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WO1992007347A1 - Etiquettes synthetiques a moulage incorpore par procede in-mold et pourvues de rayures ainsi que substrats moules servant a les fixer - Google Patents

Etiquettes synthetiques a moulage incorpore par procede in-mold et pourvues de rayures ainsi que substrats moules servant a les fixer Download PDF

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Publication number
WO1992007347A1
WO1992007347A1 PCT/US1991/007386 US9107386W WO9207347A1 WO 1992007347 A1 WO1992007347 A1 WO 1992007347A1 US 9107386 W US9107386 W US 9107386W WO 9207347 A1 WO9207347 A1 WO 9207347A1
Authority
WO
WIPO (PCT)
Prior art keywords
section
synthetic
scored
mold label
film layer
Prior art date
Application number
PCT/US1991/007386
Other languages
English (en)
Inventor
Robert M. Mortellite
George A. Strutz
Pai-Chuan Wu
Original Assignee
Clopay Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Clopay Corporation filed Critical Clopay Corporation
Publication of WO1992007347A1 publication Critical patent/WO1992007347A1/fr

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D25/00—Details of other kinds or types of rigid or semi-rigid containers
    • B65D25/34—Coverings or external coatings
    • B65D25/36—Coverings or external coatings formed by applying sheet material
    • G—PHYSICS
    • G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F3/00—Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
    • G09F3/02—Forms or constructions
    • G09F3/0288—Labels or tickets consisting of more than one part, e.g. with address of sender or other reference on separate section to main label; Multi-copy labels
    • G—PHYSICS
    • G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F3/00—Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
    • G09F3/04—Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps to be fastened or secured by the material of the label itself, e.g. by thermo-adhesion

Definitions

  • the present invention relates to synthetic in-mold labels divided into sections which can be separated from one another by hand along score lines and which can be applied to molded substrates, such as hollow molded containers, during the molding operations.
  • the present invention further relates to molded substrates labeled with such scored synthetic in-mold labels.
  • labels are prepared from cellulosic base stocks, such as paper, and have proof-of-purchase coupons which can be separated from the rest of the labels by perforations.
  • the proof-of-purchase coupon areas are generally affixed to the packages so that they can be easily removed therefrom by consumers while the remaining portions of the labels remain affixed to the packages. See, for example, U.S. Patent No. 3,702,511. See also U.S. Patent No. 4,312,523 and U.S. Patent Re. 30,958.
  • the plastic containers formed by means of blow-molding or injection-molding are fabricated from plastic, polyethylene, polypropylene, polyvinyl chloride, polyethylene terephthalate and the like, and especially high-density polyethylene (HDPE) , and are prevalent today in a wide variety of shapes and sizes for holding many different kinds of materials, such as light duty liquids (e.g., dishwashing detergents), heavy duty liquids (e.g., laundry detergents), motor oil, vegetable oil, herbicides, etc.
  • light duty liquids e.g., dishwashing detergents
  • heavy duty liquids e.g., laundry detergents
  • motor oil vegetable oil
  • herbicides etc.
  • the blow-molded or injection- molded containers are provided with a label which designates the trade name of the product and may contain other information as well.
  • the label is merely attached to the container after molding by means of an adhesive or the like. See, for example, U.S. Patent No. 4,587,158 and U.S. Patent Re. 32,929.
  • the label may also be attached to the container during the container molding process.
  • This technology by which the label is mounted to the container during the molding operation is generally referred to as an in-mold label (IML) process.
  • IML in-mold label
  • an in-mold label is placed in a blow or injection mold prior to the formation of a container. Once the label is in position, the container is formed by blowing or injecting plastic in the mold.
  • the label which may include an adhesive, attaches or adheres to the outer surface of the container. In some instances, the label is partially or completely embedded in the plastic surface of the blow- or injection-molded container.
  • the in-mold labeling of the molded plastic containers allows manufacturers to readily and inexpensively produce labeled containers directly during the molding operations without the need to apply labels in subsequent steps. By elim ⁇ inating subsequent handling, capital investment and handling costs are substantially reduced. See, for example, U.S. Patent Nos.
  • in-mold labels prepared from cellu- losic base stocks, such as paper have proven to be undesirable in operation.
  • conventional paper labels can wrinkle, curl or craze when exposed to heat and moisture associated with container formation and use. This can result in labels which may not be completely adhered to the outer surfaces of the containers.
  • the wrinkling, curling and crazing of the paper labels provide unsightly aesthetic appearances and detract from the marketing appeal of the containers labeled therewith.
  • paper labels associated with certain types of con ⁇ tainers e.g., shampoo containers, which are exposed to very humid environments, e.g., shower stalls, may eventually disintegrate and become separated from those containers.
  • Another problem common with paper-labeled plastic containers is recyclability. Occasionally a defective container will be produced during the molding process. The recycle of scrap molded objects having such labels affixed thereto requires tedious mechanical means or solvents to first remove the labels. In order to reclaim or recycle such plastic containers, particularly defective bottles prepared during the molding process, it is first necessary to remove the paper labels therefrom. Contamination from residual adhesive and small portions of unremoved paper may make it practically impossible to reclaim defective molded plastic containers bearing such labels.
  • in-mold labels A serious drawback associated with the application of in-mold labels is that, if they are perforated, they will not be held properly, if held at all, in the mold sections by the vacuum during the molding operations. Consequently, in-mold labels provided with, for example, tearable proof-of-purchase coupons have been commercially unavailable hitherto. Accordingly, there is a demand in the industry for synthetic in-mold labels which are divided into sections which can be torn by hand along lines of weakness for removing sections in the form of, for example, proof-of-purchase coupons, from hollow plastic containers after the containers have been labeled with such in-mold labels during the molding operations.
  • the present invention alleviates certain of the above-mentioned disadvantages and shortcomings of the present state of the in-mold label art through the discovery of novel, scored synthetic in-mold labels which are tearable by hand along lines of weakness and molded substrate labeled therewith.
  • the in-mold labels of the instant invention are " in the form of single- or multi-layered plastic films, which are intended to be applied to molded substrates, such as hollow molded containers, during the molding operations.
  • the novel in-mold labels are typically prepared from olefin resins and are scored with lines of weakness for dividing the in-mold labels into unique removable and non-removable sections which may be separated from one another by hand.
  • the non-removable sections of the in-mold labels of the instant invention are affixed to the molded substrates by permanent bonding means, such as permanent adhesives or thermal bonds, while the remov ⁇ able sections of the same in-mold labels are affixed to the molded substrates via removable bonding means, such as release coatings, removable adhesives or light thermal bonds. Nevertheless, in some instances, depending upon the materials selected to manufacture the molded substrates and the in-mold labels of the instant invention, the removable sections of the in-mold labels may remain unaffixed to the molded substrates so long as the other sections thereof are permanently bonded to the molded substrates.
  • the novel synthetic in-mold labels include score lines which function to divide the synthetic in-mold labels into sections which can be easily separated from one another by hand along the score lines when the areas encompassing the score lines are subjected to suffi ⁇ cient non-parallel stresses.
  • the synthetic in-mold labels are provided with fine, unperforated score lines whereby the labels may be torn by hand along the score lines to remove sections therefrom.
  • the score lines may be continuous or interrupted, but not perforated, the novel in-mold labels of the instant invention can be uniquely applied in the molds via vacuum to the molded containers during the molding operations.
  • the score lines for dividing the novel synthetic in-mold labels of the instant invention into sections can be formed by, for example, engaging a sharp blade, such as a razor blade or a laser beam, into the surface of the in-mold label,material at a selected or predetermined depth as the material passes over a smooth roller or stationary bar. This can be accomplished, for instance, by applying a selected force to the sharp blade through the use of an air cylinder, a weight, a spring, an electromagnet or the like, or by establishing a blade protrusion beyond a fixed wide shoulder and applying the wide shoulder to the surface of the material being scored by the application of force.
  • a sharp blade such as a razor blade or a laser beam
  • the novel synthetic in-mold labels of the instant invention are preferably unstretched, i.e., substantially free of mechanically produced microvoids, and are formed with a continuous polyolefin resin matrix containing an effective amount of a particulate filler having pre-existing microvoids provided therein.
  • the microvoid particulate fillers of such unstretched in-mold labels are dispersed throughout the continuous olefin resin matrix of the synthetic in-mold labels of the instant invention to provide microvoids in communication with the surfaces of the synthetic in-mold labels for imparting thereto receptivity and retentivity for the common writing and printing materials.
  • Such synthetic unstretched in-mold labels according to the present invention are believed to have excellent stiffness, tensile strength, and flexibility as are required for paper materials, they are generally uniform in thickness, and they have good tear resistance and writable and printable properties.
  • These surprising characteris ⁇ tics are believed to incur since the icrovoid par ⁇ ticulate fillers, which are integrally formed with the continuous olefin resin matrix, are dispersed somewhat uniformly but randomly therethroughout so that the non-mechanically produced microvoids are provided at the exterior surfaces of the in-mold labels to render such surfaces porous for imparting writability and printability thereto.
  • a method for producing preferred in-mold labels according to the instant invention provides for admixing the constituents into, for example, a homo ⁇ genous blend in the form of a pellet and extruding the pellet into a polymer matrix in the form of a film or sheet having a thickness (gauge) of about 1 mil to about 10 mils or more and preferably of about 4 mils to about 6 mils for making the in-mold labels.
  • the preferred polymer resins which can be used include, for instance, polyethylene, polypropylene, copolymers and the like.
  • Microvoid particulate fillers which are suitable for use include, for example, diatomaceous earth, volcanic ash, silica gels, styrogels, porous glass beads or other such equivalents.
  • the polymer matrix may also include other additives for achieving desired properties.
  • the polymer matrix of the synthetic in-mold labels of the instant inven- tion may include a foldability improving agent, such as a styrene resin, in a specific content. By intro ⁇ ducing the styrene resin into the polymer matrix, the foldability of the instant synthetic in-mold labels is believed to be improved.
  • the synthetic in-mold labels of the present inventior acquire the appearance of being multi-layered which is commonly associated with conventional pulp writing paper.
  • the unique and surprising writable, print ⁇ able and paper-like properties associated with the preferred synthetic in-mold labels of the present invention are remarkably accomplished without having to resort to other complex and/or expensive mechanical, chemical and electrical processes.
  • the synthetic in-mold labels of the instant invention can be formulated with a continuous polymer matrix which incl des an effective amount of a particular filler having pre-existing microvoids formed therein for providing microvoids at, on or near the exterior surfaces thereof for imparting writability and print- ability thereto.
  • the synthetic in-mold labels of the instant invention may be formulated with other polymers or additives, or coextruded with, for example, polystyrene or the like to impart further writability to the exterior surfaces thereof.
  • the synthetic in-mold labels of the instant invention may be electrically, mechanically or chemically treated to also further impart writeability to the exterior surfaces thereof so long as the scoring objectives of the present invention are not defeated.
  • the present invention therefore now makes it possible to produce synthetic in-mold labels for hollow molded containers which can be applied during the molding operations and which include removable sections, such as proof-of-purchase coupons, which can be torn from the labels positioned on the molded containers by consumers along tear lines for redemp ⁇ tion or use to purchase additional like goods at reduced prices.
  • the novel synthetic, sectionalized in-mold labels of the instant invention uniquely afford cost saving and convenient advantages by permitting the plastic hollow molded containers labeled with such in-mold labels to be easily recycled without having to first remove the labels therefrom. It should therefore now be apparent to those versed in this field that certain of the problems attendant with paper and/or plastics in-mold labels provided hitherto are overcome in a relatively simple, yet unobvious manner by the present invention.
  • Fig. 1 is a view magnified by 5,000X of diatomaceous earth particulate filler particles having pre-existing microvoids inherent thereto which can be utilized in the instant invention;
  • Fig. 2 is a view magnified by 5,000X of a portion of a surface of an unstretched synthetic paper-like film produced with diatomaceous earth particulate filler particles having pre-existing microvoids inherent thereto in accordance with the instant invention, which illustrates such a particle on or at the surface thereof for imparting write- ability and printability thereto;
  • Fig. 3 is a view magnified by 5,000X of a portion of a cross-section of an unstretched synthetic paper-like film produced in accordance with the instant invention illustrating diatomaceous earth particulate filler particles having pre-existing microvoids inherent thereto which are dispersed therethroughout, as indicated by a sponge-like tex ⁇ ture;
  • Fig. 4 is a view magnified by 5,000X of calcium carbonate particles which appear to be devoid of any pre-existing microvoids;
  • Fig. 5 is a view magnified by 5,000X of a portion of a surface of an unstretched plastic film formed with calcium carbonate particles devoid of microvoids, which illustrates such a particle on or at the surface thereof;
  • Fig. 6 is a view magnified by 5,000X of a portion of a cross-section of an unstretched plastic film formed with calcium carbonate particles devoid of microvoids which are dispersed therethroughout;
  • Fig. 7 is a photomicrograph of a cross section magnified approximately 560X of an in-mold label of the instant invention which is approximately 0.004 inches thick with a score depth of approximately 33% of the thickness;
  • Fig. 8 is a graph of the tear strength of a score line versus the depth of a score line as a percentage of material thickness for an in-mold label formulated with a composition designated as composi- tion I in Example I;
  • Fig. 9 is a rear plan view of a plastic in-mold label of the present invention.
  • Fig. 10 is an enlarged fragmentary sectional view of the in-mold label shown in Figs. 9 and 11; and Fig. 11 is a perspective view of a hollow container labeled with the plastic in-mold label shown in Figs. 9 and 10.
  • the scored synthetic in-mold labels of the instant invention may comprise one or more layers and are intended to be applied to molded substrates, such as hollow molded containers, typically made of olefin plastic materials during the molding operations.
  • the scored in-mold labels of the present invention are also typically made of olefin plastic materials.
  • a hollow plastic container 10 such as a plastic container for motor oil, comprising an outer surface 11, a bottom wall 12, and a cap 13 mounted on a neck 14 is shown.
  • hollow plastic container 10 is depicted with a sectionalized in-mold label 20 affixed thereto.
  • Sectionalized in-mold label 20 as shown in Fig. 11 comprises permanent sections 21 and 25 divided from removable section 23 via score lines 22 and 24, respectively.
  • removable section 23 is provided with edge tab 40 for facili ⁇ tating removal of removable section 23 along score lines 22 and 24 from permanent sections 21 and 25 and from the outer surface 11 of hollow plastic container 10 « With reference to Figs.
  • a hollow plastic container labeled with an in-mold label of the instant invention is made by, for example, conventional blow molding techniques wherein a preform or parison at the blow molding temperature is enclosed in a hollow mold which has an in-mold label suitably held against a surface of the cavity of the mold by, for example, vacuum, and the parison is expanded or blown outwardly against the confines of the mold so that the in-mold label is affixed to the outer surface of the resultant hollow plastic container.
  • in-mold label 20 is made from an olefin plastic material in the form of a plastic film layer having a surface which is adapted for receiving and retaining thereon common writing and printing materials and having permanent sections 21 and 25 separated from removable section 23, which can be in the form of a proof-of-purchase coupon, by score lines 22 and 24, as indicated above.
  • core line(s) it is meant herein to refer to a line of relative weakness in the form of a groove along a predetermined path in one or more layers of an in-mold label of the instant invention which allows the in-mold label to be preferentially folded, torn, separated, divided or otherwise manipulated along that path in a manner that was not possible without the line of relative weakness, particularly when the area encompassing the line of relative weakness is sub ⁇ jected to sufficient stresses which are non-parallel thereto.
  • groove it is used herein to refer to any alteration that penetrates only a portion of but does not cut through the total thickness of an in-mold label of the instant invention.
  • the term "score line(s)" as used herein excludes perforations. It is presently believed that the lines of relative weakness imparted to the in-mold labels of the present invention are typically a result of two factors. These are a reduction in cross-sectional thickness of the material selected to form the in-mold labels of the instant invention and an introduction of a flaw or stress riser therein, e.g., the grooves.
  • a synthetic film selected to form an in-mold label of the instant invention having thickness ranges and compositions disclosed herein may have a groove depth of about 10% to about 50% of the film thickness (gauge) with a preferred depth of about 33%, as illustrated in Figs. 7 and 8.
  • Figs. 7 and 8 it can be seen that when the groove depth is less than about 10% of the material thickness, the tear strength is believed to be too great whereas when the groove depth is greater than about 50% of the material thickness, the material strength is believed to be rendered too weak to operate in accordance with the present invention.
  • the depth of a groove in a synthetic film selected to form an in-mold label of the instant invention can conceivably be of any depth so long as the depth of the groove is sufficient to accomplish the objectives of the instant invention.
  • the method involves the engagement of a sharp blade, such as a razor blade, or laser beam, into the surface of a moving web as it passes over a smooth back-up roller or stationary bar.
  • the blade is engaged by application of a force through the use of, for example, an air cylinder, weight, spring, electro- magnet or the like.
  • the required depth of cut is achieved by adjusting the force, typically in a range of between about 0.1 and about 3 lbs.
  • the necessary force of course is a function of depth of cut, blade sharpness, material properties, back-up roller diame ⁇ ter, and other factors.
  • groove depth can be regulated by establishing a blade protrusion beyond a fixed wide shoulder.
  • the shoulder would be pressed into contact with the surface of the material being grooved by the application of a force.
  • the blade would then engage the surface of the material by the amount of a preset protrusion.
  • a blade protrusion could be preset for about 0.001" for grooving a material of this invention to produce a groove depth of approximately 0.001".
  • line speed of the process affects the quality of the score line.
  • the grooving process as disclosed is believed to have no lower speed limit, and the upper speed limit has not been determined since it is believed to be outside of the range of speeds normally used to process materials of the invention.
  • the score lines formed tend to become more easily detectable as line speed is increased. This is believed to be due to localized heating which softens the material, allowing it to be displaced out of the groove areas creating a furrow effect on the surface of the material along the score lines. In most product applications, this microscopic roughness surrounding the score lines, as shown in Fig. 7, is of no significance.
  • score lines can be formed on either side of the film and at over 300 feet per minute with the score lines being virtually invisible on the final products.
  • the score lines of the instant invention may be formed by any other suitable methods, such as those disclosed in U.S. Patents, No. 4,217,327, No.
  • permanent sections 21 and 25 of in-mold label are permanently bonded to the outer surface 11 of the hollow plastic container 10 via permanent adhesive 30 whereas re ov- able section 23 is removably bonded to the outer surface 11 of the hollow plastic container 10 via removable adhesive 31.
  • Exemplary of permanent adhe- sives that may be employed include adhesive No. CA-231 distributed by Century Adhesives, adhesive No. J9775D (EVA gel lacquer adhesive) distributed by Pierce and Stevens, and adhesive No. 4983 distributed by Michel an.
  • Exemplary of removable adhesives that may be employed include adhesives distributed by Air Products under the names AIRFLEX 400 and AIRFLEX 465 (very slightly tacky) , and by Unocal under product No.
  • Exemplary of other potential adhesives include those disclosed by Wie ⁇ man, D.K. et al., Water-Borne Heat Seal Coatings for In-Mold Labeling, TAPPI Proceedings, pp 29-33 (1990 Polymers, Laminations & Coatings Conference) , such as the solvent-borne gel lacquer heat seal coatings, the water-borne heat seal coatings and the 100% solids heat seal coatings, which cited disclosure is incor ⁇ porated herein by reference in its entirety.
  • Examples of still other potential adhesives include those set forth in for example U.S. Patents, No. 4,837,075, No. 4,601,926 and No. 4,587,158, and European Patent No. 281,701 A2, all of which are incorporated herein by reference in their entireties.
  • such adhesives can be cast from a water emulsion onto the inner surface of the film at an amount of about 15 gm/yd2 or less and dried for a suitable time at a suitable temperature known to those versed in the adhesive art.
  • the application roll for the Pierce and Stevens adhesive No. J9775D may be a 140-150 line quad application roll which, when applied via such roll at that amount, can be dried at about 140-150 ⁇ F.
  • the laid down adhesive can be heat sealed to the inner surface 11 of the hollow plastic con ⁇ tainer 10 during the blow- or injection-molding processes. It is believed that when the Michelman
  • adhesive is laid down in the stated amount on a film having the composition recited in Example I, such adhesive has an adhesive strength of about 5 pli whereas the AIRFLEX 400, AIRFLEX 465 and Unocal 6130 adhesives are believed to each have an adhesive strength of about 0.15 pli, about 0.50 pli and about 0.50 pli, respectively, on the same film when laid down in about the same amounts.
  • the adhesive strength for the removable adhesive should be preferably less than or equal to about 0.2 pli.
  • the AIRFLEX 465 and Unocal 6130 adhesives are believed to be less desir ⁇ able at the above-stated lay down amounts.
  • any adhesive may vary and will depend upon the particular adhesive selected as well as the objectives intended therefor.
  • a tacky or pressure sensitive adhesive is selected, there is the possibility that it may inter- fere with the label making operations concerning the steps involving sheet and die cutting the in-mold labels into stacks.
  • tacky adhesives can also interfere when attempting to separate individual in-mold labels from the stacks for insertion into the molds during the molding operations.
  • the permanent and removable bonding means are preferably located on those surfaces of the in-mold labels which make contact with the molded substrates during the molding operations.
  • the permanent and removable bonding means are permanent and light thermal bonds, respectively
  • the permanent and removable bonding means are the surfaces of the in-mold labels making contact with the molded substrates
  • the permanent and removable bonding means are permanent and removable adhesives, respectively, such adhesives are positioned on the surfaces of the in-mold labels making contact with the molded substrates.
  • in-mold label 20 is typically formed with suitable indicia or graphics such as printing to produce identification as well as desired aesthetic effects.
  • in-mold label 20 can be provided with normal trademark and instructional material printed thereon in the permanent as well as removable sections, as shown in Fig. 11.
  • the in-mold labels of the instant invention may have printed matter on one or both sides thereof.
  • the removable section 23 of in-mold label 20 may be used for promotional purposes as a proof-of-purchase label.
  • the printing on the outside of the removable section 23 may contain instructions, for example, on how to redeem the proof of purchase label or to remove the proof-of-purchase label without destroying it.
  • In-mold label 20 is applied to the hollow plastic container 10 to form a unit as shown in Fig. 11.
  • in-mold label 20 has a perma ⁇ nent adhesive 30 on the back side of portions 21 and 5 25 and a removable adhesive 31 on the back side of removable section 23 thereof, as indicated herein ⁇ before.
  • the permanent sections 21 and 25 of in-mold label 20 can be formed with an olefin plastic material or layer which is compatible 0 with the outer surface 11 of hollow plastic container 10 so that during the molding process, these permanent sections are heat bonded to outer surface 11.
  • a foamed polystyrene label stock such as Opticite TM distributed by Dow Chemical, 5 or a coextruded label stock with an ethylene- vinylacetate (EVA) layer contacting the container could be used.
  • bonding could be enhanced by the use of corona treat ⁇ ment and high parison temperature.
  • removable section 23 can be formed with an olefin plastic material or layer which is not compatible with outer surface 11 of the hollow plastic container 10 or with a thermally insulative layer so that removable 5 section 23 will form either a light thermal bond or no thermal bond at all during the molding process. It is believed that this level of bonding can be tailored through control of temperature of the parison, temper ⁇ ature of the mold, molding pressure and/or, as already indicated, label composition.
  • removable section 23 can be bonded to the outer surface 11 of the hollow plastic container 10 via a release coating.
  • a release coating formed of, for example, a silicone, paraffin, lacquer or the like, could be applied in a line or dot pattern of any geometric type.
  • a release coating formed of, for example, a silicone, paraffin, lacquer or the like, could be applied in a line or dot pattern of any geometric type.
  • permanent adhesive bonding can be utilized only in the permanent sections in those cases where little or no thermal bonding is achieved.
  • the same permanent adhesive may be applied to the removable section of the in-mold label, but in a line or dot pattern of any geometric type to reduce the percentage of surface area bonded to effect a removable bond between the removable section of the in-mold label and the hollow plastic container.
  • removable section 23 may be provided with an edge tab 40 for facilitating the removal of removable section 23 from the hollow plastic container 10, as shown in Figs. 9 and 11 and indicated hereinbefore.
  • edge tab 40 for facilitating the removal of removable section 23 from the hollow plastic container 10, as shown in Figs. 9 and 11 and indicated hereinbefore.
  • the inner surfaces of the edge tabs should be formed with an incompatible olefin plastic layer or a thermally insulative layer so that either a very light thermal bond or no thermal bond will result during the molding process. If the olefin plastic selected to formulate the in-mold labels of the instant invention does not form thermal bonds with the outer surface of the hollow plastic containers during the molding opera ⁇ tions, no further treatment of the edge tabs is required.
  • the adhesive selected for the removable section of the in-mold label or other adhesives may be laid down over the edge tab area in the same or lesser amounts for forming a removal bond between the edge tab and outer surface of the hollow plastic container, as shown in Fig. 9.
  • the plastic in-mold labels of the instant invention are preferably produced by a process com- prising melt mixing and forming a homogeneous blend comprising an olefin resin in an amount by weight of about 60% to about 90% and a particulate filler having pre-existing microvoids provided therewith in an amount by weight of about 10% to about 40%, and thereafter shaping the melt mixed homogeneous blend into a film or sheet having a continuous matrix.
  • the microvoid particulate filler is dispersed somewhat uniformly but randomly throughout the continuous matrix such that microvoids are provided in communica- tion with the surface for imparting writeability and printability thereto, as illustrated in Figs. 1-3.
  • the film or sheet can be scored, written or printed on, adhesive or release coated on one side thereof if desired, and die cut to form the in-mold labels.
  • particulate filler having microvoids or “microvoid particulate filler,” they are used in a broad sense herein and refer to any organic or inorganic substance in the form of parti- cles having microvoids for imparting porosity, such that when the particulate filler is blended into the continuous olefin resin matrix, the particulate filler provides microvoids at, on and/or near the surfaces of the unstretched synthetic in-mold labels produced to impart writeability and printability thereto, as depicted in Figs. 1-3 and 8.
  • porate filler having microvoids or “microvoid particulate filler” are also intended to include any organic or inorganic substance which has the ability to impart effective porosity to at least the surface of an unstretched synthetic in-mold label produced in accordance with the teachings of the instant invention to impart acceptable writeability and printability thereto.
  • particulate filler having microvoids or “microvoid particulate filler” are not meant, however, to include those fillers which are incapable of imparting porosity to the surface of the in-mold labels produced for imparting good writeability or printability thereto, such as particulate fillers vir ⁇ tually devoid of microvoids and formed of nonporous materials, like calcium carbonate, as illustrated by Figs. 4-6.
  • microvoid as used herein in the above-phrases, it too is used in a broad sense herein and refers to voids smaller than about 20 microns, but nevertheless of any sufficient size for receiving and retaining writing materials for impart ⁇ ing writeability to the surfaces of the in-mold labels of the present invention. See for example the particulate filler depicted in Fig. 1, as compared to the particles illustrated in Fig. 4.
  • microvoid particulate fillers examples include diatomaceous earths, volcanic ash, silica gels, styrogels, porous glass beads and the like.
  • diatomaceous earths that may be dispersed within the continuous olefin resin matrix of the plastic in-mold labels of the instant invention include
  • microvoid particulate filler should have the properties defined above so that when dis ⁇ persed throughout the continuous olefin resin matrix of the in-mold labels in an effective amount, an effective amount of microvoids are in communication with the surface to impart writeability and print- ability thereto.
  • microvoid particulate filler to be used will of course be influenced by the size of the particles, the type of olefin resin selected, the amount of other additives used, the molding conditions, the thickness of the in-mold labels produced and the like, but generally, such particulate fillers are used in an amount of between about 5% and about 30% by weight.
  • the microvoid particulate fillers have a particle size in the range of between about 2 microns and about 20 microns, and preferably between about 5 microns and about 10 microns.
  • the olefin resins that can be used to formulate the in-mold labels of the instant invention are, for example, high density polyethylene, medium density polyethylene, low density polyethylene, ethylene-vinylacetate copolymers, ethylene-propylene copolymers, polypropylene, polybutene-1 and the like. Such olefin resins may be used individually, or in combination. High density polyethylene is especially preferred and examples thereof include those available through Dow Chemicals, HDPE (10062) and Quantum Chemical HDPE (6206) .
  • additive resins it may also be desirable to add other additive resins to the above-mentioned composition.
  • a styrene resin or the like is used as the additive resin, good printability, stiffness as well as fold- ability is imparted to the in-mold labels. It is believed, however, that good foldability typically is not obtained with a styrene resin content of less than about 5% by weight.
  • the styrene resin content should not be greater than about 10% by weight in order to prevent substan ⁇ tial lowering of the tear strength, impact strength and tensile strength of the in-mold labels produced therewith.
  • styrene resins examples include polystyrene, poly- alpha-methylstyrene, styrene-butadiene copolymers having a high styrene content, high impact poly ⁇ styrene, acrylonitrile-butadiene-styrene copolymer, acrylonitrile-styrene copolymer, styrene-methylene- methacryate copolymer and the like.
  • styrene content should be at least about 50%.
  • An example of a polystyrene resin that can be used in the instant invention may be obtained from Dow Chemicals under the trademark Styron 420 or from Phillip under polystyrene resin.
  • an inorganic filler may be further added to the in-mold label mixture of the olefin resin and microvoid particulate filler with or without the above-mentioned additive resins, such as a styrene resin.
  • additive resins such as a styrene resin.
  • the inorganic filler talc, kaline, zeolite, mica powder, asbestos powder, calcium carbonate, magnesium carbonate, calcium sulfate, clay, silica powder, aluminum magnesium sulfate, barium sulfate, zinc sulfite, titanium dioxide, zinc oxide and the like may be used.
  • an inorganic filler When an inorganic filler is selected, it is preferred that such inorganic filler have an average particle size of less than about 10 microns, and more preferably less than about 5 microns.
  • the inorganic fillers can be used in amounts of between about 0 and about 20% by weight, and preferably between about 5% to about 10% by weight.
  • calcium carbonate is particularly preferred and may be obtained from ECCA Calcium Products, Inc., Supercoat, Georgia Marble, Gamma Sphere CaCO_, and Pfizer, multi-flex MM coated and uncoated CaCO_.
  • microvoid-free inorganic fillers such as calcium carbonate
  • the particulate fillers having microvoids since effective stretching of the in-mold labels will impart the necessary porosity to the exterior surfaces thereof for permitting writing and printing thereon.
  • the in-mold labels may be pigmented to impart desirable aesthetic qual ⁇ ities by for example incorporating into the continuous matrix a colored or white pigment, such as titanium dioxide.
  • a colored or white pigment such as titanium dioxide
  • it is also possible to further add other various additives to the in-mold labels such as a plasticizer, a stabilizer or other similar agents.
  • a surfactant for promoting the dispersion of the particulate filler and/or inorganic filler, it may be advantageous to use a surfactant, a dispersing agent or other similar agent.
  • an ultraviolet ray absorbent or an anti-oxidant so as to improve weatherability of the resultant structure, or to add an anti-static agent.
  • an in-mold label having the appearance of multi-layers may result due to the fact that when an additive resin is blended into the composition, the resultant product has a tendency of sometimes undergoing separation of the olefin resin from the additive resin, such as a styrene resin, to create the appearance of a multi-layered-like struc ⁇ ture which is characteristic of conventional pulp paper.
  • an in-mold label produced in accordance with the instant invention has the charac ⁇ teristics of being stiff and foldable, and it can be torn.
  • styrene resin when utilized, it is believed that various layers may be peeled from the in-mold labels produced in accordance with the instant invention which is further characteristic of conventional pulp paper.
  • the above-mentioned specific compositions are typically melt mixed sufficiently by means of, for example, a mixing roll, a Banbury mixer, an extruder or the like, and then molded into a film or sheet by means of, for example, a calendar roll, an extruder or the like.
  • the molding is performed in a manner such that the resultant film or sheet product has a continuous olefin resin matrix with a thickness (gauge) of between about 1 mil and about 10 mils, with a preferable thickness of between about 4 mils and about 6 mils.
  • the present invention also admits of a number of variations all within the scope thereof.
  • One possibility is to form a sheet of tearable decorative material 6 mils in thickness by co-extrusion of 4 mils of the preferred compositions set forth above and 2 mils of high density polyethylene.
  • the co-extruded sheet may then be embossed or otherwise treated to form the desired tear lines before undergoing further processing to form the in-mold labels.
  • plastic film layer comprising a sheet of tearable decorative material 6 mils in thickness by co-extrusion of 4 mils of a suitable synthetic material and 2 mils of polystyrene to impart writeability and printability thereto.
  • plastic film layer by extru ⁇ sion coating the preferred polymeric film material on paper, scrim or other substrate.
  • addi- tional synthetic labels that may be employed in accordance with the teachings of the present invention include those disclosed in U.S. Patents, No. 4,904,324, No. 4,837,075 and No. 4,601,926 and in European Patent 281,701 A2, all of which are incor- porated herein by reference.
  • the in-mold labels of the instant invention are typically first formed into films or sheets which can be scored, adhesive or release coated, printed and die cut into plastic in-mold labels for labeling plastic molded articles, such as bottles, produced by, for example, blow-molding or injection-molding opera ⁇ tions.
  • the plastic in-mold labels of the instant invention have many advantages over paper labels. For example, the plastic in-mold labels and plastic articles to which they are applied can be easily and advantageously recycled.
  • the in-mold labels can be formed with removable sections, such as proof-of-purchase coupons or the like, which can be torn from the main portions of the in-mold labels by hand along the score lines without significant loss of tensile strength of the in-mold labels as a whole or without removing the main portions of the in-mold labels affixed to the molded containers.
  • the in-mold labels of the present invention may be applied to the plastic molded containers by vacuum during article molding operations in accordance with techniques well known to those versed in the art, such as those described in U.S. Patents, No. 4,708,630, No. 3,108,850, and No. 3,417,175, all of which are incor ⁇ porated herein by reference in their entireties.
  • a scored, synthetic in-mold label of the instant invention and a hollow molded plastic con ⁇ tainer labeled therewith can be produced in accordance with the following brief description.
  • a roll of film produced in accordance with Example I is unwound and past through scoring equipment. All score lines, which are preferentially made simultaneously, are positioned relative to one another and a reference edge. Once the score lines have been made, the film is rewound.
  • the scored roll of film is then unwound into appropriate adhesive coatings and printing equipment.
  • the adhesive coats are patterned relative to a reference edge with three levels of adhesive being laid down on preferably the score line side. A high level of adhesive is laid down where the remov ⁇ able section, i.e., proof-of-purchase coupon, is not.
  • a low level of adhesive is laid down where the remov ⁇ able section, i.e., proof-of-purchase coupon, is. With respect to the edge tab, no adhesive is laid down at the edge tab portion of the removable section. If desired, however, the same low level of adhesive that is laid down over the removable section can be laid down over the edge tab region in the same or lesser amounts.
  • the solvents are flashed from the adhesives. Thereafter, appropriate colors and patterns relative to the reference edge and in register with the tab area can be printed. Following each printing station, the solvents should be flashed. Once complete, the printed and adhesive coated, scored film is rewound.
  • the printed and adhesive coated, scored roll of film is unwound into sheet cutting equipment.
  • the film is then sheet cut relative to the printing and adhesive, and stacked.
  • the stacks of labels are shear cut in register with label graphics and adhesive coating into stacks of individual label blanks.
  • Pick-and-place device with vacuum end effector picks finished labels from magazine and places them individually in open container mold.
  • Composition I By Weight High density polyethylene About 62%
  • Titanium dioxide " 5% Composition II By Weight
  • Titanium dioxide " 6%
  • the pellet is extruded with, for example, a conven ⁇ tional single screw extruder into a film or sheet having a continuous olefin resin matrix and a thick ⁇ ness of between about 1 mil and about 10 mils, and preferably about 4 mils to about 6 mils.
  • the resulting unstretched film or sheet exhibits excellent receptivity and retentivity for common writing mate ⁇ rials, such as ink, pencil lead, paint and the like, when it is written or printed on the surface thereof.
  • the sheet or film of Example I can be blown or cast, embossed, matte or flat.
  • a suitable heat acti- vatable adhesive is applied or coated onto selected sections on one side of the film.
  • the adhesive is such that the adhesion properties are preferentially activated in a subsequent blow-molding or injection- molding operation during application of the in-mold label to a plastic container.
  • suitable score lines are made and selected decorative patterns are applied to the appropriate sections normally by printing, to provide an in-mold label design and information required for the finished article, such as a bottle or container.
  • the printing can be done by various methods including rotogravure, offset, flexographic and the like.
  • Surface primers may be coated onto the film prior to printing to enhance printing.
  • Protec- tive coatings such as a lacquer, may be applied on top of the printing to protect the printing from moisture, abrasion, etc.
  • the film is then die cut, used as label stock in an in-mold label application.
  • the adhesively coated, scored film may be first cut into sheets, then printed, and finally die cut into individual labels.
  • rotogravure printing the sheet or film is printed and die cut after printing. After die cutting, the film is then in the proper shape and size for the final label.
  • the finished labels are applied to the bottle or container during the in-mold labeling operation.
  • This process involves directly applying the in-mold labels via vacuum inside of the mold during the blow molding operation which forms the bottle or container.
  • the semi-molten parison extruded into the mold when blown, expands and contacts the label strategically positioned within the mold and in particular the adhesive or release coating side thereof as well as the mold wall, at which point the molten plastic solidifies to form the finished article.
  • the heat from the molten plastic activates the adhesive on the film and forms the bond between the bottle or container and the film.
  • the in-mold labels of this Example are believed to perform equally as well as equivalent paper-based products, with the added advantages of: 1.) the in-mold labels may match the thermal charac ⁇ teristics, i.e., melting temperature, shrinkage, heat capacity, etc. , of the blow molded plastic bottles or containers; and 2.) scrap molded bottles or containers formed with the in-mold labels of this Example may be easily recycled due to the fact that the in-mold labels are formed with materials similar in nature to those utilized to form the bottles or containers. Moreover, because the in-mold labels of this Example ar formed with materials generally similar in nature to those utilized tc form the bottles or containers, the conformity problem due to shrinkage normally associated with paper labels is substantially, if not totally, eliminated.
  • the overall product performance during use of the bottles or containers is believed to be greatly enhanced by use of the in-mold labels of this invention.
  • the in-mold labels produced in accordance with the instant invention are effective substitutes for conventional pulp paper and the like.
  • the in-mold labels of the instant invention provide simple, but unobvious means heretofore unavailable for providing in-mold labels.

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Theoretical Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Blow-Moulding Or Thermoforming Of Plastics Or The Like (AREA)

Abstract

L'invention décrit de nouvelles étiquettes synthétiques, pourvues de rayures, à moulage incorporé par procédé in-mold (20) ainsi que des substrats moulés sous forme, par exemple, de réservoirs creux en plastique (10) sur lesquels lesdites étiquettes sont fixées. Les nouvelles étiquettes synthétiques (20) sont appliquées aux réservoirs creux en plastique pendant les opérations de moulage desdits réservoirs, au moyen d'un procédé sous vide. Les étiquettes à moulage incorporé (20) sont produites à partir de résines oléfines et peuvent se présenter sous forme de structures à couches unique ou multiples. De plus, les étiquettes présentent des rayures définissant des lignes d'affaiblissement (22, 24) servant à les diviser en sections amovibles et non amovibles (23 et 21, 25) qu'on peut séparer les unes des autres manuellement le long des lignes d'affaiblissement (22, 24). On peut fixer les sections non amovibles (21, 25) aux réservoirs moulés au moyen d'adhésifs permanents (30) ou par points de soudure thermique, tandis qu'on peut fixer les sections amovibles aux réservoirs moulés par l'intermédiaire de revêtements détachables, d'adhésifs amovibles (31) ou par points de soudure thermique légère. De façon alternative, les sections amovibles (23) peuvent être conçues pour ne pas être fixées aux réservoirs moulés. Lesdites sections amovibles (23) des étiquettes à moulage incorporé (20) peuvent se présenter sous forme de coupons de preuve d'achat.
PCT/US1991/007386 1990-10-16 1991-10-03 Etiquettes synthetiques a moulage incorpore par procede in-mold et pourvues de rayures ainsi que substrats moules servant a les fixer WO1992007347A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US59836490A 1990-10-16 1990-10-16
US598,364 1990-10-16

Publications (1)

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WO1992007347A1 true WO1992007347A1 (fr) 1992-04-30

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AU (1) AU9030891A (fr)
IE (1) IE913622A1 (fr)
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WO (1) WO1992007347A1 (fr)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0587178A3 (fr) * 1992-09-10 1995-08-02 Oji Yuka Goseishi Kk Label avec coupon, réalisé durant moulage.
EP0854051A1 (fr) * 1997-01-17 1998-07-22 Nitto Denko Corporation Feuille adhésive imprimable et étiquette
EP0891861A1 (fr) * 1997-07-17 1999-01-20 Alusuisse Technology & Management AG Matériau pour emballage et couvercle
US6432528B1 (en) 1998-12-09 2002-08-13 3M Innovative Properties Company Variably printed tape and system for printing and applying tape onto surfaces
US6884312B2 (en) 2002-04-12 2005-04-26 3M Innovative Properties Company Apparatus for printing and applying tape and methods of printing and applying tape
US6910820B2 (en) 2003-07-25 2005-06-28 3M Innovative Properties Company Apparatus and method for handling linerless label tape
US6991261B2 (en) * 2001-06-22 2006-01-31 Multi-Color Corporation Labels with removable section for in-mold production of in-mold labeled molded containers
FR2926066A1 (fr) * 2008-01-04 2009-07-10 Europlastiques Soc Par Actions Contenant ou couvercle recouvert par une etiquette amovible en partie pour un emballage.
CN103366636A (zh) * 2012-03-28 2013-10-23 深圳坤邦标价用品有限公司 一种模内标签及其制造方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2119746A (en) * 1982-05-04 1983-11-23 Millet Marius & Cie Labelling plastics objects, such as plastics containers
FR2602487A1 (fr) * 1986-08-11 1988-02-12 Verreries Generales Recipient avec etiquette ou manchon solidement fixe
EP0349670A1 (fr) * 1988-06-28 1990-01-10 HAGEN & SORENSEN A/S Etiquette pour récipients, en particulier pour bouteilles en verre ou plastique

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2119746A (en) * 1982-05-04 1983-11-23 Millet Marius & Cie Labelling plastics objects, such as plastics containers
FR2602487A1 (fr) * 1986-08-11 1988-02-12 Verreries Generales Recipient avec etiquette ou manchon solidement fixe
EP0349670A1 (fr) * 1988-06-28 1990-01-10 HAGEN & SORENSEN A/S Etiquette pour récipients, en particulier pour bouteilles en verre ou plastique

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0587178A3 (fr) * 1992-09-10 1995-08-02 Oji Yuka Goseishi Kk Label avec coupon, réalisé durant moulage.
EP0854051A1 (fr) * 1997-01-17 1998-07-22 Nitto Denko Corporation Feuille adhésive imprimable et étiquette
US6090483A (en) * 1997-01-17 2000-07-18 Nitto Denko Corporation Adhesive sheet for printing and label
EP0891861A1 (fr) * 1997-07-17 1999-01-20 Alusuisse Technology & Management AG Matériau pour emballage et couvercle
US6258425B1 (en) 1997-07-17 2001-07-10 Alusuisse Technology & Management Ltd. Packaging and lidding material
US6432528B1 (en) 1998-12-09 2002-08-13 3M Innovative Properties Company Variably printed tape and system for printing and applying tape onto surfaces
US6991261B2 (en) * 2001-06-22 2006-01-31 Multi-Color Corporation Labels with removable section for in-mold production of in-mold labeled molded containers
US6884312B2 (en) 2002-04-12 2005-04-26 3M Innovative Properties Company Apparatus for printing and applying tape and methods of printing and applying tape
US6910820B2 (en) 2003-07-25 2005-06-28 3M Innovative Properties Company Apparatus and method for handling linerless label tape
US7220071B2 (en) 2003-07-25 2007-05-22 3M Innovative Properties Company Apparatus and method for handling linerless label tape
FR2926066A1 (fr) * 2008-01-04 2009-07-10 Europlastiques Soc Par Actions Contenant ou couvercle recouvert par une etiquette amovible en partie pour un emballage.
FR2927314A1 (fr) * 2008-01-04 2009-08-14 Europlastiques Soc Par Actions Contenant ou couvercle recouvert par une etiquette amovible en partie pour un emballage
CN103366636A (zh) * 2012-03-28 2013-10-23 深圳坤邦标价用品有限公司 一种模内标签及其制造方法
CN103366636B (zh) * 2012-03-28 2016-08-17 深圳坤邦标价用品有限公司 一种模内标签及其制造方法

Also Published As

Publication number Publication date
IE913622A1 (en) 1992-04-22
MX9101609A (es) 1992-06-05
AU9030891A (en) 1992-05-20

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