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KR970001227B1 - Liquid detergent composition - Google Patents

Liquid detergent composition Download PDF

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KR970001227B1
KR970001227B1 KR1019940023760A KR19940023760A KR970001227B1 KR 970001227 B1 KR970001227 B1 KR 970001227B1 KR 1019940023760 A KR1019940023760 A KR 1019940023760A KR 19940023760 A KR19940023760 A KR 19940023760A KR 970001227 B1 KR970001227 B1 KR 970001227B1
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liquid detergent
composition
detergent composition
extract
plant
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KR960010844A (en
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김태곤
이동환
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주식회사 태평양
한동근
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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/38Products with no well-defined composition, e.g. natural products
    • C11D3/382Vegetable products, e.g. soya meal, wood flour, sawdust
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/96Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
    • A61K8/97Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • A61Q19/10Washing or bathing preparations
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • A61Q5/02Preparations for cleaning the hair
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/10Objects to be cleaned
    • C11D2111/12Soft surfaces, e.g. textile

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  • Wood Science & Technology (AREA)
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  • Chemical Kinetics & Catalysis (AREA)
  • Dermatology (AREA)
  • Biotechnology (AREA)
  • Botany (AREA)
  • Microbiology (AREA)
  • Mycology (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Detergent Compositions (AREA)
  • Cosmetics (AREA)

Abstract

내용 없음.No content.

Description

액체 세정제 조성물Liquid detergent composition

본 발명은 주방용 및 인체용의 액체 세정제 조성물에 관한 것이고, 보다 상세하게는 사포닌을 함유하는 식물 추출물들이 배합되어 있어 이들 추출물들의 본래 기능을 유지할 뿐 아니라 사용시 기포력과 세척력을 증진시켜주는 것을 특징으로 하는 주방용 및 인체용의 액체 세정제 조성물에 관한 것이다.The present invention relates to a liquid detergent composition for dishwashing and human body, and more particularly, plant extracts containing saponin are formulated to maintain the original function of these extracts, as well as to enhance the foaming and cleaning power in use. It relates to a liquid detergent composition for kitchen and human body.

일반적으로 액체 세정제는 계면활성제, 세정보조제, 유효성분, 향 및 물 등으로 조성되며 이중에서 세척능과 기포력을 동시에 발휘하는 것은 계면활성제 뿐이다.In general, the liquid detergent is composed of a surfactant, a detergent preparation, an active ingredient, a fragrance and water, etc. Among them, only the surfactant exerts the washing ability and the bubble power at the same time.

세정제에 주로 사용되는 계면활성제로는 알킬벤젠술포네이트, 알파올레핀술페이트, 소듐 또는 암모늄라우릴술페이드, 알킬베타인, 아민옥사이드, 에톡시화 알콜에테르, 알킬폴리 글루코사이드, 지방산 아마이드 등이 있으며, 이들은 모두 석유 또는 식물의 1성분을 출발물질로 하는 합성 계면활성제이다. 그러나 합성 계면활성제들은 경우에 따라 피부자극과 주부습진 같은 피부염을 유발하고 세척후 피세정 물질 표면에 잔류하여 이로 인한 인체독성의 원인제공이 되기도 한다.Surfactants commonly used in cleaning agents include alkylbenzenesulfonates, alphaolefin sulfates, sodium or ammonium lauryl sulfates, alkylbetaines, amine oxides, ethoxylated alcohol ethers, alkylpolyglucosides, and fatty acid amides. All are synthetic surfactants starting from one component of petroleum or plant. However, synthetic surfactants sometimes cause skin irritation and dermatitis such as housewife eczema and remain on the surface of the substance to be cleaned after washing, thereby providing a cause of human toxicity.

따라서 저자극성 계면활성제의 개발 또는 가능한 소량의 계면활성제를 사용하는 제품의 개발노력이 꾸준히 계속되고 있다. 또한 최근에는 액체 세정제에 천연의 추출물, 오이즙, 살구즙, 레몬즙, 알로에 등을 첨가하여 자연의 신선한 향취를 부여하고 이들 추출물이 갖는 보습 및 영양공급 효과를 제품에 부여하고자 하는 시도가 계속되고 있다.Therefore, efforts are being made to develop hypoallergenic surfactants or products using small amounts of surfactants as much as possible. In addition, in recent years, attempts have been made to add natural extracts, cucumber juice, apricot juice, lemon juice, aloe, etc. to liquid detergents to impart a fresh natural flavor and to provide the product with moisturizing and nourishing effects. have.

그러나 이러한 식물 추출물들은 경우에 따라 세정제 본래의 세척력 및/또는 기포력의 감소를 초래하고 이로 인하여 사용량에 제한을 받게 되는 등의 문제점을 갖고 있다.However, these plant extracts have a problem such that, in some cases, the inherent washing power and / or foaming power of the cleaning agent are reduced, thereby limiting the amount used.

이러한 상황하에서 본 발명자들은 상기한 종래 기술의 문제점을 갖지 않으면서 액체 세정제에 첨가되는 경우 피부보호 효과, 보습 효과, 식물 추출물의 신선한 식물취의 부여효과를 나타내며, 종래의 식물 추출물들과는 달리 세척력 및 기포력을 증가시켜 합성 계면활성제의 사용량을 감소시킬 수 있는 식물 추출물을 함유하는 액체 세정제를 제공하고자 광범위하게 연구한 결과, 사포닌을 함유하는 식물의 추출물을 액체 세정제에 배합시키면 상기 목적을 달성할 수 있음을 발견하고 본 발명을 완성하기에 이르렀다.Under these circumstances, the present inventors show a skin protection effect, a moisturizing effect, and impart a fresh plant odor of a plant extract when added to a liquid detergent without having the problems of the prior art described above, and unlike the conventional plant extracts, the cleaning power and air bubbles are different. Extensive research has been conducted to provide a liquid detergent containing a plant extract capable of increasing the use of synthetic surfactants to reduce the amount of synthetic surfactants. The purpose of this can be achieved by incorporating an extract of a plant containing saponin into the liquid detergent. To discover and complete the present invention.

즉, 본 발명의 목적은 사포닌을 함유하는 식물의 추출물을 조성물 총 중량의 0.5~20중량부의 양으로 함유함을 특징으로 하는 액체 세정제 조성물을 제공하는 것이다.That is, an object of the present invention is to provide a liquid detergent composition, characterized in that it contains an extract of a plant containing saponin in an amount of 0.5 to 20 parts by weight of the total weight of the composition.

본 발명의 다른 목적은 사포닌을 함유하는 식물의 추출물로서 천문동(Asparagus), 버쳐스 블룸(Butchers bloom), 금잔화(Calendula), 데드 넷틀(Dead nettle), 인삼(Ginseng), 호스 체스넛(Horse chesetnut), 쇠뜨기(Horse tail), 감초(Liquorice), 로즈마리(Rosemary), 사게(Sage), 유카(Yucca) 및 퀼랄라(Quillala)로 이루어진 군에서 선택된 1종 또는 2종 이상의 식물의 추출물을 조성물 총 중량의 0.5~20중량부의 양으로 함유함을 특징으로 하는 액체 세정제 조성물을 제공하는 것이다.Another object of the present invention is as an extract of a plant containing saponin, Asparagus, Butchers bloom, Calendula, Dead nettle, Ginseng, Horse chesetnut The total weight of the composition of the extract of one or two or more plants selected from the group consisting of Horsetail, Liquorice, Rosemary, Sage, Yucca and Quillala It is to provide a liquid detergent composition characterized by containing in an amount of 0.5 to 20 parts by weight.

본 발명의 또다른 목적은 사포닌을 함유하는 식물의 추출물로서 천문동(Asparagus), 버쳐스 블룸(Butchers bloom), 금잔화(Calendula), 데드 넷틀(Dead nettle), 인삼(Ginseng), 호스 체스넛(Horse chesetnut), 쇠뜨기(Horse tail), 감초(Liquorice), 로즈마리(Rosemary), 사게(Sage), 유카(Yucca) 및 퀼랄라(Quillala)로 이루어진 군에서 선택된 2종 이상의 식물의 추출물을 조성물 총 중량의 0.5~20중량부의 양으로 함유함을 특징으로 하는 액체 세정제 조성물을 제공하는 것이다.Still another object of the present invention is an extract of a plant containing saponin, Asparagus, Butchers bloom, Calendula, Dead nettle, Ginseng, Horse chesetnut ), Horsetail, Liquorice, Rosemary, Rosemary, Sage, Yucca and Quilala, extracts of two or more plants from 0.5% of the total weight of the composition. It is to provide a liquid detergent composition characterized by containing in an amount of ˜20 parts by weight.

본 발명의 또다른 목적 및 적용은 하기 발명의 상세한 설명으로부터 당업자에게 명백해질 것이다.Still other objects and applications of the present invention will become apparent to those skilled in the art from the following detailed description.

본 발명에 따르면 사포닌을 함유하는 식물 추출물들을 배합시킨 액체 세정제 조성물이 제공된다.According to the present invention there is provided a liquid detergent composition comprising a combination of plant extracts containing saponin.

사포닌은 식물중에 함유되어 기포를 생성시키는 식물성 계면활성 물질을 총칭하여 일컫는 용어이며, 자연계에 존재하는 사포닌은 다음의 두 종류의 비당부(Aglycone)와 당부(Glucose moiety)의 결합구조로 이루어져 있다.Saponin is a generic term for vegetable surfactants contained in plants to create bubbles. Saponins in nature are composed of the following two structures: Aglycone and Glucose moiety.

사포닌의 비당부(非糖部)Unsugared part of saponin

사포닌을 함유하는 식물의 추출물로는 천문동(Asparagus), 버쳐스 블룸(Butchers bloom), 금잔화(Calendula), 데드 넷틀(Dead nettle), 인삼(Ginseng), 호스 체스넛(Horse chesetnut), 쇠뜨기(Horse tail), 감초(Liquorice), 로즈마리(Rosemary), 사게(Sage), 유카(Yucca) 및 퀼랄라(Quillala) 등을 예시할 수 있으며, 이러한 식물들이 함유하고 있는 주요 성분과 효과는 다음 표 1과 같다.Extracts of plants containing saponins include Asparagus, Butchers bloom, Calendula, Dead nettle, Ginseng, Horse chesetnut, Horsetail ), Liquorice, Rosemary, Sage, Yucca, and Quilala, and the main components and effects of these plants are shown in Table 1 below. .

식물 추출물을 함유하는 종래의 액체 세정제 조성물은 술폰산염 5.0~20.0중량%, 지방산 아마이드, 아민옥사이드 등의 증포제 0.5~10.0중량%로 조성되고, 여기에 오이즙, 레몬즙, 알로에 등의 식물 추출물 0.0~3.0중량부를 더 함유시켜 인체에 접촉 또는 사용시에 피부보습효과와 자연취를 부여하고 있다. 이들 조성물들은 상술한 바와 같이, 세정제 조성물의 기포력과 세정력을 감소시키기 때문에 그의 사용량에 제한이 있었고, 따라서 소량의 사용으로는 목적하는 효과를 얻기가 어려웠다.Conventional liquid detergent composition containing a plant extract is composed of 5.0 to 20.0% by weight of sulfonate, 0.5 to 10.0% by weight of a thickener such as fatty acid amide, amine oxide, etc., plant extracts of cucumber juice, lemon juice, aloe and the like. It contains 0.0 ~ 3.0 parts by weight to give skin moisturizing effect and natural odor when in contact with or use of human body. As described above, these compositions have limited use amount because they reduce the foaming force and the cleaning power of the cleaning composition, and thus, it is difficult to obtain a desired effect with a small amount of use.

그러나 본 발명에서 처럼 사포닌계 식물 추출물을 액체 세정제의 총 중량을 기준으로 하여 0.5 내지 20중량부의 양으로 함유시키면 식물 추출물 자체의 보습효과, 자연취 기능은 물론 세척력 및 기포력도 가지므로, 기존에 세정제에 배합되는 합성 계면활성제의 사용량을 감소시키거나 성능을 개선시킬 수 있는 장점을 갖는다. 본 발명에 따른 식물 추출물은 각 식물을 처리하여 식물로부터 추출물을 얻는 통상의 방법에 의해 얻을 수 있다. 특히 추출용매로는 바람직하게는 물이 사용된다.However, when the saponin-based plant extract is contained in an amount of 0.5 to 20 parts by weight based on the total weight of the liquid detergent, as in the present invention, the plant extract itself has a moisturizing effect, natural odor function, as well as washing power and foaming power. It has the advantage of reducing the amount of synthetic surfactant formulated into the detergent or improving its performance. The plant extract according to the present invention can be obtained by a conventional method of treating each plant to obtain an extract from the plant. In particular, water is preferably used as the extraction solvent.

천연 계면활성제와 합성 계면활성제의 인체 안전성에 대한 차이는 합성 계면활성제는 그의 합성시에 과도한 화학반응을 시켜야 되고 이때 부생 또는 잔존하는 산화 생성물 또는 금속 산화물이 주로 독성 원인 물질이 되는 것에서 기인한다. 따라서 인체 안전성을 높이기 위하여는 가능한한 합성 계면활성제 함유량을 줄이는 것이 필요한데, 본 발명에 의한 사포닌계 식물 추출물은 천연의 계면활성제 기능을 하면서 공지의 액체세정제에 있어 합성의 계면활성제 대체 기능을 할 수 있으므로 합성 계면활성제의 사용량을 줄일 수 있게 하는 것이 본 발명에 의한 특징중의 하나인 것이다.The difference in the human safety of natural and synthetic surfactants is due to the fact that synthetic surfactants must undergo excessive chemical reactions in their synthesis, whereby by-products or residual oxidation products or metal oxides are mainly toxic agents. Therefore, in order to increase human safety, it is necessary to reduce the content of the synthetic surfactant as much as possible. Since the saponin-based plant extract according to the present invention functions as a natural surfactant, it can function as a substitute for a synthetic surfactant in a known liquid detergent. It is one of the features of the present invention to be able to reduce the amount of synthetic surfactant used.

이하 본 발명을 실시예에 따라 상세히 설명하면 다음과 같다.Hereinafter, the present invention will be described in detail with reference to Examples.

실시예 1 및 비교예 2~3Example 1 and Comparative Examples 2-3

주 1 : POE는 플레옥시에틸렌기를 의미한다.Note 1: POE means pleoxyethylene group.

상기한 각 성분을 실온에서 순서대로 혼합하여 주방용 액체 세정제를 제조하였다.Each of the above components was mixed in order at room temperature to prepare a dishwashing liquid detergent.

상기 성분중, (e), (f), (g) 및 (h)의 식물 추출물은 각 식물을 파쇄한 후 적량의 물과 함께 내압용기에서 가온한 후 압착여과하고, 그 여액을 진공건조하여 얻은 분말상의 추출물이다.Among the above components, the plant extracts of (e), (f), (g) and (h) are crushed to each plant, warmed in a pressure vessel with an appropriate amount of water, compressed and filtered, and the filtrate is vacuum dried. It is the powdery extract obtained.

각 조성물의 기포력, 세척력 및 사용감을 측정하고 향취를 관능적으로 평가하였다. 결과를 하기 표 2에 나타내었다.The foaming power, washing power, and usability of each composition were measured, and the smell was sensory evaluated. The results are shown in Table 2 below.

주 1 : 기포력은 직경 3cm, 높이 30cm의 실린더에 각 0.2% 수용액, 25ml를 30℃에서, 동일한 회전방법으로 100회전시킨 후의 기포 높이이다.Note 1: The bubble force is the bubble height after rotating 100 ml of each 0.2% aqueous solution and 25 ml in a cylinder of diameter 3cm and height 30cm by 30 degreeC at the same rotation method.

주 2 : 세척력은 리너츠방법(KSM 2716)에 준하여 현미경글라스에 식용유지로 만든 기름때를 오염시킨 후 각 0.2% 수용액을 실온에서 교반기로 5분간 회전시킨 후 세정된 무게 비율로 계산하였다.Note 2: The washing power was calculated by the weight ratio of each 0.2% aqueous solution rotated for 5 minutes with a stirrer at room temperature after contaminating the oil stain made of edible oil on the microscope glass according to the Linz method (KSM 2716).

주 3 : 30명에게 주방에서 식기 세정후의 피부의 거칠음을 감각적으로 판단하게 하고 그 결과를 상호 비교하여 다음 기준으로 평가하였다.Note 3: Thirty patients were sensibly judged on the roughness of skin after dish washing in the kitchen, and the results were compared and evaluated based on the following criteria.

◎ 거칠어지지 않고 당김이 적다. ○ 보통이다. △ 나쁘다.◎ It does not become rough and draws little. ○ Normal. △ bad.

상기 표 3의 결과에서 알 수 있듯이, 실시예 1의 본 발명의 세정제 조성물은 계면활성제 총량이 동일한 비교예 2의 조성물에 비하여 세척력, 기포력, 사용감 그리고 향취에 있어 우위를 보여주며 계면활성제 총량에 있어 25%를 더 사용한 비교예 1의 조성물과는 거의 동일한 세척력 및 기포력을 보여주며 향취와 사용감에 있어서는 우위를 보여주고 있다.As can be seen from the results of Table 3, the detergent composition of the present invention of Example 1 shows the superiority in the cleaning power, foaming force, feeling and smell compared to the composition of Comparative Example 2 the total amount of the surfactant and the total amount of the surfactant As shown in FIG. 1, the composition of Comparative Example 1, which was used at 25% more, showed the same cleaning power and foaming power, and showed an excellent smell and feeling.

실시예 2 및 비교예 3,4Example 2 and Comparative Examples 3 and 4

상기 각 성분을 70℃에서 용해 교반하여 두발용 세정제 조성물을 제조하였다. 이들 실시예 2 및 비교예 3-4의 두발용 세정제 조성물에 함유되는 식물 추출물들인 (m), (o), (p), (q), (r) 및 (s)의 성분은 실시예 1과 동일한 방법으로 제조한 것이다.Each component was dissolved and stirred at 70 ° C to prepare a cleaning composition for hair. The components of the plant extracts (m), (o), (p), (q), (r) and (s) which are contained in the hair cleanser compositions of Examples 2 and Comparative Examples 3-4 are Example 1 It is prepared in the same manner as.

상기 세종류의 두발용 세정제 조성물에 대하여 기포력, 세척력 및 사용감을 측정하며, 향취를 관능적으로 평가하고 그 결과를 하기 표 3에 나타내었다.For the three types of hair cleansing composition, the foaming power, the washing power, and the feeling of use were measured, the fragrance was evaluated sensoryly, and the results are shown in Table 3 below.

주 1 : 기포력은 직경 15mm, 높이 20cm의 비이커에 각 0.2% 수용액 300ml를 넣고 30℃, r.p.m 2000으로 교반시킬때 5분후 생성된 기포의 양을 높이로 측정.Note 1: Bubble force is measured by measuring the amount of bubbles generated after 5 minutes by adding 300 ml of 0.2% aqueous solution to a beaker of 15 mm diameter and 20 cm height and stirring at 30 ° C and r.p.m 2000.

주 2 : 세척력은 실시예 1과 동일한 방법으로 측정.Note 2: The washing power was measured in the same manner as in Example 1.

주 3 : 20명에게 각 세정제 조성물을 이용하여 세발하게 한 후 머리결의 상태를 감각적으로 상호 비교하게 하고, 상대적으로 다음 기준으로 평가하였다.Note 3: Twenty subjects were subjected to trituration using each detergent composition, and then the condition of hair was sensibly compared with each other, and evaluated based on the following criteria.

◎ 부드럽고 매끈하다. ○ 보통이다. △ 다소 빽빽하다.◎ Soft and smooth. ○ Normal. △ somewhat dense.

상기 표 3의 결과에서 알 수 있듯이, 본 발명에 따른 실시예 2의 조성물은 계면활성제의 총량이 동일한 비교예 4의 조성물에 비하여 세척력, 기포력, 사용감, 그리고 향취에 있어서 우위를 보여주며, 계면활성제 총량에 있어 3%를 더 사용한 비교예 3의 조성물과는 거의 동일한 세척력 및 기포력을 보여주며 향취와 사용감에 있어서는 우위를 보여주고 있다.As can be seen from the results of Table 3, the composition of Example 2 according to the present invention shows an advantage in washing power, foaming force, usability, and odor compared to the composition of Comparative Example 4 in the total amount of the surfactant, the interface The composition of Comparative Example 3, which further used 3% in the total amount of the active agent, showed almost the same washing power and foaming power, and showed an advantage in smell and feeling.

Claims (2)

조성물 총 중량을 기준으로 계면활성제 5.0~20.0중량% 및 증포제 0.5~10.0중량%로 조성되는 액체 세정제 조성물에 있어서, 사포닌을 함유하는 식물의 추출물을 조성물 총 중량의 0.5~20중량부의 양으로 함유하는 것을 특징으로 하는 액체 세정제 조성물.A liquid detergent composition composed of 5.0 to 20.0 wt% surfactant and 0.5 to 10.0 wt% thickener based on the total weight of the composition, wherein the extract of a plant containing saponin is contained in an amount of 0.5 to 20 parts by weight of the total weight of the composition A liquid detergent composition, characterized in that. 제 1항에 있어서, 사포닌을 함유하는 식물의 추출물은 천문동(Asparagus), 버쳐스 블룸(Butchers bloom), 금잔화(Calendula), 데드 넷틀(Dead nettle), 인삼(Ginseng), 호스 체스넛(Horse chesetnut), 쇠뜨기(Horse tail), 감초(Liquorice), 로즈마리(Rosemary), 사게(Sage), 유카(Yucca) 및 퀼랄라(Quillala)로 이루어진 군에서 선택된 1종 또는 2종 이상의 식물의 추출물임을 특징으로 하는 액체 세정제 조성물.The method of claim 1, wherein the extract of the plant containing saponin is Asparagus, Butchers bloom, Calendula, Dead nettle, Ginseng, Horse chesetnut Characterized in that the extract of one or two or more plants selected from the group consisting of horsetail (Horse tail), Liquorice, Rosemary, Rosemary, Sage, Yucca and Quilala (Quillala) Liquid detergent composition.
KR1019940023760A 1994-09-17 1994-09-17 Liquid detergent composition Expired - Fee Related KR970001227B1 (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100987344B1 (en) * 2008-11-17 2010-10-18 박종호 Water soap using natural raw materials
KR20190026121A (en) * 2017-09-04 2019-03-13 김대송 Liquid detergent composition

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100467022B1 (en) * 1997-02-19 2005-06-22 주식회사 엘지생활건강 Cosmetic soap composition
KR100426265B1 (en) * 2000-01-06 2004-04-13 김용준 salt of rosemary

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100987344B1 (en) * 2008-11-17 2010-10-18 박종호 Water soap using natural raw materials
KR20190026121A (en) * 2017-09-04 2019-03-13 김대송 Liquid detergent composition

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