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WO1993006038A1 - Procede de production de brome a partir d'eau de mer - Google Patents

Procede de production de brome a partir d'eau de mer Download PDF

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Publication number
WO1993006038A1
WO1993006038A1 PCT/US1992/007822 US9207822W WO9306038A1 WO 1993006038 A1 WO1993006038 A1 WO 1993006038A1 US 9207822 W US9207822 W US 9207822W WO 9306038 A1 WO9306038 A1 WO 9306038A1
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WO
WIPO (PCT)
Prior art keywords
stream
hbr
seawater
catalyst
bromine
Prior art date
Application number
PCT/US1992/007822
Other languages
English (en)
Inventor
Paul F. Schubert
Arnold R. Smith
Henry Taube
David W. Schubert
Original Assignee
Catalytica, Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Catalytica, Inc. filed Critical Catalytica, Inc.
Publication of WO1993006038A1 publication Critical patent/WO1993006038A1/fr

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/08—Halides
    • B01J27/122—Halides of copper
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B7/00—Halogens; Halogen acids
    • C01B7/09—Bromine; Hydrogen bromide
    • C01B7/096—Bromine

Definitions

  • This invention is a combination process for producing elemental bromine using a seawater feed.
  • the process involves a series of steps in which seawater is acidified, chlorinated, and air stripped to remove the bromine.
  • the stripping effluent is reacted with an S0 2 stream to convert the bromine to hydrogen bromide and H 2 S0 4 in the air stream.
  • the process continues by absorbing hydrogen bromide and H 2 S0 4 from the resulting acidic fog to produce an aqueous H 2 S0 4 stream containing HBr.
  • the HBr is stripped from the liquid stream and passed to a oxidation reactor where it is catalytically oxidized with an oxygen-containing gas to produce a stream of Br 2 and H 2 0.
  • the hot reactor effluent is quenched and the product Br 2 is separated from the H 2 0 and any inert gases such as air.
  • This invention is a process for producing elemental bromine from hydrogen bromide recovered from seawater involving a catalytic oxidation step.
  • the catalytic oxidation step permits the inventive process to eliminate nearly 50% of the chlorine requirements of the known processes.
  • Bromine is a chemical feedstock often used for the production of bromoalkanes or olefins from alkanes. Bromine is present in nature only in dilute sources such as in seawater or in brines of the Dead Sea or the United States.
  • the classic process for producing bromine from seawater involves a multistage process of acidifying and chlorinating the brine to release elemental bromine into a solution; aerating the resulting dilute solution; reacting the bromine with S0 2 to produce hydrogen bromide and sul uric acid; absorbing the hydrogen bromide and sulfuric acid from the aeration effluent into water; heating, chlorinating, and steaming the resulting absorbate; stripping the bromine overhead; and decanting the resulting overhead product to recover the bromine.
  • This invention includes a catalytic process sequence which may be inserted into the classic process as a substitute for the steps of heating, chlorinating, and steaming the aeration effluent. The process steps may include: (a) stripping the aeration effluent to produce an HBr/H 2 0 stream,
  • the soluble metal may be gold, cerium, chromium, nickel, platinum, thorium, titanium, or vanadium; but preferably is iron or copper.
  • a gas containing oxygen is passed through the acidic solution containing HBr and the dissolved metal, all at a temperature below the boiling point of the liquid. The gaseous effluent is then separated via condensation and distillation into product bromine, water, and HBr for recycle to the oxidation step.
  • U.S.Pat.No. 3,179,498, to Harding et al disclose a process in which a nitrite catalyst is employed in the acidic, aqueous solution of HBr to effect the oxidation of the HBr to Br 2 .
  • the temperature of the liquid is maintained between 0° and 100°C.
  • preferred catalysts are alkali or alkaline earth metal nitrites.
  • U.S. Pat. No. 2,536,457, to Mugdan teaches such a process.
  • the conversion is carried out at a temperature between 800° and 1200°C (preferably between 800° and 1000°C) with an excess of oxygen.
  • the catalyst is preferably cerium oxide and may be supported on pumice granules or other refractory materials. If excessive water is included in the reactor, a combustible gas such as hydrogen is included to maintain the reaction temperature. Clearly the reaction temperature for this process is quite high.
  • U.S. Pat. No. 3,273,964 shows a process in which the effluent from a dehydrobromination reaction is contacted with a catalyst-adsorbent composite.
  • the effluent contains olefinic hydrocarbons and is produced by a series of steps in which an alkane is brominated to form a bromoalkane; the bromoalkane is then dehydrobrominated to form the effluent of olefinic hydrocarbons and HBr.
  • the catalyst-adsorbent composite adsorbs the HBr in a first step and, during regeneration, catalyzes the oxidation of HBr to form the desired Br 2 .
  • the composite contains an adsorbent of a basic metal oxide such as magnesium, calcium, or zinc oxide, and a catalyst of a Group IV-B metal oxide such as titania, magnesia, or zirconia.
  • the preferred composite contains magnesia and zirconia in a ratio from about 0.5:1 to about 5:1.
  • U.S. Pat. No. 3,260,568, to Bloch et al. teaches a process in which a stream containing substantially dry HBr contacts a solid adsorbent containing a metal "subchloride" and which is the reaction product of a refractory metal oxide and a metal chloride.
  • the contact takes place at conditions where the HBr replaces at least a portion of the chloride in the adsorbent.
  • the adsorbent When the adsorbent has reached about six percent by weight, the adsorbent is regenerated by contacting it with a dry hydrogen chloride gas.
  • the patent does not appear to suggest the conversion of the adsorbed-HBr to Br 2 even though the adsorbent is suggested to be selected from metal chlorides such as aluminum, antimony, beryllium, iron, gallium, tin, titanium, and zinc chlorides.
  • 3,310,380 discloses a process for the adsorption of combined bromine (e.g., HBr and alkyl bromides) on a catalytic-adsorbent composite, recovering unsaturated hydrocarbons, and when the adsorbent is filled, contacting the composite with an oxygen-containing gas at a temperature between 50° and 450°C to produce a Br 2 stream also containing water and unreacted HBr.
  • This stream (also in admixture with an oxygen-containing gas) is then contacted with a second stage reactor also containing the composite but at a temperature between 200° and 600°C.
  • the composite in the first stage comprises, preferably, 0.5 to 10% by weight of copper or cerium oxide composited on magnesium oxide: the second stage composite comprises, preferably, 2.0 to about 50% by weight of copper or cerium oxide composited on an alumina or zirconia support.
  • U.S. Pat. No. 3,346,340 suggests a process for the oxidation of HBr to Br 2 using a catalyst-inert support composite.
  • the composite comprises a copper or cerium oxide on an inert support having a surface area between 5 and 100 square meters per gram and containing less than about 50 micromoles of hydroxyl per gram.
  • the supports may be alpha- or theta- alumina or zirconia.
  • the preferred temperature is between 300° and 600°C.
  • U.S. Pat. No. 3,353,916, to Lester discloses a two stage process for oxidizing HBr to form Br 2 by the steps of mixing the HBr-containing gas with an oxygen- containing gas and passing the mixture at a temperature of at least 225°C over a catalyst selected from the oxides and salts of cerium, manganese, chromium, iron, nickel, and cobalt and converting a major portion of the HBr to Br 2 .
  • the partially converted gas, still containing excess oxygen, is then passed through a second stage catalyst comprising a copper oxide or salt at a temperature of at least about 225°C but not exceeding a "catalyst peak temperature" of 35Q°C to convert the remaining HBr.
  • the preferred support appears to be zirconia.
  • This two-stage arrangement is carried out to prevent loss of copper catalyst. Because the preferred copper oxide is converted to copper bromide during the course of the reaction, at reaction conditions, and copper bromide volatilizes at "temperatures in excess of about 350°C", the "copper bromide migrates through the catalyst mass in the direction of flow with eventual loss of copper bromide and premature deactivation."
  • U.S. Pat. No. 3,379,506, to Massonne et al. discloses a process for the selective oxidation of hydrogen bromide to bromine in the presence of fluoro ⁇ arbons by passing the mixture of gases over a Deacon catalyst at a temperature of 250 to 475°C, preferably between 300 and 400°C.
  • the Deacon catalyst is said to be a "mostly porous carrier such as pumice, alumina, silica gel, clay, or bentonite, impregnated with a solution of bromides or chlorides of metals such as copper, iron, titanium, vanadium, chromium, manganese, cobalt, molybdenum, tungsten, or mixtures thereof."
  • the preferred catalyst is said to be a chloride of copper.
  • "£a] very efficient and stable catalyst is an oxidation catalyst which is prepared by impregnating active alumina with chlorides of copper, rare earths and ⁇ or alkali metals, drying at about 120°C and subsequent activation at a temperature of 300° to 450°C.”
  • One example shows the production and use of a catalyst of alumina, potassium, copper, and an amount of "rare earths of the cerite group as chlorides”.
  • Another patent which notes the problem with the volatilization of copper bromide in the oxidation of hydrogen bromide to bromine is U.S. Pat. No. 3,437,445, to Hay et al. The solution is to eliminate the copper in favor of a noble metal, such as platinum and palladium.
  • the reaction is carried out at a temperature of about 175° and about 700 ⁇ C with a contact time of at least about 0.1 sec, "but for best operation a contact time of about five and 25 seconds is preferred.”
  • the yield of bromine is only between 28 and 78 molar percentage.
  • U.S. Pat. No. 4,131,626, to Shar a et al. suggests a process in which bromide salts are heated in the presence of an oxygen-containing gas, silicon dioxide, and an oxidation catalyst at a temperature of about 500° to 1000°C. The bromine is produced in conjunction with sodium silicate.
  • This invention is a process for producing Br 2 from seawater in which an intermediate catalytic step comprises oxidizing hydrogen bromide with 0 2 to form that elemental bromine.
  • seawater is screened of solid material such as seaweed and fish and acidified with H 2 S0 4 to produce an acidified stream having a pH between 3.0 and 3.5. This improves bromine recovery by suppressing the hydrolysis of bromine as it is formed:
  • This acid fog is then condensed or absorbed and introduced to a refluxed stripping column using, e.g., steam, to form a wet vaporous stream of HBr and a liquid stream of H 2 S0.
  • the H 2 S0 4 may be recycled to the initial acidification step.
  • the vaporous HBr is mixed with an oxygen-containing gas and heated to a temperature between about 125°C and about 500°C.
  • the heated gas mixture is passed over the catalyst at conditions suitable for the formation of bromine.
  • the bromine is then separated from the feed and co-produced water by quenching, absorbing the Br 2 in a bromide salt solution and desorbing pure Br 2 .
  • the Br 2 may be further dried, if so desired.
  • Figure l shows a block diagram of a generic embodiment of the inventive process.
  • Figure 2 is a schematic diagram of a known process for producing Br 2 from seawater.
  • Figure 3 shows a schematic of a front end of a process modified from the process shown in Figure 2 providing a feedstream for the processes shown in Figures 4 and 5.
  • FIGs 4 and 5 show preferred process embodiments of this invention as terminal portions of the Figure 3 process steps.
  • Figure 6 is a graph of the performance of a preferred HBr oxidation catalyst over a range of operating temperatures.
  • Figure 7 is a graph of the performance of a preferred HBr oxidation catalyst over a period of time.
  • this invention is an improved process for producing bromine from seawater.
  • Several of the steps of the process are from an older process in wide use.
  • the improvement largely involves an intermediate catalytic step of oxidizing hydrogen bromide with an oxygen-containing gas to form elemental bromine according to the equation: 4 HBr + 0 2 > 2 Br 2 + 2 H 2 0. This step permits elimination of the chlorine oxidation step utilized in the older process.
  • This invention is a process for producing Br 2 from seawater in which an intermediate catalytic step comprises oxidizing hydrogen bromide to that elemental bromine.
  • the catalyst desirably comprises a supported copper or cerium bromide but may comprise a homogeneous catalyst system generally as described below.
  • seawater is screened of solid material such as seaweed and fish and is mixed with H 2 S0 4 to produce an acidified stream having a pH between 3.0 and 3.5.
  • H 2 S0 4 This improves bromine recovery by suppressing the hydrolysis of bromine as it is formed in a later step:
  • the bromine is then stripped from the acidified, chlorinated seawater in an aerator or air stripper to form a dilute Br 2 fog and a bromine-depleted seawater stream.
  • the dilute bromine fog is reacted with sulfur dioxide and forms an acid fog:
  • FIG. 2 shows a widely used variation of a process for producing Br 2 from seawater.
  • the bromine content of seawater varies throughout the oceans of the world but often is in the range of about 50 to 70 ppm.
  • the bromine typically is completely ionized or nominally in the form of a salt such as NaBr.
  • the process involves introducing the seawater through a pipeline (202) into a solids separator (204) such as a screen or filter to remove large or entrained solids, e.g. , seaweed, fish, mud and sand.
  • a solids separator (204) such as a screen or filter to remove large or entrained solids, e.g. , seaweed, fish, mud and sand.
  • the filtered seawater is then transported via line (206) and thoroughly mixed with a H 2 S0 4 stream (210) in that line (206) .
  • the pH level of the liquid in line (206) is maintained at about 3.0-3.5 so to prevent hydrolysis of produced Br 2 .
  • the form of mixing line (206) is obviously not critical but need only be substantially resistant to corrosion at the noted conditions.
  • the acidified seawater is then mixed with a chlorine stream (212) .
  • the bromide ion in the seawater is oxidized using that chlorine in the following manner: 2 Br" + Cl 2 —> Br 2 + 2
  • the resulting stream (214) is then sent to a packed stripping column (218) where a stream of air (216) is utilized to strip the bromine from the liquid.
  • the resulting water stream (220) is then properly disposed of, typically by returning it to the sea.
  • the vapor stream (222) from aerator (218) is a very dilute stream of Br 2 and water usually in the form of a saturated vapor or "fog" in air.
  • This vapor stream (222) is then mixed with sulfur dioxide (224) and forms a dilute acidic vaporous stream (226) of hydrobromic and sulfuric acids:
  • This acid stream (226) is contacted with a water stream (232) in absorber (230) .
  • the air stream (234) is relatively clean; it may be recycled if so desired.
  • the resulting aqueous H 2 S0 4 /HBr stream (236) is then of sufficient strength to be efficiently oxidized.
  • the aqueous H 2 S0 4 /HBr stream (236) is optionally heated in exchanger (238) by feed/effluent exchange with the heated effluent stream (246) and mixed with a second chlorine stream (240) again to oxidize the bromine ion; a portion of the chlorine is introduced through line (241) to the bottom of stripping column (242) : 2 Br" + Cl 2 —> Br 2 + 2 el" .
  • the bromine is then stripped in a steam stripper (242) .
  • the steam (244) in steam stripper (242) separates the incoming stream into a liquid sulfuric acid/hydrochloric acid stream (246) and a gaseous Br 2 stream (248) containing some Cl 2 and H 2 0 vapor.
  • the gaseous Br 2 /Cl 2 /H 2 0 is condensed in exchanger (249) .
  • a water phase (containing some Br 2 ) (262) from decanter (254) is used as reflux in column (242) .
  • the Br 2 product (260) is discharged from the bottom of the decanter (254) through line (260) into the purification unit (255) .
  • the purification unit (255) is used to remove chlorine for recycle via line (261) and drying of the Br 2 product.
  • the Br 2 product is discharged from the unit in line (263) . After drying and chlorine removal, the Br 2 product stream (263) is suitable for use
  • SUBSTITUTESHEET in that it contains only about 0.5-1.0 % water, but is often subjected to a drying step by contact with a strong (93-97 %) sulfuric acid stream.
  • our process eliminates the necessity of introducing additional chlorine at (240) and (241) to oxidize the bromide ion to Br 2 and instead utilizes an oxidation step using 0 2 or air to produce the Br 2 product. In practical terms, nearly half of the chlorine requirement of the prior art process is eliminated by use of our process.
  • Figure 3 shows a front end portion of our inventive process adapting several stages of the prior art process mentioned above and suitable for producing an HBr stream which may be used in our catalytic oxidation stage as described below with respect to Figures 4 and 5.
  • the solids separator (204) , mixing line (206) , stripping column or aerator (218) , and absorber (230) are all used as in the process shown in Figure 2.
  • the aqueous H 2 S0 4 /HBr stream (236) is subjected to a steam stripping step in stripper (302) .
  • the stripper utilizes a small reflux to prevent sulfuric acid entrainment in the overhead HBr/H 2 0 (308) stream.
  • the bottom stream (310) is typically aqueous sulfuric acid and may be used to acidify the seawater in the front end of the process.
  • the overhead HBr/H 2 0 (308) stream may be subjected to an S0 2 removal step (312) using an appropriate adsorbent or a combination of a condenser to condense the HBr/H 2 0 stream, an oxidation step of converting the S0 2 to H 2 S0 4 by reaction with introduced Br 2 , and a reboiled stripper column to strip HBr from the resulting liquid stream.
  • This step may be desirable only if there is a trace of S0 2 remaining in the feedsteam.
  • the resulting HBr stream (314) may then be applied to the oxidation stages shown below.
  • Figures 4 and 5 show desirable integrated processes for the oxidation of HBr to Br 2 using the catalyst described above.
  • Figure 4 shows a process using reasonably pure 0 2 as the process feed;
  • Figure 5 shows a process in which air is the process feed.
  • the oxidation step involves the simple expedient of mixing the gaseous or vaporous HBr from the feed preparation step with a suitable amount of an oxygen-containing gas, such as air, oxygen-enhanced air, or oxygen and passing the mixture to the catalyst.
  • the 0 2 is desirably added in an amount producing an HBr:0 2 molar ratio of between about 3.00 and 4.25.
  • the 0 2 may be present in excess not only to assist in the HBr oxidation but also to oxidize any hydrocarbonaceous materials present in the feedstream. Nevertheless an HBr:0 2 molar ratio of between above 3.9 and up to 4.1 is preferred.
  • the HBr-0 2 mixture is then passed through one or more beds of the catalysts described above.
  • the temperature in the reactor may be controlled in a variety of ways. For instance, if an adiabatic reactor is desired, the feed HBr likely will need be diluted with steam, nitrogen, air, product stream recycle, or the like to prevent excessive temperature rise in the reactor.
  • the HBr feedstream may have an HBr content of between 25% and 99.5% (wt) but desirably has an HBr content between 35% and 55% (wt) but most preferably between 45% and 55% (wt) .
  • the catalyst bed or beds may be fluidized or ebullated if so desired. Fluidization allows superior control of the bed temperature and prevents the occurrence of "hot-spots" in the catalyst.
  • the materials of construction for the reactor should be selected using normal materials criteria but bearing in mind that the system is fairly corrosive. For instance, if the reactor is operated at the lower end of the reaction range noted above and the reactor is a nickel alloy, the reactor should be maintained above the temperature of condensation lest liquid phase corrosion occur. Similarly, the upper range of temperature should be controlled to prevent vapor phase corrosion. If a ceramic system is chosen, similar criteria are applicable to prevent dissolution of the ceramic or to prevent creep of the polymeric seals used at joints and flanges.
  • an HBr stream (314) is introduced from the front end process shown in Figure 3.
  • the HBr feedstream (preferably of about 48% HBr in water) is sent to an evaporator (404) and to a superheater (406) .
  • the resulting HBr vapor should be at a
  • SUBSTITUTESHEET temperature of about 230-250°C.
  • the oxygen feedstream (408) is similarly warmed to about 230-250°C with superheater (410) .
  • the heat for superheaters (406) and (410) may, for instance, be supplied by a circulating hot oil system including hot oil heater (412) .
  • the heated HBr feedstream and the heated oxygen feedstream are then mixed to form a reactor feedstream (414) which is then introduced into reactor (416) .
  • the reactor (416) is desirably of a multi-tube design containing the catalyst or may be of a multi-bed design. Since the reaction is quite exothermic, reactor designs which are capable of removing the heat of reaction from the catalyst mass are obviously very desirable.
  • the reactor design shown is also used as a steam generator.
  • the reaction product stream (418) may then be cooled in two stages.
  • the first stage of cooling (420) shown is a desuperheater and merely lowers the temperature of the stream down to the neighborhood of the stream's dew point, e.g., about 150°C. This stream is then condensed and cooled to a temperature of about 40°C in condenser (422) .
  • the condensate is then separated into a liquid Br 2 stream (424) saturated with water, a water stream (426) saturated with Br 2 , and a vaporous vent stream (428) containing unreacted oxygen, bromine, water, and a small amount of inerts.
  • the device used for that separation (430) may be a simple phase separation device such as a decanter. Other density separation devices are just as suitable.
  • the vapor stream (428) is then chilled in refrigeration unit (432) to a temperature sufficient to remove most of the Br 2 found in the vent stream.
  • the condensed Br 2 stream is separated in drum (432) and the resulting Br 2 stream (434) is mixed with Br 2 stream (424) for further processing.
  • SUBSTITUTESHEET oxygen vapor stream (436) is scrubbed in a gas treater (438) using, for instance, sodium hydroxide remove any remaining Br 2 before the treated oxygen is vented (440) into the atmosphere.
  • the vent gas treatment step may be omitted and recycled into the reactor (416) if the oxygen is of sufficient purity.
  • the aqueous stream (426) coming from the separator (432) is then stripped of its Br 2 content in a distillation column (442) .
  • Distillation column (442) produces two streams.
  • the overhead vapor stream (444) is condensed in overhead condenser (446) and collected in reflux drum (448) .
  • the reflux drum (448) is a decanter design.
  • the lighter phase is largely water and is recycled to the distillation tower (442) as reflux.
  • the heavier phase is Br 2 and the stream (450) is mixed with other Br 2 streams, (424) and (434) , for further treatment such as by drying with strong H 2 S0 4 in a countercurrent absorption tower (456) .
  • the tower produces a weaker H 2 S0 4 stream and the desired Br 2 product stream (458) .
  • the oxidation process step is preferably operated using a less concentrated oxygen feedstream, e.g., air or oxygen-enriched air. This variation is shown in Figure 5.
  • an HBr feedstream (314) is sent to an evaporator (504) and to a superheater (506) .
  • the air feedstream (508) is compressed in compressor (509) and heated in superheater (510) .
  • the heat for superheaters (506) and (510) may, for instance, be supplied by a circulating hot oil system including hot oil heater (512).
  • the heated HBr feedstream and the heated oxygen feedstream are then mixed to form a reactor feedstream (514) which is then introduced into reactor (516) .
  • the reactor (516) is desirably of a design similar to that described above although because of the additional diluent in the feedstream is a little less sensitive to reactor design, but those which are capable of removing the heat of reaction from the catalyst mass are obviously very desirable.
  • the reaction product stream (518) may then be cooled in two stages.
  • the first stage of cooling (520) shown is a desuperheater and lowers the temperature of the stream down to the neighborhood of the stream's dew point, e.g., about 150°C.
  • This stream is then condensed and cooled to a temperature of about 40°C in condenser (522) .
  • the condensed reactor product stream (524) is fed to a phase separator (526) where it is separated into an aqueous stream (528) saturated in Br 2 and containing any unconverted HBr and an overhead vapor stream (530) containing all of the Br 2 .
  • the aqueous stream (528) may be treated in a manner similar to that discussed above.
  • the aqueous stream (528) coming from the separator (526) is stripped of its Br 2 content in a distillation column (530) .
  • Distillation column (530) produces an overhead vapor stream (532) which is condensed in overhead condenser (534) and collected in reflux drum (536) . Water from the drum is recycled to the distillation tower (530) as reflux.
  • the Br 2 stream (538) is mixed with other Br 2 streams for further treatment such as drying.
  • the bottom stream (540) from distillation tower (530) is reboiled.
  • the stream is mostly water and contains unconverted HBr feed and the water of reaction formed in the reactor (516) . All or a portion of this stream (542) may be neutralized to produce a waste water stream (546) or maybe recycled via line (548) .
  • the overhead vapor stream (N 2r Br 2 , and H 2 0) may be introduced into the bottom of an absorption column (550) where cold (-15°C) lean NaBr brine (552) is fed to the top to act as absorption media for Br 2 .
  • the overhead stream (554) is substantially free of Br 2 .
  • the bottom stream (556) is heated (preferably in feed-effluent heat exchanger (558) with the heat from the bottom of stripper column (560)) and introduced into stripper column (560) .
  • Br 2 is stripped from the NaBr brine into an overhead stream (562) . That steam is condensed in exchanger (564) and collected in reflux vessel (566) .
  • the water stream is decanted in reflux vessel (566) and is both used as reflux in stripper tower (560) and in the feed to distillation tower (530) .
  • the vapor line (568) from the reflux drum (566) may be mixed with the overhead vapor stream (554) from absorber (550) and treated by neutralization in absorber (570) to remove any remaining HBr before disposing of the N 2 via vent (572) .
  • the decanted Br 2 (574) from reflux vessel (566) may be mixed with the Br 2 stream (538) from reflux vessel (536) and treated with concentrated H 2 S0 4 in absorber (576) to remove water and produce the dry product Br 2 .
  • the Catalyst Catalysts suitable for this process include a wide variety of supported or homogeneous materials.
  • the active catalyst may be selected from the metals; and the oxides, halides (particularly chlorides and bromides) , and oxyhalides of the following metals: Group IB (particularly Cu) , Group IVB (particularly Ti and Zr) , Group VB (particularly V) , Group VIB (particularly Cr,Mo, and W) , Group VIIB (particularly Mn and Re), Group VIII (particularly Fe, Co> Ni, Pt, And
  • the active catalyst may be promoted with one or more Group IIA metals (particularly Ca) or lanthanides, if so desired.
  • the active catalyst and the promoter,if any, may be supported on known catalyst supports such as MgO, A1 2 0 3 (particularly in eta- or delta-form) , Zr0 2 , Hf0 2 , Si0 2 (particularly in silica gel form) , clays such as bentonite or attapulgite, and natural materials such as pumice.
  • the active catalysts listed above should be present in at least a catalytic amount, that is to say, an amount sufficient at least to catalyze the reaction of HBr and oxygen to produce Br 2 .
  • Active catalytic metals depending upon the metal selected, may be present in the amount of 0.1 % to 35 % (by weight) of the overall composition is desirable; 1.0 % to 20 % (by weight) of catalytic metal is more desirable and 3.0 % to 10.0 % (by weight) of catalytic metal is most desirable.
  • the promoters/stabilizers may be any salt or complex of the noted metals, whether oil or water soluble, which can be impregnated onto the catalyst support or mixed with the support, e.g. , as by ball milling with the support precursor.
  • the bromide salts are especially suitable, but other halides (iodide or chloride) , oxyhalides, oxides, phosphates, sulfides, sulfates; complexes such as acetylacetonates, and the like are also suitable.
  • the bromides, oxybromides, oxides, and mixtures are useful and conveniently available.
  • the promoter/stabilizer metal-bearing material should be present in an amount such that the overall content (in whatever form) is desirably between 0.1 % and 10 % (by weight) of the overall composition; 1.0 % to 6.0 % (by weight) is more desirable; 1.0 % to 4.0 % (by weight) is most desirable.
  • the catalyst support is zirconium- containing, it desirably contains more than about 50% (wt) of zirconia.
  • a minor amount of other metal oxides, e.g., alumina, titania, yttria, silica, hafnia, etc., may be included as a binder or extrusion aid or to increase surface area if so desired.
  • the support is zirconium-containing or not, it is desirable to use a support which has significant porosity in the range between 30 and lOoA, e.g., > 0.01 cc/gm pore volume in the range of 30 and 10oA.
  • the preferred catalyst comprises promoted copper bromide on a zirconia support.
  • the copper bromide does not substantially migrate from the catalyst composition nor among different regions of the catalyst and is very active. This high activity permits the use of comparatively lower temperatures thereby enhancing, even more, the catalyst's stability.
  • This preferred catalyst is produced by placing copper bromide directly onto the support, and is not made by converting another copper-bearing material into copper bromide on the support.
  • the support most desirably comprises a zirconium-containing material such as zirconia, other supports are suitable.
  • the preferred catalyst is a composite comprising or desirably consisting essentially of copper bromide; promoter/stabilizer selected from materials containing one or more salts, oxides, or complexes of metals selected from Ca, Y, Nd, or La or of metals having an ionic radius between about.0.9 and 1.4 A; and an oxidic zirconium-containing catalyst support.
  • promoters are Nd and La. Most preferred is La.
  • the copper bromide should be present in at least a catalytic amount, that is to say, an amount sufficient at least to catalyze the reaction of HBr and oxygen to produce Br 2 .
  • a catalytic amount that is to say, an amount sufficient at least to catalyze the reaction of HBr and oxygen to produce Br 2 .
  • copper bromide in the amount of 0.1 % to 20 % (by weight) of the overall composition is desirable; 1.0 % to 6 % (by weight) of copper bromide is more desirable and 3.0 % to 6.0 % (by weight) of copper bromide is most desirable.
  • SUBSTITUTESHEET support in the form of copper bromide results in a catalyst composition which is both more stable and more active than compositions in which the catalyst is introduced in another form, such as by the oxide.
  • the x-ray diffraction spectrum (Cu ⁇ ) of the catalyst composition does not show the presence of crystalline CuBr 2 .
  • the x- ray diffraction spectrum of crystalline CuBr 2 contains the following lines:
  • the bromide salts are especially suitable, but other halides (iodide or chloride) , oxyhalides, oxides, phosphates, sulfides, sulfates; complexes such as acetylacetonates, and the like are also suitable.
  • the promoter/stabilizer metal-bearing material should be present in an amount such that the overall content (in whatever form) is desirably between 0.1 % and 10 % (by weight) of the overall composition; 1.0 % to 6.0 % (by weight) is more desirable; 1.0 % to 4.0 % (by weight) is most desirable.
  • the zirconium-containing support typically should contain more than about 50% (wt) of zirconia.
  • a minor amount of other metal oxides e.g., alumina, titania, yttria, hafnia, silica, etc., may be included as a binder or extrusion aid or to increase the surface area or porosity if so desired.
  • a zirconia support which has significant porosity in the range between 30 and lOoA, e.g., > 0.01 cc/gm pore volume in the range of 30 and 10oA.
  • the catalyst material may be utilized in any physical form convenient to the process in which it is utilized. Such forms may include tablets, extrudates, raschig rings, Pall rings, or the like.
  • the reaction is very exothermic and consequently the relative external surface area may be an important consideration in some reactor/process configurations.
  • the catalyst desirably is prepared by dissolving the appropriate catalyst metal and the promoter/stabilizer metal compounds or complexes independently in aqueous acid, preferably HBr, solutions and impregnating them into the catalyst supports.
  • the catalyst supports should be dried at, e.g., 110° to 135°C in air, before impregnation so to allow accurate measurement of the metal content added to the support.
  • the method and sequence of impregnating the support has not been found to be critical. If the various compounds
  • SUBSTITUTESHEET are compatible, e.g., they don't react together and don't precipitate from solution, a single solution containing the metals may be used as the impregnating solution. Depending upon the impregnating procedure chosen, the solutions may be saturated or not. If an incipient wetness method is selected, the amount of solution will match the pore volume of the support requiring that the composition of the solution be adjusted to assure that the amount of metal added to the support is appropriate. If other procedures are elected, saturated solutions may be used and a particular amount of the solutions chosen. The impregnated support is dried and ready for use.
  • This example shows a long term test of the a highly desired CuBr 2 /LaBr 3 /Zr0 2 catalyst in the HBr oxidation step.
  • a pore diameter was used to prepare the CuBr 2 /LaBr 3 /Zr0 2 catalyst.
  • the support was a powdered zirconia support which was impregnated with solutions of CuBr 2 and LaBr 3 and pressed in a die using a carved press. This pressing was then ground and sieved to give a 20-30 mesh fraction.
  • the finished catalyst contained 0.2 mmoles/cc of CuBr 2 and 0.6 mmoles/cc of LaBr 3 .
  • the pore size distributions were determined using a Micromeritics Autopore II 9220 mercury porosimeter.
  • the catalyst was tested for activity using the following procedure:
  • a 1 cm OD by 45 cm long glass reactor tube was filled to about its length-wise center with glass beads.
  • a glass wool plug was then inserted. About 1 cc of catalyst was placed on the glass wool. Another glass wool plug was placed over the catalyst bed. The remainder of the glass tube was packed with glass beads.
  • the glass reactor was then placed in a tube furnace with an aluminum sleeve between the outer reactor wall and the inner wall of the furnace to aid in heat distribution.
  • a thermocouple was included at the center of the catalyst bed.
  • a 48% HBr solution was delivered to the reactor at a rate of 6 cc/hr using a syringe pump. During the test, the syringe pump had to be refilled about every 20 hours.
  • the reaction products and unreacted feed materials were condensed in traps containing KI.
  • the product Br 2 formed reacts there with the KI to form the I 3 ' ion.
  • the I 3 _ ion was then titrated with Na 2 S 2 0 3 .
  • the amount of bromine formed in the reactor was calculated from the titration results.
  • the reactor effluent was collected in the traps, measured at various intervals, and the reaction rates calculated. The measured rate at intervals over the 100 hours is shown in the Table. The data show no decrease in activity over the 100 hour run, and perhaps show some increase in activity during that period. This indicates good long term life for the CuBr 2 /LaBr 3 /Zr0 2 catalyst.
  • This example shows the use of the preferred CuBr 2 /LaBr 3 /Zr0 2 oxidation catalyst in the temperature range between 150°C and 350°C.
  • the catalyst was tested as in Example 1; again, the rate of 48% HBr feed was 6 cc/hr, and the rate of 0 2 feed was 6 cc/min.
  • the temperature was varied to produce bed temperatures ranging from 150° to about 350°C.
  • Figure 6 shows the average reaction rates for the catalyst as a function of temperature for a 2 hour test.
  • This example shows the use of an homogeneous catalyst system for conversion of HBr to Br 2 .
  • a 250 ml Fisher-Porter bottle equipped with an overhead stirrer was charged with 30 g CuBr 2 (as catalyst) and 110 ml of 48% HBr.
  • the assembly was placed in an oil bath and brought to about 135°C.
  • the stirring rate was 750 rpm.
  • Anhydrous HBr was metered to the reactor at 350 ml per minute and 0 2 was fed at 750 ml per minute.
  • the total pressure was maintained at 50 psig.
  • a gas stream continuously stripped any Br 2 formed in the system, which Br 2 was trapped downstream using a KI trap.
  • the trap operated to detect the amount of Br 2 formed in the reactor by reacting with the Br 2 to form the I 3 " ion.
  • the I 3 " ion was titrated with NaS 2 0 3 and the amount of produced Br 2 was calculated using the result.
  • the traps were checked about every ten minutes.
  • Figure 7 shows the rate of Br ⁇ production as a function of time. This example shows the effectiveness of the catalyst in oxidizing HBr to Br 2 .

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Abstract

Cette invention concerne un procédé combiné permettant de produire du brome élémentaire à partir d'eau de mer. Le procédé comprend une série d'étapes au cours desquelles l'eau de mer est acidifiée, chlorée et strippée avec de l'air pour retirer le brome. On fait réagir l'effluent de stripage avec un courant de SO2 afin de convertir le brome en bromure d'hydrogène et H2SO4 dans le courant d'air. Le procédé se poursuit par absorption du bromure d'hydrogène et de H2SO4 du brouillard acide obtenu afin de produire un courant aqueux de H2SO4 contenant HBr. Le HBr est strippé du courant liquide puis on le fait passer vers un réacteur d'oxydation où il subit une oxydation catalytique avec un gaz contenant de l'oxygène afin de produire un courant de Br2 et H2O. L'effluent chaud du réacteur est refroidi brusquement et le produit Br2 est séparé de H2O et des gaz inertes tels que l'air. Dans la figure 2, l'eau de mer entre dans la conduite (202) et est mélangée à un courant de H2SO4 (200). Le courant résultant (214) est envoyé à une colonne de stripage (218) dans laquelle un courant d'air (216) sépare le brome du liquide. Le courant B22 sous forme de vapeur (222) est mélangé à SO2 (224) qui est mis en contact avec un courant d'eau. Le courant aqueux obtenu de H2SO4/HBr (236) est chauffé et mélangé à un courant de chlore (240). Une partie du chlore est introduite dans la conduite (241) et amenée au fond de la colonne de stripage (242) et se sépare avec la vapeur (244) en un courant (246) contenant H2O4 et HCl se sépare avec le courant (244) en un courant (246) contenant H2SO4 et HCl et le courant (248) contenant Br2. Le produit Br2 (260) est déchargé du décanteur (254) dans l'unité de purification (255).
PCT/US1992/007822 1991-09-16 1992-09-16 Procede de production de brome a partir d'eau de mer WO1993006038A1 (fr)

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GB2351282A (en) * 1999-06-15 2000-12-27 Tosoh Corp Recovering bromine from dilute aqueous bromide solutions
RU2246510C2 (ru) * 1998-12-24 2005-02-20 Омя Аг, Сн Обработанный наполнитель, или пигмент, или минерал для бумаги, в частности, пигмент, содержащий природный карбонат кальция, способ его получения, содержащие его композиции и их применения
WO2013177438A3 (fr) * 2012-05-23 2014-01-16 Grt, Inc. Conversion du propane en propylène
CN112902447A (zh) * 2021-01-27 2021-06-04 潍坊惠贤信息科技有限公司 一种氢溴酸母液加热管控装置、方法及其应用
EP3936472A3 (fr) * 2020-07-10 2022-04-06 Reaction 35, LLC Procédé de récupération et de séparation de brome et d'eau à partir de l'oxydation du bromure d'hydrogène
CN117430088A (zh) * 2023-11-07 2024-01-23 绍兴市上虞众联环保有限公司 一种工业含溴废盐制备溴素的资源化处置方法

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US2536457A (en) * 1944-08-29 1951-01-02 Distillers Co Yeast Ltd Recovery of bromine from hydrogen bromide
FR1291932A (fr) * 1961-05-26 1962-04-27 California Research Corp Oxydation catalytique de l'acide bromhydrique au moyen d'oxygène gazeux
US3816599A (en) * 1971-11-16 1974-06-11 Lummus Co Hydrogen chloride recovery
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Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2246510C2 (ru) * 1998-12-24 2005-02-20 Омя Аг, Сн Обработанный наполнитель, или пигмент, или минерал для бумаги, в частности, пигмент, содержащий природный карбонат кальция, способ его получения, содержащие его композиции и их применения
US7638017B2 (en) 1998-12-24 2009-12-29 Omya Development Ag Filler or pigment or processed mineral for paper, in particular a pigment containing natural CaCO3, its manufacturing process, preparations containing it and their applications
EP3020769A1 (fr) 1998-12-24 2016-05-18 Omya International AG Nouvelle charge ou pigment ou mineral traité pour papier, notamment pigment contenant du caco3 naturel, son procédé de fabrication, compositions les contenant, et leurs applications
GB2351282A (en) * 1999-06-15 2000-12-27 Tosoh Corp Recovering bromine from dilute aqueous bromide solutions
GB2351282B (en) * 1999-06-15 2001-05-02 Tosoh Corp Method for collecting bromine
US8940954B2 (en) 2011-05-23 2015-01-27 Reaction35, LLC Conversion of propane to propylene
CN104903278A (zh) * 2012-05-23 2015-09-09 反应35有限责任公司 丙烷转化为丙烯
WO2013177438A3 (fr) * 2012-05-23 2014-01-16 Grt, Inc. Conversion du propane en propylène
EP3936472A3 (fr) * 2020-07-10 2022-04-06 Reaction 35, LLC Procédé de récupération et de séparation de brome et d'eau à partir de l'oxydation du bromure d'hydrogène
IL284667B1 (en) * 2020-07-10 2024-09-01 Reaction 35 Llc Process for recovery and separation of bromine and water from oxidation of hydrogen bromide
IL284667B2 (en) * 2020-07-10 2025-01-01 Reaction 35 Llc Process for recovering and separating bromine and water from the oxidation of hydrogen bromide
CN112902447A (zh) * 2021-01-27 2021-06-04 潍坊惠贤信息科技有限公司 一种氢溴酸母液加热管控装置、方法及其应用
CN117430088A (zh) * 2023-11-07 2024-01-23 绍兴市上虞众联环保有限公司 一种工业含溴废盐制备溴素的资源化处置方法

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