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WO1988007030A3 - Olefines detergentes, alkyl benzenes et sulfonates d'alkyl benzene - Google Patents

Olefines detergentes, alkyl benzenes et sulfonates d'alkyl benzene Download PDF

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Publication number
WO1988007030A3
WO1988007030A3 PCT/US1988/000750 US8800750W WO8807030A3 WO 1988007030 A3 WO1988007030 A3 WO 1988007030A3 US 8800750 W US8800750 W US 8800750W WO 8807030 A3 WO8807030 A3 WO 8807030A3
Authority
WO
WIPO (PCT)
Prior art keywords
alkylbenzenes
preparing
processes
alkylbenzene sulfonates
olefins
Prior art date
Application number
PCT/US1988/000750
Other languages
English (en)
Other versions
WO1988007030A2 (fr
Inventor
Richard S Threlkel
Original Assignee
Chevron Res
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chevron Res filed Critical Chevron Res
Publication of WO1988007030A2 publication Critical patent/WO1988007030A2/fr
Publication of WO1988007030A3 publication Critical patent/WO1988007030A3/fr

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Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C309/00Sulfonic acids; Halides, esters, or anhydrides thereof
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00Aliphatic unsaturated hydrocarbons
    • C07C11/02Alkenes
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C15/00Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
    • C07C15/02Monocyclic hydrocarbons
    • C07C15/107Monocyclic hydrocarbons having saturated side-chain containing at least six carbon atoms, e.g. detergent alkylates
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08Catalytic processes
    • C07C2/26Catalytic processes with hydrides or organic compounds
    • C07C2/32Catalytic processes with hydrides or organic compounds as complexes, e.g. acetyl-acetonates
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08Catalytic processes
    • C07C2/26Catalytic processes with hydrides or organic compounds
    • C07C2/32Catalytic processes with hydrides or organic compounds as complexes, e.g. acetyl-acetonates
    • C07C2/34Metal-hydrocarbon complexes
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08Catalytic processes
    • C07C2/26Catalytic processes with hydrides or organic compounds
    • C07C2/36Catalytic processes with hydrides or organic compounds as phosphines, arsines, stilbines or bismuthines
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/12Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • C07C2531/14Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/22Organic complexes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Detergent Compositions (AREA)
  • Catalysts (AREA)

Abstract

Procédé de dimérisation en deux étapes pour la préparation d'oléfines semi-linéaires en C12, utilisant des catalyseurs de dimérisation homogènes et de nouveaux mélanges d'oléfines en C12. Le produit en C12 est particulièrement utile pour la production d'alkylaryles sulfonés à titre de détergents biodégradables et de produits intermédiaires.
PCT/US1988/000750 1987-03-11 1988-03-11 Olefines detergentes, alkyl benzenes et sulfonates d'alkyl benzene WO1988007030A2 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US024,742 1987-03-11
US07/024,742 US4959491A (en) 1987-03-11 1987-03-11 Detergent grade olefins, alkylbenzenes and alkylbenzene sulfonates and processes for preparing

Publications (2)

Publication Number Publication Date
WO1988007030A2 WO1988007030A2 (fr) 1988-09-22
WO1988007030A3 true WO1988007030A3 (fr) 1988-10-06

Family

ID=21822164

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1988/000750 WO1988007030A2 (fr) 1987-03-11 1988-03-11 Olefines detergentes, alkyl benzenes et sulfonates d'alkyl benzene

Country Status (4)

Country Link
US (1) US4959491A (fr)
EP (1) EP0304471A1 (fr)
JP (1) JPH01502752A (fr)
WO (1) WO1988007030A2 (fr)

Families Citing this family (35)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5196625A (en) * 1990-04-27 1993-03-23 Chevron Research & Technology Company Detergent grade to C10 to C28 olefins, (C10 to C28 alkyl) benzenes and (C10 to C28 alkyl) benzene sulfonates and process for preparing same using a phosphite containing catalyst
US5196624A (en) * 1990-04-27 1993-03-23 Chevron Research And Technology Company Detergent grade to C10 to C28 olefins, (C10 to C28 alkyl)benzenes and C10 to C28 alkyl) benzene sulfonates and process for preparing same using a phosphine containing catalyst
US6150322A (en) * 1998-08-12 2000-11-21 Shell Oil Company Highly branched primary alcohol compositions and biodegradable detergents made therefrom
US5849960A (en) * 1996-11-26 1998-12-15 Shell Oil Company Highly branched primary alcohol compositions, and biodegradable detergents made therefrom
US5780694A (en) * 1996-11-26 1998-07-14 Shell Oil Company Dimerized alcohol compositions and biodegradible surfactants made therefrom having cold water detergency
WO1999005242A1 (fr) 1997-07-21 1999-02-04 The Procter & Gamble Company Tensio-actifs ameliores d'alkylbenzenesulfonate
PH11998001775B1 (en) * 1997-07-21 2004-02-11 Procter & Gamble Improved alkyl aryl sulfonate surfactants
ATE240999T1 (de) * 1997-07-21 2003-06-15 Procter & Gamble Reinigungsmittelzusammensetzungen mit kristallinitätsstörenden tensiden
WO1999005084A1 (fr) * 1997-07-21 1999-02-04 The Procter & Gamble Company Procede de preparation de tensioactifs alkylbenzenesulfonate a partir d'alcools et produits contenant lesdits tensioactifs
CA2297010C (fr) 1997-07-21 2003-04-15 Kevin Lee Kott Produits de nettoyage comportant des tensioactifs alkylarylsulfonate ameliores prepares a l'aide d'olefines de vinylidene et procedes de preparation desdits produits
ATE239681T1 (de) * 1997-07-21 2003-05-15 Procter & Gamble Verbessertes verfahren zur herstellung von alkylbenzolsulfonat-tensiden und daraus erhaltene produkte
EP1027312B1 (fr) 1997-08-08 2005-01-12 The Procter & Gamble Company Procedes ameliores de fabrication de tensio-actifs selon une technique de separation par adsorption
BR9914678A (pt) 1998-10-20 2001-10-09 Procter & Gamble Detergentes para a lavagem de roupas compreendendo sulfonatos de alquilbenzeno modificados
CA2346711C (fr) 1998-10-20 2003-12-30 Kevin Lee Kott Detergents a lessive comprenant des alcoylbenzenesulfonates modifies
US7795483B2 (en) 1998-12-29 2010-09-14 Uop Llc Phenyl-alkane compositions produced using an adsorptive separation section
US6617481B1 (en) * 1998-12-29 2003-09-09 Uop Llc Process for producing phenyl-alkanes using an adsorptive separation section
EP1022326A1 (fr) 1999-01-20 2000-07-26 The Procter & Gamble Company Compositions de nettoyage de surfaces dures contenant des alkylbenzènes sulfonates modifiés
CZ20012570A3 (cs) 1999-01-20 2002-07-17 The Procter & Gamble Company Prostředky na mytí nádobí obsahující alkylbenzensulfonátové tenzidy
US6774099B1 (en) 1999-01-20 2004-08-10 The Procter & Gamble Company Dishwashing detergent compositions containing mixtures or crystallinity-disrupted surfactants
EP1022325A3 (fr) 1999-01-20 2003-01-02 The Procter & Gamble Company Compositions detergentes pour les surfaces dures comprenant des sulfonates d'alkyl benzene
DE19910103A1 (de) 1999-03-08 2000-09-14 Basf Ag Verfahren zur Oligomerisierung von C¶6¶-Olefinen
DE19912418A1 (de) * 1999-03-19 2000-09-21 Basf Ag Verfahren zur Herstellung von Tensidalkoholen und Tensidalkoholethern, die hergestellten Produkte und ihre Verwendung
US6187981B1 (en) 1999-07-19 2001-02-13 Uop Llc Process for producing arylalkanes and arylalkane sulfonates, compositions produced therefrom, and uses thereof
US7202205B1 (en) 1999-09-01 2007-04-10 Daniel Stedman Connor Processes for making surfactants via adsorptive separation and products thereof
DE10039995A1 (de) 2000-08-11 2002-02-21 Basf Ag Verfahren zur Herstellung von Alkylarylsulfonaten
CN1323991C (zh) * 2001-10-01 2007-07-04 巴斯福股份公司 制备烷基芳基化合物及其磺酸盐的方法
US20040176655A1 (en) * 2003-02-05 2004-09-09 Ayoub Paul Marie Methods of preparing branched alkyl aromatic hydrocarbons
DE602004009290T2 (de) * 2003-02-05 2008-07-03 Shell Internationale Research Maatschappij B.V. Verfahren zur herstellung verzweigter alkylaromatischer kohlenwasserstoffe unter verwendung eines verfahrensstroms aus einer dimerisierungseinheit
US7335802B2 (en) * 2003-10-15 2008-02-26 Shell Oil Company Methods of preparing branched aliphatic alcohols
US6974788B2 (en) * 2004-03-12 2005-12-13 Chevron Oronite Company Llc. Zeolite Y alkylation catalysts
FR2959737B1 (fr) * 2010-05-06 2012-06-08 Inst Francais Du Petrole Procede de production d'alkylbenzenes ramifies utilisant une source de carbone renouvelable.
FR2959736B1 (fr) 2010-05-06 2012-06-08 Inst Francais Du Petrole Procede de production d'alkylbenzenes a partir d'une charge produite par oligomerisation catalysee par voie homogene.
MX2017002969A (es) 2014-09-08 2017-06-15 Procter & Gamble Composiciones detergentes que contienen un surfactante ramificado.
EP3191569B1 (fr) 2014-09-08 2023-01-25 The Procter & Gamble Company Compositions détergentes contenant un tensioactif ramifié
CN111892482B (zh) * 2020-06-24 2023-05-30 万华化学集团股份有限公司 一种异构十三醇的制备方法

Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2969408A (en) * 1955-12-30 1961-01-24 Phillips Petroleum Co Process and catalyst for polymerization of olefins
GB983376A (en) * 1962-10-16 1965-02-17 British Hydrocarbon Chem Ltd Process for the production of detergent alkylate
GB1007033A (en) * 1962-04-18 1965-10-13 British Petroleum Co Production of alkylate and products produced therefrom
GB1011347A (en) * 1963-10-28 1965-11-24 British Petroleum Co Process for the production of detergent alkylate
GB1063825A (en) * 1963-07-12 1967-03-30 Monsanto Co Production of polymers and detergent compounds therefrom
US3424815A (en) * 1967-05-29 1969-01-28 Shell Oil Co Olefin oligomerization
GB1185490A (en) * 1967-12-28 1970-03-25 British Petroleum Co Dimerisation of Olefins
US4069273A (en) * 1977-01-24 1978-01-17 Chevron Research Company Dimerization of linear alpha-olefins
US4366087A (en) * 1979-09-03 1982-12-28 Institut Francais Du Petrole Oligomerization catalyst and process
US4677241A (en) * 1986-08-15 1987-06-30 Chevron Research Company Olefin oligomerization process and catalyst

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA534167A (fr) * 1956-12-04 Esso Research And Engineering Company Sulfonation d'hydrocarbures aromatiques d'alkyle
GB645195A (en) * 1946-11-29 1950-10-25 Universal Oil Prod Co Process for the production of alkyl aromatic hydrocarbons
GB825952A (en) * 1956-08-03 1959-12-23 Continental Oil Co Improvements in or relating to process of producing sulphonated alkylated aromatic hydrocarbons
US3317628A (en) * 1963-07-12 1967-05-02 Monsanto Co Polymerization of olefins using ammoniated cobalt salt impregnated carbon catalyst

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2969408A (en) * 1955-12-30 1961-01-24 Phillips Petroleum Co Process and catalyst for polymerization of olefins
GB1007033A (en) * 1962-04-18 1965-10-13 British Petroleum Co Production of alkylate and products produced therefrom
GB983376A (en) * 1962-10-16 1965-02-17 British Hydrocarbon Chem Ltd Process for the production of detergent alkylate
GB1063825A (en) * 1963-07-12 1967-03-30 Monsanto Co Production of polymers and detergent compounds therefrom
GB1011347A (en) * 1963-10-28 1965-11-24 British Petroleum Co Process for the production of detergent alkylate
US3424815A (en) * 1967-05-29 1969-01-28 Shell Oil Co Olefin oligomerization
GB1185490A (en) * 1967-12-28 1970-03-25 British Petroleum Co Dimerisation of Olefins
US4069273A (en) * 1977-01-24 1978-01-17 Chevron Research Company Dimerization of linear alpha-olefins
US4366087A (en) * 1979-09-03 1982-12-28 Institut Francais Du Petrole Oligomerization catalyst and process
US4677241A (en) * 1986-08-15 1987-06-30 Chevron Research Company Olefin oligomerization process and catalyst

Also Published As

Publication number Publication date
US4959491A (en) 1990-09-25
WO1988007030A2 (fr) 1988-09-22
JPH01502752A (ja) 1989-09-21
EP0304471A1 (fr) 1989-03-01

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