KR102120835B1 - Natural deodorant composition using polyphenol - Google Patents

Abstract

Natural deodorant compositions using polyphenolic components are disclosed. The natural deodorant composition using the polyphenol component of the present invention is characterized by comprising Angelica and green tea, sodium hydrogen carbonate, chrysanthemum, cinnamon, octagonal and purified water.

Description

Natural deodorant composition using polyphenol component {NATURAL DEODORANT COMPOSITION USING POLYPHENOL}

The present invention relates to a natural deodorant composition, and more particularly, to a natural deodorant composition using a polyphenol component.

In general, sebum is released from the sebaceous glands in human skin to the skin surface through pores to prevent evaporation of moisture and maintain the elasticity of the skin. However, when the discharged sebum comes into contact with the air on the surface of the skin, microorganisms existing on the skin multiply and thereby oxidize the sebum to make body odor bad.

Particularly, in old age, fatty acid in sebum is oxidized to a substance called lipid peroxide, and odor is generated. 2-nonenal, a kind of volatile aldehyde generated from 9-hexadecenoic acid, which increases in sebum in middle-aged and older people, has an aging odor. Becomes the main reason.

In order to reduce such odor, the generated body odor component is removed through bath or indoor air circulation, a method of massaging through fragrance and deodorant, and body odor components are adsorbed together with the precursors to volatilize body odor components. There are methods to prevent it, and to suppress the formation of body odor components from precursors by oxidation reactions or bacterial activities. The method of masking using the above-mentioned fragrance and deodorant does not suppress the body odor component itself, but also may cause undesirable new odors due to the mixture of the problem body odor and the fragrance component, which causes body odor. It is difficult to solve the problem, and by destroying and removing a certain amount of bacteria present on the skin used to suppress the formation of body odor and volatilization, microbial inhibitors, enzyme inhibitors and sebum that prevent oxidation from being prevented from being oxidized in the air Given that chemical components such as antioxidants have a slight deodorizing effect, but have serious problems such as causing irritation to the skin, it is urgent to develop a composition that ensures safety and efficacy.

In addition, body odor includes eccrine sweat, apocrine sweat, sebum, and contaminants, and has a specificity that causes and odors are different depending on body parts. In the case of odor, which is the most worrisome among body odors, apocrine sweat, which is odorless, is caused by decomposition of axillary flora and odor causing bacteria. There are many reports of odor-related microorganisms, but among them, it is probable that odor is caused by lipophilic diphtheroid or large colony diphtheroid. As such, it is decomposed by microorganisms to generate volatile odorous substances, including lower fatty acids, caproic acid, caprylic acid, isovaleric acid, and butyric acid. ), ammonia, amine, indole, mercaptan, hydrogen sulfide, phosphine, steroids, etc. are involved, especially isoglycoacetic acid among lower fatty acids, 5 alpha-androst-16 among steroids -N-3 alpha-ol (5α-androst-16-en-3α-ol) and 5 alpha-androst-16-en-3 alpha-one (5α-androst-16-en-3α-one) are the main factors It is known as. In addition, in the case of foot and foot, it is known that isogilacetic acid produced by the action of microorganisms on secreted eccrine sweat is the main factor.

In general, deodorant for human body refers to a product that removes or prevents body odors generated in the human body such as axilla smell (liquid), foot odor (foot odor), sweat odor, and odor of the human body. Aerosol type, pump type, roll-on type , Stick-type, powder-type, granular-type, liquid-type, and gel-type.

The principle that these deodorants remove odors is odors by physical deodorization, which is a method of removing odors by ventilation and diffusion, or adsorbing odors using porous materials such as activated carbon, zeolite, and silica gel, and odors by aromatic substances (perfumes). A sensory deodorization method that blocks the chemical deodorization method, and a chemical deodorization method that chemically reacts a deodorant with a malodor component to make it odorless by neutralization reaction, addition reaction, condensation reaction, oxidation reaction, etc., and sterilizes bacteria or bacteria that cause odor or prevents corruption There are biological deodorization methods that fundamentally prevent the cause of odors.

Among these, the physical deodorization method is one of the widely used deodorization methods, and is widely used as a residential deodorant other than the human body, but is ineffective in terms of feeling when used in the human body. The sensory deodorization method is a method of blocking the odor by its own scent, etc., but it is difficult to keep the balance between the odor and the odor in harmony, and it is not suitable for use as a general method because the preference for the odor of the deodorant varies depending on the individual. not.

In addition, the chemical deodorization method can be effectively used for various odor components, but there is a inconvenience that requires careful handling depending on the drug used. In addition, the biological deodorization method has a disadvantage in that it is impossible to obtain a highly expected effect after the odor is generated.

Therefore, new improvement measures that are harmless to the human body while using natural materials are required.

The above-described technical configuration is a background technique for helping the understanding of the present invention, and does not mean a conventional technique well known in the art.

Korean Registered Patent Publication No. 10-1068997 (Lotte Holding Co., Ltd.) 2011. 09. 23.

Therefore, the technical problem to be achieved by the present invention is to provide a natural deodorant composition harmless to the human body using a polyphenol component.

According to an aspect of the present invention, a natural deodorant composition using a polyphenol component characterized by comprising Angelica and green tea, sodium hydrogen carbonate, chrysanthemum, cinnamon, octagonal and purified water may be provided.

It may further include rosemary hydrosol, peppermint oil, and polysorbate 20.

The Angelica is 1 to 3% by weight, the green tea is 1 to 3% by weight, the sodium hydrogen carbonate is 1 to 3% by weight, the chrysanthemum is 10.5 to 15% by weight, the cinnamon is 1 to 10.5% by weight, the octagonal fennel 0.1 to 0.5% by weight of silver, 56 to 69.5% by weight of purified water, 1 to 10% by weight of rosemary hydrosol, 0.1 to 0.3% by weight of peppermint oil, and 0.11 to 0.3% by weight of polysorbate 20 Can be.

Fermentation alcohol and spearmint oil may be further included.

Rosemary hydrosol may further include.

It may further include rosemary hydrosol, peppermint oil, and polysorbate 20.

It can be used to remove odors from the elderly.

Embodiments of the present invention, there is an advantage that can use the natural material is harmless to the human body and there is no feeling of rejection of chemicals, so that the preferences of consumers can be greatly increased.

1 is a graph schematically showing an alcohol extract content of each raw material applied to a natural deodorant composition using a polyphenol component according to an embodiment of the present invention.
2 is a graph showing the odor index of the ethanol extract for each raw material applied to this embodiment.
Figure 3 is a graph showing the content of hot water extract for each raw material applied to this embodiment.
4 is a graph showing the odor index of the hot water extract for each raw material applied to the present embodiment.
5 is a graph showing the odor index of hydrosol and sodium hydrogen carbonate for each raw material applied to this embodiment.
FIG. 6 is a graph showing the results of gas chromatography mass spectrometry analysis of the hexane-soluble part of the isogilacetic acid and trans-2-nonenal mixture applied to the present embodiment.
7 is a view showing the results of gas chromatography mass spectrometry analysis of the hexane-soluble part after adding the extract mixture solution to the isogil acetic acid and trans-2-nonenal mixture solution applied to the present embodiment.
8 is a view schematically showing a deodorant measurement method for measuring using a portable deodorant meter applied to the present embodiment.

In order to fully understand the present invention, the operational advantages of the present invention, and the objects achieved by the practice of the present invention, reference should be made to the accompanying drawings and the contents described in the accompanying drawings, which illustrate preferred embodiments of the present invention.

Hereinafter, the present invention will be described in detail by explaining preferred embodiments of the present invention with reference to the accompanying drawings. The same reference numerals in each drawing denote the same members.

1 is a graph schematically showing the content of alcohol extracts by raw material applied to a natural deodorant composition using a polyphenol component according to an embodiment of the present invention, and FIG. 2 is a view of ethanol extracts by raw material applied to this embodiment It is a graph showing the odor index, Figure 3 is a graph showing the content of the hot water extract for each raw material applied to this embodiment, Figure 4 is a graph showing the odor index of the hot water extract for each raw material applied to this embodiment.

In addition, FIG. 5 is a graph showing the odor index of hydrosol and sodium hydrogen carbonate for each raw material applied to this embodiment, and FIG. 6 is hexane of isogilacetic acid and a trans-2-nonenal mixture applied to this embodiment Gas chromatography mass spectrometry analysis results of the soluble part, and FIG. 7 shows the gas chromatographic mass of the hexane soluble part after adding the extract mixture solution to the mixed isogilacetic acid and trans-2-nonenal solution applied to the present embodiment. 8 is a view showing a result of spectroscopy analysis, and FIG. 8 is a diagram schematically showing a deodorization measurement method for measuring using a portable deodorization meter applied to the present embodiment.

As shown in these drawings, the natural deodorant composition using the polyphenol component according to the present embodiment is sodium hydrogen carbonate, fermented alcohol, purified water, chrysanthemum, cinnamon (cinnamon), rosemary hydrosol, Angelica, green tea, spearmint oil , It may include a plurality of recipes selected from peppermint oil, polysorbate 20 and octagonal fennel.

In this embodiment, the main raw materials used to select raw materials having deodorizing efficacy are divided into parts as shown in Table 1 below.

division Extraction sample (g) Remark Ethanol (99%) extraction Hot water extraction Flower Safflower 10 10 Persimmon soup 10 10 Herbaceous green tea 10 10 Sleeping cow 10 10 Mulberry leaves 10 10 Elementary School 10 10 Dog wormwood 10 10 Fruit Cloves 10 10 Root Per ear 10 10 Heaven 10 10 Peony 10 10 cinnamon 10 10

Hwa-ryu prepares safflower and chrysanthemums, herbaceous green tea and shiso, mulberry leaves, Seonhak-cho and thrush, and the fruit prepares cloves, and the roots prepare Angelica, celery, peony and cinnamon.

The above-mentioned material was used for testing by extracting alcohol (99% ethanol) and hot water. In the alcohol extraction method, alcohol is added to the raw material, and the mixture is allowed to stand at room temperature for 3 days and then concentrated by filtration. In addition, in the hot water extraction method, water is added to the raw material, heated at 100° C. for 2 hours, and then filtered and concentrated.

In this embodiment, the concentrate of 12 raw materials is suspended by adding distilled water to prepare 20 ppm.

In this embodiment, the deodorant standard was prepared isoisoacetic acid (Isovaleric acid, 99%) and trans-2-nonenal (95%), respectively, and these two substances were the main components of the elderly odor. Is known. Isogil acetic acid is water soluble and trans-2-nonal is fat soluble and suspended in a 20% alcohol solution as a homogenizer. The two substances were mixed in a 5: 5 state, most similar to the smell of the elderly. The mixture is prepared at 20 ppm.

As a raw material for medicinal herbs, the alcohol extract meter is sensitive to alcohol, so it is suspended in water.

In this embodiment, the deodorization measuring device for the development of a natural deodorant, uses a portable deodorizer 10 shown in FIG. 8.

As shown in Fig. 8, the measurement method is performed by inserting a sensor at the inlet of the tube, closing an extra space with a thumb, and then measuring.

This embodiment is a natural deodorant component, as shown in Table 2 below, may have an ethanol extract.

In the present embodiment, as shown in Table 2, as shown in Table 2, the flower part had the most safflower as 21.5%, the herbaceous green tea leaves were 16.7%, the fruits were cloves 19.3%, and the roots were Angelica 13.0%. It contains.

division Extract content (%) Remark Flower Safflower 21.5 Persimmon soup 9.4 Herbaceous green tea 16.7 Sleeping cow 6.6 Mulberry leaves 11.4 Elementary School 8.7 Dog wormwood 5.4 Fruit Cloves 19.3 Root Per ear 13.0 Heaven 2.3 Peony 3.4 cinnamon 1.0

In addition, the extract content of each raw material in this embodiment is shown graphically in FIG. 1.

In this embodiment, the deodorizing efficacy of the ethanol extract, as shown in Table 3 below, the chrysanthemum of the flower is the highest with an odor index of 29.7, and the root of Angelica with the odor index of 29.7 shows the same results as the chrysanthemum.

division Deodorizing efficacy (odor concentration) Odor index Remark Control 1,328 31.2 Flower Safflower 1,100 30.4 Chrysanthemum 951 29.7 Great Herbaceous green tea 1,172 30.7 Jaso 987 29.9 Mulberry leaves 987 29.9 Seonhak Elementary School 1,031 30.1 Wormwood 1,026 30.1 Fruit cloves 980 29.9 Root Angelica 940 29.7 Great Heaven 1,045 30.2 Peony 1,055 30.2 cinnamon 970 29.8

In addition, in this embodiment, the odor index of the ethanol extract for each raw material is shown graphically in FIG. 2.

In this embodiment, the content of the hot water extract, as shown in Table 4 below, the flower part is the highest with 12.6% persimmon, herbaceous is the highest with 48% mulberry leaves, 16.5% with the cloves of the fruit, and peony with the roots. This shows 49.9%.

division Extract content (%) Remark Flower Safflower 9.3 Chrysanthemum 12.6 Herbaceous green tea 33.0 Jaso 33.0 Mulberry leaves 48.0 Seonhak Elementary School 39.3 Wormwood 17.9 Fruit cloves 16.5 Root Angelica 48.0 Heaven 35.2 Peony 49.9 cinnamon 37.7

In addition, in this embodiment, the content of the hot water extract for each raw material is shown graphically in FIG. 3.

In this embodiment, the deodorizing efficacy of the hot water extract, as shown in Table 5 below, green tea, mulberry leaves, cloves, Angelica are shown to have high deodorizing efficacy.

division Deodorizing effect
(Odor concentration) Odor index Remark Control 1328 31.23 Flower Safflower 906 29.57 Chrysanthemum 740 28.69 Herbaceous green tea 572 27.57 Great Jaso 758 28.79 Mulberry leaves 600 27.78 Great Seonhak Elementary School 848 29.28 Wormwood 820 29.13 Fruit cloves 630 27.99 Great Root Angelica 652 28.14 Great Heaven 910 29.59 Peony 830 29.19 cinnamon 670 28.26

In addition, in this embodiment, the odor index of the hot water extract for each raw material is shown graphically in FIG. 4.

In this embodiment, the deodorizing effect of hydrosol and sodium bicarbonate, as shown in Table 6 below, Hydurosol of chrysanthemum and cinnamon had no significant deodorizing effect, but sodium bicarbonate (sodium hydrogen carbonate) had an excellent odor concentration of 750. Results are shown.

division Deodorizing efficacy (odor concentration) Odor index Remark Control 1,328 31.2 Hydrosol Chrysanthemum 1,309 31.2 cinnamon 1,310 31.2 food baking soda 750 28.7

In addition, in this embodiment, the odor index of hydrosol and sodium hydrogen carbonate for each raw material is shown graphically in FIG. 5.

As shown in FIG. 6, the results of gas chromatography mass spectrometry analysis of the hexane-soluble part of the mixed isogilacetic acid and trans-2-nonenal solution in this embodiment, the main components are 2-Nonenal, 2-Undecene, and Cycloburanecarboxylic acid , (S)-8,8-Dimethyl-2-oxo7,8-dihydro-, 1,3,6-triethyl-8-methyl-2,7-napthyridine, 1-hydroxy-3,6,7,7, 8-pentamethyl-8-oxo-8-phospha-9-oxabicyclo[4,3,0]nonane.

Table 7 below shows the main components of the hexane-soluble part of the mixed solution of isogil acetic acid and trans-2-nonenal.

No. RT(min.) Compound name Remark One 7.995 Hexanal 2 8.208 3-Hexanol 3 13.095 Heptanal 4 15.511 Acetaldehyde 5 16.009 5-Nonanone 6 22.873 Phosphonic acid 7 23.415 3-Acetonylcycloheptanone 8 25.448 (E)-4-Oxo2-hexenal 9 26.594 2-Nonenal 10 30.452 2-Undecene 11 32.426 Cycloburanecarboxylic acid 12 55.848 (S)-8,8-Dimethyl-2-oxo7,8-dihydro 13 56.231 1,3,6-triethyl-8-methyl-2,7-naptha 14 56.488 (E)-4-(2,2-Dimethyl-2H-Chromen-3-yl)but-3-en-2-one 15 56.685 Phenol 16 60.282 1-hydroxy-3,6,7,7,8-pentamethyl-8-oxo-8-phospha-9-oxabicyclo[4,3,0]nonane

As shown in FIG. 7, gas chromatography mass spectrometry analysis results of the hexane-soluble part after adding the extract mixture solution to the mixed isogilacetic acid and trans-2-nonenal solution in this example, Hexanal, 3-Hexanol, Acetaldehyde , 5-Nonanone, Acetic acid, 1-Deuterio-2-hydroxyethylprppadiene, Nonanal, hexane.

Table 8 below shows the main components of the hexane-soluble part after adding the extract mixture solution to the isogilacetic acid and trans-2-nonenal mixture solution.

No. RT(min.) Compound name Remark One 7.995 Hexanal 2 8.208 3-Hexanol 3 13.095 Heptanal 4 15.511 Acetaldehyde 5 16.009 5-Nonanone 6 22.993 Acetic acid 7 23.155 1-Deuterio-2-hydroxyethylprppadiene 8 23.517 Nonanal 9 24.914 hexane

In conclusion, the mixture of green tea, Angelica kerosene and sodium hydrogen carbonate in a 5:5 mixed solution of the standard sample isogilacetic acid and trans-2-nonal was analyzed by gas chromatography mass spectroscopy, and the hexane-soluble part was analyzed. As can be seen, the peak between the retention time (Retention Time) 25 minutes and 60 minutes disappears.

Therefore, it can be seen that green tea, Angelica sulphate, and sodium hydrogen carbonate exerted a deodorizing effect.

In this example, the development of a natural deodorant recipe was based on purified water that is friendly to the human body, and Angelica and green tea hot water extracts with high deodorizing effect and sodium hydrogen carbonate were added.

In addition, the addition of persimmon, cinnamon and rosemary hydrosol was added, and peppermint oil and octagonal fennel extract were added to scent the fragrance.

In this embodiment, polysorbate 20 was used to facilitate mixing between raw materials.

In this example, natural deodorant recipes, as shown in Table 9 below, developed six recipes from A to F, and optimal recipes can exclude fermentation and select F using purified water.

No Raw material A B C D E F One Sodium hydrogen carbonate 1.00 3.00 1.00 3.00 1.00 3.00 2 Fermentation 15.00 15.00 0.00 0.00 0.00 0.00 3 Purified water 58.00 56.00 69.50 67.50 68.30 66.30 4 Chrysanthemum hydrosol 10.50 10.50 15.00 15.00 15.00 15.00 5 Cinnamon Hydrosol 10.50 10.50 5.00 5.00 1.00 1.00 6 Rosemary Hydrosol 0.00 0.00 5.00 5.00 10.00 10.00 7 Angelica extract 2.00 2.00 2.00 2.0 2.00 2.00 8 Green Tea Extract 2.00 2.00 2.00 2.0 2.00 2.00 9 Spiamine oil 0.50 0.50 0.00 0.00 0.00 0.00 10 Peppermint oil 0.00 0.00 0.00 0.00 0.10 0.10 11 Polysorbate 20 0.00 0.00 0.00 0.00 0.10 0.10 12 Octagonal fennel extract 0.50 0.50 0.50 0.50 0.50 0.50 system 100 100 100 100 100 100

The overall reaction of the sensory evaluation subjects showed that F with a weak mint scent was the best.

As described above, since this embodiment uses natural materials, it has the advantage of being harmless to the human body and not having a feeling of rejection for chemicals, thereby greatly increasing consumer preference.

As described above, the present invention is not limited to the described embodiments, and it is obvious to those skilled in the art that various modifications and modifications can be made without departing from the spirit and scope of the present invention. Therefore, such modifications or variations will have to belong to the claims of the present invention.

10: portable deodorizer

Claims (7)

Includes Angelica, green tea, sodium hydrogen carbonate, chrysanthemum, cinnamon, octagonal fennel and purified water,
Rosemary hydrosol and peppermint oil and polysorbate 20 further included,
The Angelica is 1 to 3% by weight, the green tea is 1 to 3% by weight, the sodium hydrogen carbonate is 1 to 3% by weight, the chrysanthemum is 10.5 to 15% by weight, the cinnamon is 1 to 10.5% by weight, the octagonal fennel 0.1 to 0.5% by weight of the silver, 56 to 69.5% by weight of the purified water, 1 to 10% by weight of the rosemary hydrosol, 0.1 to 0.3% by weight of the peppermint oil, and 0.11 to 0.3% by weight of the polysorbate 20 Natural deodorant composition using a polyphenol component, characterized in that. delete delete The method according to claim 1,
Natural deodorant composition using a polyphenol component characterized in that it further comprises fermented spirits and spearmint oil. The method according to claim 1,
Natural deodorant composition using a polyphenol component, characterized in that it further comprises rosemary hydrosol. delete The method according to claim 1,
Natural deodorant composition using a polyphenol component, characterized in that used to remove the smell of the elderly.

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