KR101215033B1 - 실리콘 함유 전구체 및 원자 산소를 이용하는 고품질플로우-형 실리콘 이산화물의 화학적 기상 증착 - Google Patents
실리콘 함유 전구체 및 원자 산소를 이용하는 고품질플로우-형 실리콘 이산화물의 화학적 기상 증착 Download PDFInfo
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- KR101215033B1 KR101215033B1 KR1020077020861A KR20077020861A KR101215033B1 KR 101215033 B1 KR101215033 B1 KR 101215033B1 KR 1020077020861 A KR1020077020861 A KR 1020077020861A KR 20077020861 A KR20077020861 A KR 20077020861A KR 101215033 B1 KR101215033 B1 KR 101215033B1
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Abstract
Description
Claims (31)
- 기판 상에 실리콘 산화물층을 증착하는 방법으로서,증착 챔버에 기판을 제공하는 단계;상기 증착 챔버 외부에서 원자 산소를 발생시키고, 상기 챔버에 상기 원자 산소를 주입하는 단계;상기 증착 챔버에 실리콘 전구체를 주입하는 단계 ? 상기 실리콘 전구체와 상기 원자 산소는 상기 챔버에서 먼저 혼합됨 ? ;상기 기판 상에 상기 실리콘 산화물층을 형성하기 위해 상기 실리콘 전구체와 상기 원자 산소를 반응시키는 단계 ? 상기 실리콘 산화물층이 형성될 때 상기 기판은 0℃ 내지 150℃의 온도에서 유지되고, 증착 이후 상기 실리콘 산화물층은 초기에 유동 가능함(initially flowable) ? ; 및상기 증착된 실리콘 산화물층을 어닐링하는 단계를 포함하는, 실리콘 산화물층 증착 방법.
- 제 1 항에 있어서,상기 기판은 300mm 또는 그 미만의 직경을 가지는 실리콘 웨이퍼를 포함하는, 실리콘 산화물층 증착 방법.
- 제 1 항에 있어서,상기 기판의 표면 상에 다수의 구조물들이 형성되며, 상기 구조물들은 7:1 또는 그 초과의 높이 대 폭 종횡비들을 가지는 갭들 및 트렌치들을 포함하는, 실리콘 산화물층 증착 방법.
- 제 1 항에 있어서,아르곤을 포함하는 가스 혼합물로부터 플라즈마를 형성하는 단계; 및상기 플라즈마에 산소 전구체를 주입하는 단계에 의해 상기 원자 산소가 형성되며, 상기 산소 전구체는 상기 원자 산소를 형성하도록 해리되는, 실리콘 산화물층 증착 방법.
- 제 4 항에 있어서,상기 산소 전구체는 분자형 산소, 오존, 수증기(H2O), 및 이산화질소로 이루어진 그룹에서 선택되는, 실리콘 산화물층 증착 방법.
- 제 1 항에 있어서,광해리(photodissociation) 챔버에 산소 전구체를 주입하는 단계; 및상기 산소 전구체를 자외선 광에 노출시키는 단계에 의해 상기 원자 산소가 형성되며, 상기 자외선 광은 상기 원자 산소를 형성하기 위해 상기 산소 전구체를 해리시키는, 실리콘 산화물층 증착 방법.
- 제 6 항에 있어서,상기 산소 전구체는 분자형 산소, 오존 및 이산화질소로 이루어진 그룹에서 선택되는, 실리콘 산화물층 증착 방법.
- 제 1 항에 있어서,상기 실리콘 전구체는 실란, 디메틸실란, 트리메틸실란, 테트라메틸실란, 디에틸실란, 테트라메틸오르쏘실리케이트(TMOS), 테트라에틸오르쏘실리케이트(TEOS), 옥타메틸트리실록산(OMTS), 옥타메틸시클로테트라실록산(OMCTS), 테트라메틸디메틸디메톡시디실란, 테트라메틸시클로테트라실록산(TOMCATS), 디메틸 디메톡시실란(DMDMOS), 디에톡시메틸실란(DEMS), 메틸트리에톡시실란(MTES), 페닐디메틸실란, 및 페닐실란으로 이루어진 그룹에서 선택되는, 실리콘 산화물층 증착 방법.
- 제 1 항에 있어서,상기 실리콘 전구체는 헬륨을 포함하는 캐리어 가스와 혼합되는, 실리콘 산화물층 증착 방법.
- 제 1 항에 있어서,상기 증착 챔버는 상기 기판을 지지하는 웨이퍼 페데스탈을 포함하며, 상기 기판 온도는 상기 웨이퍼 페데스탈에 의해 조절되는, 실리콘 산화물층 증착 방법.
- 제 1 항에 있어서,상기 증착 챔버는 상기 실리콘 산화물층이 형성될 때 0.1 Torr 내지 10 Torr의 압력을 갖는, 실리콘 산화물층 증착 방법.
- 제 1 항에 있어서,상기 실리콘 산화물층은 250Å/min 내지 2㎛/min의 속도로 형성되는, 실리콘 산화물층 증착 방법.
- 제 1 항에 있어서,상기 증착된 실리콘 산화물을 어닐링하는 단계는 열적 어닐링, 스팀 어닐링, 플라즈마 어닐링, 자외선 광 어닐링, e-빔 어닐링, 또는 마이크로파 어닐링을 포함하는, 실리콘 산화물층 증착 방법.
- 제 1 항에 있어서,상기 증착된 실리콘 산화물층을 어닐링하는 단계는,스팀의 존재하에 제 1 어닐링 온도로 상기 기판을 가열하는 단계; 및건식 질소에서 제 2 어닐링 온도로 상기 기판을 가열하는 단계를 포함하는, 실리콘 산화물층 증착 방법.
- 제 14 항에 있어서,상기 제 1 어닐링 온도는 최대 950℃이고, 상기 제 2 어닐링 온도는 900℃인, 실리콘 산화물층 증착 방법.
- 제 1 항에 있어서,상기 방법은, 상기 증착 챔버로 상기 원자 산소 전구체 또는 실리콘 전구체를 주입하기 이전에 예비처리 플라즈마에 상기 기판을 노출시키는 단계를 포함하는, 실리콘 산화물층 증착 방법.
- 제 16 항에 있어서,상기 예비처리 플라즈마는 아르곤, 헬륨, 수소(H2), 크세논, 또는 암모니아를 포함하는 고밀도 플라즈마인, 실리콘 산화물층 증착 방법.
- 제 1 항에 있어서,상기 증착 챔버는 고밀도 플라즈마 화학적 기상 증착(HDPCVD) 시스템의 일부인, 실리콘 산화물층 증착 방법.
- 기판 상에 실리콘 산화물층을 형성하는 방법으로서,반응 챔버에 실리콘 웨이퍼 기판을 제공하는 단계;고밀도 아르곤 플라즈마에서 분자형 산소의 해리로부터 원자 산소를 발생시키는 단계 ? 상기 원자 산소는 상기 반응 챔버 외부에 있는 원격 플라즈마 발생 챔버에서 발생됨 ? ;상기 반응 챔버에서 실리콘 전구체와 상기 원자 산소를 혼합하는 단계 ? 상기 원자 산소와 상기 실리콘 전구체는 상기 반응 챔버에 도달하기 이전에 혼합되지 않음 ? ; 및상기 기판 상에 상기 실리콘 산화물층을 증착하는 단계 ? 상기 실리콘 산화물층은 상기 실리콘 전구체와 상기 원자 산소의 반응으로부터의 반응 생성물들을 포함하고, 상기 실리콘 산화물층이 증착될 때 상기 기판은 0℃ 내지 150℃의 온도에서 유지되고, 증착 이후 상기 실리콘 산화물층은 초기에 유동 가능함 ?를 포함하는, 실리콘 산화물층 형성 방법.
- 제 19 항에 있어서,상기 방법은 상기 증착된 실리콘 산화물층을 어닐링하는 단계를 더 포함하는, 실리콘 산화물층 형성 방법.
- 제 20 항에 있어서,상기 증착된 실리콘 산화물을 어닐링하는 단계는 열적 어닐링, 스팀 어닐링, 플라즈마 어닐링, 자외선 광 어닐링, e-빔 어닐링, 또는 마이크로파 어닐링을 포함하는, 실리콘 산화물층 형성 방법.
- 제 19 항에 있어서,상기 실리콘 전구체는 실란, 디메틸실란, 트리메틸실란, 테트라메틸실란, 디에틸실란, 테트라메틸오르쏘실리케이트(TMOS), 테트라에틸오르쏘실리케이트(TEOS), 페닐디메틸실란, 및 페닐실란으로 이루어진 그룹에서 선택되는, 실리콘 산화물층 형성 방법.
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| US11/754,440 US7825038B2 (en) | 2006-05-30 | 2007-05-29 | Chemical vapor deposition of high quality flow-like silicon dioxide using a silicon containing precursor and atomic oxygen |
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| US7902080B2 (en) * | 2006-05-30 | 2011-03-08 | Applied Materials, Inc. | Deposition-plasma cure cycle process to enhance film quality of silicon dioxide |
| US7629273B2 (en) | 2006-09-19 | 2009-12-08 | Taiwan Semiconductor Manufacturing Company, Ltd. | Method for modulating stresses of a contact etch stop layer |
| US7737050B2 (en) * | 2006-10-30 | 2010-06-15 | International Business Machines Corporation | Method of fabricating a nitrided silicon oxide gate dielectric layer |
| US20080102223A1 (en) | 2006-11-01 | 2008-05-01 | Sigurd Wagner | Hybrid layers for use in coatings on electronic devices or other articles |
| KR100866143B1 (ko) * | 2007-08-03 | 2008-10-31 | 주식회사 하이닉스반도체 | 반도체 소자의 소자분리막 형성방법 |
| US7745352B2 (en) | 2007-08-27 | 2010-06-29 | Applied Materials, Inc. | Curing methods for silicon dioxide thin films deposited from alkoxysilane precursor with harp II process |
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| US7541297B2 (en) | 2007-10-22 | 2009-06-02 | Applied Materials, Inc. | Method and system for improving dielectric film quality for void free gap fill |
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| US7943531B2 (en) * | 2007-10-22 | 2011-05-17 | Applied Materials, Inc. | Methods for forming a silicon oxide layer over a substrate |
| US7935643B2 (en) * | 2009-08-06 | 2011-05-03 | Applied Materials, Inc. | Stress management for tensile films |
| US8741788B2 (en) * | 2009-08-06 | 2014-06-03 | Applied Materials, Inc. | Formation of silicon oxide using non-carbon flowable CVD processes |
| US7989365B2 (en) * | 2009-08-18 | 2011-08-02 | Applied Materials, Inc. | Remote plasma source seasoning |
| US8449942B2 (en) * | 2009-11-12 | 2013-05-28 | Applied Materials, Inc. | Methods of curing non-carbon flowable CVD films |
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2007
- 2007-05-29 US US11/754,440 patent/US7825038B2/en active Active
- 2007-05-30 CN CN201010169884A patent/CN101831631A/zh active Pending
- 2007-05-30 KR KR1020077020861A patent/KR101215033B1/ko active Active
- 2007-05-30 CN CN2007800001303A patent/CN101310039B/zh active Active
- 2007-05-30 TW TW096119407A patent/TWI399453B/zh active
-
2008
- 2008-10-10 US US12/249,816 patent/US20090031953A1/en not_active Abandoned
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20160011151A (ko) * | 2014-07-16 | 2016-01-29 | 어플라이드 머티어리얼스, 인코포레이티드 | 유동성 증착에 의한 저-k 유전체 갭필 |
| KR102454422B1 (ko) * | 2014-07-16 | 2022-10-14 | 어플라이드 머티어리얼스, 인코포레이티드 | 유동성 증착에 의한 저-k 유전체 갭필 |
| WO2019032457A1 (en) * | 2017-08-08 | 2019-02-14 | Applied Materials, Inc. | METHODS AND APPARATUSES FOR DEPOSITING LOW DIELECTRIC CONSTANT FILMS |
| US11990332B2 (en) | 2017-08-08 | 2024-05-21 | Applied Materials, Inc. | Methods and apparatus for deposition of low-k films |
| WO2021050308A1 (en) * | 2019-09-12 | 2021-03-18 | Applied Materials, Inc. | Repulsion mesh and deposition methods |
| WO2021055918A1 (en) * | 2019-09-20 | 2021-03-25 | Applied Materials, Inc. | Methods and apparatus for depositing dielectric material |
| KR20250109310A (ko) | 2024-01-10 | 2025-07-17 | 에스케이트리켐 주식회사 | 저 유전율 실리콘 함유 박막 형성용 전구체 및 이를 이용한 저 유전율 실리콘 함유 박막 형성 방법. |
| KR20250122057A (ko) | 2024-02-06 | 2025-08-13 | 에스케이트리켐 주식회사 | 저 유전율 실리콘 함유 박막 형성용 전구체 및 이를 이용한 저 유전율 실리콘 함유 박막 형성 방법. |
Also Published As
| Publication number | Publication date |
|---|---|
| KR20090036068A (ko) | 2009-04-13 |
| TWI399453B (zh) | 2013-06-21 |
| TW200811309A (en) | 2008-03-01 |
| US20070281496A1 (en) | 2007-12-06 |
| CN101831631A (zh) | 2010-09-15 |
| US7825038B2 (en) | 2010-11-02 |
| CN101310039B (zh) | 2012-04-18 |
| US20090031953A1 (en) | 2009-02-05 |
| CN101310039A (zh) | 2008-11-19 |
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