TW520274B - Fungicidal mixtures based on tris (oxime ether) derivatives and insecticides - Google Patents

Abstract

Mixtures for crop protection, comprising as active components (a) phenylacetic acid derivatives of formula I in which the substituents and the index are each as defined in the description, and their salts, and (b) at least one compound of the formulae II, V, X and XI in a synergistically effective amount. A mixture for crop protection, comprising as active components (a) phenylacetic acid derivatives of the formula (I) in which the substituents and the index have the following meaning: X is NOCH3; Y is NR; R1, R independently of one another are each hydrogen or C1-C4-alkyl; R3 is hydrogen or C1-C4-alkyl; R4, R6 independently of one another are each hydrogen or C1-C4-alkyl; R5 is hydrogen or C1-C4-alkyl; and their salts, and (b) at least one compound of formulae (II), (V), (X) and (XI) in a synergistically effective amount.

Description

~ Υζ / 4, Description of the invention (1) The present invention relates to the control of harmful maggots and insect mixtures, including a) phenylacetic acid derivative R3 of formula I

(I) The substituents and parameters have the following definitions: X is noch3, choch3, or chch2 is oxygen or NR; R is hydrogen and CrC4-alkyl, respectively; cyano, nitro, tris-methyl, and crc4 -Alkoxy; 0, 1 or 2; where m is 2, then the R2 group may be different; C "C4-alkyl, cvcv haloalkyl, C3-C6- Y R1 R2 m R3 halogen, CrC4- Base and ------- ^ ------- Shang --- (Please read the phonetic on the back? Matters on this page} Order · Department of hydrogen and cyano ring; R4 and R6 are each Hydrogen CrC1 ()-Alkyl- 丨 Line · Printed by C3_C6-Wei Keji, c2-C1 ()-Aminoyl, CrC1G-Alkylcarbonyl, c2_Ci (renecarbonyl, c3_c) ^ Alkynyl or CrC1 (r), where these groups may be partially or fully dented or may carry one to three of the following groups: cyano, nitro, hydroxyl, fluorenyl, amine, j , Amine carbonyl, amine thiocarbonyl, 1¾, C, C6-fe, c, c6-fluorenyl, Ci-CV, fluorenyl, C, C6-alkylidene, c, c6-alkoxy Basic, c "C6- 卣 C2-C1 (r -4- 'paper size applies to China National Standard (CNS) A4 specification (210 X 297 mm) 520274 A7 ----- B7 V. Description of the invention (2) (Please read the precautions on the back page first) Oxygen, CrC6-oxooxycarbonyl, c "c6-thiothio, CrC6_ amine, di-C "C6-alkylamino, Crc6-alkylaminocarbonyl, di-CVCV alkylaminecarbonyl, crc6-alkylaminethiocarbonyl, di-CrC6 ^ aminothiocarbonyl, C2-C6-fluorenyl, C2-C6-alkenyloxy, c3-c6-cyclo, C3-C0-cycloalkoxy, heterocyclyl, heterocyclyl, fluorenyl, fluorenyloxy, aryl, aryloxy, arylthio, heteroaryl, heteroaryloxy And heteroarylthio groups, in which the cyclic group may be partially or completely atomized or may carry one to three of the following groups: cyano, nitro, benzyl, sharp, amine, compound, Amine carbonyl, amine thiocarbonyl, i element, crc6-: fe · group, cvc6-fluorenyl group, cvcv alkyl group, CVC6-alkylene group, c3-C6-cycloalkyl group, cv c6-alkyloxy group, crc6 -Haloalkoxy, crC6-alkoxycarbonyl, cvcvsulfanyl, crc6-alkylamino, di-crc6-alkylamino, CVCV alkylamine carbonyl, di-c "c6-alkylaminecarbonyl, c" C6- Alkylaminothio, di-C6-C6-alkylaminethiocarbonyl, c2-cv alkenyl, c2-c0-enyloxy, fluorenyl, fluorenyloxy, aryl, aryloxy , Arylthio, heteroaryl, heteroaryloxy, heteroarylthio or C (= NOR7) -An-R8; printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, aryl, arylcarbonyl, arylsulfonyl, Heteroaryl, heteroarylcarbonyl or heteroarylsulfonyl, where these groups may be partially or completely halogenated or may carry one to three of the following groups: cyano, nitro, hydroxyl, thiol, amino, carboxyl, aminecarbonyl , Amine thiocarbonyl, pixel, Crc6-alkyl, Crc6-haloalkyl, alkylcarbonyl, CrC6-alkylsulfonyl, crc6-alkylene, c3-C6-cyclohexyl, CrC6-fluoren-5- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 520274 A7 B7 V. Description of the invention (3) Oxygen, CrC6-haloalkoxy, CrC6-alkoxycarbonyl, c "c6- pit Stone JfL group, CrC6-pit amino group, di-CVCV amine group, alkylamine carbonyl group, di-CrC6-alkylamine carbonyl group, CVC6-alkylamine thiocarbonyl group, di-CrC6-alkylamine thiocarbonyl group, C2-C6- Alkenyl, C2-C6-fluorenyloxy, fluorenyl, fluorenyloxy, aryl, aryloxy, heteroaryl, heteroaryloxy or C (= NOR7) -An-R8; R5 is hydrogen,

Ci-C6-fe group, C2-C6-fluorenyl group, C2-C6-block group, in which the hydrocarbon group of these groups may be partially or completely self-defined or may carry one to three of the following groups: cyano, nitro, · Hydroxyl, thiol, amine, amide, aminocarbonyl, aminethiocarbonyl, halogen, Crc6-alkylaminecarbonyl, di-CVCV alkylaminecarbonyl, crc6-alkylaminethiocarbonyl, di-cvcv alkylaminethiocarbonyl, CrC6 -Alkylsulfonyl, crC6-alkylsulfinyl, crC6-alkoxy, CrC6-halohaloxy, c6-C6-alkoxycarbonyl, CrC6-alkylthio, crc6-alkylamino, di-C "C6-alkylamino, c2-c6-fluorenyloxy, c3-cv cycloalkyl, C3-C6-cycloalkoxy, heterocyclyl, heterocyclyloxy, aryl, aryloxy, aryl_ Crcv alkoxy, arylthio, aryl-Crc4-alkylthio, heterosquare, heteroaryloxy, heteroaryl-C, C4-alkoxy, heteroarylthio, heteroaryl-CrCV Thio, in which the cyclic group may be partially or fully halogenated and / or may carry one to three of the following groups: cyano, nitro, hydroxy, thiol, amine, carboxyl, aminecarbonyl, aminecarboxanyl , Base, CrCV ^:!: Wanji, CVC6-: fe jiji, CVCV sulfinyl, C3- (V ring CrCV -6-This paper size is applicable to China National Standard (CNS) A4 specification (210 X 297 public love) -------------- install ----(Please read the Note on this page) 1Τ · _ 丨 Line · Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs 'Consumer Cooperatives 520274 A7 V. Description of the invention (4 Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs' Consumer Cooperatives where A η R7 R8 thiol, crc6- Haloalkoxy, crc6-alkoxycarbonyl, crc6-sulfanyl, c "c6-alkylamino, di-C" C6-alkylamino, crC6-alkylaminocarbonyl, di-C "C6-alkylaminecarbonyl , Alkylamine thiocarbonyl, -crc6-aminoamine thiocarbonyl, C2-C6-fluorenyl, c2-C6-associyloxy, fluorenyl, benzyloxy, aryl, aryloxy, arylthio, heteroaryl , Heteroaryloxy, heteroarylthio, and C (= NOR7;)-An_ R8; n C3-C6 cycloalkyl, C3_C6_cycloalkenyl, heterocyclyl, aryl, heteroaryl, among which the cyclic group May be partially or completely halogenated or may carry one to two of the following groups: cyano, nitro, hydroxyl, thiol, amine, fluorenyl, amine carbonyl, amine thiocarbonyl, halogen, alkyl, C1-C6-halo Alkyl, crc6-alkanesulfenyl, alkylsulfinyl, C3-C6-cyclofluorene , Cvcy alkoxy, Ci-Cv_alkoxy, Crc6-carboxycarbonyl, C "C6-fluorenylthio, c" c6 • regamine, di-crc6-carbamine, cvcv alkyl, Di-c "C6-alkylamine carbonyl, Cl_c6-alkylamine thiocarbonyl, dialkylamine stone as a radical, C2-C6-alkenyl, c2-C6-alkenyloxy, benzyl, benzyloxy, aryl, Aryloxy, heteroaryl, and heteroaryloxy; is oxygen, sulfur, or nitrogen and wherein nitrogen bears hydrogen or K "alkyl; is 0 or 1; is hydrogen or CrC6-alkyl and is hydrogen or CrC6-alkane Base, — and its salts

------------- Installation --- * * (Please read the note on the back page first) Order--Line Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 520274 A7 B7___ V. Invention description (8)

Otsuka; Furacon® from Siapa Chem); IX · CAS RN 1 1 1 988-49-9, common name: thiacloprid (developed product from Bayer); X · Porc · of the 1998 Brighton Conference f, Pests and

Diseases ’’, Vol. 1, pp. 21-26 (MTI 446 from Mitsui);

Proc. Of the Brighton Conference on Pests and Diseases,

Vol. 1, pp. 27-36 (CGA 293 343, from Novartis) o Due to the c = C-and c = N-double bonds of compound I, compound I can be obtained as a mixture of E / z isomers, It can be separated into individual compounds in a conventional manner, such as crystallization or chromatography. If a mixture of isomers is synthesized, separation is usually not required, because in some cases the isomers can be converted into each other during compounding or application (such as exposure, acid or base). Similar transformations can also occur after application, such as in the treatment of plants, or harmful fungi or animal pests to be controlled. From the perspective of C = x double bond, the £ type isomer of the compound has better activity (mainly in the -OCH3 or 弋 h3 group relative to -C ^ R1). From the point of view of < (! 13) = > ^ 0 (: 112_double bond, the cis isomer of the compound〗 has better activity (the main configuration is the R3 group relative to the -OCH2 · group) ). In the definition of the compound at the beginning! The collective terms used often list substituents: halides · fluorine, chlorine, bromine, and permutation; k-groups. Straight chain of 1 to 4, 6 or 0 carbon atoms Or a branched alkyl group, such as a methyl group, such as methyl, ethyl, propane 1, 1-methylethyl, butyl, i-propylpropyl, 2. methylpropyl, 1, "dimethyl Ethyl, pentyl, methylbutyl. I ---- --- * ♦ (Please read the precautions on this page first)

It, ... --line -11-520274 A7 B7 V. Description of the invention (9) group, 2-methylbutyl, 3-methylbutyl, 2, dimethylpropyl, ethylethyl, hexyl, 1 Dimethyl propyl, i, 2 dimethyl propyl, p-methylpentyl, 2-fluorenylpentyl, 3-fluorenylpentyl, 4-methylpentyl ... methylbutyl, i, 3-dimethylbutyl, 2,2 · dimethyl: butyl methyl; butyl 2,3-dimethylbutyl, 3,3-dimethylbutyl, ethyl ethyl, butyl ethyl '1 1,2-trimethylpropyl, ^ 2-trimethylpropyl, 丨 ethyl small methylpropyl and 1-ethyl-2-methylpropyl; i alkyl · 1 to 6 Carbon atom of the above straight or branched alkyl group, in which some or all of the hydrogen atoms of these groups may be replaced by the above quotient atom, such as Cr Criyl group such as methyl, dimethyl, trimethyl , Fluoromethyl, difluoromethyl, trifluoromethyl, chlorofluoromethyl, difluorofluoromethyl, fluorodifluoromethyl, 1-fluoroethyl, 2-chloroethyl, 2,2-difluoro Ethyl, 2,2,2-trifluoroethyl, 2-chloro-2-fluoroethyl, 2-chloro-2,2-difluoroethyl, 2,2-dichlorofluoroethyl, 2,2 , 2-trifluoroethyl and pentafluoroethyl; ¥ alkane Group: monocyclic alkyl group with 3 to 6 carbon ring members, such as cyclopropyl, cyclobutyl, cyclopentyl and cyclohexyl; Alkenyl: unsaturated straight or branched chain with 2 to 6 or Carbon atom and a hydrocarbon group having a double bond at any position, such as c2-C6-alkenyl such as vinyl, propenyl, 2-propenyl, 1-methylvinyl, butenyl, 2-butene Methyl, 3-butyridinyl, 1-methyl-1-propenyl, 2-methyl- 丨 -propenyl, methyl-2-propenyl, 2-methyl-2-propenyl, 1-pentenyl, 2-pentenyl, pentenyl, 4-pentenyl, 1-methyl-1-butenyl, 2-methyl-butenyl, 3-methyl-butenyl, 1-methyl 2-butenyl-methyl-2-butenyl, 3-methyl-2-butenyl, 1-fluorenyl-3-butenyl, 2-methyl-3-butenyl, 3 -Methyl- 12 This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) -------------- install --- * * (Please read the Note on this page) Order ·· 丨 Line · Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 520274 A7 ------ -B7 'V. Description of the invention (1〇) 3-butenyl, 1, 1_ Dimethacryl, L2-di _ 丨 _propenyl, 1,2-dimethyl-2-propenyl, b ethylpropenyl, ^ ethylpropenyl, 1-hexenyl, 2-hexenyl, 3_hexyl Methyl, hexenyl, 5-hexenyl, 1-methyl-1-pentenyl, 2-methyl 4-pentenyl, 3-methyl 4-pentyl, 4-methyl-1 -Pentenyl, 5-methylpentenyl, methylpentenyl, 3-methyl-2-pentenyl, 4-methyl-2-pentenyl, 1-methyl-3-pentene Group, 2-methyl-3-pentenyl, 3-methyl-3-pentenyl, 4-methyl-3-pentenyl, 1-fluorenyl-4-pentenyl, 2-methyl 4-pentenyl, 3-fluorenyl-4-pentenyl, 4-methyl-4-pentenyl, ι, ι-dimethyl · 2-butenyl, 丨, dimethyl · 3-butenyl, 1,2-dimethyl · ι_butylfluorenyl-, dimethylbutylfluorenyl, 1,2-dimethyl-3-butenyl, 1,3-dimethyl_1_butyl Alkenyl, 丨,% dimethylbutytyl, 1,3-dimethyl-3-butytyl, 2,2-dimethyl-3-butenyl, 2,3-monomethyl-butenyl, 2,3-dimethyl-2-butenyl, 2,3-dimethyl-3-butenyl, 3,3-dimethyl-1-butenyl, 3,2-dimethyl-2-butene Methyl, ethyl-1-butenyl, 1-ethyl-2- Alkenyl, 1-ethylbutenyl, 2-ethyl-l-butenyl, 2-ethyl-2-butenyl, 2-ethyl-3-butenyl, 1,1,2-trimethyl- 2-propenyl, 1-ethyl- 丨 _methacryl, 丨 _ethylmethpropenyl, and 1-ethyl-2-methyl-2-propenyl; alkynyl: having 2 to 1 0 Straight or branched hydrocarbon groups with three carbon bonds at any position, such as C2-C6-block groups such as ethynyl, 丨 -propynyl, 2-propynyl, 1-butynyl, 2 -Butynyl, 3-butynyl, 1-methyl-2-propynyl, 1-pentyl, 2-pentyl, 3-pentynyl, 4-pentynyl, 1-fluorenyl -2-butynyl, 1-methyl-3-butynyl, 2-methyl-3-butynyl, 3-methyl-1-butynyl, 1,1-monomethyl-2-propane Base, 1-ethyl-2-propanyl, 1-hexadecane-13- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) ---------- I --- Install i I * Please read the phonetic on the back? Matters on this page} Order:-丨 Printed by the Employees 'Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs Printed by the Employees' Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs Printed by 520274 A7 _____ B7 V. Description of the invention (11), 2-Hexynyl, 3 -Hexynyl, 4-hexynyl, 5-hexynyl, 1-methyl-2-pentynyl, 1-methyl-3-pentyl, 1-fluorenyl_4-pentynyl, 2-methyl-3-pentynyl, 2-methyl-4-pentynyl, 3-methyl-1 -pentynyl, 3-methyl-4-pentynyl, 4-methyl-1 -Pentynyl, 4-methyl-1pentynyl, ^ -dimethyl-2-butynyl, M-dimethyl-3-butynyl, i, 2-dimethyl-3-but Alkynyl, 2,2-dimethyl-3-butynyl, 3,3-dimethyl-1-butynyl, 1-ethyl-2-butynyl, 1-ethyl-3-but Alkynyl, 2-ethyl-3-butynyl, and 1-ethyl-bumethyl-2-propynyl; heterocyclyl or heterocyclooxy, heterothio, and heterocyclic amino · 3 to 6 Member, saturated or partially unsaturated mono- or polycyclic heterocyclic ring, which contains 1 to 3 heteroatoms selected from oxygen, nitrogen and sulfur and which is passed through an oxygen atom (heterocyclooxy) or a sulfur atom (hetero Epithio) or directly via nitrogen (heterocyclic amino) Bind to the main chain such as 2-tetra-p-furanyl'synyloxyethylammonium '3-tetraaza-p-furanyl, 2-tetra-nitro-p-sedenyl, 3-tetrahydropyrimyl, 2-pyrrole Pyridyl, 3-pyrrolidinyl, 3-isoxazolidinyl '4-isoisopyridyl, 5-isoisopyridyl, 3-isoimidazolidinyl, 4-isopyrazolidyl, 5- Iso-pyrazolidyl, 3-pyrazolidyl, 4-pyrazolidyl, 5-pyrazolidyl, 2-humidazolyl, 4-oxazolidyl, 5-pyrazolidyl, 2 -Pyrazolidinyl, 4-pyrazolidinyl, 5-pyrazolidinyl, 2-imidazolidyl, 4-imidazolidyl, 1,2,4-pyridazidin-3-yl, 1,2 , 4-pyridazolidin-5-yl, 1,2,4-pyrimidine. Sitazidin-3-yl, 1,2,4-pyrimidazol-5-yl, 1,2,4-triazolidin-3-yl, 1,3,4-amidazolidin-2-yl , 1,3,4-pyridazolidin-2-yl, 1,3,4-triazolidin-2-yl, 2,3, -dihydrofuran-2-yl, 2,3-dihydro Furan-3-yl, 2,3-dihydrofuran-4-yl, 2,3-dihydrofuran-5-yl T " 2,5-dihydrofuran-2-yl, 2,5-dihydro Furan-3-yl, 2,3-dihydropyrimidin-2-yl, 2,3-dihydropyrimidin-3-yl, -14- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) -------------- install ----. (Please read the note on the back page first) Order ·-· Line · Printed by the Consumers ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs Preparation 520274 A7 B7 V. Description of the invention (12) 2.3-dihydro p-phenphen-4-yl, 2,3-dihydro p-phenphen-5-yl, 2,5-dihydro p-phenphen-2-yl , 2,5-Dihydrop-phenphen-3-yl, 2,3-dihydropyrrole-2-yl, 2,3-dihydropyrrole-3 -yl '2,3-^' wind p Billot- 4 -yl '2,3-^ — Fengerlo-5 -yl' 2,5-dichloroρ birrol-2-yl, 2,5-dihydropyrrole-3-yl, 2,3-dihydro Isoxazol-3-yl, 2,3-dihydroisoxazol-4-yl, 2,3-dihydroisoxazol-5-yl, 4,5-di Isozazol-3-yl, 4,5-dihydroisoindazol-4-yl, 4,5-dihydroisoxazol-5-yl, 2,5-dihydroisopyrazol-3-yl, 2,5-dihydroisothiazol-4-yl, 2,5-dihydroisopyrazol-5-yl, 2,3-dihydroisopyrazol-3-yl, 2,3-dihydroisopyrazine Azol-4-yl, 2,5-dihydroisopyryl-5-yl, 4,5-dihydroisop-pyridol-3-yl, 4,5-dihydroisop-pyridyl-4-yl, 4,5-dihydroisop ratio Jun-5-yl, 2,5 · -dihydroisop ratio Jun-3-yl, 2,5-dihydroisopyrazol-4-yl, 2,5-di Hydroisopyrazol-5-yl, 2,3-dihydroindazol-3-yl, 2.3-dihydror 唆 -4-yl, 2,3-dihydrop p-5-yl, 4, 5-dihydro p-thol-3-yl, 4,5-dihydropyrazol-4-yl, 4,5-dihydroindazol-5-yl, 2,5-dihydroazazol-3-yl , 2,5-dihydroazol-4-yl, 2,5-dihydroazazol-5-yl, 2,3-dihydropyrazol-2-yl, 2,3-dihydrothiazole-4- Methyl, 2,3-dihydrothiazol-5-yl, 4,5-dihydrorimazol-2-yl, 4,5-dihydro4-zol-4-yl, 4,5-dihydrohumidazole-5 -Yl, 2,5-dihydro4azol-2-yl, 2,5-dihydropetazol-4-yl, 2,5-dihydrodanazol-5-yl, 2,3-dihydroimidazole -2-yl, 2,3-dihydroimidazol-4-yl, 2,3-dihydroimidazol-5-yl, 4,5-nitros 17-syl-2-yl '4,5-diazine -4 -yl '4,5-dichloroamiwa-5-yl, 2,5-dihydroimidazol-2-yl, 2,5-dihydroimidazol-4-yl, 2,5-dihydroimidazol- 5-radical '2 _ 17 lyme' 3-morphine lyme '2-" ττ wind p ratio yodo' 3-7T chloro p ratio yodo, 4-hexahydro p ratio pyridyl, 3-tetra Hydrogen tower, 4-tetrahydrodaphthyl, 2-tetrahydropyrimidyl, 4-tetrahydropyranyl, 5-tetrahydropyridyl, 2-tetrahydroρ ratio wells, 1, 3 , 5-tetrakis-three-cultivation-2-based, 1,2,4-tetrahydro-three-cultivation-3-based, 1,3-dihydro-15- This paper's? Ft scale applies to China National Standard (CNS) A4 specifications ( 210 X 297 mm) -------------- install --- t (please read the precautions on the back page first) Order · Line * 520274 A7 Employee Consumer Cooperative of Intellectual Property Bureau, Ministry of Economic Affairs Printed π V. Description of the invention (13): Well 2 · based 'UU-based' 2 * · tetrahydropiperanyl, 1,3-dioxolane ==, 3,4,5,6-tetra Hydrogen ...- based ', 2 · base, 4h_3 small—Kaisaijing 2 base, 1,1_ monooxy_2,3,4,5-tetrahydro " sephen-2-yl, 2H-1, 4-Hydroxythiazol-3-yl, 2H-1 4-benzy # 啐 喵 q 甘!, 4 Jujube τ well_stilbyl, 1,3-dihydrogen-2-yl and 1,3-di Thia-2-yl Aryloxy, pure, arylcarbonyl, and arylgalanyl: aromatic monocyclic or cyclamyl 'which is directly or via an oxygen atom (_〇_) (aryloxy) or a sulfur atom (= yl), Bonded to the main chain via several groups (_co_) (arylfluorenyl), via continyl (_S02_) or (broadenyl), for example, phenyl, theyl and phenanthryl, or phenoxy, naphthalene Oxy and phenanthryloxy groups and corresponding carbonyl and sulfonyl groups, etc .; heteroaryl or heteroaryloxy, heteroarylthio, heteroaryl and heteroaryl groups: aromatic-ring or polycyclic groups, In addition to carbon ring members, it may contain one to four nitrogen atoms or-to three nitrogen atoms and one oxygen or sulfur atom or one oxygen or sulfur atom, and is directly or via an oxygen atom (_〇_) ( (Heteroaryloxy) or via a sulfur atom (-S-) (heteroarylthio), via a carbonyl (_c〇_) (heteroarylcarbonyl) or via a Si group (-S〇2_) or (heteroarylsulfonate) Fluorenyl) and other bonds to the main chain; for example-five-membered heteroaryl group containing one to three nitrogen atoms · 5-membered heteroaryl ring group, in addition to carbon atoms may contain 1 to 3 nitrogen atoms as a ring Members such as 2-pyrrolidinyl, pyrimidine = yl, 3-pyrazolyl, 4 -Pyrazolyl, 5-pyrazolyl, 2-imidazolyl, 4-tyl, 1,2,4 · triazol-3-yl and 1,3, cardiac triazole-.2-yl;--containing 1 5-membered heteroaryl group with 4 to 4 nitrogen atoms or 1 to 3 nitrogen atoms and 1 sulfur or oxygen atom or working oxygen or sulfur atom: a heteroaryl group having a 5-membered ring, which may contain 1 To 4 nitrogen atoms or 1 to 1 nitrogen atom and 1 sulfur or oxygen atom or 1 oxygen or sulfur atom as a ring member, for example, 2 _ sulphanyl, 3 _ p fulanf, imi son I ί — i _ II • 0 C Please read the notes on the back page first) Order · 丨 Line. 16 This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 520274 A7 Employees ’Consumption of Intellectual Property, Ministry of Economic Affairs Printed by the cooperative V. Description of the invention (14) 2 stilbyl 3-orthophenidyl, 2-p-pyrrolyl, 3-p-pyrrolyl, 3-iso-slogan succinyl, 4-isopyrazolyl, 5 · isoxazolyl,% isopyrazolyl, 5isopyrazolyl, 3-p ratio pi group, 4 _ p ratio group, 5 _ p ratio group, 2 _ group Base 4 ·. No. octyl, 5-oxazolyl, 2-xazosyl, 4-ττ plug. Sitting base, 5 plug sitting base, 2-mi. Sorryl, 4-imidyl, dioxan-3-yl, 1,3,4- $ dijunyl, thiadiazol-3-yl, thiadiazolyl, 2 ,, 2, 4-triazol-3-yl, 1,3,4-humidazol-2-yl, 1,3,4-pyrimidazol-2-yl, 1,3,4-triazol-2-yl; _Benzo-fused 5-membered heteroaryl group containing 1 to 3 nitrogen atoms or 1 nitrogen atom and / or 1 oxygen or sulfur atom: a heteroaryl group having a 5-membered ring, which may contain 1 in addition to carbon atoms To 4 nitrogen atoms or 丨 to 3 nitrogen atoms and 丨 sulfur or oxygen atoms are ring members, and two adjacent carbocyclic members or 1 nitrogen and 1 adjacent carbocyclic members may be d-1,3-a晞 -1,4-diyl bridge;-5-membered heteroaryl group bonded via nitrogen and containing 丨 to 4 nitrogen atoms or benzo-fused 5-nitrogen bonded and containing 1 to 3 nitrogen atoms 5 Heteroaryl: a heteroaryl with a 5-membered ring, in addition to carbon atoms, may contain 丨 to 4 nitrogen atoms or 丨 to 3 nitrogen atoms, and two adjacent carbocyclic members or 1 nitrogen and 1 Adjacent carbocyclic members can be bridged by butane-1,3-monoene-i, 4-diyl, these rings are bonded to the main chain via-of nitrogen ring members;-containing 1 to 3 or 1 or 4 6-membered heteroaryl with 5 nitrogen atoms: heteroaryl with 6-membered ring Group, in addition to carbon atoms, may contain i to 3 or i to 4 nitrogen atoms as ring members, such as 2-pyridyl, 3-pyridyl, 4-pyridyl, daphyl, stilbyl, 2- Pyrimidinyl, 4-pyrimidinyl, 5] pyrimidinyl, 2-pyridinyl, i 3 5 triphen-2-yl, 1,2,4-trigon-3-yl and 1,2,4, 5-four-cultivation-3-based; -17- This paper size applies to Chinese National Standard (CNS) A4 (210 X 297 mm) (Please read the note on the back? Matters page first) Binding. 520274 A7 Ministry of Economic Affairs Printed by the Intellectual Property Bureau, Consumer Cooperatives, Invention Description (15)-Benzene condensed with 1 to 4 nitrogen atoms, 6-membered heteroaryl group: 6 One of the adjacent carbon ring members can be Ding · i, 3_ 二Ethylene ---: clay, leaching, foreign materials, L, etc., such as M, ... and bridging, such as corresponding oxygen, sulfur, carbonyl or fluorenyl. _ Group: aromatic-ring or polycyclic group, in addition to carbon-J four chaotic atoms or containing one to three nitrogen atoms and-one oxygen or-: child, and is directly bonded to the main chain. #, And the term " partially or completely " means that some or all of the chlorine atoms in the group may be replaced by the same or different halogen atoms as described above. With regard to its biological activity, the compounds of formula I are preferred, and 0 is preferred. Likewise, 'preferred' is a compound of formula I, wherein R1 is methyl. In addition, the preferred ones are compounds! Where R3 is hydrogen, cyanomethyl, ethyl, 1-methylethyl or ^. In addition, car cheer is compound j, of which R3 is methyl. Preferred is compound I, wherein R3 is cyano. Chevrolet is compound I, of which R3 is cyclopropyl. Fortunately, the father is Compound I, and R3 is CF3. Chevrolet is a compound I, wherein R5 is hydrogen, cyclopropylethyl, isopropyl, unsubstituted or substituted aryl or heteroaryl. In addition, preferred is compound j, in which R5 is methyl. R5 is ethyl. Among them, R5 is isopropyl. Among them, 1R5 is cyclopropyl. Among them, R5 is CF3. Cyclopropyl -------------- Packing --- One-(Please read the precautions on the back page first) Order

The better one is compound I, the better one is compound j, the better one is compound j, and the better one is compound I. 18- This paper size is applicable to Chinese National Standard (CNS) A4 specification (21〇X 297 mm) i-line. A Base 520274

V. Description of the invention (16) In addition, the best car is the compound J, in which R5 is an unsubstituted or substituted aryl or heteroaryl. , In addition, the better ones are compounds! , Where R5 is unsubstituted or substituted pyridyl, pyrimidinyl, pyridyl, daphyl or trigyl. In addition, preferred is compound J, in which R5 is an unsubstituted or substituted furanyl group, a pthiophene group, or each group of P to P. In addition, the preferred ones are compounds! , Wherein R5 is unsubstituted or substituted oxazolyl, pyrazolyl, isoxazolyl, isopyrazolyl, pyrazolyl or pyrazolyl. In addition, the better ones are compounds! , Wherein R5 is unsubstituted or substituted fluorenyl dithiol, fluorenediazole, or triazolyl. · In addition, preferred compounds! , Where R5 is phenyl, which is unsubstituted or has one or two of the following groups: nitro, cyano, hydroxy, amine, amine carbonyl, & fluorenyl, halogen, c , CrC4-_alkyl, crc4-fluorenyloxyCrCr haloalkoxy, cvcv alkylamino, dialkylamino, Ci C: 4-methylamino, crC4-alkoxycarbonyl, aminecarbonyl, or di_Crc4 -Alkylamine carbonyl. In addition, compounds Ϊ are preferred, in which R4 is hydrogen, Ci_C6_alkyl, C2_Q-alkenyl, cvcv alkynyl, allyl, aralkyl, heteroaralkyl, aryloxycarbon. Group, heteroaryloxyalkyl group, aryl group or heteroaryl group. In addition, compound I is preferred, in which R4 is Ci_c "alkyl. In addition, compound I is disclosed in WO 9 7/15, 5 5 2 The compound π contained in the mixture of the present invention has good activity against a wide range of phytopathogenic fungi, especially from the ascomycetes, semi-monophyte, thin-form and basidiomycetes. -19- Winter Paper size used Chinese National Standard (CNS) A4 specification (210 X 297 public love) -------------- install --- < * (Please read the notes on the back first to write this Page) Order: —Line · Economy Printed by the Intellectual Property Bureau's Consumer Cooperatives 520274 A7 B7 V. Description of the Invention (17) They control various crops such as cotton, vegetables (such as cucumbers, beans, rice, potatoes and gourds), barley, grass, oats, Fragrant, coffee, corn, fruit, rice, rye, soybeans, grapes, wheat, ornamental plants, sugar cane and many seeds are particularly important. It is particularly suitable for controlling the following phytopathogenic fungi: cereals Erysiphe graminis, Erysiphe graminis (cichoraceamm) and monofilament shell (Sphaerotheca fuHginea), Podsphaera leucotricha of apple, Unciniila of grape necator), Puccinia species of cereals, Rhizoctonia species of cotton, rice and grass, cereals and Ustilago species of apple Venturia inaequalis (Scabies), Helminthosporium species of cereals, Septoria nodorum of wheat, strawberry Botrytis cinerea (Botrytis cinerea) of vegetables, decorative plants and grapes, Cercospora arachidicola, Pseudocercosporella herpotrichoides of wheat and barley, Pyriculada of rice oryzae), Phytophthora infestans' Plasmopara viticola of grapes, pseudoperonospora species of hops and courgette species, Alternaria of vegetables and fruits ( Alternaria species), Mycosphaerella species and Fusarium and Verticillium species. The compounds of formula 11 to XI are used to control the movement of insects, spiders and nematodes. -20-This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) --------- ----- Equipment—— Qin- (Please read the note on the back page first) Order · Thread · Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 520274 A7 B7 V. Description of the invention (18) Pests. They can be used for crop protection and hygiene, and store products for controlling animal pests. In particular, they are suitable for controlling the following animal pests: The worms σ include the order of the butterfly order (Lepidoptera) such as small silkworm, yellow tiger, Alabama argiUacea, Spodoptera litura, and Rhizoma , Spodoptera frugiperda, Pine loopworm, Rat gray roll moth; Capua miculana, Cheimatobia brumata, Spruce Leaf Roller Moth, Western Spruce Leaf Roller Moth, American armyworm, Crocidolomia binotalis, Apple Guiae, European Pine Caterpillar, Cucurbita spp. Corn borer, Egyptian gold diamond, small corn borer, Eupoecilia ambiguella, Evetria b〇uliana, grained tiger, large wax owl, Prunus beetle, Pear beetle, cotton budworm, Spodoptera frugiperda, Corn earworm , Cabbage magpie, Hibernia defolia, American white moth, apple nest moth, tomato nori moth, hemlock hemiptera, beet armyworm, coffee dice / moth, spiny leaf moth, Lithocolletis blancardella, Lobesia botrana, yellow-green stripe Pupae, Gypsy moth, Monk poisonous moth, Narrow-winged leaf miner, Celestial caterpillar, Cabbage night moth, 〇rgyia pseud〇tsugate, Wozhou corn borer, pan〇hs flammea, Red bollworm, Potato block Stem moth, Citrus nocturnal moth, Plutella xylostella, Spodoptera frugiperda, piatyn〇ta stultana, Plutella xylostella, Orange flower moth, Grease moth, prOdenia surna, Yellow-striped slimeworm, Spodoptera exigua, Pine Leaf-roller moth, Scrobipai㈧ absoiuta, Great cockroach, Grapegrass leafgrass, Grassland armyworm, Egyptian cotton leafworm, Spodoptera litura, Thaumatop0ea pityocampa, Oak leafleaf, Spodoptera litura, and Spruce Leaf curl moth; • Beetle order (Coleoptera) such as AgrTlus sinuatus, Striped beetle, Agdotes 〇bScurus, wild cotton weevil, apple flower weevil, At〇maria -21-This paper size applies to China National Cricket Standard (CNS) A4 Specifications (210 X 297 Public Love) .I — — — — — — — — — — — * II (Please read the notes on the back page first) Order and line. Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs and Consumer Cooperatives 520274 A7 B7_____ 5. Description of the invention (19) linearis, large pine ointment, beet tortoise shell, bean leaf beetle, kale pod weevil, Ceuthorrhynchus napi, beet tibia beetle, grass gold needle beetle, asparagus twelve star leaf beetle, spruce red wing Barberry, long-horned leaf beetle, twelve Melon leaf beetle, corn root beetle, mexican bean ladybug, grass beetle, Eutinobothms brasiliensis, Hylobius abietis, Egyptian alfalfa weevil, alfalfa leaf weevil, Lema bilineata, Lema melanopus, potato beetle, beet gold needle, rice Weevil, Melanotus communis, Meligethes aeneus, Melolontha hippocastani, I horn beetle, rice worm, Otiorrhynchus sulcatus, Otiorrhynchus ovatus, eared steel ape leaf worm, garden beetle, Phyllophaga sp Foot jumping cricket, yellow stripe jumper, Japanese beetle, Psylliodes napi, intricate small pheasant, stone bowl bean leaf weevil, and broad bean, bowl bean, Bruchus lends, valley elephant, grasshopper, silver (chest) valley Pirates, glutinous rice owls, rice elephants, red phoenix pitworms, pitworms, and Sitona lineatus, Sitophilus granaria; • Diptera such as Egyptian spotted mosquitoes, Anopheles mosquitoes, Anastrepha ludens, Anopheles maculipennis, Ceratitis capitata, Chrysomya bezziana, Chrysomya hominivorax, Chrysomya macellaria Contarinia sorghicola, Cordylobia anthropophaga, Culex pipiens, Dacus cuc urbitae, Dacus oleae, Dasineura brassicae, Fannia canicularis, Gasterophilus intestinalis, Glossina morsitans, Haematobia irritans, Haplodiplosis equestris, Hylemyia platura, Hypoderma lineata, Liriomyza sativae, Liriomyza trifolii, Lucilia cup, Lucilia cup Home Standard (CNS) A4 Specification (210 > < 297 Male -------------- ^ ---.-(Please read the Precautions on the back page first) Order '-Comprehensive · Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 520274 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 ___B7___ V. Invention Description (2〇) pectoralis, Mayetiola destructor, Musca domestica, Muscina stabulans, Oestrus ovis? Oscinella frit, Pegomya hysocyami, Phorbia antiqua, Phorbia brassicae, Phorbia coarctata, Rhagoletis cerasi, Rhagoletis pomonella, Tabanus bovinus, Tipula oleracea and Tipula paludosa 0 • Pteroptera, such as grass brown thrips, alfalfa thrips, flower thrips, wheat thrips, Orange thrips, rice thrips, Thrips palmi and cotton thrips; • Hemiptera such as Xinjiang leaf bee, Atta cephalotes, Atta sexdens, Texas leaf-cutting moth, Hoplocampa minuta, leafhopper, Argentine ant, kitchen ant, fire ant, exogenous red fire ant and black fire ant; Orders of Heteroptera, such as the green magpie, hairy long pheasant, black-spotted pheasant, cotton red spring, Dysdercus intermedius, Eurygaster integriceps, cotton brown magpie, leaf foot magpie, pod pod magpie, forage maggot (Lygus lineolaris), Lygus pratensis, rice green wall, beet mimicry, Solubea insularis, and Thyanta perditor; • Homoptera such as Acyrthosiphon onobrychis, pea tooth, larch ball tooth, red round valance, Aphidula nasturtii, broad bean worm tooth, cotton aphid, apple aphid, potato aphid, whitefly, thistle shorttail aphid, cabbage worm tooth, Dalbulus maid is, Dreyfus ia nordmannianae, Dreyfusia piceae, Dysaphis radicola, broad bean micro leafhopper, apple cotton aphid, Rice planthopper, Aphis gossypii, Aphis gossypii, Aphis gossypii, broad bean aphid, Aphis gossypii, peach (red) aphid, cherry melanoma frontal tooth, Tail leaf hui, rice brown fly SL, squirrel fly squirrel, Phorodon humuli, orange powder pupae, apple psyllid, pear yellow psyllid, corn borer aphid, putty pupae, wheat-23-this paper? Long scales are applicable to Chinese national standards (CNS> A4 Specifications (210 X 297 mm) -------------- Packing ----* (Please read the precautions on the back page first.) Printed by the cooperative 520274 A7 B7______ Five. Explanation of splash month (21) Aphid, white-backed planthopper, orange aphid, wheat whitefly, greenhouse whitefly, and grape nodule aphid; • termites (Isooptera) such as Calotermes flavicollis, Leucotermes flavipes, Reticulitermes lucifugus, and Termes natalensis; • Orthopterans such as European salamanders, Tibetan flying gifts, double-banded grasshoppers, red-legged grasshoppers, Mexican grasshoppers, migratory grasshoppers, Rocky Mountain grasshoppers, red-winged locusts, American grasshoppers Mighty, Schistocerca peregrina, Stauronotus maroccanus, Badlands grasshopper, and domestic crickets, Oriental crickets, German cockroaches, and American cockles Insects, Brevipalpus phoeni cis, alfalfa moss madder, hellebore oriental leaf snail, Texas orange leaf worm Yu, Eriophyes sheldoni, grass small snail, apple red for spider, orange whole snail, orange rust snail, multi-eating Selenium elegans, Vermilion leaf snail, Tetranychus kanzawai, Pacific red leaf snail, Nematode Yu, beak monuments such as American flower ticks, Amblyomma variegatum, Persian hidden horn monument, square-headed tick, Boophilus decoloratus, tiny tick loss, Dermacentor silvarum , Hyalomma truncatum, Ixodes sheep, Ixodes rubicundus, Ornithodorus moubata, ear tick residual taste, Rhipicephalus appendiculatus, Rhipicephalus evertsi, Sarcoptes scabiei, Tetranychus cinnabarinus, Tetranychus kanzawai, Tetranychus pacificus, Tetranychus telarius and Tetanychus urticae; • Meloidogyne Nematoda e.g. For example, horse # root nematodes, peanut root-knot nematodes and cotton root nematodes, forming cyst nematodes such as Globodera rostochiensis, -24- This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) ----- --------- Installation——--(Please read the precautions on the back page first ) Order · • Line-520274 A7 B7 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs

V. Description of the invention (22) Heterodera avenae, soybean nematodes and Heterodera schachtii, Heterodera trifolii stems and leaf nematodes such as Belonolaimus longicaudatus, destructive stem nematodes, corn stem nematodes, Heliocotylenchus multicinctus, Longidorus elongatus, Radopholus similius, RotylenTrusus, Rotylen Tylenchorhynchus claytoni, Tylenchorhynchus dubius, Pratylenchus neglectus, Pratylenchus penetrans, Pratylenchus curvitatus N Pratylenchus goodeyi 0 In agricultural conditions, the application rate of active ingredients for controlling animal pests is usually 0.01 to 2.0, preferably 0.02 to 1.0 kg / ha. The mixture of the invention is particularly suitable for controlling plant diseases and harmful insects in rice. The mixture of Compound I and at least one of Compounds 11 to XI can be applied together or separately or simultaneously or sequentially. When applied separately, the order usually does not have any effect on the control results. Depending on the type of effect desired, the application rate of the mixture of the invention (especially for agricultural crops) is from 0.01 to 8 kg / ha, preferably from 0.1 to 5 kg / ha, especially from 0.5 to 3.0 kg / ha. The application rate of Compound I is from 0.01 to 2.5 kg / ha, preferably from 0.05 to 2.5 kg / ha, especially from 0.1 to 1.0 kg / ha. For seed treatment, the application rate of the mixture is usually from 0.001 to 250 g / kg of seed, preferably from 0.01 to 100 g / kg, and especially from 0.01 to 50 g / kg. Harmful fungi I, compound I and at least one of 11 to XI are applied separately or together, or contain compound I and at least one compound II -25- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) ) (Please read the precautions on the back page first) Binding: 丨 line · 520274 King into K mixture can A7 V. Description of the invention (23) Plant or soil before or after sowing, or spray before or after germination, spray Or dusting. The fungicidal synergistic mixture of the present invention can be formulated into a solution, an end of a tank and a suspended liquid for immediate spraying or a highly concentrated aqueous, oily or other county ^, a dispersion, an emulsion, an oil dispersion, a paste, a powder, Private shells or granules for dissemination, and application by spraying, atomizing, dusting, dispersing or watering; the state of use varies according to the intended purpose; in any case, the distribution of this rhyme mixture must be as fine as possible and Even. • The formulation is prepared in a known manner, such as diluting the active ingredient with a solvent and / or carrier and, if necessary, emulsifiers and dispersants. If water is used as a diluent, other solvents may be used as auxiliary solvents. Suitable assistants for this purpose are as follows: base: the following: solvents such as aromatics (such as xylene), gasification aromatics (oral milk year), chains; ^ (dark oil museum), alcohols (such as methanol, butanol ), Ketones (such as cyclohexane), amines (such as ethanolamine, dimethylformamide) and water; carriers such as substances (such as kaolin, clay, talc, chalk) and grinding synthesis such as fine-grained oxygen cutting, Saline salt); emulsifiers such as non-ionic and anionic = chemical agents (such as Chuanxiong fatty alcohol brewing, burning acid brewing and aromatic sulfonic acid vinegar) and political agents such as lignosulfite waste liquor and methyl fiber Vegetarian. Suitable (Surface active agent is aromatic continuous acid such as wood _, 酉., Wen and dibutyl; pu = metal test salt, soil test metal salt and ammonium salt, fatty acid, appearance two? Yuan square sulfonic acid alkali metal Salt, alkaline earth metal salt and ammonium salt, fluorenyl group = and fat! Alcohol sulfate 'and sulfated ten-hexyl-, seventeen- and eighteen-yakiri, or fatty alcohol glycol ether salts Derivatives Condensate κ, condensate of tea or tea acid, and polycondensation, polyoxyethylene i_______-26-

This paper is suitable for the country's specifications (210 X

520274 V. Description of the invention (24) Octylphenol ether, ethoxy isooctyl_, octanyl or nonyl-phenol, alkylphenol polyglycol ether, tributylphenyl polyglycol ether ^ ^ 砭Wanji Polyether Alcohol, Isotridecyl Alcohol, Fatty Alcohol, Ethylene Oxide Condensate, Cantonal R # 0TJ, π Emulsified Vima Oil, Polyoxyethylene Benzyl Ether or Polyoxypropylene Alkyl Ether, Month 1 It is known that glutarol ether acetate, sorbitol, lignosulfite waste liquid or methyl cellulose. Powders, substances for dispersal and powders can be prepared by mixing or grinding together a compound] and a mixture of at least one compound π · or a compound and at least one compound Η XI with a solid carrier. Granules (such as coated granules, infiltrated granules, or homogeneous granules) are prepared by combining the active ingredient (or active ingredients) on a solid support. The filler or solid support is, for example, mineral silica, silica gel, silicic acid Salt, talc, kaolin, limestone, lime, chalk, red basalt, loess, clay, dolomite, diatomaceous earth, calcium sulfate, magnesium sulfate, magnesium oxide, abrasive synthetic materials and fertilizers such as ammonium sulfate, ammonium phosphate, ammonium nitrate , Urea, and plant-derived products such as cereal flour, bark flour, wood flour and nut cereal flour, cellulose powder or other solid carriers. This wither usually comprises from 0.1 to 95% by weight, preferably 0.5 to 90 weight 0/0 of any one of compound I and at least one compound Z Z to X j or a mixture of compound I and at least 11 to XI. The active ingredient is used in a purity of 90% to 100%, preferably 95%. Up to 100% (determined by NMR spectrum or HPLC)-Compound I and at least one compound IISXI, the mixture or the corresponding formulation can kill a mixture of fungicidal effective amount or fungicidal effective amount of compound I and at least one Compounds 11 to XI (in the case of separate application) are used to treat harmful fungi, their habitats, or plants, seeds, soil, and areas where fungi are to be controlled. 27 Paper size applies to Chinese National Standard (CNS) A4 (210 X 297) (Mm) Packing ----. (Please read the notes on the back to write this page) Order · Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs, printed by the Consumer Cooperative 520274 A7 B7 V. Description of the invention (25 domains, materials or space Protect from damage. Application can be performed before and after being infected by harmful fungi. Examples of such preparations including active ingredients are: I. A solution containing 90 parts by weight of the active ingredient and 10 parts by weight of N-methylpyrrolidone; Use of drops; II. Contains 20 parts by weight of active ingredient, 80 parts by weight of dimethyl, 10 parts by weight of 8 to 10 moles of ethylene oxide and mololeic acid ^ monoethanolamine, A mixture of 5 parts by weight of dodecaphenoxybenzoic acid salt, 5 parts by weight of an adduct of mol ¥ oxyethane and 1 mol castor oil; the solution is finely distributed in water to obtain a dispersion; III · Contains 20 parts by weight of active ingredient, 40 parts by weight of cyclohexanone, 30%. Aqueous dispersion of adduct of 20 parts by weight of isobutanol, 20 parts by weight of 40 moles of ethylene oxide and 1 mole of castor oil; IV. 20 parts by weight of active ingredient, 25 parts by weight of cyclohexanol, 65 parts by weight Stagnation point 210 to 280C, mineral oil, and 10 parts by weight of 4q mole of ethylene oxide and 1 mole of castor oil adduct of the aqueous dispersion; V. 80 mill parts by weight in a hammer mill A mixture of ingredients, 3 parts by weight of diisobutylphosphonium-1-sulfonate sodium salt, 10 parts by weight of lignosulfonic acid sodium salt obtained from sulfite waste liquid, and 7 parts by weight of crushed silicone; finely distribute the mixture in water Obtaining a spray mixture;-VI. An intimate mixture of 3 parts by weight of the active ingredient and 97 parts by weight of fine-grained kaolin; this dust includes 3% by weight of the active ingredient; VII. 30% by weight of the active ingredient, 9 2% by weight of crushed silicone and 8% by weight An intimate mixture of stone sacrificial oil that has been sprayed onto the surface of this stone glue; this formulation gives live -28- this paper? Long-scale applicable to China National Standard (CNS) A4 specifications (210 x 297 mm) 7, Packing-( Please read the caution page on the back first) Order ·; Line. Ministry of Economic Affairs Intellectual Property Printed by the Bureau ’s Consumer Cooperative 520274 A7 _ B7___ V. Description of the invention (27) X When using active ingredient a at concentration a, the efficiency expressed as% of untreated control group y When using active ingredient B at concentration b, use The efficiency indicated by the% of the untreated control group. Example 1 · Activity against rice blast fungus (protection) Spray the potted rice seedlings with an aqueous preparation of the active ingredient, and the leaves of Tainong 67 "until the soil is combined, the 绾 preparation It is prepared from a stock solution containing 0% active ingredients, 63% cyclohexanone, and a 27/0 chemotherapeutic agent. The next day, the plants were inoculated with an aqueous spore suspension of the rice fungus. The test plants were then placed in a greenhouse at 22_2c & 95_99% relative humidity for 6 days. Then visually inspect the progress of leaf infection. Visual determination of the percentage of woody leaf area of the sensation. Table 7F was converted to efficiency as a percentage to the untreated control group. An efficiency of 0 indicates the same degree of disease as the untreated control group, and an efficiency of 100 indicates 0% of the disease. Using the Kirby formula ((^ 丨 0, 3 on " Calculating synergistic and antagonistic responses of herbicide Combinations ", Weeds, 15, page 2 (K22, i967) to determine the expected efficiency of the active ingredient composition and compare it with the observed efficiency The compound Γ used is the following component a): The experimental results are shown in the following Tables 1 and 2: _______30_ This paper? The long scale applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) ---------- ---- 装 —— * # (Please read the note on the back page first) Order: Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs

520274 A7 B7 V. Description of the invention (28) Table 1 Ex. Active ingredient concentration in ppm Untreated control group% efficacy 1C None (100% disease) 0 2C compound Γ 2.0 20 0.5 0 3C compound 11 2.0 0 0.5 0 4C compound V 2.0 0 0.5 0 Table 2: E X. The mixture of the present invention (concentration to ppm) Calculate the efficacy by observing the efficacy * 5 2 ppm Γ + 2 ppm II 50% 20% 6 0.5 ppm Γ + 0.5 ppm II 30% 10% 7 2 ppm Γ + 2 ppm V 40% 20% 8 0.5 ppm Γ + 0.5 ppm V 25% 10% *) Calculated using Kirby formula. The test results show that the observed power of all mixed ratios is more efficient than that calculated using the Kirby program. --------------- Installation --- f S (Please read the phonetic on the back? Matters page) Order • Thread. The Intellectual Property Bureau, Ministry of Economic Affairs, Consumer Consumption Cooperatives prints the code A4 S) N (C quasi-standard countries IX. 7 -31-centimeters 7 9 2 X ο 520274 Patent Application No. 88104751 Patent Specification Revised Page (March 90) V. Description of Invention (5) L And b) at least one insecticide selected from Formulae II to XI

ch3nh (III; (IV) (Please read the notes on the back before filling out this page) Order Printed by the Staff Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs

Cl

N

Cl NH

CN (V) 2 CF,

OCONHCH

(VI) -8- This paper size applies Chinese National Standard (CNS) A4 specification (210X297 mm) 520274 No. 088104751 Patent Application Chinese Specification Correction Page (November 91 γ Α7 Β7 91. 11. 29 V. Invention Description (a ch3 I 3

(VII) OCON—S — N [(CH2) 3CH3] s -〇v CH,

This paper size applies to China National Standard (CNS) A4 (210 X 297 mm)

Printed by the Consumer Standards Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 520274 No. 88104751 Patent Application Chinese Specification Revised Page (90 / month) V. Description of the Invention (7 One of the items of the invention is to provide a mixture with good fungicidal activity, especially It is an antifungal disease against rice, and on the other hand, it provides good insecticidal activity. Since the climatic zone in which rice is cultivated often encounters many harmful insects, a combination of fungicidal and insecticidal activity is expected. We found that the target can The mixture requested by the scope of the patent application is achieved in item 1. The compounds of formula I are known per se and are described in the literature (WO 97 / 15,552). Insecticides of the formulae II to VII are also known and described in the literature In addition, they are commercially available under the trade names described in the following brackets as required: II: EP-A 192,060, common name: imidacloprid (trade name: Admire®,

Gaucho⑧, from Bayer); III: Common name: acetamiprid (trade name: Mospilan @, from Nippon

Soda); IV · CAS RN 120738-89-8, trade name: nitenpyram (trade name:

Bestgard (R) from Takeda Chemicals); V: Colliot et al., Proc. Br · Conf · Dis · JL, (1992), 29, common name: fipronil (trade name: Regent (R) from Rhone-Poulenc); VI: US 3,474, 170; US 3,474,171 and DE-C 1,493,646; common name: carbofuran (trade name: Curaterr® from Bayer; Furadan® from FMC); VII: Proc · ΒΓ · Crop Prot. Conf · 2 (1979), 557, common name: cairbosulfan (trade name: Marshall®, from FMC); VIII: FR-A 2,489,329; Proc. Int. Congr. Plant Port. 10th5 2_ (1983), 360, common name: benfuracarb (trade name: Oncol ⑧, From -10-This paper size applies Chinese National Standard (CNS) A4 (210X 297mm) (Please read the precautions on the back before filling this page)

520274 Patent Application No. 088HH751 Revised Chinese Manual (November 91) A7 V. Description of Invention (26) Bulletin | 繁 O: g— V · 丨 丨 ί __, 丨 __ Ν__ι__ · _ — _ι_ι ·. ， _ ___,-Good adhesion of unisex ingredients; VIII. 40 weight active ingredient, 〇〇part by weight sodium salt of phenolsulfonic acid / urea / formaldehyde condensate, 2 parts by weight of silicone and 48 parts by weight of stable aqueous dispersion This dispersion can be further diluted; IX. 20 weight active ingredient, 2 parts by weight calcium dodecylbenzenesulfonate, 8 parts by weight fatty alcohol polyglycol ether, 20 parts by weight phenolsulfonic acid / urea / Sodium salt of formaldehyde condensate and stable oily dispersion of 88 parts by weight of shikan mineral oil. The synergistic activity of the mixture of the present invention is proved by the following experiments: The active ingredients (respectively or together) are formulated into a 10% emulsion in a mixture containing 63% by weight of cyclohexanone and 27% by weight of an emulsifier, and diluted with water. To the required degree. Estimated by measuring the percentage of infected leaf area. These percentages translate into efficiency. Efficiency (where J is calculated using the Abbot's, S) equation as follows: W = (la // 5) · 100α is equivalent to the% of the treated plant infected with the fungus, and / 5 is equivalent to the untreated Treated plants are infected by fungi. / 0. Efficiency 0 means that the treated plants are infected to the same extent as the untreated counterparts; efficiency 100 means that the treated plants are not infected. Using the Colbyfs equation [Rs · Colby , Weeds U, 20-22 (1 967)] Determine the expected efficiency of the active ingredient mixture and compare it with the observed efficiency. Kirby formula: E = x + yx · y / l 〇〇E When using concentrations a and b For mixtures of active ingredients A and B, the expected efficiency expressed as% of the untreated control group -29- This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) * -----

Claims (1)

520274 Patent Application No. 088104751 A8 B8 Chinese Patent Application Scope Amendment (9 Γ Year T1 " Month · ^ ~ 1 91 11.) r Six. Patent Application Announcement 1. ^ — 'Μ -14 A crop Protected mixture comprising, in synergistically effective amounts, the following ingredients as active ingredient a) phenylacetic acid derivative R3 of formula (I) (工) 'Wherein the substituents and parameters have the following definitions: X is noch3; Y is NR; R1' R is independently hydrogen or CrC4-alkyl; R3 is hydrogen or Ci-CV alkyl; R4 and R6 are each independently Hydrogen or crc4-alkyl; R5 is hydrogen or CrC4-alkyl; and salts thereof, and b) at least one compound of formula (II), (V), (X), and (XI) 520274 A8 B8 C8 D8 Cl (\ • N 2 · The mixture according to item 1 of the scope of the patent application is adjusted into two parts, one part of which contains the compound (1) in a solid or liquid carrier, and the other part of which is packed in a solid Or at least one compound (ιι), (v), (X) and (χυ.) In a liquid carrier 3. A method for controlling harmful fungi, comprising treating the fungus with a mixture according to item 1 or 2 of the scope of the patent application and inhabiting it Or materials, plants, seeds, soil, areas or spaces where fungi are to be protected from invasion, where compound (I) and at least one compound (11), (V), (χ) and (χι) may be simultaneously , Together or separately or sequentially. 4. The method according to item 3 of the scope of the patent application, in which harmful fungi, its floor-2-520274 8 8 8 8 AB c D 6. The area of the patent application, or fungal control Materials, plants, seeds, soil, areas or spaces protected from them are treated with 0.005 to 1 kg / ha according to the compound (I) in item 1 of the scope of the patent application. -3- This paper scale applies Chinese national standards ( CNS) A4 size (210 X 297 PCT)