WO1993010049A1 - Procede de purification d'eau - Google Patents
Procede de purification d'eau Download PDFInfo
- Publication number
- WO1993010049A1 WO1993010049A1 PCT/RU1992/000190 RU9200190W WO9310049A1 WO 1993010049 A1 WO1993010049 A1 WO 1993010049A1 RU 9200190 W RU9200190 W RU 9200190W WO 9310049 A1 WO9310049 A1 WO 9310049A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- water
- iron
- suspension
- vοdy
- выяв
- Prior art date
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 47
- 238000000034 method Methods 0.000 title claims description 16
- 238000000746 purification Methods 0.000 title abstract description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 79
- 239000000725 suspension Substances 0.000 claims abstract description 42
- 229910052742 iron Inorganic materials 0.000 claims abstract description 41
- 239000006185 dispersion Substances 0.000 claims abstract description 8
- 238000004519 manufacturing process Methods 0.000 claims description 5
- 239000012535 impurity Substances 0.000 abstract description 6
- 239000008188 pellet Substances 0.000 abstract description 2
- 239000010865 sewage Substances 0.000 abstract description 2
- 239000003643 water by type Substances 0.000 abstract description 2
- 229910021645 metal ion Inorganic materials 0.000 abstract 1
- 229910001960 metal nitrate Inorganic materials 0.000 abstract 1
- 150000002823 nitrates Chemical class 0.000 abstract 1
- 238000001179 sorption measurement Methods 0.000 abstract 1
- 238000005406 washing Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 description 12
- 238000004364 calculation method Methods 0.000 description 9
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- 229910000831 Steel Inorganic materials 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 239000010959 steel Substances 0.000 description 5
- 239000002699 waste material Substances 0.000 description 5
- 239000002253 acid Substances 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- 238000009434 installation Methods 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 239000002585 base Substances 0.000 description 3
- 239000003651 drinking water Substances 0.000 description 3
- 238000001914 filtration Methods 0.000 description 3
- 229910001385 heavy metal Inorganic materials 0.000 description 3
- 239000008213 purified water Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000002351 wastewater Substances 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 235000020188 drinking water Nutrition 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 238000005265 energy consumption Methods 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 229910001339 C alloy Inorganic materials 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- -1 Iron metals Chemical class 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
- 210000000988 bone and bone Anatomy 0.000 description 1
- 235000012206 bottled water Nutrition 0.000 description 1
- 238000001311 chemical methods and process Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 230000007717 exclusion Effects 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 210000004907 gland Anatomy 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 150000002506 iron compounds Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000005923 long-lasting effect Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000001465 metallisation Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 238000011017 operating method Methods 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
- 239000002594 sorbent Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 210000004291 uterus Anatomy 0.000 description 1
- 238000004065 wastewater treatment Methods 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/281—Treatment of water, waste water, or sewage by sorption using inorganic sorbents
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/70—Treatment of water, waste water, or sewage by reduction
- C02F1/705—Reduction by metals
Definitions
- ⁇ atsi ⁇ naln ⁇ e is ⁇ lz ⁇ - vanie and the calculation of water for machine-building enterprises ( Russia, 1988, pp. 159-170).
- the waste of the machine is a large waste of iron and electricity and the unreliability of the operation of the electric & zarea.
- the method of calculating water from heavy metals with the use of iron was also known (Application Japan 52-45665). Therefore, the water supply, which contains heavy metals, imports 5-7% of iron with a dispersion of 25-150 mkm, which results in a minimum of 30 WATER PREPARATION AND THEREFORE ARE AVAILABLE FOR ACCOUNTING PROCESSES - SEDIMENTS.
- the waste water is a large amount of iron by-pass (up to 15 to 75 g per 1 liter of water or 50 to 300 g per day).
- the disadvantage is not a very high degree of purity of water and a greater amount of suspension of suspension - and, consequently, - 3 - and iron for clean water (from 7.7 to 26 g for cleaned impurities contained in water).
- Pe ⁇ vaya task ⁇ eshae ⁇ sya blag ⁇ da ⁇ ya ⁇ mu, ch ⁇ in izves ⁇ - n ⁇ m s ⁇ s ⁇ be ⁇ chis ⁇ i v ⁇ dy ⁇ u ⁇ em introducing therein sus ⁇ enzii, ⁇ luchenn ⁇ y ele ⁇ e ⁇ zi ⁇ nnym dis ⁇ e ⁇ i ⁇ vaniem iron v ⁇ - dB and vyde ⁇ zhann ⁇ y d ⁇ ⁇ b ⁇ az ⁇ vaniya magne ⁇ i ⁇ a, and ⁇ e ⁇ emeshivaniya ⁇ sleduyuscheg ⁇ ⁇ deleniya ⁇ sad ⁇ a, ele ⁇ e ⁇ zi ⁇ nn ⁇ mu dis ⁇ e ⁇ - gi ⁇ vaniyu shdve ⁇ gayu ⁇ gubcha ⁇ e zhelez ⁇ , ⁇ luchenn ⁇ e the restoration of iron ore bites.
- Spongy iron obtained by the restoration of hydrogen in the water (metalization) of iron ore is produced in bulky cases of non-profitability for non-payment.
- the casters provide a 5–15 mm diameter sponge made of sponge thermal passive iron. They can have a long service (a year or more) to get out of the way without getting into it.
- the chemical composition of the glands - other waste products is regulated by technical conditions and in them the presence of such foreign impurities as copper, zinc and other is not allowed.
- the proposed method does not acidify all the water that is being cleaned, but only the suspension that is introduced into it, which is 100-1000 times less than water. This leads to a reduction in acid costs.
- the water changes little. Therefore, with clearly neutral or weakly alkaline water, the following neutralization is not required, which reduces the resultant click. All of this is provided by the material parties and is subject to the prior art.
- the proposed method includes the following operations
- Iron metals are not removed (those installed in the water) and are thermally passive and they are electrically discharged. Making this incident possible may be unsuccessful, such as taking, for example, CCC * 663515 and * 997988.
- the mixture is stored in the factory, where it is kept for 5-30 minutes before the precipitation occurs.
- ⁇ chis ⁇ i took 500 ml * ⁇ myvn ⁇ G v ⁇ dy having a 1" value ⁇ , u ⁇ azannuyu of ⁇ ablitse I, s ⁇ e ⁇ i ⁇ vali value ⁇ e ⁇ "v ⁇ dy d ⁇ values ⁇ 2, u ⁇ azann ⁇ g ⁇ of ⁇ ablitse 1 d ⁇ bav- ⁇ y in e ⁇ u v ⁇ du ⁇ i ⁇ e ⁇ eme ⁇ ivanii its ⁇ as ⁇ v ⁇ a se ⁇ n ⁇ y ⁇ isl ⁇ - ⁇ y.
- Suspension is obtained in the same way as in Example I. With the help of the suspension, there is a purification of drinking water. For this, the suspension is described with salic acid * to ⁇ • 5, and then it is absorbed from the waste and the standard consumer appliance. " After the appliance has been dispensed with drinking water with a flow rate of 30 l / h, it is immediately analyzed for the contents before and after the calculation. The results of the experiment are given in table 3. EXAMPLE 4.
- the raw material base is expanding for the production of depreciation due to the involvement of new raw materials in iron ore - iron ore; - the degree of contamination of the suspension in the process of its irradiation with random impurities is reduced due to the fact that the chemical composition of the iron ore particles is controlled;
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
Abstract
L'invention concerne le traitement des eaux et peut être utilisée pour extraire des ions métalliques, des nitrates ainsi que d'autres impuretés pendant la purification d'eaux d'égoût, de lavage et autre. On procède à la purification par sorption des impuretés au moyen d'une suspension obtenue par dispersion par électroérosion dans l'eau d'éponge de fer obtenu, à son tour, par réduction de pellets de minerai de fer.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
SU5013611 | 1991-11-22 | ||
SU5013611/26 | 1991-11-22 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1993010049A1 true WO1993010049A1 (fr) | 1993-05-27 |
Family
ID=21590073
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/RU1992/000190 WO1993010049A1 (fr) | 1991-11-22 | 1992-10-19 | Procede de purification d'eau |
Country Status (1)
Country | Link |
---|---|
WO (1) | WO1993010049A1 (fr) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2001034526A1 (fr) * | 1999-11-12 | 2001-05-17 | San Diego State University Foundation | Procedes d'elimination des perchlorates |
US7393454B2 (en) * | 2001-03-13 | 2008-07-01 | Centre National De La Recherche Scientifique (C.N.R.S) | Elimination of metal ions from aqueous effluents |
CN105502733A (zh) * | 2015-12-02 | 2016-04-20 | 南京大学 | 一种协同去除及选择性回收废水中重金属阳离子和非金属阴离子的方法 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3960723A (en) * | 1972-12-26 | 1976-06-01 | Ford Motor Company | Magnetization of iron chromium system |
US4362629A (en) * | 1980-10-08 | 1982-12-07 | Murata Manufacturing Co., Ltd. | Method for processing solution including heavy metal |
WO1992010427A1 (fr) * | 1990-12-07 | 1992-06-25 | Environ Umweltschutz Aktiengesellschaft | Procede de purification d'eau |
-
1992
- 1992-10-19 WO PCT/RU1992/000190 patent/WO1993010049A1/fr unknown
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3960723A (en) * | 1972-12-26 | 1976-06-01 | Ford Motor Company | Magnetization of iron chromium system |
US4362629A (en) * | 1980-10-08 | 1982-12-07 | Murata Manufacturing Co., Ltd. | Method for processing solution including heavy metal |
WO1992010427A1 (fr) * | 1990-12-07 | 1992-06-25 | Environ Umweltschutz Aktiengesellschaft | Procede de purification d'eau |
Non-Patent Citations (1)
Title |
---|
REFERATIVNY ZHURNAL, "Khimia", 19 Svodny Tom, ch. 11, 1988, "VINITI", (Moscow), page 45, Abstract 22I358, AZAKI HIROAKI, "Udalenie Rastvorennykh Tyzhelykh Metallov s Pomoschju Khimicheskoi Koagulyatsii"; & page 48, Abstract 22I380, DAGDIGIAN J.V., "Ekonomicheski Vygodnaya Tekhnologia Ochistki Stochnykh Vod". * |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2001034526A1 (fr) * | 1999-11-12 | 2001-05-17 | San Diego State University Foundation | Procedes d'elimination des perchlorates |
US6531065B2 (en) | 1999-11-12 | 2003-03-11 | San Diego State University Foundation | Perchlorate removal methods |
US7393454B2 (en) * | 2001-03-13 | 2008-07-01 | Centre National De La Recherche Scientifique (C.N.R.S) | Elimination of metal ions from aqueous effluents |
CN105502733A (zh) * | 2015-12-02 | 2016-04-20 | 南京大学 | 一种协同去除及选择性回收废水中重金属阳离子和非金属阴离子的方法 |
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