KR20200137796A - An electrolysis method through motional electromotive force of electrolyte fluid and a power-generative electrolyzer using it - Google Patents

Abstract

When an aqueous electrolyte solution flows at a high speed under a transverse magnetic field by using the electromagnetic law that generates electromotive force in the space where the time-varying magnetic flux is generated, the magnetic flux to be linked changes with time, thereby generating a kinetic electromotive force in the electrolyte fluid. The positive ions undergo an oxidation/reduction reaction, that is, electrolysis, which exchanges electrons at the positive and negative electrodes, respectively, and can generate electricity as a result of charge transfer. The electrolysis method of the present invention by kinetic electromotive force of the electrolyte fluid and the electrolytic cell with power generation capability using the same, unlike the conventional electrolysis without the flow of the electrolyte, by utilizing the characteristics of the'speed' variable at which the electrolyte flows at a high speed, By shortening the reaction time by allowing more ions to contact the electrode at a faster rate, it is possible to greatly reduce the time and energy consumed compared to the conventional electrolysis even when energy is input for the flow of the fluid. In addition, due to the high-speed circulation of the electrolyte fluid, it allows the operation of the device at any pH, the separation membrane can be removed to reduce the complexity and cost of the device, and the conventional electrolysis due to advantages such as reduced ionic resistance and scale. It could be an alternative to the method.

Description

An electrolysis method through motional electromotive force of electrolyte fluid and a power-generative electrolyzer using it}

The present invention relates to an electrolysis method using a kinetic electromotive force generated in an electrolyte fluid flowing under a transverse magnetic field, and an electrolytic cell having power generation capability using the same.

Electrolysis is an involuntary electrochemical reaction that occurs only when energy that generates a potential difference, that is, an electromotive force, is introduced into the reaction from an external source.

The electrolysis of a conventional electrolyzer decomposes a substance by forcibly causing an oxidation/reduction reaction in which electrolyte ions exchange electrons to and from an electrode by an electromotive force given by externally applied electric energy.

On the other hand, the generation of electromotive force in the space where the time-varying magnetic flux is generated is one of the fundamental laws of electromagnetics. Using this, if the aqueous electrolyte solution flows at a high speed under a transverse magnetic field, a kinetic electromotive force is generated in the electrolyte fluid as the magnetic flux linking changes with time, and the charged negative and negative ions transfer electrons at the positive and negative electrodes, respectively. The exchange of oxidation/reduction reactions can occur, and electricity can be generated as a result of charge transfer.

Therefore, the conventional electrolysis that introduces the voltage of electric energy into the reaction and the electrolysis by the kinetic electromotive force of the electrolyte fluid according to the electromagnetic law are essentially the same electrochemical reaction, and only how to apply the electromotive force, which is the driving force that drives the reaction. There is only a difference between whether it is a thing or not.

However, the bigger difference can be said to be the difference in the'speed' of movement of ions that transport charges by the electromotive force generated between the electrodes at both ends. It is said that the effect of the externally applied electric field on the movement of ions in the direction of the electrode in the conventional electrolyzer without the flow of the electrolyte is said to have only a very slight effect, and thus the progression speed of the ions as the charge carrier is about 10 ^-7 m/sec. Although it is inevitable to rely on microscopic molecular motion of only (10 ^-4 mm/sec), the electrolysis method by kinetic electromotive force presupposes a macroscopic speed of motion capable of generating electromotive force.

The electrolysis device by kinetic electromotive force, which is properly configured to utilize the characteristics of the'speed' variable as described above, shortens the reaction time by allowing more ions to contact the electrode at a much faster rate, thereby introducing energy for the flow of fluid. In addition, time and energy consumed compared to conventional electrolysis can be significantly reduced.

In addition, due to the high-speed transport of the electrolyte fluid, it allows the operation of the device at any pH, and the removal of the separator reduces the complexity and cost of the device, and reduces ionic resistance and scale. It could be an alternative to the method.

The present invention provides a method of electrolysis by kinetic electromotive force of an electrolyte fluid and an electrolytic cell having power generation capability using the same based on the above principle.

PCT/IB2015/058050, MEMBRANE-LESS ELECTROLYZER

De Luca, Roberto. (2011). Electromotive Force Generation with Hydrogen Release by Salt Water Flow under a Transverse Magnetic Field. Journal of Modern Physics, Vol.2 No.10, 2011.DOI: 10.4236/jmp.2011.210138 S. Mohammad H. Hashemi, Miguel A. Modestino and Demetri Psaltis. (2015). A membrane-less electrolyzer for hydrogen production across the pH scale. Article in Energy & Environmental Science, April 2015.DOI: 101039/C5EE00083A

An object of the present invention is to provide an electrolysis method with high efficiency compared to the conventional method and an electrolytic cell having power generation capability using the same through a kinetic electromotive force generated in an electrolyte fluid flowing under a transverse magnetic field.

The electrolysis method through the electromotive force of the electrolytic fluid according to one aspect of the present invention for achieving the above object and the electrolytic cell having power generation capability using the same, A pair of flow paths spirally wound in a predetermined manner in which the anode flow path provided with the anode electrode and the cathode flow path provided with the cathode electrode are paired left and right or up and down on both the ceiling and the floor or on either side; A circuit in which two electrodes of the channel pair are connected; A plurality of predetermined magnetic body pairs provided opposite to each other on the inside and outside of the spiral body so that magnetic flux horizontally traverses the flow path pair and including a magnetic flux frame; A separator for separating gas from the mixture of the electrolyte fluid and gas discharged from the respective flow paths and transferring the gas to a gas compression device; An injection pipe and a discharge pipe connected to each other in a staggered manner so that residual electrolyte fluid in the separator may alternately circulate between the positive flow path and the negative electrode flow path, and connect the flow paths to the separators; A pump provided in the injection pipe and configured to discharge the electrolyte fluid continuously replenished from a predetermined supply pipe and the residual electrolyte fluid sucked from the separator into each flow path at high speed; A housing containing the pair of flow paths and the pair of magnetic bodies inside, including a predetermined support and a connector, and having a predetermined cooling device; And an operation system for automatically controlling the injection amount and speed of the electrolyte fluid by sensing gas generation amount, flow rate, temperature and pressure in the separator, and output voltage and current in the circuit and displaying operation performance for each flow path.

In addition, the shape of the flow path may be provided in that it is a flow path formed by joining members to form a ceiling and a floor of a square cross section in a spiral shape in the gap between the inner/outer cylinders of the double cylinder.

In addition, the shape of the flow path may be provided in that it is a flow path molded by a three-dimensional lamination printing or injection molding method to form a ceiling, a floor, and left and right sides of a square cross section in a spiral shape.

In addition, the flow path is a flow path in which electrodes are provided on both left and right sides of a rectangular cross section, or on either side, and the magnetic body is a magnetic body provided opposite to each other on the upper and lower portions of the spiral flow path pair body so that magnetic flux vertically traverses the flow path. It can be provided as a feature.

In addition, it may be provided in a manner in which a predetermined catalyst and a current collector are added to each electrode of the flow path.

In addition, the magnetic material may be provided as characterized in that the electromagnet.

In addition, the flow path may be provided in that the gap between the electrode and the opposite surface becomes narrower as it proceeds from the electrolyte fluid inlet to the outlet port.

In addition, there are a plurality of pairs of flow paths, each electrode is connected to form one circuit, the branch pipes extending from the injection pipes and the discharge pipes are connected to each flow path, and the air gap combined with the cooling device between the flow path pair and the flow path pair Alternatively, it may be provided by providing a refrigerant passage.

In addition, the magnetic flux frame of the magnetic material pair may be provided in that it is possible to open/close and adjust the distance between the magnetic material, and that the number of the flow path pair or the flow path can be changed and detachable.

The present invention can expect the following effects.

First, time and energy consumption is significantly reduced compared to the conventional method, thereby contributing to the transition of the hydrogen production paradigm from gray to green.

Second, since the device is simple and the budget burden is low, it is suitable not only for the distributed hydrogen production for each base but also for the individual on-site method of demand or sales.

Third, it has high applicability as an energy storage method (PtoG) that produces hydrogen by combining it with an intermittent renewable energy source that changes day and night, such as sunlight or wind power.

Fourth, it can be applied to various scales ranging from small size to large capacity.

1 is a system diagram illustrating water electrolysis according to an embodiment of the present invention.
2 is a perspective view of an electrolyzer having power generation capability in which the flow path of the electrolyzer having power generation capability is formed in a pair of left and right according to an embodiment of the present invention and wound in a spiral manner.
3 is a plan view of an electrolyzer having power generation capability in which the flow path of the electrolyzer having power generation capability is formed in a pair of left and right according to an embodiment of the present invention, and is wound in a spiral shape.
4 is an exploded view of a pair of spiral flow paths of an electrolytic cell having power generation capability according to an embodiment of the present invention formed as a pair of top and bottom and spirally wound.

The size or shape of the components shown in the drawings may be exaggerated for clarity and convenience of description, and terms specially defined in consideration of the configuration and operation of the present invention should be determined based on the contents of the present specification.

Hereinafter, with reference to the accompanying drawings will be described in detail an electrolysis method using the electromotive force of an electrolyte fluid according to a preferred embodiment of the present invention and an electrolytic cell having power generation capability using the same.

1 is a system diagram illustrating a water electrolysis according to an embodiment of the present invention as an example, and FIGS. 2, 3 and 4 schematically show a perspective view, a plan view, and an exploded view of an electrolytic cell having power generation capability that forms the core of the system. It is shown.

The configuration of each device and a connection relationship between the devices according to a preferred embodiment of the present invention are as follows.

A positive flow path (+110) equipped with a positive electrode (+120) and a negative flow path (-110) provided with a negative electrode (-120) on both the ceiling and the floor of a square cross section are in a pair of top and bottom or left and right A flow path pair 100 wound in a spiral in a predetermined manner is provided.

A circuit 200 to which two electrodes of the pair of flow paths are connected is provided.

A plurality of predetermined magnetic body pairs 300 including magnetic flux frames integrally formed to face each other on the inside and outside of the spiral body so that the magnetic flux horizontally traverses the channel pair 100 is provided.

A separator 400 for separating gas from a mixture of an electrolyte fluid and gas discharged from the flow path 110 and transferring it to a gas compression device through a gas transfer pipe 900 is provided.

The electrolyte fluid injection pipes configured to be alternately connected to each of the flow paths 110 and the separators 400 so that residual electrolyte fluid in the separator alternately circulates between the positive flow path (+110) and the negative flow path (-110) 500 and a discharge pipe 600 are provided.

A pump 800 is provided in the injection pipe 500 and discharges the residual electrolyte fluid sucked from the separator 400 together with a fluid continuously replenished from the electrolyte fluid supply pipe 700 to each flow path.

The flow path pair 100 and the magnetic body pair 300 are accommodated inside, and a housing including a predetermined support and a connection port is provided.

In addition, it includes a driving system for automatically controlling the injection amount and speed of the electrolyte fluid by sensing gas generation amount, flow rate, temperature and pressure in the separator, output voltage and current, and displaying operation performance for each flow path.

The operation of the device provided as described above and detailed embodiments will be described below.

The electrolyte fluid discharged at high speed from the injection port above each of the flow paths (+110, -110) of the flow path pair 100 flows linearly, but since the flow path is wound in a spiral shape, the flow path is continuously rotated around the circle and is not subject to gravity. It is accelerated and descended by the magnetic flux of the pair of magnetic bodies 300 by repeatedly passing through the space where the magnetic flux crosses and the space without magnetic flux, so that the magnetic flux in the fluid is recognized as a time-varying magnetic flux. The same electromotive force is generated.

The above device has a configuration similar to a conventional generator in which an armature, which is a rotor, rotates in the inner space of a field, which is a stator, and induces electromotive force to the armature. By utilizing the characteristic of a fluid that can flow easily and freely, the electrolyte fluid flows linearly in a transverse magnetic field, but passes through a spirally wound flow path, thereby reaping the same effect as the rotation of a rigid armature.

The body of the pair of flow paths, which can be referred to as the main body of the electrolytic cell having power generation capability according to the present invention, is presented in the present embodiment of a device having a cylindrical appearance, but in reality, it may be any shape suitable for the characteristics of the installation site. .

The magnetic flux frame added to the magnetic material pair has a function of preventing leakage magnetic flux by inducing the magnetic flux to flow only to the opposite magnetic material, and a frame for fixing the magnetic material.

In the flow path separated by the positive electrode flow path (+110) and the negative electrode flow path (-110), the electrolyte fluid reacts in half at each electrode without the electrolyte membrane by the above electromotive force. A predetermined catalyst coated on the surface of each electrode or contained in the electrode promotes electrolysis. Taking water electrolysis as an example, the reaction equation is as follows.

In the anode flow path (+110), electrons are released to the electrode by oxidation reaction, and oxygen gas (O ₂ ) and hydrogen ions (H ⁺ ) are generated and flow with the residual aqueous solution. accept an electron from the electrode hydrogen gas (H ₂₎ and hydroxide ions (OH ^-) are generated flow together with the remaining aqueous solution.

The electrode surface provided on the ceiling and the floor of the channel 110 having a rectangular cross section or on one of the surfaces must be installed to always be horizontal with the magnetic field of the magnetic body 300 crossing the channel. The current flowing through the electrode also generates a reactive magnetic field due to the redox reaction, because when the magnetic flux of the pair of magnetic bodies that must traverse the fluid and the electrode surface face each other, the reactive magnetic field on the electrode surface will interfere with the magnetic flux path of the magnetic material.

In addition, since the energy that flows the fluid passing through the flow path without decomposition is lost, the height of the flow path, which is the gap between the electrode and the surface facing the electrode, is made as small as possible, but the width is the largest, so that the injected fluid is wide. It is desirable to be able to contact the surface. Half-reaction in the flow path Considering this, the efficiency of the euro per unit time can be expressed as follows.

As shown in the above reaction equation, gas and ions generated by the half reaction in each flow path pass through the flow path together with the residual electrolyte fluid and are transferred to each separator (+400, -400) for each flow path through the discharge pipe 600. The separator functions to separate the gas from the mixture of the gas discharged from the flow path and the residual electrolyte fluid, and the remaining electrolyte fluid is a stopover for the next circulation.

It is preferable that the separator 400 is provided with a means for separating fluid and ions by installing a cooler in order to primarily collect the produced gas and increase the purity of the collected gas. It is also possible to consider applying a deaerator. In addition, it is necessary to install a flow gauge sensor and a sensor for measuring internal temperature and pressure in the separator and utilize it in the operation system.

The injection pipe 600 sucks ions and residual electrolyte fluid from each separator, but is injected into a flow path opposite to the discharged flow path, so that positive ions and fluid discharged from the positive flow path pass through the negative flow path, and negative ions discharged from the negative flow flow path. The superfluid is connected to the flow path by crossing the discharge pipe and the injection pipe in a manner that faces the anode flow path.

In other words, the electrolyte fluid is the same as the positive flow path (+110) -> separator (+400) -> negative flow path (-100) -> separator (-400) -> positive flow path (+100). By circulating the separators alternately, a half reaction occurs in an independent space without a separator like a conventional electrolyzer, so there is no room for the gases produced by the reaction to recombine with each other, and the ions are the electrodes that will react without resistance of the counter ions at high speed. Is transported.

Therefore, by alternately circulating the acidic solution that has passed through the oxidizing electrode to the cathode and the basic solution that has passed through the reducing electrode to the oxidizing electrode, the separation of the catholyte/anolyte by the membrane and the selective permeation of ions are not required, and the solution around the electrode. Efficient electrolysis can be performed regardless of changes in pH of

It is preferable to provide a device that prevents gas that may remain in the fluid from being mixed in the suction port of the injection pipe 600 that is introduced into the fluid in the separator 400.

The pump 800 of the injection pipe discharges and injects the fluid sucked from the separator 400 and the electrolyte fluid continuously replenished from the supply pipe coupling unit 700 connected together with the flow controller to the inlet of the flow path 110 at high speed. .

Due to the buoyancy of the gas continuously generated by the oxidation source reaction in each of the flow channels and the velocity of the fluid flowing from the electrolyte fluid supply pipe, a pressure difference occurs between the flow path-separator-injection pipe. The principle of a siphon in which the circulation process of suction-discharge-discharge can be operated continuously. Therefore, the pump can be operated intermittently to save energy and prevent overheating of the pump.

When a reaction occurs in the flow path 110 and a current flows through the electrode, Joule heat is generated, and there is a possibility of overheating, especially when the electrode is facing each other.Therefore, a predetermined cooling device is provided in the housing, and the gap between the flow path or the pair of flow paths is A predetermined air gap or refrigerant passage must be combined with the cooling device to maintain a predetermined temperature.

In addition, in the driving system, it is preferable that the performance of each flow path is converted into a database based on an operating time, so that it can be used for determination of maintenance and replacement of a flow path or a pair of flow paths.

The efficiency of the electrolysis method using the electromotive force of the electrolytic fluid according to the present invention and the electrolytic cell having power generation capability using the same is the power applied to the magnetic material pair 300 in the case of a pump driving, a cooling device and an electromagnet that injects the electrolyte fluid. It is appropriate to calculate the ratio of the hydrogen or the object produced to the actual power consumed by subtracting the output on the circuit from the sum. Alternatively, it may be possible to simply indicate the actual power consumed per unit (mass or volume) of hydrogen produced or the object.

On the other hand, since the generation of gas will entail a current flow due to the movement of charges transported by ions, the ratio of the amount of gas to output electricity will always be the same regardless of the flow rate of the electrolyte fluid.

The embodiment described above may be provided with the following additional items or changed characteristics.

The shape of the flow path is a flow path formed by joining members to form a ceiling and a floor of a square cross section in a spiral in the gap between the inner/outer cylinders of a double cylinder, or 3 to form a ceiling, a floor and left and right sides of a square cross section in a spiral form. It may be provided as a flow path molded by dimensional lamination printing or injection molding.

In addition, the flow path is not a ceiling and a floor having a square cross section, but a flow path having electrodes on both left and right or on one side, and may be provided opposite to each other at the upper and lower portions of the spiral flow path pair body so that magnetic flux vertically traverses the flow path. This case may be useful for small devices.

In addition, a predetermined catalyst and a current collector may be added to each electrode of the flow path and provided. The current collector can improve current flow.

In addition, the magnetic material may be provided as an electromagnet. In particular, an electromagnet is preferably used in an electrolytic cell having a plurality of flow path pairs and capable of generating power for the purpose of generating a large amount of gas.

In addition, the flow path may be provided such that the gap between the electrode and the surface facing the electrode becomes narrower as it proceeds from the electrolyte fluid inlet to the outlet port. In this case, since the contact surface between the ions and the electrode plate is maintained and the velocity of the fluid increases, the electromotive force will be improved and the generated gas will be transported.

In addition, there are a plurality of pairs of flow paths, each electrode is connected to form one circuit, the branch pipes extending from the injection pipes and the discharge pipes are connected to each flow path, and the air gap combined with the cooling device between the flow path pair and the flow path pair Alternatively, it may be provided in a manner in which a refrigerant flow path is provided. In this case, it is a suitable method for mass production of products, and economies of scale can be realized even when driven by a pump. As reactions occur in a large number of flow path pairs, it is desirable to optimize the cooling device to prevent overheating.

The magnetic flux frame of the magnetic material pair can be opened and closed and a distance between the magnetic material can be adjusted, and the number of the flow path pair or the flow path can be changed and detachable. As a result, the electrolysis method using the electromotive force of the electrolyte fluid according to the present invention and one of the most important devices in the electrolyzer with the power generation capability using the same, when damaged due to the electric resistance, ionic resistance and scale of the flow path pair, or Partial conversion of the euro-pair system may be possible through the addition of a new euro-pair with improved efficiency.

As described above, the electrolysis method using the electromotive force of the electrolyte fluid according to the present invention and the preferred embodiment of the electrolyzer having power generation capability using the same have been described, but this is described as at least one embodiment, whereby the technical idea of the present invention and The configuration and operation thereof are not limited, and the scope of the technical idea of the present invention is not limited/restricted by the drawings or description with reference to the drawings. In addition, the concepts and embodiments of the invention presented in the present invention may be used by those of ordinary skill in the technical field to which the present invention pertains as a basis for modifying or designing a different structure in order to perform the same object of the present invention. , Modified or changed equivalent structure by a person of ordinary skill in the technical field to which the present invention belongs is bound by the technical scope of the present invention described in the claims, and the spirit or scope of the invention described in the claims Various changes, substitutions, and changes can be made without departing from the limit.

) 자속방향 - 자속이 지면을 뚫고 들어가는 방향
330 자속이 미치는 범위-폭
400 분리기
+400 양극 유로에서 배출된 유체를 수용하는 분리기
-400 음극 유로에서 배출된 유체를 수용하는 분리기
500 주입관
600 배출관
700 전해질 유체 공급관이 주입관에 결합된 결합부
800 펌프
900 생성기체 이송관100 euro pairs
110 euros
+110 positive flow path
-110 cathode flow path
120 electrodes
+120 anode electrode
-120 cathode electrode
200 circuits
300 magnetic body pairs
310 Magnetism
320(

) Magnetic flux direction-The direction in which the magnetic flux penetrates the ground
330 magnetic flux range-width
400 separator
Separator to hold fluid discharged from the +400 anode flow path
Separator to receive fluid discharged from -400 cathode flow path
500 infusion tube
600 discharge pipe
700 Electrolytic fluid supply pipe coupled to the injection pipe
800 pump
900 Generating gas transfer pipe

Claims (9)

Square section A pair of flow paths spirally wound in a predetermined manner in which the anode flow path provided with the anode electrode and the cathode flow path provided with the cathode electrode are paired left and right or up and down on both the ceiling and the floor or on either side;
A circuit in which two electrodes of the channel pair are connected;
A plurality of predetermined magnetic body pairs provided to face each other on the inside and outside of the spiral body so that the magnetic flux horizontally traverses the flow path pair and including a magnetic flux frame;
A separator for separating gas from the mixture of the electrolyte fluid and gas discharged from the respective flow paths and transferring the gas to a gas compression device;
An injection pipe and a discharge pipe connected to each other in a staggered manner so that residual electrolyte fluid in the separator may alternately circulate between the positive flow path and the negative electrode flow path, and connect the flow paths to the separators;
A pump provided in the injection pipe and configured to discharge the electrolyte fluid continuously replenished from a predetermined supply pipe and the residual electrolyte fluid sucked from the separator into each flow path at high speed;
A housing containing the pair of flow paths and the pair of magnetic bodies inside, including a predetermined support and a connector, and having a predetermined cooling device; And
Electrolyte fluid, characterized in that it comprises an operation system for automatically controlling the injection amount and speed of the electrolyte fluid and displaying operation performance for each flow path by sensing gas generation amount, flow rate, temperature and pressure in the separator, and output voltage and current in the circuit. Electrolyzer with electrolysis method and power generation capability using the same. In claim 1 above,
The shape of the flow path is a flow path formed by joining members to form a ceiling and a floor of a square cross section in a spiral shape in the gap between the inner/outer cylinders of the double cylinder, and the electrolysis method using the electromotive force of the electrolyte fluid and the same Electrolyzer with used power generation capability. In claim 1 above,
The shape of the flow path is a flow path formed by a three-dimensional lamination printing or injection molding method to form a ceiling, a floor, and left and right sides of a square cross section in a spiral manner, characterized in that the electrolysis method through the electromotive force of the electrolyte fluid and power generation using the same Electrolyzer with ability. In any one of claims 1 to 3,
The flow path is a flow path in which electrodes are provided on both left and right sides of a rectangular cross section,
The magnetic body is a magnetic body provided opposite to each other on the upper and lower portions of the spiral flow path pair body so that the magnetic flux vertically traverses the flow path, and an electrolytic cell having power generation capability using the same. In any one of claims 1 to 4,
A method of electrolysis through kinetic electromotive force of an electrolyte fluid, characterized in that a predetermined catalyst and a current collector are added to each electrode of the flow path, and an electrolytic cell having power generation capability using the same. In any one of claims 1 to 5,
The magnetic material is an electrolysis method using the electromotive force of the electrolytic fluid, characterized in that the electromagnet, and an electrolytic cell having power generation capability using the same. In any one of claims 1 to 6,
The flow path is an electrolysis method using the electromotive force of the electrolyte fluid, characterized in that the gap between the electrode and the opposing surface becomes narrower as it proceeds from the injection port of the electrolyte fluid toward the discharge port, and an electrolytic cell having power generation capability using the same. In any one of claims 1 to 7,
The plurality of flow path pairs are connected to each electrode to form one circuit, the branch pipes extending from the injection pipes and the discharge pipes are connected to each flow path, and voids or refrigerants combined with a cooling device between the flow path pairs and the flow path pairs An electrolytic cell having a power generation capability using the electrolysis method using the electromotive force of the electrolyte fluid, characterized in that the flow path is provided. In any one of claims 1 to 8,
The magnetic flux frame of the magnetic material pair can be opened and closed and the distance between the magnetic material can be adjusted, and the quantity of the flow path pair or the flow path can be changed and detached, and the electrolysis method using the electromotive force of the electrolytic fluid and power generation capability using the same. Electrolyzer.

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