JPS59111183A - Sticking electrostatic sheet and sticking method - Google Patents
Sticking electrostatic sheet and sticking methodInfo
- Publication number
- JPS59111183A JPS59111183A JP22077482A JP22077482A JPS59111183A JP S59111183 A JPS59111183 A JP S59111183A JP 22077482 A JP22077482 A JP 22077482A JP 22077482 A JP22077482 A JP 22077482A JP S59111183 A JPS59111183 A JP S59111183A
- Authority
- JP
- Japan
- Prior art keywords
- sheet
- electrostatic
- pasting
- sticking
- electrostatic sheet
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000034 method Methods 0.000 title claims description 14
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 4
- 229910052731 fluorine Inorganic materials 0.000 claims description 4
- 239000011737 fluorine Substances 0.000 claims description 4
- 229920000642 polymer Polymers 0.000 claims description 4
- 230000001070 adhesive effect Effects 0.000 description 10
- 239000000853 adhesive Substances 0.000 description 9
- 239000004744 fabric Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000004381 surface treatment Methods 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 229920000840 ethylene tetrafluoroethylene copolymer Polymers 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 230000003068 static effect Effects 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 1
- 239000012790 adhesive layer Substances 0.000 description 1
- 239000002390 adhesive tape Substances 0.000 description 1
- 238000003486 chemical etching Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000003851 corona treatment Methods 0.000 description 1
- 238000004049 embossing Methods 0.000 description 1
- 229920002313 fluoropolymer Polymers 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- -1 polytetrafluoroethylene, ethylene-tetrafluoroethylene copolymer Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 238000000992 sputter etching Methods 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 230000002747 voluntary effect Effects 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Landscapes
- Laminated Bodies (AREA)
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】
本発明は壁面等の被貼着物に軽度の接着性を有する貼着
用静電シートとその貼着方法に関する。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to an electrostatic sheet for pasting that has slight adhesiveness to objects to be pasted, such as walls, and a method for pasting the same.
従来、一般に貼着用シートとしては、粘着層を形成して
なる粘着シート等が用いられているが、本発明はこのよ
うな従来物品とは全く異なる新規な貼着用静電シートと
その粘着方法に係るもので、本発明によると被貼着物表
面に各種紙葉材料を固定する場合、単に本発明の貼着用
静電シートとそ貼着用方法を実施することにより極めて
簡単に初期の目的の達成”が可能になり、しかも再使用
が可能のなったものである。Conventionally, adhesive sheets formed with an adhesive layer have generally been used as adhesive sheets, but the present invention provides a new electrostatic adhesive sheet and its adhesive method that are completely different from such conventional products. Accordingly, according to the present invention, when fixing various paper materials to the surface of an object to be adhered, the initial objective can be achieved very easily by simply implementing the electrostatic sheet for pasting and the method for pasting the same of the present invention. It has become possible to do this, and it is also reusable.
即ち、木発明の特徴とするところは体積抵抗＋９
率ｌＯΩ−ＣＩ１１以上のフッソ系重合体からなり、か
つ被貼着物に対し、適度の接着性を有する貼着用静電シ
ート、及び体積抵抗率ｌＯΩ−Ｃ１１以上のフッソ系重
合体からなるシートをその静電気的作用により、被貼着
物表面に適度に接着せしめてなる貼着用静電シートの貼
着方法を見出した点にある。In other words, the characteristics of the invention are: an electrostatic sheet for pasting, which is made of a fluorocarbon polymer having a volume resistivity of +9 and a ratio of lOΩ-CI of 11 or more, and has appropriate adhesion to the object to be pasted, and a volume resistivity of lOΩ The present invention is based on the discovery of a method for attaching an electrostatic sheet for attaching, which comprises adhering a sheet made of a fluorine-based polymer of -C11 or higher to the surface of an object to be adhered appropriately by its electrostatic action.
木発明に係るフッソ系重合体とはポリテトラフルオロエ
チレン、エチレン−テトラフルオロエチレン共重合体、
テトラフルオロエチレン−パーフルオロアルキルビニル
エーテル共重合体等を例示でき、特に制限はないが、こ
れらのうち体積抵抗率１０”０− ａｍ以−上のものが
好んで用いられる。１０”０− ｃｍ以下のものは静電
気の発生に乏しく、従って被貼着物に対し接着性を有し
にくい而があるか、もしくは数日ではがれるため貼着用
としては利用し難い面もあった。被貼着物としては前記
の通り各種壁面、カラス面、金属材料面、板面等を例示
でき特に制限を受けるものでなく、また、適度の接着性
とは限定的意味を有するものでないが、通常の白壁面に
付着して１ケ月以上、好ましくは数ケ月間に渡ってずり
落ちることがない程度、及び大きな力を加えることなく
はがすことができる程度を、一応の目安としており、通
常の粘着テープ程、接着力がなくても十分である６要は
必要に応じ適宜の接着性を有するものであればよい。係
る貼着用静電シートはその貼着使用前に必要箇所を軽く
摩擦すると一層静電気の発生が顕著となり、その接着力
が増強することもあるので、こうした使用法を検討する
ことにより、その応用範囲は一層増大することも考えら
れる。The fluorine-based polymer according to the wood invention includes polytetrafluoroethylene, ethylene-tetrafluoroethylene copolymer,
Examples include tetrafluoroethylene-perfluoroalkyl vinyl ether copolymers, etc., and although there are no particular limitations, those with a volume resistivity of 10"0-am or more are preferably used. 10"0-cm or less They do not generate enough static electricity, and therefore have difficulty in adhesion to objects, or they peel off within a few days, making them difficult to use for pasting purposes. Examples of objects to be adhered to include, as mentioned above, various wall surfaces, glass surfaces, metal material surfaces, plate surfaces, etc., and there are no particular restrictions.Also, moderate adhesion does not have a limiting meaning, but usually As a rough guideline, the adhesive tape should adhere to the white wall surface for at least one month, preferably several months, without falling off, and that it can be removed without applying a lot of force. 6. It is sufficient even if there is no adhesive force.The 6 points are sufficient as long as they have appropriate adhesive properties as required. When such an electrostatic sheet for pasting is lightly rubbed on the required area before being used for pasting, the generation of static electricity becomes more pronounced and the adhesive force may be strengthened. It is also conceivable that the amount will increase further.
次に本発明に係る１、２の実施例を述べつつ、その使用
法と好ましい実施態様を示す。Next, while describing one or two embodiments of the present invention, its usage and preferred embodiments will be shown.
〈実施例１〉
第１図は本発明に係るエチレン−テトラフルオロエチレ
ン共重合体からなる厚さ２５終、４０×３０ｃｍの貼着
用静電シート（１）（体積抵抗率１０Ω−ｃｍ）を用い
、白壁面（２）に厚さ８０ＩＬ、３０Ｘ２０ｃｍのメモ
書（３）を貼着した状態を示すもので、この際、壁面（
２）とシート（りは適度に接着しており、手ではぐらな
いと両者は分離しなかった。一方手ではぐった後はメモ
書用紙は何ら損傷等の起こることもなく、貼着前の状態
と全たく同じであった。また、はがしたシートを軽く摩
擦した後、再び使用することができた。<Example 1> Figure 1 shows an electrostatic adhesive sheet (1) made of the ethylene-tetrafluoroethylene copolymer according to the present invention with a thickness of 25 mm and a size of 40 x 30 cm (volume resistivity: 10 Ω-cm). , shows a state in which a memo (3) with a thickness of 80 IL and 30 x 20 cm is pasted on a white wall surface (2).
2) and the sheet (glue) were moderately adhered, and the two did not separate unless they were pulled apart by hand.On the other hand, after being pulled out by hand, the memo paper was not damaged in any way, and remained in its original state before being pasted. It was exactly the same as the sheet.Furthermore, after lightly rubbing the removed sheet, it was possible to use it again.
本発明における体積抵抗率の測定法としては、ＡＳＴＭ
−Ｄ２５７−６１に記載された方法によるものである。As a method for measuring volume resistivity in the present invention, ASTM
-D257-61.
一般に帯電圧の数値化については体積抵抗率の外に、Ｊ
ＩＳ−Ｌ１０９４−１９８０ｒＩ＆物及び編物の帯電圧
試験方法Ｂ法」に準じて行なわれる摩擦帯電圧の値も参
考にしており、実施例（１）及びポリ塩化ビニールフィ
ルムの体積抵抗率及び摩擦帯電圧の比較を次表に示す。In general, in order to quantify electrostatic voltage, in addition to volume resistivity, J
The value of the frictional charging voltage conducted in accordance with IS-L1094-1980rI & Method B for testing the charging voltage of fabrics and knitted materials is also used as a reference, and the volume resistivity and frictional charging voltage of Example (1) and polyvinyl chloride film are also referred to. A comparison is shown in the table below.
第１表
※摩擦帯電圧については摩擦布として綿布を用いた際の
データで、その１分後の帯電圧も併せて記載した。Table 1 *The frictional charging voltage is data when cotton cloth was used as the friction cloth, and the charging voltage 1 minute later is also listed.
〈実施例２〉
第２図に示すは実施例（１）と同じ体積抵抗率を有する
同じ大きさの袋状物（４）を予じめ作成しておき、これ
を白壁面（２）に貼着せしめたもので、これは開口部（
５）から適宜の書類や実施例（１）と同様のメモ書（２
）を出し入れできるようになっている。こうしておくと
袋と各遺書類のサイズの等しいものでも簡単に壁面に添
付できる利点もある。また、開口部は封緘自在であって
もかまわない。<Example 2> As shown in Fig. 2, a bag-like object (4) of the same size and the same volume resistivity as Example (1) is prepared in advance, and this is placed on a white wall surface (2). This is the opening (
5) to appropriate documents and memo (2) similar to Example (1).
) can be put in and taken out. This has the advantage that even if the bag and each document are of the same size, they can be easily attached to the wall. Further, the opening may be freely sealed.
以上の如く本発明は本発明に係る貼着用静電シートを少
なくともその裏面要部に有する袋状物もその範囲内のも
ので、シートから作成される加工物も当然その範囲に含
まれるものである。また、こうしたものはその裏面を適
宜に摩擦すると一層接着力が増大する。As described above, the scope of the present invention includes a bag-like article having the electrostatic sheet for pasting according to the present invention on at least the main part of its back surface, and naturally also includes processed products made from the sheet. be. Moreover, if the back surface of such a material is appropriately rubbed, the adhesive force will be further increased.
のシートを用い、実施例（１）及び（２）と同様の試験
を行なったところ結果はほとんど同じであった・
〈実施例４〉
第３図に示すは実施例（１）と同様の貼着用静電シート
面（１）に紙（６）等がラミネートされた構造を有する
複合貼着用静電シート（７）の−例を示すもので、この
際貼着物面と貼着用静電シート（ＩＪ とが適宜に接着
される。こうするとペーパー面にそのまま必要事項、例
えば行動予定表等を書き込むことができ便利である。When the same tests as in Examples (1) and (2) were conducted using the same sheet as in Example (1), the results were almost the same. This shows an example of a composite electrostatic sheet for adhesion (7) having a structure in which paper (6), etc. is laminated on the electrostatic sheet surface (1) to be applied. IJ is glued as appropriate.This makes it convenient to write necessary information, such as an activity schedule, directly on the paper surface.
〈実施例５〉
第４図に示すは表面の被貼着物面（８）に表面処理の程
こされた体積抵抗率１０”０− ｃｍの貼着用静電シー
ト（９）であり、こうすることにより、シート（９）に
直にペン書、鉛筆書等が可能となるのみならず、必要に
応じ消去することも可能となる場合もあり、極めて応用
範囲が広いものである。表面処理としては化学エツチン
グ方法、コロナ放電処理、スパッタエツチング法、微細
なエンボス処理等適宜のものを例示でき、特に制限はな
いことは勿論である。〈Example 5〉 Fig. 4 shows an electrostatic sheet for pasting (9) having a volume resistivity of 10”0-cm and whose surface to be pasted (8) has been subjected to surface treatment. As a result, it is not only possible to write in pen or pencil directly on the sheet (9), but also to erase it if necessary, so it has an extremely wide range of applications.As a surface treatment. Examples of suitable methods include chemical etching, corona discharge treatment, sputter etching, fine embossing, and there are no particular limitations.
以上は本発明の好ましい実施例であり１本発明は係る実
施例に制限を受けるものでないことは勿論である。The above are preferred embodiments of the present invention, and it goes without saying that the present invention is not limited to these embodiments.
本発明は以−１−の通りであり、本発明のものζ±例え
ば壁等の被貼着物に対し、その静電気的作用番こより、
適度に接着することができるｍ−と透明性も極めて良好
かつ、表面を軽く摩擦すること番こより再使用が可能で
、その応用範囲ｔよ極めて広ｌ／Ｘ等格別顕茗な効果を
奏するものである。４ν番と、例えｉｆ各種文書やメモ
書き、ポスター等を一時的番と壁面１こ固定しておく場
合などは、本発明のものを用（Ｘると極めて簡単にその
実施が可能であり、各方面で今後多くの利用が期待され
てし）る。The present invention is as follows-1-, and from the electrostatic effect on the object to be adhered to, for example, a wall,
It has excellent adhesion and transparency, and can be reused by lightly rubbing the surface.It has a wide range of applications, such as L/X, and has exceptional effects. It is. For example, if you want to temporarily fix various documents, memos, posters, etc. to a wall, use the one of the present invention. It is expected that it will be used extensively in various fields in the future.
また、その貼着に当っても特別な操作を程こすことな〈
実施できる一方１手や衣ネ４＆こべたべたと接着するこ
とがない等を効果をも有するものである。Also, there is no need to perform any special operations when pasting it.
While it is easy to use, it also has the advantage of not being sticky with one hand or with a cloth.
第１図、第２図は本発明に係るシートのイ史用法を示す
斜視図であり、第３図、第４図を古本発明に係る他の実
施例を示す断面図である。
（１）−・・貼着用静電シート
（２）・・・壁 （３）・・・メモ用紙（４）・
・・袋状物 （５）・・・開口部（６）拳・・紙
（８）・・・表面処理面！１〜１作出願人
グンゼ株式会社
１Ｊ３１局 １１図
７ Ｌ
手続補ｉＴＥ −！：ｆ （自発）
昭和５８年２り／Ｓ日
特許庁長官 若杉 和犬 殿
１、事件の表示
昭和５７年特許願第２２０７７４号
２、発明の名称
貼着用静電シート及びその貼着方法
３、補正をする者
氏 名 （１３３）グンゼ株式会社
４、補正の対象
明細書における発明の詳細な説明の欄
５、補正の内容
５、補正の内容
（１）明細占第２頁１行の「粘着方法」を「貼着方法」
と訂正する。
（２）同第４頁３〜４行の［エチレン−テトラフルオロ
エチレン共重合体」を「テトラフルオロエチレン−パー
フルオロアルキルビニルエーテル共重合体」と訂正する
。
（３）同第５頁下から４行の「て記載した。」を下記の
通り訂正する。
「て記載した。
尚、貼着用静電シート（１）を予じめ白壁面（２）に貼
着し、その」−からメモ書（３）を貼着用静電シート（
’１）の表面に貼着した所、１力月以前に１１って、初
期の貼着状態を維持できた。
本発明はこのような貼着方法をとることも可能である。
」1 and 2 are perspective views showing the historical usage of the sheet according to the present invention, and FIGS. 3 and 4 are sectional views showing other embodiments according to the old invention. (1) - Electrostatic sheet for pasting (2) Wall (3) Memo paper (4)
... Bag-like object (5) ... Opening (6) Fist ... Paper
(8)...Surface treatment surface! 1-1 Applicant Gunze Co., Ltd. 1J31 Bureau 11 Figure 7 L Procedure Supplement iTE -! :f (Voluntary) Mr. Kazuinu Wakasugi, Commissioner of the Japan Patent Office, 2/S, 1983, 1, Indication of the case, Patent Application No. 220774, 1982, 2, Electrostatic sheet for pasting the name of the invention and its pasting method, 3, Name of the person making the amendment (133) Gunze Co., Ltd. 4, Column 5 for detailed explanation of the invention in the specification to be amended, Contents of the amendment 5, Contents of the amendment (1) “Adhesive "Method" to "Pasting method"
I am corrected. (2) "Ethylene-tetrafluoroethylene copolymer" on page 4, lines 3-4 is corrected to "tetrafluoroethylene-perfluoroalkyl vinyl ether copolymer." (3) On the 5th page, 4 lines from the bottom, ``described.'' is corrected as follows. Note that the electrostatic sheet for pasting (1) was pasted on the white wall surface (2) in advance, and the memo (3) was attached to the electrostatic sheet for pasting (2).
When pasted on the surface of '1), the initial state of adhesion was maintained as it became 11 before the end of the month. The present invention can also employ such an attachment method. ”
Claims (1)
合体からなり、かつ被貼着物に対し適度の接着性を有す
ることを特徴とする貼着用静電シート。 ２） 体積抵抗率１０Ω−ＣＩ１１以−にのフッソ系重
合体からなるシートをその静電気的作用により、被貼着
物の表面ｉ適度に接着せしめることを特徴とする貼着用
静電シートの貼着方法。[Scope of Claims] 1) An electrostatic sheet for pasting, characterized in that it is made of a fluorine-based polymer having a volume resistivity of 10"0-cm or more, and has appropriate adhesion to objects to be pasted. 2) Adhesion of an electrostatic sheet for adhesion, which is characterized in that a sheet made of a fluorine-based polymer having a volume resistivity of 10Ω-CI11 or more is appropriately adhered to the surface of an object to be adhered by its electrostatic action. Method.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP22077482A JPS59111183A (en) | 1982-12-15 | 1982-12-15 | Sticking electrostatic sheet and sticking method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP22077482A JPS59111183A (en) | 1982-12-15 | 1982-12-15 | Sticking electrostatic sheet and sticking method |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS59111183A true JPS59111183A (en) | 1984-06-27 |
Family
ID=16756346
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP22077482A Pending JPS59111183A (en) | 1982-12-15 | 1982-12-15 | Sticking electrostatic sheet and sticking method |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS59111183A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5010671A (en) * | 1987-11-13 | 1991-04-30 | Dennison Stationery Products Company | Flip chart pad |
| US6258200B1 (en) | 1997-06-25 | 2001-07-10 | Lemeer Design, L.L.C. | Static-cling intermediary |
| US7422648B1 (en) | 1997-06-25 | 2008-09-09 | Lemeer Design, L.L.C. | Method of releasably adhering sticker to vehicle windshield |
| GB2480600A (en) * | 2010-05-18 | 2011-11-30 | Jonathan Jordan | Electrostatic notice board |
| US8114495B1 (en) | 2007-06-08 | 2012-02-14 | Lemeer Design, L.L.C. | Vehicle sticker film intermediary |
| US8318279B1 (en) | 2001-07-09 | 2012-11-27 | Lemeer Design, L.L.C. | Vehicle sticker film intermediary |
-
1982
- 1982-12-15 JP JP22077482A patent/JPS59111183A/en active Pending
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5010671A (en) * | 1987-11-13 | 1991-04-30 | Dennison Stationery Products Company | Flip chart pad |
| US6258200B1 (en) | 1997-06-25 | 2001-07-10 | Lemeer Design, L.L.C. | Static-cling intermediary |
| US7422648B1 (en) | 1997-06-25 | 2008-09-09 | Lemeer Design, L.L.C. | Method of releasably adhering sticker to vehicle windshield |
| US8318279B1 (en) | 2001-07-09 | 2012-11-27 | Lemeer Design, L.L.C. | Vehicle sticker film intermediary |
| US8114495B1 (en) | 2007-06-08 | 2012-02-14 | Lemeer Design, L.L.C. | Vehicle sticker film intermediary |
| GB2480600A (en) * | 2010-05-18 | 2011-11-30 | Jonathan Jordan | Electrostatic notice board |
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