US20160093695A1 - Forming iv fins and iii-v fins on insulator - Google Patents
Forming iv fins and iii-v fins on insulator Download PDFInfo
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- US20160093695A1 US20160093695A1 US14/499,395 US201414499395A US2016093695A1 US 20160093695 A1 US20160093695 A1 US 20160093695A1 US 201414499395 A US201414499395 A US 201414499395A US 2016093695 A1 US2016093695 A1 US 2016093695A1
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- fins
- top surface
- spacer layer
- nfet region
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- 239000004065 semiconductor Substances 0.000 claims abstract description 62
- 125000006850 spacer group Chemical group 0.000 claims abstract description 60
- 238000000034 method Methods 0.000 claims abstract description 54
- 239000000463 material Substances 0.000 claims description 34
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- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims description 8
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 claims description 6
- 238000005468 ion implantation Methods 0.000 claims description 6
- 229910052710 silicon Inorganic materials 0.000 claims description 5
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- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
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- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D84/00—Integrated devices formed in or on semiconductor substrates that comprise only semiconducting layers, e.g. on Si wafers or on GaAs-on-Si wafers
- H10D84/80—Integrated devices formed in or on semiconductor substrates that comprise only semiconducting layers, e.g. on Si wafers or on GaAs-on-Si wafers characterised by the integration of at least one component covered by groups H10D12/00 or H10D30/00, e.g. integration of IGFETs
- H10D84/82—Integrated devices formed in or on semiconductor substrates that comprise only semiconducting layers, e.g. on Si wafers or on GaAs-on-Si wafers characterised by the integration of at least one component covered by groups H10D12/00 or H10D30/00, e.g. integration of IGFETs of only field-effect components
- H10D84/83—Integrated devices formed in or on semiconductor substrates that comprise only semiconducting layers, e.g. on Si wafers or on GaAs-on-Si wafers characterised by the integration of at least one component covered by groups H10D12/00 or H10D30/00, e.g. integration of IGFETs of only field-effect components of only insulated-gate FETs [IGFET]
- H10D84/85—Complementary IGFETs, e.g. CMOS
- H10D84/853—Complementary IGFETs, e.g. CMOS comprising FinFETs
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- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/31—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to form insulating layers thereon, e.g. for masking or by using photolithographic techniques; After treatment of these layers; Selection of materials for these layers
- H01L21/3105—After-treatment
- H01L21/3115—Doping the insulating layers
- H01L21/31155—Doping the insulating layers by ion implantation
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- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/26—Bombardment with radiation
- H01L21/263—Bombardment with radiation with high-energy radiation
- H01L21/265—Bombardment with radiation with high-energy radiation producing ion implantation
- H01L21/26506—Bombardment with radiation with high-energy radiation producing ion implantation in group IV semiconductors
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- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/302—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to change their surface-physical characteristics or shape, e.g. etching, polishing, cutting
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- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/302—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to change their surface-physical characteristics or shape, e.g. etching, polishing, cutting
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- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/31—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to form insulating layers thereon, e.g. for masking or by using photolithographic techniques; After treatment of these layers; Selection of materials for these layers
- H01L21/3105—After-treatment
- H01L21/311—Etching the insulating layers by chemical or physical means
- H01L21/31105—Etching inorganic layers
- H01L21/31111—Etching inorganic layers by chemical means
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- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D30/00—Field-effect transistors [FET]
- H10D30/60—Insulated-gate field-effect transistors [IGFET]
- H10D30/67—Thin-film transistors [TFT]
- H10D30/674—Thin-film transistors [TFT] characterised by the active materials
- H10D30/6741—Group IV materials, e.g. germanium or silicon carbide
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- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D30/00—Field-effect transistors [FET]
- H10D30/60—Insulated-gate field-effect transistors [IGFET]
- H10D30/67—Thin-film transistors [TFT]
- H10D30/674—Thin-film transistors [TFT] characterised by the active materials
- H10D30/675—Group III-V materials, Group II-VI materials, Group IV-VI materials, selenium or tellurium
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- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D30/00—Field-effect transistors [FET]
- H10D30/60—Insulated-gate field-effect transistors [IGFET]
- H10D30/67—Thin-film transistors [TFT]
- H10D30/6757—Thin-film transistors [TFT] characterised by the structure of the channel, e.g. transverse or longitudinal shape or doping profile
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- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D30/00—Field-effect transistors [FET]
- H10D30/60—Insulated-gate field-effect transistors [IGFET]
- H10D30/751—Insulated-gate field-effect transistors [IGFET] having composition variations in the channel regions
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- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D62/00—Semiconductor bodies, or regions thereof, of devices having potential barriers
- H10D62/10—Shapes, relative sizes or dispositions of the regions of the semiconductor bodies; Shapes of the semiconductor bodies
- H10D62/113—Isolations within a component, i.e. internal isolations
- H10D62/115—Dielectric isolations, e.g. air gaps
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- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D62/00—Semiconductor bodies, or regions thereof, of devices having potential barriers
- H10D62/80—Semiconductor bodies, or regions thereof, of devices having potential barriers characterised by the materials
- H10D62/83—Semiconductor bodies, or regions thereof, of devices having potential barriers characterised by the materials being Group IV materials, e.g. B-doped Si or undoped Ge
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- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D62/00—Semiconductor bodies, or regions thereof, of devices having potential barriers
- H10D62/80—Semiconductor bodies, or regions thereof, of devices having potential barriers characterised by the materials
- H10D62/85—Semiconductor bodies, or regions thereof, of devices having potential barriers characterised by the materials being Group III-V materials, e.g. GaAs
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- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D86/00—Integrated devices formed in or on insulating or conducting substrates, e.g. formed in silicon-on-insulator [SOI] substrates or on stainless steel or glass substrates
- H10D86/01—Manufacture or treatment
- H10D86/011—Manufacture or treatment comprising FinFETs
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- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D86/00—Integrated devices formed in or on insulating or conducting substrates, e.g. formed in silicon-on-insulator [SOI] substrates or on stainless steel or glass substrates
- H10D86/201—Integrated devices formed in or on insulating or conducting substrates, e.g. formed in silicon-on-insulator [SOI] substrates or on stainless steel or glass substrates the substrates comprising an insulating layer on a semiconductor body, e.g. SOI
- H10D86/215—Integrated devices formed in or on insulating or conducting substrates, e.g. formed in silicon-on-insulator [SOI] substrates or on stainless steel or glass substrates the substrates comprising an insulating layer on a semiconductor body, e.g. SOI comprising FinFETs
Definitions
- the present invention generally relates to semiconductor device manufacturing, and more particularly to the fabrication of III-V fins and IV fins having a similar fin pitch and on a shared surface.
- MOSFETs metal oxide semiconductor field effect transistors
- FETs fin field effect transistor's
- tri-gate structures have been proposed as promising candidates for 14 nm technology nodes and beyond.
- high-mobility channel materials such as III-V and germanium, have been proposed as technology boosters to further improve MOSFET scaling improvements.
- CMOS complementary metal-oxide-semiconductor
- FET field-effect transistors
- the heterointegration of lattice mismatched semiconductor materials with silicon will be useful for a wide variety of device applications.
- disadvantages associated with structural characteristics of lattice mismatched devices can decrease device performance, require additional processes or design constraints to counter-effect such structural characteristics or reduce manufacturing yield.
- a method may include forming first fins on sidewalls of mandrels using epitaxial growth, the mandrels are on a buried insulator layer, the buried insulator layer is on a base substrate, the first fins have a first pitch between adjacent first fins, the first fins include a material of the IV semiconductor group, the first fins are grown in a pFET region and an nFET region; removing the mandrels; forming a conformal spacer layer directly on the first fins, the conformal spacer layer is in the nFET region and the pFET region; damaging the conformal spacer layer on a top surface and a first side surface of the first fins in the nFET region, a portion of the conformal spacer layer remains undamaged on a protected side of the first fins in the nFET region, the protected side of the first fins in the nFET region include surfaces opposite the first side surface,
- a method may include forming first fins on sidewalls of mandrels using epitaxial growth, the first fins have a first pitch between adjacent first fins, the first fins are in a pFET region and an nFET region; forming a spacer layer on the first fins in the pFET region and in the nFET region; removing the spacer layer from a top surface and a first side of the first fins in the nFET region, a portion of the spacer layer remains on a protected side of the first fins in the nFET region, a portion of the first fins are exposed on the top surface and the first side of the first fins in the nFET region, wherein the first fins remain covered by the spacer layer in the pFET region; forming second fins on the exposed portion of the first fins using epitaxial growth, the second fins have a second pitch between adjacent second fins, the first pitch is equal to the second
- a structure may include a set of first fins in a pFET region and a set of second fins in an nFET region, the first fins and the second fins are on a buried insulator layer, the first fins have a bottom surface coplanar with a bottom surface of the second fins, the first fins have a first pitch between adjacent first fins that is equal to a second pitch between adjacent second fins, the first fins include a group IV semiconductor material, the second fins include a group III-V semiconductor material.
- FIG. 1 is a cross section view of a semiconductor structure, according to an exemplary embodiment.
- FIG. 2 is a cross section view of the semiconductor structure and illustrates the formation of mandrels.
- FIG. 3 is a cross section view of the semiconductor structure and illustrates the formation of IV fins on sidewalls of the mandrels.
- FIG. 4 is a cross section view of the semiconductor structure and illustrates the removal of the mandrels.
- FIG. 5 is a cross section view of the semiconductor structure and illustrates the formation of a spacer layer on the IV fins.
- FIGS. 6 and 7 are cross section views of the semiconductor structure and illustrate the removal of the spacer layer from a top surface and a side surface of the IV fins in an nFET region.
- FIGS. 8 and 9 are cross section views of the semiconductor structure and illustrate the formation of III-V fins on the top surface and the side surface of the IV fins in the nFET region.
- FIGS. 10 and 11 are cross section views of the semiconductor structure and illustrate the removal of the IV fins from the nFET region and the spacer layer from the nFET region and a pFET region.
- references in the specification to “one embodiment”, “an embodiment”, “an example embodiment”, etc., indicate that the embodiment described may include a particular feature, structure, or characteristic, but every embodiment may not necessarily include the particular feature, structure, or characteristic. Moreover, such phrases are not necessarily referring to the same embodiment. Further, when a particular feature, structure, or characteristic is described in connection with an embodiment, it is submitted that it is within the knowledge of one skilled in the art to affect such feature, structure, or characteristic in connection with other embodiments whether or not explicitly described.
- the terms “upper”, “lower”, “right”, “left”, “vertical”, “horizontal”, “top”, “bottom”, and derivatives thereof shall relate to the disclosed structures and methods, as oriented in the drawing figures.
- the terms “overlying”, “atop”, “on top”, “positioned on” or “positioned atop” mean that a first element, such as a first structure, is present on a second element, such as a second structure, wherein intervening elements, such as an interface structure may be present between the first element and the second element.
- the term “direct contact” means that a first element, such as a first structure, and a second element, such as a second structure, are connected without any intermediary conducting, insulating or semiconductor layers at the interface of the two elements.
- the present invention generally relates to semiconductor device manufacturing, and more particularly to the fabrication of III-V fins and IV fins having a similar fin pitch and on a shared surface. Ideally, it may be desirable to form III-V fins and IV fins having a similar fin pitch and on a shared surface without the need for long epitaxial growth times and with low levels of defects.
- the purpose of forming III-V fins and IV fins having a similar fin pitch and on a shared surface may be to allow circuit designers to follow the design rule, as is known in the art.
- III-V fins and IV fins having a similar fin pitch and on a shared surface is to form the IV fins in a pFET region and an nFET region, form a spacer layer on the IV fins, remove the spacer layer from a top surface and a side surface of the IV fins in the nFET region, form the III-V fins on the top surface and the side surface of the IV fins in the nFET region, remove the IV fins from the nFET region, and remove the spacer layer from both the pFET and nFET regions.
- III-V fins and IV fins having a similar fin pitch and on a shared surface is described in detail below with reference to the accompanying drawings FIGS. 1-11 . It should be noted, the present embodiment utilizes the III-V group and IV group semiconductors but other materials may be used. Additionally, IV fins may be referred to as first fins and the III-V fins may be referred to as second fins.
- FIGS. 1 and 2 demonstrative illustrations of a structure 100 during an intermediate step of a method of fabricating III-V fins and IV fins having a similar fin pitch and on a shared surface are provided, according to an exemplary embodiment. More specifically, the method can start with fabricating mandrels 106 in a substrate.
- the substrate may be any substrate known in the art, such as, for example, a semiconductor-on-insulator (SOI) substrate or a bulk substrate.
- SOI substrate is used.
- the SOI substrate includes a semiconductor layer 105 , a buried insulator layer 104 , and a base substrate 102 .
- the semiconductor layer 105 is on the buried insulator layer 104 and the buried insulator layer 104 is on the base substrate 102 .
- the SOI substrate may be formed using any technique known in the art, such as, for example, Separation by Ion Implantation of Oxygen (SIMOX) or a layer transfer process. When a layer transfer process is employed, an optional thinning step may follow the bonding of two semiconductor wafers together.
- SIMOX Separation by Ion Implantation of Oxygen
- the optional thinning step can reduce the thickness of a layer to a desirable thickness.
- an insulating material e.g., oxide
- subsequently formed components e.g., fins
- the base substrate 102 and the semiconductor layer 105 may include a same or similar semiconductor material. In other embodiments, the base substrate 102 and the semiconductor layer 105 may include a different material.
- semiconductor material as used herein may denote any semiconducting material including, for example, silicon (Si), germanium (Ge), silicon-germanium (SiGe) or other semiconductors. Multi-layers of semiconductor materials can also be used for the base substrate 102 and/or the semiconductor layer 105 . In an embodiment, both the base substrate 102 and the semiconductor layer 105 include silicon. In another embodiment, the base substrate 102 is a non-semiconductor material, such as, for example, a dielectric material and/or a conductive material.
- the base substrate 102 and the semiconductor layer 105 may have similar or may have different crystal orientations.
- the crystal orientation of the base substrate 102 and/or the semiconductor layer 105 may be ⁇ 100 ⁇ , ⁇ 110 ⁇ , or ⁇ 111 ⁇ . Other crystallographic orientations besides those specifically mentioned can also be used.
- the base substrate 102 and/or the semiconductor layer 105 may be a single crystalline semiconductor material, a polycrystalline material, or an amorphous material. Typically, at least the semiconductor layer 105 is a single crystalline semiconductor material.
- the semiconductor layer 105 located above the buried insulator layer 104 , can be processed to include semiconductor regions having different crystal orientations.
- the buried insulator layer 104 may be a crystalline or non-crystalline oxide or nitride.
- the buried insulator layer 104 is an oxide, such as, for example, silicon dioxide.
- the buried insulator layer 104 may be continuous or discontinuous.
- the buried insulator layer 104 may typically have a thickness from about 1 nm to about 500 nm.
- the buried insulator layer 104 may have a thickness ranging from about 10 nm to about 100 nm.
- the buried insulator layer 104 may include multiple dielectric layers or a stack of dielectric layers including a silicon oxide layer and/or a silicon nitride layer.
- the mandrels 106 may be formed in the semiconductor layer 105 using a hardmask 108 .
- the hardmask 108 may be formed on the semiconductor layer 105 using any deposition technique known in the art, such as, for example, chemical vapor deposition, plasma enhanced chemical vapor deposition, atomic layer deposition, or physical vapor deposition.
- the hardmask 108 may include any masking material known in the art, such as, for example, silicon nitride (Si 3 N 4 ), silicon carbide (SiC), silicon carbon nitride (SiCN), hydrogenated silicon carbide (SiCH), or any other masking material.
- the hardmask 108 is a silicon nitride.
- a mandrel pattern may be formed in the hardmask 108 using any known patterning technique known in the art, such as, photolithography.
- the mandrels 106 may be formed by transferring the mandrel pattern into the semiconductor layer 105 .
- the mandrel pattern may be transferred into the semiconductor layer 105 by etching the semiconductor layer 105 selective to the hardmask 108 and the buried insulator layer 104 (i.e., etching the semiconductor layer 105 , where the hardmask 108 is a mask and the buried insulator layer 104 is an etch stop).
- a set of mandrels may be in a pFET region 101 and a set of mandrels may be in an nFET region 103 .
- a “set” may refer to any number of mandrels 106 , including a single mandrel.
- the mandrels 106 may have the same width as any adjacent mandrels.
- FIG. 3 a demonstrative illustration of a structure 100 during an intermediate step of a method of fabricating III-V fins and IV fins having a similar fin pitch and on a shared surface is provided, according to an exemplary embodiment. More specifically, the method can include growing IV fins 110 on sidewalls of the mandrels 106 .
- the IV fins 110 may be grown on the sidewalls of the mandrels 106 in the pFET and nFET regions 101 , 103 using any formation technique known in the art, such as, for example, epitaxial growth.
- Epitaxy growth may be a layer of monocrystalline semiconductor material which grows outward from an exposed surface of an existing monocrystalline semiconductor region or layer.
- the epitaxial layer may have the same composition as the semiconductor region on which it is grown, the same impurities (e.g., dopants and their concentrations), or, alternatively, the compositions of the epitaxial layer and the underlying semiconductor region can be different.
- the IV fins 110 may have a thickness ranging from about 2 nm to about 10 nm.
- Defects may begin to occur in epitaxial growth if a critical thickness is exceeded, the critical thickness may range from about 2 nm to about 10 nm.
- the IV fins 110 may be selectively grown on the sidewalls of the mandrels 106 and not on the hardmask 108 or the buried insulator layer 104 , as illustrated.
- the IV fins 110 may be germanium and have a thickness of about 8 nm.
- the IV fins 110 may be any material known in the art, such as, for example, germanium, silicon germanium, or other good pFET materials. In an embodiment, the IV fins 110 may be germanium. There may be a fin pitch between any two adjacent IV fins 110 . A first pitch (p 1 ) may be between adjacent IV fins 110 in the pFET region 101 and a second pitch (p 2 ) may be between adjacent IV fins 110 in the nFET region 103 . The first pitch (p 1 ) may be the same as the second pitch (p 2 ). In an embodiment, both the first pitch (p 1 ) and the second pitch (p 2 ) are equal to about 42 nm.
- FIG. 4 a demonstrative illustration of a structure 100 during an intermediate step of a method of fabricating III-V fins and IV fins having a similar fin pitch and on a shared surface is provided, according to an exemplary embodiment. More specifically, the method can include removing the hardmask 108 and the mandrels 106 .
- the hardmask 108 and the mandrels 106 may be removed using any mask removal technique as is known in the art, such as, for example, RIE.
- the etching technique used to remove the mandrels 106 may etch the mandrels 106 selective to the IV fins 110 and the buried insulator layer 104 (i.e., etching the mandrels 106 and using the IV fins 110 and the buried insulator layer 104 as an etch stop).
- An alternative method may include depositing a protective material on the buried insulator layer 104 and etching the mandrels 106 selective to the IV fins 110 .
- FIG. 5 a demonstrative illustration of a structure 100 during an intermediate step of a method of fabricating III-V fins and IV fins having a similar fin pitch and on a shared surface is provided, according to an exemplary embodiment. More specifically, the method can include forming a spacer layer 112 on the IV fins 110 .
- the spacer layer 112 may be conformally formed on the IV fins 110 using any deposition technique known in the art, such as, for example, chemical vapor deposition, plasma enhanced chemical vapor deposition, or atomic layer deposition.
- the spacer layer 112 may have a thickness ranging from about 2 nm to about 15 nm.
- the spacer layer 112 may be any spacer material known in the art, such as, for example, an oxide or a nitride.
- FIGS. 6 and 7 demonstrative illustrations of a structure 100 during an intermediate step of a method of fabricating III-V fins and IV fins having a similar fin pitch and on a shared surface are provided, according to an exemplary embodiment. More specifically, the method can include removing the spacer layer 112 from a top surface and a side surface of the IV fins 110 in the nFET region 103 .
- a mask 113 may be formed on the IV fins 110 in the pFET region 101 using any deposition and patterning technique known in the art, such as, for example, photolithography.
- the mask 113 may be any masking material known in the art, such as, for example, oxide, nitride, or oxynitrides.
- a portion of the spacer layer 112 may be removed from the top surface and the side surface of the IV fins 110 in the nFET region 103 by exposing the top surface and the side surface to an angled removal process 150 .
- a protected surface of the IV fins 110 may be a side opposite the side surface of the IV fins 110 in the nFET region 103 exposed to the angled removal process 150 .
- the angled removal process 150 may be any angled removal process known in the art, such as, for example, an angled ion implantation (damaging the spacer layer 112 on the top surface and the side surface of the IV fins 110 in the nFET region 103 and not damaging the spacer layer 112 on the protected surface) and a wet etch (removing the damaged spacer layer 112 ) or an angled etch (e.g., gas cluster ion beam).
- the angled removal process 150 may expose a portion of the IV fins 110 on the top surface and the side surface of the IV fins 110 in the nFET region 103 (i.e., remove a covering portion of the spacer layer 112 from above the IV fins 110 in the nFET region 103 ).
- the spacer layer 112 may remain on the protected surface of the IV fins 110 in the nFET region 103 .
- the mask 113 may be removed using any mask removal technique as is known in the art.
- a possible ion implantation for performing damage to the spacer layer 112 is Xenon ions at 5 keV to a concentration of 3 ⁇ 10 14 /cm 2 at an angle of 30°. More generally, it is preferred to use relatively massive ions both as a matter of delivering a suitable level of kinetic energy to target materials and damaging the targeted materials to cause the materials to etch more rapidly.
- the ion implantation angle chosen should also assure the implantation into the entire height of the spacer layer 112 and may need to be adjusted if the IV fins 110 are formed in particularly close proximity to each other.
- the implant dose can range from 2 ⁇ 10 13 /cm 2 to 2 ⁇ 10 15 /cm 2
- the implant energy can range from about 0.5 KeV to about 100 KeV and the implant angle can range from 15° to 75°.
- a removal step may be performed to remove the damaged spacer layer 112 using any technique known in the art, such as, for example, a wet etch containing a solution of hydrofluoric acid as the etchant.
- FIGS. 8 and 9 demonstrative illustrations of a structure 100 during an intermediate step of a method of fabricating III-V fins and IV fins having a similar fin pitch and on a shared surface are provided, according to an exemplary embodiment. More specifically, the method can include forming the III-V fins 114 on the exposed portion of the IV fins 110 in the nFET region 103 .
- the III-V fins 114 may be formed on the exposed portions of the IV fins 110 using any technique known in the art, such as, for example, epitaxial growth.
- the epitaxial growth of the III-V fins 114 may use the IV fins 110 as a seed layer.
- the spacer layer 112 may protect against the growth of III-V fins 114 on the IV fins 110 in the pFET region 101 and the protected surface of the IV fins 110 in the nFET region 103 .
- the III-V fins 114 may directly contact the buried insulator layer 104 ; the III-V fins 114 and the IV fins 110 may share a bottom surface coplanar with a top surface of the buried insulator layer 104 .
- the III-V fins 114 may be removed from the top surface of the IV fins 110 using any removal technique known in the art, such as, for example, reactive ion etch (RIE) or any chemical mechanical polishing.
- RIE reactive ion etch
- the III-V fins 114 may be etched or polished to have a top surface coplanar with the top surface of the IV fins 110 .
- the III-V fins 114 may be removed from the top surface of the IV fins 110 in the nFET region 103 using RIE, where the spacer layer 112 remains on the top surface of the IV fins 110 in the pFET region 101 .
- the III-V fins 114 may be polished and the spacer layer 112 may be removed from the top surface of the IV fins 110 in both the pFET and nFET regions 101 , 103 , this may subsequently require another masking step to protect the IV fins 110 in the pFET region 101 during subsequent processing steps.
- the III-V fins 114 may have a similar thickness to the IV fins 110 (e.g., ranging from about 5 nm to about 100 nm).
- the III-V fins 114 may have a third pitch (p 3 ) between any adjacent III-V fins 114 .
- the third pitch (p 3 ) may be similar to the first pitch (p 1 ).
- FIGS. 10 and 11 demonstrative illustrations of a structure 100 during an intermediate step of a method of fabricating III-V fins and IV fins having a similar fin pitch and on a shared surface are provided, according to an exemplary embodiment. More specifically, the method can include removing the IV fins 110 from the nFET region 103 and removing the spacer layer 112 from both the pFET and nFET regions 101 , 103 .
- the spacer layer 112 may cover the IV fins 110 in the pFET region 101 , where the top surface of the IV fins 110 in the nFET region 103 are exposed.
- the IV fins 110 in the nFET region 103 may be removed using any etching technique known in the art, such as, for example, RIE selective to the spacer layer 112 , the III-V fins 114 , and the buried insulator layer 104 .
- the IV fins 110 in the nFET region 103 may be etched, where the spacer layer 112 and the III-V fins 114 are used as masks, and the buried insulator layer 104 is used as an etch stop.
- the spacer layer 112 may be removed from both the pFET and nFET regions 101 , 103 using any etching technique known in the art, such as, for example, RIE selective to the III-V fins 114 and the buried insulator layer 104 .
- the third pitch (p 3 ) may be equal to the first pitch (p 1 ).
- the bottom surface of the III-V fins 114 may be coplanar with the bottom surface of the IV fins 110 , and both the III-V fins 114 and the IV fins 110 may be directly on the shared surface (e.g., the top surface of the buried insulator layer 104 ).
- Circuit designers may prefer to follow a design rule for adjacent nFET and pFET regions (e.g., nFET fins and pFET fins having a similar thickness and pitch), as is known in the art.
- a benefit may include reducing cost and processing time by forming the III-V fins 114 with a thickness less than the critical thickness described above.
- the embodiment may avoid long growth times used in deep trench growth (i.e. aspect ratio trench growth), which may also avoids the defects that come with such growth.
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Abstract
Description
- The present invention generally relates to semiconductor device manufacturing, and more particularly to the fabrication of III-V fins and IV fins having a similar fin pitch and on a shared surface.
- The downscaling of the physical dimensions of metal oxide semiconductor field effect transistors (MOSFETs) has led to performance improvements of integrated circuits and an increase in the number of transistors per chip. Multiple gate MOSFET structures, such as fin field effect transistor's (finFETs) and tri-gate structures, have been proposed as promising candidates for 14 nm technology nodes and beyond. In addition, high-mobility channel materials, such as III-V and germanium, have been proposed as technology boosters to further improve MOSFET scaling improvements.
- Integration of lattice mismatched semiconductor materials is one path to high performance semiconductor devices such as complementary metal-oxide-semiconductor (CMOS) field-effect transistors (FET) due to their high carrier mobility. For example, the heterointegration of lattice mismatched semiconductor materials with silicon will be useful for a wide variety of device applications. However, disadvantages associated with structural characteristics of lattice mismatched devices can decrease device performance, require additional processes or design constraints to counter-effect such structural characteristics or reduce manufacturing yield.
- According to one embodiment of the present invention, a method is provided. The method may include forming first fins on sidewalls of mandrels using epitaxial growth, the mandrels are on a buried insulator layer, the buried insulator layer is on a base substrate, the first fins have a first pitch between adjacent first fins, the first fins include a material of the IV semiconductor group, the first fins are grown in a pFET region and an nFET region; removing the mandrels; forming a conformal spacer layer directly on the first fins, the conformal spacer layer is in the nFET region and the pFET region; damaging the conformal spacer layer on a top surface and a first side surface of the first fins in the nFET region, a portion of the conformal spacer layer remains undamaged on a protected side of the first fins in the nFET region, the protected side of the first fins in the nFET region include surfaces opposite the first side surface, a mask protects the conformal spacer layer in the pFET region from damage; removing the damaged conformal spacer layer from the top surface and the first side surface of the first fins in the nFET region exposing a portion of the first fins in the nFET region; forming second fins on the exposed portion of the first fins using epitaxial growth, a bottom surface of the second fins is coplanar with a bottom surface of the first fins, the second fins have a second pitch between adjacent second fins, the second pitch is equal to the first pitch, the second fins include a material of the III-V semiconductor group, the second fins are grown in the nFET region; etching a top surface of the second fins to the top surface of the first fins, wherein the top surface of the second fins is coplanar with the top surface of the first fins; and removing the first fins from the nFET region.
- According to another embodiment of the present invention, a method is provided. The method may include forming first fins on sidewalls of mandrels using epitaxial growth, the first fins have a first pitch between adjacent first fins, the first fins are in a pFET region and an nFET region; forming a spacer layer on the first fins in the pFET region and in the nFET region; removing the spacer layer from a top surface and a first side of the first fins in the nFET region, a portion of the spacer layer remains on a protected side of the first fins in the nFET region, a portion of the first fins are exposed on the top surface and the first side of the first fins in the nFET region, wherein the first fins remain covered by the spacer layer in the pFET region; forming second fins on the exposed portion of the first fins using epitaxial growth, the second fins have a second pitch between adjacent second fins, the first pitch is equal to the second pitch, the second fins are in the nFET region, the first fins and the second fins have a shared surface comprising a coplanar bottom surface of the first fins and a coplanar bottom surface of the second fins; and etching a top surface of the second fins to the top surface of the first fins, wherein the top surface of the second fins is coplanar with the top surface of the first fins.
- According to another embodiment of the present invention, a structure is provided. The structure may include a set of first fins in a pFET region and a set of second fins in an nFET region, the first fins and the second fins are on a buried insulator layer, the first fins have a bottom surface coplanar with a bottom surface of the second fins, the first fins have a first pitch between adjacent first fins that is equal to a second pitch between adjacent second fins, the first fins include a group IV semiconductor material, the second fins include a group III-V semiconductor material.
- The following detailed description, given by way of example and not intended to limit the invention solely thereto, will best be appreciated in conjunction with the accompanying drawings, in which:
-
FIG. 1 is a cross section view of a semiconductor structure, according to an exemplary embodiment. -
FIG. 2 is a cross section view of the semiconductor structure and illustrates the formation of mandrels. -
FIG. 3 is a cross section view of the semiconductor structure and illustrates the formation of IV fins on sidewalls of the mandrels. -
FIG. 4 is a cross section view of the semiconductor structure and illustrates the removal of the mandrels. -
FIG. 5 is a cross section view of the semiconductor structure and illustrates the formation of a spacer layer on the IV fins. -
FIGS. 6 and 7 are cross section views of the semiconductor structure and illustrate the removal of the spacer layer from a top surface and a side surface of the IV fins in an nFET region. -
FIGS. 8 and 9 are cross section views of the semiconductor structure and illustrate the formation of III-V fins on the top surface and the side surface of the IV fins in the nFET region. -
FIGS. 10 and 11 are cross section views of the semiconductor structure and illustrate the removal of the IV fins from the nFET region and the spacer layer from the nFET region and a pFET region. - The drawings are not necessarily to scale. The drawings are merely schematic representations, not intended to portray specific parameters of the invention. The drawings are intended to depict only typical embodiments of the invention. In the drawings, like numbering represents like elements.
- Detailed embodiments of the claimed structures and methods are disclosed herein; however, it can be understood that the disclosed embodiments are merely illustrative of the claimed structures and methods that may be embodied in various forms. This invention may, however, be embodied in many different forms and should not be construed as limited to the exemplary embodiments set forth herein. Rather, these exemplary embodiments are provided so that this disclosure will be thorough and complete and will fully convey the scope of this invention to those skilled in the art. In the description, details of well-known features and techniques may be omitted to avoid unnecessarily obscuring the presented embodiments.
- References in the specification to “one embodiment”, “an embodiment”, “an example embodiment”, etc., indicate that the embodiment described may include a particular feature, structure, or characteristic, but every embodiment may not necessarily include the particular feature, structure, or characteristic. Moreover, such phrases are not necessarily referring to the same embodiment. Further, when a particular feature, structure, or characteristic is described in connection with an embodiment, it is submitted that it is within the knowledge of one skilled in the art to affect such feature, structure, or characteristic in connection with other embodiments whether or not explicitly described.
- For purposes of the description hereinafter, the terms “upper”, “lower”, “right”, “left”, “vertical”, “horizontal”, “top”, “bottom”, and derivatives thereof shall relate to the disclosed structures and methods, as oriented in the drawing figures. The terms “overlying”, “atop”, “on top”, “positioned on” or “positioned atop” mean that a first element, such as a first structure, is present on a second element, such as a second structure, wherein intervening elements, such as an interface structure may be present between the first element and the second element. The term “direct contact” means that a first element, such as a first structure, and a second element, such as a second structure, are connected without any intermediary conducting, insulating or semiconductor layers at the interface of the two elements.
- In the interest of not obscuring the presentation of embodiments of the present invention, in the following detailed description, some processing steps or operations that are known in the art may have been combined together for presentation and for illustration purposes and in some instances may have not been described in detail. In other instances, some processing steps or operations that are known in the art may not be described at all. It should be understood that the following description is rather focused on the distinctive features or elements of various embodiments of the present invention.
- The present invention generally relates to semiconductor device manufacturing, and more particularly to the fabrication of III-V fins and IV fins having a similar fin pitch and on a shared surface. Ideally, it may be desirable to form III-V fins and IV fins having a similar fin pitch and on a shared surface without the need for long epitaxial growth times and with low levels of defects. The purpose of forming III-V fins and IV fins having a similar fin pitch and on a shared surface may be to allow circuit designers to follow the design rule, as is known in the art.
- One way to form III-V fins and IV fins having a similar fin pitch and on a shared surface is to form the IV fins in a pFET region and an nFET region, form a spacer layer on the IV fins, remove the spacer layer from a top surface and a side surface of the IV fins in the nFET region, form the III-V fins on the top surface and the side surface of the IV fins in the nFET region, remove the IV fins from the nFET region, and remove the spacer layer from both the pFET and nFET regions. One embodiment by which to form III-V fins and IV fins having a similar fin pitch and on a shared surface is described in detail below with reference to the accompanying drawings
FIGS. 1-11 . It should be noted, the present embodiment utilizes the III-V group and IV group semiconductors but other materials may be used. Additionally, IV fins may be referred to as first fins and the III-V fins may be referred to as second fins. - Referring now to
FIGS. 1 and 2 , demonstrative illustrations of astructure 100 during an intermediate step of a method of fabricating III-V fins and IV fins having a similar fin pitch and on a shared surface are provided, according to an exemplary embodiment. More specifically, the method can start with fabricatingmandrels 106 in a substrate. - The substrate may be any substrate known in the art, such as, for example, a semiconductor-on-insulator (SOI) substrate or a bulk substrate. In an embodiment, an SOI substrate is used. The SOI substrate includes a
semiconductor layer 105, a buriedinsulator layer 104, and abase substrate 102. Thesemiconductor layer 105 is on the buriedinsulator layer 104 and the buriedinsulator layer 104 is on thebase substrate 102. The SOI substrate may be formed using any technique known in the art, such as, for example, Separation by Ion Implantation of Oxygen (SIMOX) or a layer transfer process. When a layer transfer process is employed, an optional thinning step may follow the bonding of two semiconductor wafers together. The optional thinning step can reduce the thickness of a layer to a desirable thickness. In an alternative embodiment, if a bulk substrate is used, an insulating material (e.g., oxide) may be used to electrically isolate subsequently formed components (e.g., fins). - In some embodiments, the
base substrate 102 and thesemiconductor layer 105 may include a same or similar semiconductor material. In other embodiments, thebase substrate 102 and thesemiconductor layer 105 may include a different material. The term “semiconductor material” as used herein may denote any semiconducting material including, for example, silicon (Si), germanium (Ge), silicon-germanium (SiGe) or other semiconductors. Multi-layers of semiconductor materials can also be used for thebase substrate 102 and/or thesemiconductor layer 105. In an embodiment, both thebase substrate 102 and thesemiconductor layer 105 include silicon. In another embodiment, thebase substrate 102 is a non-semiconductor material, such as, for example, a dielectric material and/or a conductive material. - The
base substrate 102 and thesemiconductor layer 105 may have similar or may have different crystal orientations. For example, the crystal orientation of thebase substrate 102 and/or thesemiconductor layer 105 may be {100}, {110}, or {111}. Other crystallographic orientations besides those specifically mentioned can also be used. Thebase substrate 102 and/or thesemiconductor layer 105 may be a single crystalline semiconductor material, a polycrystalline material, or an amorphous material. Typically, at least thesemiconductor layer 105 is a single crystalline semiconductor material. In some embodiments, thesemiconductor layer 105, located above the buriedinsulator layer 104, can be processed to include semiconductor regions having different crystal orientations. - The buried
insulator layer 104 may be a crystalline or non-crystalline oxide or nitride. In an embodiment, the buriedinsulator layer 104 is an oxide, such as, for example, silicon dioxide. The buriedinsulator layer 104 may be continuous or discontinuous. The buriedinsulator layer 104 may typically have a thickness from about 1 nm to about 500 nm. In an embodiment, the buriedinsulator layer 104 may have a thickness ranging from about 10 nm to about 100 nm. In an alternative embodiment, the buriedinsulator layer 104 may include multiple dielectric layers or a stack of dielectric layers including a silicon oxide layer and/or a silicon nitride layer. - With reference to
FIG. 2 , themandrels 106 may be formed in thesemiconductor layer 105 using ahardmask 108. Thehardmask 108 may be formed on thesemiconductor layer 105 using any deposition technique known in the art, such as, for example, chemical vapor deposition, plasma enhanced chemical vapor deposition, atomic layer deposition, or physical vapor deposition. Thehardmask 108 may include any masking material known in the art, such as, for example, silicon nitride (Si3N4), silicon carbide (SiC), silicon carbon nitride (SiCN), hydrogenated silicon carbide (SiCH), or any other masking material. In an embodiment, thehardmask 108 is a silicon nitride. A mandrel pattern may be formed in thehardmask 108 using any known patterning technique known in the art, such as, photolithography. Themandrels 106 may be formed by transferring the mandrel pattern into thesemiconductor layer 105. The mandrel pattern may be transferred into thesemiconductor layer 105 by etching thesemiconductor layer 105 selective to thehardmask 108 and the buried insulator layer 104 (i.e., etching thesemiconductor layer 105, where thehardmask 108 is a mask and the buriedinsulator layer 104 is an etch stop). There may be a mandrel pitch between any two adjacent mandrels. In an embodiment, a set of mandrels may be in apFET region 101 and a set of mandrels may be in annFET region 103. It should be noted, a “set” may refer to any number ofmandrels 106, including a single mandrel. Themandrels 106 may have the same width as any adjacent mandrels. - Referring now to
FIG. 3 , a demonstrative illustration of astructure 100 during an intermediate step of a method of fabricating III-V fins and IV fins having a similar fin pitch and on a shared surface is provided, according to an exemplary embodiment. More specifically, the method can include growingIV fins 110 on sidewalls of themandrels 106. - The
IV fins 110 may be grown on the sidewalls of themandrels 106 in the pFET andnFET regions IV fins 110 may have a thickness ranging from about 2 nm to about 10 nm. Defects may begin to occur in epitaxial growth if a critical thickness is exceeded, the critical thickness may range from about 2 nm to about 10 nm. In an embodiment, theIV fins 110 may be selectively grown on the sidewalls of themandrels 106 and not on thehardmask 108 or the buriedinsulator layer 104, as illustrated. TheIV fins 110 may be germanium and have a thickness of about 8 nm. - The
IV fins 110 may be any material known in the art, such as, for example, germanium, silicon germanium, or other good pFET materials. In an embodiment, theIV fins 110 may be germanium. There may be a fin pitch between any twoadjacent IV fins 110. A first pitch (p1) may be betweenadjacent IV fins 110 in thepFET region 101 and a second pitch (p2) may be betweenadjacent IV fins 110 in thenFET region 103. The first pitch (p1) may be the same as the second pitch (p2). In an embodiment, both the first pitch (p1) and the second pitch (p2) are equal to about 42 nm. - Referring now to
FIG. 4 , a demonstrative illustration of astructure 100 during an intermediate step of a method of fabricating III-V fins and IV fins having a similar fin pitch and on a shared surface is provided, according to an exemplary embodiment. More specifically, the method can include removing thehardmask 108 and themandrels 106. - The
hardmask 108 and themandrels 106 may be removed using any mask removal technique as is known in the art, such as, for example, RIE. The etching technique used to remove themandrels 106 may etch themandrels 106 selective to theIV fins 110 and the buried insulator layer 104 (i.e., etching themandrels 106 and using theIV fins 110 and the buriedinsulator layer 104 as an etch stop). An alternative method may include depositing a protective material on the buriedinsulator layer 104 and etching themandrels 106 selective to theIV fins 110. - Referring now to
FIG. 5 , a demonstrative illustration of astructure 100 during an intermediate step of a method of fabricating III-V fins and IV fins having a similar fin pitch and on a shared surface is provided, according to an exemplary embodiment. More specifically, the method can include forming aspacer layer 112 on theIV fins 110. - The
spacer layer 112 may be conformally formed on theIV fins 110 using any deposition technique known in the art, such as, for example, chemical vapor deposition, plasma enhanced chemical vapor deposition, or atomic layer deposition. Thespacer layer 112 may have a thickness ranging from about 2 nm to about 15 nm. Thespacer layer 112 may be any spacer material known in the art, such as, for example, an oxide or a nitride. - Referring now to
FIGS. 6 and 7 , demonstrative illustrations of astructure 100 during an intermediate step of a method of fabricating III-V fins and IV fins having a similar fin pitch and on a shared surface are provided, according to an exemplary embodiment. More specifically, the method can include removing thespacer layer 112 from a top surface and a side surface of theIV fins 110 in thenFET region 103. - First, a
mask 113 may be formed on theIV fins 110 in thepFET region 101 using any deposition and patterning technique known in the art, such as, for example, photolithography. Themask 113 may be any masking material known in the art, such as, for example, oxide, nitride, or oxynitrides. - Next, a portion of the
spacer layer 112 may be removed from the top surface and the side surface of theIV fins 110 in thenFET region 103 by exposing the top surface and the side surface to anangled removal process 150. A protected surface of theIV fins 110 may be a side opposite the side surface of theIV fins 110 in thenFET region 103 exposed to theangled removal process 150. Theangled removal process 150 may be any angled removal process known in the art, such as, for example, an angled ion implantation (damaging thespacer layer 112 on the top surface and the side surface of theIV fins 110 in thenFET region 103 and not damaging thespacer layer 112 on the protected surface) and a wet etch (removing the damaged spacer layer 112) or an angled etch (e.g., gas cluster ion beam). Theangled removal process 150 may expose a portion of theIV fins 110 on the top surface and the side surface of theIV fins 110 in the nFET region 103 (i.e., remove a covering portion of thespacer layer 112 from above theIV fins 110 in the nFET region 103). Thespacer layer 112 may remain on the protected surface of theIV fins 110 in thenFET region 103. Themask 113 may be removed using any mask removal technique as is known in the art. - In an embodiment, a possible ion implantation for performing damage to the
spacer layer 112 is Xenon ions at 5 keV to a concentration of 3×1014/cm2 at an angle of 30°. More generally, it is preferred to use relatively massive ions both as a matter of delivering a suitable level of kinetic energy to target materials and damaging the targeted materials to cause the materials to etch more rapidly. The ion implantation angle chosen should also assure the implantation into the entire height of thespacer layer 112 and may need to be adjusted if theIV fins 110 are formed in particularly close proximity to each other. Depending on the thickness of thespacer layer 112, the implant dose can range from 2×1013/cm2 to 2×1015/cm2, the implant energy can range from about 0.5 KeV to about 100 KeV and the implant angle can range from 15° to 75°. Once thespacer layer 112 is damaged, a removal step may be performed to remove the damagedspacer layer 112 using any technique known in the art, such as, for example, a wet etch containing a solution of hydrofluoric acid as the etchant. - Referring now to
FIGS. 8 and 9 , demonstrative illustrations of astructure 100 during an intermediate step of a method of fabricating III-V fins and IV fins having a similar fin pitch and on a shared surface are provided, according to an exemplary embodiment. More specifically, the method can include forming the III-V fins 114 on the exposed portion of theIV fins 110 in thenFET region 103. - The III-
V fins 114 may be formed on the exposed portions of theIV fins 110 using any technique known in the art, such as, for example, epitaxial growth. The epitaxial growth of the III-V fins 114 may use theIV fins 110 as a seed layer. Thespacer layer 112 may protect against the growth of III-V fins 114 on theIV fins 110 in thepFET region 101 and the protected surface of theIV fins 110 in thenFET region 103. The III-V fins 114 may directly contact the buriedinsulator layer 104; the III-V fins 114 and theIV fins 110 may share a bottom surface coplanar with a top surface of the buriedinsulator layer 104. If the III-V fins 114 form on the top surface of theIV fins 110, the III-V fins 114 may be removed from the top surface of theIV fins 110 using any removal technique known in the art, such as, for example, reactive ion etch (RIE) or any chemical mechanical polishing. The III-V fins 114 may be etched or polished to have a top surface coplanar with the top surface of theIV fins 110. In an embodiment, the III-V fins 114 may be removed from the top surface of theIV fins 110 in thenFET region 103 using RIE, where thespacer layer 112 remains on the top surface of theIV fins 110 in thepFET region 101. In an alternative embodiment, the III-V fins 114 may be polished and thespacer layer 112 may be removed from the top surface of theIV fins 110 in both the pFET andnFET regions IV fins 110 in thepFET region 101 during subsequent processing steps. - The III-
V fins 114 may have a similar thickness to the IV fins 110 (e.g., ranging from about 5 nm to about 100 nm). The III-V fins 114 may have a third pitch (p3) between any adjacent III-V fins 114. The third pitch (p3) may be similar to the first pitch (p1). - Referring now to
FIGS. 10 and 11 , demonstrative illustrations of astructure 100 during an intermediate step of a method of fabricating III-V fins and IV fins having a similar fin pitch and on a shared surface are provided, according to an exemplary embodiment. More specifically, the method can include removing theIV fins 110 from thenFET region 103 and removing thespacer layer 112 from both the pFET andnFET regions - The
spacer layer 112 may cover theIV fins 110 in thepFET region 101, where the top surface of theIV fins 110 in thenFET region 103 are exposed. First, theIV fins 110 in thenFET region 103 may be removed using any etching technique known in the art, such as, for example, RIE selective to thespacer layer 112, the III-V fins 114, and the buriedinsulator layer 104. In other words, theIV fins 110 in thenFET region 103 may be etched, where thespacer layer 112 and the III-V fins 114 are used as masks, and the buriedinsulator layer 104 is used as an etch stop. Next, thespacer layer 112 may be removed from both the pFET andnFET regions V fins 114 and the buriedinsulator layer 104. - After the
IV fins 110 are removed from thenFET region 103 and thespacer layer 112 is removed from both the pFET andnFET regions IV fins 110 may remain in thepFET region 101 and a set of III-V fins 114 may remain in thenFET region 103. The third pitch (p3) may be equal to the first pitch (p1). The bottom surface of the III-V fins 114 may be coplanar with the bottom surface of theIV fins 110, and both the III-V fins 114 and theIV fins 110 may be directly on the shared surface (e.g., the top surface of the buried insulator layer 104). Circuit designers may prefer to follow a design rule for adjacent nFET and pFET regions (e.g., nFET fins and pFET fins having a similar thickness and pitch), as is known in the art. A benefit may include reducing cost and processing time by forming the III-V fins 114 with a thickness less than the critical thickness described above. The embodiment may avoid long growth times used in deep trench growth (i.e. aspect ratio trench growth), which may also avoids the defects that come with such growth. - The descriptions of the various embodiments of the present invention have been presented for purposes of illustration, but are not intended to be exhaustive or limited to the embodiments disclosed. Many modifications and variations will be apparent to those of ordinary skill in the art without departing from the scope and spirit of the invention. The terminology used herein was chosen to best explain the principles of the embodiment, the practical application or technical improvement over technologies found in the marketplace, or to enable others of ordinary skill in the art to understand the embodiments disclosed herein.
Claims (20)
Priority Applications (2)
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US14/499,395 US9299787B1 (en) | 2014-09-29 | 2014-09-29 | Forming IV fins and III-V fins on insulator |
US14/992,050 US9543302B2 (en) | 2014-09-29 | 2016-01-11 | Forming IV fins and III-V fins on insulator |
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US14/499,395 US9299787B1 (en) | 2014-09-29 | 2014-09-29 | Forming IV fins and III-V fins on insulator |
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US14/992,050 Division US9543302B2 (en) | 2014-09-29 | 2016-01-11 | Forming IV fins and III-V fins on insulator |
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US20160093695A1 true US20160093695A1 (en) | 2016-03-31 |
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US14/499,395 Expired - Fee Related US9299787B1 (en) | 2014-09-29 | 2014-09-29 | Forming IV fins and III-V fins on insulator |
US14/992,050 Expired - Fee Related US9543302B2 (en) | 2014-09-29 | 2016-01-11 | Forming IV fins and III-V fins on insulator |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
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US20170154776A1 (en) * | 2014-12-08 | 2017-06-01 | Applied Materials, Inc. | 3d material modification for advanced processing |
WO2018004537A1 (en) * | 2016-06-28 | 2018-01-04 | Intel Corporation | Integration of single crystalline transistors in back end of line (beol) |
US20210249521A1 (en) * | 2018-04-04 | 2021-08-12 | International Business Machines Corporation | Direct growth of lateral iii-v bipolar transistor on silicon substrate |
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US10002867B2 (en) * | 2016-03-07 | 2018-06-19 | Taiwan Semiconductor Manufacturing Co., Ltd. | Fin-type field effect transistor structure and manufacturing method thereof |
US10199265B2 (en) * | 2017-02-10 | 2019-02-05 | Globalfoundries Inc. | Variable space mandrel cut for self aligned double patterning |
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US9245805B2 (en) | 2009-09-24 | 2016-01-26 | Taiwan Semiconductor Manufacturing Company, Ltd. | Germanium FinFETs with metal gates and stressors |
US8716797B2 (en) | 2009-11-03 | 2014-05-06 | International Business Machines Corporation | FinFET spacer formation by oriented implantation |
US8617937B2 (en) * | 2010-09-21 | 2013-12-31 | International Business Machines Corporation | Forming narrow fins for finFET devices using asymmetrically spaced mandrels |
US9099388B2 (en) | 2011-10-21 | 2015-08-04 | Taiwan Semiconductor Manufacturing Company, Ltd. | III-V multi-channel FinFETs |
US9012284B2 (en) | 2011-12-23 | 2015-04-21 | Intel Corporation | Nanowire transistor devices and forming techniques |
WO2013095656A1 (en) | 2011-12-23 | 2013-06-27 | Intel Corporation | Common-substrate semiconductor devices having nanowires or semiconductor bodies with differing material orientation or composition |
US8486770B1 (en) | 2011-12-30 | 2013-07-16 | Taiwan Semiconductor Manufacturing Company, Ltd. | Method of forming CMOS FinFET device |
US20130193482A1 (en) | 2012-01-27 | 2013-08-01 | International Business Machines Corporation | Fin Structures with Damage-Free Sidewalls for Multi-Gate Mosfets |
CN103295902A (en) | 2012-03-02 | 2013-09-11 | 中芯国际集成电路制造(上海)有限公司 | Finned field-effect tube and forming method thereof |
US8580642B1 (en) | 2012-05-21 | 2013-11-12 | Globalfoundries Inc. | Methods of forming FinFET devices with alternative channel materials |
US8669147B2 (en) | 2012-06-11 | 2014-03-11 | Globalfoundries Inc. | Methods of forming high mobility fin channels on three dimensional semiconductor devices |
US9123585B1 (en) | 2014-02-11 | 2015-09-01 | International Business Machines Corporation | Method to form group III-V and Si/Ge FINFET on insulator |
-
2014
- 2014-09-29 US US14/499,395 patent/US9299787B1/en not_active Expired - Fee Related
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Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20170154776A1 (en) * | 2014-12-08 | 2017-06-01 | Applied Materials, Inc. | 3d material modification for advanced processing |
US9773675B2 (en) * | 2014-12-08 | 2017-09-26 | Applied Materials, Inc. | 3D material modification for advanced processing |
WO2018004537A1 (en) * | 2016-06-28 | 2018-01-04 | Intel Corporation | Integration of single crystalline transistors in back end of line (beol) |
US10727138B2 (en) | 2016-06-28 | 2020-07-28 | Intel Corporation | Integration of single crystalline transistors in back end of line (BEOL) |
US20210249521A1 (en) * | 2018-04-04 | 2021-08-12 | International Business Machines Corporation | Direct growth of lateral iii-v bipolar transistor on silicon substrate |
US11916130B2 (en) * | 2018-04-04 | 2024-02-27 | International Business Machines Corporation | Direct growth of lateral III-V bipolar transistor on silicon substrate |
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US20160126244A1 (en) | 2016-05-05 |
US9299787B1 (en) | 2016-03-29 |
US9543302B2 (en) | 2017-01-10 |
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