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KR900006513B1 - Microbio cidal mixture - Google Patents

Microbio cidal mixture Download PDF

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Publication number
KR900006513B1
KR900006513B1 KR1019860002512A KR860002512A KR900006513B1 KR 900006513 B1 KR900006513 B1 KR 900006513B1 KR 1019860002512 A KR1019860002512 A KR 1019860002512A KR 860002512 A KR860002512 A KR 860002512A KR 900006513 B1 KR900006513 B1 KR 900006513B1
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acid
solution
composition
microbio
aqueous
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KR870009637A (en
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이. 온 미카엘
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인터내쇼날 인터스트리스, 아이엔씨이
미카엘 이. 혼
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/02Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents

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  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Agronomy & Crop Science (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

내용 없음.No content.

Description

살균제 조성물Fungicide composition

본 발명은 소듐 클로라이드 수용액과 산, 바람직하게는 락틴산을 약 15wt%로 배합하여 제조한 살균제 조성물에 관한 것이다.The present invention relates to fungicide compositions prepared by combining sodium chloride aqueous solution with an acid, preferably lactinic acid, at about 15 wt%.

본 발명에 의하여 생성된 용액의 pH를 7이하로 감소시키기에 층분한 양의 산을 포함하고 있는 것으로 공기중의 미생물뿐만 아니라 여러가지의 물질들에 존재하는 미생물들에 대하여 살미생물 활성을 갖는 것이다.It contains an amount of acid in order to reduce the pH of the solution produced by the present invention to 7 or less, and has microbicidal activity against microorganisms in various substances as well as in the air.

염소화합물들의 살균제로서의 활성은 오랫동안 알려져온 것이나, 이러한 공지의 제제들에는 여러가지의 단점이 있는 것이다.The activity of the chlorine compounds as fungicides has been known for a long time, but these known agents have various disadvantages.

예를들면, 염소화된 페놀(예를들면, 헥사클로로펜)은 인체에 심각한 독성 및 치사작용을 나타내며 염소가스는 폐로 흡입된 경우에 치명적이고 차아염소산 용액은 유기물에 의하여 불활성화 되거나 희석하여 사용하는 경우에는 비교적 곧 활성이 소실되는 등의 단점이 있는 것이다.For example, chlorinated phenols (e.g. hexachlorophene) have serious toxic and lethal effects on the human body, and chlorine gas is lethal if inhaled into the lungs, and hypochlorous acid solutions are inactivated or diluted by organics. In this case, there are disadvantages such as loss of activity relatively soon.

본 발명에서는 소듐 클로라이드에 산을 가하여 병원 미생물 및 아포를 포함하는 모든 형태의 미생물들을 단시간내에 살멸시킬 수 있는 극히 효과적인 살균제인 이산화염소(CIO2)를 생성시키는데, 이렇게하여 생성된 살균물질은 인체에 대하여 극히 적은 독성만을 나타내는 것이다.In the present invention, acid is added to sodium chloride to produce chlorine dioxide (CIO 2 ), an extremely effective fungicide capable of killing all types of microorganisms including hospital microorganisms and apo, in a short time. Very little toxicity.

본 발명의 산 유래의 생성물인 CIO2는 생성된 CIO2와 반응하는 경향이 있는 광산에 의하여 생성된 것보다 훨씬 효과적이므로, 본 발명은 살균제로서 유용한 생성물의 유효량을 감소시키는 것이다.Since the CIO 2 , an acid-derived product of the present invention, is much more effective than that produced by mines that tend to react with the produced CIO 2 , the present invention is to reduce the effective amount of the product useful as a fungicide.

소듐 클로라이드의 양을 증가시키면 증가시킬수록 CIO2로 더 많이 생성될 것이나, 이는 공기중의 미생물에 사용하는 경우에 사용자에게 독성을 유발시킬 위험이 있는 것이다.Increasing the amount of sodium chloride will produce more CIO 2 , but there is a risk of toxicity to the user when used in airborne microorganisms.

이러한 조성물을 제조함에 있어서 락틴산과 같은 산을 사용하는 것은 락틴산이 클로라이드와 반응하여 이산화염소, 아염소산, 락틴산 및 소듐락데이트로된 혼합물을 생성시키기 때문에 중요한 것이다. 또한, 이러한 물질들로된 평형 혼합물에 의해서는 복합체가 형성되는데, 이러한 혼합물 또는 복합체는 비교적 안정하므로 2주일 또는 그 이상동안까지 살미생물로서의 활성을 유지하는 것이다.The use of acids, such as lactic acid, in preparing such compositions is important because lactic acid reacts with chlorides to produce mixtures of chlorine dioxide, chlorochloric acid, lactinic acid, and sodium lacdate. In addition, an equilibrium mixture of these materials forms a complex, which is relatively stable and thus retains activity as a microorganism for up to two weeks or more.

한편, 본 발명에서는 생성된 용액에 열 또는 음파에너지를 가하여 용액의 살미생물 활성을 더욱 증가시켜 사용하기도 한다.On the other hand, the present invention may be used to further increase the microbial activity of the solution by applying heat or sound energy to the resulting solution.

본 발명의 용액은 침지용액 및 (클로라이드와 락틴산을 에어로졸 형태의 분리용기에 분리하여 넣은 경우에 각 용기마다 벨브 분산장치가 장치되어 있어 각각의 용액이 미세한 안개형태로 자동적으로 분산될 수 있다는 조건하에서) 에어로졸 형태로 또는 1평방 센티미터당 약 1왓트의 강도를 지닌 세척조내에서의 세척용액등으로 사용되는데, 용액에 용이하게 또는 안전하게 침지될 수 없는 물체들을 처리코져하는 경우에는 스폰지, 천 또는 가아제등에 적셔서 사용한다.The solution of the present invention is provided with a valve dispersing device for each container when the immersion solution and (chloride and lactin acid are separated into an aerosol-type separation container so that each solution can be automatically dispersed in a fine mist form) Under) aerosol or as a cleaning solution in a cleaning bath with a strength of about 1 watt per square centimeter, such as a sponge, cloth or gauze for the treatment of objects which cannot be easily or safely immersed in the solution. Soak it on your back.

본 발명에서는 락틴산을 단독으로 사용하거나 또는 다른 산들과 배합하여 사용하는데, 이러한 다른 산들로는 수용성이거나 수분산성인 아세트산, 시트르산, 아스코르빈산, 소르빈산, 푸마르산 및 탄닌산과 같은 유기산 및/또는 염산, 황산, 인산, 질산, 붕산 및 그 유사물질과 같은 무기산을 사용한다.In the present invention, lactic acid is used alone or in combination with other acids, which may be organic or hydrochloric acid such as acetic acid, citric acid, ascorbic acid, sorbic acid, fumaric acid and tannic acid, which are water-soluble or water-dispersible, Inorganic acids such as sulfuric acid, phosphoric acid, nitric acid, boric acid and the like.

용액을 완충시킬 필요가 있는 경우 특히, 생체조직이나 음식물에 사용하는 경우에는 통상적으로 탄산염/중탄산염 또는 인산염, 질산염, 아질산염 또는 다른 염들과 같은 완충제를 사용하여 완충시킨다.When the solution needs to be buffered, especially when used in biological tissues or foods, it is usually buffered with a buffer such as carbonate / bicarbonate or phosphate, nitrate, nitrite or other salts.

클로라이드의 바람직한 형태는 소듐염의 형태이나 포타슘 또는 알카리금속 또는 알카리토금속류의 금속과의 염과 같은 다른 수용성의 형태들도 사용할 수 있다.Preferred forms of the chloride may also be used in the form of sodium salts or other water soluble forms such as salts with potassium or alkali metals or metals of alkali earth metals.

클로라이드에 락틴산을 가하여 형성시킨 최종의 용액을 물로 희석하여 용액의 용량을 증가시킴으로서 용액의 정가(net cost)를 낮출 수 있는 동시에 용액의 독성을 극히 안전한 선까지 저하시킬 수 있는데, 이러한 용액은 몇몇의 식품, 식품처리장치 및 기구들에 안전하게 사용될 수 있다.The final solution formed by adding lactic acid to chloride can be diluted with water to increase the volume of the solution, thereby lowering the net cost of the solution and reducing the toxicity of the solution to an extremely safe level. Can be used safely in food, food processing equipment and appliances.

또한, 이 용액을 사람들이 모이는 병원, 진료소, 공공 및 사용건물, 학교, 가정 및 다른 여러 장소에서 질병을 유발시키는 미생물들을 제거, 조절 및 파괴시키는데 사용될 수 있으며, 동물이 모여있는 장소 또는 온실, 곡물창고, 수경 재배장치 및 식물, 곰팡이, 효모등이 생성될 수 있는 기타의 장소들 뿐만 아니라 그들이 제조되거나 발견될 수 있는 장소에서 살미생물제로서 효과적으로 사용될 수 있다.The solution can also be used to remove, control and destroy disease-causing microbes in hospitals, clinics, public and utility buildings, schools, homes and many other places where people gather, and in places where animals are gathered or in greenhouses, grains It can be effectively used as a microbicide in warehouses, hydroponic cultivators and other places where plants, molds, yeasts, etc. can be produced, as well as where they can be produced or found.

Claims (5)

클로라이드 수용액에 최종의 pH가 7이하가 되도록 산 약 15wt% 혼합함을 특징으로 하는 살균제 조성물.A fungicide composition, characterized in that about 15 wt% of acid is mixed in an aqueous solution of chloride so that the final pH is 7 or less. 제1항에 있어서, 클로라이드 수용액은 알카리 금속 및 알카리토금속으로 구성된 군으로부터 선택된 금속과의 수용성의 염용액임을 특징으로 하는 조성물.The composition of claim 1, wherein the aqueous chloride solution is a water-soluble salt solution with a metal selected from the group consisting of alkali metals and alkaline earth metals. 제1항에 있어서, 산은 수용성이거나 수분산성인 유기 및/또는 무기산임을 특징으로 하는 조성물.The composition of claim 1 wherein the acid is an organic and / or inorganic acid that is water soluble or water dispersible. 제2항에 있어서, 클로라이드 수용액은 소듐 클로라이드 수용액임을 특징으로 하는 조성물The composition of claim 2, wherein the aqueous chloride solution is an aqueous sodium chloride solution. 제3항에 있어서, 산은 락틴산염을 특징으로 하는 조성물.The composition of claim 3, wherein the acid is lactate.
KR1019860002512A 1986-04-02 1986-04-02 Microbio cidal mixture Expired KR900006513B1 (en)

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KR1019860002512A KR900006513B1 (en) 1986-04-02 1986-04-02 Microbio cidal mixture

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KR1019860002512A KR900006513B1 (en) 1986-04-02 1986-04-02 Microbio cidal mixture

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KR900006513B1 true KR900006513B1 (en) 1990-09-03

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8378130B2 (en) 2007-06-12 2013-02-19 Solvay (Societe Anonyme) Product containing epichlorohydrin, its preparation and its use in various applications
US8536381B2 (en) 2008-09-12 2013-09-17 Solvay Sa Process for purifying hydrogen chloride

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8378130B2 (en) 2007-06-12 2013-02-19 Solvay (Societe Anonyme) Product containing epichlorohydrin, its preparation and its use in various applications
US8399692B2 (en) 2007-06-12 2013-03-19 Solvay (Societe Anonyme) Epichlorohydrin, manufacturing process and use
US8536381B2 (en) 2008-09-12 2013-09-17 Solvay Sa Process for purifying hydrogen chloride

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Publication number Publication date
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