WO1991011985A1 - Colorant d'oxydation pour teinture des cheveux comprenant un mordant liquide et une composition en emulsion renfermant un agent oxydant, et procede de teinture oxydante des cheveux - Google Patents
Colorant d'oxydation pour teinture des cheveux comprenant un mordant liquide et une composition en emulsion renfermant un agent oxydant, et procede de teinture oxydante des cheveux Download PDFInfo
- Publication number
- WO1991011985A1 WO1991011985A1 PCT/EP1991/000204 EP9100204W WO9111985A1 WO 1991011985 A1 WO1991011985 A1 WO 1991011985A1 EP 9100204 W EP9100204 W EP 9100204W WO 9111985 A1 WO9111985 A1 WO 9111985A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- component
- hair
- agent
- composition according
- weight
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 52
- 239000007788 liquid Substances 0.000 title claims abstract description 31
- 230000001590 oxidative effect Effects 0.000 title claims abstract description 21
- 239000000126 substance Substances 0.000 title claims abstract description 20
- 239000000975 dye Substances 0.000 title claims abstract description 18
- 238000004043 dyeing Methods 0.000 title claims abstract description 18
- 239000007800 oxidant agent Substances 0.000 title claims abstract description 17
- 238000000034 method Methods 0.000 title claims abstract description 7
- 239000000839 emulsion Substances 0.000 title abstract description 10
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 29
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 46
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 15
- -1 C 4 alcohols Chemical class 0.000 claims description 11
- 150000002191 fatty alcohols Chemical class 0.000 claims description 11
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 5
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 5
- 239000003995 emulsifying agent Substances 0.000 claims description 5
- 239000000194 fatty acid Substances 0.000 claims description 5
- 229930195729 fatty acid Natural products 0.000 claims description 5
- 150000004665 fatty acids Chemical class 0.000 claims description 5
- 238000010168 coupling process Methods 0.000 claims description 4
- 238000005859 coupling reaction Methods 0.000 claims description 4
- 239000000982 direct dye Substances 0.000 claims description 3
- 239000002243 precursor Substances 0.000 claims description 3
- 229920006395 saturated elastomer Polymers 0.000 claims description 2
- 239000012875 nonionic emulsifier Substances 0.000 claims 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract description 32
- 229910021529 ammonia Inorganic materials 0.000 abstract description 16
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 239000000118 hair dye Substances 0.000 description 28
- 230000003647 oxidation Effects 0.000 description 28
- 238000007254 oxidation reaction Methods 0.000 description 28
- 239000003086 colorant Substances 0.000 description 19
- 210000003128 head Anatomy 0.000 description 12
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 12
- 238000002360 preparation method Methods 0.000 description 8
- 238000004040 coloring Methods 0.000 description 7
- HBXWUCXDUUJDRB-UHFFFAOYSA-N 1-octadecoxyoctadecane Chemical compound CCCCCCCCCCCCCCCCCCOCCCCCCCCCCCCCCCCCC HBXWUCXDUUJDRB-UHFFFAOYSA-N 0.000 description 6
- CWLKGDAVCFYWJK-UHFFFAOYSA-N 3-aminophenol Chemical compound NC1=CC=CC(O)=C1 CWLKGDAVCFYWJK-UHFFFAOYSA-N 0.000 description 6
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- 239000002202 Polyethylene glycol Substances 0.000 description 6
- 230000037308 hair color Effects 0.000 description 6
- 229920001223 polyethylene glycol Polymers 0.000 description 6
- 239000007864 aqueous solution Substances 0.000 description 5
- GUQPDKHHVFLXHS-UHFFFAOYSA-M sodium;2-(2-dodecoxyethoxy)ethyl sulfate Chemical compound [Na+].CCCCCCCCCCCCOCCOCCOS([O-])(=O)=O GUQPDKHHVFLXHS-UHFFFAOYSA-M 0.000 description 5
- 229940018563 3-aminophenol Drugs 0.000 description 4
- PLIKAWJENQZMHA-UHFFFAOYSA-N 4-aminophenol Chemical compound NC1=CC=C(O)C=C1 PLIKAWJENQZMHA-UHFFFAOYSA-N 0.000 description 4
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 4
- HVYWMOMLDIMFJA-DPAQBDIFSA-N cholesterol Chemical compound C1C=C2C[C@@H](O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2 HVYWMOMLDIMFJA-DPAQBDIFSA-N 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 210000004761 scalp Anatomy 0.000 description 4
- 230000035943 smell Effects 0.000 description 4
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
- DPUOLQHDNGRHBS-UHFFFAOYSA-N Brassidinsaeure Natural products CCCCCCCCC=CCCCCCCCCCCCC(O)=O DPUOLQHDNGRHBS-UHFFFAOYSA-N 0.000 description 3
- URXZXNYJPAJJOQ-UHFFFAOYSA-N Erucic acid Natural products CCCCCCC=CCCCCCCCCCCCC(O)=O URXZXNYJPAJJOQ-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 3
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 3
- 235000010323 ascorbic acid Nutrition 0.000 description 3
- 229960005070 ascorbic acid Drugs 0.000 description 3
- 239000011668 ascorbic acid Substances 0.000 description 3
- 239000002537 cosmetic Substances 0.000 description 3
- DPUOLQHDNGRHBS-KTKRTIGZSA-N erucic acid Chemical compound CCCCCCCC\C=C/CCCCCCCCCCCC(O)=O DPUOLQHDNGRHBS-KTKRTIGZSA-N 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 229920003145 methacrylic acid copolymer Polymers 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 3
- 125000006353 oxyethylene group Chemical group 0.000 description 3
- 239000002304 perfume Substances 0.000 description 3
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 2
- FBMQNRKSAWNXBT-UHFFFAOYSA-N 1,4-diaminoanthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C(N)=CC=C2N FBMQNRKSAWNXBT-UHFFFAOYSA-N 0.000 description 2
- KJCVRFUGPWSIIH-UHFFFAOYSA-N 1-naphthol Chemical compound C1=CC=C2C(O)=CC=CC2=C1 KJCVRFUGPWSIIH-UHFFFAOYSA-N 0.000 description 2
- 229940075142 2,5-diaminotoluene Drugs 0.000 description 2
- 229940075147 2,5-diaminotoluene sulfate Drugs 0.000 description 2
- KZTWOUOZKZQDMN-UHFFFAOYSA-N 2,5-diaminotoluene sulfate Chemical compound OS(O)(=O)=O.CC1=CC(N)=CC=C1N KZTWOUOZKZQDMN-UHFFFAOYSA-N 0.000 description 2
- SBUMIGFDXJIPLE-UHFFFAOYSA-N 2-(3-amino-4-methoxyanilino)ethanol Chemical compound COC1=CC=C(NCCO)C=C1N SBUMIGFDXJIPLE-UHFFFAOYSA-N 0.000 description 2
- OBCSAIDCZQSFQH-UHFFFAOYSA-N 2-methyl-1,4-phenylenediamine Chemical compound CC1=CC(N)=CC=C1N OBCSAIDCZQSFQH-UHFFFAOYSA-N 0.000 description 2
- ZTMADXFOCUXMJE-UHFFFAOYSA-N 2-methylbenzene-1,3-diol Chemical compound CC1=C(O)C=CC=C1O ZTMADXFOCUXMJE-UHFFFAOYSA-N 0.000 description 2
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 2
- JQVAPEJNIZULEK-UHFFFAOYSA-N 4-chlorobenzene-1,3-diol Chemical compound OC1=CC=C(Cl)C(O)=C1 JQVAPEJNIZULEK-UHFFFAOYSA-N 0.000 description 2
- QGNGOGOOPUYKMC-UHFFFAOYSA-N 4-hydroxy-6-methylaniline Chemical compound CC1=CC(O)=CC=C1N QGNGOGOOPUYKMC-UHFFFAOYSA-N 0.000 description 2
- GPJJASIJVRXZFI-UHFFFAOYSA-N 4-methoxybenzene-1,3-diol Chemical compound COC1=CC=C(O)C=C1O GPJJASIJVRXZFI-UHFFFAOYSA-N 0.000 description 2
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 2
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
- JSFUMBWFPQSADC-UHFFFAOYSA-N Disperse Blue 1 Chemical compound O=C1C2=C(N)C=CC(N)=C2C(=O)C2=C1C(N)=CC=C2N JSFUMBWFPQSADC-UHFFFAOYSA-N 0.000 description 2
- XUMBMVFBXHLACL-UHFFFAOYSA-N Melanin Chemical compound O=C1C(=O)C(C2=CNC3=C(C(C(=O)C4=C32)=O)C)=C2C4=CNC2=C1C XUMBMVFBXHLACL-UHFFFAOYSA-N 0.000 description 2
- 239000005642 Oleic acid Substances 0.000 description 2
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 2
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 2
- LUSZGTFNYDARNI-UHFFFAOYSA-N Sesamol Natural products OC1=CC=C2OCOC2=C1 LUSZGTFNYDARNI-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 235000012000 cholesterol Nutrition 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 2
- 230000002028 premature Effects 0.000 description 2
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 2
- OULAJFUGPPVRBK-UHFFFAOYSA-N tetratriacontan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCO OULAJFUGPPVRBK-UHFFFAOYSA-N 0.000 description 2
- NKNCGBHPGCHYCQ-UHFFFAOYSA-N (2,5-diaminophenyl)methanol Chemical compound NC1=CC=C(N)C(CO)=C1 NKNCGBHPGCHYCQ-UHFFFAOYSA-N 0.000 description 1
- XGNXYCFREOZBOL-UHFFFAOYSA-N 1,3-benzodioxol-5-amine Chemical compound NC1=CC=C2OCOC2=C1 XGNXYCFREOZBOL-UHFFFAOYSA-N 0.000 description 1
- HHVMYUPMJJDVPG-UHFFFAOYSA-N 1-(2,5-diaminophenyl)ethanol Chemical compound CC(O)C1=CC(N)=CC=C1N HHVMYUPMJJDVPG-UHFFFAOYSA-N 0.000 description 1
- ICVRBKCRXNVOJC-UHFFFAOYSA-N 1-amino-4-(methylamino)anthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C(N)=CC=C2NC ICVRBKCRXNVOJC-UHFFFAOYSA-N 0.000 description 1
- AQXYVFBSOOBBQV-UHFFFAOYSA-N 1-amino-4-hydroxyanthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C(O)=CC=C2N AQXYVFBSOOBBQV-UHFFFAOYSA-N 0.000 description 1
- KWSVXCAQFTWTEF-UHFFFAOYSA-N 2-(2,5-diaminophenyl)ethanol Chemical compound NC1=CC=C(N)C(CCO)=C1 KWSVXCAQFTWTEF-UHFFFAOYSA-N 0.000 description 1
- GHKOYBVXCWBGCT-UHFFFAOYSA-N 2-(4-amino-1,3-benzodioxol-5-yl)ethanol Chemical compound C1=C(CCO)C(N)=C2OCOC2=C1 GHKOYBVXCWBGCT-UHFFFAOYSA-N 0.000 description 1
- VLZVIIYRNMWPSN-UHFFFAOYSA-N 2-Amino-4-nitrophenol Chemical compound NC1=CC([N+]([O-])=O)=CC=C1O VLZVIIYRNMWPSN-UHFFFAOYSA-N 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- KJTXCKZBFHBRQT-UHFFFAOYSA-N 2-amino-5-ethoxyphenol Chemical compound CCOC1=CC=C(N)C(O)=C1 KJTXCKZBFHBRQT-UHFFFAOYSA-N 0.000 description 1
- HCPJEHJGFKWRFM-UHFFFAOYSA-N 2-amino-5-methylphenol Chemical compound CC1=CC=C(N)C(O)=C1 HCPJEHJGFKWRFM-UHFFFAOYSA-N 0.000 description 1
- ALQKEYVDQYGZDN-UHFFFAOYSA-N 2-amino-6-methylphenol Chemical compound CC1=CC=CC(N)=C1O ALQKEYVDQYGZDN-UHFFFAOYSA-N 0.000 description 1
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 1
- HGUYBLVGLMAUFF-UHFFFAOYSA-N 2-methoxybenzene-1,4-diamine Chemical compound COC1=CC(N)=CC=C1N HGUYBLVGLMAUFF-UHFFFAOYSA-N 0.000 description 1
- YTZJHEGRZSRVDQ-UHFFFAOYSA-N 2-n-propylpyridine-2,5-diamine Chemical compound CCCNC1=CC=C(N)C=N1 YTZJHEGRZSRVDQ-UHFFFAOYSA-N 0.000 description 1
- DPJCXCZTLWNFOH-UHFFFAOYSA-N 2-nitroaniline Chemical compound NC1=CC=CC=C1[N+]([O-])=O DPJCXCZTLWNFOH-UHFFFAOYSA-N 0.000 description 1
- GRLQBYQELUWBIO-UHFFFAOYSA-N 4,6-dichlorobenzene-1,3-diol Chemical compound OC1=CC(O)=C(Cl)C=C1Cl GRLQBYQELUWBIO-UHFFFAOYSA-N 0.000 description 1
- XRMTWJAJYBZYLZ-UHFFFAOYSA-N 4-(1-hydroxyethoxy)benzene-1,3-diol Chemical compound CC(O)OC1=CC=C(O)C=C1O XRMTWJAJYBZYLZ-UHFFFAOYSA-N 0.000 description 1
- AXDJCCTWPBKUKL-UHFFFAOYSA-N 4-[(4-aminophenyl)-(4-imino-3-methylcyclohexa-2,5-dien-1-ylidene)methyl]aniline;hydron;chloride Chemical compound Cl.C1=CC(=N)C(C)=CC1=C(C=1C=CC(N)=CC=1)C1=CC=C(N)C=C1 AXDJCCTWPBKUKL-UHFFFAOYSA-N 0.000 description 1
- NLMQHXUGJIAKTH-UHFFFAOYSA-N 4-hydroxyindole Chemical compound OC1=CC=CC2=C1C=CN2 NLMQHXUGJIAKTH-UHFFFAOYSA-N 0.000 description 1
- DBFYESDCPWWCHN-UHFFFAOYSA-N 5-amino-2-methylphenol Chemical compound CC1=CC=C(N)C=C1O DBFYESDCPWWCHN-UHFFFAOYSA-N 0.000 description 1
- RZVHIXYEVGDQDX-UHFFFAOYSA-N 9,10-anthraquinone Chemical compound C1=CC=C2C(=O)C3=CC=CC=C3C(=O)C2=C1 RZVHIXYEVGDQDX-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 206010006784 Burning sensation Diseases 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 1
- UIOFUWFRIANQPC-JKIFEVAISA-N Floxacillin Chemical compound N([C@@H]1C(N2[C@H](C(C)(C)S[C@@H]21)C(O)=O)=O)C(=O)C1=C(C)ON=C1C1=C(F)C=CC=C1Cl UIOFUWFRIANQPC-JKIFEVAISA-N 0.000 description 1
- JVTAAEKCZFNVCJ-UHFFFAOYSA-M Lactate Chemical compound CC(O)C([O-])=O JVTAAEKCZFNVCJ-UHFFFAOYSA-M 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 235000006708 antioxidants Nutrition 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000000987 azo dye Substances 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- HJMZMZRCABDKKV-UHFFFAOYSA-N carbonocyanidic acid Chemical compound OC(=O)C#N HJMZMZRCABDKKV-UHFFFAOYSA-N 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 229960000541 cetyl alcohol Drugs 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000008139 complexing agent Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000006735 deficit Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229940071106 ethylenediaminetetraacetate Drugs 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 229940093915 gynecological organic acid Drugs 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- GGNQRNBDZQJCCN-UHFFFAOYSA-N hydroxyhydroquinone Natural products OC1=CC=C(O)C(O)=C1 GGNQRNBDZQJCCN-UHFFFAOYSA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- BXWNKGSJHAJOGX-UHFFFAOYSA-N n-hexadecyl alcohol Natural products CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 239000001005 nitro dye Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- QXYMVUZOGFVPGH-UHFFFAOYSA-N picramic acid Chemical compound NC1=CC([N+]([O-])=O)=CC([N+]([O-])=O)=C1O QXYMVUZOGFVPGH-UHFFFAOYSA-N 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 229960004063 propylene glycol Drugs 0.000 description 1
- PZRKPUQWIFJRKZ-UHFFFAOYSA-N pyrimidine-2,4,5,6-tetramine Chemical compound NC1=NC(N)=C(N)C(N)=N1 PZRKPUQWIFJRKZ-UHFFFAOYSA-N 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- WBHHMMIMDMUBKC-XLNAKTSKSA-N ricinelaidic acid Chemical compound CCCCCC[C@@H](O)C\C=C\CCCCCCCC(O)=O WBHHMMIMDMUBKC-XLNAKTSKSA-N 0.000 description 1
- 229960003656 ricinoleic acid Drugs 0.000 description 1
- FEUQNCSVHBHROZ-UHFFFAOYSA-N ricinoleic acid Natural products CCCCCCC(O[Si](C)(C)C)CC=CCCCCCCCC(=O)OC FEUQNCSVHBHROZ-UHFFFAOYSA-N 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000002453 shampoo Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 235000010265 sodium sulphite Nutrition 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- AAAQKTZKLRYKHR-UHFFFAOYSA-N triphenylmethane Chemical compound C1=CC=CC=C1C(C=1C=CC=CC=1)C1=CC=CC=C1 AAAQKTZKLRYKHR-UHFFFAOYSA-N 0.000 description 1
- BSVBQGMMJUBVOD-UHFFFAOYSA-N trisodium borate Chemical compound [Na+].[Na+].[Na+].[O-]B([O-])[O-] BSVBQGMMJUBVOD-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/342—Alcohols having more than seven atoms in an unbroken chain
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/361—Carboxylic acids having more than seven carbon atoms in an unbroken chain; Salts or anhydrides thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/10—Preparations for permanently dyeing the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
- A61K2800/88—Two- or multipart kits
Definitions
- the invention relates to a means for oxidative
- Ratio of 1: 1.5 to 1: 4 is obtained, as well as a process for the oxidative dyeing of hair.
- Oxidation hair colors are, just as in the past, a central component of a cosmetic product range used for hair treatment. They consist of two components, which are mixed shortly before use and then applied to the hair to be colored.
- the first component contains the dyestuff substances. You can as
- the second component is an aqueous, creamy or powdery product in which a suitable oxidizing agent is contained.
- a suitable oxidizing agent for example hydrogen peroxide.
- 1,4-Diaminobenzene, 2,5-diaminotoluene, 2,5-diaminophenylethanol, 4-aminophenol and 4-amino-3-methylphenol are preferably used as developer substances.
- Coupler substances examples include resorcinol, 4-chlororesorcinol, sesamol, 2-methylresorcinol, 3-aminophenol, 4- (2'-hydroxyethyl) amino-1,2-methylenedioxybenzene and 2-amino-4- (2'-hydroxyethylamino) - anisole.
- Coloring compounds are preferably used in liquid form in some countries, for example in the USA.
- Liquid colorants are also of great importance in the area of public hair colors. They have the advantage that the raw materials they contain are available inexpensively and that the liquid colorant masses are easy to produce in terms of production technology.
- liquid dye compositions are mostly used in conjunction with aqueous hydrogen peroxide solutions, for example in a ratio of 1: 1 or 1: 2.
- the mixing of the liquid color carrier mass with the hydrogen peroxide solution can take place, for example, in an application bottle with which the ready-to-use oxidation hair colorant is applied to the hair to be colored after mixing.
- liquid dyes have a number of serious disadvantages.
- the liquid colorants quickly turn dark after adding the hydrogen peroxide solution.
- the hair brought into contact with the ready-to-use oxidation hair dye takes on the coloring much more slowly.
- the premature darkening of the hair of the oxidation hair has the disadvantageous effect that the coloring agent is rinsed out too early, so that the intended color intensity is often not achieved by a too short exposure time on the hair.
- liquid colorants also have the disadvantage that they very easily release the ammonia contained in the environment, which has an undesirable odor nuisance.
- liquid hair dyes are known for their inadequate skin tolerance, especially if they serve to lighten the hair.
- the object of the present invention was therefore to provide an agent for the oxidative dyeing of hair on the basis of a liquid dyestuff and a hair dyeing process using this agent, which has the disadvantages described of known agents based on liquid dyestuffs for oxidative dyeing of hair does not have.
- agents for the oxidative dyeing of hair can be prepared by mixing a liquid colorant and an emulsion-like preparation containing the oxidizing agent which are well tolerated by the skin and in which the premature darkening, which adversely affects the coloring result, after the admixing of the oxidizing agent, largely is avoided and which, compared to known agents, emits a far lower odor burden due to ammonia escaping from the agent.
- the present invention therefore relates to compositions for the oxidative dyeing of hair, obtained by mixing a component (A) which is a liquid colorant composition with a viscosity below 100 mPa.s at 30 degrees Celsius, and a component (B) which is an emulsion , 2.5 to 12 percent by weight of at least one C 10 to C 24 fatty alcohol of natural or synthetic origin and a composition containing an oxidizing agent, in the weight ratio of component (A) to component (B) 1: 1.5 to 1: 4 .
- a component (A) which is a liquid colorant composition with a viscosity below 100 mPa.s at 30 degrees Celsius
- a component (B) which is an emulsion , 2.5 to 12 percent by weight of at least one C 10 to C 24 fatty alcohol of natural or synthetic origin and a composition containing an oxidizing agent, in the weight ratio of component (A) to component (B) 1: 1.5 to 1: 4 .
- the weight ratio of component (A) to component (B) is 1: 2 to 1: 3.
- the viscosity of the liquid colorant composition was 30 at 30 using a Haake-Visco balance (rod II, 5 grams) Degrees Celsius.
- Component (B) contained fatty alcohol of natural or synthetic origin is preferably a C 1 4 - bis
- component (B) C 20 fatty alcohol.
- fatty alcohols which can be contained in component (B) are cetyl and stearyl alcohol or a mixture thereof.
- Component (B) contains 1 to 18 percent by weight, but particularly preferably 4 to 14 percent by weight of an oxidizing agent.
- the main oxidizing agents used to develop hair color are hydrogen peroxide and its addition compounds to urea, melanin and sodium borate.
- Component (B) particularly preferably contains 1 to 18 percent by weight of hydrogen peroxide.
- Component (A) contains 2 to 30 percent by weight, particularly preferably 8 to 16 percent by weight, but saturated or unsaturated C 10 to C 24 fatty acids of natural or synthetic origin, but preferably C 16 to
- C 2 2 fatty acids or mixtures thereof examples of such fatty acids which can be contained in component (A) are erucic acid, myristic acid, ricinoleic acid, lauric acid, palmitic acid and oleic acid.
- the fatty acids are preferably dissolved in the hair dye according to the invention by the addition of ammonia in the form of their ammonium soaps. Instead of ammonia, however, aliphatic amines, for example monoethanolamine, can also be used.
- Component (A) can further contain 2 to 30, but preferably 12 to 28, percent by weight of low molecular weight C 1 to C 4 alcohols, C 2 to C 6 glycols, such as, for example, ethanol, propanol, isopranol, ethylene glycol, 1,2 propylene glycol or butyl glycol, or mixtures thereof may be included.
- C 1 to C 4 alcohols such as, for example, ethanol, propanol, isopranol, ethylene glycol, 1,2 propylene glycol or butyl glycol, or mixtures thereof may be included.
- C 2 to C 6 glycols such as, for example, ethanol, propanol, isopranol, ethylene glycol, 1,2 propylene glycol or butyl glycol, or mixtures thereof may be included.
- Component (A) can also contain 0.1 to 25 percent by weight of nonionic emulsifiers.
- the hair dye according to the invention particularly preferably contains 10 to 20 percent by weight of nonionic emulsifiers.
- non-ionic emulsifiers which can be used are oxyethylated C 10 -C 20 -fatty alcohols or oxyethylated alkylphenols with a C 6 -C 14 -alkyl radical or mixtures thereof.
- the fatty alcohols and alkylphenols contained in component (A) are ethoxylated with 1 and 8, but preferably with 1 and 6, ethylene oxide units.
- Component (A) contains at least one coupler substance and at least one developer substance and, if appropriate, additionally with self-coupling color pre-mares and dyes which are absorbed directly onto the hair.
- the developer and coupler substances are used in the hair dye either as such or in the form of their physiologically acceptable salts with inorganic or organic acids, such as, for example, chloride, sulfate, phosphate, acetate, propionate, lactate or citrate.
- the coupler substances are generally used in an approximately equimolar amount, based on the developer substances used. Even if the equimolar use proves to be expedient, it is not disadvantageous if the coupler substances are used in a certain excess or deficit. It is also not necessary for the developer component and the coupler component to be uniform products; rather, both the developer component can be a mixture of known developer substances and the coupler component can be a mixture of known coupler substances.
- the liquid colorant, component (A) contains known coupler substances, alone or as a mixture with one another, in particular 1-naphthol, 4-methoxy-1-napthol, resorcinol, 4-chlororesorcinol, 4,6-dichlororesorcinol, 2-methylresorcinol, 3 Aminophenol, 4-hydroxy-1,2-methylenedioxybenzene, 4-amino-1,2-methylenedioxybenzene, 4- (ß-hydroxyethylamino) -1,2-methylenedioxybenzene, 4-hydroxyindole,
- 1,4-diaminobenzene, 2,5-diaminotoluene, 2,5-diaminoanisole, 2,5-diaminobenzyl alcohol, 3-methyl-4-aminophenol are the main constituents of the color carrier composition according to the invention.
- Oxidation dyes known and customary for hair coloring which may be contained in component (A), are found, inter alia, in the book by E. Sagarin, "Cosmetics, Science and Technology", Interscience Pubtishers Inc., New York (1957), pages 503 ff. and in the book by H. Janistyn, "Handbook of cosmetics and fragrances"
- the total amount of the developer substance-coupler substance combination contained in component (A) should be 0.01 to 12.0 weight percent, in particular 0.2 to 4.0 weight percent.
- conventional direct dyes for example triphenylmethane dyes such as Diamond Fuchsine (CI 42 510) and Leather Ruby HF (CI 42 520), aromatic nitro dyes such as 2-amino-4,6-dinitro-phenol, 2-nitro- 4- (ß-hydroxyethylamino) aniline, 2-N-ß, -dihydroxypropylamino- 5- (N-methyl, N-hydroxyethyl) amino-nitrobenzene and 2-amino-4-nitrophenol, azo dyes such as Acid Brown 4 (CI 14 805) and Acid Blue 135 (CI 13 385), Anthrachi non-dyes such as Disperse Violet 4 (CI 61 105), Disperse Blue 1 (CI 64 500), Disperse Red 15 (CI 60 710), Disperse Violet 1 (CI 61 100), also 1, 4,5,8-tetra aminoanthraquinone and 1,4-diaminoanthraquinone, can be contained in component (A).
- Component (A) can also be used with self-coupling color precursors, such as 2-amino-5-methylphenol, 2-amino-6-methylphenol, 2-amino-5-ethoxypheno L or also 2-propylamino-5- aminopyridine.
- the total amount of the direct dyes and of the self-coupling dye precursors in component (A) is 0.01 to 7.0 percent by weight, preferably 0.2 to 4.0 percent by weight.
- antioxidants such as ascorbic acid, resorcinol or sodium sulfite and
- Complexing agents for heavy metals for example ethylenediaminetetraacetate and nitriloacetic acid, can be contained in an amount of up to 0.5 percent by weight.
- Perfume oils can be contained in the color carrier composition according to the invention in an amount of up to 1 percent by weight.
- Component (A) can also contain wetting agents, emulsifiers,
- Contain care agents Contain care agents, cationic resins and other common additives.
- the ready-to-use agent for oxidative dyeing of the hair which is formed by mixing component (A) with component (B) in a quantitative ratio according to the invention, can be acidic, neutral or alkaline.
- the pH of the agent for oxidative coloring of the hair according to the invention is preferably between 7.5 and 12.0.
- the liquid colorant composition (component (A)) is mixed with the hydrogen peroxide emulsion (component (B)) immediately before use in a weight ratio of 1: 1.5 to 1: 4 according to the invention, and an amount is sufficient for coloring the hair, depending on the fullness of the hair, generally 90 to 160 g, this mixture on the hair.
- the mixture is left to act on the hair at 15 to 50 degrees Celsius for about 5 to 60 minutes, preferably 30 minutes, then the hair is rinsed with water, washed if necessary, rinsed and
- Color carrier 12.0 g erucic acid
- Hydrogen peroxide emulsion 10.0 g cetylstearyl alcohol
- the hair treated in this way is colored evenly light brown from the roots to the ends of the hair.
- the agent according to the invention for oxidatively dyeing hair darkens only slightly after mixing the two components; smells only slightly of ammonia and is well tolerated by the skin.
- the liquid colorant composition Before use, 40 g of the liquid colorant composition are mixed with 80 g of the hydrogen peroxide emulsion, corresponding to a mixing ratio of 1: 2, 120 g of the mixture are applied to gray, human hair and the mixture is left to act for 20 minutes at room temperature. The hair dye mixture is then rinsed out with water and the hair is dried.
- the agent according to the invention for oxidative dyeing of hair smells only slightly of ammonia, hardly darkens after the addition of the oxidizing agent and is well tolerated by the skin. The hair treated in this way has taken on an even, dark brown tone.
- Example 3 Oxidation hair dye: liquid colorant: 12.0 g oleic acid
- a half-side test is carried out to compare the skin tolerance of the oxidation hair dyeing agent according to the invention with known oxidation hair dyeing agents.
- a normal oxidation hair dye which is prepared by mixing 20 g of the liquid colorant composition from Example 1 and 40 g of a conventional hydrogen peroxide preparation of the following composition, is applied to human, medium-brown hair on the left half of the head of ten test participants.
- Common hydrogen peroxide preparation is
- 60 g of the ready-to-use oxidation hair dye according to the invention according to Example 1 are applied to the hair on the right half of the head of the test participants. Both agents are allowed to act on the hair and scalp for 20 minutes at room temperature, then rinsed out with water, the hair is washed with shampoo, rinsed and then dried. During the action of the two agents for oxidative dyeing of hair, the test subjects felt a significantly stronger burning sensation on the scalp on the left side of the head than on the right side of the head, which was treated with the oxidation hair dye according to the invention.
- Head half of 30% of the participants showed a clear reddening of the scalp.
- the agent according to the invention did not cause reddening of the scalp in any of the test participants.
- the customary oxidation hair dye was first prepared by mixing 20 g of the liquid colorant composition according to Example 2 with 40 g of a customary hydrogen peroxide preparation of the following composition: Common hydrogen peroxide preparation:
- Polyethylene glycol stearyl ether in which one or more monomers consist of acrylic acid, methacrylic acid or their simple esters and the polyethylene glycol stearyl ether contains twenty oxyethylene units
- this oxidation hair dye 60 g were then applied to the left half of the head of ten test subjects with gray hair.
- the oxidative hair dye according to the invention according to Example 3 was compared with a customary oxidation hair dye with regard to the darkening of the mass after the two components had been mixed.
- the usual oxidation hair dye was first prepared by mixing 20 g of the liquid colorant of Example 3 with 40 g of a conventional hydrogen peroxide preparation of the following composition: usual hydrogen peroxide preparation:
- the right half of the head was treated with 60 g each of the oxidation hair dye according to the invention as in Example 3. During the exposure time of 20 minutes The darkening of the two agents was assessed by the hairdressers at room temperature.
- the comparison experiment showed that the oxidation hair dye according to the invention darkens considerably less than the usual oxidation hair dye applied to the left half of the head. Since the agent darkens only slightly. The desired color result can be achieved safely.
- the means according to the invention can rule out the incorrect assessments of the color intensity already achieved in the case of customary oxidation hair colors as a result of rapid darkening, which lead to unintentionally weak colorations.
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Emergency Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Cosmetics (AREA)
- Processes For Solid Components From Exhaust (AREA)
- Exhaust Gas After Treatment (AREA)
Abstract
L'invention a pour objet un agent pour la teinture oxydante des cheveux, obtenu en mélangeant un mordant liquide, d'une viscosité inférieure à 100 mPa, à 30 °C, avec une composition en émulsion renfermant 2,5 à 12 % en poids d'au moins un alcool gras en C10-C24 et un oxydant, dans un rapport pondéral de 1:1,5 à 1:4, ainsi qu'un procédé pour la teinture oxydante des cheveux utilisant un tel agent. Le nouvel agent évite une coloration ultérieure plus foncée altérant le résultat de la teinture, qu'on obtient avec les colorants d'oxydation habituels pour cheveux, à base de mordants liquides. Il permet également d'éviter l'inconvénient d'une odeur désagréable consécutive à un faible dégagement d'ammoniac. Il présente en outre une bonne compatibilité avec la peau.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEP4005008.4 | 1990-02-19 | ||
DE19904005008 DE4005008C2 (de) | 1990-02-19 | 1990-02-19 | Oxidationshaarfärbemittel aus einer flüssigen Farbträgermasse und einer emulsionsförmigen, oxidationsmittelhaltigen Zusammensetzung und Verfahren zum oxidativen Färben von Haaren |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1991011985A1 true WO1991011985A1 (fr) | 1991-08-22 |
Family
ID=6400392
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP1991/000204 WO1991011985A1 (fr) | 1990-02-19 | 1991-02-04 | Colorant d'oxydation pour teinture des cheveux comprenant un mordant liquide et une composition en emulsion renfermant un agent oxydant, et procede de teinture oxydante des cheveux |
Country Status (3)
Country | Link |
---|---|
JP (1) | JPH0662395B2 (fr) |
DE (1) | DE4005008C2 (fr) |
WO (1) | WO1991011985A1 (fr) |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2751533A1 (fr) * | 1996-07-23 | 1998-01-30 | Oreal | Composition de teinture d'oxydation pour fibres keratiniques comprenant un polymere amphiphile non-ionique |
KR100264926B1 (ko) * | 1996-09-06 | 2000-09-01 | 조지안느 플로 | 양친매성음이온중합체를함유하는케라틴섬유용산화염료조성물 |
US6641618B1 (en) | 1999-01-29 | 2003-11-04 | L'oreal S.A. | Ready-to-use aqueous composition for bleaching keratin fibers, comprising a combination of a water-soluble solvent and a nonionic and/or anionic amphiphilic polymer comprising at least one fatty chain |
WO2004017932A1 (fr) * | 2002-07-31 | 2004-03-04 | Arimino Co.,Ltd | Compositions emulsionnees pour blanchiment et teinture des cheveux et procedes de blanchiment ou de teinture des cheveux au moyen de ces compositions |
WO2006106390A3 (fr) * | 2005-04-05 | 2007-01-04 | Paolo Giannico | Procede de regulation et de reduction des emissions de vapeur d'ammoniac emanant de cremes de coloration et de decoloration capillaires |
FR2942704A1 (fr) * | 2009-03-04 | 2010-09-10 | Oreal | Dispositif de distribution d'une composition tinctoriale pour les fibres keratiniques et procede associe. |
US8889110B2 (en) | 2008-12-19 | 2014-11-18 | L'oreal | Oxidizing composition for the treatment of keratin fibers comprising at least one oil, at least one fatty alcohol and at least one oxyalkylenated fatty alcohol |
US9005594B2 (en) | 2007-12-21 | 2015-04-14 | L'oreal | Method for lightening human keratin fibers using at least one anhydrous composition, at least one organic amine, and at least one oxidizing agent, and device for use thereof |
US9017424B2 (en) | 2008-12-19 | 2015-04-28 | L'oreal | Process for lightening keratin materials using an emulsion comprising an alkaline agent and an oxidizing composition |
US11691035B2 (en) | 2008-12-19 | 2023-07-04 | L'oreal | Oxidizing composition for the treatment of keratin fibers comprising at least one cationic polymer, at least one fatty amide and at least one anti-oxygen agent |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4332965A1 (de) * | 1993-09-28 | 1995-03-30 | Wella Ag | Oxidationshaarfärbemittel aus einer cremeförmigen Farbstoffträgermasse und einer ein Polymer und ein Oxidationsmittel enthaltenden Zubereitung sowie Verfahren zum oxidativen Färben von Haaren |
FR2738741B1 (fr) * | 1995-09-19 | 1997-12-05 | Oreal | Composition pour la teinture des fibres keratiniques, contenant un antagoniste de substance p |
DE19604932A1 (de) * | 1996-02-10 | 1997-08-14 | Wella Ag | Oxidationshaarfärbemittel |
DE19827434C2 (de) * | 1998-06-19 | 2000-08-17 | Goldwell Gmbh | Haarfärbemittel und Verfahren zu dessen Herstellung |
DE19847224C2 (de) * | 1998-10-14 | 2001-02-08 | Goldwell Gmbh | Verfahren zur Herstellung von stabilen Haarfärbeemulsionen |
CA2394535C (fr) * | 1999-12-17 | 2011-03-15 | Unilever Plc | Compositions de coloration et de decoloration des cheveux ayant un ph superieur a 10 et contenant du cholesterol |
FR2817468B1 (fr) * | 2000-12-04 | 2005-05-06 | Oreal | Composition destinee a la teinture d'oxydation des fibres keratiniques comprenant de la gylcerine et un polyol different de la glycerine dans un rapport donne |
FR2848841B1 (fr) * | 2002-12-24 | 2005-03-11 | Oreal | Composition colorante contenant une phase mesomorphe et son procede de preparation, composition prete a l'emploi pour la teinture des matieres keratiniques |
US7608116B2 (en) | 2002-12-24 | 2009-10-27 | L'oreal S.A. | Oxidation dye composition comprising at least one mesomorphic phase, process for preparing it and ready-to-use composition for dyeing keratin materials |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3329916A1 (de) * | 1982-08-30 | 1984-04-19 | Bristol-Myers Co., 10154 New York, N.Y. | Oxidations-haarfaerbemittel-zusammensetzung und eine verpackungseinheit dafuer |
EP0166100A1 (fr) * | 1984-06-27 | 1986-01-02 | Wella Aktiengesellschaft | Composition pour la teinture d'oxydation des cheveux à base d'un véhicule de basse viscosité |
EP0258586A1 (fr) * | 1986-07-31 | 1988-03-09 | Wella Aktiengesellschaft | Composition de teinture des cheveux par oxydation à base d'un véhicule gélifié et procédé de teinture des cheveux |
US4776855A (en) * | 1986-03-19 | 1988-10-11 | Clairol Inc. | Hair dyeing process and composition |
EP0308825A1 (fr) * | 1987-09-24 | 1989-03-29 | Henkel Kommanditgesellschaft auf Aktien | Composition sous forme d'émulsion contenant du peroxyde d'hydrogène, pour la décoloration et pour la teinture par oxydation des cheveux |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2421606A1 (fr) * | 1978-04-06 | 1979-11-02 | Oreal | Procede de teinture de fibres keratiniques en deux temps |
JPS61130209A (ja) * | 1984-11-30 | 1986-06-18 | Sunstar Inc | 白髪染毛剤 |
DE3508309A1 (de) * | 1985-03-08 | 1986-09-11 | Henkel KGaA, 4000 Düsseldorf | Haarfaerbemittel |
JP2659740B2 (ja) * | 1988-02-22 | 1997-09-30 | ホーユー株式会社 | 染毛剤組成物 |
DE3834142A1 (de) * | 1988-10-07 | 1990-04-12 | Wella Ag | Lagerstabiles cremefoermiges oxidationshaarfaerbemittel mit hohem farbstoff/elektrolyt-gehalt |
-
1990
- 1990-02-19 DE DE19904005008 patent/DE4005008C2/de not_active Revoked
-
1991
- 1991-02-04 JP JP3503700A patent/JPH0662395B2/ja not_active Expired - Lifetime
- 1991-02-04 WO PCT/EP1991/000204 patent/WO1991011985A1/fr unknown
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3329916A1 (de) * | 1982-08-30 | 1984-04-19 | Bristol-Myers Co., 10154 New York, N.Y. | Oxidations-haarfaerbemittel-zusammensetzung und eine verpackungseinheit dafuer |
EP0166100A1 (fr) * | 1984-06-27 | 1986-01-02 | Wella Aktiengesellschaft | Composition pour la teinture d'oxydation des cheveux à base d'un véhicule de basse viscosité |
US4776855A (en) * | 1986-03-19 | 1988-10-11 | Clairol Inc. | Hair dyeing process and composition |
EP0258586A1 (fr) * | 1986-07-31 | 1988-03-09 | Wella Aktiengesellschaft | Composition de teinture des cheveux par oxydation à base d'un véhicule gélifié et procédé de teinture des cheveux |
EP0308825A1 (fr) * | 1987-09-24 | 1989-03-29 | Henkel Kommanditgesellschaft auf Aktien | Composition sous forme d'émulsion contenant du peroxyde d'hydrogène, pour la décoloration et pour la teinture par oxydation des cheveux |
Cited By (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2751533A1 (fr) * | 1996-07-23 | 1998-01-30 | Oreal | Composition de teinture d'oxydation pour fibres keratiniques comprenant un polymere amphiphile non-ionique |
WO1998003150A3 (fr) * | 1996-07-23 | 1998-03-26 | Oreal | Composition de teinture d'oxydation pour fibres keratiniques comprenant un polymere amphiphile non-ionique |
US6010541A (en) * | 1996-07-23 | 2000-01-04 | L'oreal | Oxidation dye composition for keratin fibers comprising a nonionic amphiphilic polymer |
US6277155B1 (en) | 1996-07-23 | 2001-08-21 | L'oreal | Oxidation dye composition for keratin fibers comprising a nonionic amphiphilic polymer |
US6344063B1 (en) | 1996-07-23 | 2002-02-05 | L'oreal | Oxidation dye composition for keratin fibers comprising nonionic amphiphilic polymer |
CN1121207C (zh) * | 1996-07-23 | 2003-09-17 | 莱雅公司 | 含有非离子两亲型聚合物的角蛋白纤维氧化染色组合物 |
KR100264926B1 (ko) * | 1996-09-06 | 2000-09-01 | 조지안느 플로 | 양친매성음이온중합체를함유하는케라틴섬유용산화염료조성물 |
US6527814B1 (en) | 1996-09-06 | 2003-03-04 | L'oreal S.A. | Oxidation dye composition for keratin fibers, comprising an anionic amphiphilic polymer |
US6641618B1 (en) | 1999-01-29 | 2003-11-04 | L'oreal S.A. | Ready-to-use aqueous composition for bleaching keratin fibers, comprising a combination of a water-soluble solvent and a nonionic and/or anionic amphiphilic polymer comprising at least one fatty chain |
WO2004017932A1 (fr) * | 2002-07-31 | 2004-03-04 | Arimino Co.,Ltd | Compositions emulsionnees pour blanchiment et teinture des cheveux et procedes de blanchiment ou de teinture des cheveux au moyen de ces compositions |
WO2006106390A3 (fr) * | 2005-04-05 | 2007-01-04 | Paolo Giannico | Procede de regulation et de reduction des emissions de vapeur d'ammoniac emanant de cremes de coloration et de decoloration capillaires |
US9005594B2 (en) | 2007-12-21 | 2015-04-14 | L'oreal | Method for lightening human keratin fibers using at least one anhydrous composition, at least one organic amine, and at least one oxidizing agent, and device for use thereof |
US8889110B2 (en) | 2008-12-19 | 2014-11-18 | L'oreal | Oxidizing composition for the treatment of keratin fibers comprising at least one oil, at least one fatty alcohol and at least one oxyalkylenated fatty alcohol |
US9017424B2 (en) | 2008-12-19 | 2015-04-28 | L'oreal | Process for lightening keratin materials using an emulsion comprising an alkaline agent and an oxidizing composition |
US11691035B2 (en) | 2008-12-19 | 2023-07-04 | L'oreal | Oxidizing composition for the treatment of keratin fibers comprising at least one cationic polymer, at least one fatty amide and at least one anti-oxygen agent |
FR2942704A1 (fr) * | 2009-03-04 | 2010-09-10 | Oreal | Dispositif de distribution d'une composition tinctoriale pour les fibres keratiniques et procede associe. |
WO2010100231A1 (fr) * | 2009-03-04 | 2010-09-10 | L'oreal | Dispositif de distribution d'une composition colorante pour fibres de kératine, et procédé associé |
Also Published As
Publication number | Publication date |
---|---|
JPH04505459A (ja) | 1992-09-24 |
JPH0662395B2 (ja) | 1994-08-17 |
DE4005008A1 (de) | 1991-08-22 |
DE4005008C2 (de) | 1995-01-05 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP0258586B1 (fr) | Composition de teinture des cheveux par oxydation à base d'un véhicule gélifié et procédé de teinture des cheveux | |
EP0166100B1 (fr) | Composition pour la teinture d'oxydation des cheveux à base d'un véhicule de basse viscosité | |
DE4005008C2 (de) | Oxidationshaarfärbemittel aus einer flüssigen Farbträgermasse und einer emulsionsförmigen, oxidationsmittelhaltigen Zusammensetzung und Verfahren zum oxidativen Färben von Haaren | |
EP0241716B1 (fr) | Composition et procédé de coloration par oxydation des cheveux | |
DE4216381A1 (de) | Oxidationshaarfärbemittel auf der Basis einer cremeförmigen Trägermasse und Verfahren zum Färben von Haaren | |
DE3834142A1 (de) | Lagerstabiles cremefoermiges oxidationshaarfaerbemittel mit hohem farbstoff/elektrolyt-gehalt | |
DE69417698T2 (de) | Verfahren zum oxydatieven Färben von keratinen Fasern unter Anwendung von Wasserdampf | |
EP0650718B1 (fr) | Composition de coloration oxydative des cheveux constituée d'un support colorant crèmeux et d'une préparation contenant un polymère et un oxydant et procédé de coloration oxydative des cheveux | |
EP0485539B2 (fr) | Colorant par oxydation pour cheveux obtenu a partir d'un support colorant emulsionne et d'une composition emulsionnee contenant un oxydant et procede pour la coloration des cheveux par oxydation | |
EP0727203A1 (fr) | Colorant d'oxydation pour cheveux | |
DE3942294A1 (de) | Mittel und verfahren zum oxidativen faerben von haaren | |
DE3229973C2 (fr) | ||
DE4123941A1 (de) | Verfahren zur oxidativen faerbung von haaren | |
DE3743769A1 (de) | Mittel zur oxidativen faerbung von haaren | |
DE3028202C2 (fr) | ||
EP0043436B1 (fr) | Composition et procédé de teinture pour cheveux | |
EP0706787B1 (fr) | Colorant d'oxydation pour cheveux | |
DE3131348A1 (de) | Faerbemittel, welche amino-3 nitro-4 anisol-derivate enthalten, anwendungsverfahren zum faerben keratinischer fasern und neue, in den mitteln enthaltene verbindung, sowie ein verfahren zu deren herstellung | |
DE2840830C2 (fr) | ||
DE19545837A1 (de) | Oxidationshaarfärbemittel | |
WO1992006670A1 (fr) | Colorant des cheveux contenant 1,4-bis-[(dihydroxyalkyl)amino]-anthraquinone et nouvelles 1,4-bis-[(dihydroxyalkyl)amino]-anthraquinones | |
EP0788787A2 (fr) | Composition de teinture des cheveux par oxydation à base d'un véhicule gélifié | |
DE102004045353A1 (de) | Mittel zur Entfernung von Oxidationshaarfarben | |
DE3914394A1 (de) | Oxidationshaarfaerbemittel mit einem gehalt an 1,3-diethyl-2,5-diaminobenzol | |
DE9313870U1 (de) | Mittel zum gleichzeitigen Färben und Aufhellen von menschlichen Haaren |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
AK | Designated states |
Kind code of ref document: A1 Designated state(s): JP US |