WO1990010055A1 - Produit a lessive blanchissant - Google Patents
Produit a lessive blanchissant Download PDFInfo
- Publication number
- WO1990010055A1 WO1990010055A1 PCT/EP1990/000269 EP9000269W WO9010055A1 WO 1990010055 A1 WO1990010055 A1 WO 1990010055A1 EP 9000269 W EP9000269 W EP 9000269W WO 9010055 A1 WO9010055 A1 WO 9010055A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- weight
- composition according
- sodium
- soap
- less
- Prior art date
Links
- 239000007788 liquid Substances 0.000 title claims abstract description 10
- 238000004061 bleaching Methods 0.000 title claims abstract description 8
- 238000005406 washing Methods 0.000 title abstract description 6
- 239000000344 soap Substances 0.000 claims abstract description 14
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 11
- 239000011734 sodium Substances 0.000 claims abstract description 11
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 8
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 6
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 5
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 claims abstract description 5
- RYCLIXPGLDDLTM-UHFFFAOYSA-J tetrapotassium;phosphonato phosphate Chemical compound [K+].[K+].[K+].[K+].[O-]P([O-])(=O)OP([O-])([O-])=O RYCLIXPGLDDLTM-UHFFFAOYSA-J 0.000 claims abstract description 5
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 4
- 239000003752 hydrotrope Substances 0.000 claims abstract description 4
- 150000001412 amines Chemical class 0.000 claims abstract description 3
- QUCDWLYKDRVKMI-UHFFFAOYSA-M sodium;3,4-dimethylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1C QUCDWLYKDRVKMI-UHFFFAOYSA-M 0.000 claims abstract description 3
- 239000000203 mixture Substances 0.000 claims description 13
- 239000003599 detergent Substances 0.000 claims description 8
- 159000000000 sodium salts Chemical class 0.000 claims description 5
- LBLYYCQCTBFVLH-UHFFFAOYSA-M 2-methylbenzenesulfonate Chemical compound CC1=CC=CC=C1S([O-])(=O)=O LBLYYCQCTBFVLH-UHFFFAOYSA-M 0.000 claims description 3
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 3
- ZZXDRXVIRVJQBT-UHFFFAOYSA-M Xylenesulfonate Chemical compound CC1=CC=CC(S([O-])(=O)=O)=C1C ZZXDRXVIRVJQBT-UHFFFAOYSA-M 0.000 claims description 2
- 229940049964 oleate Drugs 0.000 claims description 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 2
- 229940071104 xylenesulfonate Drugs 0.000 claims description 2
- XPPKVPWEQAFLFU-UHFFFAOYSA-J diphosphate(4-) Chemical compound [O-]P([O-])(=O)OP([O-])([O-])=O XPPKVPWEQAFLFU-UHFFFAOYSA-J 0.000 claims 1
- 235000011180 diphosphates Nutrition 0.000 claims 1
- 235000014113 dietary fatty acids Nutrition 0.000 abstract description 4
- 239000000194 fatty acid Substances 0.000 abstract description 4
- 229930195729 fatty acid Natural products 0.000 abstract description 4
- 150000004665 fatty acids Chemical class 0.000 abstract description 4
- JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 abstract 1
- 239000003381 stabilizer Substances 0.000 description 5
- 229920000742 Cotton Polymers 0.000 description 4
- 244000060011 Cocos nucifera Species 0.000 description 3
- 235000013162 Cocos nucifera Nutrition 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 239000007844 bleaching agent Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 230000006641 stabilisation Effects 0.000 description 3
- 238000011105 stabilization Methods 0.000 description 3
- 102000004190 Enzymes Human genes 0.000 description 2
- 108090000790 Enzymes Proteins 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- 235000021317 phosphate Nutrition 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- RPACBEVZENYWOL-XFULWGLBSA-M sodium;(2r)-2-[6-(4-chlorophenoxy)hexyl]oxirane-2-carboxylate Chemical compound [Na+].C=1C=C(Cl)C=CC=1OCCCCCC[C@]1(C(=O)[O-])CO1 RPACBEVZENYWOL-XFULWGLBSA-M 0.000 description 2
- JBVOQKNLGSOPNZ-UHFFFAOYSA-N 2-propan-2-ylbenzenesulfonic acid Chemical compound CC(C)C1=CC=CC=C1S(O)(=O)=O JBVOQKNLGSOPNZ-UHFFFAOYSA-N 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 244000269722 Thea sinensis Species 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- -1 alkylbenzene sulfonate Chemical class 0.000 description 1
- 238000010936 aqueous wash Methods 0.000 description 1
- 239000002775 capsule Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 229920006037 cross link polymer Polymers 0.000 description 1
- 229940071118 cumenesulfonate Drugs 0.000 description 1
- SYELZBGXAIXKHU-UHFFFAOYSA-N dodecyldimethylamine N-oxide Chemical compound CCCCCCCCCCCC[N+](C)(C)[O-] SYELZBGXAIXKHU-UHFFFAOYSA-N 0.000 description 1
- DUYCTCQXNHFCSJ-UHFFFAOYSA-N dtpmp Chemical compound OP(=O)(O)CN(CP(O)(O)=O)CCN(CP(O)(=O)O)CCN(CP(O)(O)=O)CP(O)(O)=O DUYCTCQXNHFCSJ-UHFFFAOYSA-N 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- ONHFWHCMZAJCFB-UHFFFAOYSA-N myristamine oxide Chemical compound CCCCCCCCCCCCCC[N+](C)(C)[O-] ONHFWHCMZAJCFB-UHFFFAOYSA-N 0.000 description 1
- HKLOAYQLEIIGDW-UHFFFAOYSA-N n,n-diethylhexadecan-1-amine oxide Chemical compound CCCCCCCCCCCCCCCC[N+]([O-])(CC)CC HKLOAYQLEIIGDW-UHFFFAOYSA-N 0.000 description 1
- DLPZOAYAGDEIHC-UHFFFAOYSA-N n,n-dimethylpentadecan-1-amine oxide Chemical compound CCCCCCCCCCCCCCC[N+](C)(C)[O-] DLPZOAYAGDEIHC-UHFFFAOYSA-N 0.000 description 1
- ADXNPXDFKKWVGE-UHFFFAOYSA-N n,n-dimethyltridecan-1-amine Chemical compound CCCCCCCCCCCCCN(C)C ADXNPXDFKKWVGE-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 239000003605 opacifier Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 235000011837 pasties Nutrition 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 238000005375 photometry Methods 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 235000020095 red wine Nutrition 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 238000005204 segregation Methods 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
- C11D10/045—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on non-ionic surface-active compounds and soap
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
- C11D3/3418—Toluene -, xylene -, cumene -, benzene - or naphthalene sulfonates or sulfates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3947—Liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/75—Amino oxides
Definitions
- the invention relates to an aqueous liquid detergent containing builder salts, which contains hydrogen peroxide as a bleaching agent and is distinguished by high stability in storage and easy metering.
- non-aqueous and aqueous liquid detergents containing bleaching per-compounds are known.
- the stabilization of the per-compounds is usually unproblematic.
- the stabilization of anti-segregation agents often presents difficulties.
- Sedimentation stabilizers often have to be added.
- Another disadvantage is that often larger amounts of combustible organic solvents have to be added. Means of the type mentioned are described, for example, in DE 1279878 (GB 1205711), DE 22 33 771 (US 38 50 831), DE 2825 218 (US 43 16 812) and EP 30 086.
- EP 38 101 proposes to encapsulate the bleach granules and to suspend them in this form in the composition. There is no information in the document about the type of capsule material, which logically has to be stable or insoluble in the aqueous stock concentrate, but has to be inconsistent or slightly soluble in the aqueous wash liquor.
- the invention relates to a bleaching liquid detergent containing
- the alkylbenzenesulfonate is preferably in the form of the sodium salt. Its proportion is preferably 7 to 12% by weight.
- Suitable arinoxides are e.g. B. dodecyldimethylamine oxide, tride- cyldimethylamine oxide, tetradecyldimethylamine oxide, pentadecyldimethylamine oxide and hexadecyldiethylamine oxide and mixtures thereof. Their proportion is preferably 2 to 5% by weight.
- Suitable soaps are preferably those made from natural fatty acid mixtures, such as coconut or palm kernel fatty acid.
- the fatty acids with 10 and fewer carbon atoms are previously separated off in a proportion of less than 5% by weight, preferably less than 3% by weight (based on soap). It is also advisable to separate the stearic acid to a stearate content below 20% by weight, preferably below 15% by weight (based on soap).
- the proportion of unsaturated fatty acid soaps, such as oleate is advantageously also less than 10%, based on soap.
- the soaps are preferably in the form of sodium salts, the proportion of which is preferably 2 to 5% by weight.
- the proportion of the potassium pyrophosphate which is preferably used as tetra potassium pyrophosphate, is preferably 15 to 21% by weight. Higher proportions, i.e. H. up to 25% by weight are in principle possible, but less recommendable due to the phosphate restrictions in the wastewater.
- Suitable hydrotropes are toluenesulfonate, xylene sulfonate and cumene sulfonate, each in the form of the sodium salts. Their proportion is preferably 5 to 10% by weight The hydrogen peroxide is calculated as 100% H2O2. Its proportion is preferably 1 to 4% by weight.
- the water should be deionized and in particular free of heavy metal ions. Its proportion is preferably 50 to 57% by weight. In addition, small amounts of those components which are insensitive to oxidation, such as dyes or opacifiers, can be present. Additional stabilizing agents are not required, since the agents themselves have a surprisingly high storage stability. After all, small proportions, ie a maximum of 0.5 to 1% by weight, of oxidation-insensitive stabilizers having a separating action may be present, such as 1-hydroxyethane-1, 1-diphoshonic acid, ethylenediamine-tetra- (methylenephosphonic acid and diethylene triamine penta- (methylenephosphonic acid), each in the 'form of the Na or K salt.
- the agents are very stable in storage.
- the loss of active oxygen is less than 1% even after storage for several months at room temperature (20 - 25 ° C).
- they are characterized by a high washing and bleaching effect, especially in relation to colored stains.
- a clear, homogeneous, easily pourable liquid detergent had the following composition (in% by weight): 9% C ⁇ o_i3-alkylbenzenesulfonate (Na salt)
- washing tests were carried out in the landerometer.
- a commercial liquid detergent (comparable to an agent according to EP 28866) containing alkylbenzenesulfonate, nonionic surfactants, coconut soap, enzymes, enzyme stabilizers and water was used. The following were used as text samples:
- Tl cotton soiled with dust and skin fat
- T2 mixed fabric made of polyester and refined cotton (wash and wear)
- soiled with dust and skin fat T3 cotton (refined) soiled with red wine
- T4 cotton refined
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
Un produit à lessive blanchissant longue conservation contient (A) entre 5 et 15 % en poids d'un sulfonate linéaire d'alkylbenzol ayant entre 9 et 13 atomes de carbone dans la chaîne alkyle sous forme du sel de sodium ou de potassium, (B) entre 1 et 5 % en poids d'un aminoxyde, contenant un résidu alkyle linéaire ayant entre 12 et 16 atomes de carbone, (C) entre 1 et 6 % en poids d'un savon dérivé d'acides gras C12-18 sous forme du sel de sodium ou de potassium, (D) entre 10 et 22 % en poids de pyrophosphate de potassium, (E) entre 2 et 12 % en poids d'un hydrotrope, (F) entre 0,5 et 5 % en poids de peroxyde d'hydrogène et (G) entre 45 et 60 % en poids d'eau.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEP3906044.6 | 1989-02-27 | ||
| DE19893906044 DE3906044A1 (de) | 1989-02-27 | 1989-02-27 | Bleichendes fluessigwaschmittel |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO1990010055A1 true WO1990010055A1 (fr) | 1990-09-07 |
Family
ID=6375014
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/EP1990/000269 WO1990010055A1 (fr) | 1989-02-27 | 1990-02-19 | Produit a lessive blanchissant |
Country Status (4)
| Country | Link |
|---|---|
| EP (1) | EP0385216A1 (fr) |
| DE (1) | DE3906044A1 (fr) |
| PT (1) | PT93238A (fr) |
| WO (1) | WO1990010055A1 (fr) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2766724A1 (fr) * | 1997-07-31 | 1999-02-05 | Irdec Sa | Compositions decontaminantes non agressives |
Families Citing this family (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU5115796A (en) * | 1995-03-24 | 1996-10-16 | Warwick International Group Limited | Alkaline isotropic liquid detergent with peroxide |
| GB9506065D0 (en) * | 1995-03-24 | 1995-05-10 | Warwick Int Group | Alkaline isotropic liquid detergent with peroxide |
| GB9506093D0 (en) * | 1995-03-24 | 1995-05-10 | Warwick Int Group | Alkaline isotropic liquid detergent with peroxide |
| GB9506066D0 (en) * | 1995-03-24 | 1995-05-10 | Warwick Int Group | Alkaline isotropic liquid detergent with peroxide |
| EP0779357A1 (fr) * | 1995-12-16 | 1997-06-18 | The Procter & Gamble Company | Emulsions stables contenant un ingrédient hydrophobe liquide |
| EP0962520A1 (fr) * | 1998-05-29 | 1999-12-08 | The Procter & Gamble Company | Compositions liquides de blanchiment |
| GB2339789A (en) | 1998-07-16 | 2000-02-09 | Reckitt & Colman Inc | Aqueous cleaning and surface treatment compositions |
| US6010729A (en) | 1998-08-20 | 2000-01-04 | Ecolab Inc. | Treatment of animal carcasses |
| DE69924859T2 (de) * | 1998-10-22 | 2006-02-23 | Colgate-Palmolive Co. | Eingedickte flüssige wasserstoffperoxydbleichmittelzusammensetzung |
| EP1065262A1 (fr) * | 1999-06-29 | 2001-01-03 | The Procter & Gamble Company | Compositions de blanchiment |
| CA2407098C (fr) | 2000-04-28 | 2009-12-29 | Ecolab Inc. | Composition antimicrobienne |
| US7150884B1 (en) | 2000-07-12 | 2006-12-19 | Ecolab Inc. | Composition for inhibition of microbial growth |
| US6479454B1 (en) | 2000-10-05 | 2002-11-12 | Ecolab Inc. | Antimicrobial compositions and methods containing hydrogen peroxide and octyl amine oxide |
| US6514556B2 (en) | 2000-12-15 | 2003-02-04 | Ecolab Inc. | Method and composition for washing poultry during processing |
| US7316824B2 (en) | 2000-12-15 | 2008-01-08 | Ecolab Inc. | Method and composition for washing poultry during processing |
| US7622606B2 (en) | 2003-01-17 | 2009-11-24 | Ecolab Inc. | Peroxycarboxylic acid compositions with reduced odor |
| US7771737B2 (en) | 2004-01-09 | 2010-08-10 | Ecolab Inc. | Medium chain peroxycarboxylic acid compositions |
| US7504123B2 (en) | 2004-01-09 | 2009-03-17 | Ecolab Inc. | Methods for washing poultry during processing with medium chain peroxycarboxylic acid compositions |
| US7507429B2 (en) | 2004-01-09 | 2009-03-24 | Ecolab Inc. | Methods for washing carcasses, meat, or meat products with medium chain peroxycarboxylic acid compositions |
| WO2005070205A1 (fr) | 2004-01-09 | 2005-08-04 | Ecolab Inc. | Compositions d'acide peroxycarboxylique a chaine moyenne |
| US7887641B2 (en) | 2004-01-09 | 2011-02-15 | Ecolab Usa Inc. | Neutral or alkaline medium chain peroxycarboxylic acid compositions and methods employing them |
| US7754670B2 (en) | 2005-07-06 | 2010-07-13 | Ecolab Inc. | Surfactant peroxycarboxylic acid compositions |
| US8075857B2 (en) | 2006-10-18 | 2011-12-13 | Ecolab Usa Inc. | Apparatus and method for making a peroxycarboxylic acid |
| US7547421B2 (en) | 2006-10-18 | 2009-06-16 | Ecolab Inc. | Apparatus and method for making a peroxycarboxylic acid |
| CA3091170A1 (fr) | 2018-02-14 | 2019-08-22 | Ecolab Usa Inc. | Compositions et methodes pour la reduction de biofilm et de sporesa partir de membranes |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE657865A (fr) * | 1964-01-04 | 1965-07-05 | ||
| US4298492A (en) * | 1979-06-21 | 1981-11-03 | Lever Brothers Company | Built liquid detergent composition |
| DE3519689A1 (de) * | 1985-06-01 | 1986-12-04 | Henkel KGaA, 4000 Düsseldorf | Fluessiges waschmittelkonzentrat |
-
1989
- 1989-02-27 DE DE19893906044 patent/DE3906044A1/de not_active Withdrawn
-
1990
- 1990-02-19 EP EP90103139A patent/EP0385216A1/fr not_active Withdrawn
- 1990-02-19 WO PCT/EP1990/000269 patent/WO1990010055A1/fr unknown
- 1990-02-22 PT PT9323890A patent/PT93238A/pt not_active Application Discontinuation
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE657865A (fr) * | 1964-01-04 | 1965-07-05 | ||
| US4298492A (en) * | 1979-06-21 | 1981-11-03 | Lever Brothers Company | Built liquid detergent composition |
| DE3519689A1 (de) * | 1985-06-01 | 1986-12-04 | Henkel KGaA, 4000 Düsseldorf | Fluessiges waschmittelkonzentrat |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2766724A1 (fr) * | 1997-07-31 | 1999-02-05 | Irdec Sa | Compositions decontaminantes non agressives |
Also Published As
| Publication number | Publication date |
|---|---|
| PT93238A (pt) | 1990-08-31 |
| EP0385216A1 (fr) | 1990-09-05 |
| DE3906044A1 (de) | 1990-08-30 |
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