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KR910014423A - 폴리이소시아네이트혼합물, 이의 제조방법 및 피복 조성물용 결합제로서 또는 이소시아네이트 그룹 또는 카복실 그룹에 대해 반응성인 화합물용 반응물로서의 이의 용도 - Google Patents

폴리이소시아네이트혼합물, 이의 제조방법 및 피복 조성물용 결합제로서 또는 이소시아네이트 그룹 또는 카복실 그룹에 대해 반응성인 화합물용 반응물로서의 이의 용도 Download PDF

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KR910014423A
KR910014423A KR1019910000997A KR910000997A KR910014423A KR 910014423 A KR910014423 A KR 910014423A KR 1019910000997 A KR1019910000997 A KR 1019910000997A KR 910000997 A KR910000997 A KR 910000997A KR 910014423 A KR910014423 A KR 910014423A
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모스바흐 위르겐
라스 한스-요세프
쿠비짜 베르너
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클라우스 댄너, 귄터 슈마허
바이엘 아크티엔게젤샤프트
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D229/00Heterocyclic compounds containing rings of less than five members having two nitrogen atoms as the only ring hetero atoms
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08Processes
    • C08G18/0804Manufacture of polymers containing ionic or ionogenic groups
    • C08G18/0819Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups
    • C08G18/0823Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups containing carboxylate salt groups or groups forming them
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72Polyisocyanates or polyisothiocyanates
    • C08G18/77Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/78Nitrogen
    • C08G18/79Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
    • C08G18/798Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing urethdione groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72Polyisocyanates or polyisothiocyanates
    • C08G18/80Masked polyisocyanates
    • C08G18/8003Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen
    • C08G18/8048Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen with compounds of C08G18/34

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Paints Or Removers (AREA)

Abstract

내용 없음

Description

폴리이소시아네이트 혼합물. 이의 제조방법 및 피복 조성물용 결합제로서 또는 이소시아네이트 그룹 또는 카복실 그룹에 대해 반응성인 화합물용 반응물로서의 이의 용도
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (9)

  1. (a)평균 NCO 작용가가 1.5 내지 4.0이고, (b)(지환족)지방족 결합된 이소시아네이트 그룹[NCO로서 계산, 분자량:42]의 함량이 2 내지 40 중량%이며, (c)화학적으로 혼입된 카복실 그룹[COOH로서 계산, 분자량:45]의 함량이 0.01 내지 15중량%이고, (d)(지환족)지방족 결합된 우레트디온 그룹[C2N2O2로서 계산, 분자량:84]의 함량이 1 내지 23중량%인 폴리이소시아네이트 혼합물.
  2. (A)(지환족)지방족 결합된 이소시아네이트 그룹과 지환족(지방족) 결합된 우레트디온 그룹을 함유하고 분자량이 168 내지 1,000인 적어도 하나의 디이소시아네이트를 포함하는 폴리이소시아네이트 성분을 (B)분자량이 75 내지 200인 적어도 하나의 지방족 하이드록시카복실산을 포함하는 하이드록시카복실산 성분과 반응시키고, 반응시키는 동안에 하이드록실 그룹에 대한 이소시아네이트 그룹의 당량비를 1.05:1 내지 80:1로 유지함을 특징으로 하여, (a)평균 NCO 작용가가 1.5 내지 4.0이고, (b)(지환족)지방족 결합된 이소시아네이트그룹[NCO로서 계산, 분자량:42]의 함량이 2 내지 40중량%이고 (c)화학적으로 혼입된 카복실 그룹[COOH로서 계산, 분자량:45]의 함량이 0.01 내지 15중량%이고 (d)(지환족)지방족 결합된 우레트디온 그룹[C2N2O2로서 계산, 분자량:84]함량이 1 내지 23중량%인 폴리이소시아네이트 혼합물을 제조하는 방법.
  3. 제2항에 있어서, 하이드록실 그룹에 대한 이소시아네이트 그룹의 당량비를 1.05:1 내지 80:1로 유지하면서, 성분 A)를 적어도 하나의 지방족 결합된 하이드록실 그룹을 함유하는 화합물 10중량% 이하의 양[성분 A)와 B)의 중량을 기준으로 함]과 반응시킴을 추가로 포함하는 방법.
  4. 제2항에 있어서, 반응되지 않은 폴리이소시아네이트의 적어도 일정 분획을 폴리이소시아네이트 혼합물로 부터 증류시켜 제거함을 포함하는 방법.
  5. ⅰ)A)우레트디온 그룹이 필수적으로 존재하지 않고(지환족)지방족 결합된 이소시아네이트 그룹을 함유하고 분자량이 168 내지 1,000인 적어도 하나의 디이소시아네이트를 포함하는 폴리이소시아네이트 성분을 B)분자량이 76 내지 200인 적어도 하나의 지방족 하이드록시카복실산을 포함하는 하이드록시카복실산 성분과 반응시키고, 반응시키는 동안에 하이드록실 그룹에 대한 이소시아네이트 그룹의 당량비를 1.05:1 내지 400:1로 유지한 다음, ⅱ)계속해서 이량체화 촉매의 존재하에 i)에서 수득한 생성물의 이소시아네이트 그룹 5 내지 60중량%을 이량체화 및 임의로 삼량체화하며, ⅲ)임의로 반응되지 않은 출발 폴리이소시아네트의 적어도 일정 분획을 증류시켜제거함을 특징으로 하여, (a)평균 NCO 작용가가 1.5 내지 4.0이고 (b)(지환족)지방족 결합된 이소시아네이트그룹[NCO로서 계산, 분자량:42]의 함량이 2 내지 40중량%이며 (c)화학적으로 혼입된 카복실 그룹[COOH로서 계산, 분자량:45)]의 함량이 0.01 내지 15중량%이고 (d)(지환족)지방족 결합된 우레트디온 그룹[C2N2O2로서 계산,분자량:84]의 함량이 1 내지 23중량%인 폴리이소시아네이트 혼합물을 제조하는 방법.
  6. 제6항에 있어서, 하이드록실 그룹에 대한 이소시아네이트 그룹의 당량비를 1.05:1 내지 400:1로 유지하면서, 성분 A)를 적어도 하나의 지방족 결합된 하이드록실 그룹을 함유하는 화합물 10중량% 이하의 양[성분 A)와 B)를 기준으로함]과 반응시킴을 추가로 포함하는 방법.
  7. 제1항에 따르는 폴리이소시아네이트의 혼합물을 이소시아네이트-반응성 그룹 및/또는 카복실-반응성그룹을 함유하는 반응물과 반응시켜 제조한 고분자량 플라스틱.
  8. 제7항에 있어서, 제1항에 따른 폴리이소시아네이트 혼합물이 3급 아민으로 적어도 부분적으로 중화되는 고분자량 플라스틱.
  9. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019910000997A 1990-01-23 1991-01-22 폴리이소시아네이트혼합물, 이의 제조방법 및 피복 조성물용 결합제로서 또는 이소시아네이트 그룹 또는 카복실 그룹에 대해 반응성인 화합물용 반응물로서의 이의 용도 Withdrawn KR910014423A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE40017834 1990-01-23
DE4001783A DE4001783A1 (de) 1990-01-23 1990-01-23 Polyisocyanatgemische, ein verfahren zu ihrer herstellung und ihre verwendung als bindemittel fuer ueberzugsmittel oder als reaktionspartner fuer gegenueber isocyanatgruppen oder carboxylgruppen reaktionsfaehige verbindungen

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KR910014423A true KR910014423A (ko) 1991-08-31

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US (1) US5098983A (ko)
EP (1) EP0443138A1 (ko)
JP (1) JPH04211418A (ko)
KR (1) KR910014423A (ko)
CA (1) CA2033741A1 (ko)
DE (1) DE4001783A1 (ko)

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US5098983A (en) 1992-03-24
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CA2033741A1 (en) 1991-07-24
DE4001783A1 (de) 1991-07-25

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