 hours to obtain a gel-like transparent aromatic body with decorative properties.

Claims (1)

[Claims] A DIY transparent gel body that can be stored and used in a suitable storage case, which includes scales made by using water in a transparent gel body material prepared in advance. DIY transparent gel body with distinctive decorative properties. (2) The decorative DIY transparent gel body according to claim 1, characterized in that the transparent gel body material is packaged in 1 to 5 pieces.